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Egg thiamine concentrations reflect dietary differences between four hatchery strains, including two morphotypes, of Lake Trout in Lake Ontario

Objective Test whether dietary differences among hatchery strains of Lake Trout Salvelinus namaycush were associated with variation in egg thiamine concentrations and assess the potential for using strain-specific traits to mitigate thiamine deficiency complex (TDC) in Lake Ontario restoration efforts. Methods Stomach content analysis and stable isotope mixing models were used to compare diets among four hatchery strains of Lake Trout, representing lean and humper morphotypes. Egg thiamine concentrations were measured to test whether dietary differences correlated with susceptibility to TDC. Results Significant differences in diet and egg thiamine concentrations were observed among Lake Trout strains. A humper-like morphotype strain exhibited elevated thiamine levels, which were associated with reduced consumption of prey known to degrade thiamine levels when consumed, Alewife Alosa pseudoharengus and Rainbow Smelt Osmerus mordax , and increased reliance on Round Goby Neogobius melanostomus or sculpin species (Slimy Sculpin Cottus cognatus and Deepwater Sculpin Myoxocephalus thompsonii ). These findings support the link between the consumption of Alewife and Rainbow Smelt and thiamine deficiency. Conclusions Our findings support a link between strain-specific dietary preferences and susceptibility to TDC in Lake Trout. Preferential stocking of strains less prone to TDC, such as the strain derived from a humper morph from Lake Superior, could enhance restoration success in Lake Ontario. This strategy may be especially effective given the continued dominance of Alewife in the lake's prey base and the current management priorities supporting fisheries for Pacific salmon Oncorhynchus spp.

North American Journal of Fisheries Management

Flow heterogeneity controls dissolution dynamics in topologically complex rocks

Rock dissolution is a common subsurface geochemical reaction affecting pore space properties, crucial for reservoir stimulation, carbon storage, and geothermal energy. Predictive models for dissolution remain limited due to incomplete understanding of the mechanisms involved. We examine the influence of flow, transport, and reaction regimes on mineral dissolution using 29 time-resolved data from 3D rocks. We find that initial pore structure significantly influences the dissolution pattern, with reaction rates up to two orders of magnitude lower than batch conditions, given solute and fluid-solid boundary constraints. Flow unevenness determines the location and rate of dissolution. We propose two models describing expected dissolution patterns and effective reaction rates based on dimensionless metrics for flow, transport, and reaction. Finally, we analyze feedback between evolving flow and pore structure to understand conditions that regulate/reinforce dissolution hotspots. Our findings underscore the major impact of flow arrangement on reaction-front propagation and provide a foundation for controlling dissolution hotspots.

Geophysical Research Letters

Advancing sustainable groundwater management with a hydro-economic system model: Investigations in the Harney Basin, Oregon

Groundwater resources frequently trend toward unsustainable levels because, absent effective institutions, individual water users generally act independently without considering the impacts on other users. Hydro-economic models (HEMs) of human-natural systems can play a positive role toward successful groundwater management by yielding valuable knowledge and insight. The current study explores how an HEM that captures essential physical and economic characteristics of a system can shed light on the system's processes and dynamics to benefit stakeholders, managers, and also researchers. These propositions are illustrated using the Harney Basin, Oregon, which has seen large groundwater declines in the past 20 years. The HEM shows that: (a) although current groundwater pumping rates will gradually raise costs and reduce well yields, irrigators gain the highest aggregate economic return by continuing current pumping; (b) lowland areas of the basin are hydrologically connected, which limits the efficacy of remedies focused on regulations only in some portions of the basin; (c) community expectations regarding the efficacy of several proposed solutions are overly optimistic; and (d) the study's scenarios identify interventions that would stabilize the groundwater system and prevent additional adverse impacts on residential and livestock wells and groundwater-dependent ecosystems. These interventions would require limiting groundwater pumping by nearly half and reducing annual profits by $7.5–$9.0M. The HEM also demonstrated its value to researchers: its insights shifted attention toward questions about Oregon's existing groundwater institutions and their inability to adaptively manage the transition from abundant groundwater to scarce groundwater in a timely manner.

Oregon

Availability of ground water in the area surrounding the Trident submarine construction facility, Kitsap County, Washington

This report provides general information on the water resources--with emphasis on ground-water occurrence and availability--in that part of Kitsap County (referred to as Trident Impact Area) that would be most affected by the development of the Trident submarine-construction facility at Bangor. Ground water occurs principally in a lower, confined aquifer near and below sea level and an upper, unconfined aquifer above sea level; both aquifers are extensive beneath the study area and are composed of sand and gravel layers separated by poorly permeable silt, clay, and till layers. Locally throughout the area efficiently constructed wells tapping each of the two aquifers are capable of yielding 100 to 1,300 or more gallons per minute. The estimated 1970 water use in the study area averaged about 13 million gal/day (gallons per day); of this amount about 9 million gal/day came from surface-water sources--from a large reservoir outside the study area--and about 4 million gal/day came from ground water pumped from the two aquifers. Anticipated water use soon will be about 18 to 21 million gal/day; virtually all the additional quantity required (about 5 to 8 million gal/day) above present use must come from ground-water sources. Preliminary evaluation of the aquifers suggests that an additional 1.5 million gal/day can be developed from the upper aquifer and 7 million gal/day from the lower aquifer. Existing wells tapping the lower aquifer might yield additional water and increase the total yield in the area by 3.5 million gal/day, and new wells drilled in selected areas could produce an additional 3.5 million gal/day from this aquifer. However, additional, large-scale ground-water withdrawal from the lower aquifer could induce saltwater intrusion into wells situated in coastal areas. Recommended future studies include additional data collection, monitoring of chloride concentrations in water from large-yield coastal wells, confirmation of well yields and capacities, and test-well drilling and analysis.

Washington

Geologic map of the Emmons Lake volcanic center, Alaska

Introduction The Emmons Lake volcanic center is a spatially clustered group of stratovolcanoes and calderas in the southwestern part of the Alaska Peninsula, Alaska. The volcanic center is characterized by several ice- and snow-clad stratovolcanoes located within and along the margins of a nested-caldera complex that includes Emmons Lake. A shieldlike ancestral edifice (ancestral Mount Emmons) is truncated by the caldera complex and forms a broad volcanic platform around the center. The main stratovolcanoes of the Emmons Lake volcanic center are Pavlof Sister, Pavlof Volcano, Little Pavlof, Double Crater, Mount Hague, and Mount Emmons. Several small unnamed cinder cones and vents also are located within Emmons Lake volcanic center and on the east flank of Pavlof Volcano. Many of these cones and vents have been the source of the young lava flows that mantle the floor of the caldera. Pavlof Volcano, in the northeastern part of the Emmons Lake volcanic center, is one of the most historically (that is, the past about 300 years) active volcanoes in Alaska, and eruptions from Pavlof Volcano pose the greatest hazards to the region. Volcanic rocks of the Emmons Lake volcanic center overlie continental and marine sedimentary rocks of chiefly Late Jurassic to early Tertiary age. The oldest rocks in the area are those of the Naknek Formation, consisting of volcaniclastic sandstone, siltstone, and conglomerate of Late Jurassic age. The southern part of the area includes rocks of the Belkofski Formation, a thick sequence of volcaniclastic sandstone, siltstone, and conglomerate of middle Tertiary age. Lava flows, volcanic breccia, and fluvial volcaniclastic rocks of late Miocene age, which unconformably overlie the Belkofski Formation south of the Emmons Lake volcanic center, are primarily exposed on the islands just south of the Alaska Peninsula. The Emmons Lake volcanic center was affected multiple times by glaciation associated with the glacier expansion that characterized the Quaternary. Glaciation has played a key role in shaping the present-day landscape, and much of the eruptive history of the Emmons Lake volcanic center has involved interactions with glacier ice. Thus, a brief review of the Quaternary glacial history of the area is provided to establish the physical context for Emmons Lake volcanic center eruptive activity.

Alaska

Using the horizontal-to-vertical spectral ratio method to estimate thickness of the Barry Arm landslide, Prince William Sound, Alaska

Conducting detailed investigations of large landslides is difficult, especially in the subsurface, largely due to environmental factors such as steep slopes, difficult access, and numerous objective hazards. These factors have made it challenging to accurately estimate the depth to the failure surface of the Barry Arm landslide, a large (roughly 10 8 cubic meters), deep-seated bedrock landslide in Prince William Sound, Alaska, recognized in 2019. The landslide has exhibited accelerated movement in recent years and poses a potential tsunamigenic hazard if rapid failure occurs. Failure surface depth, equivalent to landslide thickness, is a necessary metric for landslide-volume calculations and associated tsunami wave models. In this report, we used seismic noise recorded by a seismometer located on the Barry Arm landslide in Alaska to calculate the horizontal-to-vertical spectral ratio (HVSR) to investigate the site fundamental frequency ( f 0 ) and depth of the failure surface. To ensure that observed peak frequencies in the spectral ratio were related to the underlying stratigraphy (and not caused by other noise sources like nearby glaciers, topographic resonance, weather, or human activities), we also calculated HVSRs using earthquake signals, HVSRs at other seismic stations within a 2.5-kilometer radius, and a standard spectral ratio between the landslide station and other sites. We observed multiple peaks in the landslide HVSR curves at 1.5 hertz (Hz), 4–5 Hz, and 7–11 Hz. The frequencies of these peaks were consistent at the landslide site through time and across methods and were dissimilar to those identified at other seismic stations in the area, making it unlikely the peaks were caused by local noise. Directional HVSRs calculated at 15-degree intervals showed amplification of the higher frequency peaks in the direction parallel to slip, indicating two-dimensional site effects. We used the distinct frequency peaks in the seismic record to develop a 4-layer conceptual model of the landslide wherein the top of the deepest layer represents the primary failure surface, or the boundary between damaged (mobile) and undamaged material. We inverted Rayleigh wave ellipticity curves within this 4-layer configuration with constraints on S-wave velocity and layer thickness based on analogous material properties identified in the literature. This was necessary absent any site-specific subsurface S-wave velocity data. The best-fitting models indicate a mean slope-normal depth to the failure surface of 188 (±9) meters (m), with additional stratigraphic boundaries at 4 and 20 m below ground surface, potentially representing layered motion. These results agree with and improve upon ranges estimated by previous studies and can support future modeling and assessment efforts at Barry Arm.

Alaska

James Buttle review: The characteristics of baseflow resilience across diverse ecohydrological terrains

The dynamic storage of aquifers is the portion of groundwater that can potentially drain to any given point along a stream to create baseflow. Baseflow typically occurs year-round in perennial streams, though the characteristics and stability of dynamic storage are often most important to instream processes during extended dry periods (without precipitation and snowmelt) when runoff and quickflows are minimised. The term ‘baseflow resilience’ is defined for this review as the tendency of baseflow in streams to maintain a consistent volume and water quality year to year while under stress from climate variability and extremes, along with anthropogenic stressors such as water withdrawals, land use change, and water quality degradation. ‘Baseflow resilience’ has, in part, a user-defined meaning spanning water supply and water quality variables of primary interest. Watershed characteristics that directly impact resilience can often produce non-intuitive feedbacks that enhance some attributes of baseflow while simultaneously impairing others. For example, permeable stream corridor geology creates strong stream-groundwater hydrologic connectivity, yet fast groundwater drainage via preferential high-permeability flowpaths can lead to streamflow not being sustained during extended dry periods. Also, shallow groundwater sources are generally more immediately vulnerable to extreme events, warming, salinization, transpiration, and precipitation drought, compared to deeper groundwater. Yet baseflow drought in streams influenced by deeper groundwater can lag precipitation drought by years, and contaminant legacies may propagate through deep groundwater flowpaths to receiving waters for decades to centuries. Finally, irrigation withdrawals can intercept groundwater that would have drained to streams, and the application of irrigation may leach contaminants from the soil zone by unnaturally raising water tables, yet irrigation return flows can sustain baseflow and groundwater-dependent habitats in semiarid areas. This review covers the concept of hydrologic resilience in the context of stream baseflow processes and summarises the common hydrogeological controls on, and multiscale stressors of, dynamic groundwater storage. Further, we present several quantitative metrics to assess a range of water supply to water quality baseflow characteristics using both broadly available and boutique data types, a subset of which are demonstrated using data from the Delaware River Basin, USA.

Delaware River Basin

Metal fingerprints of Eocene rhyolite magmas coincident with Carlin-type gold deposition in Nevada USA

Eocene magmatic systems contemporaneous with world-class Carlin-type Au deposits in Nevada (USA) have been proposed by some researchers as a key ingredient for Au mineralization, though evidence conclusively demonstrating their genetic relationship remains tenuous. This study provides the first direct evidence of the pre-eruptive metal budget of volatile- and metal-charged silicic magmas coincident in time (~41 to 34 Ma) and space (within 5 km) with Carlin-type Au deposits. We characterize the pre-eruptive metal fingerprints of these diverse magmatic systems to assess their potential as sources of metals for Carlin-type Au mineralization. Metal abundances from quartz-hosted melt inclusions (Au, Te, Ag, Sb, Tl, Mo, W, Sn, As, Pb, Co, Cu, Ni, and Zn) characterized in situ by SHRIMP-RG and LA-ICP-MS represent our best (and only) estimates for the pre-eruptive metal budget in these systems. Median metal concentrations are generally within one order of magnitude of average upper crust and average continental rhyolite values. But there are two notable exceptions, with median Au contents extending >1 order of magnitude higher than average upper crust and median Cu contents ranging >1 order of magnitude lower than upper crust. Despite this, melts contain lower Au/Cu (<0.1), Au/Ag (<5), and Au/Tl (<0.3) than most ore-grade Carlin-type rock samples and quartz-hosted fluid inclusions, regardless of their age and timing relative to nearby Carlin-type Au mineralization. The metal fingerprints of these magmatic systems, de-fined both by traditional and multivariate compositional data analysis techniques, are distinct from one another. Yet none are particularly specialized, e.g., high Au/Cu, in terms of being ideal ingredients as postulated by magmatic models for Carlin-type Au mineralization. Magmatic Au contents do not appear to be correlated with rhyolite “flavors” in the way that Cu, Sn, and Nb contents are. Fluid/melt partitioning modeling and magma volume estimates support the idea that a diverse array of non-specialized silicic magmas could feasibly contribute some or potentially all of the Au, Ag, and Cu in Carlin-type systems. The compositional diversity among contemporaneous magmatic systems could possibly contribute to some of the diversity observed across Carlin-type Au districts in Nevada.

Nevada

Geochemical evidence for the origin of late Quaternary loess, Seward Peninsula, Alaska

Loess is the most widespread surficial deposit in the state of Alaska. Although loess of last glacial age is common in mid-continental North America, records of last glacial loess in Alaska have been elusive. Here we report a record of last glacial loess on the Seward Peninsula, along with studies of a transect of loess localities also thought to date to the last glacial period. Highly diverse hypotheses on the origin of loess on the Seward Peninsula include local volcanic rocks and mountain ranges to the north and south, as well as offshore deposits. We present particle size and mineralogical and geochemical data that indicate that the most likely sources for loess in this part of eastern Beringia are glaciogenic silt particles of the Kobuk River and Noatak River, both of which drain the Brooks Range to the northeast. Northeasterly paleowinds were therefore responsible for loess on the Seward Peninsula. Such winds probably occurred during late summer or early autumn, when river discharge was at a minimum but temperatures were still above freezing. Northeasterly winds during the last glacial period are in good agreement with a recent paleoclimate model.

Alaska

Assessing environmental drivers of denitrification in restored riverine floodplains

Restoration of impaired floodplains is an increasingly prevalent strategy for alleviating water quality concerns and reducing downstream flooding at watershed scales. Floodplains temporarily store water and slow flow velocity to promote sedimentation during overbank flooding and remove inorganic nitrogen from floodwater and groundwater via denitrification. Evaluating the impacts of different restoration strategies on denitrification can inform more strategic investments into floodplain modifications that improve water quality outcomes. Our research investigates how denitrification rates in floodplains respond to environmental factors that are actionable from an engineering perspective through design and water resources management. We seasonally measured soil denitrification enzyme activity and various environmental characteristics in 4 floodplains with different restoration design and management approaches at the confluence of the Wabash and Tippecanoe Rivers in Indiana, United States. Our results showed that denitrification rates in an agricultural floodplain were significantly lower than in restored floodplains with native vegetation. Certain soil conditions characteristic of floodplain wetlands were associated with higher denitrification, particularly elevated total nitrogen, moisture, silt, and organic matter contents. Vegetation species composition was correlated with denitrification rates. This link may reflect the direct effects of vegetation on soil conditions, such as supplying labile organic carbon, or indirect effects, such as vegetation acting as an indicator of hydrologic regime and land use. Denitrification seasonally varied, peaking in winter when nitrate supply from rivers draining agricultural watersheds in the region is also high. Substrate limitation of soil denitrification enzyme activity was most significant during the summer when overbank flooding, which replenishes soil nitrogen stocks, rarely occurs. Our findings indicate that denitrification capacity will likely be maximized in riverine floodplains that are restored as wetlands with diverse native vegetation and enhanced hydrologic connectivity. Such restoration activities promote higher denitrification rates via elevated moisture, fine sediment deposition, and soil organic matter.

Tippecanoe River, Wabash River

U.S. Geological Survey global seabed mineral resources

The U.S. Geological Survey (USGS) provides science and data on seabed mineral resources and ecosystems, as well as on the potential hazards associated with extraction. The Nation relies on minerals for infrastructure, technology, manufacturing, and energy production. Critical minerals are essential to the economic and national security of the United States and have a supply chain vulnerable to disruption. For decades, USGS scientific innovation has contributed to the delineation of seabed mineral resources, the mechanisms of seabed mineral formation, and the environmental impacts of resource extraction. Since 1962, the USGS has also led scientific inquiries into the potential for deep sea mining. By providing impartial science on seabed minerals and their environmental setting in the deep oceans, the USGS enables decision-makers to evaluate the best practices for mineral resource development.

Fact Sheet

A seismic nodal deployment to understand magmatic structure in the vicinity of the Pahala earthquake swarm

In summer-fall 2022, 80 three-component SmartSolo IGU-BD3C-5 nodal seismometers were deployed surrounding the Pāhala seismic swarm on the Island of Hawaiʻi, with the goal of improving seismicity catalogs, and seismic velocity images of the crust and upper mantle in this region. The Pāhala swarm, located south of Mauna Loa and Kīlauea, has been the site of a multiyear sustained swarm of seismicity at depths of ~ 25 – 40 km, with order of magnitude increases in rate in 2015, and then again in 2019. This seismicity is possibly related to the input of magma from the mantle plume below, which may then be subsequently transported to volcanic edifices. However, these processes remain enigmatic, in part due to a lack of precise earthquake locations and seismic velocity models in this region. Here we provide an overview of the deployment, an assessment of the quality of the collected data, and discuss the viability of the dataset for local earthquake relocation, tomography, and teleseismic receiver functions. Through comparisons with proximal permanent broadband and short period instruments, we find that the nodes produce high quality data, particularly at periods shorter than 5 s, although we find, document, and correct discrepancies with the gain and polarities of the instruments. We successfully record signals from teleseismic earthquakes, even at periods longer than 5 s (the corner of the flat response of the nodes). We also record local earthquakes, including details related to source characteristics. This indicates that the data is likely to prove useful for investigations using both local and teleseismic earthquake signals to better understand the connections between the deep and shallow magmatic systems of Hawaiʻi. While this deployment provides a snapshot in time, its success may provide a useful benchmark for future studies as the volcanic systems of Hawaiʻi continue to evolve in the future.

Hawaii

Widespread terrestrial ecosystem disruption at the onset of the Paleocene–Eocene Thermal Maximum

The Paleocene–Eocene Thermal Maximum (PETM, ~56 Mya) interval was marked by massive 13 C-depleted carbon emissions into the ocean/atmosphere system, manifested as a negative carbon isotope excursion (CIE) in sedimentary components, and ~5 °C global average warming. Episodes of hydrological perturbations and soil-erosion have been widely documented for the PETM but their link with vegetation- and carbon cycle changes remain poorly constrained. Here, we present organic microfossil evidence showing a strong increase in fern-dominated pioneer vegetation that replaced coniferous forests on the margin of the Norwegian Sea during the first millennia of the CIE. With the present stratigraphic constraints, the “fern spike” occurred simultaneously in terrestrial settings along the North Sea, Arctic Ocean, the US east coast and in southern Australia, indicating that pioneer vegetation persisted for several millennia following a partial collapse of previously stable terrestrial ecosystems. Both the ferns and influx of microcharcoal imply recurrent physical disturbance, including soil destabilization and erosion, potentially linked to droughts, wildfires, and strong hydrological forcing resulting from extreme climate change. Together with evidence for reworked clay minerals and ancient organic matter (kerogen), these findings show that highly disturbed terrestrial ecosystems were widespread across mid- and high-latitude regions globally. Carbon cycle model simulations suggest that a substantial loss of standing and buried biomass, along with oxidation of soil organic matter, acted as important positive feedbacks during the onset of the CIE. Additionally, enhanced kerogen weathering likely contributed as another major positive feedback throughout both the onset and main phase of the CIE.

Proceedings of the National Academy of Sciences

Cenozoic stratigraphy of Colorado

As a successor to previous Colorado stratigraphy charts (MS-53 Colorado Stratigraphic Chart and MS-54 Cretaceous Stratigraphy of Colorado), this Colorado Geological Survey (CGS) publication resulted from a collaboration between the CGS, USGS, and the Denver Museum of Nature and Science (DMNS). The chart was designed to illustrate Cenozoic stratigraphy spanning the state’s many sedimentary basins. It builds upon the work of dozens of colleagues and updates Richard Pearl’s seminal 1974 stratigraphy chart. The chart leverages the community’s stratigraphic work in both the subsurface and outcrop, and depicts new geochronologic constraints for many units. To facilitate comparison of strata to external forcing factors, the chart employs a linear timescale. Each unit’s dominant depositional environment is depicted, as are major mountain building events, erosional events, and regional unconformities.

Colorado

Submarine groundwater discharge creates cold‐water refugia that can mitigate exposure of heat stress in nearshore corals

Coral reef mortality around the world is accelerating due to human activities and rising sea temperatures that cause bleaching, which is expected to become more frequent. Our ability to predict which corals will be most resilient, however, remains limited due to insufficient information characterizing nearshore temperature and habitat conditions. In this study, we examine how submarine groundwater discharge (SGD) reduces nearshore water temperatures and exposure of corals to heat stress, complementing the understanding that SGD can adversely affect coral when it contains elevated nutrient concentrations. Data from fixed nearshore sensors and vertical depth profiles along ~100 km of the western shoreline of the Island of Hawai’i from 2003 to 2014 demonstrate that submarine groundwater discharge (SGD) can reduce nearshore water temperatures by 1 °C–5°C and create estuarine-like conditions with salinities as low as 20 PSU, where the prevalent coral species, Pocillopora meandrina, Porites lobata , and Montipora capitata , thrive. Time-series temperature records reveal that exposure to high ambient ocean temperatures, which are known to initiate bleaching events, are reduced up to 5%–46% of the time. Coral health surveys indicated coral bleaching in response to moderately high annual temperatures in 2010 and 2011, with more colonies affected farther from cold, SGD-fed waters. Synthesis of these results, along with coral response data following the more extreme marine heat wave of 2014–2015, demonstrates lower coral loss and greater coral recovery near groundwater seeps, particularly those with higher flux and influence on reducing nearshore water temperatures. Our results demonstrate that SGD may therefore provide a beneficial ecosystem service and enhance coral reef resilience, particularly where human-related nutrient additions to groundwater can be mitigated. The implications of our findings are relevant across tropical coasts where groundwater inputs can be substantial, such as the Caribbean and Indo-Pacific, and contribute to improving our understanding of coral sensitivity to gradients in temperature and nutrient stress. Improved management of groundwater resources could thus be vital to local–regional strategies for mitigating future heat stress.

Hawaii

Oblique contraction along the fastest ocean-continent transform plate boundary focuses rock uplift west of the Fairweather fault, southeast Alaska

Contraction along the Yakutat–North America plate boundary drives 4.6–9.0 mm/year Holocene rock uplift rates along Earth's fastest slipping (≥49 mm/year) ocean–continent transform fault, the Fairweather Fault. Between Icy Point and Lituya Bay, the near-vertical Fairweather fault focuses rock uplift and rapid right-lateral slip by accommodating both vertical and fault-parallel strain during oblique-slip and separate, predominantly strike-slip ruptures. Unusually high uplift rates, indicated by radiocarbon and luminescence dating, result from a 10-km-wide, asymmetric, positive flower structure along a 20°, ∼30-km-long restraining double bend in the Fairweather fault. The principal reverse fault in the flower structure, the offshore, blind Icy Point–Lituya Bay fault, ruptures no more than every 460–1040 years evidenced by uplifted Holocene shorelines. Maximum 3–5 m coseismic uplifts imply 3.1–10 m dip slip per event and earthquake magnitudes of M w 7.0–7.5. The Yakutat block collides obliquely into North America, and our model entails oblique slip on the Fairweather fault with and without corupture on the reverse fault. Oblique slip is evident by vertically offset (&gt;25 m) fluvial and marine terraces and by the primary Fairweather fault strand that strikes &gt;20° to the west of plate-boundary motion.

Alaska

Multidecadal change in pesticide concentrations relative to human health benchmarks in the Nation’s groundwater

Groundwater-quality trend assessments identify aquifers that are responding to changes in pesticide use and the compounds that may pose a threat to water availability. The U.S. Geological Survey has been monitoring pesticide concentrations in groundwater for 25 principal aquifers across the conterminous United States since 1993. The groundwater well locations represent a range of soils, climate, and landforms. The wells are used to monitor groundwater underlying selected agricultural and urban settings and groundwater used for domestic supply. This study examined changes in relative concentrations, defined here as the percentage of wells with pesticide concentrations exceeding a human health benchmark (HHB). HHBs used in this report are legally enforceable drinking-water standards and nonenforceable drinking water levels. Relative pesticide concentration increases may lead to decreased water availability, as restrictions may be put in place for groundwater used as a drinking-water source. This study focused on concentration changes in 22 pesticides that were included in laboratory analysis from 1993 to 2023. The analysis and interpretation of these pesticide concentrations in groundwater have been separated into approximate decadal intervals (decade 1 (1993–2001), decade 2 (2002–12), and decade 3 (2013–22). For one pesticide, 1,2-dibromo-3-chloropropane (DBCP), concentration data were also collected in decade 4 (2023–onward). Atrazine, deethylatrazine, alachlor, prometon, and simazine were 5 pesticides detected at moderate concentrations (greater than 10 percent of the HHB but less than or equal to the HHB). The percentage of wells that had groundwater pesticide concentrations in the moderate concentration category decreased from 7 percent in decade 1 to 2 percent in decade 3. The agricultural networks had the highest percentages of wells with moderate concentrations, and these percentages decreased from 13 percent in decade 1 to 4 percent in decade 3. Moderate concentrations in the urban networks decreased between decades 1 and 2 from 4 percent to 0 percent. No moderate concentrations occurred in the urban networks in decade 3. The percentage of wells with moderate concentrations in the domestic supply networks (1 percent) was the lowest of all the network types and did not change across the three decades. Moderate atrazine or deethylatrazine concentrations occurred across all three decades in aggregated ecoregions representing similar soils, climate, and landforms in the Semiarid West, Midcontinent, and Northeastern United States. Moderate concentrations of prometon, alachlor, and simazine also occurred in the Midcontinent, Arid West, Northeast, South Atlantic Gulf, and Semiarid West regions, but the moderate concentrations did not persist across all three decades. DBCP was the only pesticide that exceeded its respective HHB, and the exceedances occurred across all four decades. In this report, the DBCP analysis was limited to one well network in the Central Valley, California. Agricultural use of DBCP was suspended in 1977. Forty-five years after being banned, DBCP concentrations were greater than the maximum contaminant level of 2 micrograms per liter (μg/L), but the number of exceedances decreased from 50 percent to 15 percent of the samples between 1993 and 2023. This assessment of decadal groundwater pesticide concentrations provides a characterization of changes in water availability because of pesticide contamination in areas where groundwater is used as a drinking-water source. The results highlight the importance of continued long-term monitoring and assessment of groundwater pesticides to identify locations and specific compounds that may pose a potential risk to human health.

continental United States

Geochemical disequilibrium at the brittle-ductile transition

We investigate the microtextural, microchemical, and isotopic effects of late-stage ductile deformation in quartzite mylonites and kyanite–muscovite–quartz veins from the Raft River shear zone (Utah). Quartz microstructures record pervasive disequilibrium, expressed by unannealed features including undulatory extinction, deformation lamellae, and poorly defined fabrics, typical of waning deformation in shear zones. Microchemical disequilibrium is best preserved in kyanite quartzites, where CL-zoned kyanite records repeated fractures, overgrowth, and mineral precipitation, and in muscovite from muscovite-poor quartzite mylonites that shows minor-element zoning consistent with syn-deformational overgrowth on detrital cores. In contrast, muscovite from muscovite-rich kyanite quartzites exhibits minimal chemical zoning. These microchemical variations correlate with 40 Ar/ 39 Ar age systematics. Chemically zoned muscovite preserves variable single-step ages, including ∼150 Ma ages, reflecting retention of detrital cores. In contrast, syndeformational muscovite consistently yields Miocene ages, indicating recrystallization and new growth below argon closure temperatures that reset inherited isotopic signatures. Similar trends are observed in quartzite mylonites, where increasing quartz recrystallization and stronger crystallographic preferred orientations occur toward deeper structural levels. Together, these observations indicate increasing retrograde deformation and recrystallization with depth in the Raft River shear zone and demonstrate that strain-driven recrystallization exerts a first-order control on muscovite ages. We suggest that apparent thermochronologic gradients in retrograde shear zones may reflect recrystallization gradients rather than temperature gradients. Where cooling limits the thermal driving force for recrystallization, isotopic relics are preserved, and local deformation and fluid availability control re-equilibration. Consequently, isotopic disequilibrium—particularly in the 40 Ar/ 39 Ar system—may be the rule rather than the exception of retrograde tectonic environments.

Idaho, Utah