Hydrogeology and water quality of the West Valley Creek Basin, Chester County, Pennsylvania

Lisa A. Senior; Ronald A. Sloto; Andrew G. Reif

doi:10.3133/wri944137

Home/Archive/USGS

USGS · wri944137

Hydrogeology and water quality of the West Valley Creek Basin, Chester County, Pennsylvania

Lisa A. Senior·Ronald A. Sloto·Andrew G. Reif

View original source ↗Read source document ↗Export metadata ↓

Abstract

The West Valley Creek Basin drains 20.9 square miles in the Piedmont Physiographic Province of southeastern Pennsylvania and is partly underlain by carbonate rocks that are highly productive aquifers. The basin is undergoing rapid urbanization that includes changes in land use and increases in demand for public water supply and wastewater disposal. Ground water is the sole source of supply in the basin. West Valley Creek flows southwest in a 1.5-mile-wide valley that is underlain by folded and faulted carbonate rocks and trends east-northeast, parallel to regional geologic structures. The valley is flanked by hills underlain by quartzite and gneiss to the north and by phyllite and schist to the south. Surface water and ground water flow from the hills toward the center of the valley. Ground water in the valley flows west-southwest parallel to the course of the stream. Seepage investigations identified losing reaches in the headwaters area where streams are underlain by carbonate rocks and gaining reaches downstream. Tributaries contribute about 75 percent of streamflow. The ground-water and surface-water divides do not coincide in the carbonate valley. The ground-water divide is about 0.5 miles west of the surface-water divide at the eastern edge of the carbonate valley. Underflow to the east is about 1.1 inches per year. Quarry dewatering operations at the western edge of the valley may act partly as an artificial basin boundary, preventing underflow to the west. Water budgets for 1990, a year of normal precipitation (45.8 inches), and 1991, a year of sub-normal precipitation (41.5 inches), were calculated. Streamflow was 14.61 inches in 1990 and 12.08 inches in 1991. Evapotranspiration was estimated to range from 50 to 60 percent of precipitation. Base flow was about 62 percent of streamflow in both years. Exportation by sewer systems was about 3 inches from the basin and, at times, equaled base flow during the dry autumn of 1991. Recharge was estimated to be 18.5 inches in 1990 and 13.7 inches in 1991. Ground-water quality in the basin reflects differences in lithology and has been affected by human activities. Ground water in the carbonate rocks is naturally hard, has a near neutral pH, and contains more dissolved solids and less dissolved iron, manganese, and radon-222 than ground water in the noncarbonate rocks, which is soft, with moderately acidic to acidic pH. Regional contamination by chloride and nitrate and local contamination by organic compounds and metals was detected. Natural background concentrations are estimated to be about 1 milligram per liter for nitrate as nitrogen and less than 3 milligrams per liter for chloride. Ground water in unsewered areas and agricultural areas of the basin has median concentrations of nitrate that are greater than those in ground water from other areas; septic system effluent and fertilizer are probable sources of elevated nitrate. Water samples from wells in urbanized areas contain greater concentrations of chloride than samples from wells in residential areas; road salt is the probable source of elevated chloride. Organic solvents, especially trichloroethylene, were detected in 30 percent of the wells sampled in the urbanized carbonate valley. Most of the organic solvents and some of the metals in ground water were detected near old industrial sites. Base-flow stream quality of West Valley Creek was determined at 15 sites from monthly sampling for 1 year. Differences in stream quality reflect differences in lithology, land use, and point sources in tributary subbasins and mainstem reaches. The chemical composition of base flow in the mainstem is dominated by ground-water discharge from carbonate rocks. Elevated concentrations of nitrate (greater than 3 milligrams per liter as nitrogen) in base flow were measured in a tributary draining agricultural land and in a tributary draining an unsewered residential area. Elevated concentrations of phosphate (greater than 0.5 milligrams per liter as phosphorus) were measured in a stream that receives treated sewage effluent. Discharge of water containing elevated sulfate (about 250 milligrams per liter) from quarry dewatering operations contributes to die increase in sulfate concentration (of 10 to 40 milligrams per liter) in base flow downstream from the quarry. The chloride load at all stream sites is greater than the load contributed by precipitation and mineral weathering to the basin, indicating anthropogenic sources of chloride throughout the basin. The diversity index of the benthic invertebrate community has increased since 1973 at the longterm biological monitoring site on West Valley Creek, indicating an improvement in stream quality. The improvement probably is related to controls on discharges and banning of pesticides, such as DOT, in the 1970's. Concentrations of dissolved constituents, except for chloride, determined for base flow in the autumn do not appear to have changed since 1971. Application of the seasonal Kendall test for trend indicates that concentrations of chloride in base flow have increased since 1971; this increase may be related to the increase in urbanization in the basin. The benthic community structure at the West Valley Creek site in 1991 indicates slight nutrient enrichment. Lithium was detected in ground water and surface water downgradient from two lithiumprocessing facilities. Until 1991, lithium was discharged into a losing reach of West Valley Creek, thus introducing lithium into the ground-water system. The potential for cross-contamination between the ground-water and surface-water systems is great, as demonstrated by the detection of lithium in ground water and surface water downstream and downgradient from the two lithium-processing facilities. The lithium that was discharged into the creek acts as a conservative tracer in gaining reaches of West Valley Creek, maintaining a mass balance and characteristic isotopic signature. Lithium-7/lithium-6 ratios were greater in streams that are affected by sewage and by lithium-processing discharges and in ground water downgradient from the lithium-processing facilities than natural background lithium isotopic ratios.

Explore related subjects

Water-Resources Investigations Report Report

Source-reported bounding extent: 39.91666667° to 40.08333333° latitude; -75.70833333° to -75.54166667° longitude. This indicates report coverage, not an exact sampling location. View area on OpenStreetMap.

Keep this discovery

Explore connections, maps & timelines

BibTeX RIS

Lisa A. Senior, Ronald A. Sloto, Andrew G. Reif. 1997. Hydrogeology and water quality of the West Valley Creek Basin, Chester County, Pennsylvania. https://doi.org/10.3133/wri944137

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

USGS2026

Hydrogeology of the Tully Valley and characterization of mudboil activity, Onondaga County, New York

Mudboil activity in the Tully Valley, in central New York, is causing turbidity in nearby Onondaga Creek, where it has caused a bridge to collapse; it also has threatened or damaged other structures and has caused extensive land subsidence. Mudboil activity was intermittent from its first reported appearance in the 1890's until the 1970's, when the rates of mudboil discharge and land subsidence began to increase. Historically, the water discharged from mudboils was reported as fresh, but chemical analyses in the late 1970's indicated an increase in specific conductance and chloride concentration. Mudboil discharge is driven by artesian pressure in unconsolidated sediments that are confined by a 60-foot layer of silt and red clay. This process, once begun, has been self-propagating. Artesian pressures are about 20 feet above land surface over most of the valley floor but exceed 30 feet above land surface along Onondaga Creek where Rattlesnake Gulf and Rainbow Creek enter the Tully Valley. The source of artesian pressure is recharge from the Tully (Valley Heads) Moraine at the south end of the valley, and the alluvial fans of Rattlesnake Gulf and Rainbow Creek. The mudboils are found within a 300-foot-wide by 1,500-foot-long corridor along Onondaga Creek just upstream from the two alluvial fans, and in a 5-acre subsided area just west of that corridor. Remediation efforts have entailed (1) diversion of flow from the tributary that feeds the subsided area, (2) installation of depressurizing wells at several locations, and (3) construction of a dam and settling impoundment to detain mudboil sediment that would normally discharge to Onondaga Creek. These efforts have been partly successful, but further work is needed to slow the mudboil activity, which is expected to persist in both areas. Mudboil activity is normally greatest during the early spring and late fall, when artesian pressures increase in response to seasonal ground-water recharge. Suspended-sediment concentrations at the out-flow of the subsidence area ranged from 31,210 mg/L (milligrams per liter) in October 1991 to 17 mg/L after remediation efforts in the summer of 1993. Yearly average suspended-sediment loads to Onondaga Creek from the subsidence area for water years 1992, 1993, 1994, and 1995 were 29.8, 9.75, 1.41, and 1.80 tons per day, respectively. Sediment discharged from the mudboils initially was 30 to 60 percent clay and 80 to 100 percent silt-sized or smaller sediment, and the sand fraction never exceeded 20 percent. After the remediation projects, 50 to 80 percent was clay, and nearly all sediment was silt size or smaller. Analyses of water from upstream and downstream of the subsidence area, as well as from mudboil vents within that area, indicate that the source of water for some mudboils is a confined freshwater aquifer, whereas for others it is an underlying, brackish-water aquifer. Water from the freshwater aquifer has specific conductance values ranging from about 400 ( μS /cm (microsiemens per centimeter at 25° Celsius) to almost 900 ( μS /cm, dissolved chloride concentrations range from 37 to 430 mg/L, and dissolved-solids concentrations range from 215 to 463 mg/L. Specific conductance of water from the brackish-water aquifer ranges from 17,000 to 28,000 ( μS /cm, chloride concentrations range from 2,000 to 7,100 mg/L, and dissolved-solids concentrations range from 4,200 to 12,800 mg/L. The largest landslide in New York State in the last 75 years occurred at the foot of Bare Mountain, 1 mile downstream from the mudboil area, in April 1993 and was the fourth in a series of slides that have occurred at the base of this hill. Slope instability was reported as early as May 1990. After the slide, intermittent mudboil-like activity was observed at several springs within the backscarp of the slide; water from these springs ranged from fresh to brackish. The chemical similarity between water from some springs in the backscarp area and water in the lower (brackish) aquifer beneath the mudboil area may indicate a hydraulic connection between this aquifer and the surficial deposits. Hydrologic changes in the valley during the last 100 years have been attributed to salt-solution mining in the upstream (southern) end of the valley. The removal of nearly 150 feet of salt from four evaporite beds in the Syracuse Shale of the Salina Group has caused the collapse of bedrock and unconsolidated deposits in and near the brine field, 3 miles south of the mudboil area. These collapses have created a hydraulic connection among bedding plane aquifers in the bedrock and increased the hydraulic connection with unconsolidated aquifers. The ground-water flow system after brine field closure in 1988 may have reached a new semiequilibrium, but mudboil activity will likely continue because artesian pressures remain. Whether mudboils were present before salt solution-mining began is unknown.

New York↗

USGS2018

Evaluation of the Source and Transport of High Nitrate Concentrations in Ground Water, Warren Subbasin, California

Ground water historically has been the sole source of water supply for the Town of Yucca Valley in the Warren subbasin of the Morongo ground-water basin, California. An imbalance between ground-water recharge and pumpage caused ground-water levels in the subbasin to decline by as much as 300 feet from the late 1940s through 1994. In response, the local water district, Hi-Desert Water District, instituted an artificial recharge program in February 1995 using imported surface water to replenish the ground water. The artificial recharge program resulted in water-level recoveries of as much as 250 feet in the vicinity of the recharge ponds between February 1995 and December 2001; however, nitrate concentrations in some wells also increased from a background concentration of 10 milligrams per liter to more than the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) of 44 milligrams per liter (10 milligrams per liter as nitrogen). The objectives of this study were to: (1) evaluate the sources of the high-nitrate concentrations that occurred after the start of the artificial-recharge program, (2) develop a ground-water flow and solute-transport model to better understand the source and transport of nitrates in the aquifer system, and (3) utilize the calibrated models to evaluate the possible effect of a proposed conjunctive-use project. These objectives were accomplished by collecting water-level and water-quality data for the subbasin and assessing changes that have occurred since artificial recharge began. Collected data were used to calibrate the ground-water flow and solute-transport models. Data collected for this study indicate that the areal extent of the water-bearing deposits is much smaller (about 5.5 square miles versus 19 square miles) than that of the subbasin. These water-bearing deposits are referred to in this report as the Warren ground-water basin. Faults separate the ground-water basin into five hydrogeologic units: the west, the midwest, the mideast, the east and the northeast hydrogeologic units. Water-quality analyses indicate that septage from septic tanks is the primary source of the high-nitrate concentrations measured in the Warren ground-water basin. Water-quality and stable-isotope data, collected after the start of the artificial recharge program, indicate that mixing occurs between imported water and native ground water, with the highest recorded nitrate concentrations in the midwest and the mideast hydrogeologic units. In general, the timing of the increase in measured nitrate concentrations in the midwest hydrogeologic unit is directly related to the distance of the monitoring well from a recharge site, indicating that the increase in nitrate concentrations is related to the artificial recharge program. Nitrate-to-chloride and nitrogen-isotope data indicate that septage is the source of the measured increase in nitrate concentrations in the midwest and the mideast hydrogeologic units. Samples from four wells in the Warren ground-water basin were analyzed for caffeine and selected human pharmaceutical products; these analyses suggest that septage is reaching the water table. There are two possible conceptual models that explain how high-nitrate septage reaches the water table: (1) the continued downward migration of septage through the unsaturated zone to the water table and (2) rising water levels, a result of the artificial recharge program, entraining septage in the unsaturated zone. The observations that nitrate concentrations increase in ground-water samples from wells soon after the start of the artificial recharge program in 1995 and that the largest increase in nitrate concentrations occur in the midwest and mideast hydrogeologic units where the largest increase in water levels occur indicate the validity of the second conceptual model (rising water levels). The potential nitrate concentration resulting from a water-level rise in the midwest and mideast hydrogeologic units was estimated using a simple mixing-cell model. The estimated value is within the range of concentrations measured in samples from wells, further indicating the validity of the second conceptual model. A ground-water flow model and a solute-transport model were developed for the Warren ground-water basin for the period 1956-2001. MODFLOW-96 was used for the ground-water flow model and MOC3D was used for the solute-transport model. The model cell size is about 500 feet by 500 feet and the models were discretized vertically into three layers. The models were calibrated using a trial-and-error approach using water-level and nitrate-concentration data collected between 1956-2001. In order to better match the measured data, low fault hydraulic characteristic values were required, thereby compartmentalizing the ground-water basin. In addition, it was necessary to parameterize the specific yield distribution for the top model layer where unconfined ground-water conditions occur into three homogeneous zones. Separate sets of specific- yield values were needed to simulate the drawdown and subsequent water-level recovery. In addition, the calibrated natural recharge was about 83 acre-feet per year. The entrainment of unsaturated-zone septage was simulated as recharge having an associated nitrate concentration. The volume of recharge was a function of the measured water-level rise between 1994-98 and the moisture content of the unsaturated zone. The nitrate concentration of the recharge water was a weighted function of the assumed nitrate concentration in the infiltrating water associated with the overlying land use. The simulated hydraulic head and nitrate concentration results were in good agreement with the measured data indicating that the mechanism for the increase in nitrate concentrations was rising water levels entraining high-nitrate septage in the unsaturated-zone. The calibrated models were used to simulate the possible effects of a planned conjunctive-use project in the western part of the ground-water basin. The simulated project included the addition of a new recharge pond and a new extraction well. In addition, recharge at two existing recharge ponds was increased and three existing production wells were pumped, treated in a nitrate-removal facility, and used for water supply. The simulated hydraulic heads increased in the west, the mideast, and parts of the east hydrogeologic units; however, the simulated hydraulic heads decreased in the midwest and northeast hydrogeologic units. The simulated nitrate concentrations increased to above the MCL of 44 milligrams per liter (10 milligrams per liter as nitrogen) in parts of the west as a result of the increase in simulated hydraulic head. The simulated nitrate concentrations decreased in part of the midwest hydrogeologic unit as a result of the artificial recharge and pumping from the nitrate-removal wells. The simulated nitrate concentrations increased to above the MCL of 44 milligrams per liter in part of the mideast and parts of the east hydrogeologic units beneath commercial land-use areas.

California↗

USGS2016

Clear-water abutment and contraction scour in the Coastal Plain and Piedmont Provinces of South Carolina, 1996-99

The U.S. Geological Survey, in cooperation with the South Carolina Department of Transportation, collected observations of clear-water aburment and contraction scour at 146 bridges in the Coastal Plain and Piedmont of South Carolina. Scour depths ranged from 0 to 23.6 feet. Theoretical scour depths were computed at each bridge and compared with observed scour. This comparison showed that theoretical scour depths, in general, exceeded the observed scour depths and often were excessive. A comparison of field data with dimensionless relations for laboratory data showed that the range of dimensionless variables used in laboratory investigations was outside of the range for field data in South Carolina, suggesting laboratory relations may not be applicable to field conditions in South Carolina. Variables determined to be important in developing scour within laboratory studies were investigated to understand their influence within the South Carolina field data, and many of these variables appeared to be insignificant under field conditions found in South Carolina. The strongest explanatory variables were embankment length, geometric-contraction ratio, approach velocity, and soil cohesion. Envelope curves developed with the field data are useful tools for assessing reasonable ranges of scour depth in South Carolina. These tools are simple to apply and are an improvement over the current methods for predicting theoretical scour. Data from this study have been compiled into a database that includes photographs, figures, observed scour depths, theoretical scour depths, limited basin characteristics, limited soil data, and theoretical hydraulic data. The database can be used to compare studied sites with unstudied sites to assess the potential for scour at the unstudied sites. In addition, the database can be used to assess the performance of various theoretical methods for predicting clear-water abutment and contraction scour.

South Carolina↗