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Research about Colorado

Source-linked reports with geographic coverage including Colorado.

At least 289 records · Page 16Linked to original sources

Atmospheric dust deposition varies by season and elevation in the Colorado Front Range, USA

As atmospheric dust deposition continues to increase across the southwestern United States, it has the potential to alter ecosystem productivity and structure by delivering nutrients, base cations, and pollutants to remote mountain sites. Due to the sparse distribution of dust monitoring sites, open questions remain about the spatial and temporal variability of dust fluxes and composition across mountainous terrain. We present a 1 year (November 2017 to November 2018) record of seasonal dust fluxes and composition from an elevation transect across the Colorado Front Range extending from the urban plains to the remote alpine. At all nine sites, dust was enriched in the essential nutrient phosphorus and the metals copper, zinc, lead, and cadmium, elements that are enriched in dust deposited at sites across the Rocky Mountain West. We observed a seasonal pattern in dust composition, with the highest concentrations of zinc and cadmium during the summer, when back trajectory modeling suggested a greater contribution of dust from local urban and agricultural regions to the east of the collection sites. During the summer, there was also a trend of higher dust fluxes at lower elevations; dust fluxes ranged from 18.9 ± 0.1 g m −2 yr −1 on the plains to 5.9 ± 0.2 g m −2 yr −1 in the alpine. Our results suggest that urban and agricultural land east of the Colorado Front Range is an important source of nutrients and pollutants to all elevations of the mountain range.

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Elevation and elevation-change maps of Fountain Creek, southeastern Colorado, 2015–19

The U.S. Geological Survey, in cooperation with Colorado Springs Utilities, has been collecting topographic data at 10 study areas along Fountain Creek, Colorado, annually since 2012. The 10 study areas are located between Colorado Springs and the terminus of Fountain Creek at the Arkansas River in Pueblo. The purpose of this report is to present elevation maps based on topographic surveys collected in 2015 and 2019 and to present maps of elevation change that occurred between 2015 and 2019 at all 10 study areas. Elevation and elevation-change maps were developed in ArcGIS from topographic surveys collected at each study area using real-time kinematic Global Navigation Satellite Systems during the winter months (January through April) of 2015 and 2019. Elevation-change maps were created using statistically defined minimum levels of change detection asso-ciated with the 68-percent confidence limit and the 95-percent confidence limit. Study areas along Fountain Creek underwent a range of geomorphic responses between 2015 and 2019 that often depended on the dominant channel pattern of the study area. The results of this ongoing monitoring effort can be used to assess long-term changes in land-surface elevation and to advance understanding of the geomorphic response to possible alterations in flow conditions on Fountain Creek.

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Salt flushing, salt storage, and controls on selenium: A 31-year mass-balance analysis of an irrigated, semiarid valley

Salinity, selenium, and uranium pose water‐quality challenges for the Arkansas River in southeastern Colorado and other rivers that support irrigation in semiarid regions. This study used 31 years of continuous discharge and specific conductance (SC) monitoring data to assess interannual patterns in water quality using mass balance on a 120‐km reach of river. Discrete sampling data were used to link the SC records to salinity, selenium, and uranium. Several important patterns emerged. Consumptive use reduced discharge by a median value of 33% and drove corresponding increases in salinity and uranium concentrations. Increased water availability for irrigation from rainfall and upstream snowpack in 1995–1999 flushed additional salinity and uranium into the river in 1996–2000; average annual total dissolved solids (salinity) concentrations increased 25%, and loads increased 131%. Smaller flushing events have occurred, sometimes lagging an increase in water availability by about one year. The pattern indicates flushing of salts temporarily stored, evaporatively concentrated, or of geologic origin. Mobilization of selenium from the reach was minor compared to salinity and uranium, and net selenium removal from the river was suggested in some years. Several processes related to irrigation could be removing selenium. The results provide context for efforts to improve water quality in the Arkansas River and rivers in other semiarid regions.

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Seasonal manganese transport in the hyporheic zone of a snowmelt-dominated river (East River, Colorado)

Manganese (Mn) plays a critical role in river-water quality because Mn-oxides serve as sorption sites for contaminant metals. The aim of this study is to understand the seasonal cycling of Mn in an alpine streambed that experiences large spring snowmelt events and the potential responses to changes in snowmelt timing and magnitude. To address this goal, annual variations in river-water/groundwater interaction and Mn (aq) transport were measured and modeled in the bed of East River, Colorado, USA. In observations and numerical models, oxygenated river water containing dissolved organic carbon (DOC) mixes with groundwater rich in Mn (aq) in the streambed. The mixing depth increases during spring snowmelt when river discharge increases, leading to a greater DOC supply to the hyporheic zone and net respiration of Mn-oxides, despite an enhanced supply of oxygen. As groundwater upwelling resumes during the subsequent baseflow period, Mn (aq) -rich groundwater mixes with oxygenated river water, resulting in net accumulation of Mn-oxides until the bed freezes in winter. To explore potential responses of Mn transport to different climate-induced hydrological regimes, three hydrograph scenarios were numerically modeled (historic, low-snow, and storm) for the Rocky Mountain region. In a warming climate, Mn (aq) export to the river decreases, and Mn (aq) oxidation is favored in the upper streambed sediments over more of the year. One important implication is that the streambed may have an increased sorption capacity for metals over more of the year, leading to potential changes in river-water quality.

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Geologic map of the Homestake Reservoir 7.5′ quadrangle, Lake, Pitkin, and Eagle Counties, Colorado

The Homestake Reservoir 7.5' quadrangle lies at the northwestern end of the Upper Arkansas Valley, and headwaters of the Arkansas River, and the Roaring Fork, Fryingpan, and Eagle Rivers of the Colorado River system. The quadrangle lies within tectonic provinces of the 1.4 giga-annum (Ga) Picuris orogeny and includes the late Paleozoic Ancestral Rockies, Late Cretaceous-Paleocene Laramide orogeny, Oligocene-to-Miocene and Pliocene? volcanism, and Miocene to the present Rio Grande rift extensional tectonics. In the eastern half of the quadrangle, high-angle, east-dipping, Neogene normal faults displace Proterozoic rocks, and locally Miocene-to-Pliocene? volcanic rocks. Many quartz veins and hydrothermally altered zones are exposed along the eastern flank of the quadrangle, indicative of the multiple tectonic episodes the region has experienced. The main intent of the map is to unravel the structural complexity by partitioning the structures and volcanism within the appropriate geologic interval. This ultimately permits accurate identification of geomorphic features suitable for chronologies related to landscape evolution studies, seismic and other natural hazard identification, ground and surface water modeling, and paleoclimatic studies. Within the western half of the quadrangle, Mesoproterozoic and Paleoproterozoic igneous and metamorphic rocks of 1.4 Ga St. Kevin Granite and 1.8–1.7 Ga Biotite gneiss and schist, respectively, are uplifted along the generally east-dipping, high-angle Sawatch fault system. In the northwest portion of the quadrangle, strands of the Homestake shear zone have been mapped, dated and assigned to the 1.4 Ga Picuris orogeny of northern New Mexico. 10 Be and 26 Al cosmogenic nuclide ages of the youngest glacial deposits indicate a last glacial maximum age of about 22–21 kilo-annum (ka) and complete deglaciation by about 14 kilo-annum, supported by chronologic studies in adjacent drainages. The Turquoise Lake impounding lateral and terminal moraine complex was deposited during late Pleistocene glacial maximum ~22–21 ka. No late Pleistocene tectonic activity is apparent within the quadrangle.

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Dust deposited on snow cover in the San Juan Mountains, Colorado, 2011-2016: Compositional variability bearing on snow-melt effects

Light-absorbing particles in atmospheric dust deposited on snow cover (dust-on-snow, DOS) diminish albedo and accelerate the timing and rate of snow melt. Identification of these particles and their effects are relevant to snow-radiation modeling and thus water-resource management. Laboratory-measured reflectance of DOS samples from the San Juan Mountains (USA) were compared with DOS mass loading, particle sizes, iron mineralogy, carbonaceous matter type and content, and chemical compositions. Samples were collected each spring for water years 2011-2016, when individual dust layers had merged into one (all layers merged) at the snow surface. Average reflectance values of the six samples were 0.2153 (sd, 0.0331) across the visible wavelength region (0.4-0.7 µm) and 0.3570 (sd, 0.0498) over the full-measurement range (0.4-2.50 µm). Reflectance values correlated inversely to concentrations of ferric oxide, organic carbon (1.4-10 wt. %), magnetite (0.05-0.13 wt. %), and silt (PM63-3.9; median grain sizes averaged 21.4 µm) but lacked correspondence to total iron and PM10 contents. Measurements of reflectance and Mössbauer spectra and magnetic properties indicated that microcrystalline hematite and nano-size goethite were primarily responsible for diminished visible reflectance. Positive correlations between organic carbon and metals attributed to fossil-fuel combustion, with observations from electron microscopy, indicated that some carbonaceous matter occurred as black carbon. Magnetite was a surrogate for related light-absorbing minerals, dark rock particles, and contaminants. Similar analyses of DOS from other areas would help evaluate the influences of varied dust sources, wind-storm patterns, and anthropogenic inputs on snow melt and water resources in and beyond the Colorado River basin.

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Persistence and plasticity in conifer water-use strategies

The selective use of seasonal precipitation by vegetation is critical to understanding the residence time and flow path of water in watersheds, yet there are limited datasets to test how climate alters these dynamics. Here, we use measurements of the seasonal cycle of tree ring 18O for two widespread conifer species in the Rocky Mountains of North America to provide a multi-decadal depiction of the seasonal origins of forest water use. The results show that while the conifer tree stands had a dominant preference for use of snowmelt, there were multi-annual periods over the last four decades when use of summer precipitation was preferential. Utilization of summer rain emerged during years with increased snowfall and tree growth, suggesting that summer rain enhanced the transpiration stream only during the periods of highest water use. We hypothesize this could be explained through shallowing of the root profile during wetter periods and/or through the influence of changing water table depths on the residence time of summer precipitation in the root zone. We suggest the tree ring proxy approach used here could be applied in other watersheds to provide critical insight into the temporal dynamics of plant water use that could not be inferred from short measurement campaigns. These data on the seasonal origins of forest water are critical for understanding forest vulnerability to drought, the processes that affect precipitation pathways and residence time in watersheds and the interpretation of tree ring proxy data.

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The influence of frost weathering on the debris flow sediment supply in an alpine basin

Rocky, alpine mountains are prone to mass wasting from debris flows. The Chalk Cliffs study area (central Colorado, USA) produces debris flows annually. These debris flows are triggered when overland flow driven by intense summer convective storms mobilizes large volumes of sediment within the channel network. Understanding the debris flow hazard in this, and similar alpine settings, requires determining the magnitude of sed- iment accumulation between debris flow seasons, and identifying the control on sediment production. To address these knowledge gaps, we measured changes in sediment produc- tion using a sediment retention fence to quantify how sedimentation was influenced by temperature at the plot scale. These measurements were extrapolated to a larger area, where we extended the sediment fence results to explore how rockfall sedimentation con- tributed to channel refilling between active debris flow periods. This work shows debris flow channel refilling is correlated with low temperatures and time in the frost-cracking window, implicating frost weathering mechanisms as a key driver of sedimentation. This sediment production process resulted in a large amount of sediment accumulation dur- ing a single winter season in our study reach (up to 0.4 m in some locations). Using these observations, we develop a channel refilling model that generally describes the mass bal- ance of debris flow watersheds in alpine areas.

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Hydrogeologic characterization, groundwater chemistry, and vulnerability assessment, Ute Mountain Ute Reservation, Colorado and Utah

The U.S. Geological Survey, in cooperation with the Ute Mountain Ute Tribe (UMUT), initiated a study in 2016 to increase understanding of the hydrogeology and chemistry of groundwater within select areas of the Ute Mountain Ute Reservation (UMUR) in Colorado and Utah, identify vulnerabilities to the system and other natural resources, and outline information needs to aid in the understanding and protection of groundwater resources. The results presented for this study can be used to support the UMUT’s goal of protecting their vital groundwater resources on the UMUR. Hydrogeologic conditions were characterized for the surficial aquifer contained in Quaternary-age unconsolidated surficial deposits and the Dakota aquifer contained in the Cretaceous-age Dakota Sandstone. In the surficial aquifer, median depth to water ranges from about 5.4 to 17.2 feet below land surface in the Farm and Ranch Enterprise area and 11 to 34 feet below land surface in the Towaoc area, and the water table slopes generally southwest or south. A map of depth to the top of the Dakota Sandstone was constructed from existing well data. Depths range from zero in outcrop areas to more than 3,000 feet below land surface on mesas in the southeastern part of the UMUR. Groundwater-chemistry data were collected by the UMUT from 13 springs and 31 wells from 1996 through 2017. Specific conductance was much lower for samples from springs than from wells; median values were 512 and 6,024 microsiemens per centimeter at 25 degrees Celsius, respectively. Spring samples were well oxygenated. A few well samples were anoxic (dissolved oxygen concentrations less than 0.5 milligrams per liter [mg/L]), indicating reducing conditions in the aquifer. About 75 percent of spring samples had fresh water (total dissolved solids concentrations less than 1,000 mg/L), and about 85 percent of well samples had brackish or highly saline water (total dissolved solids concentrations greater than 1,000 mg/L). Water type for springs on the Ute Mountains was calcium bicarbonate. Lower-altitude springs had a calcium-sulfate water type. Most well samples had sodium as the dominant cation, and sulfate, bicarbonate, and chloride as the dominant anions. Fluoride concentrations in about 45 percent of well samples were greater than an agricultural-use standard of 2 mg/L. Nitrate plus nitrite concentrations in most spring and well samples were less than about 1.6 mg/L per liter. Concentrations in samples from wells in the irrigated agricultural area were elevated; the maximum concentration was 78.5 mg/L. About one-half of the trace-element samples had concentrations that were less than laboratory reporting limits. Only aluminum, arsenic, and selenium in spring samples, and boron and selenium in well samples, were detected at concentrations greater than surface-water standards or water-quality standards for agricultural use of groundwater. Only three organic compounds, the pesticides alachlor and atrazine and the volatile organic compound di(2-ethylhexyl) phthalate, were detected in well samples. The Escherichia coli bacteria was detected in 47 and 23 percent of samples from wells and springs, respectively. The E. coli detections included samples from three culturally significant springs, which did not meet the UMUT cultural-use standard of total absence of E. coli. Tritium and carbon-14 were the primary environmental tracers used for interpreting groundwater ages for Lopez 2 Spring and five wells (AP–1, 5000 Block, Cottonwood Spring, Goodknight, and SE Toe). Water from the AP–1 well contained a mixture of pre- and post-1950s recharge. Tritium and carbon-14 recharge ages for Lopez 2 Spring (post-1950s in age), Goodknight and SE Toe wells (pre-1950s in age), and Cottonwood Spring well (primarily pre-1950s in age) are supported by helium-4 data. The helium-4 data for the 5000 Block well are inconsistent with the tritium and carbon-14 age of pre-1950s recharge because of interference caused by high methane concentrations in the water. Springs and surficial deposits are more vulnerable to contamination from anthropogenic chemicals than deeper bedrock wells. Bedrock aquifers are vulnerable in areas where the geologic formations containing the aquifers are exposed at the land surface. Groundwater in deep bedrock aquifers is likely thousands of years old and is not currently affected by present-day land uses. Both shallow and deep groundwater are vulnerable to naturally occurring salts and minerals, such as of total dissolved solids, major ions, nitrate, and trace elements. Effects of a changing climate on water resources and other ecological characteristics of the UMUR could include changes in evapotranspiration, a decrease in snowpack, decreased aquifer recharge and flow of springs, a decrease in soil moisture, and increased occurrence of wildfires and forest mortality. Of particular interest for the UMUT are possible effects of a changing climate on medicinal and culturally important plants and springs Several information needs were identified during this study that would aid in the understanding and protection of groundwater resources on the UMUR. These include well-completion information for bedrock wells, the collection of environmental tracer data at additional wells, the addition of methane and hydrocarbon analysis to well sampling plans, and the resampling of springs and wells that were last sampled in 2002 or earlier.

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High-resolution mapping of the freshwater-brine interface using deterministic and Bayesian inversion of airborne electromagnetic data at Paradox Valley, USA

Salt loads in the Colorado River Basin are a primary water quality concern. Natural groundwater brine discharge to the Dolores River where it passes through the collapsed salt anticline of the Paradox Valley in western Colorado is a significant source of salt to the Colorado River. An airborne electromagnetic survey of Paradox Valley has provided insights into the 3D distribution of brine in the surficial aquifer. A combination of stochastic and deterministic resistivity inversions were used to interpret the top of the freshwater-brine interface and to qualitatively describe the vertical salinity gradients across the interface. Low-resistivity regions indicative of brine occur near the land surface where brine discharges to the Dolores River and increase in depth several kilometers up-gradient along the axis of the valley. The most conductive parts of the brine plume are found in the areas below and adjacent to the river, suggesting that the brine becomes shallower and more concentrated as it reaches its natural discharge location. A significant freshwater lens overlying the brine west of the Dolores River is spatially correlated to the intermittent West Paradox Creek and agricultural irrigation. Below this lens, the transition from freshwater to brine appears to occur abruptly over a few meters and correlates to available well information. However, away from these regions and particularly with distance from the river, the freshwater-brine interface appears to be more diffuse.

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Nest site selection influences cinnamon teal nest survival in Colorado

Nest survival of ducks is partially a function of the spatiotemporal characteristics of the site at which a bird chooses to nest. Nest survival is also a fundamental component of population growth in waterfowl but is relatively unstudied for cinnamon teal ( Spatula cyanoptera ). We investigated cinnamon teal nest survival in a managed wetland complex in southern Colorado, USA, and assessed nest site selection to determine whether nest site characteristics were adaptive. We monitored 85 nests in 2015–2017 on Monte Vista National Wildlife Refuge, Colorado and did not detect a difference in nest survival across years. Based on nest site selection data from 2017, cinnamon teal selected nest sites characterized by a lower proportion of forbs than available sites. The relationships between habitat characteristics and nest survival were variable. Microhabitat characteristics exhibited only weak effects on nest survival during the laying stage. Nest survival during incubation was negatively related to the proportion of forbs at the nest site and, to a lesser extent, the proportion of grasses. Nest site selection was predictive of future nest survival based on the percent of forbs and grasses around the nest site, suggesting teal select nest locations to benefit reproductive success. These results have the potential to guide local habitat management actions for breeding waterfowl.

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Individual and population fitness consequences associated with large carnivore use of residential development

Large carnivores are negotiating increasingly developed landscapes, but little is known about how such behavioral plasticity influences their demographic rates and population trends. Some investigators have suggested that the ability of carnivores to behaviorally adapt to human development will enable their persistence, and yet, others have suggested that such landscapes are likely to serve as population sinks or ecological traps. To understand how plasticity in black bear (Ursus americanus) use of residential development influences their population dynamics, we conducted a 6 year study near Durango, Colorado, USA. Using space-use data on individual bears, we examined the influence of use of residential development on annual measures of bear body fat, cub productivity, cub survival and adult female survival, after accounting for variation in natural food availability and individual attributes (e.g., age). We then used our field-based vital rate estimates to parameterize a matrix model that simulated asymptotic population growth for bears using residential development to different degrees. We found that bear use of residential development was highly variable within and across years, with bears increasing their foraging within development when natural foods were scarce. Increased bear use of development was associated with increased body fat and cub productivity, but reduced cub and adult survival. When these effects were simultaneously incorporated into a matrix model we found that the population was projected to decline as bear use of development increased, given that the costs of reduced survival outweighed the benefits of enhanced productivity. Our results provide a mechanistic understanding of how black bear use of residential development exerts opposing effects on different bear fitness traits and a negative effect on population growth, with the magnitude of those effects mediated by variation in environmental conditions. They also highlight the importance of monitoring bear population dynamics, particularly as shifts in bear behavior are likely to drive increases in human-bear conflicts and the perception of growing bear populations. Finally, our work emphasizes the need to consider the demographic viability of large carnivore populations when promoting the coexistence of people and carnivores on shared landscapes.

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Effects of John Martin Reservoir on water quality and quantity: Assessment by chemical, isotopic, and mass-balance methods

Water quality and quantity can be influenced by transit through and storage in reservoirs. Assessing such effects can be challenging, however, because of mixing and residence times, and inter-annual net storage and release from both the reservoir itself and surrounding porosity. Here, different methodologies were used to assess the effect of John Martin Reservoir (JMR), located on the Arkansas River, on water volumes and the problematic constituents salinity (total dissolved solids, TDS), selenium (Se), and uranium (U). Methodologies addressed short-term (16 months) and long-term (31 years) effects depending upon data availability. Evaporation was assessed by using isotopes of water to determine 12% short-term evaporation, and by pan evaporation and changes in storage to determine 11% long-term evaporation. Salinity, Se, and U mass balance were assessed by using chloride (Cl−) as an index by which to measure short-term gains or losses between inflows and outflows in the short term. Chloride gain from ungaged inflows skewed those results to overestimate retention. Continuous monitoring of discharge and specific conductance for inflows and outflows, along with discrete sampling for dissolved constituents were used to compute long-term, load-based mass balance. Mild gains of TDS (34,000 ± 15,000 Mg/yr) and U (0.1 ± 0.5 Mg/yr) in JMR were detected. Although the additions are small relative to uncertainty, they indicate little to no retention of TDS and U and likely additions from ungaged inflows. In contrast, an average of 0.6 ± 0.2 Mg/yr or 23% of gaged inflow Se was removed in JMR. The study illustrates the benefit of long-term records for assessing the influence of reservoirs for which net storage and release keep them from approaching steady-state conditions.

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Temporal evolution of measured and simulated infiltration following wildfire in the Colorado Front Range, USA: Shifting thresholds of runoff generation and hydrologic hazards

Destructive flash floods and debris flows are a common menace following wildfire. The restoration of protection provided by forests from post-fire floods and debris flows depends on the recovery of infiltration and attendant reduction of infiltration-excess surface runoff generation. This work examines seven years of post-fire infiltration measurements and temporal relations fit to soil-hydraulic properties from the Colorado Front Range, USA to assess infiltration recovery with increasing time since fire. Point-scale Green-Ampt simulations of infiltration across a full spectrum of rainfall events are used to evaluate infiltration changes and shifts in surface runoff generation thresholds with post-fire temporal recovery. Measured and simulated infiltration generally recovered monotonically with increasing time since fire. This indicates a reduced vulnerability to infiltration-excess runoff generation as time elapses, with the greatest risk in the first two years after the fire. The threshold for infiltration-excess runoff advances with increasing time to rainfall events with higher intensity and greater return intervals; by the third year after wildfire only extreme events (30-100 year recurrence) generate surface runoff and by the fifth and seventh year even extreme rainfall events typically fail to generate surface runoff. Remotely-sensed vegetation indices suggest linked, or at least contemporaneous, recovery of understory vegetation and field-saturated hydraulic conductivity at this field site, suggesting coincident recovery of multiple hillslope properties impacting surface runoff generation. This work indicates that the closing of the window of disturbance after wildfire, relative to infiltration-excess runoff generation and corresponding flash flood and debris flow hazards, relies on coupled assessments of hillslope property recovery and stochasticity of high-intensity rainfall. Post-fire hazard assessments using static hillslope properties could fail to predict flash floods and debris flows associated with infrequent extreme rainfall events that strike during the post-fire recovery period when hillslope properties are partially recovered.

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Grazing-induced changes to biological soil crust cover mediate hillslope erosion in a long-term exclosure experiment

Dryland ecosystems are particularly vulnerable to erosion generated by livestock grazing. Quantifying this risk across a variety of landscape settings is essential for successful adaptive management, particularly in light of a changing climate. In the Upper Colorado River Basin, there are nearly 25 000 km 2 of rangelands with underlying soils derived from Mancos Shale, an erodible and saline geologic parent material. Salinity is a major concern within the Colorado River watershed, much of which is attributed to runoff and leaching from Mancos Shale deposits. In a 60-yr paired-watershed experiment in western Colorado, we used silt fences to measure differences in saline hillslope erosion, including both total sediment yield and concentrations of primary saline constituents (Na and Se), in watersheds that were either exposed to grazing or where livestock was excluded. After accounting for the strong effects of soil type, slope, and antecedent precipitation, we found that grazing increased sediment loss by ≈50% across our 8-yr time series (0.1–1.5 tn ha −1 ), consistent with levels reported at the watershed scale in early published work from studies at the same location. Eroded sediment Se levels were low and unaffected by grazing history, but Na concentrations were significantly reduced on grazed hillslopes, likely due to depletion of surface Na in soils exposed to chronic soil disturbance by livestock. Variable selection and path analysis identified that biological soil crust (BSC) cover, more than any other variable, explained the differences in sediment yields between grazed and ungrazed watersheds, partially through the enhancement of soil aggregate stability. Our results suggest that BSC cover should be granted heightened consideration in rangeland decision support tools (e.g., state-and-transition models) and that measures to reduce surface disturbance from livestock such as altering the timing or intensity of grazing may be effective for reducing downstream impacts.

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Preferential elution of ionic solutes in melting snowpacks: Improving process understanding through field observations and modeling in the Rocky Mountains

The preferential elution of ions from melting snowpacks is a complex problem that has been linked to temporary acidification of water bodies. However, the understanding of these processes in snowpacks around the world, including the polar regions that are experiencing unprecedented warming and melting, remains limited despite being instrumental in supporting climate change adaptation. In this study, data collected from a snowmelt lysimeter and snowpits at meadow and forest-gap sites in a high elevation watershed in Colorado were combined with the PULSE multi-phase snowpack chemistry model to investigate the controls of meltwater chemistry and preferential elution. The snowdepth at the meadow site was 64% of that at the forest-gap site, and the snowmelt rate was greater there (meadow snowpit) due to higher solar irradiance. Cations such as Ca 2+ and NH 4 + "> 4+ were deposited mostly within the upper layers of both the meadow and forest-gap snowpacks, and acid anions such as NO 3 − "> 3− and SO 4 2 − "> 42− were more evenly distributed. The snow ion concentrations were generally greater at the forest-gap snowpit, except for NH 4 + "> 4+ , which indicates that wind erosion of wet and dry deposited ions from the meadow may have reduced concentrations of residual snow. Furthermore, at the forest-gap site, snow interception and scavenging processes such as sublimation, ventilation, and throughfall led to particular ion enrichment of Ca 2+ , Mg 2+ , K + , Cl − , SO 4 2 − "> 42− and NO 3 − "> 3− . Model simulations and observations highlight that preferential elution is enhanced by low snowmelt rates, with the model indicating that this is due to lower dilution rates and increased contact time and area between the percolating meltwater and the snow. Results suggest that low snowmelt rates can cause multiple early meltwater ionic pulses for ions subject to lower ion exclusion. Ion exclusion rates at the grain-size level have been estimated for the first time.

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Wildfire-driven changes in hydrology mobilize arsenic and metals from legacy mine waste

Wildfires burning in watersheds that have been mined and since revegetated pose unique risks to downstream water supplies. A wildfire near Boulder, Colorado that burned a forested watershed recovering from mining disturbance that occurred 80-160 years ago allowed us to 1) assess arsenic and metal contamination in streams draining the burned area for a five-year period after the wildfire and 2) determine the fire-affected hydrologic drivers that convey arsenic and metals to surface water. Most metal concentrations were low in the circumneutral waters draining the burned area. Water and sediment collected from streams downstream of the burned area had elevated arsenic concentrations during and after post-fire storms. Mining-related deposits were the main source of arsenic to streams. An increased proportion of overland flow relative to infiltration after the fire mobilized arsenic- and metal- rich surface deposits and wildfire ash into streams within and downstream of the burned area. The deposition of this sediment into stream channels resulted in the remobilization of arsenic for the five-year post-fire study period. It is also possible that enhanced subsurface flow after the fire increased contact of water with arsenic-bearing minerals exposed in underground mine workings. Other studies have reported that wildfire ash can be an important source of arsenic and metals to surface waters, but wildfire ash was not an important source of arsenic in this study. Predicted increases in frequency, size, and intensity of wildfires in the western U.S., a region with widely dispersed historical mines, suggest that the intersection of legacy mining and post-wildfire hydrologic response poses an increasing risk for water supplies.

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Spatial variability in seasonal snowpack trends across the Rio Grande headwaters (1984 - 2017)

This study evaluated the spatial variability of trends in simulated snowpack properties across the Rio Grande headwaters of Colorado using the SnowModel snow evolution modeling system. SnowModel simulations were performed using a grid resolution of 100 m and 3-hourly time step over a 34-yr period (1984–2017). Atmospheric forcing was provided by phase 2 of the North American Land Data Assimilation System, and the simulations accounted for temporal changes in forest canopy from bark beetle and wildfire disturbances. Annual summary values of simulated snowpack properties [snow metrics; e.g., peak snow water equivalent (SWE), snowmelt rate and timing, and snow sublimation] were used to compute trends across the domain. Trends in simulated snow metrics varied depending on elevation, aspect, and land cover. Statistically significant trends did not occur evenly within the basin, and some areas were more sensitive than others. In addition, there were distinct trend differences between the different snow metrics. Upward trends in mean winter air temperature were 0.3°C decade −1 , and downward trends in winter precipitation were −52 mm decade −1 . Middle elevation zones, coincident with the greatest volumetric snow water storage, exhibited the greatest sensitivity to changes in peak SWE and snowmelt rate. Across the Rio Grande headwaters, snowmelt rates decreased by 20% decade −1 , peak SWE decreased by 14% decade −1 , and total snowmelt quantity decreased by 13% decade −1 . These snow trends are in general agreement with widespread snow declines that have been reported for this region. This study further quantifies these snow declines and provides trend information for additional snow variables across a greater spatial coverage at finer spatial resolution.

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