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Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

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At least 1,351 records · Page 75Linked to original sources

USGS2012

Dissipation of Titans north polar cloud at northern spring equinox

Saturn's Moon Titan has a thick atmosphere with a meteorological cycle. We report on the evolution of the giant cloud system covering its north pole using observations acquired by the Visual and Infrared Mapping Spectrometer onboard the Cassini spacecraft. A radiative transfer model in spherical geometry shows that the clouds are found at an altitude between 30 and 65 km. We also show that the polar cloud system vanished progressively as Titan approached equinox in August 2009, revealing at optical wavelengths the underlying sea known as Kraken Mare. This decrease of activity suggests that the north-polar downwelling has begun to shut off. Such a scenario is compared with the Titan global circulation model of Rannou et al. (2006) , which predicts a decrease of cloud coverage in northern latitudes at the same period of time.

Planetary and Space Science↗

USGS1994

A toxic equivalency factor scale for polychlorinated dibenzofurans

The ethoxyresorufin O -deethylase (EROD) induction of 20 polychiorinated dibenzofurans (PCDFs) was examined in the H4IIE rat hepatoma cell bioassay. The selection of the compounds tested was based on a multivariate chemical characterization laying the groundwork for covering the whole chemical series of PCDFs. The EROD induction potency was found to vary in ED50 values from 25 to 100,000,000 pg/mg, i.e., nearly seven orders of magnitude. The response of the bioassay was calibrated against the 2,3,7,8-tetrachlorodibenzo- p -dioxin, enabling the corresponding toxic equivalency factors (TEFs) to be calculated. In order to establish a quantitative structure-activity relationship (QSAR) for the TEF values, 37 physicochemical descriptor variables were used to chemically characterize the 87 tetra- to octachlorinated PCDFs. Using partial least-squares modeling on a training set of 10 congeners, a QSAR model with sound predictive power was obtained. The QSAR model was validated with a validation set of additional 10 congeners. The predicted TEFs indicate that a large number of congeners are potent EROD inducers.

Toxicological Sciences↗

USGS2018

Exposed subsurface ice sheets in the Martian mid-latitudes

Thick deposits cover broad regions of the Martian mid-latitudes with a smooth mantle; erosion in these regions creates scarps that expose the internal structure of the mantle.We investigated eight of these locations and found that they expose deposits of water ice that can be >100 meters thick, extending downward from depths as shallow as 1 to 2 meters below the surface.The scarps are actively retreating because of sublimation of the exposed water ice.The ice deposits likely originated as snowfall during Mars’ high-obliquity periods and have now compacted into massive, fractured, and layered ice.We expect the vertical structure of Martian ice-rich deposits to preserve a record of ice deposition and past climate.

Science↗

USGS1989

Turbidity-current channels in Queen Inlet, Glacier Bay, Alaska

Queen Inlet is unique among Glacier Bay fjords because it alone has a branching channel system incised in the Holocene sediment fill of the fjord floor. Bathymetry and seismic-reflection profiles show that four channels begin on, or at the base of, the delta front of this marine-outwash fjord. By midpoint of the fjord, these channels have merged into one main channel that extends the length of the fjord. The main channel cuts deeply into the scarp that separates this hanging tributary from the West Arm of Glacier Bay. The Queen Inlet channel ends on the main fjord floor as several small distributaries that form part of a lobate-fan deposit. Sand from the channel and lobate fan, in contrast to fjord-floor mud, plus steep truncated channel walls indicate that turbidity currents created this apparently active channel system. Queen Inlet and other known channel-containing fjords are marine-outwash fjords; the tidewater glacial fjords do not have steep delta fronts on which slides are generated and may not have a sufficient reservoir of potentially unstable coarse sediment to generate channel-cutting turbidity currents. Presence or absence of channels, as revealed in the ancient rock record, may be one criterion for interpreting types of fjords.

Alaska↗

USGS2015

Nelson's big horn sheep ( Ovis canadensis nelsoni ) trample Agassiz's desert tortoise ( Gopherus agassizii ) burrow at a California wind energy facility

Research on interactions between Agassiz's desert tortoises ( Gopherus agassizii ) and ungulates has focused exclusively on the effects of livestock grazing on tortoises and their habitat (Oldemeyer, 1994). For example, during a 1980 study in San Bernardino County, California, 164 desert tortoise burrows were assessed for vulnerability to trampling by domestic sheep ( Ovis aries ). Herds of grazing sheep damaged 10% and destroyed 4% of the burrows (Nicholson and Humphreys 1981). In addition, a juvenile desert tortoise was trapped and an adult male was blocked from entering a burrow due to trampling by domestic sheep. Another study found that domestic cattle ( Bos taurus ) trampled active desert tortoise burrows and vegetation surrounding burrows (Avery and Neibergs 1997). Trampling also has negative impacts on diversity of vegetation and intershrub soil crusts in the desert southwest (Webb and Stielstra 1979). Trampling of important food plants and overgrazing has the potential to create competition between desert tortoises and domestic livestock (Berry 1978; Coombs 1979; Webb and Stielstra 1979).

Bulletin of the Southern California Academy of Sci↗

USGS2015

Archive of Sidescan Sonar and Swath Bathymetry Data Collected During USGS Cruise 13CCT04 Offshore of Petit Bois Island, Gulf Islands National Seashore, Mississippi, August 2013

In August of 2013, the U.S. Geological Survey conducted a geophysical survey offshore of Petit Bois Island, Mississippi. This effort was part of the U.S. Geological Survey Gulf of Mexico Science Coordination partnership with the U.S. Army Corps of Engineers to assist the Mississippi Coastal Improvements Program and the Northern Gulf of Mexico Ecosystem Change and Hazards Susceptibility Project, by mapping the shallow geologic stratigraphic framework of the Mississippi Barrier Island Complex. This geophysical survey will provide additional data necessary for scientists to define, interpret, and provide baseline bathymetry and seafloor habitat for this area, and to aid scientists in predicting future geomorphological changes of the islands with respect to climate change, storm impact, and sea-level rise. Furthermore, these data will provide information for barrier island restoration, particularly in Camille Cut, and protection for the historical Fort Massachusetts on Ship Island, Mississippi. The geophysical data were collected during one cruise ( USGS Field Activity Numbers 13CCT04 ) aboard the Research Vessel Tommy Munro offshore along the gulf side of Petit Bois Island, Gulf Islands National Seashore, Mississippi. Data were acquired with the following equipment: a Systems Engineering and Assessment, Ltd., SWATH plus interferometric sonar (468 kilohertz (kHz)), an EdgeTech 424 (4-24 kHz), an EdgeTech 525i chirp subbottom profiling system, and a Klein 3900 sidescan sonar system. This report serves as an archive of the processed interferometric swath bathymetry and sidescan sonar data. Geographic information system data products include an interpolated digital elevation model, an acoustic backscatter mosaic, trackline maps, and point data files. Additional files include error analysis maps, Field Activity Collection System logs, and formal Federal Geographic Data Committee metadata. NOTE: These data are scientific in nature and are not to be used for navigation. Any use of trade names is for descriptive purposes only and does not imply endorsement by the U.S. Government.

Mississippi↗

USGS1995

40Ar/39Ar and 18O/16O studies of the Chegem ash-flow caldera and the Eldjurta Granite: Cooling of two late Pliocene igneous bodies in the Greater Caucasus Mountains, Russia

Volcanic and intrusive rocks of the Chegem caldera and the nearby Eldjurta (Eldzhurtinskiy) Granite record a late Pliocene episode of silicic magmatism in the north-central Caucasus Mountains. Surface exposures, created by the recent rapid uplift and erosion of the Caucasus Mountains, span a 2 km vertical section of Chegem caldera fill and 1150 m of the Eldjurta Granite; cored mineral-exploration drillholes in the Eldjurta Granite extend the sampling to a depth of 4 km. The unique sampling range available in these two young igneous bodies affords an excellent opportunity to study their denudation and cooling histories, which we examine by means of 40 Ar/ 39 Ar and 18 O/ 16 O measurements on an extensive sample suite. Total-fusion biotite and sanidine ages from eight Chegem Tuff samples, both intracaldera and outflow, are analytically indistinguishable with a weighted mean of 2.82 ± 0.02 Ma. A cross-cutting granodiorite porphyry intrusion has a sanidine total fusion age of 2.84 ± 0.03 Ma, and whole-rock incremental heating of a post-caldera andesite flow, which caps the caldera fill, yields an age of 2.82 ± 0.02 Ma. Thus, caldera formation and post-caldera resurgence and volcanism all occurred within a very short time (< 50,000 yr). Biotite total-fusion ages of ten Eldjurta Granite samples, including seven from ∼ 500 m intervals in the 4 km deep drillhole, show a systematic linear decrease in age with depth from 1.90 Ma near the roof contact of the granite to 1.56 Ma at a depth of 3700 m. Assuming these ages were set at the same temperature, this age/depth gradient implies an isotherm migration rate of 13 mm/yr between 1.90 and 1.56 Ma. This migration rate is due to a combination of rapid denudation and downward relaxation of isotherms, with cooling rates between 200 and 500°C/Ma during this period. Oxygen isotopic compositions of quartz, K-feldspar, plagioclase and biotite from the drillhole samples below the 800 m depth are fairly uniform and record primary igneous δ 18 O values with little evidence for subsolidus hydrothermal activity. However, in surface outcrop samples and in the shallowest drillhole sample, mineral δ 18 O values have been lowered by up to 3‰ by interaction with an external (meteoric-hydrothermal?) fluid. The primary mineral δ 18 O values of the Eldjurta Granite are distinctly higher than the corresponding phenocryst δ 18 O values in the Chegem volcanic rocks, indicating that the two bodies evolved as separxate magma batches.

Caucasus Mountains, Chegem Caldera↗

USGS2014

Quaternary landscape development, alluvial fan chronology and erosion of the Mecca Hills at the southern end of the San Andreas Fault zone

Quantitative geomorphic analysis combined with cosmogenic nuclide 10 Be-based geochronology and denudation rates have been used to further the understanding of the Quaternary landscape development of the Mecca Hills, a zone of transpressional uplift along the southern end of the San Andreas Fault, in southern California. The similar timing of convergent uplifts along the San Andreas Fault with the initiation of the sub-parallel San Jacinto Fault suggest a possible link between the two tectonic events. The ages of alluvial fans and the rates of catchment-wide denudation have been integrated to assess the relative influence of climate and tectonic uplift on the development of catchments within the Mecca Hills. Ages for major geomorphic surfaces based on 10 Be surface exposure dating of boulders and 10 Be depth profiles define the timing of surface stabilization to 2.6 +5.6/–1.3 ka (Qyf1 surface), 67.2 ± 5.3 ka (Qvof2 surface), and 280 ± 24 ka (Qvof1 surface). Comparison of 10 Be measurements from active channel deposits (Qac) and fluvial terraces (Qt) illustrate a complex history of erosion, sediment storage, and sediment transport in this environment. Beryllium-10 catchment-wide denudation rates range from 19.9 ± 3.2 to 149 ± 22.5 m/Ma and demonstrate strong correlations with mean catchment slope and with total active fault length normalized by catchment area. The lack of strong correlation with other geomorphic variables suggests that tectonic uplift and rock weakening have the greatest control. The currently measured topography and denudation rates across the Mecca Hills may be most consistent with a model of radial topographic growth in contrast to a model based on the rapid uplift and advection of crust.

California↗

USGS2017

Rodenticide incidents of exposure and adverse effects on non-raptor birds

Interest in the adverse effects of rodenticides on birds has focused primarily on raptors. However, non-raptor birds are also poisoned (rodenticide exposure resulting in adverse effects including mortality) by rodenticides through consumption of the rodenticide bait and contaminated prey. A literature search for rodenticide incidents (evidence of exposure to a rodenticide, adverse effects, or exposure to placebo baits) involving non-raptor birds returned 641 records spanning the years 1931 to 2016. The incidents included 17 orders, 58 families, and 190 non-raptor bird species. Nineteen anticoagulant and non-anticoagulant rodenticide active ingredients were associated with the incidents. The number of incidents and species detected were compared by surveillance method. An incident was considered to have been reported through passive surveillance if it was voluntarily reported to the authorities whereas the report of an incident found through field work that was conducted with the objective of documenting adverse effects on birds was determined to be from active surveillance. More incidents were reported from passive surveillance than with active surveillance but a significantly greater number of species were detected in proportion to the number of incidents found through active surveillance than with passive surveillance (z = 7.61, p < 0.01). Results suggest that reliance on only one surveillance method can underestimate the number of incidents that have occurred and the number of species that are affected. Although rodenticides are used worldwide, incident records were found from only 15 countries. Therefore, awareness of the breadth of species diversity of non-raptor bird poisonings from rodenticides may increase incident reportings and can strengthen the predictions of harm characterized by risk assessments.

Science of the Total Environment↗

USGS2014

Geologic implications of gas hydrates in the offshore of India: results of the National Gas Hydrate Program Expedition 01

The Indian National Gas Hydrate Program Expedition 01 (NGHP-01) is designed to study the occurrence of gas hydrate along the passive continental margin of the Indian Peninsula and in the Andaman convergent margin, with special emphasis on understanding the geologic and geochemical controls on the occurrence of gas hydrate in these two diverse settings. The NGHP-01 expedition established the presence of gas hydrates in the Krishna-Godavari and Mahanadi Basins, and the Andaman Sea. The expedition discovered in the Krishna-Godavari Basin one of the thickest gas hydrate accumulations ever documented, in the Andaman Sea one of the thickest and deepest gas hydrate stability zones in the world, and established the existence of a fully developed gas hydrate petroleum system in all three basins. The primary goal of NGHP-01 was to conduct scientific ocean drilling/coring, logging, and analytical activities to assess the geologic occurrence, regional context, and characteristics of gas hydrate deposits along the continental margins of India. This was done in order to meet the long-term goal of exploiting gas hydrate as a potential energy resource in a cost effective and safe manner. During its 113.5-day voyage, the D/V JOIDES Resolution cored and/or drilled 39 holes at 21 sites (1 site in Kerala-Konkan, 15 sites in Krishna-Godavari, 4 sites in Mahanadi, and 1 site in the Andaman deep offshore area), penetrated more than 9250 m of sedimentary section, and recovered nearly 2850 m of core. Twelve holes were logged with logging-while-drilling (LWD) tools and an additional 13 holes were wireline logged. The science team utilized extensive on-board laboratory facilities to examine and prepare preliminary reports on the physical properties, geochemistry, and sedimentology of all the data collected prior to the end of the expedition. Samples were also analyzed in additional post-expedition shore-based studies conducted in leading laboratories around the world. One of the specific objectives of this expedition was to test gas hydrate formation models and constrain model parameters, especially those that account for the formation of concentrated gas hydrate accumulations. The necessary data for characterizing the occurrence of in situ gas hydrate, such as interstitial water chlorinities, core-derived gas chemistry, physical and sedimentological properties, thermal images of the recovered cores, and downhole measured logging data (LWD and/or conventional wireline log data), were obtained from most of the drill sites established during NGHP-01. Almost all of the drill sites yielded evidence for the occurrence of gas hydrate; however, the inferred in situ concentration of gas hydrate varied substantially from site to site. For the most part, the interpretation of downhole logging data, core thermal images, interstitial water analyses, and pressure core images from the sites drilled during NGHP-01 indicate that the occurrence of concentrated gas hydrate is mostly associated with the presence of fractures in the sediments, and in some limited cases, by coarser grained (mostly sand-rich) sediments.

Marine and Petroleum Geology↗

USGS2009

Three short videos by the Yellowstone Volcano Observatory

This is a collection of videos of unscripted interviews with Jake Lowenstern, who is the Scientist in Charge of the Yellowstone Volcano Observatory (YVO). YVO was created as a partnership among the U.S. Geological Survey (USGS), Yellowstone National Park, and University of Utah to strengthen the long-term monitoring of volcanic and earthquake unrest in the Yellowstone National Park region. Yellowstone is the site of the largest and most diverse collection of natural thermal features in the world and the first National Park. YVO is one of the five USGS Volcano Observatories that monitor volcanoes within the United States for science and public safety. These video presentations give insights about many topics of interest about this area. Title: Yes! Yellowstone is a Volcano An unscripted interview, January 2009, 7:00 Minutes Description: USGS Scientist-in-Charge of Yellowstone Volcano Observatory, Jake Lowenstern, answers the following questions to explain volcanic features at Yellowstone: 'How do we know Yellowstone is a volcano?', 'What is a Supervolcano?', 'What is a Caldera?','Why are there geysers at Yellowstone?', and 'What are the other geologic hazards in Yellowstone?' Title: Yellowstone Volcano Observatory An unscripted interview, January 2009, 7:15 Minutes Description: USGS Scientist-in-Charge of Yellowstone Volcano Observatory, Jake Lowenstern, answers the following questions about the Yellowstone Volcano Observatory: 'What is YVO?', 'How do you monitor volcanic activity at Yellowstone?', 'How are satellites used to study deformation?', 'Do you monitor geysers or any other aspect of the Park?', 'Are earthquakes and ground deformation common at Yellowstone?', 'Why is YVO a relatively small group?', and 'Where can I get more information?' Title: Yellowstone Eruptions An unscripted interview, January 2009, 6.45 Minutes Description: USGS Scientist-in-Charge of Yellowstone Volcano Observatory, Jake Lowenstern, answers the following questions to explain volcanic eruptions at Yellowstone: When was the last supereruption at Yellowstone?', 'Have any eruptions occurred since the last supereruption?', 'Is Yellowstone overdue for an eruption?', 'What does the magma below indicate about a possible eruption?', 'What else is possible?', and 'Why didn't you think the Yellowstone Lake earthquake swarm would lead to an eruption?'

Wyoming↗

USGS1995

Modeling photosynthetically active radiation in water of Tampa Bay, Florida, with emphasis on the geometry of incident irradiance

A model is developed that uses a simplified geometric description of incident direct solar beam and diffuse skylight. The model incorporates effects of solar elevation angle and cloudiness on the amount of in-air photosynthetically active radiation (PAR) that passes through the air-water interface and on K0 in waters of relatively low turbidity. The value of K0 was estimated to vary as much as 41% on a clear summer day due to changes in solar elevation angle. The model was used to make estimates of the depth to which sea-grasses might receive adequate light for survival for a range of values of K0. -from Authors

Estuarine, Coastal and Shelf Science↗

USGS2010

Temporal and spatial distributions of sediment mercury at salt pond wetland restoration sites, San Francisco Bay, CA, USA

Decommissioned agricultural salt ponds within south San Francisco Bay, California, are in the process of being converted to habitat for the benefit of wildlife as well as water management needs and recreation. Little is known of baseline levels of contaminants in these ponds, particularly mercury (Hg), which has a well established legacy in the Bay. In this study we described spatial and short-term temporal variations in sediment Hg species concentrations within and among the Alviso and Eden Landing salt ponds in the southern region of San Francisco Bay. We determined total Hg (Hg t ) and methylmercury (MeHg) in the top 5 cm of sediment of most ponds in order to establish baseline conditions prior to restoration, sediment Hg t concentrations in a subset of these ponds after commencement of restoration, and variation in MeHg concentrations relative to sediment Hg t , pH, and total Fe concentrations and water depth and salinity in the subset of Alviso ponds. Inter-pond differences were greatest within the Alviso pond complex, where sediment Hg t concentrations averaged (arithmetic mean) 0.74 [mu]g/g pre and 1.03 [mu]g/g post-restoration activity compared to 0.11 [mu]g/g pre and post at Eden Landing ponds. Sediment Hg t levels at Alviso were fairly stable temporally and spatially, whereas MeHg levels were variable relative to restoration activities across time and space. Mean (arithmetic) sediment MeHg concentrations increased (2.58 to 3.03 ng/g) in Alviso and decreased (2.20 to 1.03 ng/g) in Eden Landing restoration ponds during the study. Differences in MeHg levels were related to water depth and pH, but these relationships were not consistent between years or among ponds and were viewed with caution. Factors affecting MeHg levels in these ponds (and in general) are highly complex and require in-depth study to understand.

Science of the Total Environment↗

USGS2014

Methylmercury production in sediment from agricultural and non-agricultural wetlands in the Yolo Bypass, California, USA

As part of a larger study of mercury (Hg) biogeochemistry and bioaccumulation in agricultural (rice growing) and non-agricultural wetlands in California's Central Valley, USA, seasonal and spatial controls on methylmercury (MeHg) production were examined in surface sediment. Three types of shallowly-flooded agricultural wetlands (white rice, wild rice, and fallow fields) and two types of managed (non-agricultural) wetlands (permanently and seasonally flooded) were sampled monthly-to-seasonally. Dynamic seasonal changes in readily reducible ‘reactive’ mercury (Hg(II) R ), Hg(II)-methylation rate constants (k meth ), and concentrations of electron acceptors (sulfate and ferric iron) and donors (acetate), were all observed in response to field management hydrology, whereas seasonal changes in these parameters were more muted in non-agricultural managed wetlands. Agricultural wetlands exhibited higher sediment MeHg concentrations than did non-agricultural wetlands, particularly during the fall through late-winter (post-harvest) period. Both sulfate- and iron-reducing bacteria have been implicated in MeHg production, and both were demonstrably active in all wetlands studied. Stoichiometric calculations suggest that iron-reducing bacteria dominated carbon flow in agricultural wetlands during the growing season. Sulfate-reducing bacteria were not stimulated by the addition of sulfate-based fertilizer to agricultural wetlands during the growing season, suggesting that labile organic matter, rather than sulfate, limited their activity in these wetlands. Along the continuum of sediment geochemical conditions observed, values of k meth increased approximately 10,000-fold, whereas Hg(II) R decreased 100-fold. This suggests that, with respect to the often opposing trends of Hg(II)-methylating microbial activity and Hg(II) availability for methylation, microbial activity dominated the Hg(II)-methylation process, and that along this biogeochemical continuum, conditions that favored microbial sulfate reduction resulted in the highest calculated MeHg production potential rates. Rice straw management options aimed at limiting labile carbon supplies to surface sediment during the post-harvest fall–winter period may be effective in limiting MeHg production within agricultural wetlands.

California↗

USGS2024

Flow cytometric assessments of metabolic activity in bacterial assemblages provide insight into ecosystem condition along the Buffalo National River, Arkansas

The Buffalo National River (BNR), on karst terrain in Arkansas, is considered an extraordinary water resource. Water collected in Spring 2017 along BNR was metagenomically analyzed using 16S rDNA, and for 17 months (5/2017–11/2018), bacterial responses were measured in relation to nutrients sampled along a stretch of BNR near a concentrated animal feed operation (CAFO) on Big Creek. Because cell count and esterase activity can increase proportionally with organic enrichment, they were hypothesized to be elevated near the CAFO. Counts (colony forming units; CFUs) were different among sites for 73 % of the months; Big Creek generated highest CFUs 27 % of the time, with the closest downstream site at 13.3 %. Esterase activity was different among sites 94 % of the time, with Big Creek exhibiting lowest activity 71 % of the time. Over the months, activity was similar across sites at ~70 % active, except at Big Creek (56 %). The α-diversity of BNR microbial consortia near a wastewater treatment plant (WWTP) and the CAFO was related to distance from the WWTP and CAFO. The inverse relationship between high CFUs and low esterase activity at Big Creek ( r = −0.71) actuated in vitro exposures of bacteria to organic wastewater contaminants (OWC) previously identified in the watershed. Exponential-phase Escherichia coli (stock strain), Streptococcus suis (avirulent, from swine), and S. dysgalactiae (virulent, from silver carp, Hypophthalmichthys molitrix ) were incubated with atrazine, pharmaceuticals (17 α-ethynylestradiol and trenbolone), and antimicrobials (tylosin and butylparaben). Bacteria were differentially responsive. Activity varied with exposure time and OWC type, but not concentration; atrazine decreased it most. Taken together - the metagenomic taxonomic similarities along BNR, slightly higher bacterial growth and lower bacterial esterase at the CAFO, and the lab exposures of bacterial strains showing that OWC altered metabolism - the results indicated that bioactive OWC entering the watershed can strongly influence microbial processes in the aquatic ecosystem.

Science of the Total Environment↗

USGS2020

Biological effects of hydrocarbon degradation intermediates: Is the total petroleum hydrocarbon analytical method adequate for risk assessment?

In crude oil contaminant plumes, the dissolved organic carbon (DOC) is mainly hydrocarbon degradation intermediates only partly quantified by the diesel range total petroleum hydrocarbon (TPHd) method. To understand potential biological effects of degradation intermediates, we tested three fractions of DOC: (1) solid-phase extract (HLB); (2) dichloromethane (DCM-total) extract used in TPHd; and (3) DCM extract with hydrocarbons isolated by silica gel cleanup (DCM-SGC). Bioactivity of extracts from five wells spanning a range of DOC was tested using an in vitro multiplex reporter system that evaluates modulation of the activity of 46 transcription factors; extracts were evaluated at concentrations equivalent to the well water samples. The aryl hydrocarbon receptor (AhR) and pregnane X receptor (PXR) transcription factors showed the greatest upregulation, with HLB exceeding DCM-total, and no upregulation in the hydrocarbon fraction (DCM-SGC). The HLB extracts were further studied with HepG2 chemically activated luciferase expression (CALUX) in vitro assays at nine concentrations ranging from 40 to 0.01 times the well water concentrations. Responses decreased with distance from the source but were still present at two wells without detectable hydrocarbons. Thus, our in vitro assay results indicate that risks associated with degradation intermediates of hydrocarbons in groundwater will be underestimated when protocols that remove these chemicals are employed.

Minnesota↗

USGS1990

Solid-solution aqueous-solution equilibria: Thermodynamic theory and representation

Thorstenson and Plummer's (1977) "stoichiometric saturation' model is reviewed, and a general relation between stoichiometric saturation Kss constants and excess free energies of mixing is derived for a binary solid-solution B1-xCxA: GE = RT[ln Kss - xln(xKCA) - (l-x)ln((l-x)KBA)]. This equation allows a suitable excess free energy function, such as Guggenheim's (1937) sub-regular function, to be fitted from experimentally determined Kss constants. Solid-phase free energies and component activity-coefficients can then be determined from one or two fitted parameters and from the endmember solubility products KBA and KCA. A general form of Lippmann's (1977,1980) "solutus equation is derived from an examination of Lippmann's (1977,1980) "total solubility product' model. Lippmann's II or "total solubility product' variable is used to represent graphically not only thermodynamic equilibrium states and primary saturation states but also stoichiometric saturation and pure phase saturation states.

American Journal of Science↗

USGS2002

Operating the EOSDIS at the land processes DAAC managing expectations, requirements, and performance across agencies, missions, instruments, systems, and user communities

NASA developed the Earth Observing System (EOS) during the 1990'S. At the Land Processes Distributed Active Archive Center (LP DAAC), located at the USGS EROS Data Center, the EOS Data and Information System (EOSDIS) is required to support heritage missions as well as Landsat 7, Terra, and Aqua. The original system concept of the early 1990'S changed as each community had its say - first the managers, then engineers, scientists, developers, operators, and then finally the general public. The systems at the LP DAAC - particularly the largest single system, the EOSDIS Core System (ECS) - are changing as experience accumulates, technology changes, and each user group gains influence. The LP DAAC has adapted as contingencies were planned for, requirements and therefore plans were modified, and expectations changed faster than requirements could hope to be satisfied. Although not responsible for Quality Assurance of the science data, the LP DAAC works to ensure the data are accessible and useable by influencing systems, capabilities, and data formats where possible, and providing tools and user support as necessary. While supporting multiple missions and instruments, the LP DAAC also works with and learns from multiple management and oversight groups as they review mission requirements, system capabilities, and the overall operation of the LP DAAC. Stakeholders, including the Land Science community, are consulted regularly to ensure that the LP DAAC remains cognizant and responsive to the evolving needs of the user community. Today, the systems do not look or function as originally planned, but they do work, and they allow customers to search and order of an impressive amount of diverse data.

Conference Paper↗