Ground-water age and atmospheric tracers: Simulation studies and analysis of field data from the Mirror Lake site, New Hampshire

Daniel J. Goode

Home/Archive/USGS

USGS · 70189544

Ground-water age and atmospheric tracers: Simulation studies and analysis of field data from the Mirror Lake site, New Hampshire

Daniel J. Goode

View original source ↗Export metadata ↓

Abstract

The use of environmental tracers in characterization of ground-water systems is investigated through mathematical modeling of ground-water age and atmospheric tracer transport, and by a field study at the Mirror Lake site, New Hampshire. Theory is presented for modeling ground-water age using the advective-dispersive transport equation. The transport equation includes a zero-order source of unit strength, corresponding to the rate of aging, and can accommodate matrix diffusion and other exchange processes. The effect of temperature fluctuations and layered soils on transport of atmospheric gases to the water table is investigated using a one-dimensional numerical model of chlorofluorocarbon (CFC-11) transport. The nonlinear relation between temperature and Henry's Law coefficient (reflecting air/water phase partitioning) can cause the apparent recharge temperature to be elevated above the annual mean temperature where the water table is shallow. In addition, fine-grained soils can isolate the air phase in the unsaturated zone from the atmosphere. At the USGS' Mirror Lake, New Hampshire fractured-rock research site CFC concentrations near the water table are depleted where dissolved oxygen is low. CFC-11 and CFC-113 are completely absent under anaerobic conditions, while CFC-12 is as low as one-third of modern concentrations. Anaerobic biodegradation apparently consumes CFC's near the water table at this site. One area of active degradation appears to be associated with streamflow loss to ground water. Soil gas concentrations are generally close to atmospheric levels, although some spatial correlation is observed between depleted concentrations of CFC-11 and CFC-113 in soil gas and water-table samples. Results of unsaturated-zone monitoring indicate that recharge occurs throughout the year in the watershed, even during summer evapotranspiration periods, and that seasonal temperature fluctuations occur as much as 5 meters below land surface. Application of ground-water age and CFC-11 transport models to the large-scale ground-water system at Mirror Lake illustrates the similarities between age and chemical transport. Generally, bedrock porosities required to match observed apparent ages from CFC concentrations are high relative to porosities measured on cores. Although matrix diffusion has no effect on steady-state age, it can significantly reduce CFC concentrations in fractured rock in which the effective porosity is low.

Explore related subjects

Thesis

Source-reported bounding extent: 43.9407373431014° to 43.94684008272965° latitude; -71.69662714004517° to -71.68843030929565° longitude. This indicates report coverage, not an exact sampling location. View area on OpenStreetMap.

Keep this discovery

Explore connections, maps & timelines

BibTeX RIS

Daniel J. Goode. 1998. Ground-water age and atmospheric tracers: Simulation studies and analysis of field data from the Mirror Lake site, New Hampshire. https://pubs.usgs.gov/publication/70189544

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

USGS2021

Freshwater cyanotoxin mixtures in recurring cyanobacterial blooms in Voyageurs National Park

Algal and cyanobacterial blooms can foul water systems, inhibit recreation, and produce cyanotoxins, which can be toxic to humans, domestic animals, and wildlife. Blooms that recur yearly present a special challenge, in that chronic effects of most cyanotoxins are unknown. To better understand cyanotoxin timing, possible environmental triggers, and inter-relations among taxa and toxins in bloom communities, recurring cyanobacterial blooms were investigated at three recreational sites in Kabetogama Lake in Voyageurs National Park from 2016-2019. Results indicated that peak neurotoxin concentrations occurred before peak microcystin concentrations and that toxin-forming cyanobacteria were present before visible blooms, which is a serious human health concern. Two cyanotoxin mixture models (MIX) and two microcystin (MC) models were developed using near-real-time environmental variables and additional comprehensive variables based on laboratory analyses. Comprehensive models explained more variability than the environmental models and neither MIX model was a better fit than the MC models. However, the MIX models produced no false negatives, indicating that all observations above human-health regulatory guidelines were simulated by the MIX models. The results show that a model based on a cyanotoxin mixture is more protective of human health than a model based on microcystin alone. In 2019, 7 of 19 toxins were detected in various mixtures. The potential toxin producing cyanobacteria, Microcystis , was significantly correlated with microcystin-YR, while Pseudanabaena sp. and Synechococcus sp. were negatively correlated to several toxins. Jaccard and Sorenson indices indicated strong same-day similarities among the three bloom communities. Nitrogen-fixing cyanobacteria were present at every site, and when combined with internal loading of phosphorus, might explain similarities among sites, and why seasonal differences, even in samples from the same site, were stronger. Information from this dissertation adds to the body of work on recurring blooms and under-studied toxins and toxin mixtures, providing a better understanding of future research options for freshwater cyanotoxins in and outside of Voyageurs National Park.

Minnesota↗

USGS2017

The lethality of hot water and ozone to aquatic invasive species

The spread of Aquatic Invasive Species (AIS) between the Great Lakes and Mississippi River Basin by way of the Chicago Area Waterway System (CAWS) is a pressing concern to resource managers in the Midwest region. Augmenting this spread are watercrafts traveling through the CAWS locks and dams. AIS are able to attach to boat hulls, equipment, or are present in the surrounding water during lock transfers. It has been proposed that chemically treating boats during lock transfers would be an effective way to reduce the spread of AIS. Of a range of treatments identified as candidates to do this, hot water and dissolved ozone ranked high as effective treatments causing the least amount of environmental impact. This study assessed the lethality of hot water and dissolved ozone, separately and in combination, on select AIS in a laboratory setting. Species were exposed to water temperatures ranging from 18 to 50°C, ozone concentrations ranging from 0 to 920 ORP (Oxidation-Reduction Potential), and exposure durations ranging from 10 to 60 min to find treatments capable of inducing 100% mortality. Results indicated that water at 45°C achieved 100% mortality in all species tested with a 10 min exposure. Ozone concentrations induced significant mortality to all species tested, particularly when combined with elevated temperatures.

Thesis↗

USGS2015

Soil ecology of a rock outcrop ecosystem: Abiotic stresses, soil respiration, and microbial community profiles in limestone cedar glades

Limestone cedar glades are a type of rock outcrop ecosystem characterized by shallow soil and extreme hydrologic conditions—seasonally ranging from xeric to saturated—that support a number of plant species of conservation concern. Although a rich botanical literature exists on cedar glades, soil biochemical processes and the ecology of soil microbial communities in limestone cedar glades have largely been ignored. This investigation documents the abiotic stress regime of this ecosystem (shallow soil, extreme hydrologic fluctuations and seasonally high soil surface temperatures) as well as soil physical and chemical characteristics, and relates both types of information to ecological structures and functions including vegetation, soil respiration, and soil microbial community metabolic profiles and diversity. Methods used in this investigation include field observations and measurements of soil physical and chemical properties and processes, laboratory analyses, and microbiological assays of soil samples. Stress factors quantified by this research include shallow soil (depth to bedrock ranging from 2.4 to 22.6 cm), volumetric soil water content levels seasonally ranging from xeric (below 5%) to saturated (above 50%), and seasonally extreme ground-surface temperatures (above 48°C). Findings from this research indicate that spatial and temporal heterogeneity exists in limestone cedar glades in terms of abiotic stress factors and soil physical and chemical properties. Several such soil properties (e.g. soil depth, organic matter levels, pH, and particle size distribution) are spatially correlated. These soil properties were statistically related to ecological structures and functions such as vegetation patterns, soil respiration, the density of culturable heterotrophic microbes in soil and metabolic diversity of soil microbial community profiles. In general, zones within limestone cedar glades that had relatively shallow soil, alkaline pH, low levels of organic matter and high levels of silt also tended to have depressed rates of soil respiration and reduced densities and metabolic diversity of culturable heterotrophic soil microbes. Additionally, seasonally-relevant stress factors including soil water content and temperatures at or near the soil surface were related to the same set of ecological structures and functions.

Tennessee↗