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At least 1,477 records · Page 82Linked to original sources
USGS2026

Corundum discovered by SuperCam and the Perseverance rover at Jezero crater, Mars

Mars is primarily composed of mafic mineral assemblages and their alteration products, but small, scattered rocks strewn across the landscape offer clues to greater petrological diversity. While traversing the Jezero crater rim, the Perseverance rover encountered several plagioclase-rich light-toned float rocks. SuperCam identified the distinctive signature of corundum (α-Al 2 O 3 ) in these rocks using time-resolved luminescence spectroscopy. Two strong peaks (692.7 and 694.1 nm) with millisecond lifetimes, and additional supporting lines, are consistent with Cr 3+ substitution for Al 3+ in corundum. Corundum forms in Al-rich, Si-depleted environments through magmatic or metamorphic processes. Given the rocks' small size, association with plagioclase, and location on the crater rim, we interpret the most plausible formation scenario to be impact induced metamorphism at the interface of a felsic and a mafic/ultramafic member with the likely action of fluids at some stage, although other possibilities are not excluded.

Geophysical Research Letters↗
USGS1987

Conodont color and textural alteration: An index to regional metamorphism, contact metamorphism, and hydrothermal alteration

Experimental and field data are used to extend the utility of conodonts as semi-quantitative thermal indices into the regimes of regional and contact metamorphism, as well as hydrothermal alteration. An Arrhenius plot of data from induced conodont color alteration by pyrolysis in air at 1 atm was used to generate the geologic temperatures for conodont color-alteration indices (CAI) above 300 °C, that is, for CAI values of 5½ through 8. Such CAI values occur in very low- to medium-grade, regionally metamorphosed, contact-metamorphosed, and hydrothermally altered rocks. The uniformity or variability of CAI values within a sample, together with conodont texture, can help to distinguish grades and environments of metamorphism, particularly in metacarbonate sequences. Induced CAI by pyrolysis in a water-methane mixture at ½ kbar results in retardation of CAI and in a disparate mixture of both low and high CAI values within each experimental sample. In this system, color-alteration processes, above a CAI of 2 to 3, seem to change from predominantly carbonization to predominantly loss of organic matter, presumably by oxidation and volatilization of oxides. These experiments approximate the type of CAI mixture characteristically found in conodonts recovered from hydrothermally altered rocks. These data indicate that CAI values of 6 to 8 cannot be used to assess precise temperatures of hydrothermally altered rocks but may serve as useful indicators of potential mineralization.

Geological Society of America Bulletin↗
USGS2008

Geochemical evidence for airborne dust additions to soils in Channel Islands National Park, California

There is an increasing awareness that dust plays important roles in climate change, biogeochemical cycles, nutrient supply to ecosystems, and soil formation. In Channel Islands National Park, California, soils are clay-rich Vertisols or Alfisols and Mollisols with vertic properties. The soils are overlain by silt-rich mantles that contrast sharply with the underlying clay-rich horizons. Silt mantles contain minerals that are rare or absent in the volcanic rocks that dominate these islands. Immobile trace elements (Sc-Th-La and Ta-Nd-Cr) and rare-earth elements show that the basalt and andesite on the islands have a composition intermediate between upper-continental crust and oceanic crust. In contrast, the silt fractions and, to a lesser extent, clay fractions of the silt mantle have compositions closer to average upper-continental crust and very similar to Mojave Desert dust. Island shelves, exposed during the last glacial period, could have provided a source of eolian sediment for the silt mantles, but this is not supported by mineralogical data. We hypothesize that a more likely source for the silt-rich mantles is airborne dust from mainland California and Baja California, either from the Mojave Desert or from the continental shelf during glacial low stands of sea. Although average winds are from the northwest in coastal California, easterly winds occur numerous times of the year when "Santa Ana" conditions prevail, caused by a high-pressure cell centered over the Great Basin. The eolian silt mantles constitute an important medium of plant growth and provide evidence that abundant eolian silt and clay may be delivered to the eastern Pacific Ocean from inland desert sources. ?? 2007 Geological Society of America.

Geological Society of America Bulletin↗
USGS1947

Preliminary report on the stratigraphy and structure of the area of the Utukok River with notes on the Corwin-Cape Beaufort region, Alaska

U.S. Geological Survey Party 3 studied the geology of the Utukok River area and conducted a short reconnaissance of the Corwin-Cape Beaufort Region during the period May 12 to August 31, 1947. The upper part of the Utukok River was examined for several miles on either side while the lower, or Coastal Plain-portion, was necessarily limited to the few outcrops along the river. During this study, the major emphasis was placed upon rocks of Upper Cretaceous age and their relationships to the underlying Lower Cretaceous rocks. All macrofossils, and numerous samples for porosity, heavy mineral, and microfossil determinations were collected. A triangulation net was established by theodolite from Camp. 1 near the headwaters of the river to the mouth of Carbon Creek. The survey started and ended on measured base lines, and stations were determined by intersection and resection. Stations were selected, insofar as possible, on points that could be pin pricked on aerial photographs where adequate coverage was available, Horizontal control was computed for cartographic purposes. Vertical differences were computed from an elevation at Camp 1 assumed at 2,000 feet above sea level based upon two different airplane altimeter readings. Most of the country is too rough for wheel landings with the exception of several gravel bars in the river between Camp 6 and the coast. Pontoon landings with a Cub plane can be made at most places on the river. Driftwood, Adventure, Disappointment, Carbon, and Elusive Creeks are the main tributaries to the Utukok. At various localities, terrace gravels are common on divides of these streams. A terrace north of Driftwood Creek and about ten miles east of Camp 2 is covered with a deposit of gravel which is apparently, thick and is spread over an irregular area about two miles long and a half mile wide. A thin tundra cover obscures what is probably a much larger continuation of the gravel deposit. With favorable conditions plane landings could be made, but with a little construction work a commercial size airfield could be made.

Alaska↗
USGS2022

Preliminary geologic map of the Cherry Hill quadrangle, Dinwiddie, Sussex, and Greensville Counties, Virginia

The Cherry Hill 7.5-minute quadrangle straddles the Coastal Plain and Piedmont Provinces along the Tidewater Fall Line. Rocks of the eastern Piedmont Roanoke Rapids terrane crop out in the western part of the quadrangle and consist of greenschist- to amphibolite-facies Neoproterozoic felsic to intermediate metavolcanic rocks, some of which contain flattened quartz phenocrysts and are locally isoclinally folded; greenstone that locally preserves primary layering; and intrusive metadiorite and metagabbro, much of which has been altered to amphibolite. Most of these rocks are strongly foliated and jointed. Greenschist-facies metasiltstone that preserves primary bedding also occurs locally in the Roanoke Rapids terrane. Neoproterozoic mica schist, middle Paleozoic foliated metagranite, and late Paleozoic massive and porphyritic granite crop out in the eastern part of the quadrangle and are part of the Dinwiddie terrane and the late Paleozoic De Witt pluton. Upper greenschist- to lower amphibolite-facies mica schist consists of stringers and boudins of vein quartz and contains porphyroclasts of staurolite that preserve an earlier foliation as inclusion trails. Porphyroblasts of garnet, staurolite, and kyanite also occur locally. Foliation in granites of the De Witt pluton may be magmatic. Separating the Dinwiddie terrane from the Roanoke Rapids terrane are greenschist-facies, highly strained granitic mylonite and bodies of less deformed granite within the Nottoway River fault zone, which is a strand of the eastern Piedmont fault system. Paleozoic pegmatite dikes and quartz veins cross-cut rocks of the Dinwiddie terrane, and quartz veins and Jurassic diabase dikes cross-cut rocks of the Roanoke Rapids terrane. Sand and gravel deposits of the Atlantic Coastal Plain overlie Piedmont rocks. Two units assigned to the upper part of the Neogene Chesapeake Group occur at elevations up to 295 feet (90 meters) above sea level atop the Richmond plain in the central part of the quadrangle. Two units of the Quaternary Bacons Castle Formation occupy the Essex plain and Norge uplands at elevations up to 180 feet (55 meters) above sea level in the eastern part of the quadrangle. In the western part of the quadrangle, multiple levels of terrace deposits are the fluvial equivalent of estuarine to marine units of the Atlantic Coastal Plain to the east. Holocene alluvium occurs along creeks and the Nottoway River. Quaternary colluvial deposits occur locally. Numerous Carolina bays pock the landscape of the Richmond and Essex plains, and three abandoned channelways represent former locations of Sappony Creek, one of the major drainages of the quadrangle. Brittle faults juxtapose Piedmont basement rocks against Neogene sediments of the upper part of the Chesapeake Group. These Cenozoic faults were first uncovered in mine excavations in the late 1990s; new mapping indicates that many of these faults are reactivated silicified cataclasite zones that occur throughout the Piedmont basement rocks. Silicified cataclasites and associated quartz veins are typically mineralized with iron and iron sulfide minerals. The quadrangle was the focus of extensive mining for heavy minerals, including ilmenite and zircon, in upland Atlantic Coastal Plain deposits beginning in the mid-1990s. Other mineral resources, including precious metals, clay for structural brick, crushed stone, and building stone for millstones, have also been prospected or quarried in the quadrangle.

Virginia↗
USGS1953

Geology of the Olds Mountain-Clark Peak area, Juneau and vicinity, Alaska

The area under study lies about ten miles east of Juneau, Alaska, and includes the bedded rocks adjacent to the Coast Range batholith, and intrusive rocks related to the batholith. Deep glaciated valleys and glacially scoured rocks are the major topographic features. The relief is about 3,500 feet, and the highest mountain reaches an altitude of 4,453 feet. Remnants of larger glaciers and perennial snow fields cover many of the higher summits, and glacial erratics at elevations above 3,100 feet attest to a former thick ice cover. The bedded rocks are crystalline schists that locally reach katozonal metamorphic rank as indicated by biotite-garnet-kyanite-sillimanite mineral assemblages. The schists are believed to be dominantly a product of regional metamorphism predating the intrusion of rocks related to the Coast Range batholith. It appears, however, that stresses continued to be active during igneous and granitizing activity accompanying the Coast Range orogeny. The major intrusive bodies are a composite quartz-dioritic batholith and quartz-diorite sills that locally reach a thickness of more than two thousand feet. The sills usually are notably gneissic, and appear to have formed by intrusion rather than replacement. The batholith is a composite body formed by migmatization, replacement, and local fusion. A stressed environment during formation is suggested by a primary gneissic structure. A high quartz content and a paucity of potash feldspars is diagnostic of the intrusive bodies. In addition to the bodies of quartz-diorite, small sills and dikes of gabbro, quartz-pegmatite, and unmetamorphosed diabase intrude the schists. Overturned folds in the schists are nearly isoclinal, and some of the folds are large enough to cause repetition of beds in the Clark Peak schists. Two persistent northwest-trending strike faults of small displacement cut the schists. Two east-trending faults of larger displacement are marked by thick gouge zones locally containing graphite. The rocks near the faults are hydrothermally altered and pyritized, and at least two of the diabase dikes are crushed and hydrothermally altered near one of the northwest-trending faults. Faulting and hydrothermal activity probably continued at least into the early Tertiary.

Open-File Report↗
USGS1954

Physical exploration for uranium during 1951 in the Silver Reef district, Washington County, Utah

During 1951 a joint exploration program of the most promising uraniferous areas in the Silver Reef district was made by the U.S. Geological Survey and the U.S. atomic Energy Commission. A U.S. Bureau of Mines drill crew, on contract to the Atomic Energy Commission, did 2,450 feet of diamond drilling under the geological supervision of the U.S. Geological Survey. The purpose of the drilling was to delineate broadly the favorable ground for commercial development of the uranium deposits. Ten drill holes were located around Pumpkin Point, which is the northeastern end of Buckeye Reef, to probe for extensions of small ore sheets mined on the Point in fine-grained sandstones of the Chinle formation. Three additional holes were located around Tecumseh Hill to probe for extensions of the small showings of uranium-bearing rocks of Buckeye Reef. Only one trace of uranium mineral was detected in the 13 drill holes by logging of drill cores, gamma-ray logging of the holes, and analysis of many core splits from favorable lithology. Extensive traversing with Geiger counters throughout the district and detailed geologic mapping of areas on Buckeye Reef and on East Reef indicate that the chances of discovering significant uranium deposits in the Silver Reef district are very poor, because of: highly variable lithology, closely faulted structure, and obliteration of the shallow uranium-bearing lenses by silver mining. Most of the available ore in the district was in the Pumpkin Point area and has been mined during 1950 to 1953. No ore reserves can be computed for the district before further development work. The most favorable remaining area in the district is now being explored by the operators with Atomic Energy Commission supervision.

Open-File Report↗
USGS2006

Questa baseline and pre-mining ground-water quality investigation. 20. Water chemistry of the Red River and selected seeps, tributaries, and precipitation, Taos County, New Mexico, 2000-2004

As part of a multi-year project to infer the pre-mining ground-water quality at Molycorp's Questa mine site, surface-water samples of the Red River, some of its tributaries, seeps, and snow samples were collected for analysis of inorganic solutes and of water and sulfate stable isotopes in selected samples. The primary aim of this study was to document diel, storm event, and seasonal variations in water chemistry for the Red River and similar variations in water chemistry for Straight Creek, a natural analog site similar in topography, hydrology, and geology to the mine site for inferring pre-mining water-quality conditions. Red River water samples collected between 2000 and 2004 show that the largest variations in water chemistry occur during late summer rainstorms, often monsoonal in nature. Within hours, discharge of the Red River increased from 8 to 102 cubic feet per second and pH decreased from 7.80 to 4.83. The highest concentrations of metals (iron, aluminum, zinc, manganese) and sulfate also occur during such events. Low-pH and high-solute concentrations during rainstorm runoff are derived primarily from alteration 'scar' areas of naturally high mineralization combined with steep topography that exposes continually altered rock because erosion is too rapid for vegetative growth. The year 2002 was one of the driest on record, and Red River discharge reflected the low seasonal snow pack. No snowmelt peak appeared in the hydrograph record, and a late summer storm produced the highest flow for the year. Snowmelt was closer to normal during 2003 and demonstrated the dilution effect of snowmelt on water chemistry. Two diel sampling events were conducted for the Red River, one during low flow and the other during high flow, at two locations, at the Red River gaging station and just upstream from Molycorp's mill site. No discernible diel trends were observed except for dissolved zinc and manganese at the upstream site during low flow. Straight Creek drainage water was sampled periodically from 2001 to 2004 at the down stream end of surface drainage near the point at which it disappeared into the debris fan. This water has a minimal range in pH (2.7 to 3.2) but a substantial concentration range in many solutes; for example, sulfate concentrations varied from 525 to 2,660 mg/L. Many elements covary with sulfate suggesting that dilution is the primary control of the range in solute concentrations. A transect of water samples higher in the scar area were collected in October of 2003. They had a lower range in pH (2.44 to 3.05) and higher solute concentrations than those collected periodically from lower in the catchment. Water isotopes for the upper transect samples indicated slight evaporation, and in part, may account for the higher solute concentrations. Drainage waters also were collected from Hottentot, Junebug, Hansen, Little Hansen, and Goat Hill Gulch drainages. Most constituents from other scar drainage waters showed ranges of concentration similar to those of the Straight Creek waters. An exception was water collected from Goat Hill Gulch, which has some of the highest concentrations of any surface-water sample collected but also contained waste-rock leachates.

New Mexico↗
USGS2002

Water-quality data analysis of the upper Gunnison River watershed, Colorado, 1989-99

Water-quality data from October 1969 to December 1999 for both surface water and ground water in the upper Gunnison River watershed were retrieved and compiled from the U.S. Geological Survey National Water Information System and the U.S. Environmental Protection Agency Storage and Retrieval databases. Analyses focused primarily on a subset of these data from October 1989 to December 1999. The upper Gunnison River watershed is located west of the Continental Divide in the Southern Rocky Mountains physiographic province. Surface-water-quality data were compiled for 482 sites in the upper Gunnison River watershed. Most values of surface-water temperature, dissolved oxygen, and pH were within Colorado Department of Public Health and Environment (CDPHE) in-stream standards. Calcium bicarbonate type water was the most spatially dominant water type in the basin. Nutrients were most commonly sampled along the Slate River and East River near Crested Butte and along the Gunnison River from the confluence of the East and Taylor Rivers to the western edge of the watershed. Median ammonia concentrations were low, with many concentrations less than laboratory reporting levels. All nitrate concentrations met the CDPHE in-stream standard of 10 milligrams per liter. More than 30 percent of stream sites with total phosphorus data (23 of 61 sites) had concentrations greater than the U.S. Environmental Protection Agency (USEPA) recommendation for controlling eutrophication. Ammonia concentrations at a site on the Slate River near Crested Butte had a statistically significant upward trend for the 1995–99 period. The Slate River near Crested Butte site is located immediately downstream from the towns of Crested Butte and Mount Crested Butte and may reflect recent population growth or other land-use changes. However, the rate of change of the trend is small (0.017 milligram per liter per year). Although a multiple comparison test showed nitrate concentrations were statistically different between agriculture and forest sites and between agriculture and urban land-use classified sites, median concentrations were low among all land-use settings. Median concentrations of total phosphorus were greatest in rangeland areas and least in urban areas. No significant differences were identified for median concentrations of total phosphorus in agriculture and forest land-use areas. Median concentrations of arsenic, lead, mercury, selenium, and silver were low or below reporting levels throughout the watershed. Aluminum, cadmium, copper, lead, manganese, and zinc concentrations were elevated near the town of Crested Butte and on Henson Creek upstream from Lake City, which may be explained by upstream areas of historical mining. Samples for six trace elements exceeded standards: cadmium, copper, lead, manganese, silver, and zinc. A downward trend (3 micrograms per liter per year) was identified for the dissolved iron concentration at a site on the Gunnison River at County Road 32 downstream from the city of Gunnison. Streambed-sediment samples from areas affected by historical mining also had elevated concentrations of some trace elements. Chlorophyll- a concentrations in samples from Blue Mesa Reservoir and streams in the Crested Butte and Gunnison areas were typical of unenriched to moderately enriched conditions. Median concentrations of 5-day biochemical oxygen demand concentrations for sites between Crested Butte and Blue Mesa Reservoir were less than 2 milligrams per liter. Occasional high (greater than 200 counts per 100 milliliters) concentrations for fecal coliform were determined at selected sites within the study area. However, median concentrations were less than 100 counts per 100 milliliters except for the Squaw Creek and Cimarron River areas in the western part of the watershed. Ground-water-quality data have been collected by the U.S. Geological Survey from 99 wells. Many wells were completed in aquifers composed of Holocene-age valley fill and alluvium. Most field properties were within the USEPA Secondary Drinking Water Regulations (SDWR) range for treated drinking water, except for 2 (of 40) pH samples. Calcium bicarbonate was the predominant water type in nearly all aquifers except for the aquifers composed of volcanic rock, which had more sodium and sulfate mixed water types. Wells with sulfate concentrations exceeding the SDWR of 250 milligrams per liter were completed in aquifers composed of volcanic rock near Lake City. Dissolution and oxidation of sulfide minerals in these aquifers may explain the elevated sulfate concentrations in ground water at these locations. Nutrient concentrations in ground water were generally low, and median concentrations for ammonia, nitrite, and dissolved phosphorus were below reporting levels. All nitrate concentrations in the samples were below the USEPA drinking-water maximum contaminant level of 10 mg/L. No statistical difference was found in nitrate concentrations among the four land-use classifications (agriculture, forest, rangeland, and urban). Trace elements in ground water were generally below the USEPA SDWR. Three iron samples exceeded the USEPA SDWR of 300 micrograms per liter at two wells located near the city of Gunnison and at a well south of the town of Powderhorn near the Cebolla River. Nine of 39 manganese samples exceeded the USEPA SDWR of 50 micrograms per liter and were collected from aquifers composed of Holocene-age valley fill and alluvium near Gunnison and Crested Butte and in one well near the Cebolla River. Radon gas is a natural radioactive decay product of uranium. All 39 radon samples collected from ground water in the watershed exceeded the proposed USEPA drinking-water maximum contaminant level of 300 picocuries per liter and ranged from 426 to 3,830 picocuries per liter.

Colorado↗
USGS2013

Cobalt-rich ferromanganese crusts from the Central Pacific

Ferromanganese crusts coat most hard substrates on seamounts, ridges, and plateaus in the centralPacific basin. Crusts from less than 2500 m water depth are rich in Mn, Co, Ni, Pb, and Pt. Samples we collected from the EEl of the Hawaiian, Johnston, Palmyra, and Marshall Islands are discussed. Necker Ridge in the Hawaiian EEl has the greatest average crust thickness of 4 em. The dominant mineral in all crusts is o-Mn02' Substrate rocks are dominantly volcanic breccia. Slumping and turbidity currents on the flanks of the submarine edifices partly control crust thicknesses by burial and dissolution or erosion. Regional variations in crust chemistry and mineralogy can be related to various oceanographic and geologic conditions. Of the areas examined in Some detail, the EEl of Johnston, Palmyra, and the Marshall Islands hold the greatest economic potential.

Conference Paper↗
USGS1981

Differentiation of delta-front and barrier lithofacies of the Upper Cretaceous Pictured Cliffs Sandstone, southwest San Juan Basin, New Mexico.

This Sandstone represents a regressive littoral marine unit deposited during the final retreat of the Cretaceous epeiric sea. Differences in rock type, internal and penecontemporaneous deformation structures, textural sequences, mineral composition and trace fossil content permit recognition of laterally contemporaneous delta-front and barrier lithofacies. The delta-front lithofacies consists of distal bar, distributary mouth bar, and distributary channel deposits. The barrier lithofacies consists of shoreface, beach, washover channel, tidal inlet, tidal channel, and ebb-tidal delta deposits; these lithofacies are coarsening-upward sequences of shale, siltstone and sandstone, locally scoured in the upper part by fining-upward channel deposits.-from Authors

Mountain Geologist↗
USGS2004

Non-invasive exploration in an environmentally sensitive world

Modern remote sensing provides a means for locating and characterizing exposed mineralized systems in many parts of the world. These capabilities are non-invasive and help target specific areas for more detailed exploration. An example of how remote sensing technology can be used is evident from a study of the Questa Mining District, New Mexico. Analysis of low spectral resolution data from the Landsat Thematic Mapper satellite system clearly shows the regional distribution of two broad mineral groups often associated with mineralized systems: clay-carbonate-sulfate and iron oxides-iron hydroxides. Analysis of high spectral resolution data from the Airborne Visible and Infrared Imaging System (AVIRIS) shows the occurrence and distribution of many individual mineral species that characterize the pattern of hydrothermally altered rocks in the district.

Conference Paper↗
USGS1986

Geology of the Harrisonburg and Bridgewater quadrangles, Virginia

The Harrisonburg and Bridgewater quadrangles comprise an area of approximately 117 square miles in Rockingham County in northwestern Virginia.This area is in the western part of the Shenandoah Valley, a portion of the Valley and Ridge physiographic province, and contains parts of three major geologic structures-the Staunton and North Mountain thrust faults and the Massanutten synclinorium.The roeks within the two quadrangles are folded and faulted limestones, dolomites, shales, and sandstones of Paleozoic age. These rocks have been divided into groups, formations, and members that include the Elbrook and Conococheague formations (Cambrian), the Stonehenge Formation, the Beekmantown Group, the New Market Limestone, and the Lineolnshire, Edinburg, and Martinsburg formations (Ordovieian), the Massanutten Sandstone and the Bloomsburg Formation (Silurian), and probably Upper Silurian and Iower and Middle Devonian limestones and shales that are not exposed but are judged to be on Massanutten Mountain. Triassic diabase dikes and Eocene volcanic pipes intrude the Paleozoic sequence locally. Much of the sequenee is eovered by alluvium or talus of Quaternary age. Selected strata of the Cambrian and Ordovician carbonate roek sequence are sources for road aggregate, agricultural lime, concrete aggregate, dimension stone, tettazzo, portland cement, flux stone, and pellet lime. Some of the carbonate rocks may be potential sources of lead and zinc minerals. Ordovician shale formations have potential for structural clay products.

Virginia↗
USGS2012

Cambrian–Ordovician sedimentary rocks of Alaska

Cambrian-Lower Ordovician carbonate rocks that likely formed as part of the Laurentian continental margin, and may thus have been part of the Cambrian-Ordovician great American carbonate bank, occur in east-central Alaska in the Nation Arch area. These strata accumulated on the southwestern margin (present-day coordinates) of the Yukon stable block, a broad area of early Paleozoic carbonate platform deposition in the northern Yukon Territory, and constitute two successions. The first consists of approximately 900 m (∼2950 ft) of shallow-water limestone and dolostone that are in part silicified, laminated, oolitic, and pisolitic, and make up the lower member of the Jones Ridge Limestone. Conodonts, trilobites, archaeo-cyathids, and brachiopods indicate an age of Early Cambrian to early Early Ordovician (Tremadoc; Ibexian) and have Laurentian biogeographic affinities. Upper Ordovician bio-clastic limestone (the upper member of the Jones Ridge Limestone) unconformably overlies these strata. A roughly coeval, but somewhat deeper water, succession crops out near the Jones Ridge Limestone and consists of, in ascending order, the Funnel Creek Limestone, Adams Argillite, and Hillard Limestone. The Funnel Creek (15-400 m [50-1310 ft] thick) is mainly nonfossilif-erous, extensively silicified, commonly oolitic limestone and dolostone and is assumed to be Lower Cambrian in age. It is overlain by argillite, siltstone, cross-laminated quartzite, and oolitic to sandy limestone of the Adams Argillite (90-180 m [295-550 ft] thick). This unit contains the trace fossil Oldhamia and Lower Cambrian archaeocyathids and trilobites that have Siberian affinities. The Hillard (30-150 m [100-490 ft] thick) is chiefly limestone, with local ooids, edgewise and boulder conglomerate, and phosphatic horizons, and likely formed in a platform-margin setting. Trilobites and brachiopods from this unit are Early Cambrian to earliest Ordovician in age and have mainly Laurentian affinities. Slope and/or basinal rocks of the Road River Formation that are as old as Early Ordovician (early middle Arenig; Ibexian) unconformably overlie the Hillard Limestone. Abrupt facies transitions between the two Nation Arch area carbonate successions may reflect relatively steep paleoslopes and/or telescoping of facies by imbricate thrust faults. Carbonate strata of Cambrian–Ordovician age are also found north of the Nation Arch area in the Porcupine terrane. These rocks have been little studied, and their precise Stratigraphic succession and paleogeographic setting are uncertain. The few fossil collections indicate mainly Laurentian affinities and include Cambrian(?) trilobites and Lower and Middle Ordovician conodonts. Lower Paleozoic strata of the Porcupine terrane probably formed at or near the northwestern edge (present-day coordinates) of the Yukon stable block. Cambrian–Ordovician carbonate strata occur widely in northern Alaska (parts of the Arctic Alaska, York, and Seward terranes) and interior Alaska (Farewell terrane). These rocks share distinctive lithologic and faunal features and were deposited in a range of shallow-shelf to basinal environments. Carbonate platform successions in northern and interior Alaska include fossils of both Laurentian and Siberian biotic provinces and may have formed on a single crustal fragment that rifted away from the Siberian craton during the late Proterozoic. These Alaskan strata were most likely in faunal exchange with, but not physically attached to, the great American carbonate bank. Lower–Middle Ordovician carbonate and siliciclastic rocks are also found in the White Mountains, Livengood, and Ruby terranes of interior Alaska, the Alexander terrane in southeastern Alaska, and the Goodnews terrane in southwestern Alaska. These successions were likely not attached to Laurentia during their deposition, although some authors have proposed Laurentian origins for the White Mountains and Livengood terranes. Little detailed information is available on the resource potential of Cambrian–Ordovician successions in Alaska. Most have low porosity and are too thermally mature to be prospective for oil and gas, although a few units in east-central and northern Alaska may have some potential as petroleum source and reservoir rocks. Strata of this age have potential for metallic mineral resources; strata-bound Zn-Pb ± Ag occurrences are known in the Funnel Creek Limestone in east-central Alaska, as well as several units of possible Cambrian and/or Ordovician age in northern and interior Alaska.

Alaska↗
USGS2013

Integrated geophysical imaging of a concealed mineral deposit: a case study of the world-class Pebble porphyry deposit in southwestern Alaska

We combined aeromagnetic, induced polarization, magnetotelluric, and gravity surveys as well as drillhole geologic, alteration, magnetic susceptibility, and density data for exploration and characterization of the Cu-Au-Mo Pebble porphyry deposit. This undeveloped deposit is almost completely concealed by postmineralization sedimentary and volcanic rocks, presenting an exploration challenge. Individual geophysical methods primarily assist regional characterization. Positive chargeability and conductivity anomalies are observed over a broad region surrounding the deposit, likely representing sulfide minerals that accumulated during multiple stages of hydrothermal alteration. The mineralized area occupies only a small part of the chargeability anomaly because sulfide precipitation was not unique to the deposit, and mafic rocks also exhibit strong chargeability. Conductivity anomalies similarly reflect widespread sulfides as well as water-saturated glacial sediments. Mineralogical and magnetic susceptibility data indicate magnetite destruction primarily within the Cu-Au-Mo mineralized area. The magnetic field does not show a corresponding anomaly low but the analytic signal does in areas where the deposit is not covered by postmineralization igneous rocks. The analytic signal shows similar lows over sedimentary rocks outside of the mineralized area, however, and cannot uniquely distinguish the deposit. We find that the intersection of positive chargeability anomalies with analytic signal lows, indicating elevated sulfide concentrations but low magnetite at shallow depths, roughly delineates the deposit where it is covered only by glacial sediments. Neither chargeability highs nor analytic signal lows are present where the deposit is covered by several hundred meters of sedimentary and volcanic rocks, but a 3D resistivity model derived from magnetotelluric data shows a corresponding zone of higher conductivity. Gravity data highlight geologic features within the deposit, including shallow diorite sills that locally contain higher-grade mineralization. The results thus show ways in which an integrated survey approach might be used to distinguish zones of potentially economic mineralization.

Alaska↗
USGS2021

Diagenetic barite-pyrite-wurtzite formation and redox signatures in Triassic mudstone, Brooks Range, northern Alaska

Mineralogical and geochemical studies of interbedded black and gray mudstones in the Triassic part of the Triassic-Jurassic Otuk Formation (northern Alaska) document locally abundant barite and pyrite plus diverse redox signatures. These strata, deposited in an outer shelf setting at paleolatitudes of ~45 to 60°N, show widespread sedimentological evidence for bioturbation. Barite occurs preferentially in black mudstones (TOC = 0.93–6.46 wt%), forming displacive euhedral crystals with pyrite inclusions and rims, and late albite inclusions or intergrowths. Pyrite also occurs as small (3–20 μm) framboids, discontinuous laminae, euhedral and anhedral crystals, and replacements of barite and fossils (mainly radiolarians). Paragenetically early wurtzite is present as clusters of very small (1–3 μm) aggregates of radiating crystals 0.5 to 1.0 μm long with cores of organic matter that overgrow framboidal pyrite; later wurtzite forms 10- to 30-μm bladed crystals. Equant grains (3–30 μm) and small (20 μm) angular clusters of zinc sulfide that include <1-μm-long, comb-like structures are sphalerite or wurtzite, or both. Minor siderite forms euhedral crystals intergrown with albite that enclose wurtzite and barite. Illite shows intergrowths with sphalerite; rare K-feldspar is intergrown with barite. Formation of these minerals and assemblages is attributed to early diagenetic processes. Whole-rock geochemical data for 15 samples show large ranges in redox proxies including Post Archean Average Shale (PAAS)-normalized enrichment factors (EFs) for V, U, Mo, and Re, and Al-normalized ratios for V, U, and Mo. Results for most black mudstones, with or without abundant barite and/or pyrite, suggest deposition within an oxygen minimum zone. Cerium anomalies, PAAS-normalized and calculated on a detrital-free basis, range widely from 0.49 to 0.96 and may reflect diagenetic overprinting by Ce-depleted fluids. Considering data for both black and gray mudstones, the overall geochemical pattern together with evidence from pyrite framboid sizes suggest that redox conditions fluctuated greatly from euxinic to oxic, like the redox profiles reported for modern shelf sediments offshore Peru and Namibia. The euxinic redox signatures in some Otuk black mudstones may correlate with widespread Early to Middle Triassic ocean anoxic events proposed for other regions. Calculations of median EFs for trace elements in Otuk black mudstones reveal both enrichments and depletions. Normalizations to the median composition of the three least-mineralized black mudstones show that barite- and/or pyrite-rich samples display large (>50%) positive changes for Li (+80.4%), V (+75.6%), Sr (+75.9%), Ba (+790%), Cu (+92.1%), Ni (+169%), Ag (+156%), Au (+3091%), As (+109%), Sb (+476%), and Se (+205%); Zn shows a moderate positive change of +42.1%. Moderate negative changes are evident only for Ge (−47.2%) and W (−30.6%). The local enrichments may reflect one or more factors including redox variations in bottom waters and pore fluids, element mobility during diagenesis, and selective fractionation into minerals such as barite, pyrite, and wurtzite. Anomalously low U/Al and UEF values, compared to those for other modern and ancient organic-rich sediments and sedimentary rocks, are attributed to increased solubility and loss of U during bioturbation-related oxygenation in the subsurface. Physicochemical constraints on barite, pyrite, and wurtzite formation are informed by use of a pH-fO2 plot constructed at 10 °C. Based on paragenetic evidence for multistage deposition of these three minerals, together with the presence of illite intergrown with ZnS and K-feldspar with barite, proposed diagenetic trends involve an increase in pH and fO2 related to the ingress of sulfate-rich pore fluids during bioturbation, followed by a return to lower then higher pH and fO2 conditions linked to carbon, sulfur, barium, and iron cycling during diagenesis. Labile Ba of marine pelagic origin was mobilized from organic-rich sediment upward to the sulfate-methane transition zone where barite precipitated during the interaction of reduced Ba- and CH4-rich fluids with sulfate-bearing pore fluids. The formation of paragenetically early wurtzite (ZnS) crystals, as well as locally high EF values for Cu, Ni, Ag, and Au, is attributed to metal enrichment of pore fluids, with sources being derived in part from water-column deposition from hydrothermal plumes related to coeval Triassic seafloor vent systems including a volcanogenic massive sulfide deposit in British Columbia and the Wrangellia Large Igneous Province in Alaska.

Alaska↗
USGS1985

Geology and regional setting of the Al Masane ancient mine area, southeastern Arabian Shield, Kingdom of Saudi Arabia

Stratiform zinc-copper massive-sulfide deposits at Al Masane occur in thin dolomitic interbeds within Proterozoic felsic crystal tuff and mafic flows and volcaniclastics. These strata dip steeply westward and are underlain by shale and shaly graywacke to the east and overlain by lapilli crystal tuff to the west. This section is part of the Habawnah fold or mineral belt that extends from the Wadi Wassat area southward into Yemen. Western parts of the Habawnah fold belt, including the Al Masane area, are characterized by a bimodal assemblage of of phenocryst-poor basalts and sodic rhyolite crystal tuff, and by zinc-copper mineral deposits. Strata in the eastern part of the belt, mostly east of the Ashara fault zone, contain abundant phenocryst-rich mafic volcanic rocks, little felsic crystal tuff, and barren or locally nickeliferous massive pyrite deposits. Stratified rocks and gabbro sills of the Al Masane area were isoclinally folded and metamorphosed to the greenschist facies. Structural analysis indicates that foliation, lineation, joints, major and minor folds, and one of three sets of faults formed during a single east-west compressional deformational episode. Axial-plane foliation dips steeply westward and is usually coincident with bedding. Lineation plunges steeply to the northwest throughout the map area and is parallel to the intersection of joints of two major sets and to the intersection of these joints with foliation. Major folds have north-trending, gently plunging axes to which the axis of a minor fold set is essentially parallel. A second minor fold-set has a steeply plunging axis parallel to lineation. The Saadah massive-sulfide body is elongated by a fold of this system. Unmetamorphosed Proterozoic felsic sills, quartz monzonite and gabbro plutons, porphyritic diorite dikes, mafic dikes, and basalt dikes, in that apparent order, have intruded the stratified section. Basalt dikes are offset by southwestward-dipping reverse faults and by faults parallel to bedding. Malachite and metal-oxide-bearing gossans in the Al Masane area were mined in ancient times. Radiocarbon dating of charcoal in slag indicates that the ores were smelted about 1,200 years ago. Gossans are depleted in copper, silver, and zinc, relative to underlying sulfide, by factors of about 0.33, 0.2, and 0.08, respectively. Evaluation of numerous analyses of gossans, carbonates, and silicate rocks indicates that exploration for zinc-copper massive-sulfide deposits in the region should center on detailed geochemical studies of dolomitic beds. Dolomitization of host siliceous shales and tuffs and the formation of the massive-sulfide bodies at Al Masane probably caused by submarine fumarolic hydrothermal activity during periods of relative volcanic quiescence. Further work in the Al Masane region should include a study of the dolomitized areas and a search for other potential alteration "pipe" products (e.g. chlorite) as a guide to location of proximal deposits. Zinc-copper deposits at Al Masane and in the Dhahar-Al Hajrah and Kutam-Farah Garan areas have characteristics in common and are associated with felsic volcanic centers in the western bimodal part of the Habawnah mineral belt. They probably have parallel origins related to sea-floor volcanism. Deposits at Al Masane and Dhahar-Al Hajrah are possibly in the same general stratigraphic interval. Characteristics and distribution of altered rocks at Kutam suggest that the observed structural control of mineralization may represent remobilization. Chemical characteristics of volcanic rocks at Al Masane and elsewhere, along with features such as zinc-copper-iron sulfide mineralization, rhyolite-basalt bimodality, and the quartz phenocryst-rich nature of the felsic rocks, are compatible with an unusually primitive tholeiitic island-arc origin for the strata and mineral deposits of the Habawnah mineral belt.

Open-File Report↗