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Geochemical patterns of arsenic-enriched ground water in fractured, crystalline bedrock, Northport, Maine, USA

High mean As concentrations of up to 26.6 ??mol/L (1990 ??g/L) occur in ground water collected from a fractured-bedrock system composed of sulfidic schist with granitic to dioritic intrusions. Sulfides in the bedrock are the primary source of the As in the ground water, but the presence of arsenopyrite in rock core retrieved from a borehole with As concentrations in the ground water barely above the detection limit of 2.0 ??mol/L, shows that there are complicating factors. Chemical analyses of water from 35 bedrock wells throughout a small watershed reveal spatial clustering of wells with high As concentrations. Stiff diagrams and box plots distinguish three distinct types; calcium-bicarbonate-dominated water with low As concentrations (CaHCO 3 type), sodium-bicarbonate-dominated water with moderately high As concentrations (NaHCO3 type), and calcium-bicarbonate-dominated water with very high As concentrations (High-As type). It is proposed that differences in recharge area and ground-water evolution, and possible bedrock composition difference are responsible for the chemical distinctions within the watershed. Lack of correlation of As concentrations with pH indicates that desorption of As is an insignificant control on As concentration. Correlations of As concentrations with Fe and redox parameters indicates that reductive dissolution of Fe(III) oxyhydroxides may play a role in the occurrence of high As concentrations in the NaHCO3 and High-As type water. The oxidation of sulfide minerals occurs within the ground-water system and is ultimately responsible for the existence of As in the ground water, but there is no correlation between As and SO4 concentrations, probably due to precipitation of Fe(III) oxyhydroxides and adsorption of As under oxidizing conditions. Crown Copyright ?? 2006 Published by Elsevier Ltd. All rights reserved.

Applied Geochemistry↗

Ground-water hydrology and simulated effects of development in the Milford area, an arid basin in southwestern Utah

A three-dimensional, finite-difference model was constructed to simulate ground-water flow in the Milford area. The purpose of the study was to evaluate present knowledge and concepts of the groundwater system, to analyze the ability of the model to represent past and current (1984) conditions, and to estimate the effects of various groundwater development alternatives. The alternative patterns of groundwater development might prove effective in capturing natural discharge from the basin-fill aquifer while limiting water-level declines. Water levels measured during this study indicate that ground water in the Milford area flows in a northwesterly direction through consolidated rocks in the northern San Francisco Mountains toward Sevier Lake. The revised potentiometric surface shows a large area for probable basin outflow, indicating that more water leaves the Milford area than the 8 acre-feet per year estimated previously. Simulations made to calibrate the model were able to approximate steady-state conditions for 1927, before ground-water development began, and transient conditions for 1950-82, during which groundwater withdrawal increased. Basin recharge from the consolidated rocks and basin outflow were calculated during the calibration process. Transient simulations using constant and variable recharge from surface water were made to test effects of large flows in the Beaver River. Simulations were made to project water-level declines over a 37- year period (1983-2020) using the present pumping distribution. Ground-water withdrawals were simulated at 1, 1.5, and 2 times the 1979-82 average rate. The concepts of "sustained" yield, ground-water mining, and the capture of natural discharge were tested using several hypothetical pumping distributions over a 600-year simulation period. Simulations using concentrated pumping centers were the least efficient at capturing natural discharge and produced the largest water-level declines. Simulations using strategically placed ground-water withdrawals in the discharge area were the most efficient at eliminating natural discharge with small water-level declines.

Utah↗

Trend analysis of ground-water levels and spring discharge in the Yucca Mountain Region, Nevada and California, 1960-2000

Ground-water level and discharge data from 1960 to 2000 were analyzed for the Yucca Mountain region of southern Nevada and eastern California. Included were water-level data from 37 wells and a fissure (Devils Hole) and discharge data from five springs and from a flowing well. Data were evaluated for variability and for upward, downward, or cyclic trends with an emphasis on the period 1992-2000. Potential factors causing trends in water levels and discharge include ground-water withdrawal, infiltration of precipitation, earthquakes, evapotranspiration, barometric pressure, and earth tides. Statistically significant trends in ground-water levels or spring discharge from 1992 to 2000 were upward at 12 water-level sites and downward at 14 water-level sites and 1 spring-discharge site. In general, the magnitude of the change in water level from 1992 to 2000 was small (less than 2 feet), except where influenced by pumping or local effects such as possible equilibration from well construction or diversion of nearby surface water. Seasonal trends are superimposed on some of the long-term (1992-2000) trends in water levels and discharge. Factors causing seasonal trends include barometric pressure, evapotranspiration, and pumping. The magnitude of seasonal change in water level can vary from as little as 0.05 foot in regional aquifers to greater than 5 feet in monitoring wells near large supply wells in the Amargosa Farms area. Three major episodes of earthquake activity affected water levels in wells in the Yucca Mountain region between 1992 and 2000: the Landers/Little Skull Mountain, Northridge, and Hector Mine earthquakes. The Landers/Little Skull Mountain earthquakes, in June 1992, had the largest observed effect on water levels and on discharge during the study period. Monthly measurements of wells in the study network show that earthquakes affected water levels from a few tenths of a foot to 3.5 feet. In the Ash Meadows area, water levels remained relatively stable from 1992 to 2000, with some water levels showing small rising trends and some declining slightly. Possible reasons for water-level fluctuations at sites AD-6 (Tracer Well 3), AM-5 (Devils Hole Well), and AM-4 (Devils Hole) from 1960 to 2000 include climate change, local and regional ground-water withdrawals, and tectonic activity. In Jackass Flats, water levels from 1992 to 2000 in six wells adjacent to Fortymile Wash displayed either small upward trends or no upward or downward trend. Comparison of trends in water levels from 1983 to 2000 for these six wells shows good correlations between all wells and suggests a common mechanism controlling water levels in the area. Of the likely controls on the system--precipitation or pumping in Jackass Flats--precipitation appears to be the predominant factor controlling water levels near Fortymile Wash. Water levels in the heavily pumped Amargosa Farms area declined from about 10 to 30 feet from 1964 to 2000. Water-level declines accelerated beginning in the early 1990's as pumping rates increased substantially. Pumping in the Amargosa Farms area may affect water levels in some wells as far away as 5-14 miles. The water level at site DV-3 (Travertine Point 1 Well) and discharge at site DV-2 (Navel Spring), both in the Death Valley hydrographic area, had downward trends from 1992 to 2000. The cause of these downward trends may be linked to earthquakes, pumping in the Amargosa Farms area, or both.

Water-Resources Investigations Report↗

Chlorofluorocarbons, sulfur hexafluoride, and dissolved permanent gases in ground water from selected sites in and near the Idaho National Engineering and Environmental Laboratory, Idaho, 1994-97

From July 1994 through May 1997, the U.S. Geological Survey in cooperation with the Department of Energy, sampled 86 wells completed in the Snake River Plain aquifer at and near the Idaho N ationa1 Engineering and Environmental Laboratory (INEEL). The wells were sampled for a variety of constituents including one- and two-carbon halocarbons. Concentrations of dichlorodifluoromethane (CFC-12), trichlorofluoromethane (CFC-11) and trichlorotrifluororoethane (CFC-113) were determined. The samples for halocarbon analysis were collected in 62-milliliter flame sealed borosilicate glass ampoules in the field. The data will be used to evaluate the ages of ground waters at INEEL. The ages of the ground water will be used to determine recharge rates, residence time, and travel time of water in the Snake River Plain aquifer in and near INEEL. The chromatograms of 139 ground waters are presented showing a large number of halomethanes, haloethanes, and haloethenes present in the ground waters underlying the INEEL. The chromatograms can be used to qualitatively evaluate a large number of contaminants at parts per trillion to parts per billion concentrations. The data can be used to study temporal and spatial distribution of contaminants in the Snake River Plain aquifer. Representative compressed chromatograms for all ground waters sampled in this study are available on two 3.5-inch high density computer disks. The data and the program required to decompress the data can be obtained from the U.S. Geological Survey office at Idaho Falls, Idaho. Sulfur hexafluoride (SF6) concentrations were measured in selected wells to determine the feasibility of using this environmental tracer as an age dating tool of ground water. Concentrations of dissolved nitrogen, argon, carbon dioxide, oxygen, and methane were measured in 79 ground waters. Concentrations of dissolved permanent gases are tabulated and will be used to evaluate the temperature of recharge of ground water in and near the INEEL.

Idaho↗

Hydrogeology and ground-water quality of glacial-drift aquifers, Leech Lake Indian Reservation, north-central Minnesota

Among the duties of the water managers of the Leech Lake Indian Reservation in north-central Minnesota are the development and protection of the water resources of the Reservation. The U.S. Geological Survey, in cooperation with the Leech Lake Indian Reservation Business Committee, conducted a three and one half-year study (1988-91) of the ground-water resources of the Leech Lake Indian Reservation. The objectives of this study were to describe the availability and quality of ground water contained in glacial-drift aquifers underlying the Reservation. Aquifers and confining units are present throughout the entire thickness of the glacial drift in the study area, which includes the Leech Lake Indian Reservation and adjacent parts of Beltrami, Hubbard, Itasca, and Cass Counties in north-central Minnesota, an area of approximately 2,145 square miles. An unconfined aquifer underlies most of the central and north-central parts of the study area. The saturated thickness of the aquifer ranges from 0 to about 105 feet. Horizontal hydraulic conductivity, estimated from 19 slug tests, ranges from 0.6 to 31 feet per day. The transmissivity of the aquifer ranges from 19 to more than 20,000 feet squared per day and is greatest in an area from west of Cass Lake to Lake Winnibigoshish. Theoretical maximum well yields range from less than 10 to about 2,000 gallons per minute. The unconfined and uppermost confined aquifers are physically and hydraulically separated by a fine-grained confining unit, consisting of till or lake deposits, that ranges in thickness from 3 to 254 feet. The thickness of the uppermost confined aquifer ranges from 5 to about 53 feet. On the basis of specific-capacity data, the transmissivity of the aquifer ranges from less than 100 feet squared per day in the northeastern and southeastern parts of the study area to about 21,000 feet squared per day near Cass Lake. Theoretical maximum well yields range from less than 10 to about 2,600 gallons per minute. Recharge to the ground-water system is predominantly from precipitation that infiltrates to the saturated zone. An analysis of four hydrographs for observation wells screened in the unconfined aquifer indicated spring recharge amounts during 1989 of 1-4 inches. Discharge from the ground-water system occurs by leakage to streams, lakes, and wetlands, evapotranspiration, withdrawals by wells, and underflow to the southeast within the Mississippi River Valley. Streamflow measurements indicate that ground-water discharge to the Mississippi River is greater in the western part of the study area between Cass Lake and Lake Winnibigoshish than in the eastern part downstream from Lake Winnibigoshish. The general regional direction of ground-water flow in the unconfined and uppermost confined aquifers is to the east and southeast. Ground-water flow is also toward the Mississippi River and the three large lakes in the study area, Lake Winnibigoshish and Cass and Leech Lakes. Water moves through the ground-water system predominantly horizontally in the aquifers, whereas vertical components of flow are significant in confining units. Downward leakage of water occurs in highland areas where ground water flows downward from overlying till to the uppermost confined aquifer. Water moves vertically upward from deep to shallow aquifers in areas of regional discharge, the Mississippi River, Cass Lake, Lake Winnibigoshish. and Leech Lake. Waters from both the unconfined and uppermost confined aquifers generally are suitable for domestic consumption, crop irrigation, and most other uses. Concentrations of iron and manganese in water from both aquifers frequently exceed levels that may impart an undesirable taste or odor to water. Calcium and bicarbonate are the predominant ions in water from both the unconfined and uppermost confined aquifers. Water from both the unconfined and uppermost confined aquifers is hard to very hard, averaging 187 and 247 milligrams per liter as calcium carbonate, respectively. Differences in the mean concentrations of constituents in waters from the unconfined and uppermost confined aquifers vary. The mean concentrations of chloride, manganese, dissolved organic carbon, sulfate, and dissolved iron were greater for water from the unconfined aquifer than for water from the uppermost confined aquifer. Conversely, the mean concentrations of calcium, potassium, silica, sodium, fluoride, and boron were greater for water from the uppermost confined aquifer than for water from the unconfined aquifer. These higher concentrations of naturally occurring constituents in waters from the uppermost confined aquifer may occur because of the longer flow paths and longer residence times of water in the uppermost confined aquifer as compared to the unconfined aquifer. Nutrients include nitrogen and phosphorus species. The mean concentrations of dissolved nitrogen (NO 2 + NO 3 , dissolved) and total phosphorus were about 5 and 1.5 times greater for water from the unconfined aquifer than for water from the uppermost confined aquifer, respectively. None of the water samples had concentrations of dissolved nitrogen greater than the maximum contaminant level established by the U.S. Environmental Protection Agency (10 milligrams per liter) and only one water sample had a concentration greater than 3 milligrams per liter. Water collected from wells completed in the unconfined aquifer in residential and recreational land-use areas had concentrations of arsenic, cadmium, chromium, copper, lead, mercury, and cyanide equal to or less than 6 micrograms per liter. Concentrations of organic-acid herbicides in water from three wells screened in the unconfined aquifer in managed-forest land-use areas were all below detection levels. Concentrations of U.S. Environmental Protection Agency priority pollutants in water from three wells screened in the unconfined aquifer and from one well screened in the uppermost confined aquifer were also all below detection levels.

Minnesota↗

Ground-water-flow conditions within a bottomland hardwood wetland, eastern Arkansas

Water levels were measured monthly at 9 staff gages and 35 wells along two transects within the Black Swamp bottomland hardwood wetland and perpendicular to the Cache River in eastern Arkansas from December 1989 to September 1992 in order to (1) describe the ground-water-flow conditions at locations within a bottomland hardwood wetland and (2) determine the relation between the frequency of different ground-water-flow conditions and physical characteristics within the wetland. Three ground-water-flow conditions predominated at various times in the Black Swamp: (1) discharge of water from the alluvial aquifer to the wetland, (2) recharge of water from the wetland into the alluvial aquifer, and (3) flow of water from the wetland into the alluvial aquifer and then to the nearby Cache River (local flow). Analyses of hydraulic head differences between surface and ground water indicate that discharge occurred 31% of the measurement times at both transects. Recharge occurred 39% of the measurement times and tended to occur more often at locations that are far from the Cache River and that overlie low ground-water levels in the lower part of the alluvial aquifer. Local ground-water flow occurred 28% of the measurement times and tended to occur more often at locations close to the Cache River. Ground-water pumpage results in water-level declines in the lower part of the alluvial aquifer near the Black Swamp wetland. When compared with an area not affected by pumping, these lower ground-water levels increased the frequency of recharge of Black Swamp water into the alluvial aquifer by nearly a factor of 7, decreased the frequency of local ground-water flow to the Cache River to less than half, and decreased the frequency of discharge by about 22%.

Arkansas↗

Ground water in the San Juan metropolitan area, Puerto Rico

Ground water in the San Juan, Puerto Rico, area has played a declining role in water supply since the completion of the Lofza reservoir project in the early 1950's. Ground-water potential is limited because of the small size of the aquifers and susceptibility to seawater intrusion. Of the 30 million gallons per day about half is being used. Two water-bearing zones are present: an artesian aquifer, composed of the San Sebastian Formation and the lower Cibao Formation that yields an average of 244 gallons per minute to wells; and, a water-table aquifer composed of the upper Cibao Formation and the Aguada and Aymamon Limestones that yields an average of 515 gallons per minute to wells. Ground water is less mineralized inland and in the artesian aquifer. Mean concentrations of dissolved solids are 363 milligrams per liter for the artesian aquifer and 525 milligrams per liter for the water-table aquifer. (Woodard-USGS)

Water-Resources Investigations Report↗

Nitrate retention in riparian ground water at natural and elevated nitrate levels in North Central Minnesota

The relationship between local ground water flows and NO3− transport to the channel was examined in three well transects from a natural, wooded riparian zone adjacent to the Shingobee River, MN. The hillslope ground water originated as recharge from intermittently grazed pasture up slope of the site. In the hillslope transect perpendicular to the stream, ground water NO3− concentrations decreased from ∼3 mg N L−1 beneath the ridge (80 m from the channel) to 0.01 to 1.0 mg N L−1 at wells 1 to 3 m from the channel. The Cl− concentrations and NO3/Cl ratios decreased toward the channel indicating NO3− dilution and biotic retention. In the bankside well transect parallel to the stream, two distinct ground water environments were observed: an alluvial environment upstream of a relict beaver dam influenced by stream water and a hillslope environment downstream of the relict beaver dam. Nitrate was elevated to levels representative of agricultural runoff in a third well transect located ∼5 m from the stream to assess the effectiveness of the riparian zone as a NO3− sink. Subsurface NO3− injections revealed transport of up to 15 mg N L−1 was nearly conservative in the alluvial riparian environment. Addition of glucose stimulated dissolved oxygen uptake and promoted NO3− retention under both background and elevated NO3− levels in summer and winter. Disappearance of added NO3− was followed by transient NO2− formation and, in the presence of C2H2, by N2O formation, demonstrating potential denitrification. Under current land use, most NO3− associated with local ground water is biotically retained or diluted before reaching the channel. However, elevating NO3− levels through agricultural cultivation would likely result in increased NO3− transport to the channel.

Minnesota↗

Ground-water quality in Bannock, Bear Lake, Caribou, and part of Power counties, southeastern Idaho

This report provides information about the current quality of ground waters in southeastern Idaho and discusses the natural and manmade environmental controls on that quality. This information will be useful in planning and monitoring the development and use of the ground-water resources of southeastern Idaho. The southeastern corner of Idaho, as described in this report, encompasses an area of about 4,000 mil in Bannock, Bear Lake, Caribou, and part of Power Counties. The popu- lation of the area in 1975, based on best estimates by the Idaho Division of Budget, Policy Planning, and Coordination (1976) was 75,200. About 80 percent of the population is in and near the city of Pocatello, which is the second largest population center in the State. Pocatello's economy depends largely on manufacturing and industrial processing, which includes chemicalfertilizer plants. The econ- omy in the rural areas depends largely on agriculture--both dry and irrigated farming are practiced. Mining is important and expected to dominate the economy in the eastcentral part of the area in the future. Natural resources include phosphate ore, which makes up about 35 percent of the U.S. reserves (U.S. Department of Interior and U.S. Department of Agriculture, 1977); ground water, which mostly underlies the several intermontane valleys that dissect the area; and hot springs, which indicate that geothermal energy sources may underlie part of the area. Also, current (1978) speculation is that petroleum reserves may be present in the vicinity of Bear Lake. Development of more sprink- ler-irrigated lands, increases in population, and growth of phosphate mining are expected to place stress on the ground-water resources, both in quality and quantity. The purpose of this report is to present the results of a study whose primary objectives were (1) to provide current waterquality data representative of the water in several different aquifers (water- bearing formations) in the study area, and (2) to relate these data to natural and manmade environmental controls. The wells sampled during this study establish a quasi-network, which could be resampled in the future to document and analyze changes (if any) in ground-water quality. Based on this information, planners and water managers could better understand the causeand-effect relations controlling water quality and could better manage land and water-resource development. The report is designed for ease of reading and presentation. It uses maps, tables, and abbreviated text to describe geology, hydrology, and ground-water quality and how they are interrelated. Some practical ways for improving water quality are discussed for the benefit of individual water users. The field data collected in making the study are contained in the Data Section of this report. The authors gratefully acknowledge the many individual well owners, municipal officials, and private industries that provided well information and allowed access to their properties and collection of water samples. Without their help, this work could not have been done. Water samples were collected at 103 well sites. Waterlevel measurements were made at 98 of these sites during July, August, and September of 1976. This study was made by the U.S. Geological Survey in cooperation with the Idaho Department of Water Resources. A similar study is being made (1978) in north Idaho. Other studies are planned, specifically to obtain ground-water-quality data in areas where land and water-resource development is expected or accelerating.

Idaho↗

Quality of ground water in agricultural areas of the San Luis Valley, south-central Colorado

The quality of ground water in the principal agricultural areas of the San Luis Valley, south-central Colorado was evaluated using chemical analyses of water collected from 57 wells completed in the unconfined aquifer and from 25 wells completed in the confined aquifer. Ground water in both aquifers generally contains dissolved-solids concentrations of less than 500 milligrams per liter. In most areas, calcium is the principal cation in the ground water. Nitrite plus nitrate concentrations expressed as nitrogen, are generally less than 1 milligram per liter. However, the quality of ground water in certain areas may pose health and agricultural hazards. Water in the unconfined aquifer near Center contains high nitrite plus nitrate as nitrogen concentrations. The highest measured concentration in this area was 33 milligrams per liter. Water containing more than 1 milligram per liter of nitrite as nitrogen, or 10 milligrams per liter nitrate, as nitrogen, poses a potential health hazard for infants and should not be used for drinking. In addition, dissolved-solids concentration in the ground water in some areas is greater than 500 milligrams per liter and, if used for irrigation may reduce crop yields. (USGS)

Water-Resources Investigations Report↗

Ground‐water for air‐conditioning on Long Island, New York

During the last five years ground‐water has been more and more extensively used for air‐conditioning on Long Island, New York. The wide‐spread occurrence of highly permeable water‐bearing material and the relatively small cost of installation and operation of a ground‐water, air‐conditioning system has resulted in many such installations by theaters, restaurants, stores, and other establishments. Many companies likewise have taken advantage of these favorable factors and are utilizing low‐temperature ground‐water for cooling purposes in the manufacture of ice. This new use of ground‐water has considerably increased the draft in the western end of Long Island where there had already been so much over‐development that the watertable was below sea‐level in an area of more than 40 square miles. In 1933 the State Legislature, recognizing the seriousness of this over‐development, passed a law requiring that the approval, of the State Water Power and Control Commission be secured before constructing a well with a capacity greater than 100,000 gallons a day. Since the passage of the law the‐policy of the Commission has been to require water pumped from new‐wells for cooling purposes to be returned to the ground. This requirement has resulted in the construction of many recharge‐wells (locally called diffusion‐wells) through which the warm water is returned to the ground.

New York↗

Ground-water age and atmospheric tracers: Simulation studies and analysis of field data from the Mirror Lake site, New Hampshire

The use of environmental tracers in characterization of ground-water systems is investigated through mathematical modeling of ground-water age and atmospheric tracer transport, and by a field study at the Mirror Lake site, New Hampshire. Theory is presented for modeling ground-water age using the advective-dispersive transport equation. The transport equation includes a zero-order source of unit strength, corresponding to the rate of aging, and can accommodate matrix diffusion and other exchange processes. The effect of temperature fluctuations and layered soils on transport of atmospheric gases to the water table is investigated using a one-dimensional numerical model of chlorofluorocarbon (CFC-11) transport. The nonlinear relation between temperature and Henry's Law coefficient (reflecting air/water phase partitioning) can cause the apparent recharge temperature to be elevated above the annual mean temperature where the water table is shallow. In addition, fine-grained soils can isolate the air phase in the unsaturated zone from the atmosphere. At the USGS' Mirror Lake, New Hampshire fractured-rock research site CFC concentrations near the water table are depleted where dissolved oxygen is low. CFC-11 and CFC-113 are completely absent under anaerobic conditions, while CFC-12 is as low as one-third of modern concentrations. Anaerobic biodegradation apparently consumes CFC's near the water table at this site. One area of active degradation appears to be associated with streamflow loss to ground water. Soil gas concentrations are generally close to atmospheric levels, although some spatial correlation is observed between depleted concentrations of CFC-11 and CFC-113 in soil gas and water-table samples. Results of unsaturated-zone monitoring indicate that recharge occurs throughout the year in the watershed, even during summer evapotranspiration periods, and that seasonal temperature fluctuations occur as much as 5 meters below land surface. Application of ground-water age and CFC-11 transport models to the large-scale ground-water system at Mirror Lake illustrates the similarities between age and chemical transport. Generally, bedrock porosities required to match observed apparent ages from CFC concentrations are high relative to porosities measured on cores. Although matrix diffusion has no effect on steady-state age, it can significantly reduce CFC concentrations in fractured rock in which the effective porosity is low.

New Hampshire↗

Geohydrology and quality of ground water in unconsolidated aquifers near South Bend, Indiana

Introduction The water supply for the City of South Bend, Indiana, and much of surrounding St. Joseph County is provided by 36 municipal and community well fields. Some of these well fields are located near known or potential sources of ground-water contamination that could affect ground-water supplies in the near future. As population and industry grow, it will be necessary to find additional sources of water and determine their quantity and quality. Geohydrologic and water-quality data are available to identify areas for developing additional ground-water supplies, but these data have not been compiled into one source accessible to area water-resource managers. This report presents a compilation of these geohydrologic and water-quality data for the ground-water system in and near South Bend that can be used to identify potentially favorable areas for developing additional ground-water supplies for municipal use. The data were compiled by the U.S. Geological Survey, in cooperation with the South Bend Water Works, for a study area of approximately 535 square miles that includes all of St. Joseph County and the eastern part of La Porte County. A map format has been used to facilitate comparison between geohydrologic and water-quality information. Previously published geologic maps and cross sections describe the geologic setting and aquifer deposits of the study area, the hydrogeology of northeastern St. Joseph County, and the ground-water quality of northeastern St. Joseph County. Beaty (1990) and Clendenon and Beaty (1987) produced water-resource-availability reports for the St. Joseph and Kankakee River Basins.

Indiana↗

A ground-water reconnaissance of the Republic of Ghana, with a description of geohydrologic provinces

This report gives a general summary of the availability and use of ground water and describes the occurrence of ground water in five major geohydrologic provinces lying in the eight administrative regions of Ghana. The identification and delineation of the geohydrologic provinces are based on their distinctive characteristics with respect to the occurrence and availability of ground water. The Precambrian province occupies the southern, western, and northern parts of Ghana and is underlain largely by intrusive crystalline and metasedimentary rocks. The Voltaian province includes that part of the Voltaian sedimentary basin in central Ghana and is underlain chiefly by consolidated sandstone, mudstone, and shale. Narrow discontinuous bands of consolidated Devonian and Jurassic sedimentary rocks near the coast constitute the Coastal Block Fault province. The Coastal Plain province includes semiconsolidated to unconsolidated sediments of Cretaceous to Holocene age that underlie coastal plain areas in southwestern and southeastern Ghana. The Alluvial province includes the Quaternary alluvial deposits in the principal river valleys and on the delta of the Volta River. Because of the widespread distribution of crystalline and consolidated sedimentary rocks of low permeability in the Precambrian, Voltaian, and Coastal Block Fault provinces, it is difficult to develop large or event adequate groundwater supplies in much of Ghana. On the other hand, small (1 to 50 gallons per minute) supplies of water of usable quality are available from carefully sited boreholes in most parts of the country. Also, moderate (50 to 200 gpm) supplies of water are currently (1964) obtained from small-diameter screened boreholes tapping sand and limestone aquifers in the Coastal Plain province in southwestern and southeastern Ghana, but larger supplies could be obtained through properly constructed boreholes. In the Alluvial province, unconsolidated deposits in the larger stream valleys that are now largely undeveloped offer desirable locations for shallow vertical or horizontal wells, which can induce infiltration from streams and yield moderate to large water supplies. The principal factors that limit development of ground-water supplies in Ghana are (1) prevailing low permeability and water-yielding potential of the crystalline and consolidated sedimentary rocks that underlie most of the country, (2) highly mineralized ground water which appears to be widely distributed in the northern part of the Voltaian province, and (3) potential problems of salt-water encroachment in the Coastal Plain province in the Western Region and in the Keta area. On the other hand, weathering has increased porosity and has thus substantially increased the water-yielding potential of the crystalline and consolidated sedimentary rocks in much of central and northern Ghana. Also, with proper construction and development, much larger yields than those now (1964) prevalent could be obtained from boreholes tapping sand and limestone aquifers in the Coastal Plain province.

Water Supply Paper↗

Effects of present and projected ground-water withdrawals on the Twin Cities aquifer system, Minnesota

The Twin Cities aquifer system in Minnesota contains 5 aquifers and 4 confining units composed of 14 stratigraphic units. Bedrock aquifers consist of friable sandstones and highly fractured carbonate rocks; aquifers in the glacial drift consist of outwash and alluvium. From 1880 to 1980, groundwater withdrawals had caused long-term declines of water levels of as much as 90 feet in the Prairie du Chien-Jordan aquifer and 240 feet in the deeper Mount Simon-Hinckley aquifer--the two major sources of ground-water supplies in the area. A steady-state model of ground-water flow was used successfully to simulate the potentiometric surfaces of the aquifers during the 1970's. assuming a withdrawal rate of about 190 million gallons per day from the entire system. Projected changes in population and industrial development suggest that future ground-water withdrawals may increase from those for the 1970's. Steady-state model results indicate that the potentiometric surface of the Mount Simon-Hinckley aquifer would be lowered as much as 400 feet if pumpage from that aquifer were increased by 125 percent above 1980 ground-water withdrawal rates of about 200 million gallons per day. The potentiometric surface of the Prairie du Chien-Jordan aquifer also would be lowered as much as 400 feet if pumpage from that aquifer were increased by 200 percent above 1980 ground-water withdrawals of 160 million gallons per day. Given the projected distribution of future ground-water development, and the limitations inherent in simulating ground-water flow, the model results indicate that an approximate limit of ground-water availability in the Twin Cities Metropolitan Area, Minnesota, is from about 500 to 800 million gallons per day.

Minnesota↗

Three-dimensional hydrogeologic framework model for use with a steady-state numerical ground-water flow model of the Death Valley regional flow system, Nevada and California

The U.S. Geological Survey, in cooperation with the Department of Energy and other Federal, State, and local agencies, is evaluating the hydrogeologic characteristics of the Death Valley regional ground-water flow system. The ground-water flow system covers an area of about 100,000 square kilometers from latitude 35? to 38?15' North to longitude 115? to 118? West, with the flow system proper comprising about 45,000 square kilometers. The Death Valley regional ground-water flow system is one of the larger flow systems within the Southwestern United States and includes in its boundaries the Nevada Test Site, Yucca Mountain, and much of Death Valley. Part of this study includes the construction of a three-dimensional hydrogeologic framework model to serve as the foundation for the development of a steady-state regional ground-water flow model. The digital framework model provides a computer-based description of the geometry and composition of the hydrogeologic units that control regional flow. The framework model of the region was constructed by merging two previous framework models constructed for the Yucca Mountain Project and the Environmental Restoration Program Underground Test Area studies at the Nevada Test Site. The hydrologic characteristics of the region result from a currently arid climate and complex geology. Interbasinal regional ground-water flow occurs through a thick carbonate-rock sequence of Paleozoic age, a locally thick volcanic-rock sequence of Tertiary age, and basin-fill alluvium of Tertiary and Quaternary age. Throughout the system, deep and shallow ground-water flow may be controlled by extensive and pervasive regional and local faults and fractures. The framework model was constructed using data from several sources to define the geometry of the regional hydrogeologic units. These data sources include (1) a 1:250,000-scale hydrogeologic-map compilation of the region; (2) regional-scale geologic cross sections; (3) borehole information, and (4) gridded surfaces from a previous three-dimensional geologic model. In addition, digital elevation model data were used in conjunction with these data to define ground-surface altitudes. These data, properly oriented in three dimensions by using geographic information systems, were combined and gridded to produce the upper surfaces of the hydrogeologic units used in the flow model. The final geometry of the framework model is constructed as a volumetric model by incorporating the intersections of these gridded surfaces and by applying fault truncation rules to structural features from the geologic map and cross sections. The cells defining the geometry of the hydrogeologic framework model can be assigned several attributes such as lithology, hydrogeologic unit, thickness, and top and bottom altitudes.

Water-Resources Investigations Report↗

Ground-water quality in alluvial aquifers in the eastern Iowa basins, Iowa and Minnesota

The quality of shallow alluvial ground water that is used for domestic supplies in the Wapsipinicon, Cedar, Iowa, and Skunk River Basins (Eastern Iowa Basins) is described. Water samples from 32 domestic-supply wells were collected from June through July 1998. This study of ground-water quality in alluvial aquifers in the Eastern Iowa Basins is part of the U.S. Geological Survey's National Water-Quality Assessment Program. Calcium and bicarbonate were the dominant ions in solution, likely derived from the dissolution of carbonate minerals in the alluvial aquifer material. Concentrations of iron exceeded the U.S. Environmental Protection Agency Secondary Maximum Contaminant Level (300 micrograms per liter) for drinking water in 53 percent of the samples, and 50 percent of the samples exceeded the Secondary Maximum Contaminant Level for manganese (50 micrograms per liter). pH and alkalinity increased and sulfate concentrations decreased with increasing well depth. Nitrite plus nitrate nitrogen was detected in 53 percent of the samples and exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level of 10 milligrams per liter for drinking water in 13 percent of the samples. Nitrite plus nitrate nitrogen concentrations were negatively correlated with well depth and positively correlated with percentage of oxygen saturation. Ammonia plus organic nitrogen concentrations were positively correlated with well depth, and ratios of nitrite plus nitrate to ammonia were positively correlated with percentage of oxygen saturation. The majority of samples, 72 percent, contained water recharged since the early 1950's. The recharge date of water was earlier in deeper wells. Nitrite plus nitrate and total pesticide concentrations were greater in more recently recharged water. Eight pesticides and eight pesticide metabolites were detected in ground-water samples. Atrazine was the most commonly detected pesticide, and metolachlor ethanesulfonic acid was the most commonly detected metabolite. No pesticide detections exceeded U.S. Environmental Protection Agency drinking-water Maximum Contaminant Levels. The effects of land use on ground-water quality also were examined. There was a positive correlation between percentage of land used for soybean production and concentrations of metolachlor, metolachlor ethanesulfonic acid, and metolachlor oxanilic acid in ground-water samples. Data from this study and from previous studies in the Eastern Iowa Basins were compared statistically by well type (domestic, municipal, and monitoring wells). Well depths were significantly greater in domestic and municipal wells than in monitoring wells. pH, calcium, sulfate, chloride, and atrazine concentrations were significantly higher in municipal-well samples than in domestic-well samples. pH and sulfate concentrations were significantly higher in municipal-well samples than in monitoring-well samples. Ammonia was significantly higher in domestic-well samples than in monitoring-well samples, chloride was significantly higher in monitoring-well samples than in domestic-well samples, and fluoride was significantly higher in domestic-well samples than in municipal-well samples.

Iowa, Minnesota↗

Selected Ground-Water Data for Yucca Mountain Region, Southern Nevada and Eastern California, January-December 2004

The U.S. Geological Survey, in support of the U.S. Department of Energy, Office of Repository Development, collects, compiles, and summarizes hydrologic data in the Yucca Mountain region of southern Nevada and eastern California. These data are collected to allow assessments of ground-water resources during activities to determine the potential suitability or development of Yucca Mountain for storing high-level nuclear waste. Data on ground-water levels at 35 boreholes and 1 fissure (Devils Hole), ground-water discharge at 5 springs, both ground-water levels and discharge at 1 flowing borehole, and total reported ground-water withdrawals within Crater Flat, Jackass Flats, Mercury Valley, and the Amargosa Desert are tabulated from January through December 2004. Also tabulated are ground-water levels, discharges, and withdrawals collected by other agencies (or collected as part of other programs) and data revised from those previously published at monitoring sites. Historical data on water levels, discharges, and withdrawals are presented graphically to indicate variations through time. A statistical summary of ground-water levels at seven boreholes in Jackass Flats is presented for the period 1992-2004 to indicate potential effects of ground-water withdrawals associated with U.S. Department of Energy activities near Yucca Mountain. The statistical summary includes the annual number of measurements, maximum, minimum, and median water-level altitudes, and average deviation of measured water-level altitudes compared to the 1992-93 baseline period. At six boreholes in Jackass Flats, median water levels for 2004 were slightly higher (0.3-2.7 feet) than their median water levels for 1992-93. At one borehole in Jackass Flats, median water level for 2004 equaled the median water level for 1992-93.

Open-File Report↗