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At least 1,081 records · Page 60Linked to original sources
USGS2026

Investigation of fish communities in natural channel sections of the Mohawk River, New York

Little is known about the natural resources in the natural channel sections of the Mohawk River between Rome and Frankfort, New York, where the river channel runs separately from and parallel to the Erie Canal. This river section runs through multiple locations that are listed as active remediation sites under New York’s Inactive Hazardous Waste Disposal Site Program and has negligible public or commercial access. As a result, there is minimal recreational usage of this river section, and efforts to conduct biological sampling have been limited. To better understand the composition of fish communities and contaminant concentrations in the natural channel of the Mohawk River, the U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, sampled resident fish in the 34-kilometer section from the mouth of Oriskany Creek downstream to Frankfort. Fish communities were sampled using boat electrofishing during 2021, 2023, and 2024 across multiple reaches within this section. These data were used to estimate species richness (number of species), relative abundance and biomass (catch rates), population size structure (distribution of lengths), and fish condition (a proxy for health). Some gamefish specimens were also analyzed to determine contaminant concentrations in fish tissue. A total of 1,531 individual fish and 38 fish species were captured across all surveys. Seventeen of the 38 (45 percent) species were classified as native to the Mohawk River watershed, whereas 21 of the 38 (55 percent) species were classified as nonnative. Some popular gamefish species such as largemouth bass ( Micropterus salmoides ) and smallmouth bass ( Micropterus dolomieu ) were abundant in most reaches, whereas others such as walleye ( Sander vitreus ) and northern pike ( Esox lucius ) were found sporadically. Only one round goby ( Neogobius melanostomus ) was captured, indicating that this high-profile invasive species remains uncommon in this habitat. A backwater reach had the greatest relative abundance and condition of many species. This indicates connected lentic habitats such as oxbows and backwaters may be important nursery and refuge areas in the aquatic ecosystem. Polychlorinated biphenyl (PCB) concentrations in fish tissue were highly elevated relative to the New York State Department of Health (NYSDOH) fish consumption “don’t eat” advisory guideline. Some specimens exceeded the guideline by an order of magnitude or more, particularly those from a localized area downstream from the Utica Harbor Dam. Concentrations of perfluorooctanesulfonic acid (PFOS) often approached the NYSDOH “don’t eat” consumption guideline but only one sample exceeded the guideline. Concentrations of other contaminants such as mercury and pesticides were consistently measured at less than the “don’t eat” consumption guidelines. These data indicate PCBs remain the primary contaminant of concern in the natural channel of the Mohawk River and are readily bioaccumulating in aquatic organisms despite prior remediation measures. Taken together, the findings in this report are intended to inform future decisions related to fisheries management, public access, recreational usage, and fish consumption advisories.

New York↗
USGS2024

Annotated bibliography of scientific research relevant to oil and gas reclamation best management practices in the western United States, published from 1969 through 2020

Integrating recent scientific knowledge into management decisions supports effective natural resource management and can lead to better resource outcomes. However, finding and accessing scientific knowledge can be time consuming and costly. To assist in this process, the U.S. Geological Survey has created a series of annotated bibliographies on topics of management concern for lands in the western United States (U.S.). Oil and gas development on public lands is a long-standing and substantial component of local and regional economies and has expanded in recent decades, particularly on public lands in the western U.S. This development is associated with extensive networks of pipelines, roads, and processing facilities, across which reclamation is Federally mandated following initial well pad development (“interim” reclamation) and once resource extraction is complete (“final” reclamation). Reclamation is critical for recovering ecological services to energy-affected lands, including vegetation productivity, wildlife habitat, water and air quality, and soil stability (for example, resistance to wind and water erosion). However, reclamation of oil and gas affected lands in the western U.S. has proved challenging due to an array of regulatory and environmental factors, such as minimally developed soils, short growing seasons, herbivory, high winds, invasive species, rugged terrain, and in particular, arid climates associated with low total precipitation, high evapotranspiration rates, and highly variable precipitation patterns. We compiled and summarized journal articles, government reports, technical reports, proceedings, and theses and dissertations relevant to oil and gas reclamation. We constrained our search to products published on or before December 31, 2020 but did not limit our search by a starting date; the earliest product resulting from this effort was published in March 1969. Second, we manually scanned the last 15 years (2005-2020) of tables of contents in journals, bibliographies, and proceedings of which we were aware would contain articles highly relevant to this bibliography. We carried out the search for these products through multiple means: (1) performing a structured search of two reference databases, (2) examining articles published since 2005 in highly relevant scientific journals and conference proceedings, and (3) reviewing additional material suggested by authors of products identified in steps 1 and 2. Our search was intentionally broad in order to identify as much relevant work as possible, much of which is professionally applied and tested within the industry of oil and gas reclamation, but which remains unpublished in scientific journals. We refined the initial list of products by removing: (1) duplicates, (2) products not written in English, (3) products that were not relevant to the arid ecosystems of western North America, (4) products that were not released as research, data products, or review articles in journals or as formal scientific reports, and (5) products with data which were not relevant to reclamation of oil and gas-affected lands, or for which the study did not present new data, findings, or syntheses relevant to reclamation of oil and gas-affected lands. We summarized each product using a consistent structure (background, objectives, methods, location, findings, and implications) and assigned standardized management topics to each. Management topics are intended to aid online searching within the bibliography and are described in more detail in the Methods Section of this report; they include what type of disturbance the product addresses (well pads, mining, pipelines), what aspect of oil and gas reclamation they pertain to (practices, standards, monitoring), what type of data are present in the product (for instance soil or vegetation recovery data), and an indication if the product were from a source other than a published, peer-reviewed outlet (such as dissertations or unpublished professional reports – these are identified as grey literature). The review process for this annotated bibliography included an initial internal colleague review of each summary, requesting input on each summary from an author of the original product, and a formal peer-review. Our initial searches resulted in 3,197 total products, of which 290 met our criteria for inclusion. “Reclamation Practices” is by far the management topic most addressed, followed by “Reclamation Monitoring,” for example, products assessing what and how monitoring methods are used to track and measure reclamation outcome. This document may be accessed at https://doi.org/10.3133/ofr20231068 or from the U.S. Geological Survey Publication Warehouse ( https://pubs.usgs.gov/ ). The 1-page product summaries herein will also be used to create a bibliography at https://apps.usgs.gov/science-for-resource-managers that includes links to each original product, where available, and in which subject matter will be searchable by topic, location, and year. The studies compiled and summarized here may inform planning and management actions that seek to reclaim landscapes across the western U.S. which have been affected by oil and gas development.

Open-File Report↗
USGS2013

Porphyry copper assessment of Southeast Asia and Melanesia: Chapter D in Global mineral resource assessment

The U.S. Geological Survey collaborated with member countries of the Coordinating Committee for Geoscience Programmes in East and Southeast Asia (CCOP) on an assessment of the porphyry copper resources of Southeast Asia and Melanesia as part of a global mineral resource assessment. The region hosts world-class porphyry copper deposits and underexplored areas that are likely to contain undiscovered deposits. Examples of known porphyry copper deposits include Batu Hijau and Grasberg in Indonesia; Panguna, Frieda River, and Ok Tedi in Papua New Guinea; and Namosi in Fiji. This assessment covers the countries of Cambodia, Indonesia, Lao People&rsquo;s Democratic Republic, Malaysia, Myanmar, Papua New Guinea, Singapore, Thailand, and parts of southeastern China, India, the Solomon Islands, Vanuatu, and Fiji. Twenty-two geographic areas were delineated as tracts that are permissive for porphyry copper deposits in Southeast Asia. Permissive tracts are grouped into four broadly defined geographic/geologic areas, as follows: (1) the Indochina Peninsula area, (2) Indonesian and Malaysian Islands, (3) New Guinea Island and Papuan New Guinea islands, and (4) Melanesia. Individual tracts range from less than 1,000 to more than 350,000 square kilometers in area. Permissive tracts are based on mapped and inferred subsurface (<1 kilometer depth) distributions of igneous rocks of specific age ranges that define magmatic arcs and magmatic belts that are likely to contain porphyry copper deposits. Most of these magmatic arcs are subduction-related, although some have porphyry-style deposits occurring in postcollisional and (or) poorly understood tectonic settings. Although maps at a variety of different scales were used in the compilation, the final tract boundaries are intended for use at a scale of 1:1,000,000. Global grade and tonnage models for porphyry copper deposits were evaluated. Most of the known deposits are best described as fitting the copper-gold (Cu-Au) subtype of porphyry copper deposit. For some permissive tracts, a general porphyry copper-gold-molybdenum (Cu-Au-Mo) model was used. Assessment participants estimated numbers of undiscovered deposits at different levels of confidence for most of the permissive tracts. These estimates were combined with grade and tonnage models using a Monte Carlo simulation to estimate undiscovered resources. Additional resources in extensions of deposits with identified resources were not evaluated. Assessment results, presented in tables and graphs, show mean amounts of metal and mineralized rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each tract. This assessment estimated a mean of 89 undiscovered porphyry copper deposits for the assessed permissive tracts in Southeast Asia and Melanesia. About 288 million metric tons (Mt) of copper and 18,000 metric tons (t) of gold, as well as byproduct molybdenum and silver, could be associated with undiscovered deposits. This represents about four times the number of deposits with identified resources (23) already discovered in Southeast Asia; reliable reported identified resources for those 23 deposits total 84 Mt of copper and 6,000 t of gold. Eleven permissive tracts have no known porphyry copper deposits with reported resources. Three of those 11 tracts lacked sufficient information for a probabilistic assessment and are discussed in qualitative terms. On a regional basis, both the Indochina Peninsula area and the Indonesian-Malaysian Islands area are estimated to contain about 10 times as much in place copper in undiscovered porphyry copper deposits as has been identified to date. For the New Guinea Island areas, the ratio of undiscovered to identified copper resources is about 2. Some parts of the region have a long history of porphyry exploration cycles and mine development, interrupted at times by political and social unrest, environmental concerns, and natural disasters. Changes in mining laws within the region and the recent high price of gold on the world market have prompted renewed interest in porphyry copper deposits in Southeast Asia and Melanesia. However, predicted undiscovered deposits may not be found, and if found, may not be developed. This assessment includes an overview of the assessment results with summary tables. Detailed descriptions of each tract are included in appendixes, with estimates of numbers of undiscovered deposits, and probabilistic estimates of amounts of copper, molybdenum, gold, and silver that could be contained in undiscovered deposits for each permissive tract. A geographic information system (GIS) that accompanies the report includes tract boundaries and a database of known porphyry copper deposits and significant prospects.

Scientific Investigations Report↗
USGS2013

Analysis of environmental setting, surface-water and groundwater data, and data gaps for the Citizen Potawatomi Nation Tribal Jurisdictional Area, Oklahoma, through 2011

The Citizen Potawatomi Nation Tribal Jurisdictional Area, consisting of approximately 960 square miles in parts of three counties in central Oklahoma, has an abundance of water resources, being underlain by three principal aquifers (alluvial/terrace, Central Oklahoma, and Vamoosa-Ada), bordered by two major rivers (North Canadian and Canadian), and has several smaller drainages. The Central Oklahoma aquifer (also referred to as the Garber-Wellington aquifer) underlies approximately 3,000 square miles in central Oklahoma in parts of Cleveland, Logan, Lincoln, Oklahoma, and Pottawatomie Counties and much of the tribal jurisdictional area. Water from these aquifers is used for municipal, industrial, commercial, agricultural, and domestic supplies. The approximately 115,000 people living in this area used an estimated 4.41 million gallons of fresh groundwater, 12.12 million gallons of fresh surface water, and 8.15 million gallons of saline groundwater per day in 2005. Approximately 8.48, 2.65, 2.24, 1.55, 0.83, and 0.81 million gallons per day of that water were used for domestic, livestock, commercial, industrial, crop irrigation, and thermoelectric purposes, respectively. Approximately one-third of the water used in 2005 was saline water produced during petroleum production. Future changes in use of freshwater in this area will be affected primarily by changes in population and agricultural practices. Future changes in saline water use will be affected substantially by changes in petroleum production. Parts of the area periodically are subject to flooding and severe droughts that can limit available water resources, particularly during summers, when water use increases and streamflows substantially decrease. Most of the area is characterized by rural types of land cover such as grassland, pasture/hay fields, and deciduous forest, which may limit negative effects on water quality by human activities because of lesser emissions of man-made chemicals on such areas than in more urbanized areas. Much of the water in the area is of good quality, though some parts of this area have water quality impaired by very hard surface water and groundwater; large chloride concentrations in some smaller streams; relatively large concentrations of nutrients and counts of fecal-indicator bacteria in the North Canadian River; and chloride, iron, manganese, and uranium concentrations that exceed primary or secondary drinking-water standards in water samples collected from small numbers of wells. Substantial amounts of hydrologic and water-quality data have been collected in much of this area, but there are gaps in those data caused by relatively few streamflow-gaging stations, uneven distribution of surface-water quality sampling sites, lack of surface-water quality sampling at high-flow and low-flow conditions, and lack of a regularly measured and sampled groundwater network. This report summarizes existing water-use, climatic, geographic, hydrologic, and water-quality data and describes several means of filling gaps in hydrologic data for this area.

Oklahoma↗
USGS2022

Water-surface profile maps for the Mississippi River near Prairie Island, Minnesota, 2019

Digital water-surface profile maps for a 14-mile reach of the Mississippi River near Prairie Island, Minnesota, from the confluence of the St. Croix River at Prescott, Wisconsin, to upstream from the U.S. Army Corps of Engineers Lock and Dam No. 3 (U.S. Army Corps of Engineers National Inventory of Dams number MN00595) in Welch, Minnesota, were created by the U.S. Geological Survey (USGS) in cooperation with the Prairie Island Indian Community in the State of Minnesota. The water-surface profile maps depict estimates of the areal extent and depth of water inundation corresponding to selected water levels (stages) at the USGS streamgage Mississippi River at Prescott, Wisconsin (USGS station number 05344500). Current conditions for estimating near-real-time areas of inundation by use of USGS streamgage information may be obtained from the National Water Information System on the internet at https://doi.org/10.5066/F7P55KJN . In this study, water-surface profiles were computed for the stream reach by means of a one-dimensional step-backwater model. The model was calibrated by using the most current stage-discharge relations at the USGS streamgage Mississippi River at Prescott, Wisconsin (USGS station number 05344500). The hydraulic model was then used to determine four water-surface profiles for stream stages at 37.00, 39.00, 40.00, and 41.00 feet (ft) referenced to the streamgage datum and ranging from bankfull to approximately 2 ft below the highest recorded stage at the streamgage, which is 43.11 ft. The simulated water-surface profiles were then combined with a geographic information system digital elevation model (derived from light detection and ranging data having a 0.35-ft vertical and 1.97-ft root mean square error horizontal resolution) in order to delineate the area inundated at each stage. The combination of maps provided in this report and real-time stage data from the upstream USGS streamgage provide emergency management personnel and residents with information that is critical for flood response activities such as evacuations and road closures as well as for post flood recovery efforts.

Minnesota↗
USGS2022

Update and recalibration of the Rio Grande Transboundary Integrated Hydrologic Model, New Mexico and Texas, United States, and northern Chihuahua, Mexico

The Rio Grande Transboundary Integrated Hydrologic Model (RGTIHM) was developed through an interagency effort between the U.S. Geological Survey and the Bureau of Reclamation to provide a tool for analyzing the hydrologic system response to the historical evolution of water use and potential changes in water supplies and demands in the Hatch Valley (also known as Rincon Valley in the study area) and Mesilla Basin, New Mexico and Texas, United States, and northern Chihuahua, Mexico. Reclamation operates the Rio Grande Project (RGP) to store and deliver surface water for irrigation and municipal use within the study area and in the El Paso Valley south of the El Paso Narrows. Biases in the RGTIHM’s simulation of streamflow and aquifer storage depletion and the availability of new estimates of historical agricultural consumptive use in the study area initiated an update and recalibration of the RGTIHM. In addition to the new estimates of historical agricultural consumptive use, updates were made to more accurately represent the natural system and included adjustments to the initial groundwater levels; streamflow rating tables; Rio Grande, canal, and drain streambed elevations; tributary streambed elevations; surface-water inflows and diversions; RGP surface-water deliveries and canal waste; on-farm efficiency; the routing of surface-water runoff within the MODFLOW Farm Process; and general head boundaries used to simulate interbasin groundwater flow. Model settings, including the assignment of hydraulic conductivity and storage properties to model layers and the MODFLOW solver package, were adjusted to improve numerical stability, and the model was recalibrated to better simulate the natural system. The updated and recalibrated RGTIHM demonstrates a robust ability to simulate the spatially and temporally variable measurements, estimates, or reports of hydraulic head, surface-water flows, agricultural pumping, RGP surface-water deliveries and canal waste, and decadal aquifer storage changes, with improvements over the previous version of the model.

Chihuahua, New Mexico, Texas↗
USGS2005

Effects of land-use changes and stormflow-detention basins on flooding and nonpoint-source pollution, in Irondequoit Creek basin, Monroe and Ontario counties, New York--application of a precipitation-runoff model

Urbanization of the 150-square-mile Irondequoit Creek basin in Monroe and Ontario Counties, N.Y., continues to spread southward and eastward from the City of Rochester, on the shore of Lake Ontario. Conversion of forested land to other uses over the past 40 years has increased to the extent that more than 50 percent of the basin is now developed. This expansion has increased flooding and impaired stream-water quality in the northern (downstream) half of the basin. A precipitation-runoff model of the Irondequoit Creek basin was developed with the model code HSPF (Hydrological Simulation Program--FORTRAN) to simulate the effects of land-use changes and stormflow-detention basins on flooding and nonpoint-source pollution on the basin. Model performance was evaluated through a combination of graphical comparisons and statistical tests, and indicated 'very good' agreement (mean error less than 10 percent) between observed and simulated daily and monthly streamflows, between observed and simulated monthly water temperatures, and between observed total suspended solids loads and simulated sediment loads. Agreement between monthly observed and simulated nutrient loads was 'very good' (mean error less than 15 percent) or 'good' (mean error between 15 and 25 percent). Results of model simulations indicated that peak flows and loads of sediment and total phosphorus would increase in a rural subbasin, where 10 percent of the basin was converted from forest and grassland to pervious and impervious developed areas. Subsequent simulation of a stormflow-detention basin at the mouth of this subbasin indicated that peak flows and constituent loads would decrease below those that were generated by the land-use-change scenario, and, in some cases, below those that were simulated by the original land-use scenario. Other results from model simulations of peak flows over a 30-year period (1970-2000), with and without simulation of 50-percent flow reductions at one existing and nine hypothetical stormflow-detention basins, indicated that stormflow-detention basins would likely decrease peak flows 14 to 17 percent on Allen Creek and 17 to 18 percent on Irondequoit Creek at Blossom Road. The model is intended as a management tool that water-resource managers can use to guide decisions regarding future development in the basin. The model and associated files are designed to permit (1) creation of scenarios that represent planned or hypothetical development in the basin, and (2) assessment of the flooding and chemical loads that are likely to result. Instream stormflow-detention basins can be simulated in separate scenarios to assess their effect on flooding and chemical loads. This report (1) provides examples of how the model can be applied to address these issues, (2) discusses the model revisions required to simulate land-use changes and detention basins, and (3) describes the analytical steps necessary to evaluate the model results.

Scientific Investigations Report↗
USGS2014

Digital database of microfossil localities in Alameda and Contra Costa Counties, California

The eastern San Francisco Bay region (Contra Costa and Alameda Counties, California) is a geologically complex area divided by faults into a suite of tectonic blocks. Each block contains a unique stratigraphic sequence of Tertiary sediments that in most blocks unconformably overlie Mesozoic sediments. Age and environmental interpretations based on analysis of microfossil assemblages are key factors in interpreting geologic history, structure, and correlation of each block. Much of this data, however, is distributed in unpublished internal reports and memos, and is generally unavailable to the geologic community. In this report the U.S. Geological Survey microfossil data from the Tertiary sediments of Alameda and Contra Costa counties are analyzed and presented in a digital database, which provides a user-friendly summary of the micropaleontologic data, locality information, and biostratigraphic and ecologic interpretations.

California↗
USGS2020

Groundwater quality in relation to drinking water health standards and geochemical characteristics for 54 domestic wells in Clinton County, Pennsylvania, 2017

Despite the reliance on groundwater by approximately 2.4 million rural Pennsylvania residents, publicly available data to characterize the quality of private well water are limited. As part of a regional effort to characterize groundwater in rural areas of Pennsylvania, samples from 54 domestic wells in Clinton County were collected and analyzed in 2017. The samples were evaluated for a wide range of constituents and compared to drinking-water health standards and geochemical characteristics. The sampled wells were completed to depths ranging from 46 to 500 feet in bedrock that was of predominantly sandstone, shale, or carbonate lithology. Results of this study show that the sampled groundwater quality in Clinton County generally met most drinking-water standards that apply to public water supplies. However, a percentage of samples exceeded drinking-water maximum contaminant levels (MCLs) for total coliform bacteria (57.4 percent), Escherichia coli ( E. coli ) (25.9 percent), nitrate (1.9 percent), and arsenic (1.9 percent); and secondary maximum contaminant levels (SMCLs) for pH (31.5 percent), manganese (29.6 percent), iron (13 percent), total dissolved solids (7.4 percent), aluminum (1.9 percent), and chloride (1.9 percent). Sodium concentrations exceeded the U.S. Environmental Protection Agency drinking-water advisory recommendation in 16.7 percent of the samples. Radon-222 activities exceeded the proposed drinking-water standard of 300 picocuries per liter (pCi/L) in 59.3 percent of the samples. The only volatile organic compounds (VOCs) detected were acetone and methyl ethyl ketone in two separate samples; neither constituent exceeded drinking-water standards. Higher median nitrate concentrations were found in the carbonate (3.26 milligrams per liter [mg/L]) versus shale (less than 0.04 mg/L) and sandstone (0.27 mg/L) aquifer subsets. Most of the elevated nitrate concentrations were associated with E. coli detections in the carbonate aquifers, where transmissive bedrock can facilitate groundwater contamination by human activities at the land surface. The median pH of groundwater from the sandstone aquifers (6.53) was less than those for the shale aquifers (7.31) and carbonate aquifers (7.43). Generally, the lower pH samples had greater potential for elevated concentrations of dissolved metals, including beryllium, copper, lead, nickel, and zinc, whereas the higher pH samples had greater potential for elevated concentrations of total dissolved solids, sodium, fluoride, boron, and uranium. Near-neutral samples (pH 6.5 to 7.5) had greater hardness and alkalinity concentrations than other samples with pH outside this range. Many samples from the shale or sandstone aquifers, particularly those with pH less than 6.5, were identified as having serious potential corrosivity based on the combination of the calcite saturation index and the chloride to sulfate mass ratio; however, none of the samples from the carbonate aquifers was identified as seriously corrosive. Groundwater from 3.7 percent of the wells had concentrations of methane greater than the Pennsylvania action level of 7 mg/L, and 48 of the 54 wells (88.9 percent) had detectable concentrations of methane greater than the 0.0002 mg/L detection limit. Greater methane concentrations were found more frequently in groundwater sampled from the shale aquifers than the carbonate or sandstone aquifers in the study area. Most of the samples containing elevated methane (greater than 0.2 mg/L) were located outside the area of the Appalachian Plateaus. The elevated concentrations of methane generally were associated with suboxic groundwater (dissolved oxygen less than 0.5 mg/L) that had near-neutral to alkaline pH and were correlated with concentrations of iron, manganese, ammonia, sodium, lithium, barium, fluoride, and boron. The stable carbon and hydrogen isotopic compositions of methane in two of four samples analyzed for isotopes were consistent with compositions reported for mud-gas logging samples from gas-bearing geologic units (thermogenic gas) in the Appalachian Plateaus region, whereas two others were consistent with methane of microbial origin or a mixture of microbial and thermogenic gas. Forty-two percent of samples had chloride concentrations greater than 20 mg/L with variable bromide concentrations. Corresponding chloride/bromide ratios are consistent with low-bromide sources such as road-deicing salt and septic effluent or animal waste, or, in a few cases, high-bromide brine. Brines characterized by relatively high bromide are naturally present in deeper parts of the regional groundwater system and, in some cases, may be mobilized by gas drilling. The chloride, bromide, and other constituents in road-deicing salt or brine solutions tend to be diluted by mixing with fresh groundwater in shallow aquifers used for water supply. One of the four groundwater samples with methane concentrations greater than 4 mg/L had chloride and bromide concentrations and a chloride/bromide ratio that indicates mixing with a salinity source such as road-deicing salt, whereas the chloride and bromide concentrations and ratios for the other three high-methane samples indicate mixing with a small amount of brine (0.03 percent or less). In two other eastern Pennsylvania county studies where gas drilling is absent, groundwater with comparable chloride/bromide ratios, bromide, and chloride concentrations plus other element associations have been reported. Additional sampling and analysis, such as isotopic analysis of the dissolved gas, fracture analysis, and more detailed evaluation of surrounding land uses, may be warranted to better understand the origin of the methane and brine constituents in groundwater at specific locations.

Pennsylvania↗
USGS2011

Aggregation of estimated numbers of undiscovered deposits: an R-script with an example from the Chu Sarysu Basin, Kazakhtan: Chapter B in Global mineral resource assessment

Mineral resource assessments completed by the U.S. Geological Survey during the past three decades express geologically based estimates of numbers of undiscovered mineral deposits as probability distributions. Numbers of undiscovered deposits of a given type are estimated in geologically defined regions. Using Monte Carlo simulations, these undiscovered deposit estimates are combined with tonnage and grade models to derive a probability distribution describing amounts of commodities and rock that could be present in undiscovered deposits within a study area. In some situations, it is desirable to aggregate the assessment results from several study areas. This report provides a script developed in open-source statistical software, R, that aggregates undiscovered deposit estimates of a given type, assuming independence, total dependence, or some degree of correlation among aggregated areas, given a user-specified correlation matrix.

Chu Sarysu Basin↗
USGS2019

A probabilistic assessment methodology for carbon dioxide enhanced oil recovery and associated carbon dioxide retention

The U.S. Energy Independence and Security Act of 2007 authorized the U.S. Geological Survey (USGS) to conduct a national assessment of the potential volume of hydrocarbons recoverable by injection of carbon dioxide (CO 2 ) into known oil reservoirs with historical production. The implementation of CO 2 enhanced oil recovery (CO 2 -EOR) techniques could increase the U.S. recoverable hydrocarbon resource base. Use of anthropogenic CO 2 in the CO 2 -EOR process could reduce the amount of CO 2 released to the atmosphere by allowing a percentage of the injected CO 2 to remain in reservoir pore space once occupied by produced oil and water or by CO 2 dissolution in oil and water in the reservoir. The USGS has developed a new methodology for the national assessment of technically recoverable oil resources that may be produced by using current CO 2 -EOR technologies. The methodology relies on a proprietary reservoir-level database, the comprehensive resource database (CRD). The CRD incorporates commercially available geologic and engineering data, and USGS-defined play averages or province averages of reservoir data were used to populate incomplete records. Values from the CRD are used to estimate the original oil in place ( OOIP ) for each reservoir. The inputs are reviewed by USGS geologists, particularly when play or province averages have been used. Monte Carlo simulation is used to produce a numerical probability distribution for the OOIP for each reservoir, with the mean defined as the value of the OOIP in the CRD. A reservoir model (CO 2 Prophet, developed for the U.S. Department of Energy by Texaco, Inc.) is used to determine the incremental recovery factors for oil during the CO 2 -EOR process, on an individual reservoir basis. The model is also used to estimate the volume of CO 2 remaining in the reservoir after the CO 2 -EOR process is complete. Empirical decline curve analysis and comparison with data from published papers and reports on CO 2 -EOR projects are utilized to substantiate the simulation results. Numerical distributions of recovery factors are prepared for variations in the reservoir lithology (clastic or carbonate). The distribution of incremental oil is computed by multiplying the appropriate probability distribution of recovery factors by the individual reservoir distribution of the OOIP . A way to estimate the CO 2 remaining in the reservoir after the completion of the CO 2 -EOR process is also included in the methodology. Assessment results will be aggregated to play, petroleum province, regional, and national scales. This assessment methodology has been tested on the Horseshoe Atoll, Upper Pennsylvanian-Wolfcampian play in the Permian Basin Province in Texas; the play consists of 27 reservoirs having at least 2 billion barrels of OOIP that are amenable to the CO 2 -EOR process. The play was selected as a test case because CO 2 -EOR production data and published reports are available for several reservoirs within the play. Preliminary estimates of oil recoverable by implementation of miscible CO 2 -EOR are comparable to those reported in the literature and obtained by reservoir decline curve analysis.

Scientific Investigations Report↗
USGS2021

U.S. Geological Survey Karst Interest Group Proceedings, October 19–20, 2021

Karst hydrogeologic systems represent challenging and unique conditions to scientists attempting to study groundwater flow and contaminant transport. Karst terrains are characterized by distinct and beautiful landscapes, caverns, and springs, and many of the exceptional karst areas are designated as national or state parks. The range and complexity of landforms and groundwater flow systems associated with karst terrains are enormous, perhaps more than any other type of aquifer. The U.S. Geological Survey (USGS) Karst Interest Group (KIG), formed in 2000, is a loosely knit, grassroots organization of USGS and non-USGS scientists and researchers devoted to fostering better communication among scientists working on, or interested in, karst aquifers. The primary mission of the KIG is to encourage and support interdisciplinary collaboration and technology transfer among scientists working in karst areas. To accomplish its mission, the KIG has organized a series of workshops. To date (2021), eight KIG workshops, including the workshop documented in this report, have been held. This workshop is the first virtual workshop. The abstracts and extended abstracts provide a snapshot in time of past and current karst-related studies. The field trip guide is included in the proceedings volume even though the field trip will not occur in person.

Scientific Investigations Report↗
USGS2023

South San Francisco Bay Salt Pond Restoration Project—A synthesis of Phase-1 mercury studies

The South Bay Salt Pond Restoration Project (SBSPRP) encompasses over 6,000 hectares of former salt production ponds along the south edge of the San Francisco Bay and represents the largest wetland restoration effort on the west coast of North America. A series of studies associated with Phase 1 (2010–2018) restoration activities that are focused on a historically mercury contaminated slough and series of ponds within the restoration area have recently been completed. This report brings together the key findings of these loosely coordinated studies and integrates the results into a more comprehensive and holistic product that informs future restoration activities associated with the SBSPRP and elsewhere. This report documents key findings associated with the breach of pond A6: (1) a short-term spike in slough fish (Mississippi silverside) total mercury concentration in lower Alviso Slough; (2) a short-term spike in surface-water particulate total mercury in lower Alviso Slough; (3) significant sediment scour in Alviso Slough adjacent to and downstream of the breach points; (4) a decrease in surface-sediment methylmercury (as a percentage of total mercury) in lower Alviso Slough; (5) the transport of 70 kilograms per year of sediment-associated total mercury into pond A6 during the first 2 years following the breach but with much of this coming from outside of Alviso Slough, presumably from the nearby shallows, Guadalupe Slough, and the larger southern San Francisco Bay area; and (6) a slowing of bed sediment erosion in lower Alviso Slough 3–5 years after the breaching of pond A6. Although this report is not intended to be prescriptive in terms of the next steps the SBSPRP should or should not take, the totality of the findings presented provide critical process-level information regarding the extent and the duration of spikes in mercury levels in water, sediment, fish, and birds, which appeared to result from the two management actions under study. Thus, these results can be used to anticipate similar ecosystem responses associated with similar management actions that may be considered in the future. We also conclude this report by highlighting unanswered questions associated with mercury dynamics as it relates to the restoration project, and possible future directions for research.

California↗
USGS2010

Estimation of magnitude and frequency of floods in urban basins in Missouri

Streamgage flood-frequency analyses were done for 35 streamgages on urban streams in and adjacent to Missouri for estimation of the magnitude and frequency of floods in urban areas of Missouri. A log-Pearson Type-III distribution was fitted to the annual series of peak flow data retrieved from the U.S. Geological Survey National Water Information System. For this report, the flood frequency estimates are expressed in terms of percent annual exceedance probabilities of 50, 20, 10, 4, 2, 1, and 0.2. Of the 35 streamgages, 30 are located in Missouri. The remaining five non-Missouri streamgages were added to the dataset to improve the range and applicability of the regression analyses from the streamgage frequency analyses. Ordinary least-squares was used to determine the best set of independent variables for the regression equations. Basin characteristics selected for independent variables into the ordinary least-squares regression analyses were based on theoretical relation to flood flows, literature review of possible basin characteristics, and the ability to measure the basin characteristics using digital datasets and geographic information system technology. Results of the ordinary least-squares were evaluated on the basis of Mallow's Cp statistic, the adjusted coefficient of determination, and the statistical significance of the independent variables. The independent variables of drainage area and percent impervious area were determined to be statistically significant and readily determined from existing digital datasets. The drainage area variable was computed using the best elevation data available, either from a statewide 10-meter grid or high-resolution elevation data from urban areas. The impervious area variable was computed from the National Land Cover Dataset 2001 impervious area dataset. The National Land Cover Dataset 2001 impervious area data for each basin was compared to historical imagery and 7.5-minute topographic maps to verify the national dataset represented the urbanization of the basin at the time streamgage data were collected. Eight streamgages had less urbanization during the period of time streamflow data were collected than was shown on the 2001 dataset. The impervious area values for these eight urban basins were adjusted downward as much as 23 percent to account for the additional urbanization since the streamflow data were collected. Weighted least-squares regression techniques were used to determine the final regression equations for the statewide urban flood-frequency equations. Weighted least-squares techniques improve regression equations by adjusting for different and varying lengths in streamflow records. The final flood-frequency equations for the 50-, 20-, 10-, 4-, 2-, 1-, and 0.2-percent annual exceedance probability floods for Missouri provide a technique for estimating peak flows on urban streams at gaged and ungaged sites. The applicability of the equations is limited by the range in basin characteristics used to develop the regression equations. The range in drainage area is 0.28 to 189 square miles; range in impervious area is 2.3 to 46.0 percent. Seven of the 35 selected streamgages were used to compare the results of the existing rural and urban equations to the urban equations presented in this report for the 1-percent annual exceedance probability. Results of the comparison indicate that the estimated peak flows for the urban equation in this report ranged from 3 to 52 percent higher than the results from the rural equations. Comparing the estimated urban peak flows from this report to the existing urban equation developed in 1986 indicated the range was 255 percent lower to 10 percent higher. The overall comparison between the current (2010) and 1986 urban equations indicates a reduction in estimated peak flow values for the 1-percent annual exceedance probability flood.

Missouri↗
USGS2012

Alluvial diamond resource potential and production capacity assessment of Guinea

In May of 2000, a meeting was convened in Kimberley, South Africa, by representatives of the diamond industry and leaders of African governments to develop a certification process intended to assure that export shipments of rough diamonds were free of conflict concerns. Outcomes of the meeting were formally supported later in December of 2000 by the United Nations in a resolution adopted by the General Assembly. By 2002, the Kimberley Process Certification Scheme (KPCS) was ratified and signed by diamond-producing and diamond-importing countries. The goal of this study was to estimate the alluvial diamond resource endowment and the current production capacity of the alluvial diamond mining sector of Guinea. A modified volume and grade methodology was used to estimate the remaining diamond reserves within Guinea's diamondiferous regions, while the diamond-production capacity of these zones was estimated by inputting the number of artisanal miners, the number of days artisans work per year, and the average grade of the deposits into a formulaic expression. Guinea's resource potential was estimated to be approximately 40 million carats, while the production capacity was estimated to lie within a range of 480,000 to 720,000 carats per year. While preliminary results have been produced by integrating historical documents, five fieldwork campaigns, and remote sensing and GIS analysis, significant data gaps remain. The artisanal mining sector is dynamic and is affected by a variety of internal and external factors. Estimates of the number of artisans and deposit variables, such as grade, vary from site to site and from zone to zone. This report has been developed on the basis of the most detailed information available at this time. However, continued fieldwork and evaluation of artisanally mined deposits would increase the accuracy of the results.

Scientific Investigations Report↗
USGS2023

Statewide sampling to determine spatial distribution, prevalence, and occurrence of per- and polyfluoroalkyl substances (PFAS) in Illinois community water supplies, 2020–21

Per- and polyfluoroalkyl substances (PFAS) are a group of synthetic chemicals that have been manufactured and used globally since the 1940s. PFAS are used for their oil- and water-repellent properties, ability to reduce friction, and their flame-retardant nature. PFAS are widely used in a variety of products, including clothing, carpet, food packaging, and firefighting foam. The properties that make them useful in manufacturing, however, also make them persistent and mobile, causing potential exposures to the environment and humans. Known as “forever chemicals,” these compounds resist degradation and have been determined to bioaccumulate in humans and wildlife. The Illinois Environmental Protection Agency (IEPA) collected a total of 1,711 samples (includes quality-control samples) of finished water at 1,428 entry points from 1,017 Illinois community water supply (CWS) systems and analyzed the water samples for PFAS. The results following confirmation samples indicated a mean of 99 percent of all sample results were below the minimum reporting level (MRL) of 2 nanograms per liter (ng/L). Of the detections at or above the MRL, 7 of 18 PFAS were detected in 149 of 1,428 entry points (about 10 percent). Of the nearly 7.4 million residents directly served by the CWS systems sampled, more than 1.3 million residents (about 18 percent) are served by CWS systems that had at least one detection of PFAS above the MRL of 2 ng/L. The most frequently detected PFAS were perfluorobutanesulfonic acid (about 6.2 percent, 37 ng/L maximum concentration), perfluorooctanesulfonic acid (PFOS) (about 5.0 percent, 150 ng/L maximum concentration), and perfluorooctanoic acid (PFOA) (about 4.8 percent, 25 ng/L maximum concentration). Of the 1,428 entry point samples from the CWS systems, 149 samples had confirmed detections of PFAS, with 93 of those 149 (about 62 percent) samples having at least one PFAS with a concentration that exceeded the median detected concentration of 3.2 ng/L. The highest concentrations detected were 150 ng/L (PFOS) and 140 ng/L (perfluorohexanesulfonic acid) at one CWS location which has been shut down and a different source of water has been provided to the consumers. Although PFAS detections were more common in CWS systems using surface-water sources (about 35 percent, 30 of 85) and mixed sources (50 percent, 5 of 10) compared to those using groundwater sources (about 9 percent, 114 of 1,333), a greater range of PFAS concentrations were observed in groundwater CWS systems (2 to 150 ng/L) than in surface-water CWS systems (2 to 15 ng/L). Statistically significant differences were determined between some detected PFAS (PFOA, PFOS, and perfluorohexanoic acid) and the source of drinking water (groundwater, surface water, or mixed). This report summarizes the occurrence and spatial distribution of PFAS in CWS systems across Illinois. The results from this sampling effort could be used by Illinois public health officials to identify the potential risk of PFAS in drinking water to human health.

Illinois↗
USGS2006

Ground-water hydrology and water quality of the Southern High Plains Aquifer, Cannon Air Force Base, Curry County, New Mexico, 1994-2005

In cooperation with the U.S. Air Force, the U.S. Geological Survey has collected hydrologic data about the Southern High Plains aquifer at Cannon Air Force Base in east-central New Mexico since 1994. Under the guidance of the State of New Mexico, ground-water quality of the aquifer has been analyzed as part of annual monitoring at regulated sites at the base. This report provides a summary and interpretation of all available hydrologic data collected by the U.S. Geological Survey for Cannon Air Force Base environmental managers for the regulated sites of Landfill 5 and the Sewage Lagoons between 1994 and 2005.

New Mexico↗
USGS2019

Spatial and Temporal Patterns of Best Management Practice Implementation in the Chesapeake Bay Watershed, 1985–2014

Efforts to restore water quality in Chesapeake Bay and its tributaries often include extensive Best Management Practice (BMP) implementation on agricultural and developed lands. These BMPs include a variety of methods to reduce nutrient and sediment loads, such as cover crops, conservation tillage, urban filtering systems, and other practices. Estimates of BMP implementation throughout the Chesapeake Bay watershed were provided for each year from 1985 through 2014 by the Chesapeake Bay Program (CBP). This dataset of BMP implementation is a compilation of actions reported by New York, Maryland, Pennsylvania, Delaware, West Virginia, Virginia, and the District of Columbia, and includes a wide array of management activities. Management actions vary among the jurisdictions and generally reflect the typical land use in each region. The amount of implementation also varies according to different priorities, reporting practices, and special programs within each jurisdiction. For example, extensive cover crop implementation was reported in Maryland whereas Pennsylvania, in general, has lower levels of BMP implementation reported on cropland. Pennsylvania and Maryland have higher levels of infiltration BMPs on developed land compared to those in Virginia. Conservation tillage BMPs accounted for the majority of reported agricultural BMP implementation in 1985. By 2014, however, a more diverse collection of agricultural BMPs was reported and conservation tillage BMPs accounted for a smaller proportion of overall reported agricultural BMP implementation. After the year 2000, land-use change BMPs, such as land retirement, pasture fencing, and forest buffers, were more commonly reported across the Chesapeake Bay watershed. Expected changes in nutrient and sediment loads in the Chesapeake Bay watershed due to BMP implementation were estimated by use of specially designed annual scenarios of the CBP Partnership Phase 5.3.2 Watershed Model. Nitrogen loads to streams were estimated to be reduced by 11 percent from 1985 to 2014 due to the implementation of BMPs. Compared with 1985, phosphorus loads were estimated to be 19 percent lower and sediment loads were estimated to be 23 percent lower by 2014 due to the effects of BMPs. Reductions in total nitrogen from 1985 to 2014 due to BMPs varied spatially across the watershed and were estimated to be as high as 42 percent in areas of the Eastern Shore of the Chesapeake Bay. Reductions in phosphorus and sediment also varied spatially, with the largest reductions occurring in the Potomac watershed upstream of Washington, D.C. and the Eastern Shore of Maryland, according to the CBP model results. Additional model scenarios were developed to estimate the effect of individual BMP types. The largest estimated reductions in total nitrogen loads on agricultural lands in 2014 were attributed to land retirement, animal waste management systems, and conservation tillage. The largest estimated reductions in total phosphorus loads on agricultural lands were attributed to animal waste management systems, pasture fencing, and phytase feed additives in 2014. The largest estimated reduction in total sediment loads on agricultural lands was attributed to conservation tillage, pasture fencing, and conservation plans. Dry ponds, wet ponds, and constructed wetlands were reported extensively throughout the watershed. These BMPs accounted for about half of the reduction in nitrogen loads from developed land to streams, half of the phosphorus reduction, and about a third of the sediment reduction.

Chesapeake Bay Watershed↗