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Characterization of the International Humic Substances Society standard and reference fulvic and humic acids by solution state carbon-13 (13C) and hydrogen-1 (1H) nuclear magnetic resonance spectrometry

Standard and reference samples of the International Humic Substances Society have been characterized by solution state carbon-13 and hydrogen-1 nuclear magnetic resonance (NMR) spectrometry. Samples included the Suwannee River, soil, and peat standard fulvic and humic acids, the Leonardite standard humic acid, the Nordic aquatic reference fulvic and humic acids, and the Summit Hill soil reference humic acid. Aqueous-solution carbon-13 NMR analyses included the measurement of spin-lattice relaxation times, measurement of nuclear Overhauser enhancement factors, measurement of quantitative carbon distributions, recording of attached proton test spectra, and recording of spectra under nonquantitative conditions. Distortionless enhancement by polarization transfer carbon-13 NMR spectra also were recorded on the Suwannee River fulvic acid in deuterated dimethyl sulfoxide. Hydrogen-1 NMR spectra were recorded on sodium salts of the samples in deuterium oxide. The carbon aromaticities of the samples ranged from 0.24 for the Suwannee River fulvic acid to 0.58 for the Leonardite humic acid.

Water-Resources Investigations Report↗

Geologic map of upper Eocene to Holocene volcanic and related rocks in the Cascade Range, Washington

Since 1979 the Geothermal Research Program of the U.S. Geological Survey has carried out a multidisciplinary research effort in the Cascade Range. The goal of this research is to understand the geology, tectonics, and hydrology of the Cascades in order to characterize and quantify geothermal resource potential. A major goal of the program is compilation of a comprehensive geologic map of the entire Cascade Range that incorporates modern field studies and that has a unified and internally consistent explanation. This map is one of a series presently being compiled that shows Cascade Range geology by fitting published and unpublished mapping into a province-wide scheme of lithostratigraphic units; map sheets of the Cascade Range in California and in Oregon complete the series. The complete series forms a guide to exploration and evaluation of the geothermal resources of the Cascade Range and will be useful for studies of volcanic hazards, volcanology, and tectonics. For geothermal reasons, the maps emphasize Quaternary volcanic rocks. Large igneous-related geothermal systems that have high temperatures are associated with Quaternary volcanic fields, and geothermal potential declines rapidly as age increases (Smith and Shaw, 1975). Most high-grade recoverable geothermal energy is likely to be associated with silicic volcanism less than 1 Ma. Lower grade (= lower temperature) geothermal resources may be associated with somewhat older rocks; however, volcanic rocks older than about 2 Ma are unlikely geothermal targets (Smith and Shaw, 1975).

Washington↗

Geologic map of Mount Mazama and Crater Lake Caldera, Oregon, including the database for the geologic map of Mount Mazama and Crater Lake Caldera, Oregon

Crater Lake partly fills one of the most spectacular calderas of the world, an 8-by-10-km basin more than 1 km deep formed by collapse of the volcano known as Mount Mazama (fig. 1) during a rapid series of explosive eruptions about 7,700 years ago. Having a maximum depth of 594 m, Crater Lake is the deepest lake in the United States. Crater Lake National Park, dedicated in 1902, encompasses 645 km2 of pristine forested and alpine terrain, including the lake itself, virtually all of Mount Mazama, and most of the area of the geologic map. The geology of the area was first described in detail by Diller and Patton (1902) and later by Williams (1942), whose vivid account led to international recognition of Crater Lake as the classic collapse caldera. Because of excellent preservation and access, Mount Mazama, Crater Lake caldera, and the deposits formed by the climactic eruption constitute a natural laboratory for study of volcanic and magmatic processes. For example, the climactic ejecta are renowned among volcanologists as evidence for systematic compositional zonation within a subterranean magma chamber. Mount Mazama's climactic eruption also is important as the source of the widespread Mazama ash, a useful Holocene stratigraphic marker throughout the Pacific Northwest, adjacent Canada, and offshore. A detailed bathymetric survey of the floor of Crater Lake in 2000 (Bacon and others, 2002) provides a unique record of postcaldera eruptions, the interplay between volcanism and filling of the lake, and sediment transport within this closed basin. Knowledge of the geology and eruptive history of the Mount Mazama edifice, greatly enhanced by the caldera wall exposures, gives exceptional insight into how large volcanoes of magmatic arcs grow and evolve. Lastly, the many smaller volcanoes of the High Cascades beyond the limits of Mount Mazama are a source of information on the flux of mantle-derived magma through the region. General principles of magmatic and eruptive processes revealed by the present study have been incorporated not only in scientific investigations elsewhere, but in the practical evaluation of hazards (Bacon and others, 1997b) and geothermal resources (Bacon and Nathenson, 1996) in the Crater Lake region. In addition to papers in scientific journals, field trip guides, and the hazard and geothermal reports, the major product of this long-term study of Mount Mazama is the geologic map. The map is unusual because it portrays bedrock (outcrop), surficial, and lake floor geology. Caldera wall geology is depicted in detail on the accompanying geologic panoramas.

Oregon↗

A condensed middle Cenomanian succession in the Dakota Sandstone (Upper Cretaceous), Sevilleta National Wildlife Refuge, Socorro County, New Mexico

The upper part of the Dakota Sandstone exposed on the Sevilleta National Wildlife Refuge, northern Socorro County, New Mexico, is a condensed, Upper Cretaceous, marine succession spanning the first five middle Cenomanian ammonite zones of the U.S. Western Interior. Farther north in New Mexico these five ammonite zones occur over a stratigraphic interval more than an order of magnitude thicker. The basal part of this marine sequence was deposited in Seboyeta Bay, an elongate east-west embayment into New Mexico that marked the initial transgression of the western shoreline of the Late Cretaceous seaway into New Mexico. The primary mechanism for condensing this section was nearshore, submarine erosion, although nondeposition played a minor role. The ammonite fossils from each zone are generally fragments of internal molds that are corroded on one side, indicating submarine burial, erosion of the prefossilized steinkern, and corrosion on the sea floor. In addition, the base of the condensed succession is marked by a thin bed that contains abundant, white-weathering, spherical to cylindrical phosphate nodules, many of which contain a cylindrical axial cavity of unknown origin. The nodules lie on the bedding surface of the highly burrowed, ridge-forming sandstone near the top of the Dakota and occur in the overlying breccia. The breccia consists of rip-up clasts of sandstone and eroded internal molds of the ammonite Conlinoceras tarrantense, the zonal index for the basal middle Cenomanian. The nodules below the breccia imply a time of erosion followed by nondeposition or sediment bypass during which the phosphatization occurred. The breccia implies a time of submarine erosion, probably storm-related. Remarkably, this condensed succession and the basal part of the overlying Mancos Shale tongue contain one of the most complete middle Cenomanian ammonite sequences in the U.S. Western Interior. Five of the six ammonite zones that characterize the middle Cenomanian of the Western Interior are found on Sevilleta National Wildlife Refuge. Only representatives of the second oldest zone are missing, although stratigraphically there is room for this zone. Fossils from each zone occur in stratigraphically separated beds; no zone overlaps with or is superimposed on another. Maps of the western shoreline of the seaway at the beginning and end of the time represented by the condensed succession show the progression of the Late Cretaceous seaway from embayment to ocean covering most of New Mexico. These maps, combined with the resolving power of the middle Cenomanian biostratigraphic framework, indicate that the southern shoreline of Seboyeta Bay, which was only a few miles south of Sevilleta National Wildlife Refuge, was virtually stationary for most of this time. This ensured that the refuge was under shallow, well-oxygenated, marine waters for much of middle Cenomanian time. It also ensured that deposited sediments would be subjected periodically to erosion by nearshore waves and currents. This report marks the first recorded occurrence in New Mexico of the following ammonite species: Acanthoceras muldoonense (zonal index), A. bellense (zonal index), Turrilites (Euturrilites) scheuchzerianus , Cunningtoniceras cf. C. cunningtoni , and Paraconlinoceras leonense . The occurrences of the zonal indices in the Dakota Sandstone on and to the south of the refuge increase not only their geographic distributions, but also the biostratigraphic resolution in the middle Cenomanian of New Mexico.

New Mexico↗

Coal resources, reserves and peak coal production in the United States

In spite of its large endowment of coal resources, recent studies have indicated that United States coal production is destined to reach a maximum and begin an irreversible decline sometime during the middle of the current century. However, studies and assessments illustrating coal reserve data essential for making accurate forecasts of United States coal production have not been compiled on a national basis. As a result, there is a great deal of uncertainty in the accuracy of the production forecasts. A very large percentage of the coal mined in the United States comes from a few large-scale mines (mega-mines) in the Powder River Basin of Wyoming and Montana. Reported reserves at these mines do not account for future potential reserves or for future development of technology that may make coal classified currently as resources into reserves in the future. In order to maintain United States coal production at or near current levels for an extended period of time, existing mines will eventually have to increase their recoverable reserves and/or new large-scale mines will have to be opened elsewhere. Accordingly, in order to facilitate energy planning for the United States, this paper suggests that probabilistic assessments of the remaining coal reserves in the country would improve long range forecasts of coal production. As it is in United States coal assessment projects currently being conducted, a major priority of probabilistic assessments would be to identify the numbers and sizes of remaining large blocks of coal capable of supporting large-scale mining operations for extended periods of time and to conduct economic evaluations of those resources.

International Journal of Coal Geology↗

Hydrodynamic model of the Colorado River, Glen Canyon Dam to Lees Ferry in Glen Canyon National Recreation Area, Arizona

The U.S. Geological Survey constructed a two-dimensional hydrodynamic model that was applied to a 15.8-mile tailwater reach of the Colorado River in Glen Canyon that begins 0.25 mile downstream from Glen Canyon Dam and extends to Lees Ferry in Glen Canyon National Recreation Area, Arizona. The model used the Flow and Sediment Transport with Morphological Evolution of Channels (FaSTMECH) solver in the International River Interface Cooperative (iRIC) modeling interface. The model grid was developed from a full channel digital elevation model derived by combining bathymetric and topographic data collected from March 2013 to February 2016. The model was used to predict water-surface elevations, depths, depth-averaged flow velocities, and bed shear stresses for discharges ranging from 1,000 to 70,000 cubic feet per second. Modeled water-surface elevations matched well with measured values at cross sections throughout the reach, with a mean absolute error of 0.14 meter over the range of typical discharge releases from Glen Canyon Dam. The mean error on discharge, a measure of how well the model solution converged, averaged 0.6 percent and did not exceed 2 percent over the range of discharges modeled. These results indicate that model predictions of hydraulic parameters are reasonably accurate and suitable for use for a variety of purposes, such as ecological and geomorphic modeling.

Arizona↗

The ShakeOut earthquake scenario: Verification of three simulation sets

This paper presents a verification of three simulations of the ShakeOut scenario, an M w 7.8 earthquake on a portion of the San Andreas fault in southern California, conducted by three different groups at the Southern California Earthquake Center using the SCEC Community Velocity Model for this region. We conducted two simulations using the finite difference method, and one by the finite element method, and performed qualitative and quantitative comparisons between the corresponding results. The results are in good agreement with each other; only small differences occur both in amplitude and phase between the various synthetics at ten observation points located near and away from the fault-as far as 150 km away from the fault. Using an available goodness-of-fit criterion all the comparisons scored above 8, with most above 9.2. This score would be regarded as excellent if the measurements were between recorded and synthetic seismograms. We also report results of comparisons based on time-frequency misfit criteria. Results from these two criteria can be used for calibrating the two methods for comparing seismograms. In those cases in which noticeable discrepancies occurred between the seismograms generated by the three groups, we found that they were the product of inherent characteristics of the various numerical methods used and their implementations. In particular, we found that the major source of discrepancy lies in the difference between mesh and grid representations of the same material model. Overall, however, even the largest differences in the synthetic seismograms are small. Thus, given the complexity of the simulations used in this verification, it appears that the three schemes are consistent, reliable and sufficiently accurate and robust for use in future large-scale simulations. ?? 2009 The Authors Journal compilation ?? 2009 RAS.

Geophysical Journal International↗

Network global navigation satellite system surveys to harmonize American and Canadian datum for the Lake Champlain Basin

Historically high flood levels were observed during flooding in Lake Champlain and the Richelieu River from late April through May 2011. Flooding was caused by record spring precipitation and snowmelt from the third highest cumulative snowfall year on record, which included a warm, saturated late spring snowpack. Flood stage was exceeded for a total of 67 days from April 13 to June 19, 2011. During this flooding, shoreline erosion and lake flood inundation were exacerbated by wind-driven waves associated with local fetch and lake-wide seiche effects. In May 2011, a new water-surface-elevation record was set for Lake Champlain. Peak lake-level water-surface elevations varied at the three U.S. Geological Survey lake-level gages on Lake Champlain in 2011. The May 2011 peak water-surface elevations for Lake Champlain ranged from 103.20 feet above the National Geodetic Vertical Datum of 1929 at the northern end of Lake Champlain (at its outlet into the Richelieu River at Rouses Point, New York) to 103.57 feet above the National Geodetic Vertical Datum of 1929 at the southern end of the Lake in Whitehall, New York. The water-surface elevations for the Richelieu River in Canada are referenced to a different vertical datum than are those in Lake Champlain in the United States, which causes difficulty in assessing real-time flood water-surface elevations and comparing of flood peaks in the Lake Champlain Basin in the United States and Canada. On March 19, 2012, as a result of the flood event of April and May 2011, the Governments of Canada and the United States asked the International Joint Commission to draft a plan of study to examine the causes and the effects of the spring 2011 flooding on Lake Champlain and the Richelieu River and develop potential mitigation measures. Specific challenges noted by the International Lake Champlain-Richelieu River Technical Working Group (established by the International Joint Commission) included harmonization of vertical datums within the drainage basin. Harmonization of the vertical datum discrepancy is needed for flood assessment and future efforts to model the flow of water through the Lake Champlain Basin in the United States and Canada. In April 2015, the U.S. Geological Survey and Environment Canada began a joint field effort with the goal of obtaining precise elevations representing a common vertical datum for select reference marks used to determine water-surface elevations throughout Lake Champlain and the Richelieu River. To harmonize the datum difference between the United States and Canada, Global Navigation Satellite System surveys were completed at nine locations in the Lake Champlain Basin to collect simultaneous satellite data. These satellite data were processed to produce elevations for two reference marks associated with dams and seven reference marks associated with active water-level gages (lake gages in Lake Champlain and streamgages in the Richelieu River) to harmonize vertical datums throughout the Lake Champlain Basin. The Global Navigation Satellite System surveys were completed from April 14 to 16, 2015, at locations ranging from southern Lake Champlain near Whitehall, New York, to the northern end of the Richelieu River in Sorel, Quebec, at its confluence with the St. Lawrence River in Canada. Lake-gage water-surface elevations determined during the 3 days of surveys were converted to water-surface elevations referenced to the North American Vertical Datum of 1988 by using calculated offsets and historical water-surface elevations. In this report, an “offset” refers to the adjustment that needs to be applied to published data from a particular gage to produce elevation data referenced to the North American Vertical Datum of 1988. Offsets presented in this report can be used in the evaluation of water-surface elevations in a common datum for Lake Champlain and the Richelieu River. In addition, the water-level data referenced to the common datum (as determined from the offsets) may be used to calibrate flow models and support future modeling studies developed for Lake Champlain and the Richelieu River.

New York, Quebec, Vermont↗

Fort Collins Science Center- Policy Analysis and Science Assistance Branch : Integrating social, behavioral, economic and biological sciences

The Fort Collins Science Center's Policy Analysis and Science Assistance (PASA) Branch is a team of approximately 22 scientists, technicians, and graduate student researchers. PASA provides unique capabilities in the U.S. Geological Survey by leading projects that integrate social, behavioral, economic, and biological analyses in the context of human-natural resource interactions. Resource planners, managers, and policymakers in the U.S. Departments of the Interior (DOI) and Agriculture (USDA), State and local agencies, as well as international agencies use information from PASA studies to make informed natural resource management and policy decisions. PASA scientists' primary functions are to conduct both theoretical and applied social science research, provide technical assistance, and offer training to advance performance in policy relevant research areas. Management and research issues associated with human-resource interactions typically occur in a unique context, involve difficult to access populations, require knowledge of both natural/biological science in addition to social science, and require the skill to integrate multiple science disciplines. In response to these difficult contexts, PASA researchers apply traditional and state-of-the-art social science methods drawing from the fields of sociology, demography, economics, political science, communications, social-psychology, and applied industrial organization psychology. Social science methods work in concert with our rangeland/agricultural management, wildlife, ecology, and biology capabilities. The goal of PASA's research is to enhance natural resource management, agency functions, policies, and decision-making. Our research is organized into four broad areas of study.

Fact Sheet↗

Tales from a distant swamp: Petrological and paleobotanical clues for the origin of the sand coal lithotype (Mississippian, Valley Fields, Virginia)

Tournasian (Mississippian) Price Formation semianthracites (Rmax = 2.40%) in the Valley Fields of southwestern Virginia contain a lithotype described in an early-20th-century report as a "sand" coal. The Center for Applied Energy Research inherited a collection of coals containing sand coal specimens, making it possible to study the lithotype from the long-closed mines. The sand coal consists of rounded quartz sand and maceral assemblages (secretinite, corpogelinite, and rounded collotelinite) along with banded collotelinite, vitrodetrinite, and inertodetrinite assemblages. The association of rounded macerals and similar-size quartz grains suggests transport. Oxidation rims surrounding the rounded collotelinite provides further evidence for transport. Due to the semianthracite rank, palynology could not be performed. Stratigraphic evidence indicates that the Lepidodendropsis flora would have been the dominant mire vegetation. Pteridosperms in this assemblage could have contributed resin rodlets, subsequently metamorphosed to collogelinite or secretinite. While a resin rodlet origin is an intriguing possibility for the origin of the rounded macerals (at least some of the rounded maceral, the rounded collotelinite clearly has a different origin), we cannot definitively prove this origin. ?? 2008 Elsevier B.V. All rights reserved.

International Journal of Coal Geology↗

Mineral-deposit model for lithium-cesium-tantalum pegmatites

Lithium-cesium-tantalum (LCT) pegmatites comprise a compositionally defined subset of granitic pegmatites. The major minerals are quartz, potassium feldspar, albite, and muscovite; typical accessory minerals include biotite, garnet, tourmaline, and apatite. The principal lithium ore minerals are spodumene, petalite, and lepidolite; cesium mostly comes from pollucite; and tantalum mostly comes from columbite-tantalite. Tin ore as cassiterite and beryllium ore as beryl also occur in LCT pegmatites, as do a number of gemstones and high-value museum specimens of rare minerals. Individual crystals in LCT pegmatites can be enormous: the largest spodumene was 14 meters long, the largest beryl was 18 meters long, and the largest potassium feldspar was 49 meters long. Lithium-cesium-tantalum pegmatites account for about one-fourth of the world’s lithium production, most of the tantalum production, and all of the cesium production. Giant deposits include Tanco in Canada, Greenbushes in Australia, and Bikita in Zimbabwe. The largest lithium pegmatite in the United States, at King’s Mountain, North Carolina, is no longer being mined although large reserves of lithium remain. Depending on size and attitude of the pegmatite, a variety of mining techniques are used, including artisanal surface mining, open-pit surface mining, small underground workings, and large underground operations using room-and-pillar design. In favorable circumstances, what would otherwise be gangue minerals (quartz, potassium feldspar, albite, and muscovite) can be mined along with lithium and (or) tantalum as coproducts. Most LCT pegmatites are hosted in metamorphosed supracrustal rocks in the upper greenschist to lower amphibolite facies. Lithium-cesium-tantalum pegmatite intrusions generally are emplaced late during orogeny, with emplacement being controlled by pre-existing structures. Typically, they crop out near evolved, peraluminous granites and leucogranites from which they are inferred to be derived by fractional crystallization. In cases where a parental granite pluton is not exposed, one is inferred to lie at depth. Lithium-cesium-tantalum LCT pegmatite melts are enriched in fluxing components including H2O, F, P, and B, which depress the solidus temperature, lower the density, and increase rates of ionic diffusion. This, in turn, enables pegmatites to form thin dikes and massive crystals despite having a felsic composition and temperatures that are significantly lower than ordinary granitic melts. Lithium-cesium-tantalum pegmatites crystallized at remarkably low temperatures (about 350–550 °C) in a remarkably short time (days to years). Lithium-cesium-tantalum pegmatites form in orogenic hinterlands as products of plate convergence. Most formed during collisional orogeny (for example, Kings Mountain district, North Carolina). Specific causes of LCT pegmatite-related magmatism could include: ordinary arc processes; over thickening of continental crust during collision or subduction; slab breakoff during or after collision; slab delamination before, during, or after collision; and late collisional extensional collapse and consequent decompression melting. Lithium-cesium-tantalum pegmatite deposits are present in all continents including Antarctica and in rocks spanning 3 billion years of Earth history. The global age distribution of LCT pegmatites is similar to those of common pegmatites, orogenic granites, and detrital zircons. Peak times of LCT pegmatite genesis at about 2640, 1800, 960, 485, and 310 Ma (million years before present) correspond to times of collisional orogeny and supercontinent assembly. Between these pulses were long intervals when few or no LCT pegmatites formed. These minima overlap with supercontinent tenures at ca. 2450–2225, 1625–1000, 875–725, and 250–200 Ma. Exploration and assessment for LCT pegmatites are guided by a number of observations. In frontier areas where exploration has been minimal at best, the key first-order criteria are an orogenic hinterland setting, appropriate regional metamorphic grades, and the presence of evolved granites and common granitic pegmatites. New LCT pegmatites are most likely to be found near known deposits. Pegmatites tend to show a regional mineralogical and geochemical zoning pattern with respect to the inferred parental granite, with the greatest enrichment in the more distal pegmatites. Mineral-chemical trends in common pegmatites that can point toward an evolved LCT pegmatite include: increasing rubidium in potassium feldspar, increasing lithium in white mica, increasing manganese in garnet, and increasing tantalum and manganese in columbite-tantalite. Most LCT pegmatite bodies show a distinctive internal zonation featuring four zones: border, wall, intermediate (where lithium, cesium, and tantalum are generally concentrated), and core. This zonation is expressed both in cross section and map view; thus, what may appear to be a common pegmatite may instead be the edge of a mineralized body. Neither lithium-cesium-tantalum pegmatites nor their parental granites are likely to cause serious environmental concerns. Soils and country rock surrounding a LCT pegmatite, as well as waste from mining operations, may be enriched in characteristic elements relative to global average soil and bedrock values. These elements may include lithium, cesium, tantalum, beryllium, boron, fluorine, phosphorus, manganese, gallium, rubidium, niobium, tin, and hafnium. Among this suite of elements, however, the only ones that might present a concern for environmental health are beryllium and fluorine, which are included in the U.S. Environmental Protection Agency drinking-water regulations with maximum contaminant levels of 4 micrograms per liter and 4 milligrams per liter, respectively.

Scientific Investigations Report↗

The Moloka‘i coral reef today, and alternatives for the future: Summary in The coral reef of south Moloka‘i, Hawai‘i—Portrait of a sediment-threatened fringing reef

From the contributions collected in this publication have emerged two important observations that have significance locally, nationally, and internationally. First, the fringing coral reef along the south coast of Moloka'i is one of the most extensive and luxuriant reefs in the eight main Hawaiian Islands. It is longer and more continuous and has denser coral cover than reefs at any of the other islands—this alone makes it a state and national treasure worthy of study and protection. The second observation is more sobering: sections of the south Moloka'i reef have been damaged in the past by sedimentation ultimately caused by human activities in adjacent watersheds. Although some of those activities are no longer taking place, their lingering effects are still being felt in the form of excess sediment runoff. We here review the basis for each of these observations, discuss how sedimentation affects the reef, and summarize the choices that are faced by the people of Moloka'i and the State of Hawai'i with regard to the reef’s future.

Hawai‘i↗

Assessing risk communication in the pet and aquarium trade: An analysis of outreach and engagement efforts

The international pet and aquarium trade, and intentional or unintentional release of those pets by individuals, has contributed to the establishment of many species to areas where they are not native, resulting in detrimental consequences to local ecosystems, economies, and livelihoods. A number of outreach campaigns across the United States aim to communicate the risk of non-native pet release through education and the offering of alternative solutions to pet owners who are no longer able to care for their pets. Through semi-structured interviews with campaign managers, content analysis of campaign materials, and an analysis of relevant online search results, our project aims to assess the scope of these outreach strategies to understand whether they are effectively intervening in an individual’s decision-making process to release a non-native pet. Ultimately, this project’s outcomes will ensure that economic and human resources invested in risk communication campaigns are using effective and inclusive techniques.

Report↗

U.S. Geological Survey Colorado River Basin Actionable and Strategic Integrated Science and Technology (ASIST)—Information Management Technology Plan

Introduction More than 840 publications, 575 data releases, and 330 project web pages from the U.S. Geological Survey (USGS) pertain to the Colorado River Basin. Limited interconnections between Colorado River Basin publications, data, and web pages restrict the ability to synthesize and interpret scientific resources. Currently, these pieces are spread across multiple isolated locations, internal systems, data repositories, and local offices. The increasing size, complexity, and diversity of Colorado River Basin data creates additional need for integration. These different data types—including discrete, continuous, aerial, remote sensing, geophysical, geospatial, and other types in varied formats—are collected over numerous time and space scales and require data-intensive science and technology to integrate. Information management technology (IMT) resources are enterprise capabilities that the USGS workforce can leverage at multiple scales with consistent interoperable solutions to better facilitate integrated science. The USGS 21st Century Science Strategy directs the USGS to establish enterprise IMT capabilities that support integrated work through interoperable software and database solutions at multiple scales. This Information Management Technology Plan identifies nine steps to leverage new and existing technologies, data, models, and scientific knowledge to support integrated science projects conducted across the Colorado River Basin. These steps are transferable to integrated-science studies in other locations.

Arizona, Colorado, Nevada, New Mexico, Utah, Wyomi↗

Bibliography of fine-grained siliceous deposits

This bibliography was compiled under the auspices of the International Geologic Correlations Project's (IGCP) Research Group 115, "Siliceous Deposits of the Pacific Region"; IGCP is sponsored by UNESCO and the International Union of Geological Sciences (IUGS). Research Group 115 was originally proposed to IGCP in 1974 by Professor Azuma Iijima, University of Tokyo, and is now headed by James R. Hein, U.S. Geological Survey. Cooperative efforts by 86 members from 17 countries help in accomplishing Research Group 115's objectives of correlating sedimentary processes of siliceous deposits in the Pacific Basin and neighboring geosynclinal areas by means of stratigraphy, sedimentology, geochemisty, and paleontology. These correlations will allow us to estimate the geochemical silica budget in the Earth's crust; to estimate the production of silica in the marine environment through geologic time; to formulate a general rule on sedimentation of siliceous deposits in geosynclines; to increase understanding of the development of circum-Pacific orogenic belts; and to obtain basic methods to evaluate siliceous deposits of economic interest. The group agreed to focus on fine-grained siliceous deposits (cherts, siliceous shales, diatomites, and the like) and to exclude quartz sand deposits and quartzose sandstones.

Open-File Report↗

Water-resources activities of the U.S. Geological Survey in Idaho, fiscal years 1989-90

Twenty-five funded projects were conducted by the Water Resources Division of the U.S. Geological Survey, Idaho District, during fiscal years 1989-90. These projects were done in cooperation with 13 State and local agencies, 11 other Federal agencies, and 1 International Commission. State and local cooperative funding amounted to about $1.1 million in fiscal year 1989 and $1 million in fiscal year 1990; Federal funding amounted to about $3.6 million in fiscal year 1989 and about $4.4 million in fiscal year 1990. In conducting its fiscal year 1989-90 activities, the Idaho District employed a total of 83 employees. Projects other than continuing programs for collection of hydrologic data included establishment of statewide surface-water and groundwater-quality monitoring networks; study of effects of irrigation drainage; development of a hydraulic model to determine water-surface elevations for decreased discharges of the Snake River at Swan Falls Dam; evaluation of subsurface waste disposal; delineation of agricultural areas of the State with high concentrations of dissolved nitrogen; evaluation of water use and its effect on groundwater levels and thermal waters in specific areas of the State; and determination of the cause or causes of rapidly decreasing hot-spring discharges along Hot Creek. (USGS)

Open-File Report↗

Reconnaissance investigation of water-quality, bottom sediment, and biota associated with irrigation drainage in the Lower Rio Grande Valley and Laguna Atascosa National Wildlife Refuge, Texas, 1986-87

In 1986, the Department of the Interior conducted reconnaissance investigations in nine areas of the western conterminous United States to determine whether irrigation drainage has caused or has the potential to cause harmful effects to human health, fish, and wildlife, or may adversely affect the suitability of water for beneficial uses. Data collected in the lower Rio Grande valley and Laguna Atascosa National Wildlife Refuge reconnaissance investigation indicate that concentrations of dissolved minor elements in water are small. The maximum dissolved concentrations of arsenic, cadmium, mercury, chromium, selenium, and zinc exceed the 75th-percentile baseline values developed for the study; however, maximum dissolved concentrations of cadmium, mercury, and selenium exceeded the 75th-percentile baseline values by 1 microgram per liter or less. Concentrations of dissolved boron increased significantly from west to east. The smallest concentration of dissolved boron, 220 micrograms per liter, was detected in International Falcon Reservoir. The largest concentration of dissolved boron, 11,000 micrograms per liter, was detected on the refuge in Athel Pond. No chlorophenoxy herbicides were detected in water during the June 1986 sampling. Simazine, prometone, and atrazine were the only triazine herbicides detected, and concentrations of these herbicides did not exceed 0.8 microgram per liter. DDE, the only organochlorine Insecticide detected in water, was detected at two locations at concentrations of 0.01 micrograms per liter. Methyl parathion, malathion, and diazinon were the only organophosphorus compounds detected in the June 1986 sampling, and the maximum concentrations of these compounds were 0.75, 0.71, and 0.26 micrograms per liter, respectively. The analysis of three samples collected in August 1986 indicate that the types of pesticides collected during runoff were similiar to those detected during the June 1986 sampling. The exception was that the herbicide 2,4-D was detected during runoff. Concentrations of dissolved cadmium exceeded the chronic criteria for freshwater aquatic life in the Cayo Atascoso in the Laguna Atascosa National Wildlife Refuge. Chromium exceeded the acute and chronic freshwater criteria at four locations in the refuge and in the Laguna Madre. Chromium also exceeded the chronic saltwater criteria in Athel Pond. Concentrations of dissolved copper exceeded the acute and chronic criteria for saltwater aquatic life at 13 locations. Mercury exceeded the chronic criteria for freshwater and saltwater aquatic life at three locations, and dissolved nickel concentrations exceeded the chronic criteria for saltwater aquatic life in the Rio Grande at Anzalduas Dam and in the Resaca de los Frenos near Russeltown. No organophosphorus insecticides, polychlorinated napthalenes, or polychlorinated biphenyl compounds were detected in four bed-sediment samples. DDE, an organochlorine insecticide, was detected in all four samples at concentrations ranging from 0.2 to 34 micrograms per kilogram. Chlordane, ODD, DDE, DOT, and dieldrin were all detected in the Resaca de los Fresnos at U.S. Highway 77 at San Benito with concentrations of 4.0, 9.7, 9.3, 7.3, and 0.1 micrograms per kilogram, respectively. Data collected by U.S. Fish and Wildlife Service in 1985 indicate that DDE was detected in approximately 75 percent of the bed sediment samples analyzed. The maximum concentration detected in that study was 6.0 micrograms per gram; the median concentration was 0.01 micrograms per gram. Minor-element data from 22 fish samples indicate that the maximum concentrations of arsenic, copper, mercury, selenium, and zinc exceeded the 85thpercentile baseline concentrations established by the U.S. Fish and Wildlife Service for the National Contaminant Biomonitoring Program. None of the median concentrations of these minor elements exceeded the baseline concentrations. The maximum concentrations of aluminum, barium, iron, manganese, and tin were detected in fish collected from International Falcon Reservoir. This reservoir stratifies in the summer, and minor elements may be released from the bed sediments in the deep parts of the reservoir and incorporated into the food chain. Toxaphene was detected in 11 fish samples; detectable concentrations ranged from 0.98 to 5.1 micrograms per gram, wet weight. DOT also was detected in 11 fish samples with concentrations ranging from 0.021 to 0.066 micrograms per gram, wet weight. ODD was detected in 21 fish samples; concentrations ranged from 0.015 to 0.16 micrograms per gram, wet weight. DDE was detected in all 22 fish samples, and concentrations ranged from 0.36 to 9.9 micrograms per gram, wet weight. The maximum concentrations of DOT and ODD exceeded the 1980-81 baseline concentrations. The median and maximum concentrations of toxaphene and DDE exceeded the 1980-81 baseline concentrations. The largest concentrations of toxaphene, ODD, and DDE in fish were all measured in samples collected at the Main Floodway near Progreso.

Texas↗

Hydrologic analysis of the upper San Pedro basin from the Mexico-United States international boundary to Fairbank, Arizona

A definition of the hydrologic system of the upper San Pedro basin was obtained by developing a numerical ground-water model to evaluate a conceptual model of the system. Information on hydraulic properties of the basin fill, recharge from bordering mountain ranges, discharge by evapotranspiration, and exchange of water between aquifer and stream was available from previous measurements or estimates. The steady-state calibration procedure and subsequent transient simulations demonstrated that the original conceptualization can be reasonably simulated. An analysis of model sensitivity to increases and decreases in certain hydraulic properties indicated a low sensitivity to aquifer anisotropy and a low to moderate sensitivity to stream leakance and evapotranspiration rate. An analysis to investigate the effects of generalizing aquifer conductivity and recharge showed that flow components and water-level response to stress could be simulated adequately but that steady-state water-level conditions could not. During equilibrium conditions, recharge to and discharge from the basin was about 16,500 acre-feet per year. Modeling results indicated that by 1978 the storage depletion rate had reached 5,600 acre-feet per year resulting from a ground-water withdrawal rate of 10,500 acre-feet per year. (USGS)

Arizona↗