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USGS1968

Use of water by riparian vegetation, Cottonwood Wash, Arizona

The change in water use as a result of the modification of riparian vegetation was measured in Cottonwood Wash, Mohave County, Ariz. A 4.1-mile length of the stream channel was selected and divided into a 2.6-mile upper reach and a 1.5-mile lower reach. Measurements of streamflow, ground-water levels, vegetation, and meteorological phenomena in the area defined the use of water by riparian vegetation under natural hydrologic conditions. Subsequent defoliation and eradication of the vegetation in the lower reach permitted the determination of the change in water use as a result of the modification. The computed average loss of water from the lower reach before modification was 80 acre-feet per growing season, a quantity which represented about 18 percent of the average flow entering the reach in the same period. The average loss after modification of the vegetation was 42 acre-feet per growing season, a quantity which represented about 12 percent of the average flow entering the reach in the same period.

Arizona↗

USGS2017

Water-resources and land-surface deformation evaluation studies at Fort Irwin National Training Center, Mojave Desert, California

The U.S. Army Fort Irwin National Training Center (NTC), in the Mojave Desert, obtains all of its potable water supply from three groundwater basins (Irwin, Langford, and Bicycle) within the NTC boundaries (fig. 1; California Department of Water Resources, 2003). Because of increasing water demands at the NTC, the U.S. Geological Survey (USGS), in cooperation with the U.S. Army, completed several studies to evaluate water resources in the developed and undeveloped groundwater basins underlying the NTC. In all of the developed basins, groundwater withdrawals exceed natural recharge, resulting in water-level declines. However, artificial recharge of treated wastewater has had some success in offsetting water-level declines in Irwin Basin. Additionally, localized water-quality changes have occurred in some parts of Irwin Basin as a result of human activities (i.e., wastewater disposal practices, landscape irrigation, and/or leaking pipes). As part of the multi-faceted NTC-wide studies, traditional datacollection methods were used and include lithological and geophysical logging at newly drilled boreholes, hydrologic data collection (i.e. water-level, water-quality, aquifer tests, wellbore flow). Because these data cover a small portion of the 1,177 square-mile (mi2 ) NTC, regional mapping, including geologic, gravity, aeromagnetic, and InSAR, also were done. In addition, ground and airborne electromagnetic surveys were completed and analyzed to provide more detailed subsurface information on a regional, base-wide scale. The traditional and regional ground and airborne data are being analyzed and will be used to help develop preliminary hydrogeologic framework and groundwater-flow models in all basins. This report is intended to provide an overview of recent water-resources and land-surface deformation studies at the NTC.

California↗

USGS1958

History of natural flows--Kansas River

Through its Water Resources Division, the United States Geological Survey has become the major water-resources historian for the nation. The Geological Survey's collection of streamflow records in Kansas began on a very small scale in 1895 in response to some early irrigation interest, Since that time the program has grown, and we now have about 21 350 station-years of record accumulated. A station-year of record is defined as a continuous record of flow collected at a fixed point for a period of one year. Volume of data at hand, however, is not in itself an, adequate measure of its usefullness. An important element in historical streamflow data which enhances its value as a tool for the prediction of the future is the length of continuous records available in the area being studied. The records should be of sufficient length that they may be regarded as a reasonable sample of what has gone before and may be expected in the future. Table 1 gives a graphical inventory of the available streamflow records in Kansas. It shows that, in general, there is a fair coverage of stations with records of about thirty-seven years in length, This is not a long period as history goes but it does include considerable experience with floods and droughts. Although a large quantity of data on Kansas streamflow has been accumulated, hydrologists and planning engineers find that stream flow information for many areas of the State is considerably less than adequate. The problem of obtaining adequate coverage has been given careful study by the Kansas Water Resources Board in cooperation with the U. S. Geological Survey and a report entitled "Development of A Balanced Stream-Gaging Program For Kansas", has been published by the Board as Bulletin No. 4, That report presents an analysis of the existing stream-gaging program and recommendations for a program to meet the rapidly expanding needs for more comprehensive basic data. The Kansas River is formed near Junction City, Kansas, by the confluence of the Smoky Hill and Republican Rivers, From that point the river flows eastward about 175 miles to Kansas City where it empties into the Missouri River. The basic history of its natural flow can be depicted in general by the records from three gaging stations. The one at Bonner Springs, about 21 miles upstream from the mouth, may be considered as representing the total outflow from the basin; the one at Ogden, about 8 miles downstream from the confluence of the Smoky Hill and Republican Rivers, may be considered as representing the combined contribution of those streams to the Kansas River flow; and the one at Topeka, being only about 16 river miles nearer to Ogden than to Bonner Springs, may be considered as representing flows at the mid-point along the river.

Kansas↗

USGS1997

Hydrogeology and water quality of the West Valley Creek Basin, Chester County, Pennsylvania

The West Valley Creek Basin drains 20.9 square miles in the Piedmont Physiographic Province of southeastern Pennsylvania and is partly underlain by carbonate rocks that are highly productive aquifers. The basin is undergoing rapid urbanization that includes changes in land use and increases in demand for public water supply and wastewater disposal. Ground water is the sole source of supply in the basin. West Valley Creek flows southwest in a 1.5-mile-wide valley that is underlain by folded and faulted carbonate rocks and trends east-northeast, parallel to regional geologic structures. The valley is flanked by hills underlain by quartzite and gneiss to the north and by phyllite and schist to the south. Surface water and ground water flow from the hills toward the center of the valley. Ground water in the valley flows west-southwest parallel to the course of the stream. Seepage investigations identified losing reaches in the headwaters area where streams are underlain by carbonate rocks and gaining reaches downstream. Tributaries contribute about 75 percent of streamflow. The ground-water and surface-water divides do not coincide in the carbonate valley. The ground-water divide is about 0.5 miles west of the surface-water divide at the eastern edge of the carbonate valley. Underflow to the east is about 1.1 inches per year. Quarry dewatering operations at the western edge of the valley may act partly as an artificial basin boundary, preventing underflow to the west. Water budgets for 1990, a year of normal precipitation (45.8 inches), and 1991, a year of sub-normal precipitation (41.5 inches), were calculated. Streamflow was 14.61 inches in 1990 and 12.08 inches in 1991. Evapotranspiration was estimated to range from 50 to 60 percent of precipitation. Base flow was about 62 percent of streamflow in both years. Exportation by sewer systems was about 3 inches from the basin and, at times, equaled base flow during the dry autumn of 1991. Recharge was estimated to be 18.5 inches in 1990 and 13.7 inches in 1991. Ground-water quality in the basin reflects differences in lithology and has been affected by human activities. Ground water in the carbonate rocks is naturally hard, has a near neutral pH, and contains more dissolved solids and less dissolved iron, manganese, and radon-222 than ground water in the noncarbonate rocks, which is soft, with moderately acidic to acidic pH. Regional contamination by chloride and nitrate and local contamination by organic compounds and metals was detected. Natural background concentrations are estimated to be about 1 milligram per liter for nitrate as nitrogen and less than 3 milligrams per liter for chloride. Ground water in unsewered areas and agricultural areas of the basin has median concentrations of nitrate that are greater than those in ground water from other areas; septic system effluent and fertilizer are probable sources of elevated nitrate. Water samples from wells in urbanized areas contain greater concentrations of chloride than samples from wells in residential areas; road salt is the probable source of elevated chloride. Organic solvents, especially trichloroethylene, were detected in 30 percent of the wells sampled in the urbanized carbonate valley. Most of the organic solvents and some of the metals in ground water were detected near old industrial sites. Base-flow stream quality of West Valley Creek was determined at 15 sites from monthly sampling for 1 year. Differences in stream quality reflect differences in lithology, land use, and point sources in tributary subbasins and mainstem reaches. The chemical composition of base flow in the mainstem is dominated by ground-water discharge from carbonate rocks. Elevated concentrations of nitrate (greater than 3 milligrams per liter as nitrogen) in base flow were measured in a tributary draining agricultural land and in a tributary draining an unsewered residential area. Elevated concentrations of phosphate (greater than 0.5 milligrams per liter as phosphorus) were measured in a stream that receives treated sewage effluent. Discharge of water containing elevated sulfate (about 250 milligrams per liter) from quarry dewatering operations contributes to die increase in sulfate concentration (of 10 to 40 milligrams per liter) in base flow downstream from the quarry. The chloride load at all stream sites is greater than the load contributed by precipitation and mineral weathering to the basin, indicating anthropogenic sources of chloride throughout the basin. The diversity index of the benthic invertebrate community has increased since 1973 at the longterm biological monitoring site on West Valley Creek, indicating an improvement in stream quality. The improvement probably is related to controls on discharges and banning of pesticides, such as DOT, in the 1970's. Concentrations of dissolved constituents, except for chloride, determined for base flow in the autumn do not appear to have changed since 1971. Application of the seasonal Kendall test for trend indicates that concentrations of chloride in base flow have increased since 1971; this increase may be related to the increase in urbanization in the basin. The benthic community structure at the West Valley Creek site in 1991 indicates slight nutrient enrichment. Lithium was detected in ground water and surface water downgradient from two lithiumprocessing facilities. Until 1991, lithium was discharged into a losing reach of West Valley Creek, thus introducing lithium into the ground-water system. The potential for cross-contamination between the ground-water and surface-water systems is great, as demonstrated by the detection of lithium in ground water and surface water downstream and downgradient from the two lithium-processing facilities. The lithium that was discharged into the creek acts as a conservative tracer in gaining reaches of West Valley Creek, maintaining a mass balance and characteristic isotopic signature. Lithium-7/lithium-6 ratios were greater in streams that are affected by sewage and by lithium-processing discharges and in ground water downgradient from the lithium-processing facilities than natural background lithium isotopic ratios.

Pennsylvania↗

USGS2014

Hydrologic models and analysis of water availability in Cuyama Valley, California

Changes in population, agricultural development practices (including shifts to more water-intensive crops), and climate variability are placing increasingly larger demands on available water resources, particularly groundwater, in the Cuyama Valley, one of the most productive agricultural regions in Santa Barbara County. The goal of this study was to produce a model capable of being accurate at scales relevant to water management decisions that could be considered in the evaluation of the sustainable water supply. The Cuyama Valley Hydrologic Model (CUVHM) was designed to simulate the most important natural and human components of the hydrologic system, including components dependent on variations in climate, thereby providing a reliable assessment of groundwater conditions and processes that can inform water users and help to improve planning for future conditions. Model development included a revision of the conceptual model of the flow system, construction of a precipitation-runoff model using the Basin Characterization Model (BCM), and construction of an integrated hydrologic flow model with MODFLOW-One-Water Hydrologic Flow Model (MF-OWHM). The hydrologic models were calibrated to historical conditions of water and land use and, then, used to assess the use and movement of water throughout the Valley. These tools provide a means to understand the evolution of water use in the Valley, its availability, and the limits of sustainability. The conceptual model identified inflows and outflows that include the movement and use of water in both natural and anthropogenic systems. The groundwater flow system is characterized by a layered geologic sedimentary sequence that—in combination with the effects of groundwater pumping, natural recharge, and the application of irrigation water at the land surface—displays vertical hydraulic-head gradients. Overall, most of the agricultural demand for water in the Cuyama Valley in the initial part of the growing season is supplied by groundwater, which is augmented by precipitation during wet winter and spring seasons. In addition, the amount of groundwater used for irrigation varies from year to year in response to climate variation and can increase dramatically in dry years. Model simulation results, however, also indicated that irrigation may have been less efficient during wet years. Agricultural pumpage is a major component to simulated outflow that is often poorly recorded. Therefore, an integrated, coupled farm-process model is used to estimate historical pumpage for water-balance subregions that evolved with the development of groundwater in the Valley from 1949 through 2010. The integrated hydrologic model includes these water-balance subregions and delineates natural, municipal, and agricultural land use; streamflow networks; and groundwater flow systems. The redefinition of the geohydrologic framework (including the internal architecture of the sedimentary units) and incorporation of these units into the simulation of the regional groundwater flow system indicated that faults have compartmentalized the alluvial deposits into subregions, which have responded differently to regional groundwater flow, locations of recharge, and the effects of development. The Cuyama Valley comprises nine subregions grouped into three regional zones, the Main, Ventucopa Uplands, and Sierra Madre Foothills, which are fault bounded, represent different proportions of the three alluvial aquifers, and have different water quality. The CUVHM uses MF-OWHM to simulate and assess the use and movement of water, including the evolution of land use and related water-balance regions. The model is capable of being accurate at annual to interannual time frames and at subregional to valley-wide spatial scales, which allows for analysis of the groundwater hydrologic budget for the water years 1950–2010, as well as potential assessment of the sustainable use of groundwater. Simulated changes in storage over time showed that significant withdrawals from storage generally occurred not only during drought years (1976–77 and 1988–92) but also during the early stages of industrial agriculture, which was initially dominated by alfalfa production. Since the 1990s, agriculture has shifted to more water-intensive crops. Measured and simulated groundwater levels indicated substantial declines in selected subregions, mining of groundwater that is thousands to tens of thousands of years old, increased groundwater storage depletion, and land subsidence. Most of the recharge occurs in the upland regions of Ventucopa and Sierra Madre Foothills, and the largest fractions of pumpage and storage depletion occur in the Main subregion. The long-term imbalance between inflows and outflows resulted in simulated overdraft (groundwater withdrawals in excess of natural recharge) of the groundwater basin over the 61-year period of 1949–2010. Changes in storage varied considerably from year to year, depending on land use, pumpage, and climate conditions. Climatically driven factors can greatly affect inflows, outflows, and water use by more than a factor of two between wet and dry years. Although precipitation during inter-decadal wet years previously replenished the basin, the water use and storage depletion have lessened the effects of these major recharge events. Simulated and measured water-level altitudes indicated the presence of large areas where depressed water levels have resulted in large desaturated zones in the younger and Older Alluvium layers in the Main-zone subregions. The results of modeled projection of the base-case scenario 61 years into the future indicated that current supply-and-demand are unsustainable and will result in additional groundwater-level declines and related storage depletion and land subsidence. The reduced-supply and reduced-demand projections reduced groundwater storage depletion but may not allow for sustainable agriculture under current demands, agricultural practices, and land use.

California↗

USGS1978

Water-supply potential of the lower Hillsborough River, Florida, 1976

The Tampa Reservoir Dam, constructed in 1945 on the lower Hillsborough River 10 miles above the mouth, provides 12.5 miles of natural channel storage for city water supply. Flow of the lower Hillsborough River and storage in Tampa Reservoir become deficient during annual dry periods. Excluding dead storage, Tampa Reservoir capacity is 2,000 million gallons at a maximum stage of 22.5 feet above mean sea level. For 20-year, annual-minimum-flow conditions, Hillsborough River flow is exceeded when the draft rate reaches 38 million gallons per day. In any year, at full capacity, Tampa Reservoir and Hillsborough River have a 5-percent chance of failing to supply at least 66 million gallons of water per day; and a 2-percent chance of failing to supply at least 59 million gallons per day. Runoff and effluent from agricultural, industrial, and urban areas enter the stream system above Tampa Reservoir. A wide range of chemical constituents, including nutrients, metals, herbicides, and pesticides analyzed in samples taken at the reservoir, are all below the maximum acceptable limits set by the U.S. Environmental Protection Agency for raw waters used for public supply. Water color exceeds the recommended level based on aesthetic considerations. The color is successfully removed through the treatment process at the Tampa water treatment plant.

Florida↗

USGS1971

Annual compilation and analysis of hydrologic data for Calaveras Creek, San Antonio River basin, Texas 1970

The U.S. Soil Conservation Service is actively engaged in the installation of flood and soil erosion reducing measures in Texas under the authority of "The Flood Control Act of 1936 and 1944" and ''Watershed Protection and Flood Prevention Act" (Public Law 566), as amended. The Soil Conservation Service has found a total of approximately 3,500 floodwater-retarding structures to be physically and economically feasible in Texas. As of September 30, 1970, 1,439 of these structures had been built. This watershed-development program will have varying but important effects on the natural surface- and ground-water resources of river basins, especially where a large number of the floodwater-retarding structures are built. Basic hydrologic data under natural and developed conditions are needed to appraise the effects of the structures on the yield and mode of occurrence of runoff.

Texas↗

USGS1971

Annual compilation and analysis of hydrologic data for Honey Creek, Trinity River Basin, Texas, 1969

The U.S. Soil Conservation Service is actively engaged in the installation of flood and soil erosion reducing measures in Texas under the authority of ''The Flood Control Act of 1936 and 1944" and ''Watershed Protection and Flood Prevention Act" (Public Law 566), as amended. The Soil Conservation Service has found a total of approximately 3,500 floodwater-retarding structures to be physically and economically feasible in Texas. As of September 30, 1969, 1,355 of these structures had been built. This watershed-development program will have varying but important effects on the natural surface- and ground-water resources of river basins, especially where a large number of the floodwater-retarding structures are built. Basic hydrologic data under natural and developed conditions are needed to appraise the effects of the structures on the yield and mode of occurrence of runoff .

Texas↗

USGS1977

Selected water-level records for western Oklahoma, 1975-1976

A systematic program to collect water-level records in Oklahoma began in 1937. The objectives of this program are (1) to provide long-term records of water-level fluctuations in representative wells, (2) to facilitate the prediction of water-level trends and indicate future availability of ground-water supplies, and (3) to provide information for use in basic research. Water-level data in table 1 are from wells that are measured annually, prior to the irrigation season to achieve the most natural representation of the static water level. Water level measurements listed in the column under 1975 may have been made during December, 1974 or January or February, 1975. Measurements listed in the column 1976 may have been made during December 1975 or January or February 1976. Figure 1 shows the counties and number of wells therein, where data were obtained for this report. The stratigraphic nomenclature and age determinations used in this report are those accepted by the Oklahoma Geological Survey and do not necessarily agree with those at the U.S. Geological Survey. Records of water levels in Oklahoma are collected through a cooperative program by the U.S. Geological Survey and the Oklahoma Water Resources Board. The records are tabulated and published by the U.S. Geological Survey on an annual basis.

Oklahoma↗

USGS1977

Selected water-level records for western Oklahoma, 1950-1975

Open-File Report↗

USGS1978

Selected water-level records for Oklahoma, 1975-1977

A systematic program to collect water-level records in Oklahoma began in 1937. The objectives of this program are (1) to provide long-term records of water-level fluctuations in representative wells, (2) to facilitate the prediction of water-level trends and indicate future availability of ground-water supplies, and (3) to provide information for use in basic research. Water-level data in table 1 are from wells that are measured annually, prior to the irrigation season to achieve the most natural representation of the static water level. Water-level measurements listed in the column under 1976 may have been made during December, 1975 or January, February, March, April, or May, 1976. Measurements listed in the column 1977 may have been made during December, 1976 or January, February, March, or April, 1977. Figure 1 shows the counties and number of wells therein, where data were obtained for this report. Records of water levels in Oklahoma are collected through a cooperative program by the U.S. Geological Survey and the Oklahoma Water Resources Board. The records are tabulated and published by the U.S. Geological Survey on an annual basis.

Oklahoma↗

USGS1979

Selected water-level records for Oklahoma, 1976-1978

A systematic program to collect water-level records in Oklahoma began in 1937. The objectives of this program are (1) to provide long-term records of water-level fluctuations in representative wells, (2) to facilitate the prediction of water-level trends and indicate future availability of ground-water supplies, and (3) to provide information for use in basic research. Water-level data in table 1 are from wells that are measured annually, prior to the irrigation season, to achieve the most natural representation of the static water level. Water-level measurements listed in the column under 1976 may have been made during December 1975 or January, February, March, April, or May, 1976. Measurements listed in the column 1977 may have been made during December 1976 or January, February, March, or April 1977. Figure 1 shows the counties and number of wells therein, where data were obtained for this report. Records of water levels in Oklahoma are collected through a cooperative program by the U.S. Geological Survey and the Oklahoma Water Resources Board. The records are tabulated and published by the U.S. Geological Survey on an annual basis. The stratigraphic nomenclature and age determinations used in this report are those accepted by the Oklahoma Geological Survey and do not necessarily agree with those of the U.S. Geological Survey except for the Cheyenne Sandstone which is considered to be Purgatoire Sandstone by the Oklahoma Geological Survey (Robert 0. Fay, Personal Communication, August 9, 1979).

Oklahoma↗

USGS1980

Selected water-level records for Oklahoma, 1979-80

A systematic program to collect water-level records in Oklahoma began in 1937. The objectives of this program are (1) to provide long-term records of water-level fluctuations in representative wells, (2) to facilitate the prediction of water-level trends and indicate future availability of ground-water supplies, and (3) to provide information for use in basic research. Water-level data in table 1 are from wells that are measured annually, prior to the irrigation season to achieve the most natural representation of the static water level. Water level measurements listed in the column under 1979 may have been made during December 1978 or January, February, March, April, or May 1979. Measurements listed in the column 1980 may have been made during December 1979 or January, February, March, or April 1980. Figure 1 shows the counties and number of wells therein, where data were obtained for this report. Records of water levels in Oklahoma are obtained through a cooperative program by the Oklahoma Water Resources Board and the U.S. Geological Survey. The Oklahoma Water Resources Board collects water level data for all counties in the State and the records are tabulated and published by the U.S. Geological Survey on an annual basis. The stratigraphic nomenclature and age determinations used in this report are those accepted by the Oklahoma Geological Survey and do not necessarily agree with those at the U.S. Geological Survey except for the Cheyenne Sandstone which is considered to be Purgatoire Sandstone by the Oklahoma Geological Survey (Robert O. Fay, Personal Communication, August 9, 1979).

Open-File Report↗

USGS2003

Aquifer susceptibility in Virginia, 1998-2000

The U.S. Geological Survey (USGS), in cooperation with the Virginia Department of Health, sampled water from 171 wells and springs across the Commonwealth of Virginia between 1998 and 2000 as part of the Virginia Aquifer Susceptibility study. Most of the sites sampled are public water supplies that are part of the comprehensive Source Water Assessment Program for the Commonwealth. The fundamental premise of the study was that the identification of young waters (less than 50 years) by multiple environmental tracers could be used as a guide for classifying aquifers in terms of susceptibility to contamination from near-surface sources. Environmental tracers, including chlorofluorocarbons (CFCs), sulfur hexafluoride (SF6), tritium (3H), and tritium/helium-3 (3H/3He), and carbon isotopes (14C and d13C) were used to determine the age of water discharging from wells and springs. Concentrations of CFCs greater than 5 picograms per kilogram and 3H concentrations greater than 0.6 tritium unit were used as thresholds to indicate that parts of the aquifer sampled have a component of young water and are, therefore, susceptible to near-surface contamination. Concentrations of CFCs exceeded the susceptibility threshold in 22 percent of the wells and in one spring sampled in the Coastal Plain regional aquifer systems. About 74 percent of the samples from wells with the top of the first water zone less than 100 feet below land surface exceeded the threshold values, and water supplies developed in the upper 100 feet of the Coastal Plain are considered to be susceptible to contamination from near-surface sources. The maximum depth to the top of the screened interval for wells that contained CFCs was less than 150 feet. Wells completed in the deep confined aquifers in the Coastal Plain generally contain water older than 1,000 years, as indicated by carbon-14 dating, and are not considered to be susceptible to contamination under natural conditions. All of the water samples from wells and springs in the fractured-rock terrains (the Appalachian Plateaus, Valley and Ridge, Blue Ridge, and Piedmont regional aquifer systems) contained concentrations of CFCs and 3H greater than one or both of the thresholds. Because all of the water samples exceeded at least one of the threshold values, young water is present throughout most of these regional aquifer systems; therefore, water supplies developed in these systems are susceptible to contamination from near-surface sources. No relation between well depth and presence of CFCs is evident from samples in the fractured-rock terrains. More than 95 percent of the samples for which the dating methods were applicable contained waters with apparent ages less than 35 years. About 5 percent of these samples, most of which were from the Blue Ridge and Piedmont regional aquifer systems, contained young waters with apparent ages of less than 5 years. Most of the samples from the Valley and Ridge Carbonate, Blue Ridge, and Piedmont regional aquifer systems had young water fractions of more than 50 percent, whereas samples from the Coastal Plain Shallow and Appalachian Plateaus regional aquifer systems contained less than 40 percent young waters. Concentrations of CFCs in excess of air-water equilibrium, which can indicate that nonatmospheric sources (such as sewage effluent) have introduced CFCs into the ground-water system, were measured in 6 and 48 percent of the water samples from the Coastal Plain and fractured-rock regional aquifer systems, respectively. The nitrate (NO3) concentrations greater than the USGS detection level of 0.05 milligrams per liter generally increase as the apparent age of the young water fraction decreases, with the highest NO3 concentrations for samples in which one or more of the CFCs are above modern atmospheric mixing ratios (commonly referred to as 'contaminated' for ground-water dating purposes).

Virginia↗

USGS2004

Organic and inorganic species in produced water: Implications for water reuse

Currently 20-30 billion barrels of formation water are co-produced annually in the USA with conventional oil and natural gas. The large database on the geochemistry of this produced water shows salinities that vary widely from ~5,000 to >350,000 mg/L TDS. Chloride, Na and Ca are generally the dominant ions, and concentrations of Fe, Mn, B, NH3 and dissolved organics, including, BTEX, phenols and poly aromatic hydrocarbons (PAHs) may be relatively high. Hazardous concentrations of NORMs, including Ra-226 and Rn-222 have been reported in produced water from several states. Coal-bed methane (CBM) wells currently produce close to a billion barrels of water and deliver ~8% of total natural gas. The salinity of this produced water generally is lower than that of water from petroleum wells; salinity commonly is 1,000-20,000 mg/L, but ranges to150,000 mg/L TDS. Most CBM wells produce Na-HCO3-Cl type water that is low in trace metals and has no reported NORMs. This water commonly has no oil and grease and has relatively low DOC, but its organic composition has not been characterized in detail. The water is disposed of by injection into saline aquifers, through evaporation and/or percolation in disposal pits, road spreading, and surface discharge. Water that has an acceptable salinity and sodium absorption ratio (SAR) is considered acceptable for surface discharge and for injection into freshwater aquifers. As an alternative to costly disposal, low salinity produced water is being considered for reclamation, especially in the arid western USA. The cost of reclaiming this water to meet irrigation, industrial and drinking water standards was evaluated in a 10 gpm pilot field study at Placerita oil field, California. This produced water had a low salinity of ~8,000 mg/L, but high concentration of Si and organics. Removal of B, Si, NH3 and especially organics from this water proved difficult, and the estimated treatment cost was high at $0.08-$0.39/bbl for water treated for industrial and municipal uses.

Conference Paper↗

USGS2023

Environmental tracers of groundwater source, age, and geochemical evolution

Hexavalent chromium, Cr(VI), was discharged in cooling wastewater to unlined surface ponds from 1952 to 1964 and reached the underlying unconsolidated aquifer at the Pacific Gas and Electric Company (PG&E) Hinkley compressor station in the Mojave Desert, 80 miles northeast of Los Angeles, California. A suite of environmental tracers was analyzed in water samples collected from more than 100 wells to characterize the source, age, and geochemical evolution of groundwater within and near the Cr(VI) plume in Hinkley and Water Valleys. This information was used to help determine the extent of Cr(VI) associated with releases from the Hinkley compressor station and to identify Cr(VI) associated with natural sources. The source of water in most wells, indicated by stable oxygen and hydrogen isotope values for water, delta oxygen-18 and delta deuterium, was recharge by infiltration of intermittent surface flows in the Mojave River. With the exception of small flows in 1958, the Mojave River was largely dry between 1952 and 1969. This dry period spans the period of Cr(VI) releases from the Hinkley compressor station; 1952–69 also spans the period of high tritium levels in precipitation resulting from the atmospheric testing of nuclear weapons and, as a consequence, tritium concentrations in groundwater in Hinkley Valley were comparatively low. Groundwater ages (time since recharge) increased downgradient from the Mojave River and with depth. Tritium, measured by helium ingrowth with a study reporting level of 0.05 tritium unit, was detected in water from 51 percent of wells, with detectable tritium as far as 7 miles downgradient from the Mojave River. Tritium concentrations were higher, and tritium/helium-3 groundwater ages younger, in water from wells near the Mojave River and in water from shallower wells downgradient. Agricultural pumping has decreased groundwater levels as much as 60 feet since 1952. As a result of this pumping, some groundwater containing tritium, and presumably anthropogenic Cr(VI), has been removed from the aquifer. The distribution of wells having carbon-14 activities near or greater than 100-percent modern carbon, consistent with post-1952 recharge water, was similar to the distribution of wells containing detectable tritium. Carbon-14 activities as low as 8.9-percent modern carbon, with carbon-14 ages (unadjusted for reactions with aquifer materials) of almost 20,000 years before present (ybp), were sampled in water from some deep wells. Hexavalent chromium concentrations in older groundwater were as high as 11 micrograms per liter but did not exceed 3.6 micrograms per liter in older water from wells completed in “Mojave-type” deposits (composed of felsic Mojave River stream and near-shore lake deposits sourced from the Mojave River); this value may represent an upper limit on Cr(VI) concentrations in groundwater within Mojave-type deposits that likely approximates background Cr(VI) concentrations in the study area. Chlorofluorocarbons were released to the atmosphere and hydrologic cycle as a result of industrial activity beginning in the 1930s. Chlorofluorocarbon data were not generally suitable for groundwater-age dating in Hinkley and Water Valley because of nonatmospheric contributions from local sources. Strontium-87/86 isotope ratios and stable chromium isotopes, delta chromium-53, provide information on the geochemical evolution of groundwater in the aquifer. Highly radiogenic strontium-87/86 ratios greater than 0.71000 were present in water from wells completed in coarse-textured Mojave-type deposits having low chromium concentrations but were not diagnostic of these materials. Nonradiogenic strontium-87/86 ratios less than 0.70950 were diagnostic of weathered materials in the northern subarea of Hinkley and in Water Valley that were eroded from Miocene (23–5 million ybp) deposits east of the study area. Values for delta chromium-53 ranged from near 0 to 2.8 parts per thousand (‰) difference. The extent of reductive fractionation, mixing with native groundwater, and longitudinal dispersion within the October–December 2015 (Q4 2015) regulatory Cr(VI) plume can be estimated on the basis of the delta chromium-53 isotope composition of groundwater within the plume. Reduction of Cr(VI) to trivalent chromium, Cr(III), can occur in the presence of natural reductants in oxic groundwater. Although not diagnostic of anthropogenic chromium at the concentrations of interest near the Q4 2015 regulatory Cr(VI) plume margin, delta chromium-53 data indicate anthropogenic Cr(VI) within the plume is not conservative and has reacted with aquifer materials; these reactions have removed some anthropogenic Cr(VI) from groundwater. Environmental tracers, and the distribution of modern (post-1952) and premodern (pre-1952) groundwater, inform understanding of the extent of anthropogenic and naturally occurring Cr(VI) near the Q4 2015 regulatory Cr(VI) plume and the understanding of geochemical processes occurring in and near the margins of the Cr(VI) plume. The oxygen and hydrogen isotope compositions of water, tritium/helium-3 groundwater-age data, and carbon-14 data were used with mineralogy and chemistry data as part of a summative-scale analysis to determine the Cr(VI) plume extent later in this professional paper (chapter G).

California↗

USGS2019

Influence of salinity on relative density of American crocodiles (Crocodylus acutus) in Everglades National Park: Implications for restoration of Everglades ecosystems

The status of the American crocodile (Crocodylus acutus) has long been a matter of concern in Everglades National Park (ENP) due to its classification as a federal and state listed species, its recognition as a flagship species, and its function as an ecosystem indicator. Survival and recovery of American crocodiles has been linked with regional hydrological conditions, especially freshwater flow to estuaries, which affect water levels and salinities. We hypothesize that efforts to restore natural function to Everglades ecosystems by improving water delivery into estuaries within ENP will change salinities and water levels which in turn will affect relative density of crocodiles. Monitoring ecological responses of indicator species, such as crocodiles, with respect to hydrologic change is necessary to evaluate ecosystem responses to restoration projects. Our objectives were to monitor trends in crocodile relative density within ENP and to determine influences of salinity on relative density of crocodiles. We examined count data from 12 years of crocodile spotlight surveys in ENP (2004 to 2015) and used a hierarchical model of relative density that estimated relative density with probability of detection. The mean predicted value for relative density (λ) across all surveys was 2.9 individuals/km (95% CI: 2.0 – 4.2); relative density was estimated to decrease with increases in salinity. Routes in ENP’s Flamingo/Cape Sable area had greater crocodile relative density than routes in the West Lake/Cuthbert Lake area and Northeast Florida Bay areas. These results are consistent with the hypothesis that restored flow and lower salinities will result in an increase in crocodile population size and provide support for the ecosystem management recommendations for crocodiles, which currently are to restore more natural patterns of freshwater flow to Florida Bay. Thus, monitoring relative density of American crocodiles will continue to be an effective indicator of ecological response to ecosystem restoration.

Florida↗

USGS2003

Potential for saltwater intrusion into the lower Tamiami aquifer near Bonita Springs, southwestern Florida

A study was conducted to examine the potential for saltwater intrusion into the lower Tamiami aquifer beneath Bonita Springs in southwestern Florida. Field data were collected, and constant- and variable-density ground-water flow simulations were performed that: (1) spatially quantified modern and seasonal stresses, (2) identified potential mechanisms of saltwater intrusion, and (3) estimated the potential extent of saltwater intrusion for the area of concern. MODFLOW and the inverse modeling routine UCODE were used to spatially quantify modern and seasonal stresses by calibrating a constant-density ground-water flow model to field data collected in 1996. The model was calibrated by assuming hydraulic conductivity parameters were accurate and by estimating unmonitored ground-water pumpage and potential evapotranspiration with UCODE. Uncertainty in these estimated parameters was quantified with 95-percent confidence intervals. These confidence intervals indicate more uncertainty (or less reliability) in the estimates of unmonitored ground-water pumpage than estimates of pan-evaporation multipliers, because of the nature and distribution of observations used during calibration. Comparison of simulated water levels, streamflows, and net recharge with field data suggests the model is a good representation of field conditions. Potential mechanisms of saltwater intrusion into the lower Tamiami aquifer include: (1) lateral inland movement of the freshwater-saltwater interface from the southwestern coast of Florida; (2) upward leakage from deeper saline water-bearing zones through natural upwelling and upconing, both of which could occur as diffuse upward flow through semiconfining layers, conduit flow through karst features, or pipe flow through leaky artesian wells; (3) downward leakage of saltwater from surface-water channels; and (4) movement of unflushed pockets of relict seawater. Of the many potential mechanisms of saltwater intrusion, field data and variable-density ground-water flow simulations suggest that upconing is of utmost concern, and lateral encroachment is of second-most concern. This interpretation is uncertain, however, because the predominance of saltwater intrusion through leaky artesian wells with connection to deeper, more saline, and higher pressure aquifers was difficult to establish. Effective management of ground-water resources in southwestern Florida requires an understanding of the potential extent of saltwater intrusion in the lower Tamiami aquifer near Bonita Springs. Variable-density, ground-water flow simulations suggest that when saltwater is at dynamic equilibrium with 1996 seasonal stresses, the extent of saltwater intrusion is about 100 square kilometers areally and 70,000 hectare-meters volumetrically. The volumetric extent of saltwater intrusion was most sensitive to changes in recharge, ground-water pumpage, sea level, salinity of the Gulf of Mexico, and the potentiometric surface of the sandstone aquifer, respectively.

Florida↗