USGS Science⌕ Search

SEARCH · USGS Science

Results for “Electronics”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,405 records · Page 78Linked to original sources
USGS1978

Inflatable straddle packers and associated equipment for hydraulic fracturing and hydrologic testing

Independent aquifer testing is the only way to fully understand the hydrology encountered in boreholes intersecting multiple aquifers. The most feasible method to accomplish the testing of multiple aquifer wells is through the use inflatable packers. The straddle packers and associated equipment herein described arE valuable tools for making isolated aquifer tests as well as conducting hydraulic fracturing experiments. The system, due to design, permits multiple tests in a bore-hole without the necessity of tripping in and out of the hole to redress the packers prior to testing each zone. Electronic pressure transducers, the output of which was fed into strip-chart recorders, were used to monitor the zone being tested, as well as to monitor the zones above and below the packers. This was necessary to ensure that no leaking had occurred around the packers, causing hydraulic continuity between the isolated zones.

Water-Resources Investigations Report↗
USGS1979

Evaluation of methods for estimating ground-water withdrawals in western Kansas

During 1978, methods of estimating ground-water withdrawals in western Kansas were examined and evaluated, using both existing data from the files of the U.S. Geological Survey and newly collected data. Values for annual ground-water withdrawals reported to the Division of Water Resources, Kansas State Board of Agriculture, by water users probably contain substantial errors because most individual users do not possess the means to measure or accurately estimate the discharge rates of their wells. Such reported values are estimated to average 10 to 15 percent higher than the actual discharge rate. Values obtained from discharge-totaling meters are reasonably accurate, but few wells are equipped with these meters, and the cost of equipping all wells with meters may be prohibitive. Measured rates of power consumption can give good estimates of total withdrawal from wells where the power consumption is measured. However, power-consumption values cannot be extrapolated reliably from one well to another. Three techniques are regarded as promising for estimating areal ground-water withdrawals from readily collected data: Examination of a small sample of withdrawal values from metered wells indicates that the statistical approach used by Luckey (1972) may be applied to western Kansas to estimate total withdrawal with acceptable accuracy in a large area from a statistical sample of measured values. Measured values of irrigation application at a small number of selected wells might be used to compute total withdrawal for irrigation by crop type and precipitation zone. Evaluation of reported values of irrigation-water application for selected crops in zones of generally similar precipitation showed that, although the reported values are judged to be erroneously high, the reported values were consistent with each other and with average precipitation. Power-consumption coefficients may be used to calculate an average coefficient for an area. The method described by Luckey (1972) was used to calculate the number of power-consumption coefficients that would have to be determined to estimate the mean power consumption of wells pumped by electric or natural-gas engines. The results indicate that as few as 100 values would produce results accurate to within 10 percent of the true average at the 95-percent confidence level. Thus, power coefficients for a particular type of irrigation system in any given area can be used even though values of power coefficients have little transfer value from well to well. Efforts by the Instrument Development Laboratofy of the U.S. Geological Survey to design improved instruments for measuring ground-water withdrawals have produced two promising results: An electronic running-time meter (Running-time Sentry) that was tested during 1978 in western Kansas and Florida appears to give accurate values of total pumping time. Large-scale testing of this prototype running-time meter is planned for 1979. A low-cost discharge-totaling meter (REELTOT), based on the concept of sensing the velocity head in a pipe with differential-pressure transducers permanently installed in the pipe, is nearly complete. Early prototypes of this instrument may be tested in western Kansas during 1979. For the remainder of this study, the three techniques for estimating areal ground-water withdrawals described above will be tested on a larger scale in Groundwater Management District No. 1, an area of about 1,800 square miles in west-central Kansas. About 150 randomly selected wells will be equipped with Running-time Sentry units and monitored for total withdrawal, instantaneous discharge, and power consumption. A few wells will be equipped with prototype discharge-totaling meters. The performance of the Sentry units and discharge-totaling meters will be evaluated. Areal estimates of withdrawal from measured withdrawal values, from average power-consumption coefficients, and from irrigation application by crop will be calculated and compared with each other and with reported values of withdrawal.

Kansas↗
USGS1986

Design, operation, and monitoring capability of an experimental artificial-recharge facility at East Meadow, Long Island, New York

Artificial recharge with tertiary-treated sewage is being tested at East Meadow to evaluate the physical and chemical effects on the groundwater system. The recharge facility contains 11 recharge basins and 5 injection wells and is designed to accept 4 million gallons of reclaimed water per day. Of the 11 basins, 7 are recently constructed and will accept 0.5 million gallons per day each. An observation manhole (12-foot inside diameter and extending 16 feet below the basin floor) was installed in each of two basins to enable monitoring and sampling of percolating reclaimed water in the unsaturated zone with instruments such as tensiometers, gravity lysimeters, thermocouples, and soil-gas samplers. Five shallow (100-feet deep) injection wells will each return 0.5 million gallons per day to the groundwater reservoir. Three types of injection-well design are being tested; the differences are in the type of gravel pack around the well screen. When clogging at the well screen occurs, redevelopment should restore the injection capability. Flow to the basins and wells is regulated by automatic flow controllers in which a desired flow rate is maintained by electronic sensors. Basins can also operate in a constant-head mode in which a specified head is maintained in the basin automatically. An observation-well network consisting of 2-inch- and 6-inch-diameter wells was installed within a 1-square-mile area at the recharge facility to monitor aquifer response and recharge. During 48 days of operation within a 17-week period (October 1982 through January 1983), 88.5 million gallons of reclaimed water was applied to the shallow water table aquifer through the recharge basins. A 4.29-foot-high groundwater mound developed during a 14-day test; some water level increase associated with the mound was detected 1,000 ft from the basins. Preliminary water quality data from wells affected by reclaimed water show evidence that mechanisms of mixing, dilution, and dispersion are affecting chemical concentrations of certain constituents, such as nitrogen and trichloroethane, in the shallow aquifer beneath the recharge area. (USGS)

Water-Resources Investigations Report↗
USGS1996

Evaluation of Acoustic Doppler Current Profiler measurements of river discharge

Developments in Acoustic Doppler Current Profiler (ADCP) technologies have made these instruments potentially useful for making measurements of discharge in rivers and large streams. Although there have been several laboratory studies and some field experiments, quantitative information on the performance of ADCP's under field conditions is relatively rare but essential to proper assessment of the potential uses and limitations of these instruments. This study was a comparative evaluation of river discharge data and ADCP data collected with conventional methods at 12 selected U.S. Geological Survey streamflow- gaging stations in the continental United States. ADCP discharge measurements were made at the 12 sites in 1994. Twenty-six of the 31 measurements differed by less than 5 percent from the discharges determined with conventional methods. All 31 ADCP measurements were within 8 percent of the conventional method discharges. The standard deviations of the ADCP measurements ranged from approximately 1 to 6 percent and were generally higher than the measurement errors predicted by error-propagation analysis of ADCP instrument performance. These error-prediction methods assume that the largest component of ADCP discharge measurement error is instrument related. The larger standard deviations indicate that substantial portions of measurement error may be attributable to sources unrelated to ADCP electronics or signal processing and are functions of the field environment.

Water-Resources Investigations Report↗
USGS1997

Guidelines and standard procedures for studies of ground-water quality; selection and installation of wells, and supporting documentation

This is the first of a two-part report to document guidelines and standard procedures of the U.S. Geological Survey for the acquisition of data in ground-water-quality studies. This report provides guidelines and procedures for the selection and installation of wells for water-quality studies/*, and the required or recommended supporting documentation of these activities. Topics include (1) documentation needed for well files, field folders, and electronic files; (2) criteria and information needed for the selection of water-supply and observation wells, including site inventory and data collection during field reconnaissance; and (3) criteria and preparation for installation of monitoring wells, including the effects of equipment and materials on the chemistry of ground-water samples, a summary of drilling and coring methods, and information concerning well completion, development, and disposition.

Water-Resources Investigations Report↗
USGS1998

Lithology and fracture characterization from drilling investigations in the Mirror Lake area, Grafton County, New Hampshire

The lithology and fracture network of the bedrock aquifer in the Mirror Lake area were characterized from hydrogeologic data collected from 1979-95 in Grafton County, N.H. The collection of these data is an integral part of an ongoing multidisciplinary study by the U.S. Geological Survey to characterize groundwater flow and solute transport in fractured rock. The data provide a physical framework and enable the characterization of the fractures and the rock types in the bedrock aquifer in the Mirror Lake study area. In addition, these data provide a detailed description of the subsurface intersected by boreholes that can be used to compare the results of other borehole testing. The Mirror Lake area is characterized by steep bedrock uplands that are mostly covered by colluvium, discontinuous stratified-drift deposits, and glacial till that varies locally in thickness from less than 10 meters to as much as 50 meters. The land-surface altitude ranges from 180 meters near the Pemigewasset River to 720 meters on the mountain top on the northwestern side of the study area. The bedrock in the area is predominantly sillimanite-grade pelitic schists that have been complexly folded and intruded by granitoids, pegmatites, and diabase dikes. The bedrock has been fractured in response to local and tectonic stress. The resulting interconnected network of fractures forms the bedrock aquifer. This report describes the lithologic units in the study area and provides a characterization of the lithology and fractures found in 40 boreholes, which range in depth from 60 to 305 meters, that were drilled for this study. Drilling logs and color video surveys were used to locate and characterize the fractures and rock types in the subsurface. Solid bedrock core was obtained from three of the boreholes. Petrographic thin-section, x-ray diffraction and scanning electron microscope with energy dispersive x-ray fluorescence spectrometry analyses were done on selected samples from boreholes and outcrops. Observations recorded at the time of drilling, descriptions of rock samples collected from the boreholes, interpretation of rock type and fractures based on boreholeimaging surveys, descriptions of rock core and petrographic analyses of selected rock samples are in tables and figures. Analysis of the data provided information on the distribution of fractures and lithology in the boreholes at Mirror Lake. The relative abundances of the rock types were computed for three groups of boreholes, including (1) the Forest Service Experimental (FSE) well field, (2) the Camp Osceola (CO) well field, and (3) the index boreholes, which are 15 boreholes distributed areally throughout the study area including the deepest borehole from each of the two well fields. The index boreholes are separated by hundreds of meters and are typically 100 meters deep. The FSE well field includes 13 boreholes that are separated by 10 to 40 meters. These 13 boreholes are approximately 100 meters deep, except for one borehole that is 230 meters deep. The rocks penetrated by the FSE wells are predominantly igneous. Approximately 70 percent of the rocks encountered in the boreholes in the FSE well field were granite, pegmatite, and aplite. The CO well field includes 9 boreholes that range from 60-70 meters deep and one borehole that is 175 meters deep. The rocks encountered in these boreholes were predominantly metamorphic. The distribution of rock types in the CO well field is similar to the distribution of rocks in highway roadcuts, that are approximately 90 to 150 meters east of the well field. Seventy percent of the roadcut exposures are schist. Collectively, in the 15 index boreholes, the metamorphic and igneous rocks are equally distributed. Analysis of the rock types in these boreholes indicates that the rock types tend to "change" every 5 to 9 meters. Although the metamorphic and igneous rocks each comprise approximately 50 percent of the rock types observed in the 15 index boreholes, 73 percent of the fractures were in the igneous rocks. This indicates that the granitoids tend to be more fractured than the metamorphic rocks. Pegmatite, diabase, quartzite, and gneissic rocks are relatively unfractured. Boreholes completed in bedrock generally have one or two water-bearing zones, which were identified during the drilling process. At the completion of drilling a borehole, the driller estimated the yield of the borehole with an air-lift test. Yields estimated by drillers ranged from less than 3 to 378 liters per minute. These yields are typical of the yields measured for domestic wells in Grafton County. Water levels measured in the open boreholes after the boreholes recovered from the hydraulic stresses of drilling were usually in the steel casing and were within 10 meters of the land surface. Water levels in eight of the boreholes were above the top of casing or above land surface.

New Hampshire↗
USGS1999

Development of a 14-digit Hydrologic Unit Code Numbering System for South Carolina

A Hydrologic Unit Map showing the cataloging units, watersheds, and subwatersheds of South Carolina has been developed by the U.S. Geological Survey in cooperation with the South Carolina Department of Health and Environmental Control, funded through a U.S. Environmental Protection Agency 319 Grant, and the U.S. Department of Agriculture, Natural Resources Conservation Service. These delineations represent 8-, 11-, and 14-digit Hydrologic Unit Codes, respectively. This map presents information on drainage, hydrography, and hydrologic boundaries of the water-resources regions, subregions, accounting units, cataloging units, watersheds, and subwatersheds. The source maps for the basin delineations are 1:24,000-scale 7.5-minute series topographic maps and the base maps are from 1:100,000-scale Digital Line Graphs; however, the data are published at a scale of 1:500,000. In addition, an electronic version of the data is provided on a compact disc. Of the 1,022 subwatersheds delineated for this project, 1,004 range in size from 3,000 to 40,000 acres (4.69 to 62.5 square miles). Seventeen subwatersheds are smaller than 3,000 acres and one subwatershed, located on St. Helena Island, is larger than 40,000 acres. This map and its associated codes provide a standardized base for use by water-resource managers and planners in locating, storing, retrieving, and exchanging hydrologic data. In addition, the map can be used for cataloging water-data acquisition activities, geographically organizing hydrologic data, and planning and describing water-use and related land-use activities.

South Carolina↗
USGS1999

Ground-water contamination by crude oil: Section B in U.S. Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Charleston, South Carolina, March 8-12, 1999: Volume 3 (Part C)

Ground water contamination by crude oil, and other petroleum-based liquids, is a widespread problem. An average of 83 crude-oil spills occurred per year during 1994-96 in the United States, each spilling an average of about 50,000 barrels of crude oil (U.S. Office of Pipeline Safety, electronic commun., 1997). An understanding of the fate of organic contaminants (such as oil and gasoline) in the subsurface is needed to design innovative and cost-effective remedial solutions at contaminated sites.

Water-Resources Investigations Report↗
USGS2000

Heavy minerals and sedimentary organic matter in Pleistocene and Cretaceous sediments on Long Island, New York, with emphasis on pyrite and marcasite in the Magothy aquifer

Abundance and distribution of iron-bearing and other heavy minerals in sediments of Long Island, N.Y., were examined to identify sources and sinks of dissolved iron and other ground-water constituents along a deep flow path from the ground-water divide to the southern shore along the Nassau-Suffolk County border. The occurrence and reactivity of many iron-bearing minerals in the aquifer system are affected by terminal electron-accepting processes, which are a function of depth below land surface, distance from the ground-water divide, and organic-matter content of the sediment. The lateral distribution of heavy minerals within lithologic sediments is not uniform throughout Long Island, or even along the 30-kilometer study section at the Nassau-Suffolk County border. Mineralogy and mineral abundance in Pleistocene units differ from those in Cretaceous sediments, and some of the trends vary with depth as well as from north to south. Major heavy minerals in the Cretaceous sediments at the study sites include pyrite, marcasite, muscovite, leucoxene, ilmenite, rutile, staurolite, chloritoid, and aluminosilicates (Al2SiO5); those in the overlying Pleistocene deposits at one site include iron oxides, leucoxene, zircon, garnet, ilmenite, aluminosilicates, and hornblende. Pyrite, marcasite, garnet, hornblende, and tourmaline were found locally in the Cretaceous sediments. Pyrite and marcasite were detected less frequently in borehole samples from near the ground-water divide, where the ground water is generally oxic, than in those from near the southern shore of Long Island, but were found in sulfate- reducing zones throughout the Magothy aquifer. Glauconite was present in Cretaceous and Pleistocene deposits, but only in the marine or transitional units. The most abundant and potentially reactive of the iron-bearing minerals found were iron (hydr)oxides, leucoxene, glauconite, chlorite, pyrite, and marcasite. The presence and morphology of pyrite and marcasite can be indicative of the microbial and geochemical environments. Pyrite generally was found in association with lignite or as interstitial cement. Marcasite was found as interstitial cement and is associated with the oxidation of iron-sulfide minerals upgradient. Pyrite crystals were octahedral, cubic, cubo-octahedral, and framboidal, and many samples showed more than one generation of crystal growth. Marcasite cement, which consisted of platey crystals in most samples, probably forms only under nonmarine conditions.

Water-Resources Investigations Report↗
USGS1968

Water-discharge determinations for the tidal reach of the Willamette River from Ross Island Bridge to Mile 10.3, Portland, Oregon

Water-discharge, velocity, and slope variations for a 3.7-mile-Iong tidal reach of the Willamette River at Portland, Oreg., were defined from discharge measurements and river stage data collected between July 1962 and January 1965. Observed water discharge during tide-affected flows, during floods, and during backwater from the Columbia River and recorded stages at each end of the river reach were used to determine water discharge from two mathematical models. These models use a finite-difference method to solve the equations of moderately unsteady open-channel streamflow, and discharges are computed by an electronic digital computer. Discharges computed by using the mathematical models compare satisfactorily with observed discharges, except during the period of backwater from the annual flood of the Columbia River. The flow resistance coefficients used in the models vary with discharge; for one model, the coefficients for discharges above 30,000 cfs (cubic feet per second) are 12 and 24 percent less than the coefficient used for discharges below 30,000 cfs. Daily mean discharges were determined by use of one mathematical model for approximately two-thirds of the water year, October 1963 through September 1964. Agreement of computed with routed daily mean discharges is fair; above 30,000 cfs, average differences between the two discharges are about 10 percent, and below 30,000 cfs, computed daily discharges are consistently greater (by as much as 25 percent) than routed discharges. The other model was used to compute discharges for the unusually high flood flows of December 1964.

Water Supply Paper↗
USGS1964

Apparatus and techniques for measuring bedload

The need for accurate determinations of the total sediment discharge of particles of bedload size has prompted this investigation of available and possible measuring apparatus and procedures. The accuracy of measurements of sediment discharge made with trap-type samplers is affected by the variability of sampler efficiency, by the oscillatory variation of bedload discharge, and by sampler placement. Equations that were developed for determining total discharge from measured bedioad discharge and measured suspended-sediment discharge are simplest if the bedload apparatus measures only the true bedload. Early bedload samplers are generally unsatisfactory. Recently developed or suggested apparatus include various improved samplers of the pressure-difference type, a pumping sampler, a magnetic sampler, acoustical instruments that measure the magnitude of the sound of particle collisions, an ultrasonic bedload sampler designed to measure and integrate electronically the concentration and velocity, and a tiltmeter designed to measure the total sediment discharge from the ground tilt that results from the passage of flow. All the pressure-difference samplers are improvements over early samplers, but none are void of the inherent shortcomings of trap-type apparatus; probably the Sphinx (Dutch) and VUV (Hungarian) samplers are the most satisfactory. The acoustical instruments are capable of measuring only the relative discharge. The ultrasonic sampler and the tiltmeter are not adequate without further development. Some new possible apparatus and means for measuring or aiding in measuring bedload discharge are small pit samplers, ultrasonic sounders, pressure transducers, and photography. A small pit sampler for measuring bedload discharge was designed to provide self-placement and portability ; however, its practicability and efficiency are undetermined. Exploratory films show that by using slowmotion photography the discharge of particles larger than about pea size can be determined provided the flow is clear; however, photography generally is not practical. Ultrasonic sounders provide continuous and accurate data on bed configuration and dune movement for use in equations that were developed for computing the bedload discharge. Computations with the equations indicate that the interpretation of the sounding data needs further study. Pressure transducers placed beneath the bed surface possibly can be used to provide information on dune movement; however, their installation would be difficult. The time required for collecting data on bed configuration and dune movement throughout a cross section could be substantially reduced by using several transducers simultaneously in conjunction with an ultrasonic sounder. A modified ultrasonic sounder that provides information on the shape and velocity of large particles and a method for determining the discharge of such particles were proposed; the method seems most feasible for particles of high sphericity.

Water Supply Paper↗
USGS1967

Form and stability of aluminum hydroxide complexes in dilute solution

Laboratory studies of solutions 4.53 x 10 -4 to 4.5 x 10 -5 molal (12.2-1.2 ppm) in aluminum, in 0.01 molal sodium perchlorate, were conducted to obtain information as to the probable behavior of aluminum in natural water. When the solutions were brought to pH 7.5-9.5 and allowed to stand for 24 hours, a precipitate was obtained which was virtually amorphous as shown by X-rays, and which had a solubility equivalent to that of boehmite. This precipitate had a hydrolysis constant (*Ks4) of 1.93 x 10 -13a. When solutions were allowed to stead at this pH range for 10 days, their precipitates gave the X-ray pattern of bayerite (*Ks4 = 1.11 > (10- 4). These hydrolysis constants were obtained at 25?C. and corrected to zero ionic strength and are in close agreement with other published values. The predominant dissolved form in this pH range is Al(OH) -4. Below neutral pH (7.0) the dissolved aluminum species consist of octahedral units in which each aluminum ion is surrounded by six water molecules or hydroxide ions. Single units such as Al(OH2)6 + 3 and AlOH(OH2)5+2 are most abundant below pH 5.0, and where the molar ratio (r) of combined hydroxide to total dissolved aluminum is low. When r is greater than 1.0, polymerization of the octahedral units occurs. When r is between 2.0 and 3.0, solutions aged for 10 days or more contained colloidal particles between 0.10 and 0.45 ? in diameter. Particles whose diameters were greater than 0.10 ? were identified by X-ray diffraction as gibbsite. Particles smaller than 0.10 ? were also present and were shown by means of the electron microscope to have a hexagonal crystal pattern. Structured material consisting of sheets of coalesced six-membered rings of aluminum ions held together by double OH bridges has a distinctive kinetic behavior. This property was used to determine amounts of polymerized material in solutions having r between 1.0 and 3.0 after aging times ranging from a few hours to more than 4 months. Aging increased the size and orderliness of the polymeric aggregates and was accompanied by a decrease in the pH of the solution. The kinetic experiments and stoichiometric data for solutions aged for long periods provided a means of determining activities of polymerized aluminum. From these values the solubility product for microcrystalline gibbsite was determined to be 2.24 x 10 -3, and its free energy of formation, -? 272.3 0.4 kcal per mole. Where polymerization was observed, the process did not stop with small polynuclear complexes containing a few aluminum ions, but proceeded with aging until macromolecules or colloidal-sized particles were formed.

Water Supply Paper↗
USGS1973

Chemical interactions of aluminum with aqueous silica at 25 degrees Celsius

Solutions containing from 10 -5 to 10 -2 moles per liter of aluminum and dissolved silica in various ratios were aged at pH levels between 4 and 10 at 25?C. A colloidal amorphous product having the composition of halloysite was produced in most solutions. It had a consistent and reversible equilibrium solubility equivalent to a standard free energy of formation of -8974 ? 1.0 kcal per mole for the formula A12Si2O5(OH)4. Some aging times were longer than 4 years, but most solutions gave consistent solubilities after only a few months of aging. Where silica concentrations were below about 10 -4 molar, microcrystalline gibbsite was formed below pH 6.0 and crystalline bayerite above pH 7.0, but only after much longer aging than was required for crystallization in silica-free solutions. Electron micrographs and diffraction patterns of the synthesized material indicate some crystallinity in the aluminosilicate, but no X-ray diffraction patterns could be obtained even in the material aged 4 years. Solubility relationships for solutions containing fluoride as well as silica and aluminum are explainable by using cryolite stabilities determined in previous work. Aluminum contents of 51 samples of water analyzed for other purposes are in reasonable agreement with the assumption of equilibrium with amorphous clay mineral species similar to the material synthesized in this work. Solubility calculations are summarized graphically for solutions of ionic strength of 0.01 and 0.10.

Water Supply Paper↗
USGS1975

Reactions of aqueous aluminum species at mineral surfaces

Aqueous aluminum solutions containing 4.5 ? 10 4 molar aluminum in 0.01 molar NaC104 were partly neutralized with NaOH to give OH:A1 mole ratios from 1.40 to 2.76. Measured amounts of montmorillonite, kaolinite, volcanic ash, or feldspathic sand were added to provide an area of inert surface. Reactions that occurred during 100 days of aging were compared with those in similar solutions without added surfaces, studied in earlier work. Adsorption of monomeric species Al(H20)6+3, AlOH(H2O)5+2, and Al(OH)2(H2O 4? on the added surfaces follows a cation exchange mass law equilibrium model, and adsorption is essentially complete in 1 hour. Only minor changes in monomeric aluminum species occurred after that. Rapid adsorption of polynuclear aluminum hydroxide species also occurs and follows the pattern of the Langmuir adsorption isotherm. In the absence of surfaces, the polynuclear ions slowly increase in size and become microcrystalline gibbsite during aging. Electron micrographs showed microcrystalline gibbsite was present or surfaces after aging only 2 days. However, the analytical data suggest this material must have been adsorbed after it had already attained a near-crystalline state. Adsorbed polynuclear aluminum hydroxide species were not extensively converted to microcrystalline gibbsite during 100 days of aging.

Water Supply Paper↗
USGS1975

Effects of organic solutes on chemical reactions of aluminum

Concentrations of organic matter in the general range of 1-10 milligrams per litre organic carbon are common in natural water, and many naturally occurrin7 organic compounds form aluminum complexes. The aluminum concentrations in near-neutral pH solutions may be 10-100 times higher than the values predicted from solubility data if formation of such organic complexes is ignored. The processes of polymerization of aluminum hydroxide and precipitation of gibbsite are inhibited by the presence of the organic flavone compound quercetin in concentrations as low as 10 x -5.3 mole per litre. Quercetin forms a complex, with a probable molar ratio of 1:2 aluminum to quercetin, that has a formation constant (f12) of about 10 12. A complex with a higher aluminum-quercetin ratio also was observed, but this material tends to evolve into a compound of low solubility that removes aluminum from solution. In the presence of both dissolved aluminum and aqueous silica, low concentrations of quercetin improved the yield of crystallized kaolinite and halloysite. Small amounts of well-shaped kaolinite and halloysite crystals were identified by electron microscopy in solutions with pH's in the range 6.5-8.5 after 155 days aging in one experimer t and 481 days aging in a repeated experiment. The bulk of the precipitated material was amorphous to X-rays, and crystalline material was too small a proportion of the total to give identifiable X-ray diffraction peaks. The precipitates had aluminum-silicon ratios near 1, and their solubility corresponded to that found by Hem, Roberson, Lind, and Polzer (1973) for similar aluminosilicate precipitated in the absence of organic solutes. The improved yield of crystalline material obtained in the presence of quercetin probably is the result of the influence of the organic compound on the aluminum hydroxide polymerization process. Natural water containing color imparted by organic material tends to be higher in aluminum than would be predicted by pH, silica concentrations, and solubility data for inorganic aluminum species.

Water Supply Paper↗
USGS1983

Acoustic systems for the measurement of streamflow

The acoustic velocity meter (AVM), also referred to as an ultrasonic flowmeter, has been an operational tool for the measurement of streamflow since 1965. Very little information is available concerning AVM operation, performance, and limitations. The purpose of this report is to consolidate information in such a manner as to provide a better understanding about the application of this instrumentation to streamflow measurement. AVM instrumentation is highly accurate and nonmechanical. Most commercial AVM systems that measure streamflow use the time-of-travel method to determine a velocity between two points. The systems operate on the principle that point-to-point upstream travel-time of sound is longer than the downstream travel-time, and this difference can be monitored and measured accurately by electronics. AVM equipment has no practical upper limit of measurable velocity if sonic transducers are securely placed and adequately protected. AVM systems used in streamflow measurement generally operate with a resolution of ?0.01 meter per second but this is dependent on system frequency, path length, and signal attenuation. In some applications the performance of AVM equipment may be degraded by multipath interference, signal bending, signal attenuation, and variable streamline orientation. Presently used minicomputer systems, although expensive to purchase and maintain, perform well. Increased use of AVM systems probably will be realized as smaller, less expensive, and more conveniently operable microprocessor-based systems become readily available. Available AVM equipment should be capable of flow measurement in a wide variety of situations heretofore untried. New signal-detection techniques and communication linkages can provide additional flexibility to the systems so that operation is possible in more river and estuary situations.

Water Supply Paper↗
USGS2020

Characterization of feed coals and coal combustion byproducts from the Wyodak-Anderson coal zone, Powder River Basin, Wyoming

The U.S. Geological Survey (USGS) determined the physical and chemical properties of more than 260 feed coal and coal combustion byproducts from two coal-fired power plants. These plants utilized a low-sulfur (0.23-0.47 wt. % S) and low ash (4.9-6.3 wt. % ash) subbituminous coal from the Wyodak-Anderson coal zone in the Tongue River Member of the Paleocene Fort Union Formation, Powder River Basin, Wyoming. Fifty-three samples of bituminous coal were collected and analyzed from a Kentucky power plant, which used several sources of bituminous coals from the Appalachian and Illinois Basins. Based on scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses of feed coal samples collected and analyzed from 1996 through the late 2000s, two mineral suites were identified: (1) a primary or detrital suite consisting of quartz (including beta-form grains), biotite, feldspar, and minor zircon; and (2) a secondary authigenic mineral suite containing alumino-phosphates (crandallite and gorceixite), kaolinite, carbonates (calcite and dolomite), quartz, anatase, barite, and pyrite. The detrital mineral suite is interpreted, in part, to be of volcanic origin, whereas the authigenic mineral suite is interpreted, in part, to be the result of the alteration of the volcanic minerals. The mineral suites have contributed to the higher amounts of barium, calcium, magnesium, phosphorus, sodium, strontium, and titanium in the Powder River Basin feed coals in comparison to eastern US coals. XRD analysis indicates that (1) fly ash is mostly aluminate glass, perovskite, lime, gehlenite, quartz, and phosphates with minor amounts of periclase, anhydrite, hematite, and spinel group minerals; and (2) bottom ash is predominantly quartz, plagioclase (albite and anorthite), pyroxene (augite and fassaite), rhodonite, and akermanite, and spinel group minerals. Microprobe and SEM analyses of fly ash samples revealed quartz, zircon, and monazite, euhedral laths of corundum with merrillite, hematite, dendritic spinels/ferrites, wollastonite, and periclase. The abundant calcium and magnesium mineral phases in the fly ash are attributed to the alteration of carbonate, clay, and phosphate minerals in the feed coal during combustion. The calcium- and magnesium-rich and alumino-phosphate mineral phases in the coal combustion byproducts can be attributed to volcanic minerals deposited in peat-forming mires. Dissolution and alteration of these detrital volcanic minerals occurred either in the peat-forming stage or during coalification and diagenesis, resulting in the authigenic mineral suite. The presence of free lime (CaO) in fly ash produced from Wyodak-Anderson coal acts as a self-contained “scrubber” for SO 3 , where CaO + SO 3 form anhydrite either during combustion or in the upper parts of the boiler. Considering the high lime content in the fly ash and the resulting hydration reactions after its contact with water, there is little evidence that major amounts of leachable metals are mobilized in the disposal or utilization of this fly ash.

Wyoming↗
USGS1989

Gill tissue reactions in walleye Stizostedion vitreum vitreum and common carp Cyprinus carpio to glochidia of the freshwater mussel Lampsilis radiata siliquoidea

The glochidia of many freshwater mussels, which are obligate parasites on the gills, fins, and other body parts of specific fishes, attach to a suitable host, become encapsulated, and develop to the free-living juvenile stage. Using light and electron microscopy we compared gill tissue reactions in a suitable host (walleye Stizostedion vitreum vitreum ) and unsuitable host (common carp Cyprinus carpio ) infected with Lampsilis radiata siliquoidea . Encapsulation of glochidia on walleye gills was completed by 6 h post-infection at 20 to 22°C. Capsular formation and compaction were accompanied by a general increase in epithelioid cells. Fibrotic material appeared in capsules at about 48 h and virtually filled capsular cells from about Day 5 to Day 11 post-infection. Liberation of juvenile mussels was accompanied by thinning of the capsule from about Day 11 to Day l7. Although glochidia attached to the gills of common carp, few became encapsulated. By 48 h post-infection, preliminary capsular growth was evident and necrotic cells and cellular debris appeared at the edges of the growth. However, all glochidia were sloughed from carp gills by 60 h. Host specificity of L. radiata siliquoidea apparently depended on a combination of the attachment response of glochidia, differences in the encapsulation process, and tissue reactions in the fish.

Diseases of Aquatic Organisms↗