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Hydrologic and water-quality conditions in the Horse Creek basin, west-central Florida, October 1992-February 1995

A baseline study of the 241-square-mile Horse Creek basin was undertaken from October 1992 to February 1995 to assess the hydrologic and water-quality conditions of one of the last remaining undeveloped basins in west-central Florida. During the period of the study, much of the basin remained in a natural state, except for limited areas of cattle and citrus production and phosphate mining. Rainfall in 1993 and 1994 in the Horse Creek basin was 8 and 31 percent, respectively, above the 30-year long-term average. The lowest and highest maximum instantaneous peak discharge of the six daily discharge stations occurred at the Buzzard Roost Branch and the Horse Creek near Arcadia stations with 185 to 4,180 cubic feet per second, respectively. The Horse Creek near Arcadia station had the lowest number of no-flow days with zero days and the Brushy Creek station had the highest number with 113 days. During the study, the West Fork Horse Creek subbasin had the highest daily mean discharge per square mile with 30.6 cubic feet per second per square mile, and the largest runoff coefficient of 43.7 percent. The Buzzard Roost Branch subbasin had the lowest daily mean discharge per square mile with 5.05 cubic feet per second per square mile, and Brushy Creek and Brandy Branch shared the lowest runoff coefficient of 0.6 percent. Brandy Branch had the highest monthly mean runoff in both 1993 and 1994 with 11.48 and 19.28 inches, respectively. During the high-baseflow seepage run, seepage gains were 8.87 cubic feet per second along the 43-mile Horse Creek channel. However, during the low-baseflow seepage run, seepage losses were 0.88 cubic foot per second. Three methods were used to estimate average annual ground-water recharge in the Horse Creek basin: (1) well hydrograph, (2) chloride mass balance, and (3) streamflow hydrograph. Estimated average annual recharge using these three methods ranged from 3.6 to 8.7 inches. The high percentage of carbonate plus bicarbonate analyzed at the Carlton surficial aquifer well could indicate an upward ground-water flow from the underlying intermediate aquifer system. Based on constituent concentrations in water samples from the six daily discharge stations, concentrations generally are lower in the upper three subbasins, West Fork Horse Creek, Upper Horse Creek, and Brushy Creek than in the lower three subbasins. Typically, concentrations were highest for major ions at Buzzard Roost Branch and nutrients at Brushy Creek.

Florida

Geochemical processes related to mined, milled, or natural metal deposits in a rapidly changing global environment

The demand for metals and raw materials, such as nickel and copper, has been projected to expand in the coming decades, driven by the global energy transition, the need for green technologies, and expanding infrastructure. Consequently, the increasing extraction and production of mining waste can have adverse impacts on surrounding environments and human health. The aim of this thematic collection is to fill critical knowledge gaps in the present-day cycles of metal(loid)s from source to larger sinks, and the effect of environmental management, anthropogenic development, and climate change. Altogether, the studies have been conducted in different natural settings around the world and comprise investigations in laterites, a soil-medicinal plant system, watersheds, and banded iron formations, among others. The geochemical applications in tracing mineralization, its secondary products, and/or potential impact on the immediate environment are highly diverse with applied tools ranging from isotope tracers to major and trace element systematics. Particularly the use of rare earth elements, their patterns and anomalies are methods employed by several studies in this collection. We summarize the findings to offer a potential future direction for the use of geochemical tracing techniques in resource exploration in the context of climate change and environmental challenges.

Geochemistry: Exploration, Environment, Analysis

Assessing nonpoint-source uranium pollution in an irrigated stream-aquifer system

Uranium (U) in rocks and soils of arid and semi-arid environments can be mobilized by irrigation and fertilization, posing environmental and health risks. Elevated U, along with selenium (Se) and nitrate (NO 3 ) co-constituents, necessitates careful monitoring and management. We developed a distributed-parameter numerical model to assess U pollution in an irrigated stream-aquifer system, applying it to a 552 km 2 region in Colorado's Lower Arkansas River Valley (LARV) over 14 years. A MODFLOW model, describing groundwater and stream flow, was coupled with an RT3D-OTIS model to portray reactive U transport. Calibration using the PESTPP-iES iterative ensemble smoother (iES) software indicated good agreement with observed U concentrations. The model revealed substantial and variable U levels across the LARV, highlighting potential hotspots and possible contributing factors, such as geological composition of the bedrock and near-surface shale and aquifer sediments derived from them, irrigation practices, and riparian landscape. U levels exceed the chronic standard (85th percentile = 30 μg/L, set by the US Environmental Protection Agency), which is the permissible regulatory threshold, in groundwater across 44 % of the region and along the river by an average factor of 2.9. Simulated average U concentrations in the non-riparian aquifer and river are 124 μg/L and 60 μg/L, respectively, compared with 112 μg/L and 62 μg/L for measured values. The average 85th percentile U concentration is 222 μg/L in the aquifer and 82 μg/L in the river. Average simulated U mass loading to the river is 0.17 kg/day per km, compared to an estimated 0.23 kg/day per km. Findings provide a baseline for comparing future simulated outcomes of alternative best management practices (BMPs) for U pollution mitigation and offer a methodology applicable to other irrigated regions.

Colorado

Modeling byproduct and coproduct mine production and mineral substitution using multidimensional supply curves: Application to the Cu-Co-Ni system and beyond

Rapid demand growth is expected for many metals used in the energy transition. Many of these metals are byproducts of other commodities. Byproduct production’s price response is tied to host mineral economics, complicating its supply dynamics. Moreover, many of these metals are used in applications where the material properties desired are difficult to substitute; effectively, limiting how quickly demand can adapt to changes in commodity price. Previous work has demonstrated the interconnectivity of jointly produced mineral commodities from the supply side, where the copper–cobalt–nickel system was used and demand was assumed independent across commodities. Studies to understand byproduct-coproduct market interconnectivity on the demand side are limited, while studies on the interconnectivity of supply and demand simultaneously are even more so. We propose a modification to the multicommodity supply curve method to enable inter-commodity effects on demand simultaneous with supply. In batteries, high cobaltprices may push consumers to transition to high-nickel chemistries, causing the nickel demand surface to decrease with nickel price but increase with cobaltprice, creating a two-dimensional demand surface. Below cross-price elasticities of 0.05, inter-commodity effects were found to be negligible, potentially permitting exclusion of these effects for many commodities. This additional demand curve complexity introduces potential computation challenges alongside the capacity to model many interrelated commodity systems such as rare earth elements, ferroalloys, country-oriented subsidies or restrictions, and bifurcated sustainable metals markets. By presenting the work done on multicommodity supply surfaces to date and potential new directions, this work aims to catalyze the next round of innovative approaches to modeling jointly produced commodities.

Conference Paper

Updated three-dimensional temperature maps for the Great Basin, USA

As part of the periodic update of the geothermal energy assessments for the USA (e.g., last update by Williams and others, 2008), a new three-dimensional temperature map has been constructed for the Great Basin, USA. Williams and DeAngelo (2011) identified uncertainty in estimates of conductive heat flow near land surface as the largest contributor to uncertainty in previously published temperature maps. The new temperature maps incorporate new conductive heat flow estimates developed by DeAngelo and others (2023). Predicted temperatures at depth are compared with representative measurements (for conductively dominated conditions), showing good agreement under relatively simple uniform conditions. Inputs included radiogenic heat production for all layers of 1.89 μW/m 3 , effective bulk thermal conductivity of 2.7 W/m/°C for all rocks underlying sedimentary basins, and a previously published (Williams and DeAngelo, 2011) empirically driven estimate of increasing thermal conductivity with depth in sedimentary sequences. The resulting three-dimensional temperature model is published in a USGS data release associated with this manuscript (Burns and others, 2023).

Arizona, California, Idaho, Nevada, Oregon, Utah

Water use in Louisiana, 2020

The U.S. Geological Survey (USGS), in cooperation with the Louisiana Department of Transportation and Development, collected water-withdrawal and water-use data from a 2020 inventory of water withdrawals in Louisiana. In 2020, approximately 8,700 million gallons per day (Mgal/d) of water was withdrawn from groundwater and surface-water sources in Louisiana, which represented a 0.22-percent decrease from 2015. Total groundwater withdrawals were about 1,900 Mgal/d, an increase of 7.1 percent from 2015, and total surface-water withdrawals were about 6,800 Mgal/d, a decrease of 2.1 percent from 2015 to 2020. Total water withdrawals, in million gallons per day, in 2020 for the various categories of use were as follows: public supply, 720; industry, 2,100; power generation, 4,100; rural domestic, 39; livestock, 7.0; rice irrigation, 930; general irrigation, 250; and aquaculture, 590. From 2015 to 2020, Louisiana’s total withdrawals for public supply increased by 1.4 percent, industry decreased by 2.3 percent, power generation decreased by 4.9 percent, rural domestic decreased by 1.2 percent, livestock increased by 11 percent, rice irrigation increased by 13 percent, general irrigation increased by 12 percent, and aquaculture increased by 20 percent. About 51 percent (approximately 960 Mgal/d) of all groundwater withdrawn was from the Chicot aquifer system and 24 percent (approximately 450 Mgal/d) was withdrawn from the Mississippi River alluvial aquifer. Since 2015, withdrawals from the Chicot aquifer system increased by 13 percent, and withdrawals from the Mississippi River alluvial aquifer increased by 18 percent. About 72 percent (4,900 Mgal/d) of all surface water withdrawn was from the Mississippi River main stem. This value represents a 1.1-percent decrease in withdrawals from 2015 to 2020. All water-withdrawal and water-use data presented in this report should be considered estimates. Because of rounding, totals and percentages presented in the tables, figures, and text in the report may differ slightly from totals or percentages calculated individually.

Louisiana

Reconciling bias in moderate magnitude earthquake ground motions predicted by numerical simulations

Recent studies found a significant underprediction in ground motion intensity measures for finite-fault simulations of moderate magnitude events in southern California relative to established ground motion models. This study aims to understand the source(s) of this bias by evaluating ground motion residuals. For this, simulations have been performed for a total of 27 well-recorded earthquakes in southern California. Systematic efforts have been employed to identify the source(s) of bias by ruling out factors that are insignificant. Preliminary findings indicate that the magnitude-area scaling used in the simulations is the likely major cause of the observed bias. Adjustment in the source attributes on event-by-event basis is underway to study if the observed bias can be reconciled.

Conference Paper

Streamflow, water quality, and constituent loads and yields, Scituate Reservoir drainage area, Rhode Island, water year 2023

As part of a long-term cooperative program to monitor water quality within the Scituate Reservoir drainage area, the U.S. Geological Survey, in cooperation with Providence Water (formerly the Providence Water Supply Board), collected streamflow and water-quality data in tributaries to the Scituate Reservoir, Rhode Island. Streamflow and concentrations of chloride and sodium estimated from records of specific conductance for 16 tributaries were used to calculate loads of chloride and sodium during water year 2023 (October 1, 2022, through September 30, 2023). Water-quality samples were collected by Providence Water at 38 sampling stations on tributaries to the Scituate Reservoir during water year 2023. These water-quality data are summarized by using values of central tendency and are used, in combination with measured (or estimated) streamflows, to calculate loads and yields of selected water-quality constituents for water year 2023. Annual mean streamflows for monitoring stations in this study ranged from 0.47 to 34.4 cubic feet per second during water year 2023. At the 16 continuous-record streamgages, tributaries transported about 3,000 metric tons of chloride and 1,900 metric tons of sodium to the Scituate Reservoir; annual chloride yields for the tributaries ranged from 19 to 200 metric tons per square mile, and annual sodium yields ranged from 13 to 120 metric tons per square mile. At the stations where water-quality samples were collected by Providence Water, the medians of the median daily loads were 65,000 million colony forming units per day for coliform bacteria, 870 million colony forming units per day for Escherichia coli , 200 kilograms per day for chloride, 8.2 grams per day as nitrogen for nitrite, 520 grams per day as nitrogen for nitrate, and 300 grams per day as orthophosphate for phosphate. The medians of the median yields were 25,000 million colony forming units per day per square mile for coliform bacteria, 600 million colony forming units per day per square mile for Escherichia coli , 65 kilograms per day per square mile for chloride, 4.6 grams per day per square mile as nitrogen for nitrite, 180 grams per day per square mile as nitrogen for nitrate, and 180 grams per day per square mile as orthophosphate for phosphate.

Rhode Island

Carbonatite-hosted residual REE deposits

Rare earth elements (REEs) occur in magmatic rocks but are especially enriched in carbonatite and alkaline silicates. If these rocks are chemically weathered, then the REEs may become further enriched within the regolith developed from these rocks. Primary magmatic REE minerals, as well as the various carbonate minerals and apatite, provide the REEs which, under pervasive chemical weathering, are incorporated within low-temperature REE minerals forming within the regolith. Many of these minerals, as well as their textures, are characteristic of this mode of formation. Lateritic conditions of weathering are instrumental in producing a thick, weathered, or regolith, profile, and the roles of sulfide oxidation, fluctuating groundwater tables, and downward mass wasting due to carbonate dissolution are identified as the most important controls on REE enrichment in the regolith.

Book chapter

The U.S. Geological Survey National Water Quality Network—Groundwater, 2024

The U.S. Geological Survey (USGS) operates a National Water Quality Network (NWQN) to monitor trends in groundwater quality and assess emerging contaminants of concern. It is a “network of networks” with 81 subnetworks being sampled on a decadal time scale. Each year, 8 of the subnetworks are sampled. Subnetworks have 20–30 wells each and include studies of domestic supply wells or shallow groundwater (20–50 feet deep) underlying urban land use or agricultural land use. Currently there are 2,089 wells in the network. All wells are sampled for physical properties, nutrients, major ions, trace elements, per- and polyfluoroalkyl substances (PFAS), and a subset of wells are sampled for pesticides, volatile organic compounds, radionuclides, and microbiological contaminants.

Contiguous United States

Alteration mapping in granitic gneiss using handheld geophysical and geochemical instruments: Implications for iron oxide-apatite and rare earth elements exploration

The Adirondack Mountains of New York, U.S.A. contain iron oxide-apatite (IOA) mineral deposits with variable concentrations of rare earth elements (REE). The IOA mineral deposits are typically hosted in the Lyon Mountain Granite Gneiss and are spatially correlated with extensive Na metasomatism (albitization) of the surrounding country rocks, although some mineral deposits also occur in metagabbro, paragneiss, and anorthosite hosts. The location of albitization zones is key to finding new IOA mineral deposits and better understanding the mineralization processes associated with their genesis. However, the Na alteration zones are generally not visibly identifiable in outcrop or hand specimens because the color and textural changes are subtle and are thus difficult to map. Here, we discuss the results from testing two spectroscopic techniques (handheld, field gamma-ray spectroscopy, and portable X-ray fluorescence (pXRF)) to characterize albitization zones surrounding IOA mineral deposits. The gamma-ray and pXRF spectrometers successfully distinguished the relative intensity of alteration in the Lyon Mountain Granite Gneiss based on the K abundance. The measured K content decreases towards the IOA mineral deposits, and the magnitude and width of the gradient are similar along the strike of each mineral deposit. Elevated Th and U values are present in host rocks adjacent to REE-bearing IOA mineral deposits. The pXRF and gamma-ray spectrometer K values are remarkably consistent with laboratory-based, whole-rock XRF compositional data and, therefore, useful for semi-quantitative analysis. Notably, albitization aureoles are consistent around REE-rich and REE-poor mineral deposits, suggesting that saline fluids are essential for the petrogenesis of IOA mineral deposits but may not be critical to REE mineralization. Ultimately, this study demonstrates the utility of handheld gamma-ray and pXRF spectrometry for identifying otherwise cryptic albitization gradients associated with IOA mineral deposits in granitic gneiss.

New York

Connecting flood-related fluvial erosion and deposition with vulnerable downstream road-stream crossings

Fluvial erosion is increasingly responsible for infrastructure and building damages associated with floods as the intensity of extreme rainfalls hit rural and urban rivers in a variety of climate settings across the United States. Extreme floods in 2016 and 2018 caused widespread culvert blockages and road failures, including extensive damage along steep tributaries and ravines in the Marengo River, Wisconsin, watershed during 2016 and 2018. A study conducted by the U.S. Geological Survey (USGS), Wisconsin Wetlands Association (WWA), Ashland County, and the Northwest Wisconsin Regional Planning Commission (NWRPC) investigated the special concern of fluvial erosion hazards (FEHs) associated with gullying, streamside landslides, and the loss of wetland storage in headwaters. In 2019, a pilot study was begun to map and classify ephemeral and perennial streams and wetlands in terms of their sensitivity to FEHs. This study combined data from field-based rapid geomorphic assessments (RGAs) coupled with a stream network-wide geographic information system (GIS) approach for mapping stream segments, referred to as fluvial process zones (FPZ), sensitive to erosion, deposition, and channel change. The GIS approach used nationally available 10-meter (m) resolution topology and an extended stream network to map FPZs based on Strahler stream order, stream power, channel slope, presence of adjacent steep valley sides and headwater flats, and adjacent landform setting. Bankfull channel widths derived from RGA-based hydraulic geometry curves combined with drainage areas, an estimate of bankfull flow, and channel slope were used to calculate specific stream power for the FPZs. Lastly, the FPZs were characterized by their location within three major landform settings that affect erosion potential. The resulting vulnerability maps provided a screening framework to identify FPZs that are sensitive to incision, gullying and mass wasting along steep headwater ephemeral channels, as well as downstream perennial channels that have the potential for valley-side landslides, coarse sediment deposition, and channel change. Lastly, each FPZ was characterized in terms of hydrologic alteration associated with ditching. The vulnerability mapping products and rankings of sensitivity of FPZs will ultimately be used by Ashland County and their collaborators to prioritize natural flood management projects that mitigate FEHs, restore hydrology, and reconnect channels with adjacent wetlands and floodplains.

Wisconsin

Widespread landslide activity in an extreme wet season and implications for regional sediment management, eastern San Francisco Bay area, California

Watershed sediment production is expected to increase in a warmer future with more extreme rain, with cascading effects throughout drainage and sediment-transport networks. This study investigated landscape-scale sediment movement in the eastern San Francisco Bay area, California, USA, during the extreme 2016–2017 wet season that brought major rainfall, landslides, and flooding. Mapping 8,928 landslides across a 1,050-km 2 study area revealed new sediment yield of 510–956 t/km 2 , equivalent to denudation of 193–361 mm/ky. These results correspond closely to long-term denudation rates in the northern and central California Coast Ranges, indicating that mass wasting in very wet years dominates long-term sediment mobilization. However, due to long residence times in drainage networks, the 2017 landslides contributed at most ∼1%–2% of the estimated locally derived fluvial sediment transport to San Francisco Bay. Although the amount of sediment mobilized did not threaten municipal water supplies, small rangeland impoundments in this mixed-use landscape lost storage capacity to new sedimentation. Considering regional sediment supply and demand, even the exceptionally large sediment delivery in an extreme wet year cannot meet the need for sediment to accrete tidal wetlands in the bay. To keep pace with rising sea levels, this abnormally high terrestrial sediment input would need to occur in 50 of the next 75 years, an unlikely occurrence due to the prevalence of recent drought years. Shoreline protection and restoration in the bay would need additional sources of sediment, such as through management of dredged sediment through beneficial-reuse programs.

California

Only very strong shaking can break a tree

A handful of credible accounts, both recent and historical, describe trees being broken during earthquakes. Apart from landslides and tsunamis, such accounts are uncommon, suggesting that trees break only when ground acceleration is extreme or when trees are especially vulnerable to breakage. Here, I consider the question: what ground acceleration is required to break a living tree? I present simplified first‐principles calculations, considering the properties of common trees, focusing on tall, thin trees that can be approximated as uniform vertical cantilevers. The results suggest that, possibly excepting tall trees with heavy canopies, standing trees can only be broken by shaking approaching or exceeding 1 g , as anticipated by the rarity of documented accounts of snapped trees. I briefly consider several well‐documented instances of tree damage during strong earthquakes, drawing inferences about local ground motions.

The Seismic Record

Intense alteration on early Mars revealed by high-aluminum rocks at Jezero Crater

The NASA Perseverance rover discovered light-toned float rocks scattered across the surface of Jezero crater that are particularly rich in alumina ( ~ 35 wt% Al 2 O 3 ) and depleted in other major elements (except silica). These unique float rocks have heterogeneous mineralogy ranging from kaolinite/halloysite-bearing in hydrated samples, to spinel-bearing in dehydrated samples also containing a dehydrated Al-rich phase. Here we describe SuperCam and Mastcam-Z observations of the float rocks, including the first in situ identification of kaolinite or halloysite on another planet, and dehydrated phases including spinel and apparent partially dehydroxylated kaolinite. The presence of spinel in these samples is likely detrital in origin, surviving kaolinitization, pointing to an ultramafic origin. However, the association of low hydration with increased Al 2 O 3 abundances suggests heating-induced dehydration which could have occurred during the lithification or impact excavation of these rocks. Given the orbital context of kaolinite-bearing megabreccia in the Jezero crater rim, we propose an origin for these rocks involving intense aqueous alteration of the parent material, followed by dehydration/lithification potentially through impact processes, and dispersion into Jezero crater through flood or impact-related processes.

Communications Earth & Environment

Mapping bedrock outcrops in the Sierra Nevada Mountains (California, USA) using machine learning

Accurate, high-resolution maps of bedrock outcrops can be valuable for applications such as models of land–atmosphere interactions, mineral assessments, ecosystem mapping, and hazard mapping. The increasing availability of high-resolution imagery can be coupled with machine learning techniques to improve regional bedrock outcrop maps. In the United States, the existing 30 m U.S. Geological Survey (USGS) National Land Cover Database (NLCD) tends to misestimate extents of barren land, which includes bedrock outcrops. This impacts many calculations beyond bedrock mapping, including soil carbon storage, hydrologic modeling, and erosion susceptibility. Here, we tested if a machine learning (ML) model could more accurately map exposed bedrock than NLCD across the entire Sierra Nevada Mountains (California, USA). The ML model was trained to identify pixels that are likely bedrock from 0.6 m imagery from the National Agriculture Imagery Program (NAIP). First, we labeled exposed bedrock at twenty sites covering more than 83 km 2 (0.13%) of the Sierra Nevada region. These labels were then used to train and test the model, which gave 83% precision and 78% recall, with a 90% overall accuracy of correctly predicting bedrock. We used the trained model to map bedrock outcrops across the entire Sierra Nevada region and compared the ML map with the NLCD map. At the twenty labeled sites, we found the NLCD barren land class, even though it includes more than just bedrock outcrops, accounted for only 41% and 40% of mapped bedrock from our labels and ML predictions, respectively. This substantial difference illustrates that ML bedrock models can have a role in improving land-cover maps, like NLCD, for a range of science applications.

California

Young explosive eruptions from the Clear Lake volcanic field

The Clear Lake volcanic field is the northernmost and youngest field in a chain of volcanic fields in and near the California Coast Range mountains. For 2 million years, numerous eruptions have happened around (and through) Clear Lake. The most recent period of activity in the Clear Lake volcanic field probably started around 40,000 years ago and was mainly explosive eruptions concentrated on and near faults in and around the lake. The combination of hot magma and groundwater created explosive releases of hot steam. The craters, called maars, threw out volcanic ash, pumice, and lava fragments, which fell back to the ground and draped the surrounding landscape. The deposits are visible in many places around the southeast end of the lake.

California

HyFlood: A surrogate-model-based framework for compound coastal flooding

Compound coastal flooding is a major threat to low-lying coastal regions and is expected to intensify under future climate change projections. However, modeling the joint interaction of waves, storm surge, tides, and rainfall remains computationally demanding, limiting the development of fast and reliable forecast tools. Here we present HyFlood, a hybrid statistical-numerical downscaling framework capable of computing and mapping high-resolution compound flood hazards while substantially reducing the computational cost compared with fully process-based hydrodynamic modeling. HyFlood combines statistical sampling and selection algorithms with a cascade of reduced-complexity surrogate models that emulate nearshore wave transformation, surf-zone hydrodynamics, and coastal, fluvial, and pluvial flooding. The surrogate models employ machine-learning and regression algorithms applied to a low-dimensional representation of the flooding outputs, obtained through statistical dimensionality reduction. The framework is demonstrated in southern O'ahu, Hawai'i, a region exposed to elevated sea levels driven by tides, waves, and storm surge along with frequent precipitation-driven flash flooding. Validation of the surrogates against the physics-based model outputs demonstrates that HyFlood accurately reproduces daily maxima of spatially distributed flooding depths. This hybrid approach offers a scalable and efficient tool to better quantify how changes in flooding drivers translate into hazard and impact assessments, and to support compound-flood risk assessments and climate-change adaptation planning.

Hawaii