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USGS2005

Water Quality, Fish Tissue, and Bed Sediment Monitoring in Waterbodies of Fort Chaffee Maneuver Training Center, Arkansas, 2002-2004

The Fort Chaffee Maneuver Training Center is a facility used to train as many as 50,000 Arkansas National Guardsmen each year. Due to the nature of ongoing training and also to a poor understanding of environmental procedures that were practiced in the World War II era, areas within Fort Chaffee have the potential to be sources of a large number of contaminants. Because some streams flow on to Fort Chaffee, there is also the potential for sources that are off post to affect environmental conditions on post. This study evaluates constituent concentrations in water, fish tissue, and bed sediment collected from waterbodies on Fort Chaffee between September 2002 and July 2004. Constituent concentrations detected in the three media and measured at nine stream sites and four lake sites were compared to national and regional criteria when available. Two of the larger streams, Big and Vache Grasse Creeks, were sampled at multiple sites. All three sampled media were analyzed for insecticides, PCBs, explosives, and trace elements. Additionally, water samples were analyzed for nutrients and herbicides. The different constituents detected in the three sample media (water, fish tissue, and bed sediment) indicate that land-use activities both on and off post are influencing environmental conditions. Contaminants such as explosives that were sometimes detected in water samples have an obvious relation to military training; however, the occurrence and locations of some nutrients, insecticides, and trace elements suggest that land use both on and off post also could be influencing environmental conditions to some degree. Constituent concentrations at sites on Vache Grasse Creek, and particularly the most upstream site, which was located immediately downstream from an off-post wastewater-treatment facility, indicate that environmental conditions were being influenced by an off-post source. The most upstream site on Vache Grasse Creek had both the highest number of detections and the highest concentrations detected of all sites sampled. Event-mean storm concentrations and storm loads calculated from storm-flow samples at two sites each for Big and Vache Grasse Creeks indicate that storm loads were highest at the two Vache Grasse Creek sites for 24 of the 25 constituents detected. Further evaluation by normalizing storm loads at Big Creek to storm loads at Vache Grasse Creek by stream flow indicate that event loads at Vache Grasse Creek were about two or more times higher than those on Big Creek for 15 of the 25 constituents measured. Low concentrations of arsenic and lead were detected in water samples, but all detections for the two trace elements occurred in samples collected at the upstream site on Vache Grasse Creek. The nickel concentration in fish livers collected from the upstream site on Vache Grasse Creek was 45 percent higher than the median of a national study of 145 sites. Mercury concentrations in edible fish tissue, which are a widespread concern in the United States, exceeded an USEPA criterion for methylmercury of 300 ?g/kg in four of nine samples; however, concentrations are typical of mercury concentrations in fish tissues for the State of Arkansas. Constituent concentrations at some sites indicate that environmental conditions are being influenced by on-post activities. Of the 55 (excluding total organic carbon) organic constituents analyzed in water samples, only 10 were detected above the minimum detection limit but four of those were explosives. Bed-sediment samples from one site located on Grayson Creek, and nearest the administrative and residential (cantonment) area, had detections for arsenic, copper, lead, manganese, nickel, and zinc that were above background concentrations, and concentrations for arsenic and nickel at this site exceeded lowest effect level criteria established by the U.S. Environmental Protection Agency. The site on Grayson Creek also had the only detections of DDT metabolites in bed sedi

Scientific Investigations Report↗

USGS2014

Aquifers of Arkansas: protection, management, and hydrologic and geochemical characteristics of groundwater resources in Arkansas

Sixteen aquifers in Arkansas that currently serve or have served as sources of water supply are described with respect to existing groundwater protection and management programs, geology, hydrologic characteristics, water use, water levels, deductive analysis, projections of hydrologic conditions, and water quality. State and Federal protection and management programs are described according to regulatory oversight, management strategies, and ambient groundwater-monitoring programs that currently (2013) are in place for assessing and protecting groundwater resources throughout the State. Physical attributes, groundwater geochemistry, and groundwater quality are described for each of the 16 aquifers of the State. Information in regard to the hydrology and geochemistry of each of the aquifers is summarized from about 550 historical and recent publications. Additionally, more than 8,000 sites with groundwater-quality data were obtained from the U.S. Geological Survey National Water Information System and the Arkansas Department of Environmental Quality databases and entered into a spatial database to investigate distribution and trends in chemical constituents for each of the aquifers. The 16 aquifers of the State were divided into two major physiographic regions of the State: the Coastal Plain Province (referred to as Coastal Plain) of eastern and southern Arkansas, which includes 11 of the 16 aquifers, and the Interior Highlands Division (referred to as Interior Highlands) of western Arkansas, which includes the remaining 5 aquifers. The 11 aquifers in the Coastal Plain consist of various geologic units that are Cenozoic in age and consist primarily of Cretaceous, Tertiary, and Quaternary sands, gravels, silts, and clays. Groundwater in the Coastal Plain represents one of the most valuable natural resources in the State, driving the economic engines of agriculture, while also supplying abundant water for commercial, industrial, and public-supply use. In terms of age from youngest to oldest, the aquifers of the Coastal Plain include Quaternary alluvial aquifers, including the Mississippi River Valley alluvial aquifer (the most important aquifer in Arkansas in terms of volume of use and economic benefits), the Jackson Group (a regional confining unit that served for decades as an important source of domestic supply), and the Cockfield, Sparta, Cane River, Carrizo, Wilcox, Nacatoch, Ozan, Tokio, and Trinity aquifers. The Mississippi River Valley alluvial aquifer accounts for approximately 94 percent of all groundwater used in the State, and the aquifer is used primarily for irrigation purposes. The Sparta aquifer is the second most important aquifer in terms of use, and the aquifer was used in the past dominantly as a source of public and industrial supply, although increasing irrigation use is occurring because of critically declining water levels in the Mississippi River Valley alluvial aquifer. Other aquifers of the Coastal Plain generally are used as important local sources of domestic, industrial, and public supply, in addition to other minor uses. Water quality generally is good for all aquifers of the Coastal Plain, except for elevated iron concentrations and localized areas of high salinity. The high salinity results from intrusion from underlying formations, evapotranspiration processes in areas of low recharge, and inadequate flushing in downgradient areas of residual salinity from deposition in marine environments. Trends in the spatial distribution of individual chemical constituents are related to position along the flow path for most aquifers of the Coastal Plain. These trends include elevated iron and nitrate concentrations with lower pH values and dissolved solids in groundwater from the outcrop areas, transitioning to lower iron and nitrate (related to changes in redox) and higher pH and dissolved solids (dominantly from the dissolution of carbonate minerals) in groundwater downgradient from outcrop areas. Groundwater generally trended from a calcium- to a sodium-bicarbonate water type with increasing cation exchange along the flow path. The Interior Highlands of western Arkansas has less reported groundwater use than other areas of the State, reflecting a combination of factors. These factors include prevalent and increasing use of surface water, less intensive agricultural uses, lower population and industry densities, lesser potential yield of the resource, and lack of detailed reporting. The overall low yields of aquifers of the Interior Highlands result in domestic supply as the dominant use, with minor industrial, public, and commercial-supply use. Where greater volumes are required for growth of population and industry, surface water is the greatest supplier of water needs in the Interior Highlands. The various aquifers of the Interior Highlands generally occur in shallow, fractured, well-indurated, structurally modified bedrock of this mountainous region of the State, as compared to the relatively flat-lying, unconsolidated sediments of the Coastal Plain. In terms of age from youngest to oldest, the aquifers of the Interior Highlands include: the Arkansas River Valley alluvial aquifer, the Ouachita Mountains aquifer, the Western Interior Plains confining system, the Springfield Plateau aquifer, and the Ozark aquifer. Spatial trends in groundwater geochemistry in the Interior Highlands differ greatly from trends noted for aquifers of the Coastal Plain. In the Coastal Plain, the prevalence of long regional flow paths results in regionally predictable and mappable geochemical changes along the flow paths. In the Interior Highlands, short, topographically controlled flow paths (from hilltops to valleys) within small watersheds represent the predominant groundwater-flow system. As such, dense data coverage from numerous wells would be required to effectively characterize these groundwater basins and define small-scale geochemical changes along any given flow path for aquifers of the Interior Highlands. Changes in geochemistry generally were related to rock type and residence time along individual flow paths. Dominant changes in geochemistry for the Ouachita Mountains aquifer and the Western Interior Plains confining system are attributed to rock/water interaction and changes in redox zonation along the flow path. In these areas, groundwater evolves along flow paths from a calcium- to a sodium-bicarbonate water type with increasing reducing conditions resulting in denitrification, elevated iron and manganese concentrations, and production of methane in the more geochemically evolved and strongest reducing conditions. In the Ozark and Springfield Plateau aquifers, rapid influx of surface-derived contaminants, especially nitrogen, coupled with few to no attenuation processes was attributed to the karst landscape developed on Mississippian- and Ordovician-age carbonate rocks of the Ozark Plateaus. Increasing nitrate concentrations are related to increasing agricultural land use, and areas of mature karst development result in higher nitrate concentrations than areas with less karst features.

Arkasas↗

USGS2008

Temporal Differences in the Hydrologic Regime of the Lower Platte River, Nebraska, 1895-2006

In cooperation with the Lower Platte South Natural Resources District for a collaborative study of the cumulative effects of water and channel management practices on stream and riparian ecology, the U.S. Geological Survey (USGS) compiled, analyzed, and summarized hydrologic information from long-term gaging stations on the lower Platte River to determine any significant temporal differences among six discrete periods during 1895-2006 and to interpret any significant changes in relation to changes in climatic conditions or other factors. A subset of 171 examined hydrologic indices (HIs) were selected for use as indices that (1) included most of the variance in the larger set of indices, (2) retained utility as indicators of the streamflow regime, and (3) provided information at spatial and temporal scale(s) that were most indicative of streamflow regime(s). The study included the most downstream station within the central Platte River segment that flowed to the confluence with the Loup River and all four active streamflow-gaging stations (2006) on the lower Platte River main stem extending from the confluence of the Loup River and Platte River to the confluence of the Platte River and Missouri River south of Omaha. The drainage areas of the five streamflow-gaging stations covered four (of eight) climate divisions in Nebraska?division 2 (north central), 3 (northeast), 5 (central), and 6 (east central). Historical climate data and daily streamflow records from 1895 through 2006 at the five streamflow-gaging stations were divided into six 11-water-year periods: 1895?1905, 1934?44, 1951?61, 1966?76, 1985?95, and 1996?2006. Analysis of monthly climate variables?precipitation and Palmer Hydrological Drought Index?was used to determine the degree of hydroclimatic association between streamflow and climate. Except for the 1895?1905 period, data gaps in the streamflow record were filled by data estimation techniques, and 171 hydrologic indices were calculated using the Hydroecological Integrity Assessment Process software developed by the U.S. Geological Survey. A subset of 27 nonredundant indices (of the 171 indices) was selected using principal component analysis. Indices that described monthly streamflow?mean, maximum, minimum, skewness, and coefficients of variation?also were used. Comparison of these selected indices allowed determination of temporal differences among the six 11-water-year periods for each gaging station. The lower Platte River basin was affected by moderate to severe drought conditions in the 1934?44 period. The widespread drought was preceded by mildly to moderately wet conditions in the 1895?1906 period, followed by incipient drought to incipiently wet conditions in the 1951?61 periods and mildly wet conditions in 1966?76 period, moderately wet conditions in the 1985?1995 period, and incipient drought to mildly wet conditions in the 1996?2006 period. Monthly streamflow of the Platte River from Duncan through Louisville, Nebraska, correlated significantly with the monthly Palmer Hydrological Drought Index. Temporal differences in median values of monthly-mean and monthly-maximum streamflow measured at Duncan, North Bend, and Ashland stations between the two moderately wet periods (1895?1905 and 1985?95) indicated that streamflow storage reservoirs and regulation some time after 1906 significantly reduced monthly streamflow magnitude and amplitude?the difference between the highest and lowest median values of monthly mean streamflow. Effects of storage reservoirs on the median values of monthly-minimum streamflow were less obvious. Temporal differences among the other five periods, from 1934 through 2006 when streamflow was affected by storage and regulation, indicated the predominant effects of contrasting climate conditions on median values of monthly mean, maximum, and minimum streamflow. Significant temporal differences in monthly streamflow values were evident mainly between the two periods of greatly

Scientific Investigations Report↗

USGS2012

Occurrence of pharmaceuticals, hormones, and organic wastewater compounds in Pennsylvania waters, 2006-09

Concern over the presence of contaminants of emerging concern, such as pharmaceutical compounds, hormones, and organic wastewater compounds (OWCs), in waters of the United States and elsewhere is growing. Laboratory techniques developed within the last decade or new techniques currently under development within the U.S. Geological Survey now allow these compounds to be measured at concentrations in nanograms per liter. These new laboratory techniques were used in a reconnaissance study conducted by the U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection, to determine the occurrence of contaminants of emerging concern in streams, streambed sediment, and groundwater of Pennsylvania. Compounds analyzed for in the study are pharmaceuticals (human and veterinary drugs), hormones (natural and synthetic), and OWCs (detergents, fragrances, pesticides, industrial compounds, disinfectants, polycyclic aromatic hydrocarbons, fire retardants and plasticizers). Reconnaissance sampling was conducted from 2006 to 2009 to identify contaminants of emerging concern in (1) groundwater from wells used to supply livestock, (2) streamwater upstream and downstream from animal feeding operations, (3) streamwater upstream from and streamwater and streambed sediment downstream from municipal wastewater effluent discharges, (4) streamwater from sites within 5 miles of drinking-water intakes, and (5) streamwater and streambed sediment where fish health assessments were conducted. Of the 44 pharmaceutical compounds analyzed in groundwater samples collected in 2006 from six wells used to supply livestock, only cotinine (a nicotine metabolite) and the antibiotics tylosin and sulfamethoxazole were detected. The maximum concentration of any contaminant of emerging concern was 24 nanograms per liter (ng/L) for cotinine, and was detected in a groundwater sample from a Lebanon County, Pa., well. Seven pharmaceutical compounds including acetaminophen, caffeine, carbamazepine, and the four antibiotics tylosin, sulfadimethoxine, sulfamethoxazole, and oxytetracycline were detected in streamwater samples collected in 2006 from six paired stream sampling sites located upstream and downstream from animal-feeding operations. The highest reported concentration of these seven compounds was for the antibiotic sulfamethoxazole (157 ng/L), in a sample from the downstream site on Snitz Creek in Lancaster County, Pa. Twenty-one pharmaceutical compounds were detected in streamwater samples collected in 2006 from five paired stream sampling sites located upstream or downstream from a municipal wastewater-effluent-discharge site. The most commonly detected compounds and maximum concentrations were the anticonvulsant carbamazepine, 276 ng/L; the antihistamine diphenhydramine, 135 ng/L; and the antibiotics ofloxacin, 329 ng/L; sulfamethoxazole, 1,340 ng/L; and trimethoprim, 256 ng/L. A total of 51 different contaminants of emerging concern were detected in streamwater samples collected from 2007 through 2009 at 13 stream sampling sites located downstream from a wastewater-effluent-discharge site. The concentrations and numbers of compounds detected were higher in stream sites downstream from a wastewater-effluent-discharge site than in stream sites upstream from a wastewater-effluent-discharge site. This finding indicates that wastewater-effluent discharges are a source of contaminants of emerging concern; these contaminants were present more frequently in the streambed-sediment samples than in streamwater samples. Antibiotic compounds were often present in both the streamwater and streambed-sediment samples, but many OWCs were present exclusively in the streambed-sediment samples. Compounds with endocrine disrupting potential including detergent metabolites, pesticides, and flame retardants, were present in the streamwater and streambed-sediment samples. Killinger Creek, a stream where wastewater-effluent discharges contribute a large percentage of the total flow, stands out as a stream with particularly high numbers of compounds detected and detected at the highest concentrations measured in the reconnaissance sampling. Nineteen contaminants of emerging concern were detected in streamwater samples collected quarterly from 2007 through 2009 at 27 stream sites within 5 miles of a drinking-water intake. The number of contaminants and the concentrations detected at the stream sites within 5 miles of drinking-water intakes were generally very low (concentrations less than 50 ng/L), much lower than those at sites downstream from a wastewater-effluent discharge. The most commonly detected compounds and maximum concentrations were caffeine, 517 ng/L; carbamazepine, 95 ng/L; sulfamethoxazole, 146 ng/L; and estrone, 3.15 ng/L. The concentrations and frequencies of detection of some of the contaminants of emerging concern appear to vary by season, which could be explained by compound use, flow regime, or differences in degradation rates. Concentrations of some contaminants were associated with lower flows as a result of decreased in-stream dilution of wastewater effluents or other contamination sources. Twenty-two contaminants of emerging concern were detected once each in streamwater samples collected in 2007 and 2008 from 16 fish-health stream sites located statewide. The highest concentrations were for the OWCs, including flame retardants tri(2-butoxyethyl)phosphate (604 ng/L) and tri(2-chloroethyl)phosphate (272 ng/L) and the fragrance isoquinoline (330 ng/L). Far fewer numbers of contaminants of emerging concern were detected at the fish-health sites than at the wastewater-effluent-discharge sites. Most of the fish-health sites were not located directly downstream from a wastewater-effluent discharge, but there were multiple wastewater-effluent discharges in the drainage basins upstream from the sampling sites. No distinct pattern of contaminant occurrence could be discerned for the fish-health stream sites

Pennsylvania↗

USGS2007

Water-Quality Characteristics for Sites in the Tongue, Powder, Cheyenne, and Belle Fourche River Drainage Basins, Wyoming and Montana, Water Years 2001-05, with Temporal Patterns of Selected Long-Term Water-Quality Data

Water-quality sampling was conducted regularly at stream sites within or near the Powder River structural basin in northeastern Wyoming and southeastern Montana during water years 2001-05 (October 1, 2000, to September 30, 2005) to characterize water quality in an area of coalbed natural gas development. The U.S. Geological Survey, in cooperation with the Wyoming Department of Environmental Quality, characterized the water quality at 22 sampling sites in the Tongue, Powder, Cheyenne, and Belle Fourche River drainage basins. Data for general hydrology, field measurements, major-ion chemistry, and selected trace elements were summarized, and specific conductance and sodium-adsorption ratios were evaluated for relations with streamflow and seasonal variability. Trend analysis for water years 1991-2005 was conducted for selected sites and constituents to assess change through time. Average annual runoff was highly variable among the stream sites. Generally, streams that have headwaters in the Bighorn Mountains had more runoff as a result of higher average annual precipitation than streams that have headwaters in the plains. The Powder River at Moorhead, Mont., had the largest average annual runoff (319,000 acre-feet) of all the sites; however, streams in the Tongue River drainage basin had the highest runoff per unit area of the four major drainage basins. Annual runoff in all major drainage basins was less than average during 2001-05 because of drought conditions. Consequently, water-quality samples collected during the study period may not represent long-term water-quality con-ditions for all sites. Water-quality characteristics were highly variable generally because of streamflow variability, geologic controls, and potential land-use effects. The range of median specific-conductance values among sites was smallest in the Tongue River drainage basin. Median values in that basin ranged from 643 microsiemens per centimeter at 25 degrees Celsius (?S/cm at 25?C) on the Tongue River to 1,460 ?S/cm at 25?C on Prairie Dog Creek. The Tongue River drainage basin has the largest percentage of area underlain by Mesozoic-age and older rocks and by more resistant rocks. In addition, the higher annual precipitation and a steeper gradient in this basin compared to basins in the plains produce relatively fast stream velocities, which result in a short contact time between stream waters and basin materials. The Powder River drainage basin, which has the largest drainage area and most diverse site conditions, had the largest range of median specific-conductance values among the four major drainage basins. Median values in that basin ranged from 680 ?S/cm at 25?C on Clear Creek to 5,950 ?S/cm at 25?C on Salt Creek. Median specific-conductance values among sites in the Cheyenne River drainage basin ranged from 1,850 ?S/cm at 25?C on Black Thunder Creek to 4,680 ?S/cm at 25?C on the Cheyenne River. The entire Cheyenne River drainage basin is in the plains, which have low precipitation, soluble geologic materials, and relatively low gradients that produce slow stream velocities and long contact times. Median specific-conductance values among sites in the Belle Fourche River drainage basin ranged from 1,740 ?S/cm at 25?C on Caballo Creek to 2,800 ?S/cm at 25?C on Donkey Creek. Water in the study area ranged from a magnesium-calcium-bicarbonate type for some sites in the Tongue River drainage basin to a sodium-sulfate type at many sites in the Powder, Cheyenne, and Belle Fourche River drainage basins. Little Goose Creek, Goose Creek, and the Tongue River in the Tongue River drainage basin, and Clear Creek in the Powder River drainage basin, which have headwaters in the Bighorn Mountains, consistently had the smallest median dissolved-sodium concentrations, sodium-adsorption ratios, dissolved-sulfate concentrations, and dissolved-solids concentrations. Salt Creek, Wild Horse Creek, Little Powder River, and the Cheyenne River, which have headwat

Scientific Investigations Report↗

USGS2007

Evaluation of Street Sweeping as a Stormwater-Quality-Management Tool in Three Residential Basins in Madison, Wisconsin

Recent technological improvements have increased the ability of street sweepers to remove sediment and other debris from street surfaces; the effect of these technological advancements on stormwater quality is largely unknown. The U.S. Geological Survey, in cooperation with the City of Madison and the Wisconsin Department of Natural Resources, evaluated three street-sweeper technologies from 2002 through 2006. Regenerative-air, vacuum-assist, and mechanical-broom street sweepers were operated on a frequency of once per week (high frequency) in separate residential basins in Madison, Wis., to measure each sweeper's ability to not only reduce street-dirt yield but also improve the quality of stormwater runoff. A second mechanical-broom sweeper operating on a frequency of once per month (low frequency) was also evaluated to measure reductions in street-dirt yield only. A paired-basin study design was used to compare street-dirt and stormwater-quality samples during a calibration (no sweeping) and a treatment period (weekly sweeping). The basis of this paired-basin approach is that the relation between paired street-dirt and stormwater-quality loads for the control and tests basins is constant until a major change is made at one of the basins. At that time, a new relation will develop. Changes in either street-dirt and/or stormwater quality as a result of street sweeping could then be quantified by use of statistical tests. Street-dirt samples collected weekly during the calibration period and twice per week during the treatment period, once before and once after sweeping, were dried and separated into seven particle-size fractions ranging from less than 63 micrometers to greater than 2 millimeters. Street-dirt yield evaluation was based on a computed mass per unit length of pounds per curb-mile. An analysis of covariance was used to measure the significance of the effect of street sweeping at the end of the treatment period and to quantify any reduction in street-dirt yield. Both the regenerative-air and vacuum-assist sweepers produced reductions in street-dirt yield at the 5-percent significance level. Street-dirt yield was reduced by an average of 76, 63, and 20 percent in the regenerative-air, vacuum-assist, and high-frequency broom basins, respectively. The low-frequency broom basin showed no significant reductions in street-dirt yield. Sand-size particles (greater than 63 micrometers) recorded the greatest overall reduction. Street-sweeper pickup efficiency was determined by computing the difference between weekly street-dirt yields before and after sweeping cleaning. The regenerative-air and vacuum-assist sweepers had similar pickup efficiencies of 25 and 30 percent, respectively. The mechanical broom sweeper operating at high frequency was considerably less efficient, removing an average of 5 percent of street-dirt yield. The effects of street sweeping on stormwater quality were evaluated by use of statistical tests to compare event mean concentrations and loads computed for individual storms at the control and test basins. Loads were computed by multiplying the event mean concentrations by storm-runoff volumes. Only ammonia-nitrogen for the test basin with the vacuum-assist sweeper showed significant load increases over the control basin, at the 10-percent significance level, of 63 percent. Difficulty in detecting significant changes in constituent stormwater-quality loads could be due, in part, to the large amount of variability in the data. Coefficients of variation for the majority of constituent loads were greater than 1, indicating substantial variability. The ability to detect changes in constituent stormwater-quality loads was likely hampered by an inadequate number of samples in the data set. However, sediment transport in the storm-sewer pipe, sediment washing onto the street from other source areas, winter sand application, and sampling challenges were additional sources of variability within each study ba

Scientific Investigations Report↗

USGS2009

Water-level conditions in selected confined aquifers of the New Jersey and Delaware coastal plain, 2003

The Coastal Plain aquifers of New Jersey provide an important source of water for more than 2 million people. Steadily increasing withdrawals from the late 1800s to the early 1990s resulted in declining water levels and the formation of regional cones of depression. In addition to decreasing water supplies, declining water levels in the confined aquifers have led to reversals in natural hydraulic gradients that have, in some areas, induced the flow of saline water from surface-water bodies and adjacent aquifers to freshwater aquifers. In 1978, the U.S. Geological Survey began mapping the potentiometric surfaces of the major confined aquifers of New Jersey every 5 years in order to provide a regional assessment of ground-water conditions in multiple Coastal Plain aquifers concurrently. In 1988, mapping of selected potentiometric surfaces was extended into Delaware. During the fall of 2003, water levels measured in 967 wells in New Jersey, Pennsylvania, northeastern Delaware, and northwestern Maryland were used estimate the potentiometric surface of the principal confined aquifers in the Coastal Plain of New Jersey and five equivalent aquifers in Delaware. Potentiometric-surface maps and hydrogeologic sections were prepared for the confined Cohansey aquifer of Cape May County, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand, the Vincentown aquifer, and the Englishtown aquifer system in New Jersey, as well as for the Piney Point aquifer, the Wenonah-Mount Laurel aquifer, and the Upper Potomac-Raritan-Magothy, the Middle and undifferentiated Potomac-Raritan-Magothy, and the Lower Potomac-Raritan-Magothy aquifers in New Jersey and their equivalents in Delaware. From 1998 to 2003, water levels in many Coastal Plain aquifers in New Jersey remained stable or had recovered, but in some areas, water levels continued to decline as a result of pumping. In the Cohansey aquifer in Cape May County, water levels near the center of the cone of depression underlying the southern part of the peninsula remained about the same as in 1998. To the south, recoveries up to 8 feet were observed in southern Lower Township as withdrawals had decreased since 1998. In the northern part of Cape May County, water levels had not changed substantially from historic conditions. In the Rio Grande water-bearing zone, water levels rose by as much as 13 ft at the Rio Grande well field; elsewhere across the aquifer, little change had occurred. In the Atlantic City 800-foot sand, water-level changes were greatest in southern Cape May County; at the Cape May desalination wells, water levels were as much as 32 ft lower in 2003 than in 1998. In contrast, water levels at the center of a regional cone of depression near Atlantic City rose by as much as 10 ft. Within the Piney Point aquifer water levels rose by 46 ft near Seaside Park. Similarly, water levels increased by more than 30 ft in and around the major cone of depression underlying Dover, Delaware. In the Vincentown aquifer, water levels stabilized or recovered by 2 ft to 6 ft from 1998 to 2003 in most of the wells measured; the exception is near Adelphia in Monmouth County, where water levels rose by as much as 18 ft. From 1998 to 2003, water levels near the center of a large cone of depression that extends from Monmouth to Ocean County recovered by as much as 20 ft in the Wenonah-Mount Laurel aquifer. Concurrently, ground-water levels within the Englishtown aquifer system declined by as much as 13 ft in the same area. Water levels across much of the Upper Potomac-Raritan-Magothy aquifer in the northern Coastal Plain remained about the same as 5 years previous, except in northern Ocean County where ground-water levels declined 10 ft to 33 ft. Water levels in the Middle Potomac-Raritan-Magothy aquifer declined from 5 to 9 ft along the border between Monmouth and Middlesex County. Elsewhere, across the northern part of the Coastal Plain, water levels stabilized within the Cretaceous-a

Delaware, New Jersey↗

USGS2018

Simulation of hydrodynamics, water quality, and lake sturgeon habitat volumes in Lake St. Croix, Wisconsin and Minnesota, 2013

Lake St. Croix is a naturally impounded, riverine lake that makes up the last 40 kilometers of the St. Croix River. Substantial land-use changes during the past 150 years, including increased agriculture and urban development, have reduced Lake St. Croix water-quality and increased nutrient loads delivered to Lake St. Croix. A recent (2012–13) total maximum daily load phosphorus-reduction plan set the goal to reduce total phosphorus loads to Lake St. Croix by 20 percent by 2020 and reduce Lake St. Croix algal bloom frequencies. The U.S. Geological Survey, in cooperation with the National Park Service, developed a two-dimensional, carbon-based, laterally averaged, hydrodynamic and water-quality model, CE–QUAL–W2, that addresses the interaction between nutrient cycling, primary production, and trophic dynamics to predict responses in the distribution of water temperature, oxygen, and chlorophyll a. Distribution is evaluated in the context of habitat for lake sturgeon, including a combination of temperature and dissolved oxygen conditions termed oxy-thermal habitat. The Lake St. Croix CE–QUAL–W2 model successfully reproduced temperature and dissolved oxygen in the lake longitudinally (from upstream to downstream), vertically, and temporally over the seasons. The simulated water temperature profiles closely matched the measured water temperature profiles throughout the year, including the prediction of thermocline transition depths (often within 1 meter), the absolute temperature of the thermocline transitions (often within 1.0 degree Celsius), and profiles without a strong thermocline transition. Simulated dissolved oxygen profiles matched the trajectories of the measured dissolved oxygen concentrations at multiple depths over time, and the simulated concentrations matched the depth and slope of the measured concentrations. Additionally, trends in the measured water-quality data were captured by the model simulation, gaining some potential insights into the underlying mechanisms of critical Lake St. Croix metabolic processes. The CE–QUAL–W2 model tracked nitrate plus nitrite, total nitrogen, and total phosphorus throughout the year. Inflow nutrient contributions (loads), largely dominated by upstream St. Croix River loads, were the most important controls on Lake St. Croix water quality. Close to 60 percent of total phosphorus to the lake was from phosphorus derived from organic matter, and about 89 percent of phosphorus to Lake St. Croix was delivered by St. Croix River inflows. The Lake St. Croix CE–QUAL–W2 model offered potential mechanisms for the effect of external and internal loadings on the biotic response regarding the modeled algal community types of diatoms, green algae, and blue-green algae. The model also suggested the seasonal dominance of blue-green algae in all four pools of the lake. A sensitivity analysis was completed to test the total maximum daily load phosphorus-reduction scenario responses of total phosphorus and chlorophyll a. The modeling indicates that phosphorus reductions would result in similar Lake St. Croix reduced concentrations, although chlorophyll a concentrations did not decrease in the same proportional amounts as the total phosphorus concentrations had decreased. The smaller than expected reduction in algal growth rates highlighted that although inflow phosphorus loads are important, other constituents also can affect the algal response of the lake, such as changes in light penetration and the breakdown of organic matter releasing nutrients. The available habitat suitable for lake sturgeon was evaluated using the modeling results to determine the total volume of good-growth habitat, optimal growth habitat, and lethal temperature habitat. Overall, with the calibrated model, the fish habitat volume in general contained a large proportion of good-growth habitat and a sustained period of optimal growth habitat in the summer. Only brief periods of lethal oxy-thermal habitat were present in Lake St. Croix during the model simulation.

Minnesota, Wisconsin↗

USGS2016

Transport and deposition of asbestos-rich sediment in the Sumas River, Whatcom County, Washington

Heavy sediment loads in the Sumas River of Whatcom County, Washington, increase seasonal turbidity and cause locally acute sedimentation. Most sediment in the Sumas River is derived from a deep-seated landslide of serpentinite that is located on Sumas Mountain and drained by Swift Creek, a tributary to the Sumas River. This mafic sediment contains high amounts of naturally occurring asbestiform chrysotile. A known human-health hazard, asbestiform chrysotile comprises 0.25–37 percent, by mass, of the total suspended sediment sampled from the Sumas River as part of this study, which included part of water year 2011 and all of water years 2012 and 2013. The suspended-sediment load in the Sumas River at South Pass Road, 0.6 kilometers (km) downstream of the confluence with Swift Creek, was 22,000 tonnes (t) in water year 2012 and 49,000 t in water year 2013. The suspended‑sediment load at Telegraph Road, 18.8 km downstream of the Swift Creek confluence, was 22,000 t in water year 2012 and 27,000 t in water year 2013. Although hydrologic conditions during the study were wetter than normal overall, the 2-year flood peak was only modestly exceeded in water years 2011 and 2013; runoff‑driven geomorphic disturbance to the watershed, which might have involved mass wasting from the landslide, seemed unexceptional. In water year 2012, flood peaks were modest, and the annual streamflow was normal. The fact that suspended-sediment loads in water year 2012 were equivalent at sites 0.6 and 18.8 km downstream of the sediment source indicates that the conservation of suspended‑sediment load can occur under normal hydrologic conditions. The substantial decrease in suspended-sediment load in the downstream direction in water year 2013 was attributed to either sedimentation in the intervening river reach, transfer to bedload as an alternate mode of sediment transport, or both. The sediment in the Sumas River is distinct from sediment in most other river systems because of the large percentage of asbestiform chrysotile in suspension. The suspended sediment carried by the Sumas River consists of three major components: (1) a relatively dense, largely non-flocculated material that settles rapidly out of suspension; (2) a lighter component containing relatively high proportions of flocculated material, much of it composed of asbestiform chrysotile; and (3) individual chrysotile fibers that are too small to flocculate or settle out, and remain in suspension as wash load (these fibers are on the order of microns in length and tenths of microns in diameter). Whereas the bulk density of the first (heaviest) component of suspended sediment was between 1.5 and 1.6 grams per cubic centimeter (g/cm3), the bulk density of the flocculated material was an order of magnitude lower (0.16 g/cm3), even after 24 hours of settling. Soon after immersion in water, the fresh chrysotile fibers derived from the Swift Creek landslide seem to flocculate readily into large bundles, or floccules, that exhibit settling velocities characteristic of coarse silts and fine sands (30 and 250 micrometers). In quiescent water within this river system, the floccules settle out quickly, but still leave between 2.4 and 19.5 million chrysotile fibers per liter in the clear overlying water. Consistent with the results from previous laboratory research, the amounts of asbestiform chrysotile in the water column in Swift Creek, as well as in the Sumas River close to and downstream of its confluence with Swift Creek, were determined to be directly correlated with pH. This observation offers a possible alternative to either turbidity or suspended‑sediment concentration as a surrogate for the concentration of fresh asbestiform chrysotile in suspension. Continued movement and associated erosion of the landslide through mass wasting and runoff will maintain large sediment loads in Swift Creek and in the Sumas River for the foreseeable future. Given the present channel morphology of the river system, aggradation (that is, sediment accumulation) in Swift Creek and the Sumas River are also likely to continue.

Washington↗

USGS2006

Borehole geophysical logging and aquifer-isolation tests conducted in well MG-1693 at North Penn Area 5 Superfund Site near Colmar, Montgomery County, Pennsylvania

Borehole geophysical logging and aquifer-isolation (packer) tests were conducted in well MG-1693 (NP-87) at the North Penn Area 5 Superfund Site near Colmar, Montgomery County, Pa. Objectives of the study were to identify the depth and yield of water-bearing zones, occurrence of vertical borehole flow, and effects of pumping on water levels in nearby wells. Caliper, natural-gamma, single-point-resistance, fluidtemperature, fluid-resistivity, heatpulse-flowmeter, and borehole-video logs were collected. Vertical borehole-fluid movement direction and rate were measured under nonpumping conditions. The suite of logs was used to locate water-bearing fractures, determine zones of vertical borehole-fluid movement, and select depths to set packers. Aquifer-isolation tests were conducted to sample discrete intervals and to determine specific capacities of water-bearing zones and effects of pumping individual zones on water levels in two nearby monitor wells. Specific capacities of isolated zones during aquifer-isolation tests ranged from 0.03 to 3.09 (gal/min)/ft (gallons per minute per foot). Fractures identified by borehole geophysical methods as water-producing or water-receiving zones produced water when isolated and pumped. Water enters the borehole primarily through high-angle fractures at 416 to 435 ft bls (feet below land surface) and 129 to 136 ft bls. Water exits the borehole through a high-angle fracture at 104 to 107 ft bls, a broken casing joint at 82 ft bls, and sometimes as artesian flow through the top of the well. Thirteen intervals were selected for aquifer-isolation testing, using a straddle-packer assembly. The specific capacity of interval 1 was 2.09 (gal/min)/ft. The specific capacities of intervals 2, 3, and 4 were similar—0.27, 0.30, and 0.29 (gal/min)/ft, respectively. The specific capacities of intervals 5, 6, 7, 8, and 10 were similar—0.03, 0.04, 0.09, 0.09, and 0.04 (gal/min)/ft, respectively. Intervals 9, 11, and 12 each showed a strong hydraulic connection outside the borehole with intervals above and below the isolated interval. The specific capacities of intervals 9, 11, 12, and 13 were similar—2.12, 2.17, 3.09, and 3.08 (gal/min)/ft, respectively. The aquifer-isolation tests indicate that wells MG-1693 (NP-87) and MG-924 (NP-21) are connected primarily through the high-angle fracture from 416 to 435 ft bls. Pumping in either of these wells directly impacts the other well, allowing the pumped well to draw from water-bearing zones in the nonpumped well that are not present in or are not connected directly to the pumped well. The two boreholes act as a single, U-shaped well. The aquifer-isolation tests also show that the lower zones in well MG-1693 (NP-87) are a major source of hydraulic head in well MG-1661 (W-13) through the broken casing joint at 82 ft bls. Water moving upward from the lower intervals in well MG-1693 (NP-87) exits the borehole through the broken casing joint, moves upward outside the borehole, possibly around and (or) through a poor or damaged casing seal, and through the weathered zone above bedrock to well MG-1661 (W-13). Samples for volatile organic compounds (VOCs) were collected in nine isolated intervals. Six compounds were detected (1,1-dichloroethane, 1,1-dichloroethene, cis-1,2-dichloroethene, toluene, 1,1,1-trichloroethane, and trichloroethene (TCE)), and TCE was found in all nine isolated intervals. Intervals 4 (124-149 ft bls) and 6 (277-302 ft bls) had the highest total concentration of VOCs (6.66 and 6.2 micrograms per liter, respectively). Intervals 1 (68-93 ft bls) and 4 each had five compounds detected, which was the highest number of compounds detected. Interval 5 (252-277 ft bls) had the lowest total concentration of VOCs (0.08 microgram per liter) and the least number of VOCs detected (one). Detected compounds were not evenly distributed throughout the intervals. Contaminants were found in shallow, intermediate, and deep intervals and were associated with high-angle fractures and rough areas that showed no distinct fractures.

Pennsylvania↗

USGS2023

Changes in phosphorus and suspended solids loading in the Fox River, northeastern Wisconsin, 1989–2021

The entire Lower Fox River and inner bay of Green Bay, in northeastern Wisconsin, have been listed as impaired by the Wisconsin Department of Natural Resources (WDNR) for low dissolved oxygen and degraded habitat, with total phosphorus (TP) and total suspended solids (TSS) concentrations listed as the likely causes of these impairments. To restore the Fox River and Green Bay, total maximum daily loads (TMDLs) were developed for TP and TSS, and actions were taken throughout the Fox River Basin to improve water quality. In this study, we estimated concentrations and loads of TP, dissolved phosphorus (DP), and TSS at the Lake Winnebago outlet, De Pere, and the mouth of the Fox River from water year (WY) 1989 to WY 2021; described changes in concentrations and loads through time during this period; and compared the concentrations and loads for the most recent 5-year period (WYs 2017–21) with the WDNR criteria for TP impairment and the TMDL loading goals. TP, DP, TSS, and total suspended sediment concentration data were obtained from NEW Water (the brand of the Green Bay Metropolitan Sewerage District), the WDNR, and the U.S. Geological Survey and combined into one dataset. All the TSS and total suspended sediment data were used together with no adjustment factor and are referred to as simply “TSS.” During WYs 1989–2021, mean annual TP concentrations increased from 0.089 milligram per liter (mg/L) at the Lake Winnebago outlet to 0.128 mg/L at the mouth of the Fox River, and concentrations decreased at all three sites from WY 1989 to WY 2021. The most recent (WYs 2017–21) median May–October TP concentrations were just less than the 0.1-mg/L WDNR criterion for TP impairment at the two upstream sites (Lake Winnebago outlet and De Pere) but were slightly greater than the criterion for impairment at the mouth of the Fox River. Mean annual DP concentrations increased from 0.024 mg/L at the Lake Winnebago outlet to 0.036 mg/L at the mouth of the Fox River. DP concentrations increased from WY 1989 to WY 2021 at the Lake Winnebago outlet but not at the other sites. Mean annual TSS concentrations increased from 13.5 mg/L at the Lake Winnebago outlet to 23.9 mg/L at the mouth of the Fox River and have decreased at all three sites from WY 1989 to WY 2021. The recent median May–October TSS concentrations were less than the 20-mg/L WDNR criterion for impairment at all three sites. Streamflow and TP, DP, and TSS loads increased from the Lake Winnebago outlet to the mouth of the Fox River (TP loads increased from 360,000 to 557,000 kilograms per year [kg/yr], DP loads increased from 114,000 to 162,000 kg/yr, and TSS loads increased from 60,400 metric tons per year [t/yr] to 122,600 t/yr). At the Lake Winnebago outlet, DP concentrations and TP and DP loads increased from WY 1989 to WY 2021 because of an increase in DP concentrations in Lake Winnebago resulting from the lake becoming nitrogen limited as a result of biological processes not consuming the DP in the lake and an increase in streamflow leaving the lake. Although TP and TSS concentrations decreased at De Pere and the mouth of the Fox River, there was little change in the loading because of an increase in flow. Flow-normalized TP and TSS loads at De Pere and the mouth of the Fox River decreased possibly because of implementation of agricultural conservation management practices, reductions in point-source discharges in its drainage basin, and deposition of sediment and phosphorus in recently dredged areas of the Lower Fox River. Additional studies are needed to determine the relative importance of each of these actions and whether the decrease in concentrations and flow-normalized loads will continue to be observed in the Fox River.

Wisconsin↗

USGS2008

Hydrology Prior to Wetland and Prairie Restoration in and around the Glacial Ridge National Wildlife Refuge, Northwestern Minnesota, 2002-5

The Nature Conservancy (TNC) owned and managed 24,795 acres of mixed wetland, native prairie, farmland and woods east of Crookston, in northwestern Minnesota. The original wetlands and prairies that once occupied this land are being restored by TNC in cooperation with many partners and are becoming part of the Glacial Ridge National Wildlife Refuge. Results of this study indicate that these restorations are likely to have a substantial effect on the local hydrology. Water occurs within the study area on the land surface, in surficial aquifers, and in buried aquifers of various depths, the tops of which are 50 to several hundred feet below the land surface. Surficial aquifers are generally thin (about 20 feet), narrow (several hundred feet), and long (tens of miles). Estimates of the horizontal hydraulic conductivity of surficial aquifers were 2.7?300 feet per day. Buried aquifers underlie much of the study area, but interact with surficial aquifers only in isolated areas. In these areas, water flows directly from buried to surficial aquifers and forms a single aquifer as much as 78 feet thick. The surface?water channel network is modified by several manmade ditches that were installed to remove excess water seasonally and to drain wetlands. The channels of the network lie primarily parallel to the beach ridges but cut through them in places. Back?beach basin wetlands delay and reduce direct runoff to ditches. Recharge to the surficial aquifers (10.97?25.08 inches per year during 2003?5) is from vertical infiltration of rainfall and snowmelt (areal recharge); from surface waters (particularly ephemeral wetlands); and from upward leakage of water from buried aquifers through till confining units (estimated at about 1 inch per year). Areal recharge is highly variable in space and time. Water leaves (discharges from) the surficial aquifers as flow to surface waters (closed basins and ditches), evapotranspiration, and withdrawals from wells. Unmeasured losses (primarily discharge to ungaged (closed) basins) were 53?115 percent of areal recharge during 2003?5, while discharge to ditches that leave the study area was 17?41 percent. Discharge over 100 percent of areal recharge indicates a loss in ground?water storage. During the dry year of 2003, substantial ground water (about one?third of annual areal recharge) was released from aquifer storage but was replenished quickly during the subsequent normal year. Shallow ground?water flow is complex, with water in surficial aquifers, ditches, and wetlands part of a single hydrologic system. The ages determined for surficial ground?water samples were less than 15 years old, and one?third (8 of 24) were less than 5 years old, substantiating the close connection of surficial ground water to the land surface. During the study, 68?81 percent of water left the area through unmeasured surface?water losses (primarily evapotranspiration), which is 2? to 4?times that leaving through the ditch system. Base flow in ditches (ground?water discharge) was 30 to 71 percent of all ditch flow. Mean annual runoff in all gaged basins except SW3 (2.26 inches per year) was similar (3.69?4.12 inches per year). The quality of water samples from surficial aquifers and surface water collected in the study area was generally suitable for most uses but was variable. Most ground? and surface?water samples were dominated by calcium, magnesium, and bicarbonate ions. About one?quarter of surficial ground?water samples contained nitrate at concentrations greater than the U.S. Environmental Protection Agency?s (USEPA) Maximum Contaminant Level for human consumption. The median concentration of dissolved phosphorus ranged from 0.0108 milligrams per liter as phosphorus (mg/L?P) to 0.0293 mg/L?P. Nutrient concentrations in ditches were generally above the USEPA nutrient guidelines for reference streams in the area. Water samples contained detectable concentrations of atrazine, acetachlor, metolachlor, pendimethalin

Scientific Investigations Report↗

USGS2009

Physical and Vegetative Characteristics of a Newly Constructed Wetland and Modified Stream Reach, Tredyffrin Township, Chester County, Pennsylvania, 2000-2006

To compensate for authorized disturbance of naturally occurring wetlands and streams during roadway improvements to U.S. Highway 202 in Chester and Montgomery Counties, Pa., the Pennsylvania Department of Transportation (PennDOT) constructed 0.42 acre of emergent wetland and 0.94 acre of scrub-shrub/forested wetland and modified sections of a 1,600-foot reach of Valley Creek with woody riparian plantings and streambank-stabilization structures (including rock deflectors). In accordance with project permits and additional guidance issued by the U.S. Army Corps of Engineers, the U.S. Geological Survey (USGS), in cooperation with PennDOT, collected data from 2000 through 2006 to quantify changes in 1) the vegetation, soils, and extent of emergent and scrub-shrub/forested parts of the constructed wetland, 2) the profile, dimension, and substrate in the vicinity of rock deflectors placed at two locations within the modified stream reach, and 3) the woody vegetation within the planted riparian buffer. The data for this investigation were collected using an approach adapted from previous investigations so that technology and findings may be more easily transferred among projects with similar objectives. Areal cover by planted and non-planted vegetation growing within the emergent and scrub-shrub/forested parts of the constructed wetland exceeded 85 percent at the end of each growing season, a criterion in special condition 25c in the U.S. Army Corps of Engineers project permit. Areal cover of vegetation in emergent and scrub-shrub/forested parts of the constructed wetland exceeded 100 percent in all but one growing season. Frequent and long-lasting soil saturation favored obligate-wetland species like Typha latifolia (broadleaf cattail) and Scirpus validus (great bulrush), both of which maintained dominance in the emergent wetland throughout the study (percent cover was 20 and 78 percent, respectively, in 2006). Echinocloa crusgalli (barnyard grass), an annual invasive from Eurasia, initially established in the newly disturbed soils of the scrub-shrub/forested wetland (areal cover was 56 percent in 2000), but by 2002, E. crusgalli was not growing in any sample plots and other species including Agrostis stolonifera (creeping bent grass), Festuca rubra (red fescue), Cornus spp. (dogwood species), and Salix nigra (black willow) were becoming more common. Sal. nigra contributed 30-percent cover in the scrub-shrub/forested wetland part by fall 2003. Rapid colonization of this species in subsequent years increased annual cover through 2006, when 15- to 25-foot tall Sal. nigra trees dominated the tree/shrub stratum (48 percent of the areal cover in 2006). The understory of the scrub-shrub/forested wetland was mostly shaded because of the canopy of Sal. nigra trees. Herbaceous species growing under and near the margins of the canopy included Ag. stolonifera and Ty. latifolia (29- and 23-percent areal cover, respectively). Flows in Valley Creek are responsible for transporting sediment and shaping the channel. Annual mean streamflow during the period the modified stream reach was monitored ranged from 15.2 cubic feet per second (ft3/s) in the 2002 water year to 53.0 ft3/s in the 2004 water year. This is a range of about 55 percent lower to 58 percent higher than the annual mean streamflow for the period of record. Despite the variability in streamflow, longitudinal profiles surveyed near rock deflectors in two short (100-foot) reaches within the modified stream reach maintained a constant slope throughout the monitoring period, most likely because of the presence of bedrock control. Cross-section geometry in the upstream reach was virtually unchanged during the monitoring period but 10 feet of bank migration was measured downstream, leaving the rock deflectors in mid-stream. As indicated by the change in channel morphology at the downstream reach, it is apparent that the rock deflectors were ineffective at adequately protecting the bank

Scientific Investigations Report↗

USGS2010

Water levels and selected water-quality conditions in the Mississippi River Valley alluvial aquifer in Eastern Arkansas, 2008

During the spring of 2008, the U.S. Geological Survey, in cooperation with the Arkansas Natural Resources Commission and the Arkansas Geological Survey, measured 670 water levels in 659 wells completed in the Mississippi River Valley alluvial aquifer in eastern Arkansas. Groundwater levels are affected by groundwater withdrawals resulting in potentiometric-surface depressions. In 2008, the lowest water-level altitude was 69 feet above National Geodetic Vertical Datum of 1929 in the center of Arkansas County. The highest water-level altitude was 288 feet above National Geodetic Vertical Datum of 1929 in northeastern Clay County on the west side of Crowleys Ridge. Two large depressions in the potentiometric surface are located in Arkansas, Lonoke, and Prairie Counties and west of Crowleys Ridge in Craighead, Cross, Lee, Monroe, Poinsett, St. Francis, and Woodruff Counties. The elongated depression in Arkansas, Lonoke, and Prairie Counties has two areas that have changed in horizontal area or depth when compared to previous conditions of the aquifer. The area in Arkansas County in the southeastern half of the depression has not expanded horizontally from recent years, although the center of the depression has deepened. The area in Lonoke and Prairie Counties in the northwestern half of the depression has not expanded and water level in the deeper part of the depression has risen. In Lonoke and Prairie Counties in the northwestern half of the depression, the 90-foot contour shown on the 2006 potentiometric-surface map is not shown on the 2008 potentiometric-surface map. Along the west side of Crowleys Ridge, the area enclosed by 140-foot contour in Cross and Poinsett Counties has expanded further south into Cross County. The 130-foot contour in Poinsett County expanded north in 2008. The 130-foot contour is shown in Cross County, which was not evident in previous years. The 130-foot contour in St. Francis, Monroe, and Woodruff Counties in 2006 is not shown on the 2008 potentiometric-surface map. A map showing the difference in water level was constructed using 595 differences in water levels measured in 585 wells during 2008 and 2004. The difference in measured water levels from 2004 to 2008 ranged from -20.6 feet to 25.9 feet, with a mean of -1.6 feet. The largest decline of -20.6 feet occurred in Randolph County and the largest rise of 25.9 feet occurred in Prairie County. Out of the 595 differences, 442 were declines (74.3 percent), 10 were no difference (values of 0.0 ft) (1.7 percent), and 143 were rises (24.0 percent). Five areas are dominated by declines that are west of Crowleys Ridge; in eastern Craighead County; in southern Mississippi and Crittenden Counties; in eastern Lonoke and western Prairie Counties; and in Arkansas, Ashley, Chicot, Desha, Drew, and Lincoln Counties. Long-term water-level changes were evaluated using hydrographs from 173 wells in the Mississippi River Valley alluvial aquifer for the period 1984 to 2008. The mean annual rise or decline in water level for the entire study area was -0.38 feet per year (ft/yr) with a range of -4.86 to 0.58 ft/yr. Independence and White Counties are the only counties with a mean annual rise from 1984 to 2008. Mean annual declines between -0.50 ft/yr and 0.00 ft/yr occurred in Arkansas, Chicot, Clay, Craighead, Crittenden, Drew, Greene, Jefferson, Mississippi, Monroe, Phillips, Poinsett, Prairie, Pulaski, Randolph, and Woodruff Counties. Mean annual declines between -1.00 ft/yr and -0.50 ft/yr occurred in Ashley, Desha, Jackson, Lee, Lincoln, and St. Francis Counties. Mean annual declines between -1.50 ft/yr and -1.00 ft/yr occurred in Cross and Lonoke Counties. The analysis of long-term water-level changes in Arkansas, Lonoke, and Prairie Counties shows the elongation of the depression in these three counties. Arkansas and Prairie Counties have two different rates of annual decline for the two hydrographs shown for each county. Water levels in the two we

Scientific Investigations Report↗

USGS2021

Evaluation of hydrologic simulation models for fields with subsurface drainage to mitigated wetlands in Barnes, Dickey, and Sargent Counties, North Dakota

Proper identification of wetlands, along with a better understanding of the hydrology of mitigated wetlands, is needed to assist with conservation efforts aimed at maintaining the productivity and ecological function (wetland mitigation) of agricultural lands. The U.S. Geological Survey, in cooperation with the U.S. Department of Agriculture Natural Resources Conservation Service, completed a study to evaluate two models for simulating hydrologic conditions in fields with subsurface drainage to mitigated wetlands at several sites in North Dakota. These two models were evaluated as possible tools for water resource managers to use for designing wetland mitigation projects in the area in the future. The Soil-Plant-Atmosphere-Water (SPAW) model simulates the daily hydrologic water budgets of agricultural landscapes by two linked routines, one for farm fields (field hydrology) and one for impoundments such as wetlands and ponds (pond model). The DRAINMOD model was used in conjunction with the SPAW model because although the SPAW model can be used to simulate the hydrology of small drainage basins containing wetlands, the SPAW model does not contain routines to simulate drainage, either subsurface drainage or surface (drainage ditches), that can directly affect the wetland hydrology. The wetlands in the study areas in this report are all downstream from and adjacent to drained agricultural fields. SPAW and DRAINMOD models were developed and calibrated at three study areas (study areas B, D, and S) to evaluate how the models simulated field-scale hydrologic characteristics and the water balance in wetlands from January 1, 2003, through December 31, 2018. The SPAW model developed for study area B included five modeled fields in the field hydrology portion of SPAW that contributed inflow to one wetland simulated in the pond model portion of SPAW. Simulated wetland water depths were most similar to water depths measured at site BWET1, with an absolute mean error of 0.10 foot and a root mean square error of 0.14 foot. Site BWET2 had slightly larger errors, with an absolute mean error of 0.22 foot and a root mean square error of 0.28 foot. Simulated water depths were similar to the pattern of measured water depths at BWET1 and BWET2 from about mid-April 2018 through about mid-September 2018, but overpredicted water depths in the fall from about mid-September 2018 through about mid-October 2018. The SPAW model developed for study area D included six modeled fields in the field hydrology portion of SPAW that contributed inflow to five wetlands connected in series in the pond model portion of SPAW. Simulated water depths compared relatively well to water depths in the five wetlands, with the absolute mean error ranging from 0.17 foot (DWET1) to 0.39 foot (DWET2), and the root mean square error ranging from 0.28 foot (DWET1) to 0.56 foot (DWET5). The SPAW model developed for study area S included one modeled field in the field hydrology portion of SPAW that contributed inflow to one wetland in the pond model portion of SPAW. Among the SPAW models developed for the three study areas, the model for study area S had the best comparison between simulated and measured water depths, with an absolute mean error of 0.06 foot and a root mean square error of 0.10 foot. DRAINMOD models were developed and calibrated at the three study areas and provided inflow from subsurface drainage discharge to the SPAW models for simulating water levels in wetlands in the study areas. The calibrated DRAINMOD model for study area B showed the variability of hydrologic processes in the modeled field throughout the wide range of hydrologic conditions from January 1, 2003, through December 31, 2018. In general, the discharge through the modeled subsurface drainage system was in the spring and early summer (April through June) most years, with little to no discharge later in the year. Although the subsurface drainage system in study area D was the most complex among the three study areas and was simplified into a uniform system within DRAINMOD, simulated water table depths at study area D correlated better to measured water table depths compared to results from the model applications at the other two study areas. Simulated water table depths had an absolute mean error of 0.30 foot and root mean square error of 0.37 foot at site DGW1 and an absolute mean error of 0.29 foot and a root mean square error of 0.34 foot at site DGW2. Although the subsurface drainage system in study area S was the simplest and the modeled field was the smallest among the three study areas, simulated water table depths at study area S did not correlate as well to measured water table depths compared to results from the model applications at the other two study areas. The SPAW and DRAINMOD model applications at the three study areas in southeast North Dakota adequately simulated the hydrologic processes for fields with subsurface drainage that are connected to adjacent wetlands. However, more measured data would be needed to fully evaluate the models throughout the range of possible climatic conditions.

North Dakota↗

USGS2024

U.S. Geological Survey Earthquake Hazards Program decadal science strategy, 2024–33

Executive Summary Earthquakes represent one of our Nation’s most significant and costly natural hazards, with estimated annual loses from earthquakes close to $15 billion in 2023. Over the past two centuries, 37 U.S. States have experienced an earthquake exceeding a magnitude of 5, and 50 percent of States have a significant potential for future damaging shaking; these statistics speak to the need for nationwide interest and investment in earthquake hazard characterization and risk reduction. Authorized under the Earthquake Hazards Reduction Authorization Act, the U.S. Geological Survey (USGS) Earthquake Hazards Program (EHP) provides the scientific information, situational awareness, and knowledge necessary to reduce deaths, injuries, and economic losses from earthquakes and earthquake-induced tsunamis, landslides, and soil liquefaction. The EHP supports activities in three focused topical areas: (1) earthquake monitoring, (2) hazard assessment, and (3) applied research, using the results of each—and the coordination among them—to further support risk translation and communication in regions at risk nationwide. For earthquake monitoring, the Advanced National Seismic System (ANSS), a cooperative effort of USGS networks, university partner regional seismic networks, and real-time geodetic networks, collects and analyzes data on earthquakes; issues timely, reliable notifications of their occurrence and impacts; and provides data for earthquake research, hazard, and risk assessment as a foundation for building an earthquake-resilient Nation. The USGS-operated ShakeAlert Earthquake Early Warning system is a recent addition to EHP’s ANSS infrastructure. In the realm of earthquake hazard assessment, the EHP contributes to earthquake risk mitigation strategies by developing the National Seismic Hazard Model and maps, and other related products, that describe the likelihood and potential effects of earthquakes nationwide, especially in the urban areas of highest risk. The EHP also conducts research on the causes, characteristics, and effects of earthquakes and prioritizes work that directly increases the accuracy and precision of earthquake hazards assessments, earthquake forecasts, and earthquake monitoring and situational-awareness products and that supports the Nation’s earthquake mitigation practices. Bridging the EHP’s efforts across research, hazard assessments, and earthquake monitoring is a broad and comprehensive collection of earthquake information products, including the National Seismic Hazard Model, ShakeAlert, and other products describing impact, such as ShakeMap and PAGER (Prompt Assessment of Global Earthquakes for Response), which have been developed and integrated into EHP’s real-time monitoring systems. EHP funds external partners to carry out many important collaborative activities through an active external grants program—one of the largest in the USGS—and through cooperative agreements with other partners such as the university-operated regional seismic networks, funded as part of the ANSS. To continue its support of earthquake hazard characterization and risk reduction, the EHP aims to strengthen its foundational products and practices while positioning itself to respond to the evolving needs of the Nation and follow best practices of the scientific community. This document describes a strategy for the program to ensure it can meet these demands. The foundational priorities outlined in this strategy represent those activities that remain critical to the core functionality of the program and those that can be supported under current fiscal year 2024-level appropriations. Priorities described as aspirational are important for future growth, and to maintain the program’s position as a leading global resource in earthquake science, but would require increases in appropriated funding to be fully realized. Across the program’s portfolio of activities, several major themes have been identified as the most critical activities to advance EHP science over the coming decade. Together, these activities provide the framework necessary to integrate critical hazard characterization and risk reduction activities across the program. They provide the structure for research to advance the understanding of where, when, and why earthquakes occur and how we can use improved knowledge to drive short-term and actionable forecasts of seismic activity. They expand the usefulness of critical earthquake products and advance the sophistication of those products to keep pace with the rapidly evolving needs of an ever-expanding user base while maintaining the position of the USGS as a global leader in earthquake science. Focus on system-level science. Establish an automated earthquake-processing pipeline. Enhance the accuracy and reliability of the ShakeAlert Earthquake Early Warning system and plan for extension to other regions. Implement time-dependent earthquake forecasting. Develop physically realistic models. Expand computational capacity. This science strategy is organized into three primary sections. The first section provides an overview of the EHP and its budget, governance, and program council. Readers familiar with the program may wish to focus on the second section, which describes the core of the science strategy, including priorities across each of the EHP’s major program activities in monitoring, hazard assessment, and targeted research. The third section outlines science priorities that cut across program activities, including those involving collaborations external to the EHP.

American Samoa, Guam, Northern Marianas Islands, U↗

USGS2008

Water Levels and Selected Water-Quality Conditions in the Mississippi River Valley Alluvial Aquifer in Eastern Arkansas, 2006

During the spring of 2006, the U.S. Geological Survey, in cooperation with the Arkansas Natural Resource Commission and the Arkansas Geological Survey, measured water levels in 707 wells completed in the Mississippi River Valley alluvial aquifer in eastern Arkansas. Ground-water levels are affected by ground-water withdrawals resulting in depressions. In 2006, the lowest water-level altitude was 76 feet above the National Geodetic Vertical Datum of 1929 in the center of Arkansas County. The highest water-level altitude was 289 feet above the National Geodetic Vertical Datum of 1929 in northeastern Clay County on the west side of Crowleys Ridge. Two large depressions in the potentiometric surface are located in Arkansas, Lonoke, and Prairie Counties and west of Crowleys Ridge in Craighead, Cross, Lee, Monroe, Poinsett, St. Francis, and Woodruff Counties. The elongated depression in Arkansas, Lonoke, and Prairie Counties has changed in areal extent or depth when compared to previous conditions of the aquifer. The area in Arkansas County at the southeastern half of the depression has not expanded horizontally during recent years, although the center of the depression has deepened. The area in Lonoke and Prairie Counties in the northwestern half of the depression has expanded horizontally in the deeper part of the depression. The 90-foot contour has expanded north and east in Lonoke County when compared with the 2004 potentiometric surface. Along the west side of Crowleys Ridge the 2006 potentiometric-surface map shows very little change in the area of this depression, although the deeper areas within the depression have expanded. A map showing the difference in water level was constructed using 645 differences in water-levels measured in 633 wells during 2002 and 2006. The difference in measured water levels from 2002 to 2006 ranged from -24.0 feet to 25.0 feet, with a mean of -2.0 feet. The largest decline of -24.0 feet occurred in Poinsett County and the largest rise of 25.0 feet occurred in Randolph County. Out of the 645 differences, 481 were declines (74.6 percent), 12 were no difference (values of 0.0 ft) (1.8 percent), and 152 were rises (23.6 percent). Long-term water-level trends were evaluated using hydrographs from 152 wells completed in the Mississippi River Valley alluvial aquifer for the period 1982 to 2006. The mean annual rise or decline in water level for the entire study area was -0.32 feet per year with a range of -1.28 to 0.77 feet per year. Independence and White Counties are the only counties with a mean annual rise from 1982 to 2006. Mean annual declines between -0.50 feet per year and 0.00 feet per year occurred in Arkansas, Ashley, Chicot, Clay, Craighead, Crittenden, Drew, Jefferson, Lee, Mississippi, Monroe, Phillips, Poinsett, Prairie, Pulaski, Randolph, and Woodruff Counties. Mean annual declines between -1.00 feet per year and -0.50 feet per year occurred in Cross, Desha, Greene, Jackson, Lincoln, Lonoke, and St. Francis Counties. The analysis of long-term water-level changes in Arkansas, Lonoke, and Prairie Counties shows the elongation of the depression in these three counties. Both Arkansas and Prairie Counties have two different rates of annual decline for the two hydrographs shown for each county. Water levels in the two wells near the Arkansas and White Rivers either have risen or declined at a slower rate than in the three wells in the center, northern, and western part of the depression. These rates of water-level change indicate that this depression is expanding in an elongated direction north and west into Lonoke and Prairie Counties. The depression west of Crowleys Ridge has five wells with hydrographs in or near the depression that can be used to characterize the rates of water-level change within the depression. Water samples were collected from 65 wells completed in the Mississippi River Valley alluvial aquifer and measured onsite for specific conductance and tempera

Scientific Investigations Report↗

USGS2012

Status of groundwater quality in the Upper Santa Ana Watershed, November 2006--March 2007--California GAMA Priority Basin Project

Groundwater quality in the approximately 1,000-square-mile (2,590-square-kilometer) Upper Santa Ana Watershed (USAW) study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in southern California in Riverside and San Bernardino Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The GAMA USAW study was designed to provide a spatially unbiased assessment of untreated groundwater quality within the primary aquifer systems in the study unit. The primary aquifer systems (hereinafter, primary aquifers) are defined as the perforation interval of wells listed in the California Department of Public Health (CDPH) database for the USAW study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifers; shallower groundwater may be more vulnerable to surficial contamination. The assessment is based on water-quality and ancillary data collected by the U.S. Geological Survey (USGS) from 90 wells during November 2006 through March 2007, and water-quality data from the CDPH database. The status of the current quality of the groundwater resource was assessed based on data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the USAW study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal or California regulatory or non-regulatory benchmarks for drinking-water quality. A relative-concentration greater than (>) 1.0 indicates a concentration above a benchmark, and a relative-concentration less than or equal to (≤) 1.0 indicates a concentration equal to or less than a benchmark. Organic and special-interest constituent relative-concentrations were classified as "high" (> 1.0), "moderate" (0.1 < relative-concentration ≤ 1.0), or "low" (≤ 0.1). Inorganic constituent relative-concentrations were classified as "high" (> 1.0), "moderate" (0.5 < relative-concentration ≤ 1.0), or "low" ( ≤ 0.5). Aquifer-scale proportion was used as the primary metric in the status assessment for evaluating regional-scale groundwater quality. Aquifer-scale proportions are defined as the percentage of the area of the primary aquifer system with concentrations above or below specified thresholds relative to regulatory or aesthetic benchmarks. High aquifer-scale proportion is defined as the percentage of the area of the primary aquifers with a relative-concentration greater than 1.0 for a particular constituent or class of constituents; percentage is based on an areal, rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers with moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially weighted—were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable in the USAW study unit (within 90-percent confidence intervals). Inorganic constituents with human-health benchmarks had relative-concentrations that were high in 32.9 percent of the primary aquifers, moderate in 29.3 percent, and low in 37.8 percent. The high aquifer-scale proportion of these inorganic constituents primarily reflected high aquifer-scale proportions of nitrate (high relative-concentration in 25.3 percent of the aquifer), although seven other inorganic constituents with human-health benchmarks also were detected at high relative-concentrations in some percentage of the aquifer: arsenic, boron, fluoride, gross alpha activity, molybdenum, uranium, and vanadium. Perchlorate, as a constituent of special interest, was evaluated separately from other inorganic constituents, and had high relative-concentrations in 11.1 percent, moderate in 53.3 percent, and low or not detected in 35.6 percent of the primary aquifers. In contrast to the inorganic constituents, relative-concentrations of organic constituents (one or more) were high in 6.7 percent, moderate in 11.1 percent, and low or not detected in 82.2 percent of the primary aquifers. Of the 237 organic and special-interest constituents analyzed for, 39 constituents were detected (21 VOCs, 13 pesticides, 3 pharmaceuticals, and 2 constituents of special interest). All of the detected VOCs had health-based benchmarks, and five of these—1,1-dichloroethene, 1,2-dibromo-3-chloropropane (DBCP), tetrachloroethene (PCE), carbon tetrachloride, and trichloroethene (TCE)—were detected in at least one sample at a concentration above a benchmark (high relative-concentration). Seven of the 13 pesticides had health-based benchmarks, and none were detected above these benchmarks (no high relative-concentrations). Pharmaceuticals do not have health-based benchmarks. Thirteen organic constituents were frequently detected (detected in at least 10 percent of samples without regard to relative-concentrations): bromodichloromethane, chloroform, cis-1,2-dichloroethene, 1,1-dichloroethene, dichlorodifluoromethane (CFC-12), methyl tert-butyl ether (MTBE), PCE, TCE, trichlorofluoromethane (CFC-11), atrazine, bromacil, diuron, and simazine.

California↗