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Hydrologic controls on the transport and cycling of carbon and nitrogen in a boreal catchment underlain by continuous permafrost

Boreal ecosystems represent a large carbon (C) reservoir and a substantial source of greenhouse gases. Hydrologic conditions dictate whether C leached from boreal soils is processed in catchments or flushed to less productive environments via the stream. This study quantified hydrologic and biogeochemical C loss from a boreal catchment underlain by frozen silt, where flowpaths may deepen as the active layer thaws over the summer. We hypothesized a decrease in the magnitude of C mineralization over the summer associated with changing flowpaths and decreasing hydrologic connectivity, organic matter lability, and nitrogen (N) availability. Conservative tracers were used to partition C and N loss between catchment export and biogeochemical processing. Coupling tracers with tributary and porewater chemistry indicated C and N cycling in soil flowpaths, with an exponential decrease over the summer. Nitrate was primarily reduced in hillslope flowpaths and the lack of N reaching the stream appeared to limit C mineralization. Stream export accounted for the greatest loss of C, removing 247 and 113 mol hr −1 in the early and late summer, respectively. Reactivity was related to hydrologic connectivity between the soils and stream, which was greatest early in the summer and following a large flood. While a warming climate may increase storage potential in thawed soils, the early‐season flush of labile material and late‐season runoff through mineral flowpaths may maintain high C export rates. Therefore, we highlight physical export as a dominant cause of aqueous C loss from silty catchments as the Arctic continues to thaw.

Journal of Geophysical Research G: Biogeosciences↗

Extracting low‐resolution river networks from high‐resolution digital elevation models

Including a global river network in the land component of global climate models (GCMs) is necessary in order to provide a more complete representation of the hydrologic cycle. The process of creating these networks is called river network upscaling and consists of lowering the resolution of already available fine networks to make them compatible with GCMs. Fine‐resolution river networks have a level of detail appropriate for analysis at the watershed scale but are too intensive for global hydrologic studies. A river network upscaling algorithm, which processes fine‐resolution digital elevation models to determine the flow directions that best describe the flow patterns in a coarser user‐defined scale, is presented. The objectives of this study were to develop an algorithm that advances the previous work in the field by being applicable at a global scale, allowing for the upscaling to be performed in a projected environment, and generating evenly distributed flow directions.

Water Resources Research↗

Potential for real‐time understanding of coupled hydrologic and biogeochemical processes in stream ecosystems: Future integration of telemetered data with process models for glacial meltwater streams

While continuous monitoring of streamflow and temperature has been common for some time, there is great potential to expand continuous monitoring to include water quality parameters such as nutrients, turbidity, oxygen, and dissolved organic material. In many systems, distinguishing between watershed and stream ecosystem controls can be challenging. The usefulness of such monitoring can be enhanced by the application of quantitative models to interpret observed patterns in real time. Examples are discussed primarily from the glacial meltwater streams of the McMurdo Dry Valleys, Antarctica. Although the Dry Valley landscape is barren of plants, many streams harbor thriving cyanobacterial mats. Whereas a daily cycle of streamflow is controlled by the surface energy balance on the glaciers and the temporal pattern of solar exposure, the daily signal for biogeochemical processes controlling water quality is generated along the stream. These features result in an excellent outdoor laboratory for investigating fundamental ecosystem process and the development and validation of process‐based models. As part of the McMurdo Dry Valleys Long‐Term Ecological Research project, we have conducted field experiments and developed coupled biogeochemical transport models for the role of hyporheic exchange in controlling weathering reactions, microbial nitrogen cycling, and stream temperature regulation. We have adapted modeling approaches from sediment transport to understand mobilization of stream biomass with increasing flows. These models help to elucidate the role of in‐stream processes in systems where watershed processes also contribute to observed patterns, and may serve as a test case for applying real‐time stream ecosystem models.

Water Resources Research↗

A framework for estimating global river discharge from the Surface Water and Ocean Topography satellite mission

The Surface Water and Ocean Topography (SWOT) mission will vastly expand measurements of global rivers, providing critical new data sets for both gaged and ungaged basins. SWOT discharge products (available approximately 1 year after launch) will provide discharge for all river that reaches wider than 100 m. In this paper, we describe how SWOT discharge produced and archived by the US and French space agencies will be computed from measurements of river water surface elevation, width, and slope and ancillary data, along with expected discharge accuracy. We present for the first time a complete estimate of the SWOT discharge uncertainty budget, with separate terms for random (standard error) and systematic (bias) uncertainty components in river discharge time series. We expect that discharge uncertainty will be less than 30% for two-thirds of global reaches and will be dominated by bias. Separate river discharge estimates will combine both SWOT and in situ data; these “gage-constrained” discharge estimates can be expected to have lower systematic uncertainty. Temporal variations in river discharge time series will be dominated by random error and are expected to be estimated within 15% for nearly all reaches, allowing accurate inference of event flow dynamics globally, including in ungaged basins. We believe this level of accuracy lays the groundwork for SWOT to enable breakthroughs in global hydrologic science.

Water Resources Research↗

Using imaging spectroscopy and elevation in machine learning to estimate soil salinity in intermittently tidal wetlands

Coastal soil salinization patterns are changing due to drought, sea level rise (SLR), and changing freshwater inflow. These changes are expected to impact coastal wetland plant health and ecosystem function, such as changes to biomass and productivity. These impacts have led to greater interest in how we monitor soil salinization across spatial and temporal scales. Remote sensing is a promising tool for estimating soil salinity at the spatial scales required for decision making by land managers. However, the development of a remote sensing estimation approach for wetland soil salinity must account for two factors: (1) the high spatial and temporal heterogeneity of coastal wetlands and (2) the fact that soil salinity is the result of multiple historical land use, hydrological, and geomorphic processes. In spring 2022, a combined airborne-field campaign, known as SHIFT, collected a weekly time series of airborne visible to shortwave infrared (VSWIR) image spectroscopy data. This dataset provides a unique opportunity to assess the application of fine spatial (5 m) and temporal (weekly) resolution VSWIR data to estimate root zone soil salinity; when combined with environmental variables such as elevation, these data can account for some of these factors. In this study, we utilized VSWIR and elevation datasets in a random forest regression to predict and map soil salinity in an intermittently tidal estuary, Devereux Slough, located in Santa Barbara County, California. The final model combined spectral indices with elevation to better capture soil salinity dynamics despite lower correlation ( r = 0.85) than solely using elevation ( r = 0.92). This research demonstrates the utility of remote sensing datasets, namely, elevation and the modified Anthocyanin Reflectance Index (mARI), for predicting root zone soil salinity in intermittently tidal coastal wetlands. These findings are an important step in advancing coastal remote sensing by creating a gridded salinity dataset that can be used for salinity monitoring and other coastal applications, such as modeling change in vegetation communities or ecosystems facing the impacts of climatic variability and change.

California↗

Tracing of weathering reactions and water flowpaths: A multi-isotope approach

This chapter discusses the importance of using isotopes in a complementary manner, primarily to constrain and enrich models developed from hydrologic and chemical data. Isotopes are viewed as tools for testing rather than developing hypotheses, particularly in studies operating under tight budgetary constraints. Water isotopes are very useful tools for determining water sources in catchments. Chemical tracers are very useful for understanding the reactions along flowpaths. The potential application of Fe isotopes to catchment studies lies in the assumption that Fe mobilized inorganically from minerals under either reducing or low-pH conditions will have a different isotopic composition than microbially-reduced Fe. To the extent that certain zones or flowpaths in the catchment can be characterized by microbial cycling of labile Fe, the Fe isotopes may provide an effective tracer of contributions from these pathways. The solute isotopes, for example, strontium, carbon, and lead are as yet under-utilized in catchment research compared to the water isotopes.

Book chapter↗

IASH Commission of Snow and Ice meeting: Paris, France, September 3-5, 1969

The IASH Commission of Snow and Ice met jointly with the Working Group on Glaciology of the Special Committee on Antarctic Research (SCAR). Five technical guides have been prepared by the Commission of Snow and Ice for major IHD projects and have been in press at Unesco for more than a year and a half. They should be published by December 1969. A sixth guide, on Sea, Lake and River Ice, was approved for publication, and two other guides (Avalanche Classification and Part 2 of Combined Heat, Ice, and Water Balances) have been distributed in first or second draft form. They should be ready for approval by the next meeting of the officers of the Commission. Even though these guides have not yet been officially published, they have served as instruction and coordination media for a large number of glacier and seasonal snow cover projects in many nations during the first part of the International Hydrological Decade.

Eos, Transactions, American Geophysical Union↗

Geoenvironmental model for roll-type uranium deposits in the Texas Gulf Coast

Geoenvironmental models were formulated by the U.S. Geological Survey in the 1990s to describe potential environmental effects of extracting different types of ore deposits in different geologic and climatic regions. This paper presents a geoenvironmental model for roll-front (roll-type) uranium deposits in the Texas Coastal Plain. The model reviews descriptive and quantitative information derived from environmental studies and existing databases to depict existing conditions and potential environmental concerns associated with mining this deposit type. This geoenvironmental model describes how features of the deposits including host rock; ore and gangue mineralogy; geologic, hydrologic, and climatic settings; and mining methods (legacy open-pit and in situ recovery [ISR]) influence potential environmental effects from mining. Element concentrations in soil and water are compared to regulatory thresholds to depict ambient surface water and groundwater conditions. Although most open-pit operations in this region have been reclaimed, concerns remain about groundwater quality at three of the four former mills that supported former open-pit mines and are undergoing closure activities. The primary environmental concerns with ISR mining are (1) radon gas at active ISR operations, (2) radiation or contaminant leakage during production and transport of ISR resin or yellowcake, (3) uranium excursions into groundwater surrounding active ISR operations, and (4) contamination of groundwater after ISR mining. Although existing regulations attempt to address these concerns, some problems remain. Researchers suggest that reactive transport modeling and a better understanding of geology, stratigraphy, and geochemistry of ISR production areas could minimize excursions into surrounding aquifers and improve results of groundwater restoration.

Texas↗

The role of lithology and climate on bedrock river incision and terrace development along the Buffalo National River, Arkansas

The Buffalo National River in northwest Arkansas preserves an extensive Quaternary record of fluvial bedrock incision and aggradation across lithologies of variable resistance. In this work, we apply optically stimulated luminescence (OSL) dating to strath and fill terraces along the Buffalo River to elucidate the role of lithology and climate on the development of the two youngest terrace units (Qtm and Qty). Our OSL ages suggest a minimum strath planation age of ~250 ka for the Qtm terraces followed by a ~200 ka record of aggradation. Qtm incision likely occurred near the LGM, prior to the onset of Qty fill terrace aggradation ~14 ka. Our terrace ages are broadly consistent with other regional fluvial terrace records, and comparison with available paleoclimatic archives suggests that terrace aggradation and incision occurred during drier and wetter hydrological conditions, respectively. Vertical bedrock incision rates were also calculated using OSL-derived estimates of Qtm strath planation and displayed statistically significant spatial variability with bedrock lithology, ranging from 0.04 mm/yr in the higher resistance reaches and 0.02 mm/yr in the lower resistance reaches. In combination with observations of valley width and terrace distribution, these results suggest that vertical processes outpace lateral ones in lithologic reaches with higher resistance.

Arkansas↗

Hydrologic connectivity between landscapes and streams: Transferring reach‐ and plot‐scale understanding to the catchment scale

The relationship between catchment structure and runoff characteristics is poorly understood. In steep headwater catchments with shallow soils the accumulation of hillslope area (upslope accumulated area (UAA)) is a hypothesized first‐order control on the distribution of soil water and groundwater. Hillslope‐riparian water table connectivity represents the linkage between the dominant catchment landscape elements (hillslopes and riparian zones) and the channel network. Hydrologic connectivity between hillslope‐riparian‐stream (HRS) landscape elements is heterogeneous in space and often temporally transient. We sought to test the relationship between UAA and the existence and longevity of HRS shallow groundwater connectivity. We quantified water table connectivity based on 84 recording wells distributed across 24 HRS transects within the Tenderfoot Creek Experimental Forest (U.S. Forest Service), northern Rocky Mountains, Montana. Correlations were observed between the longevity of HRS water table connectivity and the size of each transect's UAA ( r 2 = 0.91). We applied this relationship to the entire stream network to quantify landscape‐scale connectivity through time and ascertain its relationship to catchment‐scale runoff dynamics. We found that the shape of the estimated annual landscape connectivity duration curve was highly related to the catchment flow duration curve ( r 2 = 0.95). This research suggests internal catchment landscape structure (topography and topology) as a first‐order control on runoff source area and whole catchment response characteristics.

Water Resources Research↗

Climate Change Research at USGS Center for Earth Resources Observation and Science (EROS)

Research and development projects at EROS apply unique resources to support the USGS mission of developing understanding, monitoring, and modeling of climate variability and change and their human, physical, and biological impacts. Remote sensing resources, both new and archived, form the core of our ability to determine changes in the state or condition of the Earth’s surface and its dynamic landscape and ecosystem processes. This rich resource provides powerful biophysical information for local to global areas. Archival data form the basis for assessing human and climate impacts on the land surface, trends of land use, and an understanding of climate and management impacts. Biophysical information from satellite data is assimilated into quantitative models that allow all disciplines of the USGS to understand impacts on ecosystem processes. Major processes and problems we address include: carbon fluxes, hydrological processes, albedo changes and regional climates, mangroves and wetland protection of coastal environments, natural and manmade hazards (e.g., fire and drought), ecosystem change and succession, land use and land cover change, and more. The integration of remote sensing, modeling, and multidisciplinary approaches fosters international scientific leadership across all disciplines for the USGS.

Fact Sheet↗

Riparian vegetation response to the March 2008 short-duration, High-Flow Experiment— Implications of timing and frequency of flood disturbance on nonnative plant establishment along the Colorado River below Glen Canyon Dam

Riparian plant communities exhibit various levels of diversity and richness. These communities are affected by flooding and are vulnerable to colonization by nonnative species. Since 1996, a series of three high-flow experiments (HFE), or water releases designed to mimic natural seasonal flooding, have been conducted at Glen Canyon Dam, Ariz., primarily to determine the effectiveness of using high flows to conserve sediment, a limited resource. These experiments also provide opportunities to examine the susceptibility of riparian plant communities to nonnative species invasions. The third and most recent HFE was conducted from March 5 to 9, 2008, and scientists with the U.S. Geological Survey's Grand Canyon Monitoring and Research Center examined the effects of high flows on riparian vegetation as part of the overall experiment. Total plant species richness, nonnative species richness, percent plant cover, percent organic matter, and total carbon measured from sediment samples were compared for Grand Canyon riparian vegetation zones immediately following the HFE and 6 months later. These comparisons were used to determine if susceptibility to nonnative species establishment varied among riparian vegetation zones and if the timing of the HFE affected nonnative plant establishment success. The 2008 HFE primarily buried vegetation rather than scouring it. Percent nonnative cover did not differ among riparian vegetation zones; however, in the river corridor affected by Glen Canyon Dam operations, nonnative species richness showed significant variation. For example, species richness was significantly greater immediately after and 6 months following the HFE in the hydrologic zone farthest away from the shoreline, the area that represents the oldest riparian zone within the post-dam riparian area. In areas closer to the river channel, tamarisk (Tamarix ramosissima X chinensis) seedling establishment occurred (<2 percent cover) in 2008 but not to the extent reported in either 2000, a year when experimental summer flows coincided with tamarisk seed production, or in 1986, a year following several years of sustained flooding. The results from the 2008 HFE suggest that riparian vegetation zones subject to intermittent disturbance and near the river under normal dam operations are more susceptible to nonnative species introductions following a disturbance. This study also finds that the timing of an HFE affects the types of species that can become established. For example, HFEs conducted in March are associated with reduced tamarisk seedling establishment compared to disturbances later in the season. Additionally, early season, short-duration flooding that results in vegetation burial may favor clonal species. Along the Colorado River many of these clonal species are native; these species include arrowweed (Pluchea sericea), coyote willow (Salix exigua), and rivercane (Phragmites australis).

Arizona, Nevada↗

Paleohydrologic regimes in the southwestern Great Basin, 0-3.2 my ago, compared with other long records of "gobal" climate

Nine distinct paleohydrologic regimes in the southwestern Great Basin over the last 3.2 my are recorded by the lacustrine deposits in KM-3, a 930-m core from Searles Lake, California. These are characterized as being "wet," "intermediate," or "dry" (like today). Excepting the present incomplete regime, each lasted 0.12 to 0.76 my. Major regime changes 0.01, 0.13, 0.6, and 2.5 my ago appear to coincide with recognized changes in global ice-sheet histories as represented by 18O and other records from marine sediments, but comparable changes 0.3, 1.0, 1.3, and 2.0 my ago do not appear to coincide closely with comparable perturbations in ice-sheet histories. However, all regime boundaries (during the last 1.75 my) coincide closely in time with changes in sea-surface temperatures in the tropical Atlantic, and many coincide with other deep-sea and continental paleoclimatic boundaries.The average duration of these paleohydrologic regimes was about 0.4 my (standard deviation, 0.2 my or less, depending on assumptions), and it is suggested that the regime boundaries reflect times of change in global(?) sea-surface temperatures, possibly controlled in part by the Earth's 413,000-yr orbital eccentricity cycle. During the wettest and driest regimes in the Searles Lake area, lake levels were not sufficiently affected by the 23,000-, to 42,000-, or 100,000-yr climate cycles related to high-latitude ice-sheet fluctuations to produce changes in the lacustrine sediment character. During intermediate regimes, however, when lacustrine sedimentation in this area was more sensitive to climate, the sediments, in KM-3, record lake fluctuations with average frequencies near those of the ice sheets. This seems to indicate that the high-latitude ice-sheet fluctuations caused local climatic perturbations but did not dominate the hydrologic component of climate in this area. Other lacustrine deposits in the southwestern Great Basin of California and Nevada have ages comparable in part to those of the wet to intermediate regimes indicated by KM-3, and they may all be products of finite periods when lake expansion, alluvial fan growth, increased spring discharge, and fluvial deposition were promoted in this area by widespread wet climates. Glacier expansion in the Sierra Nevada may also have been primarily an expression of, and in phase with, these wet regimes. ?? 1984.

Quaternary Research↗

Landslide triggering by rain infiltration

Landsliding in response to rainfall involves physical processes that operate on disparate timescales. Relationships between these timescales guide development of a mathematical model that uses reduced forms of Richards equation to evaluate effects of rainfall infiltration on landslide occurrence, timing, depth, and acceleration in diverse situations. The longest pertinent timescale is A / D 0 , where D 0 is the maximum hydraulic diffusivity of the soil and A is the catchment area that potentially affects groundwater pressures at a prospective landslide slip surface location with areal coordinates x , y and depth H . Times greater than A / D 0 are necessary for establishment of steady background water pressures that develop at ( x , y , H ) in response to rainfall averaged over periods that commonly range from days to many decades. These steady groundwater pressures influence the propensity for landsliding at ( x , y , H ), but they do not trigger slope failure. Failure results from rainfall over a typically shorter timescale H 2 / D 0 associated with transient pore pressure transmission during and following storms. Commonly, this timescale ranges from minutes to months. The shortest timescale affecting landslide responses to rainfall is √(H/g), where g is the magnitude of gravitational acceleration. Postfailure landslide motion occurs on this timescale, which indicates that the thinnest landslides accelerate most quickly if all other factors are constant. Effects of hydrologic processes on landslide processes across these diverse timescales are encapsulated by a response function, R(t*) = √(t*/π) exp (-1/t*) - erfc (1/√t*), which depends only on normalized time, t*. Use of R(t*) in conjunction with topographic data, rainfall intensity and duration information, an infinite-slope failure criterion, and Newton's second law predicts the timing, depth, and acceleration of rainfall-triggered landslides. Data from contrasting landslides that exhibit rapid, shallow motion and slow, deep-seated motion corroborate these predictions.

Water Resources Research↗

Hydrologic functions of prairie wetlands

Wetlands in the prairie known as potholes or sloughs represent an ever-changing mosaic of surface waters interacting with the atmosphere, groundwater, and each other in a variety of ways. Studies of groups of adjacent wetlands in different parts of the glaciated North American prairie have enabled some connections to be made between hydrologic processes, biological communities, and use of these wetlands by wetland-dependent wildlife. Understanding controls on variability in water levels, water volume, and salinity in these wetlands sets the stage for understanding controls on biological communities utilizing these wetlands. The role that natural variability in water and salinity plays in making these wetlands an important resource for waterfowl will provide an important context for those who are responsible for artificially altering the variability of water and salinity in prairie wetlands.

Great Plains Research↗

Climatology and potential effects of an emergency outlet, Devils Lake Basin, North Dakota

The Devils Lake Basin is a 3,810-square-mile subbasin in the Red River of the North Basin. At an elevation of about 1,447 feet above sea level, Devils Lake begins to spill into Stump Lake; and at an elevation of about 1,459 feet above sea level, the combined lakes begin to spill through Tolna Coulee into the Sheyenne River. Since the end of glaciation about 10,000 years ago, Devils Lake has fluctuated between spilling and being dry. Research by the North Dakota Geological Survey indicates Devils Lake has overflowed into the Sheyenne River at least twice during the past 4,000 years and has spilled into the Stump Lakes several times (Bluemle, 1991; Murphy and others, 1997). John Bluemle, North Dakota State Geologist, concluded the natural condition for Devils Lake is either rising or falling, and the lake should not be expected to remain at any elevation for a long period of time. Recent conditions indicate the lake is in a rising phase. The lake rose 24.7 feet from February 1993 to August 1999, and flood damages in the Devils Lake Basin have exceeded $300 million. These damages, and the potential for additional damages, have led to an effort to develop an outlet to help control lake levels. Therefore, current and accurate climatologic and hydrologic data are needed to assess the viability of the various options to reduce flood damages at Devils Lake.

Fact Sheet↗

Assessing environmental drivers of denitrification in restored riverine floodplains

Restoration of impaired floodplains is an increasingly prevalent strategy for alleviating water quality concerns and reducing downstream flooding at watershed scales. Floodplains temporarily store water and slow flow velocity to promote sedimentation during overbank flooding and remove inorganic nitrogen from floodwater and groundwater via denitrification. Evaluating the impacts of different restoration strategies on denitrification can inform more strategic investments into floodplain modifications that improve water quality outcomes. Our research investigates how denitrification rates in floodplains respond to environmental factors that are actionable from an engineering perspective through design and water resources management. We seasonally measured soil denitrification enzyme activity and various environmental characteristics in 4 floodplains with different restoration design and management approaches at the confluence of the Wabash and Tippecanoe Rivers in Indiana, United States. Our results showed that denitrification rates in an agricultural floodplain were significantly lower than in restored floodplains with native vegetation. Certain soil conditions characteristic of floodplain wetlands were associated with higher denitrification, particularly elevated total nitrogen, moisture, silt, and organic matter contents. Vegetation species composition was correlated with denitrification rates. This link may reflect the direct effects of vegetation on soil conditions, such as supplying labile organic carbon, or indirect effects, such as vegetation acting as an indicator of hydrologic regime and land use. Denitrification seasonally varied, peaking in winter when nitrate supply from rivers draining agricultural watersheds in the region is also high. Substrate limitation of soil denitrification enzyme activity was most significant during the summer when overbank flooding, which replenishes soil nitrogen stocks, rarely occurs. Our findings indicate that denitrification capacity will likely be maximized in riverine floodplains that are restored as wetlands with diverse native vegetation and enhanced hydrologic connectivity. Such restoration activities promote higher denitrification rates via elevated moisture, fine sediment deposition, and soil organic matter.

Tippecanoe River, Wabash River↗

Prioritizing river basins for nutrient studies

Increases in fluxes of nitrogen (N) and phosphorus (P) in the environment have led to negative impacts affecting drinking water, eutrophication, harmful algal blooms, climate change, and biodiversity loss. Because of the importance, scale, and complexity of these issues, it may be useful to consider methods for prioritizing nutrient research in representative drainage basins within a regional or national context. Two systematic, quantitative approaches were developed to (1) identify basins that geospatial data suggest are most impacted by nutrients and (2) identify basins that have the most variability in factors affecting nutrient sources and transport in order to prioritize basins for studies that seek to understand the key drivers of nutrient impacts. The “impact” approach relied on geospatial variables representing surface-water and groundwater nutrient concentrations, sources of N and P, and potential impacts on receptors (i.e., ecosystems and human health). The “variability” approach relied on geospatial variables representing surface-water nutrient concentrations, factors affecting sources and transport of nutrients, model accuracy, and potential receptor impacts. One hundred and sixty-three drainage basins throughout the contiguous United States were ranked nationally and within 18 hydrologic regions. Nationally, the top-ranked basins from the impact approach were concentrated in the Midwest, while those from the variability approach were dispersed across the nation. Regionally, the top-ranked basin selected by the two approaches differed in 15 of the 18 regions, with top-ranked basins selected by the variability approach having lower minimum concentrations and larger ranges in concentrations than top-ranked basins selected by the impact approach. The highest ranked basins identified using the variability approach may have advantages for exploring how landscape factors affect surface-water quality and how surface-water quality may affect ecosystems. In contrast, the impact approach prioritized basins in terms of human development and nutrient concentrations in both surface water and groundwater, thereby targeting areas where actions to reduce nutrient concentrations could have the largest effect on improving water availability and reducing ecosystem impacts.

Environmental Monitoring and Assessment↗