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Holocene sea level and climate change in the Black Sea: Multiple marine incursions related to freshwater discharge events

Repeated marine invasions of the Black Sea during the Holocene have been inferred by many eastern scientists as resulting from episodes of marine inflow from the Mediterranean beneath a brackish outflow from the Black Sea. We support this scenario but a fundamental question remains: What caused the repeated marine invasions? We offer an hypothesis for the repeated marine invasions of the Black Sea based on: (1) the overall similarity of sea-level curves from both tectonically quiescent and active margins of the Black Sea and their similarity to a sequence stratigraphic record from the US mid-Atlantic coast. The similarity of the records from two widely-separated regions suggests their common response to documented Holocene climate ocean-atmosphere reorganizations (coolings); (2) the fact that in the modern Black Sea, freshwater runoff from surrounding rivers dominates over evaporation, so that excess runoff might have temporarily raised Black Sea level (although the Black Sea would have remained brackish). Following the initial invasion of the Black Sea by marine Mediterranean waters (through the Marmara Sea) in the early Holocene, repeated marine incursions were modulated, or perhaps even caused, by freshwater discharge to the Black Sea. Climatic amelioration (warming) following each documented ocean-atmosphere reorganization during the Holocene likely shifted precipitation patterns in the surrounding region and caused mountain glaciers to retreat, increasing freshwater runoff above modern values and temporarily contributing to an increase of Black Sea level. Freshwater-to-brackish water discharges into the Black Sea initially slowed marine inflow but upon mixing of runoff with more marine waters beneath them and their eventual exit through the Bosphorus, marine inflow increased again, accounting for the repeated marine invasions. The magnitude of the hydrologic and sea-level fluctuations became increasingly attenuated through the Holocene, as reflected by Black Sea level curves. ?? 2006 Elsevier Ltd and INQUA.

Quaternary International↗

Holocene thermal maximum in the western Arctic (0-180°W)

The spatio-temporal pattern of peak Holocene warmth (Holocene thermal maximum, HTM) is traced over 140 sites across the Western Hemisphere of the Arctic (0-180??W; north of ???60??N). Paleoclimate inferences based on a wide variety of proxy indicators provide clear evidence for warmer-than-present conditions at 120 of these sites. At the 16 terrestrial sites where quantitative estimates have been obtained, local HTM temperatures (primarily summer estimates) were on average 1.6??0.8??C higher than present (approximate average of the 20th century), but the warming was time-transgressive across the western Arctic. As the precession-driven summer insolation anomaly peaked 12-10ka (thousands of calendar years ago), warming was concentrated in northwest North America, while cool conditions lingered in the northeast. Alaska and northwest Canada experienced the HTM between ca 11 and 9ka, about 4000yr prior to the HTM in northeast Canada. The delayed warming in Quebec and Labrador was linked to the residual Laurentide Ice Sheet, which chilled the region through its impact on surface energy balance and ocean circulation. The lingering ice also attests to the inherent asymmetry of atmospheric and oceanic circulation that predisposes the region to glaciation and modulates the pattern of climatic change. The spatial asymmetry of warming during the HTM resembles the pattern of warming observed in the Arctic over the last several decades. Although the two warmings are described at different temporal scales, and the HTM was additionally affected by the residual Laurentide ice, the similarities suggest there might be a preferred mode of variability in the atmospheric circulation that generates a recurrent pattern of warming under positive radiative forcing. Unlike the HTM, however, future warming will not be counterbalanced by the cooling effect of a residual North American ice sheet. ?? 2003 Elsevier Ltd. All rights reserved.

Quaternary Science Reviews↗

Prospects for reconstructing paleoenvironmental conditions from organic compounds in polar snow and ice

Polar ice cores provide information about past climate and environmental changes over periods ranging from a few years up to 800,000 years. The majority of chemical studies have focused on determining inorganic components, such as major ions and trace elements as well as on their isotopic fingerprint. In this paper, we review the different classes of organic compounds that might yield environmental information, discussing existing research and what is needed to improve knowledge. We also discuss the problems of sampling, analysis and interpretation of organic molecules in ice. This review highlights the great potential for organic compounds to be used as proxies for anthropogenic activities, past fire events from different types of biomass, terrestrial biogenic emissions and marine biological activity, along with the possibility of inferring past temperature fluctuations and even large-scale climate variability. In parallel, comprehensive research needs to be done to assess the atmospheric stability of these compounds, their ability to be transported long distances in the atmosphere, and their stability in the archive in order to better interpret their fluxes in ice cores. In addition, specific decontamination procedures, analytical methods with low detection limits (ng/L or lower), fast analysis time and low sample requests need to be developed in order to ensure a good time resolution in the archive.

Quaternary Science Reviews↗

Assessment of estuarine water-quality indicators using MODIS medium-resolution bands: initial results from Tampa Bay, FL

Using Tampa Bay, FL as an example, we explored the potential for using MODIS medium-resolution bands (250- and 500-m data at 469-, 555-, and 645-nm) for estuarine monitoring. Field surveys during 21–22 October 2003 showed that Tampa Bay has Case-II waters, in that for the salinity range of 24–32 psu, (a) chlorophyll concentration (11 to 23 mg m −3 ), (b) colored dissolved organic matter (CDOM) absorption coefficient at 400 nm (0.9 to 2.5 m −1 ), and (c) total suspended sediment concentration (TSS: 2 to 11 mg L −1 ) often do not co-vary. CDOM is the only constituent that showed a linear, inverse relationship with surface salinity, although the slope of the relationship changed with location within the bay. The MODIS medium-resolution bands, although designed for land use, are 4–5 times more sensitive than Landsat-7/ETM+ data and are comparable to or higher than those of CZCS. Several approaches were used to derive synoptic maps of water constituents from concurrent MODIS medium-resolution data. We found that application of various atmospheric-correction algorithms yielded no significant differences, due primarily to uncertainties in the sensor radiometric calibration and other sensor artifacts. However, where each scene could be groundtruthed, simple regressions between in situ observations of constituents and at-sensor radiances provided reasonable synoptic maps. We address the need for improvements of sensor calibration/characterization, atmospheric correction, and bio-optical algorithms to make operational and quantitative use of these medium-resolution bands.

Florida↗

Web-enabled Landsat Data (WELD): Landsat ETM+ composited mosaics of the conterminous United States

Since January 2008, the U.S. Department of Interior / U.S. Geological Survey have been providing free terrain-corrected (Level 1T) Landsat Enhanced Thematic Mapper Plus (ETM+) data via the Internet, currently for acquisitions with less than 40% cloud cover. With this rich dataset, temporally composited, mosaics of the conterminous United States (CONUS) were generated on a monthly, seasonal, and annual basis using 6521 ETM+ acquisitions from December 2007 to November 2008. The composited mosaics are designed to provide consistent Landsat data that can be used to derive land cover and geo-physical and bio-physical products for detailed regional assessments of land-cover dynamics and to study Earth system functioning. The data layers in the composited mosaics are defined at 30 m and include top of atmosphere (TOA) reflectance, TOA brightness temperature, TOA normalized difference vegetation index (NDVI), the date each composited pixel was acquired on, per-band radiometric saturation status, cloud mask values, and the number of acquisitions considered in the compositing period. Reduced spatial resolution browse imagery, and top of atmosphere 30 m reflectance time series extracted from the monthly composites, capture the expected land surface phenological change, and illustrate the potential of the composited mosaic data for terrestrial monitoring at high spatial resolution. The composited mosaics are available in 501 tiles of 5000 × 5000 30 m pixels in the Albers equal area projection and are downloadable at http://landsat.usgs.gov/WELD.php . The research described in this paper demonstrates the potential of Landsat data processing to provide a consistent, long-term, large-area, data record.

Remote Sensing of Environment↗

Monitoring on-orbit calibration stability of the Terra MODIS and Landsat 7 ETM+ sensors using pseudo-invariant test sites

The ability to detect and quantify changes in the Earth's environment depends on sensors that can provide calibrated, consistent measurements of the Earth's surface features through time. A critical step in this process is to put image data from different sensors onto a common radiometric scale. This work focuses on monitoring the long-term on-orbit calibration stability of the Terra Moderate Resolution Imaging Spectroradiometer (MODIS) and the Landsat 7 (L7) Enhanced Thematic Mapper Plus (ETM+) sensors using the Committee on Earth Observation Satellites (CEOS) reference standard pseudo-invariant test sites (Libya 4, Mauritania 1/2, Algeria 3, Libya 1, and Algeria 5). These sites have been frequently used as radiometric targets because of their relatively stable surface conditions temporally. This study was performed using all cloud-free calibrated images from the Terra MODIS and the L7 ETM+ sensors, acquired from launch to December 2008. Homogeneous regions of interest (ROI) were selected in the calibrated images and the mean target statistics were derived from sensor measurements in terms of top-of-atmosphere (TOA) reflectance. For each band pair, a set of fitted coefficients (slope and offset) is provided to monitor the long-term stability over very stable pseudo-invariant test sites. The average percent differences in intercept from the long-term trends obtained from the ETM + TOA reflectance estimates relative to the MODIS for all the CEOS reference standard test sites range from 2.5% to 15%. This gives an estimate of the collective differences due to the Relative Spectral Response (RSR) characteristics of each sensor, bi-directional reflectance distribution function (BRDF), spectral signature of the ground target, and atmospheric composition. The lifetime TOA reflectance trends from both sensors over 10 years are extremely stable, changing by no more than 0.4% per year in its TOA reflectance over the CEOS reference standard test sites.

Remote Sensing of Environment↗

Spectral assessment of new ASTER SWIR surface reflectance data products for spectroscopic mapping of rocks and minerals

ASTER reflectance spectra from Cuprite, Nevada, and Mountain Pass, California, were compared to spectra of field samples and to ASTER-resampled AVIRIS reflectance data to determine spectral accuracy and spectroscopic mapping potential of two new ASTER SWIR reflectance datasets: RefL1b and AST_07XT. RefL1b is a new reflectance dataset produced for this study using ASTER Level 1B data, crosstalk correction, radiance correction factors, and concurrently acquired level 2 MODIS water vapor data. The AST_07XT data product, available from EDC and ERSDAC, incorporates crosstalk correction and non-concurrently acquired MODIS water vapor data for atmospheric correction. Spectral accuracy was determined using difference values which were compiled from ASTER band 5/6 and 9/8 ratios of AST_07XT or RefL1b data subtracted from similar ratios calculated for field sample and AVIRIS reflectance data. In addition, Spectral Analyst, a statistical program that utilizes a Spectral Feature Fitting algorithm, was used to quantitatively assess spectral accuracy of AST_07XT and RefL1b data.Spectral Analyst matched more minerals correctly and had higher scores for the RefL1b data than for AST_07XT data. The radiance correction factors used in the RefL1b data corrected a low band 5 reflectance anomaly observed in the AST_07XT and AST_07 data but also produced anomalously high band 5 reflectance in RefL1b spectra with strong band 5 absorption for minerals, such as alunite. Thus, the band 5 anomaly seen in the RefL1b data cannot be corrected using additional gain adjustments. In addition, the use of concurrent MODIS water vapor data in the atmospheric correction of the RefL1b data produced datasets that had lower band 9 reflectance anomalies than the AST_07XT data. Although assessment of spectral data suggests that RefL1b data are more consistent and spectrally more correct than AST_07XT data, the Spectral Analyst results indicate that spectral discrimination between some minerals, such as alunite and kaolinite, are still not possible unless additional spectral calibration using site specific spectral data are performed. ?? 2010.

Remote Sensing of Environment↗

Assessing the role of climate and resource management on groundwater dependent ecosystem changes in arid environments with the Landsat archive

Groundwater dependent ecosystems (GDEs) rely on near-surface groundwater. These systems are receiving more attention with rising air temperature, prolonged drought, and where groundwater pumping captures natural groundwater discharge for anthropogenic use. Phreatophyte shrublands, meadows, and riparian areas are GDEs that provide critical habitat for many sensitive species, especially in arid and semi-arid environments. While GDEs are vital for ecosystem services and function, their long-term (i.e. ~ 30 years) spatial and temporal variability is poorly understood with respect to local and regional scale climate, groundwater, and rangeland management. In this work, we compute time series of NDVI derived from sensors of the Landsat TM, ETM +, and OLI lineage for assessing GDEs in a variety of land and water management contexts. Changes in vegetation vigor based on climate, groundwater availability, and land management in arid landscapes are detectable with Landsat. However, the effective quantification of these ecosystem changes can be undermined if changes in spectral bandwidths between different Landsat sensors introduce biases in derived vegetation indices, and if climate, and land and water management histories are not well understood. The objective of this work is to 1) use the Landsat 8 under-fly dataset to quantify differences in spectral reflectance and NDVI between Landsat 7 ETM + and Landsat 8 OLI for a range of vegetation communities in arid and semiarid regions of the southwestern United States, and 2) demonstrate the value of 30-year historical vegetation index and climate datasets for assessing GDEs. Specific study areas were chosen to represent a range of GDEs and environmental conditions important for three scenarios: baseline monitoring of vegetation and climate, riparian restoration, and groundwater level changes. Google's Earth Engine cloud computing and environmental monitoring platform is used to rapidly access and analyze the Landsat archive along with downscaled North American Land Data Assimilation System gridded meteorological data, which are used for both atmospheric correction and correlation analysis. Results from the cross-sensor comparison indicate a benefit from the application of a consistent atmospheric correction method, and that NDVI derived from Landsat 7 and 8 are very similar within the study area. Results from continuous Landsat time series analysis clearly illustrate that there are strong correlations between changes in vegetation vigor, precipitation, evaporative demand, depth to groundwater, and riparian restoration. Trends in summer NDVI associated with riparian restoration and groundwater level changes were found to be statistically significant, and interannual summer NDVI was found to be moderately correlated to interannual water-year precipitation for baseline study sites. Results clearly highlight the complementary relationship between water-year PPT, NDVI, and evaporative demand, and are consistent with regional vegetation index and complementary relationship studies. This work is supporting land and water managers for evaluation of GDEs with respect to climate, groundwater, and resource management.

Remote Sensing of Environment↗

Satellite-based water use dynamics using historical Landsat data (1984–2014) in the southwestern United States

Remote sensing-based field-scale evapotranspiration (ET) maps are useful for characterizing water use patterns and assessing crop performance. The relative impact of climate variability and water management decisions are better studied and quantified using historical data that are derived using a set of consistent datasets and methodology. Historical (1984–2014) Landsat-based ET maps were generated for major irrigation districts in California, i.e., Palo Verde and eight other sub-basins in parts of the middle and lower Central Valley. A total of 3396 Landsat images were processed using the Operational Simplified Surface Energy Balance (SSEBop) model that integrates weather and remotely sensed images to estimate monthly and annual ET within the study sites over the 31 years. Model output evaluation and validation using gridded-flux data and water balance ET approaches indicated relatively good correspondence (R 2 up to 0.88, root mean square error as low as 14 mm/month) between SSEBop ET and validation datasets. In a pairwise comparison, annual variability of agro-hydrologic parameters of actual evapotranspiration ( ET a ), land surface temperature ( T s ), and runoff ( Q ) were found to be more variable than their corresponding climatic counterparts of atmospheric water demand ( ET o ), air temperature ( T a ), and precipitation ( P ), revealing process differences between regional climatic drivers and localized agro-hydrologic responses. However, only T a showed a consistent increase (up to 1.2 K) over study sites during the 31 years, whereas other climate variables such as ET o and P showed a generally neutral trend. This study demonstrates a useful application of “Big Data” science where large volumes of historical Landsat and weather datasets were used to quantify and understand the relative importance of water management and climate variability in crop water use dynamics in regards to the linkages among water management decisions, hydrologic processes and economic transactions. Irrigation district-wide ET a estimates were used to compute historical crop water use volumes and monetary equivalents of water savings for the Palo Verde Irrigation District (PVID). During the peak crop fallowing year in PVID, the water saved reached a maximum of ~ 107,200 acre-feet in 2011 with an estimated monetary payout value of $20.5 million. A significant decreasing trend in actual ET despite an increasing atmospheric demand in PVID highlights the role of management decisions in affecting local hydrologic processes. This study has importance for planning water resource allocation, managing water rights, sustaining agricultural production, and quantifying impacts of climate and land use/land cover changes on water resources. With increased computational efficiency, similar studies can be conducted in other parts of the world to help policy and decision makers understand and quantify various aspects of water resources management.

Arizona, California↗

The distribution, occurrence and environmental effect of mercury in Chinese coals

Mercury (Hg) is a toxic, persistent, and globally distributed pollutant due to its characteristic properties such as low melting and boiling points, conversion between chemical forms and participation in biological cycles. During combustion mercury in coal is almost totally emitted to the atmosphere. With a huge amount of coal consumed, coal combustion is one of the main anthropogenic sources of this element in the environment. In this study, Hg data of 1699 coal samples of China has been compiled, and the concentration, distribution, modes of occurrence, and the impact of Hg emissions on the environment are investigated. Most Chinese coals have Hg content in the range of 0.1 to 0.3??ppm, with an average of 0.19??ppm, which is slightly higher than the average Hg content of world coals and is close to that of the U.S. coals. The Hg content in coals varies in different coal basins, geological ages and coal ranks. The most likely mode of occurrences of Hg in high-sulfur and high Hg content coals is as solid solution in pyrite. But in low-sulfur coals, modes of occurrence of Hg are variable, and the organic-bound and sulfide-bound Hg may dominate. Silicate-bound Hg may be the main form in some coals because of magmatic intrusion. Mercury emissions during coal combustion have resulted in serious environmental contamination in China, particularly in the northeastern and southwestern China, where a high Hg content in the atmosphere occurs. ?? 2007 Elsevier B.V. All rights reserved.

Science of the Total Environment↗

Fate of geothermal mercury from Yellowstone National Park in the Madison and Missouri Rivers, USA

Mercury is a worldwide contaminant derived from natural and anthropogenic sources. River systems play a key role in the transport and fate of Hg because they drain widespread areas affected by aerial Hg deposition, transport Hg away from point sources, and are sites of Hg biogeochemical cycling and bioaccumulation. The Madison and Missouri Rivers provide a natural laboratory for studying the fate and transport of Hg contributed by geothermal discharge in Yellowstone National Park and from the atmosphere for a large drainage basin in Montana and Wyoming, United States of America (USA). Assessing Hg in these rivers also is important because they support fishery-based recreation and irrigated agriculture. During 2002 to 2006, Hg concentrations were measured in water, sediment, and fish from the main stem, 7 tributaries, and 6 lakes. Using these data, the geothermal Hg load to the Madison River and overall fate of Hg along 378 km of the Missouri River system were assessed. Geothermal Hg was the primary source of elevated total Hg concentrations in unfiltered water (6.2–31.2 ng/L), sediment (148–1100 ng/g), and brown and rainbow trout (0.12– 1.23 µg total Hg/g wet weight skinless filet) upstream from Hebgen Lake (the uppermost impoundment). Approximately 7.0 kg/y of geothermal Hg was discharged from the park via the Madison River, and an estimated 87% of that load was lost to sedimentation in and volatilization from Hebgen Lake. Consequently, Hg concentrations in water, sediment, and fish from main-stem sites downstream from Hebgen Lake were not elevated and were comparable to concentrations reported for other areas affected solely by atmospheric Hg deposition. Some Hg was sequestered in sediment in the downstream lakes. Bioaccumulation of Hg in fish along the river system was strongly correlated (r 2 =0.76–0.86) with unfiltered total and methyl Hg concentrations in water and total Hg in sediment.

Montana, Wyoming↗

Inorganic nitrogen wet deposition gradients in the Denver-Boulder metropolitan area and Colorado Front Range – Preliminary implications for Rocky Mountain National Park and interpolated deposition maps

For the first time in the 40-year history of the National Atmospheric Deposition Program / National Trends Network (NADP/NTN), a unique urban-to-rural transect of wet deposition monitoring stations were operated as part of the NTN in 2017 to quantify reactive inorganic nitrogen wet deposition for adjacent urban and rural, montane regions. The transect of NADP stations (sites) was used to collect continuous precipitation depth and weekly wet-deposition samples in the Denver – Boulder, Colorado urban corridor. Gradients in reactive inorganic nitrogen (Nr) concentrations and wet deposition were identified along the transect, which included Rocky Mountain National Park. Back trajectory modeling and stable isotopes suggested contribution of agricultural ammonia (NH3) to urban Nr wet deposition in Denver, but apportionment of wet-deposited Nr to agricultural versus urban mobile sources was not possible for this study. The results demonstrate the importance of multiple monitoring sites across an urban area in defining fine-scale geographic patterns in atmospheric deposition and its sources. Data from new sites located within 50 km of the urban area demonstrate that the urban influence doesn't extend as far as the Inverse Distance Weighting would have suggested without such empirical monitoring data. It is important to determine the radius of influence of urban emissions and associated deposition on the interpolated deposition raster, which is constrained by a paucity of monitoring sites east of Denver.

Colorado↗

Estimating burn severity and carbon emissions from a megafire in boreal forests of China

Wildfires, especially those of large size, worsen air quality and alter the carbon cycle through combustion of large quantities of biomass and release of carbon into the atmosphere. The Black Dragon fire, which occurred in 1987 in the boreal forests of China is among the top five of such megafires ever recorded in the world. With over 30 years of accumulation of data and availability of new greenhouse gas emission accounting methods, carbon emissions from this megafire can now be estimated with improved precision and greater spatial resolution. To do this, we combined field and remote sensing data to map four burn severity classes and calculated combustion efficiency in terms of the biomass immediately consumed in the fire. Results of the study showed that 1.30 million hectares burned and 52% of that area burned with high severity. The emitted carbon dioxide equivalents (CO2e), accounted for approximately 10% of total fossil fuel emissions from China in 1987, along with CO (2%–3% of annual anthropogenic CO emissions from China) and non-methane hydrocarbons (NMHC) contributing to the atmospheric pollutants. Our study provides an important basis for carbon emission estimation and understanding the impacts of megafires.

Science of the Total Environment↗

The response of streams in the Adirondack region of New York to projected changes in sulfur and nitrogen deposition under changing climate

Modeling studies project that in the future surface waters in the northeast US will continue to recover from acidification over decades following reductions in atmospheric sulfur dioxide and nitrogen oxides emissions. However, these studies generally assume stationary climatic conditions over the simulation period and ignore the linkages between soil and surface water recovery from acid deposition and changing climate, despite fundamental impacts to watershed processes and comparable time scales for both phenomena. In this study, the integrated biogeochemical model PnET-BGC was applied to two montane forest watersheds in the Adirondack region of New York, USA to evaluate the recovery of surface waters from historical acidification in response to possible future changes in climate and atmospheric sulfur and nitrogen deposition. Statistically downscaled climate scenarios on average project warmer temperatures and greater precipitation for the Adirondack by the end of the century. Model simulations suggest under constant climate, acid-sensitive Buck Creek would gain 12.8 μeq L −1 of acid neutralizing capacity (ANC) by 2100 from large reductions in deposition, whereas acid insensitive Archer Creek is projected to gain 7.9 μeq L −1 of ANC. However, climate change could limit those improvements in acid-base status. Under climate change, a negative offset relative to the ANC increases with no climate change are projected for both streams by 2100. In acid-insensitive Archer Creek the negative offset (−8.5 μeq L −1 ) was large enough that ANC is projected to decrease by −0.6 μeq L −1 , whereas in acid-sensitive Buck Creek, the negative offset (−0.4 μeq L −1 ) resulted in a slight decline of the projected future ANC increase to 12.4 μeq L −1 . Calculated target loads for 2150 for both sites decreased when future climate change was considered in model simulations, which suggests further reductions in acid deposition may be necessary to restore ecosystem structure and function under a changing climate.

New York↗

Effect of summer throughfall exclusion, summer drought, and winter snow cover on methane fluxes in a temperate forest soil

Soil moisture strongly controls the uptake of atmospheric methane by limiting the diffusion of methane into the soil, resulting in a negative correlation between soil moisture and methane uptake rates under most non-drought conditions. However, little is known about the effect of water stress on methane uptake in temperate forests during severe droughts. We simulated extreme summer droughts by exclusion of 168 mm (2001) and 344 mm (2002) throughfall using three translucent roofs in a mixed deciduous forest at the Harvard Forest, Massachusetts, USA. The treatment significantly increased CH4 uptake during the first weeks of throughfall exclusion in 2001 and during most of the 2002 treatment period. Low summertime CH4 uptake rates were found only briefly in both control and exclusion plots during a natural late summer drought, when water contents below 0.15 g cm-3 may have caused water stress of methanotrophs in the A horizon. Because these soils are well drained, the exclusion treatment had little effect on A horizon water content between wetting events, and the effect of water stress was smaller and more brief than was the overall treatment effect on methane diffusion. Methane consumption rates were highest in the A horizon and showed a parabolic relationship between gravimetric water content and CH4 consumption, with maximum rate at 0.23 g H2O g-1 soil. On average, about 74% of atmospheric CH4 was consumed in the top 4-5 cm of the mineral soil. By contrast, little or no CH4 consumption occurred in the O horizon. Snow cover significantly reduced the uptake rate from December to March. Removal of snow enhanced CH4 uptake by about 700-1000%, resulting in uptake rates similar to those measured during the growing season. Soil temperatures had little effect on CH4 uptake as long as the mineral soil was not frozen, indicating strong substrate limitation of methanotrophs throughout the year. Our results suggest that the extension of snow periods may affect the annual rate of CH4 oxidation and that summer droughts may increase the soil CH4 sink of temperate forest soils. ?? 2005 Elsevier Ltd. All rights reserved.

Soil Biology and Biochemistry↗

Aerobiology and the global transport of desert dust

Desert winds aerosolize several billion tons of soil-derived dust each year, including concentrated seasonal pulses from Africa and Asia. These transoceanic and transcontinental dust events inject a large pulse of microorganisms and pollen into the atmosphere and could therefore have a role in transporting pathogens or expanding the biogeographical range of some organisms by facilitating long-distance dispersal events. As we discuss here, whether such dispersal events are occurring is only now beginning to be investigated. Huge dust events create an atmospheric bridge over land and sea, and the microbiota contained within them could impact downwind ecosystems. Such dispersal is of interest because of the possible health effects of allergens and pathogens that might be carried with the dust.

Trends in Ecology and Evolution↗

Groundwater residence times in Shenandoah National Park, Blue Ridge Mountains, Virginia, USA: A multi-tracer approach

Chemical and isotopic properties of water discharging from springs and wells in Shenandoah National Park (SNP), near the crest of the Blue Ridge Mountains, VA, USA were monitored to obtain information on groundwater residence times. Investigated time scales included seasonal (wet season, April, 1996; dry season, August–September, 1997), monthly (March through September, 1999) and hourly (30-min interval recording of specific conductance and temperature, March, 1999 through February, 2000). Multiple environmental tracers, including tritium/helium-3 ( 3 H/ 3 He), chlorofluorocarbons (CFCs), sulfur hexafluoride (SF 6 ), sulfur-35 ( 35 S), and stable isotopes ( δ 18 O and δ 2 H) of water, were used to estimate the residence times of shallow groundwater discharging from 34 springs and 15 wells. The most reliable ages of water from springs appear to be based on SF 6 and 3 H/ 3 He, with most ages in the range of 0–3 years. This range is consistent with apparent ages estimated from concentrations of CFCs; however, CFC-based ages have large uncertainties owing to the post-1995 leveling-off of the CFC atmospheric growth curves. Somewhat higher apparent ages are indicated by 35 S (>1.5 years) and seasonal variation of δ 18 O (mean residence time of 5 years) for spring discharge. The higher ages indicated by the 35 S and δ 18 O data reflect travel times through the unsaturated zone and, in the case of 35 S, possible sorption and exchange of S with soils or biomass. In springs sampled in April, 1996, apparent ages derived from the 3 H/ 3 He data (median age of 0.2 years) are lower than those obtained from SF 6 (median age of 4.3 years), and in contrast to median ages from 3 H/ 3 He (0.3 years) and SF 6 (0.7 years) obtained during the late summer dry season of 1997. Monthly samples from 1999 at four springs in SNP had SF 6 apparent ages of only 1.2 to 2.5±0.8 years, and were consistent with the 1997 SF 6 data. Water from springs has low excess air (0–1 cm 3 kg −1 ) and N 2 –Ar temperatures that vary seasonally. Concentrations of He and Ne in excess of solubility equilibrium indicate that the dissolved gases are not fractionated. The seasonal variations in N 2 –Ar temperatures suggest shallow, seasonal recharge, and the excess He and Ne data suggest waters mostly confined to gas exchange in the shallow, mountain-slope, water-table spring systems. Water from wells in the fractured rock contains up to 8 cm 3 kg −1 of excess air with ages in the range of 0–25 years. Transient responses in specific conductance and temperature were observed in spring discharge within several hours of large precipitation events in September, 1999; both parameters increased initially, then decreased to values below pre-storm base-flow values. The groundwater residence times indicate that flushing rates of mobile atmospheric constituents through groundwater to streams draining the higher elevations in SNP average less than 3 years in base-flow conditions.

Virginia↗

Multiple source components in gas manifestations from north-central Italy

Gas manifestations in north-central Italy consist of CO2-rich gases with minor N2-rich emissions and discharge either along with thermal springs or into cold and stagnant waters. 'Cold' gases are prevalently CO2-dominated (> 90%) while gases related to the thermal waters have variable composition: from CO2 > 99.5% to N2 > 90%. The variable composition of 'thermal' gases is caused by differences in the thermal regime and lithology of the ascent paths, where there is mixing of gases from multiple sources, such as N2-rich atmospheric and deep CO2-rich metamorphic end-members. Elevated concentrations of CH4 and H2 in these gases are generally related to the presence of active geothermal systems at shallow depth, such as the Larderello-Travale field in Tuscany. The ??13C values between coexisting CH4 and CO2 in all samples analyzed suggest that CH4 originates abiogenically in 200-400??C hydrothermal systems. Far from geothermal areas, where the thermal gradient is lower or the water/gas ratio is high because of large inflow of meteoric waters, H2 and CH4 are usually lower. In some cases, they can be scrubbed or oxidized (especially H2), while the residual rising gas becomes indirectly enriched in N2 and CO2. Carbon dioxide is also enriched in some discharged gases because it is produced at shallow depth in lower temperature conditions (< 150??C). Heavy ??15N values for N2 to near +7.0??? suggest that, for some gas samples that contain excess nitrogen (e.g. where N2/Ar ??? 83), this component probably derives from ammonia-rich feldspars and micas within the Palaeozoic schist basement rocks. However, other samples show evidence of a shallow component of CH4 and N2 from Neogene basin sediments. The areal distribution of the 3He/4He ratio points to a general prevalence of atmospheric and crustal 4He in the gas discharges in central Italy. A significant component of mantle 3He is only found in the geothermal areas of Larderello where the large regional thermal anomaly suggests the presence of a deep magmatic body. ?? 1997 Elsevier Science B.V.

Chemical Geology↗