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USGS2019

Factors affecting 1,2,3-trichloropropane contamination in groundwater in California

1,2,3-Trichloropropane (1,2,3-TCP) is a volatile organic chemical of eminent concern due to its carcinogenic, mutagenic, and reproductive effects, and its frequent occurrence at concentrations of concern worldwide. In California, 1,2,3-TCP was detected in 6.5% of 1237 wells sampled by the U. S. Geological Survey (USGS). About 8% of domestic wells had a detection of 1,2,3-TCP, compared to 5% of public-supply wells. 1,2,3-TCP was detected in 5.5% of most recent samples from 7787 public-supply well sources of the California State Water Resources Control Board Division of Drinking Water (DDW). Concentrations ranged from <0.005 to 2.7 μg/L. The California maximum contaminant level (MCL) is 0.005 μg/L. Most of the detections occurred in the San Joaquin Valley, where 1,2,3-TCP was detected above the MCL in 16% of USGS sampled wells and 18% of DDW wells. 1,2,3-TCP occurrence and concentrations are related to legacy fumigant use and hydrogeologic factors. Understanding factors affecting 1,2,3-TCP will aid in determining vulnerability and long term persistence in the San Joaquin Valley, which can help focus efforts to manage drinking water resources on the most vulnerable areas and also inform efforts in other areas of the state and worldwide. Widespread occurrence of 1,2,3-TCP is related to nonpoint source agricultural contaminant inputs. High concentrations of 1,2,3-TCP are in young, shallow, oxic groundwater beneath primarily orchard/vineyard crops. These areas are in coarse-grained sediments that promote rapid recharge, related to proximal alluvial fan sediments deposited by large streams that drain glaciated watersheds of the Sierra Nevada. 1,2,3-TCP co-occurs with 1,2-dibromo-3-chloropropane (DBCP) and 1,2-dichloropropane (1,2-DCP) throughout modern age groundwater, indicating its long term persistence with little degradation. The highest concentrations of 1,2,3-TCP were observed at point source cleanup sites in urban areas; depending on the age and source of groundwater to nearby public-supply wells, these areas may see increasing concentrations of 1,2,3-TCP.

California↗

USGS1980

Chemical mass-wasting of the northern Yucatan Peninsula by groundwater dissolution

The northern part of the Yucatan Peninsula is a relatively flat, low-lying carbonate terrane with no geomorphic expressions of stream channels. It is estimated that mean annual recharge to the groundwater system is 150 mm. For the 65,500 km 2 study area, mean annual discharge (equivalent to recharge) is 9.8 × 10 9 m 3 , or 8.6 × 10 6 m 3 for each 1 km of the 1,100-km-long coastline. In the interior of the peninsula, the recharging water annually dissolves about 37.5 t (metric tons) of calcite per 1 km 2 . When the groundwater has become saturated with calcite, little additional water-rock interaction occurs until the active mixing (dispersion) zone is reached near the coastline. Theoretical calculations and laboratory experiments have shown that when two waters, each calcite saturated and with different salinities, are mixed, the resulting solution generally becomes undersaturated with calcite and, therefore, is capable of dissolving additional calcite. On the basis of our study of the Xel Ha lagoon on the east coast of Yucatan, we calculate that as much as 1.2 mmol/L additional calcite can be dissolved in the brackish groundwater zone of dispersion. This indicates that if the total solution potential of the amount of water discharging at Xel Ha has focused within the lagoon area, the lagoon could be chemically incised in less than 3,000 yr. We postulate that chemical mass wasting by dissolution in the zone of groundwater mixing is an important geomorphic process in coastal areas of limestone terranes.

Yucatan Peninsula↗

USGS1952

Pitchblende deposits at the Wood and Calhoun mines, Central City mining district, Gilpin County, Colorado

Pitchblende has been mined in commercial quantities from four gold- and silver-bearing pyrite-sphalerite-galena veins that occur in an area about one-half mile square on the south side of Quartz Hill, Central City district, Gilpin County, Colo. These veins are the Kirk, the German-Belcher, the Wood, and the Calhoun. Two of these veins, the Wood and the Calhoun, were studied in an attempt to determine the geologic factors favorable for pitchblende deposition. All accessible workings at the Wood and East Calhoun mines were mapped by tape and compass, and the distribution of radioactivity was studied in the field. Channel and chip samples were taken for chemical assay to compare radioactivity with uranium content. The pitchblende-bearing veins cat both pre-Cambrian granite gneiss and quartz-biotite schist; however, the gneiss was the more favorable host rock. Two bostonite porphyry dikes of Tertiary(?) age were crosscut by the Wood and Calhoun veins. The pitchblende occurs in lenses erratically distributed along the veins and in stringers extending outward from the veins. In the lenses it forms hard'. masses, but elsewhere it is Soft and powdery. The pitchblende is contemporaneous with the pyrite bat earlier than the sphalerite and galena in the same vein. All the observed pitchblende was at depths of less than 400 ft. The veins probably cannot be mined profitably for the pitchblende alone under present conditions.

Circular↗

USGS2008

Concentration and spatial distribution of selected constituents in Detroit River bed sediment adjacent to Grassy Island, Michigan, August 2006

In August 2006, the U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service, collected sediment?core samples from the bed of the Detroit River adjacent to Grassy Island. The goal of the sampling was to assess the distribution and concentration of chemical constituents in sediment adjacent to Grassy Island, which was operated from 1960 to 1982 as a confined disposal facility to hold dredge spoils. On August 31, 2006, seven samples were collected at four locations in the Detroit River on the north, south, east, and west sides of the island. Metals concentrations in the riverbed sediment tended to be higher on the west side of the island, whereas organic?compound concentrations were generally higher on the east side. Comparison of results from this sampling to concentrations reported in previous studies indicates that the concentrations of inorganic constituents, mainly metals, in the riverbed sediment around Grassy Island fell within the range of concentrations found regionally throughout the Detroit River and in most cases have lower mean and median values than found elsewhere regionally in the Detroit River. Comparison of results from the August 31, 2006, sampling to U.S. Environmental Protection Agency risk?based sediment?quality guidelines indicates that 18 organic constituents for which an ecological screening level (ESL), and (or) a threshold effect concentration (TEC), and (or) a probable effect concentration (PEC) has been defined exceeded one or more of these guidelines at least once. Further work would be needed to determine whether constituent concentrations in the river sediment are related to constituent runoff from Grassy Island.

Michigan↗

USGS2016

Data from exploratory sampling of groundwater in selected oil and gas areas of coastal Los Angeles County and Kern and Kings Counties in southern San Joaquin Valley, 2014–15: California oil, gas, and groundwater project

Exploratory sampling of groundwater in coastal Los Angeles County and Kern and Kings Counties of the southern San Joaquin Valley was done by the U.S. Geological Survey from September 2014 through January 2015 as part of the California State Water Resources Control Board’s Water Quality in Areas of Oil and Gas Production Regional Groundwater Monitoring Program. The Regional Groundwater Monitoring Program was established in response to the California Senate Bill 4 of 2013 mandating that the California State Water Resources Control Board design and implement a groundwater-monitoring program to assess potential effects of well-stimulation treatments on groundwater resources in California. The U.S. Geological Survey is in cooperation with the California State Water Resources Control Board to collaboratively implement the Regional Groundwater Monitoring Program through the California Oil, Gas, and Groundwater Project. Many researchers have documented the utility of different suites of chemical tracers for evaluating the effects of oil and gas development on groundwater quality. The purpose of this exploratory sampling effort was to determine whether tracers reported in the literature could be used effectively in California. This reconnaissance effort was not designed to assess the effects of oil and gas on groundwater quality in the sampled areas. A suite of water-quality indicators and geochemical tracers were sampled at groundwater sites in selected areas that have extensive oil and gas development. Groundwater samples were collected from a total of 51 wells, including 37 monitoring wells at 17 multiple-well monitoring sites in coastal Los Angeles County and 5 monitoring wells and 9 water-production wells in southern San Joaquin Valley, primarily in Kern and Kings Counties. Groundwater samples were analyzed for field waterquality indicators; organic constituents, including volatile and semi-volatile organic compounds and dissolved organic carbon indicators; naturally present inorganic constituents, including trace elements, nutrients, major and minor ions, and iron species; naturally present stable and radioactive isotopes; dissolved noble gases; dissolved standard and hydrocarbon gases, δ13C of methane, ethane, and δ2 H of methane. In total, 249 constituents and water-quality indicators were measured. Four types of quality-control samples (blanks, replicates, matrix spikes, and surrogates spiked in environmental and blank samples) were collected at approximately 10 percent of the wells. The quality-control data were used to determine whether the groundwater-sample data were of sufficient quality for the measured analytes to be used as potential indicators of oil and gas effects. The data from the 51 groundwater samples and from the quality-control samples are presented in this report.

California↗

USGS2025

Reconnaissance of potential alternate water supply sources for the City of Gary, West Virginia

Seven potential sources of water, consisting of free-flowing discharge from abandoned coal mines at six locations and one abandoned flooded underground coal mine air shaft, were sampled for chemical analysis to assess the quality of the groundwater emanating from the seven mine sources. The six free-flowing mine discharge sources were also assessed for discharge by current-meter measurements on two separate occasions. The U.S. Geological Survey assessed these seven sources to provide information to the City of Gary, West Virginia (W. Va.), and the City of Gary’s consulting engineer with groundwater-quality and flow data to allow them to assess the seven sites as potential alternate sources of water for the City of Gary to augment its existing supply. For the six sites where discharge could be measured, discharge ranged from a minimum of 0.082 cubic feet per second (ft 3 /s) to a maximum of 3.685 ft 3 /s. Of the six sites measured, only two, Harmon Branch at Thorpe, W. Va. (USGS site 372201081303501) and the abandoned public-supply water wells near Havaco, W. Va. (USGS site 372358081344601), had discharge in excess of 1.00 ft 3 /s. Discharge from the abandoned public supply wells was 3.685 ft 3 /s on September 20, 2023, and 2.888 ft 3 /s on October 16, 2023, and discharge from Harmon Branch at Thorpe, W. Va., was 1.049 ft 3 /s on September 22, 2023, and 1.038 ft 3 /s on October 17, 2023. Discharge in the abandoned underground mine air shaft (USGS site 372224081340901) could not be assessed, but the air shaft drains an abandoned mine that likely contains water stored in approximately 1.7 square miles (mi 2 ) of abandoned underground coal mines in the Pocahontas No. 3 coal seam, and possibly an additional 0.9 mi 2 of leakage from the overlying Pocahontas No. 4 coal seam. Discharge for the six sites measured for the study was measured during a period between September 20 and October 18, 2023, and corresponded to the 12th to the 15th percentile of flow-duration statistics for the Tug Fork downstream of Elkhorn Creek at Welch, W. Va. streamgage (USGS site 03212750). Water-quality data for the seven sites sampled overall were acceptable with respect to drinking water standards. Of the 203 constituents analyzed, only a few failed to meet applicable U.S. Environmental Protection Agency (EPA) drinking water standards. Iron exceeded the 300 micrograms per liter (μg/L) secondary maximum contaminant level (SMCL) at only 1 of the 7 sites (14.3 percent) sampled. Iron concentrations ranged from a minimum of less than (<) 5.00 μg/L to a maximum of 724 μg/L with a median concentration of 7.62 μg/L. Manganese exceeded the 50.0 μg/L SMCL at 2 of the 7 sites (28.6 percent) sampled. Manganese concentrations ranged from a minimum of 1.93 μg/L to a maximum of 271 μg/L with a median concentration of 4.03 μg/L. No sites sampled exceeded the arsenic maximum contaminant level (MCL) of 10 μg/L. Arsenic concentrations ranged from a minimum of <0.100 μg/L to a maximum of 2.35 μg/L with a median arsenic concentration of 0.200 μg/L. None of the seven sites sampled for selenium for this study exceeded the EPA MCL of 50.0 μg/L. Selenium concentrations ranged from a minimum of <0.050 μg/L to a maximum of 5.26 μg/L with a median concentration of 3.21 μg/L. All seven sites were sampled for volatile organic compounds (VOCs), semivolatile organic compounds (SVOCs), and polychlorinated biphenyls (PCBs), but most had concentrations below the detection limit. Of the 10 PCB compounds analyzed for the seven sites sampled, none contained detectable concentrations of PCBs or Aroclor compounds. Of the 44 SVOCs analyzed at each of the seven sites sampled, only 1 SVOC, acenaphthene, was detected, at a concentration of 0.02 μg/L. Of the 96 VOCs analyzed, from each of the seven sites sampled, only two were found at detectable concentrations. Trichloromethane was detected only at 1 of the 7 (14.3 percent) sites sampled at a concentration of 0.027 μg/L, and benzene was detected at the same site and 3 additional sites (4 of the 7 sites or 57.1 percent of the sites sampled) at concentrations of 0.028, 0.029, 0.021, and 0.035 μg/L, but none exceeded the EPA MCL for benzene of 5.00 μg/L. Total coliform bacteria are ubiquitous in the environment, and their presence only suggests the potential for contamination by near-surface processes. Escherichia coli ( E. coli ) bacteria are derived from either human or animal fecal material and can be an indicator of potential contamination by pathogenic bacteria or viruses. Total coliform bacteria were detected at all 7 sites sampled at concentrations ranging from 17.5 to greater than (>) 2,420 most probable number per 100 mL (MPN/100 mL) of sample, with a median total coliform concentration of 1,553 MPN/100 mL. Escherichia coli bacteria were detected at 4 of the 7 sites sampled at concentrations ranging from <1 to 11.9 MPN/100 mL, with a median E. coli concentration of 5.1 MPN/100 mL.

West Virginia↗

USGS1980

A catalogue of drill core recovered from Kilauea Iki lava lake, from 1967 to 1979

The purpose of this report is to serve as a descriptive catalogue for drill core recovered from Kilauea Iki lava lake, from 1967 to 1979. Kilauea Iki lava lake was formed when lavas of the 1959 summit eruption were ponded in Kilauea Iki pit crater, a large pit crater at the extreme upper end of Kilauea's east rift zone (Fig. 1). This eruption is one of the best documented of Kilauean eruptions: Murata and Richter (1966) and Richter and Murata (1966) presented data on the chemistry and petrography of the lavas, respectively, and Richter et al. (1970) described the complex filling of the pit crater in considerable detail. Investigation of the lava lake began a few months after the crust stabilized, with the establishment of two perpendicular lines of levelling stations on the surface of the lake. In 1960-62, four holes were drilled through the upper crust in the center of the lake; the crust was 22-44 feet (6.7-13.4 m) thick at that time. Richter and Moore (1966) presented petrographic, modal, and chemical data on the core recovered from this early drilling. The upper crust of Kilauea Iki was drilled again in 1967 by staff members of the Hawaiian Volcano Observatory, and core was recovered from three holes. In 1975, U.S. Geological Survey workers drilled three more holes, each a few feet away from one of the 1 967 holes. A summary of all work done on Kilauea Iki and other Hawaiian lava lakes through 1975 has been given by Wright et al. (1976). The lake has been redrilled twice since 1975, by workers from Sandia Laboratories, as part of their Magma Energy Research program, in cooperation with the U.S. Geological Survey. In 1976, they drilled two holes near the center of the lake. In 1978-79, they drilled a total of six holes; one, commissioned by the U.S. Geological Survey, went completely through the lava lake near its north edge, into the pre-1959 lavas below.

Hawaii↗

USGS1993

Analytical results for As species and related elements in interstitial porewater and sediment from the Maurice River and Union Lake in Vineland, New Jersey

Union Lake, the Maurice River, and the Blackwater Branch , a tributary of the Maurice River, all parts of a small watershed near Vineland, New Jersey, are contaminated by arsenic (As) from a local chemical factory (fig. l)(Faust and others, 1987). An indepth study to be used for the design of the remedial action at the Vineland Chemical Co. Superfund site was initiated by the U.S. Environmental Protection Agency to determine the extent and severity of the contamination. The Vineland Chemical Co. site is located in Cumberland County, New Jersey. Organic As herbicides were manufactured there from approximately 1949 to the late 1980's. As part of the effort, core samples were collected in the Maurice River close to the chemical factory and from Union Lake, a reservoir approximately seven miles from the factory. This report summarizes the analytical results for As speciation and various constituents in the interstitial porewater and associated sediment from these cores. Because the U.S. Geological Survey has the analytical expertise and necessary equipment, the samples were analyzed in USGS laboratories in Denver, Colorado and Seattle, Washington.

New Jersey↗

USGS2007

Assessment of elemental concentrations in streams of the New Lead Belt in southeastern Missouri, 2002-05

Concerns about possible effects of lead-mining activities on the water quality of federally protected streams located in southeastern Missouri prompted a suite of multidisciplinary studies to be conducted by the U.S. Geological Survey. As part of this investigation, a series of biological studies were initiated in 2001 for streams in the current mining region and the prospecting area. In this report, results are examined for trace elements and other selected chemical measurements in sediment, surface water, and sediment interstitial (pore) water sampled between 2002 and 2005 in association with these biological studies. Compared to reference sites, fine sediments collected downstream from mining areas were enriched in metals by factors as large as 75 for cadmium, 62 for cobalt, 171 for nickel, 95 for lead, and 150 for zinc. Greatest metal concentrations in sediments collected in 2002 were from sites downstream from mines on Strother Creek, Courtois Creek, and the West Fork Black River. Sediments from sites on Bee Fork, Logan Creek, and Sweetwater Creek also were noticeably enriched in lead. Sediments in Clearwater Lake, at least 75 kilometers downstream from mining activity, had metal concentrations that were 1.5 to 2.1 times greater than sediments in an area of the lake with no upstream mining activity. Longitudinal sampling along three streams in 2004 indicated that sediment metal concentrations decreased considerably a few kilometers downstream from mining activities; however, in Strother Creek some metals were still enriched by a factor of five or more as far as 13 kilometers downstream from the Buick tailings impoundment. Compared with 2002 samples, metals concentrations were dramatically lower in sediments collected in 2004 at an upper West Fork Black River site, presumably because beneficiation operations at the West Fork mill ceased in 2000. Concentrations of metals and sulfate in sediment interstitial (pore) waters generally tracked closely with metal concentrations in sediments. Metals, including cobalt, nickel, lead, and zinc, were elevated substantially in laboratory-produced pore waters of fine sediments collected near mining operations in 2002 and 2004. Passive diffusion samplers (peepers) buried 4 to 6 centimeters deep in riffle-run stream sediments during 2003 and 2005 had much lower pore-water metal concentrations than the laboratory-produced pore waters of fine sediments collected in 2002 and 2004, but each sampling method produced similar patterns among sites. The combined mean concentration of lead in peeper samples from selected sites located downstream from mining activities for six streams was about 10-fold greater than the mean of the reference sites. In most instances, metals concentrations in surface water and peeper water were not greatly different, indicating considerable exchange between the surface water and pore water at the depths and locations where peepers were situated. Passive sampling probes used to assess metal lability in pore waters of selected samples during 2004 sediment toxicity tests indicated that most of the filterable lead in the laboratory-prepared pore water was relatively non-labile, presumably because lead was complexed by organic matter, or was present as colloidal species. In contrast, large percentages of cobalt and nickel in pore water appeared to be labile. Passive integrative samplers deployed in surface water for up to 3 weeks at three sites in July 2005 confirmed the presence of elevated concentrations of labile metals downstream from mining operations on Strother Creek and, to a lesser extent, Bee Fork. These samplers also indicated a considerable increase in metal loadings occurred for a few days at the Strother Creek site, which coincided with moderate increases in stream discharges in the area.

Scientific Investigations Report↗

USGS2016

Sediment oxygen demand in eastern Kansas streams, 2014 and 2015

Dissolved oxygen concentrations in streams are affected by physical, chemical, and biological factors in the water column and streambed, and are an important factor for the survival of aquatic organisms. Sediment oxygen demand (SOD) rates in Kansas streams are not well understood. During 2014 and 2015, the U.S. Geological Survey, in cooperation with the Kansas Department of Health and Environment, measured SOD at eight stream sites in eastern Kansas to quantify SOD rates and variability with respect to season, land use, and bottom-sediment characteristics. Sediment oxygen demand rates (SOD T ) ranged from 0.01 to 3.15 grams per square meter per day at the ambient temperature of the measurements. The summer mean SOD rate was 3.0-times larger than the late fall mean rate, likely because of increased biological activity at warm water temperatures. Given the substantial amount of variability in SOD rates possible within sites, heterogeneity of substrate type is an important consideration when designing SOD studies and interpreting the results. Sediment oxygen demand in eastern Kansas streams was correlated with land use and streambed-sediment characteristics, though the strength of relations varied seasonally. The small number of study sites precluded a more detailed analysis. The effect of basin land use and streambed sediment characteristics on SOD is currently (2016) not well understood, and there may be many contributing factors including basin influences on water quality that affect biogeochemical cycles and the biological communities supported by the stream.

Kansas↗

USGS1974

Water resources data for Georgia, water year 1973

Water resources data for the 1973 water year for Georgia include records of streamflow or reservoir storage at gaging stations, partial record stations, miscellaneous sites, and records of water-quality data on the chemical and physical characteristics of surface-water as well as records for a few pertinent gaging and water-quality stations in bordering States. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of John R. George, district chief. These data represent the Georgia portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies.

Georgia↗

USGS1970

Water resources data for Indiana, 1969

Surface-water records for the 1969 water year for Indiana, including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, are given in this report and their locations shown in figures 1 and 3. Records for a few pertinent gaging stations in bordering States are also included. Water resources data for the 1969 water year for Indiana include records of data for the chemical and physical characteristics of surface water. Records for a few pertinent water-quality stations in bordering States are also included.

Indiana↗

USGS1972

Water resources data for Louisiana, water year 1971

Water-resources data for the 1971 water year for Louisiana, including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, and records of water-quality data on the chemical and physical characteristics of surface water are given in this report. Records for a few pertinent gaging stations in bordering States are also included. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Albert N. Cameron, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and federal agencies in Louisiana.

Louisiana↗

USGS1973

Water resources data for Louisiana, water year 1972

Water-resources data for the 1972 water year for Louisiana, including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, and records of water-quality data on the chemical and physical characteristics of surface water are given in this report. Records for a few pertinent gaging stations in bordering States are also included. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Albert N. Cameron, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and federal agencies in Louisiana.

Louisiana↗

USGS1987

Comparison of conceptually based and regression rainfall-runoff models, Denver Metropolitan area, Colorado, and potential applications in urban areas

Multievent, conceptually based models and a single-event, multiple linear-regression model for estimating storm-runoff quantity and quality from urban areas were calibrated and verified for four small (57 to 167 acres) basins in the Denver metropolitan area, Colorado. The basins represented different land-use types - light commercial, single-family housing, and multi-family housing. Both types of models were calibrated using the same data set for each basin. A comparison was made between the storm-runoff volume, peak flow, and storm-runoff loads of seven water quality constituents simulated by each of the models by use of identical verification data sets. The models studied were the U.S. Geological Survey 's Distributed Routing Rainfall-Runoff Model-Version II (DR3M-II) (a runoff-quantity model designed for urban areas), and a multievent urban runoff quality model (DR3M-QUAL). Water quality constituents modeled were chemical oxygen demand, total suspended solids, total nitrogen, total phosphorus, total lead, total manganese, and total zinc. (USGS)

Water-Resources Investigations Report↗

USGS1990

Geohydrology and water quality of Kalamazoo County, Michigan, 1986-88

Thick, glacial sand and gravel deposits provide most ground-water supplies in Kalamazoo County. These deposits range in thickness from 50 to about 600 feet in areas that overlie buried bedrock valleys. Most domestic wells completed at depths of less than 75 feet in the sands and gravels yield adequate water supplies. Most industry, public supply, and irrigation wells completed at depths of 100 to 200 feet yield 1,000 gallons per minute or more. The outwash plains include the most productive of the glacial aquifers in the county. The Coldwater Shale of Mississippian age, which underlies the glacial deposits in most of the county, usually yields only small amounts of largely mineralized water. Ground-water levels in Kalamazoo County reflect short- and long-term changes in precipitation and local pumpage. Ground-water levels increase in the spring and decline in the fall. Ground-water recharge rates, for different geologic settings, were estimated from ground-water runoff to the streams. Recharge rates ranged from 10.86 to 5.87 inches per year. A countywide-average ground-water recharge rate is estimated to be 9.32 inches per year. Chemical quality of precipitation and dry fallout at two locations in Kalamazoo County were similar to that of other areas in the State. Total deposition of dissolved sulfate is 30.7 pounds per acre per year, of total nitrogen is 13.2 pounds per acre per year, and of total phosphorus is 0.3 pounds per acre per year. Rainfall and snow data indicated that the pH of precipitation is inversely proportional to its specific conductance. Water of streams and rivers of Kalamazoo County is predominately of the calcium bicarbonate type, although dissolved sulfate concentrations are slightly larger in streams in the southeastern and northwestern parts of the county. The water in most streams is hard to very hard. Concentrations of dissolved chloride in streams draining urban-industrial areas are slightly larger than at other locations. Concentrations of total nitrogen and total phosphorus in streams are directly proportional to streamflow. Except for elevated concentrations of iron, none of the trace elements in streams exceeded maximum contaminant levels for drinking water established by the U.S. Environmental Protection Agency. Pesticides were detected in some streams. Ground water in the surficial aquifers is of the calcium bicarbonate type, although sodium, sulfate, and chloride ions predominate at some locations. Specific conductance and hardness and concentrations of total dissolved-solids slightly exceed statewide averages. Concentrations of dissolved sodium and dissolved chloride in 6 wells were greater than most natural ground waters in the State, indicating possible contamination from road salts. Water samples from 6 of the 46 wells sampled contained concentrations of total nitrate as nitrogen greater than 10.0 milligrams per liter. Elevated concentrations of total nitrate as nitrogen in water from wells in rural-agricultural areas probably are related to fertilizer applications. Results of partial chemical analyses by the Michigan Department of Public Health indicates specific conductance, and concentrations of hardness, dissolved fluoride, and total iron are fairly uniform throughout the county. Concentrations of dissolved sodium, dissolved chloride, and total nitrate as nitrogen differed among townships. Pesticides were detected in water from only one well. Water from five wells contained volatile organics. A map of susceptibility of ground water to contamination in Kalamazoo County was developed using a system created by the U.S. Environmental Protection Agency. Seven geohydrologic factors that affect and control ground-water movement are mapped and composited onto a countywide map. All seven factors have some effect on countywide susceptibility, but the most important factors are depth to water and composition of the materials above the aquifer.

Michigan↗

USGS1999

Water quality of Rob Roy Reservoir and Lake Owen, Albany County, and Granite Springs and Crystal Lake Reservoirs, Laramie County, Wyoming, 1997-98

The water quality of four reservoirs was assessed during 1997 and 1998 as a cooperative project between the Cheyenne Board of Public Utilities and the U. S. Geological Survey. The four reservoirs, Rob Roy, Lake Owen, Granite Springs, and Crystal Lake, provide approximately 75 percent of the public water supply for Cheyenne, Wyoming. Samples of water and bottom sediment were collected and analyzed for selected physical, chemical, and biological characteristics to provide data about the reservoirs. Water flows between the reservoirs through a series of pipelines and stream channels. The reservoirs differ in physical characteristics such as elevation, volume, and depth. Profiles of temperature, dissolved oxygen, specific conductance, and pH were examined. Three of the four reservoirs exhibited stratification during the summer. The profiles indicate that stratification develops in all reservoirs except Lake Owen. Stratification developed in Rob Roy, Granite Springs, and Crystal Lake Reservoirs by mid-July in 1998 and continued until September, with the thickness of the epilimnion increasing during that time. Secchi disk readings indicated Rob Roy Reservoir had the clearest water of the four reservoirs studied. The composition of the phytoplankton community was different in the upper two reservoirs from that in the lower two reservoirs. Many of the species found in Rob Roy Reservoir and Lake Owen are associated with oligotrophic, nutrient-poor conditions. In contrast, many of the species found in Granite Springs and Crystal Lake Reservoirs are associated with mesotrophic or eutrophic conditions. The total number of taxa identified also increased downstream. The chemical water type in the reservoirs was similar, but dissolved-solids concentrations were greater in the downstream reservoirs. Water in all four reservoirs was a calcium-bicarbonate type. In the fall of 1997, Rob Roy Reservoir had the lowest dissolved-solids concentration (19 milligrams per liter), whereas Crystal Lake Reservoir had the highest concentration (63 milligrams per liter). Relatively little differences in the concentrations of major-ion species were noted between samples collected near the surface and near the bottom of the same reservoir. In contrast, iron and manganese concentrations generally were higher in samples collected near the bottom of a reservoir than in near-surface samples collected from the same reservoir. Composite bottom-sediment samples from all four reservoirs contained similar concentrations of bulk constituents such as aluminum, iron, phosphorus and titanium, but varied in concentrations of trace elements. Trace-element concentrations in Rob Roy Reservoir and Lake Owen were similar to the crustal average, whereas in Granite Springs and Crystal Lake Reservoirs the concentrations were similar to granitic rocks.

Wyoming↗

USGS1975

Changes in concentration of certain constituents of treated waste water during movement through the Magothy Aquifer, Bay Park, New York

Approximately 7 million gallons (27 million litres) of tertiary-treated sewage (reclaimed water) was injected by well into the Magothy aquifer and was subsequently pumped out. As the reclaimed water moved through the aquifer, concentrations of certain dissolved constituents decreased as follows: Total nitrogen, 7 percent; methylene blue active substances, 49 percent; chemical oxygen demand, 50 percent; and phosphate, more than 93 percent.

New York↗