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Ground-water quality data for Oklahoma, 1981

The U.S. Geological Survey has collected data on Oklahoma's ground-water resources since 1934. Most of these data were collected as part of specific ground-water studies conducted in cooperation with various Federal, State, and local agencies. Ground-water quality data, as well as data on construction, yield, water levels, and other physical well parameters collected prior to 1981 are available from the U.S. Geological Survey, Oklahoma District Office. Although water-quality data for wells, test holes, and springs have been published, they are scattered though a variety of reports and are not readily available on a statewide basis. The purpose of this report is to make available, annually, all of the ground-water quality data collected by the U.S. Geological Survey in the Sate of Oklahoma. This report contains ground-water quality data collected in 1981 from 524 sites in 15 counties, predominately in eastern Oklahoma.

Open-File Report↗

Simulated effects of impoundment of lake seminole on ground-water flow in the upper Floridan Aquifer in southwestern Georgia and adjacent parts of Alabama and Florida

Hydrologic implications of the impoundment of Lake Seminole in southwest Georgia and its effect on components of the surface- and ground-water flow systems of the lower Apalachicola?Chattahoochee?Flint (ACF) River Basin were investigated using a ground-water model. Comparison of simulation results of postimpoundment drought conditions (October 1986) with results of hypothetical preimpoundment conditions (a similar drought prior to 1955) provides a qualitative measure of the changes in hydraulic head and ground-water flow to and from streams and Lake Seminole, and across State lines caused by the impoundment. Based on the simulation results, the impoundment of Lake Seminole changed ground-water flow directions within about 20?30 miles of the lake, reducing the amount of ground water flowing from Florida to Georgia southeast of the lake. Ground-water storage was increased by the impoundment, as indicated by a simulated increase of as much as 26 feet in the water level in the Upper Floridan aquifer. The impoundment of Lake Seminole caused changes to simulated components of the ground-water budget, including reduced discharge from the Upper Floridan aquifer to streams (315 million gallons per day); reduced recharge from or increased discharge to regional ground-water flow at external model boundaries (totaling 183 million gallons per day); and reduced recharge from or increased discharge to the undifferentiated overburden (totaling 129 million gallons per day).

Alabama, Florida, Georgia↗

Ground-water levels and directions of flow in the vicinity of a well field, Elkhart, Indiana, December 1989

Water levels were measured in 51 observation wells in the vicinity of the Elkhart Water Works Main Street well field during 5 days of normal pumping at the well field and little or no recharge to the ground water from precipitation. Water levels were measured once each day during December 18-22, 1989. Water-level altitudes were plotted and contoured on maps to determine the distribution of ground-water levels and directions of flow in the unconfined sand and gravel aquifer tapped by the well field. Measured ground-water levels ranged from about 7.5 to 30 feet below land surface. Ground-water levels were highest north and northwest of the Main Street well field and lowest at the Main Street well field and near the St. Joseph River. Regional ground-water flow is toward the south or southeast. Ground-water levels near the river are higher than the river stage, indicating that ground water discharges to the river. As a result of pumping, three cones of depression have formed in the water table in the mapped area. A small cone of depression northwest of the Main Street well field is caused by industrial pumping. Two cones of depression have formed at the Main Street well field-one in the eastern part of the well field and one in the western part of the well field. Horizontal hydraulic gradients are variable in the study area but are largest in the eastern part of the Main Street well field and near the St. Joseph River. In general, water levels measured in seven sets of paired wells do not indicate a vertical hydraulic gradient; however, a downward gradient was measured in one set of paired wells near a pumped area at the Main Street well field.

Indiana↗

Pesticides in surface and ground water of the San Joaquin-Tulare basins, California: Analysis of available data, 1966 Through 1992

Available pesticide data (1966-92) for surface and ground water were analyzed for the San Joaquin-Tulare Basins, California, one of 60 large hydrologic systems being studied as part of the National Water-Quality Assessment Program of the U.S. Geological Survey. Most of the pesticide data were for the San Joaquin Valley, one of the most intensively farmed and irrigated areas of the United States. Data were obtained from the Storage and Retrieval data base of the U.S. Environmental Protection Agency, the water-quality data base of the U.S. Geological Survey, and from data files of State agencies. Pesticides detected in surface water include organochlorine pesticides, organophosphate pesticides, carbamate pesticides, and triazine herbicides. Pesticides detected in ground water include triazine and other organonitrogen herbicides and soil fumi gants. Surface-water data indicate seasonal patterns for the detection of organophosphate and carbamate pesticides, which are attributed to their use on almond orchards and alfafa fields. Organochlorine pesticides were detected primarily in river-bed sediments. Concentrations detected in bed sediments of the San Joaquin River near Vernalis are among the highest of any major river system in the United States. Patterns and timing of pesticide use indicate that pesticides might be present in surface-water systems during most months of a year. The most commonly detected pesticide in ground water is the soil fumigant, dibromochloropropane. Dibromochloropropane, used primarily on vineyards and orchards, was detected in ground water near the city of Fresno. Triazine and other organonitrogen herbicides were detected near vineyards and orchards in the same general locations as the detections of dibromochloropropane. Pesticides were detected in ground water of the east side of the valley floor, where the soils are sandy or coarsegrained, and water-soluble pesticides with long environmental half-lives were used. In contrast, fewer pesticides were detected in ground water of the west side of the valley, where soils generally are finer grained.

California↗

Technology Transfer Opportunities: Automated Ground-Water Monitoring, A Proven Technology

Introduction The U.S. Geological Survey (USGS) has developed and tested an automated ground-water monitoring system that measures and records values of selected water-quality properties and constituents using protocols approved for manual sampling. Prototypes using the automated process have demonstrated the ability to increase the quantity and quality of data collected and have shown the potential for reducing labor and material costs for ground-water quality data collection. Automated ground-water monitoring systems can be used to monitor known or potential contaminant sites, such as near landfills, underground storage tanks, or other facilities where potential contaminants are stored, to serve as early warning systems monitoring ground-water quality near public water-supply wells, and for ground-water quality research.

Fact Sheet↗

Geochemical patterns of arsenic-enriched ground water in fractured, crystalline bedrock, Northport, Maine, USA

High mean As concentrations of up to 26.6 ??mol/L (1990 ??g/L) occur in ground water collected from a fractured-bedrock system composed of sulfidic schist with granitic to dioritic intrusions. Sulfides in the bedrock are the primary source of the As in the ground water, but the presence of arsenopyrite in rock core retrieved from a borehole with As concentrations in the ground water barely above the detection limit of 2.0 ??mol/L, shows that there are complicating factors. Chemical analyses of water from 35 bedrock wells throughout a small watershed reveal spatial clustering of wells with high As concentrations. Stiff diagrams and box plots distinguish three distinct types; calcium-bicarbonate-dominated water with low As concentrations (CaHCO 3 type), sodium-bicarbonate-dominated water with moderately high As concentrations (NaHCO3 type), and calcium-bicarbonate-dominated water with very high As concentrations (High-As type). It is proposed that differences in recharge area and ground-water evolution, and possible bedrock composition difference are responsible for the chemical distinctions within the watershed. Lack of correlation of As concentrations with pH indicates that desorption of As is an insignificant control on As concentration. Correlations of As concentrations with Fe and redox parameters indicates that reductive dissolution of Fe(III) oxyhydroxides may play a role in the occurrence of high As concentrations in the NaHCO3 and High-As type water. The oxidation of sulfide minerals occurs within the ground-water system and is ultimately responsible for the existence of As in the ground water, but there is no correlation between As and SO4 concentrations, probably due to precipitation of Fe(III) oxyhydroxides and adsorption of As under oxidizing conditions. Crown Copyright ?? 2006 Published by Elsevier Ltd. All rights reserved.

Applied Geochemistry↗

Ground-water hydrology and simulated effects of development in the Milford area, an arid basin in southwestern Utah

A three-dimensional, finite-difference model was constructed to simulate ground-water flow in the Milford area. The purpose of the study was to evaluate present knowledge and concepts of the groundwater system, to analyze the ability of the model to represent past and current (1984) conditions, and to estimate the effects of various groundwater development alternatives. The alternative patterns of groundwater development might prove effective in capturing natural discharge from the basin-fill aquifer while limiting water-level declines. Water levels measured during this study indicate that ground water in the Milford area flows in a northwesterly direction through consolidated rocks in the northern San Francisco Mountains toward Sevier Lake. The revised potentiometric surface shows a large area for probable basin outflow, indicating that more water leaves the Milford area than the 8 acre-feet per year estimated previously. Simulations made to calibrate the model were able to approximate steady-state conditions for 1927, before ground-water development began, and transient conditions for 1950-82, during which groundwater withdrawal increased. Basin recharge from the consolidated rocks and basin outflow were calculated during the calibration process. Transient simulations using constant and variable recharge from surface water were made to test effects of large flows in the Beaver River. Simulations were made to project water-level declines over a 37- year period (1983-2020) using the present pumping distribution. Ground-water withdrawals were simulated at 1, 1.5, and 2 times the 1979-82 average rate. The concepts of "sustained" yield, ground-water mining, and the capture of natural discharge were tested using several hypothetical pumping distributions over a 600-year simulation period. Simulations using concentrated pumping centers were the least efficient at capturing natural discharge and produced the largest water-level declines. Simulations using strategically placed ground-water withdrawals in the discharge area were the most efficient at eliminating natural discharge with small water-level declines.

Utah↗

Trend analysis of ground-water levels and spring discharge in the Yucca Mountain Region, Nevada and California, 1960-2000

Ground-water level and discharge data from 1960 to 2000 were analyzed for the Yucca Mountain region of southern Nevada and eastern California. Included were water-level data from 37 wells and a fissure (Devils Hole) and discharge data from five springs and from a flowing well. Data were evaluated for variability and for upward, downward, or cyclic trends with an emphasis on the period 1992-2000. Potential factors causing trends in water levels and discharge include ground-water withdrawal, infiltration of precipitation, earthquakes, evapotranspiration, barometric pressure, and earth tides. Statistically significant trends in ground-water levels or spring discharge from 1992 to 2000 were upward at 12 water-level sites and downward at 14 water-level sites and 1 spring-discharge site. In general, the magnitude of the change in water level from 1992 to 2000 was small (less than 2 feet), except where influenced by pumping or local effects such as possible equilibration from well construction or diversion of nearby surface water. Seasonal trends are superimposed on some of the long-term (1992-2000) trends in water levels and discharge. Factors causing seasonal trends include barometric pressure, evapotranspiration, and pumping. The magnitude of seasonal change in water level can vary from as little as 0.05 foot in regional aquifers to greater than 5 feet in monitoring wells near large supply wells in the Amargosa Farms area. Three major episodes of earthquake activity affected water levels in wells in the Yucca Mountain region between 1992 and 2000: the Landers/Little Skull Mountain, Northridge, and Hector Mine earthquakes. The Landers/Little Skull Mountain earthquakes, in June 1992, had the largest observed effect on water levels and on discharge during the study period. Monthly measurements of wells in the study network show that earthquakes affected water levels from a few tenths of a foot to 3.5 feet. In the Ash Meadows area, water levels remained relatively stable from 1992 to 2000, with some water levels showing small rising trends and some declining slightly. Possible reasons for water-level fluctuations at sites AD-6 (Tracer Well 3), AM-5 (Devils Hole Well), and AM-4 (Devils Hole) from 1960 to 2000 include climate change, local and regional ground-water withdrawals, and tectonic activity. In Jackass Flats, water levels from 1992 to 2000 in six wells adjacent to Fortymile Wash displayed either small upward trends or no upward or downward trend. Comparison of trends in water levels from 1983 to 2000 for these six wells shows good correlations between all wells and suggests a common mechanism controlling water levels in the area. Of the likely controls on the system--precipitation or pumping in Jackass Flats--precipitation appears to be the predominant factor controlling water levels near Fortymile Wash. Water levels in the heavily pumped Amargosa Farms area declined from about 10 to 30 feet from 1964 to 2000. Water-level declines accelerated beginning in the early 1990's as pumping rates increased substantially. Pumping in the Amargosa Farms area may affect water levels in some wells as far away as 5-14 miles. The water level at site DV-3 (Travertine Point 1 Well) and discharge at site DV-2 (Navel Spring), both in the Death Valley hydrographic area, had downward trends from 1992 to 2000. The cause of these downward trends may be linked to earthquakes, pumping in the Amargosa Farms area, or both.

Water-Resources Investigations Report↗

Chlorofluorocarbons, sulfur hexafluoride, and dissolved permanent gases in ground water from selected sites in and near the Idaho National Engineering and Environmental Laboratory, Idaho, 1994-97

From July 1994 through May 1997, the U.S. Geological Survey in cooperation with the Department of Energy, sampled 86 wells completed in the Snake River Plain aquifer at and near the Idaho N ationa1 Engineering and Environmental Laboratory (INEEL). The wells were sampled for a variety of constituents including one- and two-carbon halocarbons. Concentrations of dichlorodifluoromethane (CFC-12), trichlorofluoromethane (CFC-11) and trichlorotrifluororoethane (CFC-113) were determined. The samples for halocarbon analysis were collected in 62-milliliter flame sealed borosilicate glass ampoules in the field. The data will be used to evaluate the ages of ground waters at INEEL. The ages of the ground water will be used to determine recharge rates, residence time, and travel time of water in the Snake River Plain aquifer in and near INEEL. The chromatograms of 139 ground waters are presented showing a large number of halomethanes, haloethanes, and haloethenes present in the ground waters underlying the INEEL. The chromatograms can be used to qualitatively evaluate a large number of contaminants at parts per trillion to parts per billion concentrations. The data can be used to study temporal and spatial distribution of contaminants in the Snake River Plain aquifer. Representative compressed chromatograms for all ground waters sampled in this study are available on two 3.5-inch high density computer disks. The data and the program required to decompress the data can be obtained from the U.S. Geological Survey office at Idaho Falls, Idaho. Sulfur hexafluoride (SF6) concentrations were measured in selected wells to determine the feasibility of using this environmental tracer as an age dating tool of ground water. Concentrations of dissolved nitrogen, argon, carbon dioxide, oxygen, and methane were measured in 79 ground waters. Concentrations of dissolved permanent gases are tabulated and will be used to evaluate the temperature of recharge of ground water in and near the INEEL.

Idaho↗

Hydrogeology and ground-water quality of glacial-drift aquifers, Leech Lake Indian Reservation, north-central Minnesota

Among the duties of the water managers of the Leech Lake Indian Reservation in north-central Minnesota are the development and protection of the water resources of the Reservation. The U.S. Geological Survey, in cooperation with the Leech Lake Indian Reservation Business Committee, conducted a three and one half-year study (1988-91) of the ground-water resources of the Leech Lake Indian Reservation. The objectives of this study were to describe the availability and quality of ground water contained in glacial-drift aquifers underlying the Reservation. Aquifers and confining units are present throughout the entire thickness of the glacial drift in the study area, which includes the Leech Lake Indian Reservation and adjacent parts of Beltrami, Hubbard, Itasca, and Cass Counties in north-central Minnesota, an area of approximately 2,145 square miles. An unconfined aquifer underlies most of the central and north-central parts of the study area. The saturated thickness of the aquifer ranges from 0 to about 105 feet. Horizontal hydraulic conductivity, estimated from 19 slug tests, ranges from 0.6 to 31 feet per day. The transmissivity of the aquifer ranges from 19 to more than 20,000 feet squared per day and is greatest in an area from west of Cass Lake to Lake Winnibigoshish. Theoretical maximum well yields range from less than 10 to about 2,000 gallons per minute. The unconfined and uppermost confined aquifers are physically and hydraulically separated by a fine-grained confining unit, consisting of till or lake deposits, that ranges in thickness from 3 to 254 feet. The thickness of the uppermost confined aquifer ranges from 5 to about 53 feet. On the basis of specific-capacity data, the transmissivity of the aquifer ranges from less than 100 feet squared per day in the northeastern and southeastern parts of the study area to about 21,000 feet squared per day near Cass Lake. Theoretical maximum well yields range from less than 10 to about 2,600 gallons per minute. Recharge to the ground-water system is predominantly from precipitation that infiltrates to the saturated zone. An analysis of four hydrographs for observation wells screened in the unconfined aquifer indicated spring recharge amounts during 1989 of 1-4 inches. Discharge from the ground-water system occurs by leakage to streams, lakes, and wetlands, evapotranspiration, withdrawals by wells, and underflow to the southeast within the Mississippi River Valley. Streamflow measurements indicate that ground-water discharge to the Mississippi River is greater in the western part of the study area between Cass Lake and Lake Winnibigoshish than in the eastern part downstream from Lake Winnibigoshish. The general regional direction of ground-water flow in the unconfined and uppermost confined aquifers is to the east and southeast. Ground-water flow is also toward the Mississippi River and the three large lakes in the study area, Lake Winnibigoshish and Cass and Leech Lakes. Water moves through the ground-water system predominantly horizontally in the aquifers, whereas vertical components of flow are significant in confining units. Downward leakage of water occurs in highland areas where ground water flows downward from overlying till to the uppermost confined aquifer. Water moves vertically upward from deep to shallow aquifers in areas of regional discharge, the Mississippi River, Cass Lake, Lake Winnibigoshish. and Leech Lake. Waters from both the unconfined and uppermost confined aquifers generally are suitable for domestic consumption, crop irrigation, and most other uses. Concentrations of iron and manganese in water from both aquifers frequently exceed levels that may impart an undesirable taste or odor to water. Calcium and bicarbonate are the predominant ions in water from both the unconfined and uppermost confined aquifers. Water from both the unconfined and uppermost confined aquifers is hard to very hard, averaging 187 and 247 milligrams per liter as calcium carbonate, respectively. Differences in the mean concentrations of constituents in waters from the unconfined and uppermost confined aquifers vary. The mean concentrations of chloride, manganese, dissolved organic carbon, sulfate, and dissolved iron were greater for water from the unconfined aquifer than for water from the uppermost confined aquifer. Conversely, the mean concentrations of calcium, potassium, silica, sodium, fluoride, and boron were greater for water from the uppermost confined aquifer than for water from the unconfined aquifer. These higher concentrations of naturally occurring constituents in waters from the uppermost confined aquifer may occur because of the longer flow paths and longer residence times of water in the uppermost confined aquifer as compared to the unconfined aquifer. Nutrients include nitrogen and phosphorus species. The mean concentrations of dissolved nitrogen (NO 2 + NO 3 , dissolved) and total phosphorus were about 5 and 1.5 times greater for water from the unconfined aquifer than for water from the uppermost confined aquifer, respectively. None of the water samples had concentrations of dissolved nitrogen greater than the maximum contaminant level established by the U.S. Environmental Protection Agency (10 milligrams per liter) and only one water sample had a concentration greater than 3 milligrams per liter. Water collected from wells completed in the unconfined aquifer in residential and recreational land-use areas had concentrations of arsenic, cadmium, chromium, copper, lead, mercury, and cyanide equal to or less than 6 micrograms per liter. Concentrations of organic-acid herbicides in water from three wells screened in the unconfined aquifer in managed-forest land-use areas were all below detection levels. Concentrations of U.S. Environmental Protection Agency priority pollutants in water from three wells screened in the unconfined aquifer and from one well screened in the uppermost confined aquifer were also all below detection levels.

Minnesota↗

Ground-water-flow conditions within a bottomland hardwood wetland, eastern Arkansas

Water levels were measured monthly at 9 staff gages and 35 wells along two transects within the Black Swamp bottomland hardwood wetland and perpendicular to the Cache River in eastern Arkansas from December 1989 to September 1992 in order to (1) describe the ground-water-flow conditions at locations within a bottomland hardwood wetland and (2) determine the relation between the frequency of different ground-water-flow conditions and physical characteristics within the wetland. Three ground-water-flow conditions predominated at various times in the Black Swamp: (1) discharge of water from the alluvial aquifer to the wetland, (2) recharge of water from the wetland into the alluvial aquifer, and (3) flow of water from the wetland into the alluvial aquifer and then to the nearby Cache River (local flow). Analyses of hydraulic head differences between surface and ground water indicate that discharge occurred 31% of the measurement times at both transects. Recharge occurred 39% of the measurement times and tended to occur more often at locations that are far from the Cache River and that overlie low ground-water levels in the lower part of the alluvial aquifer. Local ground-water flow occurred 28% of the measurement times and tended to occur more often at locations close to the Cache River. Ground-water pumpage results in water-level declines in the lower part of the alluvial aquifer near the Black Swamp wetland. When compared with an area not affected by pumping, these lower ground-water levels increased the frequency of recharge of Black Swamp water into the alluvial aquifer by nearly a factor of 7, decreased the frequency of local ground-water flow to the Cache River to less than half, and decreased the frequency of discharge by about 22%.

Arkansas↗

Ground water in the San Juan metropolitan area, Puerto Rico

Ground water in the San Juan, Puerto Rico, area has played a declining role in water supply since the completion of the Lofza reservoir project in the early 1950's. Ground-water potential is limited because of the small size of the aquifers and susceptibility to seawater intrusion. Of the 30 million gallons per day about half is being used. Two water-bearing zones are present: an artesian aquifer, composed of the San Sebastian Formation and the lower Cibao Formation that yields an average of 244 gallons per minute to wells; and, a water-table aquifer composed of the upper Cibao Formation and the Aguada and Aymamon Limestones that yields an average of 515 gallons per minute to wells. Ground water is less mineralized inland and in the artesian aquifer. Mean concentrations of dissolved solids are 363 milligrams per liter for the artesian aquifer and 525 milligrams per liter for the water-table aquifer. (Woodard-USGS)

Water-Resources Investigations Report↗

Nitrate retention in riparian ground water at natural and elevated nitrate levels in North Central Minnesota

The relationship between local ground water flows and NO3− transport to the channel was examined in three well transects from a natural, wooded riparian zone adjacent to the Shingobee River, MN. The hillslope ground water originated as recharge from intermittently grazed pasture up slope of the site. In the hillslope transect perpendicular to the stream, ground water NO3− concentrations decreased from ∼3 mg N L−1 beneath the ridge (80 m from the channel) to 0.01 to 1.0 mg N L−1 at wells 1 to 3 m from the channel. The Cl− concentrations and NO3/Cl ratios decreased toward the channel indicating NO3− dilution and biotic retention. In the bankside well transect parallel to the stream, two distinct ground water environments were observed: an alluvial environment upstream of a relict beaver dam influenced by stream water and a hillslope environment downstream of the relict beaver dam. Nitrate was elevated to levels representative of agricultural runoff in a third well transect located ∼5 m from the stream to assess the effectiveness of the riparian zone as a NO3− sink. Subsurface NO3− injections revealed transport of up to 15 mg N L−1 was nearly conservative in the alluvial riparian environment. Addition of glucose stimulated dissolved oxygen uptake and promoted NO3− retention under both background and elevated NO3− levels in summer and winter. Disappearance of added NO3− was followed by transient NO2− formation and, in the presence of C2H2, by N2O formation, demonstrating potential denitrification. Under current land use, most NO3− associated with local ground water is biotically retained or diluted before reaching the channel. However, elevating NO3− levels through agricultural cultivation would likely result in increased NO3− transport to the channel.

Minnesota↗

Ground-water quality in Bannock, Bear Lake, Caribou, and part of Power counties, southeastern Idaho

This report provides information about the current quality of ground waters in southeastern Idaho and discusses the natural and manmade environmental controls on that quality. This information will be useful in planning and monitoring the development and use of the ground-water resources of southeastern Idaho. The southeastern corner of Idaho, as described in this report, encompasses an area of about 4,000 mil in Bannock, Bear Lake, Caribou, and part of Power Counties. The popu- lation of the area in 1975, based on best estimates by the Idaho Division of Budget, Policy Planning, and Coordination (1976) was 75,200. About 80 percent of the population is in and near the city of Pocatello, which is the second largest population center in the State. Pocatello's economy depends largely on manufacturing and industrial processing, which includes chemicalfertilizer plants. The econ- omy in the rural areas depends largely on agriculture--both dry and irrigated farming are practiced. Mining is important and expected to dominate the economy in the eastcentral part of the area in the future. Natural resources include phosphate ore, which makes up about 35 percent of the U.S. reserves (U.S. Department of Interior and U.S. Department of Agriculture, 1977); ground water, which mostly underlies the several intermontane valleys that dissect the area; and hot springs, which indicate that geothermal energy sources may underlie part of the area. Also, current (1978) speculation is that petroleum reserves may be present in the vicinity of Bear Lake. Development of more sprink- ler-irrigated lands, increases in population, and growth of phosphate mining are expected to place stress on the ground-water resources, both in quality and quantity. The purpose of this report is to present the results of a study whose primary objectives were (1) to provide current waterquality data representative of the water in several different aquifers (water- bearing formations) in the study area, and (2) to relate these data to natural and manmade environmental controls. The wells sampled during this study establish a quasi-network, which could be resampled in the future to document and analyze changes (if any) in ground-water quality. Based on this information, planners and water managers could better understand the causeand-effect relations controlling water quality and could better manage land and water-resource development. The report is designed for ease of reading and presentation. It uses maps, tables, and abbreviated text to describe geology, hydrology, and ground-water quality and how they are interrelated. Some practical ways for improving water quality are discussed for the benefit of individual water users. The field data collected in making the study are contained in the Data Section of this report. The authors gratefully acknowledge the many individual well owners, municipal officials, and private industries that provided well information and allowed access to their properties and collection of water samples. Without their help, this work could not have been done. Water samples were collected at 103 well sites. Waterlevel measurements were made at 98 of these sites during July, August, and September of 1976. This study was made by the U.S. Geological Survey in cooperation with the Idaho Department of Water Resources. A similar study is being made (1978) in north Idaho. Other studies are planned, specifically to obtain ground-water-quality data in areas where land and water-resource development is expected or accelerating.

Idaho↗

Quality of ground water in agricultural areas of the San Luis Valley, south-central Colorado

The quality of ground water in the principal agricultural areas of the San Luis Valley, south-central Colorado was evaluated using chemical analyses of water collected from 57 wells completed in the unconfined aquifer and from 25 wells completed in the confined aquifer. Ground water in both aquifers generally contains dissolved-solids concentrations of less than 500 milligrams per liter. In most areas, calcium is the principal cation in the ground water. Nitrite plus nitrate concentrations expressed as nitrogen, are generally less than 1 milligram per liter. However, the quality of ground water in certain areas may pose health and agricultural hazards. Water in the unconfined aquifer near Center contains high nitrite plus nitrate as nitrogen concentrations. The highest measured concentration in this area was 33 milligrams per liter. Water containing more than 1 milligram per liter of nitrite as nitrogen, or 10 milligrams per liter nitrate, as nitrogen, poses a potential health hazard for infants and should not be used for drinking. In addition, dissolved-solids concentration in the ground water in some areas is greater than 500 milligrams per liter and, if used for irrigation may reduce crop yields. (USGS)

Water-Resources Investigations Report↗

Ground‐water for air‐conditioning on Long Island, New York

During the last five years ground‐water has been more and more extensively used for air‐conditioning on Long Island, New York. The wide‐spread occurrence of highly permeable water‐bearing material and the relatively small cost of installation and operation of a ground‐water, air‐conditioning system has resulted in many such installations by theaters, restaurants, stores, and other establishments. Many companies likewise have taken advantage of these favorable factors and are utilizing low‐temperature ground‐water for cooling purposes in the manufacture of ice. This new use of ground‐water has considerably increased the draft in the western end of Long Island where there had already been so much over‐development that the watertable was below sea‐level in an area of more than 40 square miles. In 1933 the State Legislature, recognizing the seriousness of this over‐development, passed a law requiring that the approval, of the State Water Power and Control Commission be secured before constructing a well with a capacity greater than 100,000 gallons a day. Since the passage of the law the‐policy of the Commission has been to require water pumped from new‐wells for cooling purposes to be returned to the ground. This requirement has resulted in the construction of many recharge‐wells (locally called diffusion‐wells) through which the warm water is returned to the ground.

New York↗

Ground-water age and atmospheric tracers: Simulation studies and analysis of field data from the Mirror Lake site, New Hampshire

The use of environmental tracers in characterization of ground-water systems is investigated through mathematical modeling of ground-water age and atmospheric tracer transport, and by a field study at the Mirror Lake site, New Hampshire. Theory is presented for modeling ground-water age using the advective-dispersive transport equation. The transport equation includes a zero-order source of unit strength, corresponding to the rate of aging, and can accommodate matrix diffusion and other exchange processes. The effect of temperature fluctuations and layered soils on transport of atmospheric gases to the water table is investigated using a one-dimensional numerical model of chlorofluorocarbon (CFC-11) transport. The nonlinear relation between temperature and Henry's Law coefficient (reflecting air/water phase partitioning) can cause the apparent recharge temperature to be elevated above the annual mean temperature where the water table is shallow. In addition, fine-grained soils can isolate the air phase in the unsaturated zone from the atmosphere. At the USGS' Mirror Lake, New Hampshire fractured-rock research site CFC concentrations near the water table are depleted where dissolved oxygen is low. CFC-11 and CFC-113 are completely absent under anaerobic conditions, while CFC-12 is as low as one-third of modern concentrations. Anaerobic biodegradation apparently consumes CFC's near the water table at this site. One area of active degradation appears to be associated with streamflow loss to ground water. Soil gas concentrations are generally close to atmospheric levels, although some spatial correlation is observed between depleted concentrations of CFC-11 and CFC-113 in soil gas and water-table samples. Results of unsaturated-zone monitoring indicate that recharge occurs throughout the year in the watershed, even during summer evapotranspiration periods, and that seasonal temperature fluctuations occur as much as 5 meters below land surface. Application of ground-water age and CFC-11 transport models to the large-scale ground-water system at Mirror Lake illustrates the similarities between age and chemical transport. Generally, bedrock porosities required to match observed apparent ages from CFC concentrations are high relative to porosities measured on cores. Although matrix diffusion has no effect on steady-state age, it can significantly reduce CFC concentrations in fractured rock in which the effective porosity is low.

New Hampshire↗

Geohydrology and quality of ground water in unconsolidated aquifers near South Bend, Indiana

Introduction The water supply for the City of South Bend, Indiana, and much of surrounding St. Joseph County is provided by 36 municipal and community well fields. Some of these well fields are located near known or potential sources of ground-water contamination that could affect ground-water supplies in the near future. As population and industry grow, it will be necessary to find additional sources of water and determine their quantity and quality. Geohydrologic and water-quality data are available to identify areas for developing additional ground-water supplies, but these data have not been compiled into one source accessible to area water-resource managers. This report presents a compilation of these geohydrologic and water-quality data for the ground-water system in and near South Bend that can be used to identify potentially favorable areas for developing additional ground-water supplies for municipal use. The data were compiled by the U.S. Geological Survey, in cooperation with the South Bend Water Works, for a study area of approximately 535 square miles that includes all of St. Joseph County and the eastern part of La Porte County. A map format has been used to facilitate comparison between geohydrologic and water-quality information. Previously published geologic maps and cross sections describe the geologic setting and aquifer deposits of the study area, the hydrogeology of northeastern St. Joseph County, and the ground-water quality of northeastern St. Joseph County. Beaty (1990) and Clendenon and Beaty (1987) produced water-resource-availability reports for the St. Joseph and Kankakee River Basins.

Indiana↗