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Representation of regional urban development conditions using a watershed-based gradient study design

As part of the U.S. Geological Survey National Water-Quality Assessment Program, the effects of urbanization on stream ecosystems (EUSE) have been intensively investigated in nine metropolitan areas in the United States, including Boston, Massachusetts; Atlanta, Georgia; Birmingham, Alabama; Raleigh, North Carolina; Salt Lake City, Utah; Denver, Colorado; Dallas–Fort Worth, Texas; Portland, Oregon; and Milwaukee–Green Bay, Wisconsin. Each of the EUSE study area watersheds was associated with one ecological region of the United States. This report evaluates whether each metropolitan area can be generalized across the ecological regions (ecoregions) within which the EUSE study watersheds are located. Seven characteristics of the EUSE watersheds that affect stream ecosystems were examined to determine the similarities in the same seven characteristics of the watersheds in the entire ecoregion. Land cover (percentage developed, forest and shrubland, and herbaceous and cultivated classes), average annual temperature, average annual precipitation, average surface elevation, and average percentage slope were selected as human-influenced, climate, and topography characteristics. Three findings emerged from this comparison that have implications for the use of EUSE data in models used to predict stream ecosystem condition. One is that the predominant or "background" land-cover type (either forested or agricultural land) in each ecoregion also is the predominant land-cover type within the associated EUSE study watersheds. The second finding is that in all EUSE study areas, the watersheds account for the range of developed land conditions that exist in the corresponding ecoregion watersheds. However, six of the nine EUSE study area watersheds have significantly different distributions of developed land from the ecoregion watersheds. Finally, in seven of the nine EUSE/ecoregion comparisons, the distributions of the values of climate variables in the EUSE watersheds are different from the distributions for watersheds in the corresponding ecoregions.

Scientific Investigations Report↗

Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada-Results of a 5-year project

This report presents summary papers of work conducted between 2002 and 2007 under a 5-year project effort funded by the U.S. Geological Survey Mineral Resources Program, formerly entitled 'Tintina Metallogenic Province: Integrated Studies on Geologic Framework, Mineral Resources, and Environmental Signatures.' As the project progressed, the informal title changed from 'Tintina Metallogenic Province' project to 'Tintina Gold Province' project, the latter being more closely aligned with the terminology used by the mineral industry. As Goldfarb and others explain in the first chapter of this report, the Tintina Gold Province is a convenient term used by the mineral exploration community for a 'region of very varied geology, gold deposit types, and resource potential'. The Tintina Gold Province encompasses roughly 150,000 square kilometers, bounded by the Kaltag-Tintina fault system on the north and the Farewell-Denali fault system on the south. It extends westward in a broad arc, some 200 km wide, from northernmost British Columbia, through the Yukon, through southeastern and central Alaska, to southwestern Alaska. The climate is subarctic and, in Alaska, includes major physiographic delineations and ecoregions such as the Yukon-Tanana Upland, Tanana-Kuskokwim Lowlands, Yukon River Lowlands, and the Kuskokwim Mountains. Although the Tintina Gold Province is historically important for some of the very first placer and lode gold discoveries in northern North America, it has recently seen resurgence in mineral exploration, development, and mining activity. This resurgence is due to both new discoveries (for example, Pogo and Donlin Creek) and to the application of modern extraction methods to previously known, but economically restrictive, low-grade, bulk-tonnage gold resources (for example, Fort Knox, Clear Creek, and Scheelite Dome). In addition, the Tintina Gold Province hosts numerous other mineral deposit types, possessing both high and low sulfide content, which are not currently in development.

Alaska, Yukon↗

Linkage of the Soil and Water Assessment Tool and the Texas Water Availability Model to simulate the effects of brush management on monthly storage of Canyon Lake, south-central Texas, 1995-2010

The U.S. Geological Survey (USGS), in cooperation with the Texas State Soil and Water Conservation Board, developed and applied an approach to create a linkage between the published upper Guadalupe River Soil Water Assessment Tool (SWAT) brush-management (ashe juniper [ Juniperus ashei ]) model and the full authorization version Guadalupe River Water Availability Model (WAM). The SWAT model was published by the USGS, and the Guadalupe River WAM is available from the Texas Commission on Environmental Quality. The upper Guadalupe River watershed is a substantial component of the Guadalupe River WAM. This report serves in part as documentation of a proof of concept on the feasibility of linking these two water-resources planning models for the purpose of simulating possible increases in water storage in Canyon Lake as a result of different brush-management scenarios. The SWAT-WAM linkage for the upper Guadalupe River is documented with a principal objective to evaluate the distributional characteristics of the monthly water storage of Canyon Lake during selected drought conditions. Focus is on the relative evaluation of select scenarios of large-scale or “extensive” brush management within the upper Guadalupe River watershed. There are six SWAT simulations for the upper Guadalupe River watershed that include a baseline (0-percent management of treatable ashe juniper, the baseline scenario from a previous study in which no percentage of ashe juniper is numerically replaced with grassland) along with five scenarios (extensions of SWAT simulations from a previous study) of 20-, 40-, 60-, 80-, and 100-percent random (numerical) replacement of treatable ashe juniper with grasslands throughout the upper Guadalupe River watershed in south-central Texas. SWAT is a process-based, semidistributed, water-balance model designed to predict the effects of landscape management decisions on water yields. A watershed is subdivided into subbasins, and each subbasin is associated with a single reach on the stream network. In general a WAM, such as the Guadalupe River WAM, provides analysis of generalized water rights in a river and reservoir framework. A WAM accommodates hydrology and water usage through several input files containing water rights, watershed parameters, and naturalized streamflow time series. A WAM is generalized for application to rivers and reservoir systems, and input datasets are uniquely developed for a river basin of concern. The extractions of SWAT output for the five extensive brush-management and baseline scenarios were offset by –21 years and, in general, the results were then mapped to the WAM input-flow file. The offset of –21 years was chosen arbitrarily for technical reasons and means that the period of monthly record 1995–2010 of the upper Guadalupe River SWAT became the synthetic period of monthly record 1974–89, hereinafter 1974–89 (synthetic) period, of the Guadalupe River WAM. The relative (between scenario to baseline) effects of extensive brush-management scenarios by using the SWAT-WAM linkage were evaluated, and two critical intermediate results were total inflow to Canyon Lake from 1995 to 2010 and the monthly storage of Canyon Lake from 1974 to 1989 (synthetic). The first quartile or lower 25th percentile of monthly storage of Canyon Lake for the baseline scenario is 381,000 acre-feet (acre-ft) for the hereinafter 1974–89 (synthetic) period. This lower quartile was chosen for analysis for two critical purposes. First, Canyon Lake is managed with a conservation pool of about 386,200 acre-ft capacity (as recognized by the WAM) and is at or near conservation capacity about 50 percent or more of the time; further, there is intrinsic data censoring that occurs for the monthly storage distribution because Canyon Lake is at or near conservation pool elevation the majority of the time. This intrinsic censoring has the effect of creating a bounded distribution with a left or low-volume tail. Statistical assessment of the brush-management scenarios beginning with the 381,000 acre-ft censoring threshold provides readily interpretable results. Second, the quantification of brush management during periods lacking abundant rainfall, which were defined in this study as months for which Canyon Lake storage was below the 25th percentile for the simulation period, are of substantial interest to water-resource managers and stakeholders in the context of water-supply enhancement. A statistical assessment of the SWAT-WAM linkage for the low-volume tail of the distribution of monthly storage of Canyon Lake is the focus of analysis and interpretation. Drought periods for the analysis are defined as the months (consecutive or not) during which Canyon Lake is below the 25th percentile of storage (381,000 acre-ft) for the baseline scenario. Such months are referred to as being within the “Drought Quartile.” The Drought Quartile is a conceptual and heuristically determined waypoint for the analysis and is not related to any administrative definition of drought by stakeholders or policy makers. The five scenarios and the baseline scenario simulated in the upper Guadalupe River SWAT were all passed through the Guadalupe River WAM by the SWAT-WAM linkage described in this report. A comparison of the mean increase per month in reservoir storage for Canyon Lake conditioned for the Drought Quartile was made. For each of the five brush-management and baseline scenarios, the months with storage below 381,000 acre-ft were extracted. The mean monthly storages during the Drought Quartile were computed for each of the five scenarios and the baseline scenario. The mean of the baseline scenario was 376,458 acre-ft and subsequently was subtracted from the mean monthly storage during the Drought Quartile for each of the five scenarios. The mean monthly offset storages of Canyon Lake during the Drought Quartile were 110 acre-ft (20 percent); 448 acre-ft (40 percent); 754 acre-ft (60 percent); 1,080 acre-ft (80 percent); and 1,090 acre-ft (100 percent). A particular mean was interpreted as follows: the value of 754 acre-ft for the 60-percent brush-management scenario implies that, on average, this scenario indicates an additional 754 acre-ft per month of storage in Canyon Lake relative to the baseline during the Drought Quartile. All of the five scenarios resulted in an increase on average to water supply relative to the baseline scenario during the Drought Quartile through the SWAT-WAM linkage.

Texas↗

Investigation of pier scour in coarse-bed streams in Montana, 2001 through 2007

A primary goal of ongoing field research of bridge scour is improvement of scour-prediction equations so that pier-scour depth is predicted accurately-an important element of hydraulic analysis and design of highway bridges that cross streams, rivers, and other waterways. Scour depth for piers in streambeds with a mixture of sand, gravel, cobbles, and boulders (coarse-bed streams, which are common in Montana) generally is less than the scour depth in finer-grained (sandy) streambeds under similar conditions. That difference is attributed to an armor layer of coarser material. Pier-scour data from the U.S. Geological Survey were used in this study to develop a bed-material correction factor, which was incorporated into the Federal Highway Administration's recommended equation for computing pier scour. This report describes results of a study of pier scour in coarse-bed streams at 59 bridge sites during 2001-2007 in the mountain and foothill regions of western Montana. Respective drainage areas ranged from about 3 square miles (mi 2 ) to almost 20,000 mi 2 . Data collected and analyzed for this study included 103 pier-scour measurements; the report further describes data collection, shows expansion of the national coarse pier-scour database, discusses use of the new data in evaluation of relative accuracy of various predictive equations, and demonstrates how differences in size and gradation between surface bed material and shallow-subsurface bed material might relate to pier scour. Nearly all measurements were made under clear-water conditions with no incoming sediment supply to the bridge opening. Half of the measurements showed approach velocities that equaled or surpassed the critical velocity for incipient motion of bed material, possibly indicating that measurements were made very near the threshold between clear-water and live-bed scour, where maximum scour was shown in laboratory studies. Data collected in this study were compared to selected pier-scour data from the nationwide Bridge Scour Data Management System (BSDMS), to show the effect of bed-material size and gradation on scour depth. Unsteady field flow conditions and armoring by coarser material reduced scour relative to the clear-water/sandy-bed laboratory results at steady flow. The new correction factor and the standard scour equation produced the most accurate estimates of scour depth in armored, coarse-bed conditions. Maximum relative scour occurred at similar velocity across variations in bed material and gradation. Pier scour decreased with increased variation in particle size and gradation.

Montana↗

The 2014 annual report for the Hawaiian Volcano Observatory

Introduction This report summarizes team activities and findings of the Hawaiian Volcano Observatory during the year 2014 in geology, geodesy, seismicity, and gas geochemistry. The eruption of Pu‘u ‘Ō‘ō continued into its 32nd year with flows active to the northeast of the vent. One of them, the June 27th lava flow, named for the date in 2014 that the flow started, advanced far and fast enough to threaten the town of Pāhoa and Highway 130 in the Puna District of the Island of Hawai‘i. In response, the alert level for Kīlauea was elevated from WATCH to WARNING on September 4, followed by the declaration of a State Disaster on September 5 and a National Disaster on November 3. During 2014, renewed inflation and increased seismicity was detected beneath the summit and upper west flank of Mauna Loa. Although above background, the frequency and magnitude of the earthquakes remained at such low levels that, by year’s end, the four-tier alert level code for Mauna Loa remained at its lowest level—NORMAL. These changes were discussed in several Volcano Watch articles. Hualālai, Haleakalā, Mauna Kea, and Lo‘īhi showed no signs of unrest during the year.

Scientific Investigations Report↗

Spatiotemporal variations in copper, arsenic, cadmium, and zinc concentrations in surface water, fine-grained bed sediment, and aquatic macroinvertebrates in the upper Clark Fork Basin, western Montana—A 20-year synthesis, 1996–2016

The legacy of mining-related contamination in the upper Clark Fork Basin created an extensive longitudinal gradient in metal concentrations, extending from Silver Bow Creek to Lake Pend Oreille, Idaho. Downstream metal concentrations continue to decline, but, despite such improvements, the ecological health of much of the river remains uncertain. Understanding the long-term consequences of the Clark Fork River mining legacy may be supported by environmental monitoring techniques that include a holistic assessment of biological health or response to define organism exposure to complex contaminant mixtures and the consequences of such exposures. This report presents the spatiotemporal patterns of mining-related contaminants, copper, arsenic, cadmium, and zinc, in surface water, fine-grained bed sediment, and macroinvertebrate (aquatic insect) tissue in the upper Clark Fork from near Butte to Missoula, Montana. Overall, the patterns in water column sample concentrations observed in this study were consistent with previously observed trends, but bed sediment concentrations and concentrations of copper and arsenic varied more in tissue samples among sites. Trace element concentrations, especially copper, often exceeded the chronic aquatic life criteria and consistently exceeded the sediment probable effects level PEL for copper, particularly in the upper and middle river segments. The 20 years considered here were the wettest period since remediation started, and this increase in precipitation may have affected patterns in contaminant concentrations. Results of this study demonstrated the utility of a continued, comprehensive biomonitoring program to help guide and evaluate future environmental cleanup activities in the Clark Fork. Despite variation in defining complete restoration in these watersheds, using multiple lines of evidence in this study provided quantifiable measures of the timing and completeness of recovery relative to reference conditions. Successful recovery in the Clark Fork may benefit from an adaptive management strategy to continue collecting a comprehensive, multivariate dataset to evaluate whether established goals are being met and for subsequent adjustments and management, as needed.

Montana↗

Changing patterns in the use, recycling, and material substitution of mercury in the United States

Environmental concerns have led to numerous regulations that have dramatically decreased the reported production and use of mercury in the United States since the 1980s. Government legislation and subsequent industry actions have led to increased collection of mercury-containing materials and the recovery of mercury through recycling. Mercury emissions have been reduced and effective alternatives to mercury products have been developed for many applications. This study updates and quantifies the changes in demand, supply, use, and material flow for mercury in various sectors in the United States that have taken place since 1996. Nearly all primary mercury produced in the United States is derived as a byproduct of processing of gold and silver ore in Nevada. Since 2001, annual production of mercury from gold and silver mining in Nevada has decreased by 22 percent overall because ore from greater depths containing low grade mercury is recovered, and mercury emissions from this source have decreased by 95 percent as a result of increased regulation and improved collection and suppression technology. The distribution of consumption of mercury in the United States has changed as a result of regulation (elimination of large-scale mercury use in the paint and battery sectors), reduction by consumers (decommissioning of mercury-cell chloralkali manufacturing capacity), and technological advances (improvements in dental, lighting, and wiring sectors). Mercury use in the chloralkali sector, the leading end-use sector in the United States in 1996, has declined by 98 percent from 136 metric tons (t) in 1996 to about 0.3 t in 2010 because of increased processing and recycling efficiencies and plant closures or conversion to other technologies. As plants were closed, mercury recovered from the infrastructure of decommissioned plants has been exported, making the United States a net exporter of mercury, even though no mercury has been produced as the primary product from mines in the United States since 1992. In 1996, the three leading end-use sectors for mercury in the United States were chloralkali manufacturing (accounting for 38 percent of consumption), electrical and electronic instrumentation (13 percent of consumption), and instruments and measuring devices (11 percent of consumption). In 2010, the three leading end-use sectors were dental amalgam (accounting for between 35 and 57 percent of consumption), electrical and electronic instrumentation (29 percent of consumption), and batteries (8 percent of consumption). Mercury use in lighting is increasing because incandescent lights are being phased out in favor of mercury-containing compact fluorescent bulbs, but the demand for mercury per unit produced is small. Dental amalgam constituted the largest amount of mercury in use in the United States. One study reported about 290 t of mercury in dental amalgam was estimated to be contained in human mouths, an estimated 30 t of mercury amalgam was treated as waste, 28.5 t of mercury amalgam was released to the environment, 6 t of amalgam was recycled, and 3.5 t was treated and stored in landfills in 2009. Mercury contained in products recovered by State, municipal, or industry collection activities is recycled, but the estimated overall recycling rate is less than 10 percent. Increasingly, the U.S. mercury recycling industry has been processing a significant amount of mercury-containing material derived from foreign gold mining operations or decommissioned mercury-cell chloralkali plants. Regulation of mercury export and storage is expected to result in surplus mercury inventories in the United States. The Mercury Export Ban Act of 2008 limits elemental mercury exports for unregulated uses such as artisanal gold mining after January 1, 2013, and requires development of adequate long-term storage facilities in the United States for elemental mercury. During the past 4 years, producers and recyclers of elemental mercury have been exporting large quantities of mercury in anticipation of this regulation, but the U.S. inventory of mercury in 2010 was estimated to have exceeded 7,000 t from Government stockpiles and industry stocks. Costs attributed to long-term storage may affect the competitiveness of mercury recycling.

Scientific Investigations Report↗

Factors affecting uncertainty of public supply, self-supplied domestic, irrigation, and thermoelectric water-use data, 1985–2015—Evaluation of information sources, estimation methods, and data variability

The U.S. Geological Survey (USGS) Water-Use Program is responsible for compiling and disseminating the Nation's water-use data. Working in cooperation with local, State, and Federal agencies, the USGS has collected and published national water-use estimates every 5 years, beginning in 1950. These water-use data may vary because of actual changes in water use, because of changes in estimation methods, or because of errors. Comparison and interpretation of these data is difficult without first determining the factors that contribute to data variability. This report describes factors that may affect data quality and documents ways to investigate the variability of public supply, self-supplied domestic, irrigation, and thermoelectric water-use data for the 1985–2015 compilations. The USGS produces national water-use estimates for various categories of water use for every county in the United States. Knowledge about the sources of data for county estimates is important because factors such as estimation methodology and reporting affect data uncertainty Determination of meaningful patterns and trends in the data are contingent on the use of consistent methodology throughout the period of interest. With the many ways that water-use data have been collected, assembled, and estimated, multiple factors likely contribute to data uncertainty, Data used to produce these estimates may be furnished from agencies that collect information from entities who report water use; gaps in reported data are typically estimated to achieve a comprehensive county estimate. For example, public supply and thermoelectric category data are based primarily on furnished site-specific data; whereas crop irrigation is often furnished or estimated at the county scale. Public supply deliveries for domestic use and self-supplied domestic withdrawals are most often estimated by USGS personnel using per capita use rate coefficients. Irrigation may be estimated using crop water requirements, application rates, or other soil water balance methods when furnished reported data are not available. Rates, percentages, medians, and interquartile ranges were used to investigate variability in the water-use data among States, regions, and years. The purposes of these evaluations were to (1) identify extreme values that may reflect changes in information sources, estimation methods, or errors; (2) indicate areas of variable or consistent values that are unexpected; and (3) indicate areas where values change because of local climate or other factors. Where factors are identified that contribute to data variability, such as a change in methodology, additional work could determine uncertainty because of these factors. These evaluations identified the availability of information that is needed to address data limitations. Factors such as estimation methodology affect data quality. Some updates to method codes assigned in 2015 and assignment of method codes to earlier compilation datasets for all categories would provide much needed metadata for users of the data. Improvements in data documentation describing sources of information and estimation methods and additional metadata information from agencies and entities that furnish water-use data, would enable a more complete understanding and depiction of water-use patterns and trends. Additional metadata are needed for users of the data to better understand the water-use data and interpret changes in water use across the United States and with time.

Scientific Investigations Report↗

Occurrence and trends in the concentrations of fecal-indicator bacteria and the relation to field water-quality parameters in the Allegheny, Monongahela, and Ohio Rivers and selected tributaries, Allegheny County, Pennsylvania, 2001–09

The U.S. Geological Survey (USGS), in cooperation with the Allegheny County Health Department and Allegheny County Sanitary Authority, collected surface-water samples from the Allegheny, Monongahela, and Ohio Rivers and selected tributaries during the period 2001–09 to assess the occurrence and trends in the concentrations of fecal-indicator bacteria during both wet- and dry-weather conditions. A total of 1,742 water samples were collected at 52 main-stem and tributary sites. Quantifiable concentrations of Escherichia coli ( E. coli ) were reported in 1,667 samples, or 97.0 percent of 1,719 samples; concentrations in 853 samples (49.6 percent) exceeded the U.S. Environmental Protection Agency (EPA) recreational water-quality criterion of 235 colonies per 100 milliliters (col/100 mL). Quantifiable concentrations of fecal coliform (FC) bacteria were reported in 1,693 samples, or 98.8 percent of 1,713 samples; concentrations in 780 samples (45.5 percent) exceeded the Commonwealth of Pennsylvania water contact criterion of 400 col/100 mL. Quantifiable concentrations of enterococci bacteria were reported in 912 samples, or 87.5 percent of 1,042 samples; concentrations in 483 samples (46.4 percent) exceeded the EPA recreational water-quality criterion of 61 col/100 mL. The median percentage of samples in which bacteria concentrations exceeded recreational water-quality standards across all sites with five or more samples was 48 for E. coli , 43 for FC, and 75 for enterococci. E. coli , FC, and enterococci concentrations at main-stem sites had significant positive correlations with streamflow under all weather conditions, with rho values ranging from 0.203 to 0.598. Seasonal Kendall and logistic regression were evaluated to determine whether statistically significant trends were present during the period 2001–09. In general, Seasonal Kendall tests for trends in E. coli and FC bacteria were inconclusive. Results of logistic regression showed no significant trends in dry-weather exceedance of the standards; however, significant decreases in the likelihood that wet-weather E. coli and FC bacteria concentrations will exceed EPA recreational standards were found at the USGS streamgaging station Allegheny River at 9th Street Bridge. Nonparametric correlation analysis, including Spearman’s rho and the paired Prentice-Wilcoxon test, was used to screen for associations among fecal indicator bacteria concentrations and the field characteristics streamflow, water temperature, pH, specific conductance, dissolved-oxygen concentration, and turbidity.

Pennsylvania↗

Radiochemical sampling and analysis of shallow ground water and sediment at the BOMARC Missile Facility, east-central New Jersey, 1999-2000

A field sampling experiment was designed using low-flow purging with a portable pump and sample-collection equipment for the collection of water and sediment samples from observation wells screened in the Kirkwood-Cohansey aquifer system to determine radionuclide or trace-element concentrations for various size fractions. Selected chemical and physical characteristics were determined for water samples from observation wells that had not been purged for years. The sampling was designed to define any particulate, colloidal, and solution-phase associations of radionuclides or trace elements in ground water by means of filtration and ultrafiltration techniques. Turbidity was monitored and allowed to stabilize before samples were collected by means of the low-flow purging technique rather than by the traditional method of purging a fixed volume of water at high-flow rates from the observation well. A minimum of four water samples was collected from each observation well. The samples of water from each well were collected in the following sequence. (1) A raw unfiltered sample was collected within the first minutes of pumping. (2) A raw unfiltered sample was collected after at least three casing volumes of water were removed and turbidity stabilized. (3) A sample was collected after the water was filtered with a 0.45-micron filter. (4) A sample was collected after the water passed through a 0.45-micron filter and a 0.003-micron tangential-flow ultrafilter in sequence. In some cases, a fifth sample was collected after the water passed through a 0.45-micron filter and a 0.05-micron filter in sequence to test for colloids of 0.003 microns to 0.05 microns in size. The samples were analyzed for the concentration of manmade radionuclides plutonium-238 and -239 plus -240, and americium-241. The samples also were analyzed for concentrations of uranium-234, -235, and -238 to determine whether uranium-234 isotope enrichment (resulting from industrial processing) is present. A subset of samples was analyzed for concentrations of thorium-232, -230, and -228 to determine if thorium-228 isotope enrichment, also likely to result from industrial processing, is present. Concentrations of plutonium isotopes and americium-241 in the water samples were less than 0.1 picocurie per liter, the laboratory reporting level for these manmade radionuclides, with the exception of one americium-241 concentration from a filtered sample. A sequential split sample from the same well did not contain a detectable concentration of americium-241, however. Other filtered and unfiltered samples of water from the same well did not contain quantities of americium-241 nearly as high as 0.1 pCi/L. Therefore, the presence of americium-241 in a quantifiable concentration in water samples from this well could not be confirmed. Neither plutonium nor americium was detected in samples of settled sediment collected from the bottom of the wells. Concentrations of uranium isotopes (maximum of 0.05 and 0.08 picocuries per liter of uranium-238 and uranium-234, respectively) were measurable in unfiltered samples of turbid water from one well and in the settled bottom sediment from 6 wells (maximum concentrations of 0.25 and 0.20 picocuries per gram of uranium-238 and uranium-234, respectively). The uranium-234/uranium-238 isotopic ratio was near 1:1, which indicates natural uranium. The analytical results, therefore, indicate that no manmade radionuclide contamination is present in any of the well-bottom sediments, or unfiltered or filtered water samples from any of the sampled wells. No evidence of manmade radionuclide contamination was observed in the aquifer as settled or suspended particulates, colloids, or in the dissolved phase.

New Jersey↗

Three-Dimensional Geologic Model of Complex Fault Structures in the Upper Seco Creek Area, Medina and Uvalde Counties, South-Central Texas

This multimedia report shows and describes digital three-dimensional faulted geologic surfaces and volumes of the lithologic units of the Edwards aquifer in the upper Seco Creek area of Medina and Uvalde Counties in south-central Texas. This geologic framework model was produced using (1) geologic maps and interpretations of depositional environments and paleogeography; (2) lithologic descriptions, interpretations, and geophysical logs from 31 drill holes; (3) rock core and detailed lithologic descriptions from one drill hole; (4) helicopter electromagnetic geophysical data; and (5) known major and minor faults in the study area. These faults were used because of their individual and collective effects on the continuity of the aquifer-forming units in the Edwards Group. Data and information were compared and validated with each other and reflect the complex relationships of structures in the Seco Creek area of the Balcones fault zone. This geologic framework model can be used as a tool to visually explore and study geologic structures within the Seco Creek area of the Balcones fault zone and to show the connectivity of hydrologic units of high and low permeability between and across faults. The software can be used to display other data and information, such as drill-hole data, on this geologic framework model in three-dimensional space.

Scientific Investigations Report↗

Acute and chronic sensitivity of white sturgeon ( Acipenser transmontanus ) and rainbow trout ( Oncorhynchus mykiss ) to cadmium, copper, lead, or zinc in laboratory water-only exposures

White sturgeon (Acipenser transmontanus) are experiencing poor recruitment in the trans boundary reach of the upper Columbia River in eastern Washington State. Limited toxicity data indicated that early life stages of white sturgeon are sensitive to metals. In acute 4-day (d) exposures with larval white sturgeon, previous studies have reported that the 4-day median lethal concentrations (LC50) based on biotic ligand model (BLM) normalization for copper were below the U.S. Environmental Protection Agency national recommended acute water-quality criterion. In previously published chronic 66-d exposures starting with newly fertilized eggs of white sturgeon, 20-percent lethal effect concentrations (LC20s) for copper, cadmium, or zinc generally were within a factor of two of the chronic values of the most sensitive fish species in the databases of the U.S. Environmental Protection Agency water-quality criteria (WQC) for the three metals. However, there were some uncertainties in the chronic exposures previously performed with white sturgeon, including (1) low control survival (37 percent), (2) more control fish tested in each replicate compared to other treatments, (3) limited replication of treatments (n=2), (4) lack of reported growth data (such as dry weight), and (5) wide dilution factors for exposure concentrations (6- to 8-fold dilutions). The U.S. Environmental Protection Agency concluded that additional studies are needed to generate more toxicity data to better define lethal and sublethal toxicity thresholds for metals for white sturgeon. The objective of the study was to further evaluate the acute and chronic toxicity of cadmium, copper, lead, or zinc to early life stages of white sturgeon in water-only exposures. Toxicity tests also were performed with commonly tested rainbow trout (Oncorhynchus mykiss) under similar test conditions to determine the relative sensitivity between white sturgeon and rainbow trout to these metals. Toxicity data generated from this study were used to evaluate the sensitivity of early life stages of white sturgeon and rainbow trout relative to data published for other test organisms. Toxicity data generated from this study also were used to evaluate the level of protection of U.S. Environmental Protection Agency WQC or Washington State water-quality standards (WQS) for copper, zinc, cadmium, or lead to white sturgeon inhabiting the upper Columbia River. Chapter A of this report summarizes the results of acute toxicity tests performed for 4 d with white sturgeon and rainbow trout exposed to copper, cadmium, or zinc. Chapter B of this report summarizes the results of chronic toxicity tests performed for as many as 53 days with white sturgeon or rainbow trout exposed to copper, cadmium, zinc, or lead. Appendixes to the report are available at http://pubs.usgs.gov/sir/2013/5204 . Supporting documentation for chapter A toxicity testing is provided in appendix 1. Supporting documentation for chapter B toxicity testing is provided in Appendix 2. Supporting documentation on analysis of water chemistry for chapter A and chapter B is provided in appendix 3 and 4. The rationale for applying corrections to measured copper and zinc values in water samples from some of the toxicity tests performed in chapter A is provided in appendix 5. A summary of dissolved organic carbon measurement variability and implications for biotic ligand model normalization for toxicity data summarized in chapter A and chapter B are provided in appendix 6. An evaluation of an interlaboratory comparison of analyses for dissolved organic carbon in water from the U.S. Geological Survey Columbia Environmental Research Center and University of Saskatchewan is provided in appendix 7. Finally, appendix 8 provides a summary of retesting of white sturgeon in 2012 to determine if improved survival of sturgeon would affect copper effect concentrations in 24-d copper exposures started with newly hatched larvae, and to evaluate the effect of light intensity or temperature on the response of newly hatched larvae during a 25-d study.

Scientific Investigations Report↗

External quality-assurance project report for the National Atmospheric Deposition Program’s National Trends Network and Mercury Deposition Network, 2019–20

The U.S. Geological Survey Precipitation Chemistry Quality Assurance project (PCQA) operated four distinct programs to provide external quality-assurance monitoring for the National Atmospheric Deposition Program’s (NADP) National Trends Network (NTN) and Mercury Deposition Network (MDN) during 2019–20. The NTN programs included (1) a field audit program to evaluate sample contamination and stability, and (2) an interlaboratory comparison program to evaluate analytical laboratory performance. The MDN programs included the (3) system blank program to evaluate sample contamination and stability, and (4) an interlaboratory comparison program. The results indicated increased levels of sample contamination compared to previous years for NTN samples and decreased contamination in MDN samples. Strong analytical laboratory performance with low overall variability and bias in concentration data were indicated for the NTN’s Central Analytical Laboratory. A positive bias in the hydrogen ion concentrations in NTN samples during 2019 was eliminated by correction of a pH calibration protocol during 2020. The MDN’s Mercury Analytical Laboratory performance declined in 2020 compared to 2019 as indicated by increased variability in analytical results and a negative bias of approximately -1 nanogram per liter in the concentrations of total mercury. Slight perturbations in contamination levels in NTN samples and in analytical performance for MDN are considered small. The PCQA results indicate that NADP data continue to be of sufficient quality for applications in independent research and NADP data products, including spatial interpolations and time trends for chemical constituents in wet deposition. Small shifts in data quality indicated by the 2019–20 PCQA results are intended to be used for interpretation of the NADP data products.

Scientific Investigations Report↗

Hydrogeologic framework of the Big Lost River Basin, south-central Idaho, chap. A of Zinsser, L.M., ed., Characterization of water resources in the Big Lost River Basin, south-central Idaho

Surface-water and groundwater resources in the Big Lost River Basin of south-central Idaho are extensively interconnected; this interchange affects and is affected by water-resource management for irrigated agriculture and other uses in the basin. Concerns from water users regarding declining groundwater levels, declining streamflows, and drought helped motivate an updated evaluation of water resources in the Big Lost River Basin. The hydrogeologic framework presented in this report provides a conceptual basis for understanding groundwater resources in the Big Lost River Basin and comprises three major parts: (1) conceptual description of four hydrogeologic units, (2) development of a three-dimensional hydrogeologic framework model representing the spatial distribution of the hydrogeologic units, and (3) a description of groundwater occurrence and movement. This hydrogeologic framework represents the first of three planned reports describing water resources in the Big Lost River Basin; subsequent reports are intended to present a groundwater budget for the basin and to describe the results of a series of events measuring gains to and losses from streamflow in the Big Lost River. This report was prepared by the U.S. Geological Survey in cooperation with the Idaho Department of Water Resources. The Big Lost River Basin has four hydrogeologic units. First, the Quaternary unconsolidated sediments unit comprises the basin-fill alluvial aquifer and generally is used within 250 feet of the land surface. The Quaternary unconsolidated sediments unit is spatially heterogeneous, with locally confining conditions in some areas, and is the most heavily used hydrogeologic unit in the basin. Second, the Paleozoic sedimentary rocks unit, composed primarily of carbonates with some siliciclastic rocks, represents the major bedrock aquifer and contributes subsurface recharge at the margins of the alluvial aquifer. Third, the Tertiary volcanic rocks unit, composed primarily of andesite and dacite with lesser tuff, is locally important to water production, particularly in faulted and fractured zones. The Paleozoic sedimentary rocks hydrogeologic unit occurs at the valley margins and underlies tributaries throughout the basin, whereas the Tertiary volcanic rocks hydrogeologic unit primarily occurs in uplands in the western one-half of the basin. Fourth, the Quaternary basalt rocks unit consists of multiple basalt flows that are interbedded with the Quaternary unconsolidated sediments unit in the southern end of the Big Lost River Basin and contains at least three water-bearing zones. Insights gained from this updated hydrogeologic framework will help inform current water-resource management in the Big Lost River Basin.

Idaho↗

Production of a national 1:1,000,000-scale hydrography dataset for the United States: feature selection, simplification, and refinement

During 2006-09, the U.S. Geological Survey, in cooperation with the National Atlas of the United States, produced a 1:1,000,000-scale (1:1M) hydrography dataset comprising streams and waterbodies for the entire United States, including Puerto Rico and the U.S. Virgin Islands, for inclusion in the recompiled National Atlas. This report documents the methods used to select, simplify, and refine features in the 1:100,000-scale (1:100K) (1:63,360-scale in Alaska) National Hydrography Dataset to create the national 1:1M hydrography dataset. Custom tools and semi-automated processes were created to facilitate generalization of the 1:100K National Hydrography Dataset (1:63,360-scale in Alaska) to 1:1M on the basis of existing small-scale hydrography datasets. The first step in creating the new 1:1M dataset was to address feature selection and optimal data density in the streams network. Several existing methods were evaluated. The production method that was established for selecting features for inclusion in the 1:1M dataset uses a combination of the existing attributes and network in the National Hydrography Dataset and several of the concepts from the methods evaluated. The process for creating the 1:1M waterbodies dataset required a similar approach to that used for the streams dataset. Geometric simplification of features was the next step. Stream reaches and waterbodies indicated in the feature selection process were exported as new feature classes and then simplified using a geographic information system tool. The final step was refinement of the 1:1M streams and waterbodies. Refinement was done through the use of additional geographic information system tools.

Scientific Investigations Report↗

Transient effects on groundwater chemical compositions from pumping of supply wells at the Nevada National Security Site, 1951-2008

Nuclear testing and support activities at the Nevada National Security Site have required large amounts of water for construction, public consumption, drilling, fire protection, hydraulic and nuclear testing, and dust control. To supply this demand, approximately 20,000 million gallons of water have been pumped from 23 wells completed in 19 boreholes located across the Nevada National Security Site starting as early as the 1950s. As a consequence of more or less continuous pumping from many of these wells for periods as long as 58 years, transient groundwater flow conditions have been created in the aquifers that supplied the water. To evaluate whether long-term pumping caused changes in water compositions over time, available chemical analyses of water samples from these 19 boreholes were compiled, screened, and evaluated for variability including statistically significant temporal trends that can be compared to records of groundwater pumping. Data used in this report have been extracted from a large database (Geochem08, revision 3.0, released in September 2008) containing geochemical and isotopic information created and maintained by primary contractors to the U.S. Department of Energy, National Nuclear Security Administration, Nevada Site Office. Data extracted from this source were compiled for the entire period of record, converted to uniform reporting units, and screened to eliminate analyses of poor or unknown quality, as well as clearly spurious values. The resulting data are included in accompanying spreadsheets that give values for (1) pH and specific conductance, (2) major ion concentrations, (3) trace element concentrations and environmental isotope ratios, and (4) mean, median, and variance estimates for major ion concentrations. The resulting data vary widely in quality and time-series density. An effort has been made to establish reasonable ranges of analytical uncertainty expected for each analyte and eliminate analyses that are obvious outliers. Analysis of chemical trends in this report primarily rely on specific conductance measurements and major ion concentrations, data considered to be the most accurate and reliable over the entire time span of investigation. The analysis uses parametric and non-parametric evaluations to provide a statistical basis for trend identification. Trace element and isotope data are examined for consistency, but typically are too inaccurate or infrequent to provide a reliable long term basis for trend evaluation. Groundwater withdrawal records compiled in a companion report are included graphically in this report to allow qualitative comparisons between water quality and pumping history. Data for each supply well include (1) a borehole description and summary of pumping history, (2) a description of water-quality parameters, (3) an evaluation of temporal variations of specific conductance and major ion concentrations, and (4) an examination of supporting information from trace element and isotope data. A range of responses are observed for individual supply wells that likely include the effects of both aquifer dynamics and changing borehole conditions. Data from most wells show little or no evidence for temporal variation in water-quality parameters indicating that aquifers at the Nevada National Security Site are capable of producing large volumes of compositionally uniform water over many years of pumping. A smaller number of wells show evidence of transient changes. Wells that have ceased pumping commonly show compositions that shift toward lower concentrations in subsequent bailed samples, which indicates that more dilute water entered the well over time due to either leakage of meteoric water into the well casing or more wide-spread recharge into the shallow phreatic zone. Wells that show systematic changes in water compositions during episodes of pumping commonly have multiple open intervals whose contributions to water in the well may change over time due to hydraulic conditions or well dynamics.

Nevada↗

Analysis of trends in selected streamflow statistics for the Concho River Basin, Texas, 1916-2009

The Concho River Basin is part of the upper Colorado River Basin in west-central Texas. Monotonic trends in streamflow statistics during various time intervals from 1916-2009 were analyzed to determine whether substantial changes in selected streamflow statistics have occurred within the Concho River Basin. Two types of U.S. Geological Survey streamflow data comprise the foundational data for this report: (1) daily mean discharge (daily discharge) and (2) annual instantaneous peak discharge. Trend directions are reported for the following streamflow statistics: (1) annual mean daily discharge, (2) annual 1-day minimum discharge, (3) annual 7-day minimum discharge, (4) annual maximum daily discharge, and (5) annual instantaneous peak discharge. The South Concho, Middle Concho, and North Concho Rivers drain the upper part of the Concho River Basin. The North and South Concho Rivers converge in San Angelo, Tex., to form the Concho River. The Concho River flows east from San Angelo to its confluence with the Colorado River east of Paint Rock, Tex. The trend analyses principally focused on application of the nonparametric Kendall's Tau statistical test to detect monotonic trends (dependency) in streamflow with time; in other words, Kendall's Tau is a test of temporal independence of streamflow with time. A positive Tau indicates an upward monotonic streamflow trend; conversely, a negative Tau indicates a downward monotonic streamflow trend. Hence, the trend analysis reported here is limited to direction and not magnitude of streamflow change. Six U.S. Geological Survey streamflow-gaging stations were selected for analysis. Streamflow-gaging station 08128000 South Concho River at Christoval has downward trends for annual maximum daily discharge and annual instantaneous peak discharge for the combined period 1931-95, 2002-9. Streamflow-gaging station 08128400 Middle Concho River above Tankersley has downward trends for annual maximum daily discharge and annual instantaneous peak discharge for the combined period 1962-95, 2002-9. Streamflow-gaging station 08128500 Middle Concho River near Tankersley has no significant trends in the streamflow statistics considered for the period 1931-60. Streamflow-gaging station 08134000 North Concho River near Carlsbad has downward trends for annual mean daily discharge, annual 7-day minimum daily discharge, annual maximum daily discharge, and annual instantaneous peak discharge for the period 1925-2009. Streamflow-gaging stations 08136000 Concho River at San Angelo and 08136500 Concho River at Paint Rock have downward trends for 1916-2009 for all streamflow statistics calculated, but streamflow-gaging station 08136000 Concho River at San Angelo has an upward trend for annual maximum daily discharge during 1964-2009. The downward trends detected during 1916-2009 for the Concho River at San Angelo are not unexpected because of three reservoirs impounding and profoundly regulating streamflow.

Texas↗

Water-Table Levels and Gradients, Nevada, 1947-2004

In 1999, the U.S. Environmental Protection Agency began a program to protect the quality of ground water in areas other than ground-water protection areas. These other sensitive ground water areas (OSGWA) are areas that are not currently, but could eventually be, used as a source of drinking water. The OSGWA program specifically addresses existing wells that are used for underground injection of motor-vehicle waste. To help determine whether a well is in an OSGWA, the Nevada Division of Environmental Protection needs statewide information on depth to water and the water table, which partly control the susceptibility of ground water to contamination and contaminant transport. This report describes a study that used available maps and data to create statewide maps of water-table and depth-to-water contours and surfaces, assessed temporal changes in water-table levels, and characterized water-table gradients in selected areas of Nevada. A literature search of published water-table and depth-to-water contours produced maps of varying detail and scope in 104 reports published from 1948 to 2004. Where multiple maps covered the same area, criteria were used to select the most recent, detailed maps that covered the largest area and had plotted control points. These selection criteria resulted in water-table and depth-to-water contours that are based on data collected from 1947 to 2004 being selected from 39 reports. If not already available digitally, contours and control points were digitized from selected maps, entered into a geographic information system, and combined to make a statewide map of water-table contours. Water-table surfaces were made by using inverse distance weighting to estimate the water table between contours and then gridding the estimates. Depth-to-water surfaces were made by subtracting the water-table altitude from the land-surface altitude. Water-table and depth-to-water surfaces were made for only 21 percent of Nevada because of a lack of information for 49 of 232 basins and for most consolidated-rock hydrogeologic units. Depth to water is commonly less than 50 feet beneath valley floors, 50 to 500 feet beneath alluvial fans, and more than 500 feet in some areas such as north-central and southern Nevada. In areas without water-table information, greasewood and mapped ground-water discharge areas are good indicators of depth to water less than 100 feet. The average difference between measured depth to water and depth to water estimated from surfaces was 90 feet. More recent and detailed information may be needed than that presented in this report to evaluate a specific site. Temporal changes in water-table levels were evaluated for 1,981 wells with 10 or more years between the first depth-to-water measurement and last measurement made since 1990. The greatest increases in depth to water occurred where the first measurement was less than 200 feet, where the time between first and last measurements was 40 years or less, and for wells between 100 and 600 feet deep. These characteristics describe production wells where ground water is fairly shallow in recently developing areas such as the Las Vegas and Reno metropolitan areas. In basins with little pumping, 90 percent of the changes during the past 100 years are within ?20 feet, which is about the natural variation in the water table due to changes in the climate and recharge. Gradients in unconsolidated sediments of the Great Basin are generally steep near mountain fronts, shallow beneath valley floors, and depend on variables such as the horizontal hydraulic conductivity of adjacent consolidated rocks and recharge. Gradients beneath alluvial fans and valley floors at 58 sites were correlated with selected variables to identify those variables that are statistically related. Water-table measurements at three sites were used to characterize the water table between the valley floor and consolidated rock. Water-table gradients beneath alluvial fan

Scientific Investigations Report↗