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Estimated Withdrawals from Stream-Valley Aquifers and Refined Estimated Withdrawals from Selected Aquifers in the United States, 2000

The U.S. Geological Survey National Water Use Information Program compiles estimates of fresh ground-water withdrawals in the United States on a 5-year interval. In the year-2000 compilation, withdrawals were reported from principal aquifers and aquifer systems including two general aquifers - Alluvial and Other aquifers. Withdrawals from a widespread aquifer group - stream-valley aquifers - were not specifically identified in the year-2000 compilation, but they are important sources of ground water. Stream-valley aquifers are alluvial aquifers located in the valley of major streams and rivers. Stream-valley aquifers are long but narrow aquifers that are in direct hydraulic connection with associated streams and limited in extent compared to most principal aquifers. Based in large part on information published in U.S. Geological Survey reports, preliminary analysis of withdrawal data and hydrogeologic and surface-water information indicated areas in the United States where possible stream-valley aquifers were located. Further assessment focused on 24 states and the Commonwealth of Puerto Rico. Withdrawals reported from Alluvial aquifers in 16 states and withdrawals reported from Other aquifers in 6 states and the Commonwealth of Puerto Rico were investigated. Two additional States - Arkansas and New Jersey - were investigated because withdrawals reported from other principal aquifers in these two States may be from stream-valley aquifers. Withdrawals from stream-valley aquifers were identified in 20 States and were about 1,560 Mgal/d (million gallons per day), a rate comparable to withdrawals from the 10 most productive principal aquifers in the United States. Of the 1,560 Mgal/d of withdrawals attributed to stream-valley aquifers, 1,240 Mgal/d were disaggregated from Alluvial aquifers, 150 Mgal/d from glacial sand and gravel aquifers, 116 Mgal/d from Other aquifers, 28.1 Mgal/d from Pennsylvanian aquifers, and 24.9 Mgal/d from the Mississippi River Valley alluvial aquifer. Five States, including Colorado (552 Mgal/d), Kansas (384 Mgal/d), Oklahoma (126 Mgal/d), Kentucky (102 Mgal/d), and Ohio (100 Mgal/d), accounted for 81 percent of estimated stream-valley aquifer withdrawals identified in this report. Of the total withdrawals from stream-valley aquifers, about 63 percent (984 Mgal/d) were used for irrigation, 26 percent (400 Mgal/d) for public-supply, and 11 percent (177 Mgal/d) for self-supplied industrial uses. The largest estimated water withdrawals were from stream-valley aquifers associated with the South Platte (404 Mgal/d), Arkansas (395 Mgal/d), and Ohio (221 Mgal/d) Rivers.

Scientific Investigations Report

Analytical results for As species and related elements in interstitial porewater and sediment from the Maurice River and Union Lake in Vineland, New Jersey

Union Lake, the Maurice River, and the Blackwater Branch , a tributary of the Maurice River, all parts of a small watershed near Vineland, New Jersey, are contaminated by arsenic (As) from a local chemical factory (fig. l)(Faust and others, 1987). An indepth study to be used for the design of the remedial action at the Vineland Chemical Co. Superfund site was initiated by the U.S. Environmental Protection Agency to determine the extent and severity of the contamination. The Vineland Chemical Co. site is located in Cumberland County, New Jersey. Organic As herbicides were manufactured there from approximately 1949 to the late 1980's. As part of the effort, core samples were collected in the Maurice River close to the chemical factory and from Union Lake, a reservoir approximately seven miles from the factory. This report summarizes the analytical results for As speciation and various constituents in the interstitial porewater and associated sediment from these cores. Because the U.S. Geological Survey has the analytical expertise and necessary equipment, the samples were analyzed in USGS laboratories in Denver, Colorado and Seattle, Washington.

New Jersey

Estimated loads of selected constituents from permitted and nonpermitted sources at selected surface-water-quality stations in the Musconetcong, Rockaway, and Whippany River basins, New Jersey, 1985-90

Surface-water-quality data from the cooperative sampling network maintained by the U.S. Geological Survey and the New Jersey Department of Environmental Protection for 1985-90 are summarized for stations in the Musconetcong, Rockaway, and Whippany River Basins. Four constituents are included in the analysis: biochemical oxygen demand (BOD), total nitrogen, total phosphorus, and total organic carbon (TOC). Contemporaneous streamflow estimates were used to calculate instream loads from constituent concentrations in water-quality samples. Loads from permitted point sources were estimated as the sum of reported loads of BOD, total nitrogen, and total phosphorus upstream from each station. TOC permitted-source loads were not estimated because point-source release data were insufficient. The relative contribution of loads from permitted sources to the total instream loads differed markedly among the basins and between upstream and downstream locations within the basins. Some of these differences can be attributed to reesrvoir effects; others are related to the presence or absence of major permitted sources upstream from water-quality stations.

Water-Resources Investigations Report

Seismicity map of the State of New Jersey

This map is one of a series of seismicity maps produced by the U.S. Geological Survey that show earthquake data of individual states or groups of states at the scale of 1:1,000,000. This map shows only those earthquakes with epicenters located within the boundaries of New Jersey, even though earthquakes in nearby states may have been felt or may have caused damage in New Jersey.

New Jersey

Managing drought risk with a computer model of the Raritan River Basin water-supply system in central New Jersey

The reservoirs and pumping stations that comprise the Raritan River Basin water-supply system and its interconnections to the Delaware-Raritan Canal water-supply system, operated by the New Jersey Water Supply Authority (NJWSA), provide potable water to central New Jersey communities. The water reserve of this combined system can easily be depleted by an extended period of below-normal precipitation. Efficient operation of the combined system is vital to meeting the water-supply needs of central New Jersey. In an effort to improve the efficiency of the system operation, the U.S. Geological Survey (USGS), in cooperation with the NJWSA, has developed a computer model that provides a technical basis for evaluating the effects of alternative patterns of operation of the Raritan River Basin water-supply system. This fact sheet describes the model, its technical basis, and its operation.

New Jersey

Ground-penetrating radar and differential global positioning system data collected from Long Beach Island, New Jersey, April 2015

Scientists from the United States Geological Survey, St. Petersburg Coastal and Marine Science Center, U.S. Geological Survey Pacific Coastal and Marine Science Center, and students from the University of Hawaii at Manoa collected sediment cores, sediment surface grab samples, ground-penetrating radar (GPR) and Differential Global Positioning System (DGPS) data from within the Edwin B. Forsythe National Wildlife Refuge–Holgate Unit located on the southern end of Long Beach Island, New Jersey, in April 2015 ( FAN 2015-611-FA ). The study’s objective was to identify washover deposits in the stratigraphic record to aid in understanding barrier island evolution. This report is an archive of GPR and DGPS data collected from Long Beach Island in 2015. Data products, including raw GPR and processed DGPS data, elevation corrected GPR profiles, and accompanying Federal Geographic Data Committee metadata can be downloaded from the Data Downloads page.

New Jersey

Preliminary integrated geologic map databases for the United States: Connecticut, Maine, Massachusetts, New Hampshire, New Jersey, Rhode Island and Vermont

The rapid growth in the use of Geographic Information Systems (GIS) has highlighted the need for regional and national scale digital geologic maps that have standardized information about geologic age and lithology. Such maps can be conveniently used to generate derivative maps for manifold special purposes such as mineral-resource assessment, metallogenic studies, tectonic studies, and environmental research. Although two digital geologic maps (Schruben and others, 1994; Reed and Bush, 2004) of the United States currently exist, their scales (1:2,500,000 and 1:5,000,000) are too general for many regional applications. Most states have digital geologic maps at scales of about 1:500,000, but the databases are not comparably structured and, thus, it is difficult to use the digital database for more than one state at a time. This report describes the result for a seven state region of an effort by the U.S. Geological Survey to produce a series of integrated and standardized state geologic map databases that cover the entire United States. In 1997, the United States Geological Survey's Mineral Resources Program initiated the National Surveys and Analysis (NSA) Project to develop national digital databases. One primary activity of this project was to compile a national digital geologic map database, utilizing state geologic maps, to support studies in the range of 1:250,000- to 1:1,000,000-scale. To accomplish this, state databases were prepared using a common standard for the database structure, fields, attribution, and data dictionaries. For Alaska and Hawaii new state maps are being prepared and the preliminary work for Alaska is being released as a series of 1:250,000 scale quadrangle reports. This document provides background information and documentation for the integrated geologic map databases of this report. This report is one of a series of such reports releasing preliminary standardized geologic map databases for the United States. The data products of the project consist of two main parts, the spatial databases and a set of supplemental tables relating to geologic map units. The datasets serve as a data resource to generate a variety of stratigraphic, age, and lithologic maps. This documentation is divided into four main sections: (1) description of the set of data files provided in this report, (2) specifications of the spatial databases, (3) specifications of the supplemental tables, and (4) an appendix containing the data dictionaries used to populate some fields of the spatial database and supplemental tables.

Connecticut, Maine, Massachusetts, New Hampshire,

Distribution of chloride concentrations in the principal aquifers of the New Jersey coastal plain, 1977-81

The U.S. Geological Survey maintains a saltwater monitoring network in New Jersey to document and evaluate the movement of saline water into freshwater aquifers that serve as sources of water supply. Areas in the Coastal Plain with existing or potential saltwater intrusion are delineated. Data collected through 1981 indicate that freshwater aquifers in parts of seven Coastal-Plain counties are contaminated by saline water. Encroachment of saltwater into freshwater aquifers in the Sayreville area of Middlesex County and in the lower peninsula of Cape May County has been reported for about 40 years and is now more extensive. Several other areas are experiencing limited saltwater intrusion. These include the Keyport-Union Beach area in Monmouth County, areas along the Delaware estuary in Gloucester and Salem Counties, and at Point Pleasant Beach and Seaside Heights in Ocean County. The continuing updip movement of saline water in the Potomac-Raritan-Magothy aquifer system is also threatening existing freshwater supplies in the interior areas of Gloucester and Salem Counties. Saltwater intrusion has resulted from extensive ground-water withdrawals. The resultant freshwater head declines have caused reversals in the natural hydraulic gradients that permit inland movement of saline water from adjacent saltwater bodies. (USGS)

Water-Resources Investigations Report

Methodology for Estimation of Flood Magnitude and Frequency for New Jersey Streams

Methodologies were developed for estimating flood magnitudes at the 2-, 5-, 10-, 25-, 50-, 100-, and 500-year recurrence intervals for unregulated or slightly regulated streams in New Jersey. Regression equations that incorporate basin characteristics were developed to estimate flood magnitude and frequency for streams throughout the State by use of a generalized least squares regression analysis. Relations between flood-frequency estimates based on streamflow-gaging-station discharge and basin characteristics were determined by multiple regression analysis, and weighted by effective years of record. The State was divided into five hydrologically similar regions to refine the regression equations. The regression analysis indicated that flood discharge, as determined by the streamflow-gaging-station annual peak flows, is related to the drainage area, main channel slope, percentage of lake and wetland areas in the basin, population density, and the flood-frequency region, at the 95-percent confidence level. The standard errors of estimate for the various recurrence-interval floods ranged from 48.1 to 62.7 percent. Annual-maximum peak flows observed at streamflow-gaging stations through water year 2007 and basin characteristics determined using geographic information system techniques for 254 streamflow-gaging stations were used for the regression analysis. Drainage areas of the streamflow-gaging stations range from 0.18 to 779 mi2. Peak-flow data and basin characteristics for 191 streamflow-gaging stations located in New Jersey were used, along with peak-flow data for stations located in adjoining States, including 25 stations in Pennsylvania, 17 stations in New York, 16 stations in Delaware, and 5 stations in Maryland. Streamflow records for selected stations outside of New Jersey were included in the present study because hydrologic, physiographic, and geologic boundaries commonly extend beyond political boundaries. The StreamStats web application was developed cooperatively by the U.S. Geological Survey and the Environmental Systems Research Institute, Inc., and was designed for national implementation. This web application has been recently implemented for use in New Jersey. This program used in conjunction with a geographic information system provides the computation of values for selected basin characteristics, estimates of flood magnitudes and frequencies, and statistics for stream locations in New Jersey chosen by the user, whether the site is gaged or ungaged.

Scientific Investigations Report

Marine geophysical data collected in a shallow back-barrier estuary, Barnegat Bay, New Jersey

In 2011, the U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection, began a multidisciplinary research project to better understand the water quality in Barnegat Bay, New Jersey. This back-barrier estuary is experiencing degraded water quality, algal blooms, loss of seagrass, and increases in oxygen stress, macroalgae, stinging nettles, and brown tide. The spatial scale of the estuary and the scope of challenges within it necessitate a multidisciplinary approach that includes establishing the regional geology and the estuary’s physical characteristics and modeling how the estuary’s morphology interacts to affect its water quality. This report presents the data collected during this project for use in understanding the morphology and the distribution of sea-floor and sub-sea-floor sediments within Barnegat Bay, describes the methods used to collect and process those data, and includes links to the final processed datasets. These data can be used by scientists to understand the links between geomorphology, geologic framework, sediment transport, and estuarine water quality and circulation.

New Jersey

Hurricane Sandy washover deposits on southern Long Beach Island, New Jersey

Sedimentologic and topographic data from Hurricane Sandy washover deposits were collected from southern Long Beach Island, New Jersey, in order to document changes to the barrier-island beaches, dunes, and coastal wetlands caused by Hurricane Sandy and subsequent storm events. These data will provide a baseline dataset for use in future coastal change descriptive and predictive studies and assessments. The data presented here were collected as part of the U.S. Geological Survey’s Barrier Island and Estuarine Wetland Physical Change Assessment Project ( http://coastal.er.usgs.gov/sandy-wetland-assessment/ ), which aims to assess ecological and societal vulnerability that results from long- and short-term physical changes to barrier islands and coastal wetlands. This report describes data that were collected in April 2015, approximately 2½ years after Hurricane Sandy’s landfall on October 29, 2012. During the field campaign, washover deposits were photographed and described, and sediment cores, sediment samples, and surface-elevation data were collected. Data collected during this study, including sample locations and elevations, core photographs, computed tomography scans, descriptive core logs, sediment grain-size data, and accompanying Federal Geographic Data Committee metadata, are available in the associated U.S. Geological Survey data release (Bishop and others, 2016; http://dx.doi.org/10.5066/F7PK0D7S ).

New Jersey

Simulation of Surface-Water Conditions in the Nontidal Passaic River Basin, New Jersey

The Passaic River Basin, the third largest drainage basin in New Jersey, encompasses 950 mi2 (square miles) in the highly urbanized area outside New York City, with a population of 2 million. Water quality in the basin is affected by many natural and anthropogenic factors. Nutrient loading to the Wanaque Reservoir in the northern part of the basin is of particular concern and is caused partly by the diversion of water at two downstream intakes that is transferred back upstream to refill the reservoir. The larger of these diversions, Wanaque South intake, is on the lower Pompton River near Two Bridges, New Jersey. To support the development of a Total Maximum Daily Load (TMDL) for nutrients in the nontidal part of the basin (805 mi2), a water-quality transport model was needed. The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection and New Jersey EcoComplex, developed a flow-routing model to provide the hydraulic inputs to the water-quality model. The Diffusion Analogy Flow model (DAFLOW) described herein was designed for integration with the Water Quality Analysis Simulation Program (WASP) watershed water-quality model. The flow routing model was used to simulate flow in 108 miles of the Passaic River and major tributaries. Flow data from U.S. Geological Survey streamflow-gaging stations represent most of the model's upstream boundaries. Other model inputs include estimated flows for ungaged tributaries and unchanneled drainage along the mainstem, and reported flows for major point-source discharges and diversions. The former flows were calibrated using the drainage-area ratio method. The simulation extended over a 4+ year period representing a range in flow conditions. Simulated channel cross-sectional geometry in the DAFLOW model was calibrated using several different approaches by adjusting area and top width parameters. The model also was calibrated to observed flows for water year 2001 (low flow) at five mainstem gaging stations and one station at which flow was estimated. The model's target range was medium to low flows--the range of typical intake operations. Simulated flow mass balance, hydrographs (flood-wave speed, attenuation, and spread), flow-duration curves, and velocity and depth values were compared to observed counterparts. Mass balance and hydrograph fit were evaluated quantitatively. Simulation results generally were within the accuracy of the flow data at the measurement stations. The model was validated to observed flows for water years 2000 (average flow), 2002 (extreme low flow), and 2003 (high flow). Results for 19 of 20 comparisons indicate average mass-balance and model-fit errors of 6.6 and 15.7 percent, respectively, indicating that the model reasonably represents the time variation of streamflow in the nontidal Passaic River Basin. An algorithm (subroutine) also was developed for DAFLOW to simulate the hydraulic mixing that occurs near the Wanaque South intake upstream from the confluence of the Pompton and Passaic Rivers. The intake draws water from multiple sources, including effluent from a nearby wastewater-treatment plant, all of which have different phosphorus loads. The algorithm determines the proportion of flow from each source and operates within a narrow flow range. The equations used in the algorithm are based on the theory of diffusion and lateral mixing in rivers. Parameters used in the equations were estimated from limited available local flow and water-quality data. As expected, simulation results for water years 2000, 2001, and 2003 indicate that most of the water drawn to the intake comes from the Pompton River; however, during many short periods of low flow and high diversion, particularly in water year 2002, entrainment of the other flow sources compensated for the insufficient flow in the Pompton River. As additional verification of the flow model used in the water-quality model, a Branched Lagrangian Transport Model (B

Scientific Investigations Report

Geographic information system programs for use in the water-supply-allocation permitting process

Computer programs designed for use in a geographic information system as an aid in the water-supply- allocation permitting process are described. These programs were developed by the U.S. Geological Survey during a project conducted in cooperation with the New Jersey Department of Environmental Protection. The programs enable a user to display proposed water-supply-allocation sites in a defined area together with present sites and important hydrologic and geographic features on a computer screen or on hardcopy plots. The programs are menu-driven and do not require familiarity with geographic information systems. Source codes for the programs are included in appendixes.

Open-File Report

Implementation of MOVE.1, censored MOVE.1, and piecewise MOVE.1 low-flow regressions with applications at partial-record streamgaging stations in New Jersey

The U.S. Geological Survey (USGS) uses Maintenance of Variance Extension Type 1 (MOVE.1) regression to transfer streamflows measured at long-term continuous-record streamgaging stations to partial-record (PR) streamgaging stations where intermittent base-flow measurements are available. MOVE.1 regression is used widely throughout the hydrologic community to extend historic low flows and low-flow statistics at continuous-record streamgaging stations to streamgaging stations that have access to only a partial record of low flows. The method correlates base-flow measurements at PR streamgaging stations with daily mean streamflows measured at index stations that exhibit similar streamflow characteristics. Following changes in the computing platform for storing, processing, retrieving, and publishing National Water Information System (NWIS) hydrologic data, legacy Statistical Analysis System (SAS) code developed by the USGS to implement the MOVE.1 regression was no longer suitable for reading and processing NWIS streamflow data. To migrate the MOVE.1 program so that it could continue to read streamflow data using the new hydrologic data platform, the SAS code was re-written in R, an open source programming language and software environment for statistical computing and graphics supported by the R Foundation for Statistical Computing. The work described in this report was performed in a study conducted by USGS in cooperation with the New Jersey Department of Environmental Protection. During migration from SAS to R, graphical and tabular output generated by the R script was compared to output produced by the legacy SAS code to ensure that equations used to perform the MOVE.1 regression remained the same. An option to perform censored MOVE.1 regression was added to extend the MOVE.1 methodology to cases where one or more measured continuous-record or PR streamgaging station flows are zero valued. In addition to permitting censored regression, the new R script includes an option to perform piecewise MOVE.1 regression when the relation between PR station and index station low flows varies significantly across the range of index station streamflows. Together with traditional MOVE.1 regression, censored, and piecewise MOVE.1 regression methods implemented by the R script offer less biased estimates than ordinary least squares regression for the annual 7-day 10-year and other low-flow statistics at PR stations for a range of base-flow conditions. The R script is used to implement the MOVE.1 regression methods across a variety of computing platforms.

New Jersey

Presence and distribution of trace elements in streambed sediments, New Jersey

The National Water Quality Assessment (NAWQA) Program, developed by the U.S. Geological Survey (USGS), was implemented in 1991 to (1) provide a nationally consistent description of the status of surface- and ground-water quality in systems that represent a large part of the Nation's water resources, (2) determine water-quality trends, and (3) determine relations between past and present water quality and land- and waste-management practices. Information collected and interpreted as part of NAWQA will add to the scientific basis for water-management decisions and policy formulation (Leahy and others, 1990).

New Jersey

Real-time surface-water monitoring in New Jersey, 2003

A network of 93 gaging stations that provide surface-water stage, flow (discharge), and tide-level data on a “realtime” basis through satellite, radio, and telephone telemetry is operating (May 2003) in New Jersey through a cooperative effort of the U.S. Geological Survey (USGS) and other agencies. The stream data from these stations are transmitted every 1 to 4 hours and then are immediately posted for viewing on the Internet. This fact sheet describes the “real-time” monitoring network, and the equipment used to measure stage and flow and to transmit the data for viewing on the Internet. Instructions for viewing the data are included.

New Jersey

Application of health-based screening levels to ground-water quality data in a state-scale pilot effort

A state-scale pilot effort was conducted to evaluate a Health-Based Screening Level (HBSL) approach developed for communicating findings from the U.S. Geological Survey (USGS) National Water-Quality Assessment Program in a human-health context. Many aquifers sampled by USGS are used as drinking-water sources, and water-quality conditions historically have been assessed by comparing measured contaminant concentrations to established drinking-water standards and guidelines. Because drinking-water standards and guidelines do not exist for many analyzed contaminants, HBSL values were developed collaboratively by the USGS, U.S. Environmental Protection Agency (USEPA), New Jersey Department of Environmental Protection, and Oregon Health & Science University, using USEPA toxicity values and USEPA Office of Water methodologies. The main objective of this report is to demonstrate the use of HBSL approach as a tool for communicating water-quality data in a human-health context by conducting a retrospective analysis of ground-water quality data from New Jersey. Another important objective is to provide guidance on the use and interpretation of HBSL values and other human-health benchmarks in the analyses of water-quality data in a human-health context. Ground-water samples collected during 1996-98 from 30 public-supply, 82 domestic, and 108 monitoring wells were analyzed for 97 pesticides and 85 volatile organic compounds (VOCs). The occurrence of individual pesticides and VOCs was evaluated in a human-health context by calculating Benchmark Quotients (BQs), defined as ratios of measured concentrations of regulated compounds (that is, compounds with Federal or state drinking-water standards) to Maximum Contaminant Level (MCL) values and ratios of measured concentrations of unregulated compounds to HBSL values. Contaminants were identified as being of potential human-health concern if maximum detected concentrations were within a factor of 10 of the associated MCL or HBSL (that is, maximum BQ value (BQmax) greater than or equal to 0.1) in any well type (public supply, domestic, monitoring). Most (57 of 77) pesticides and VOCs with human-health benchmarks were detected at concentrations well below these levels (BQmax less than 0.1) for all three well types; however, BQmax values ranged from 0.1 to 3,000 for 6 pesticides and 14 VOCs. Of these 20 contaminants, one pesticide (dieldrin) and three VOCs (1,2-dibromoethane, tetrachloroethylene, and trichloroethylene) both (1) were measured at concentrations that met or exceeded MCL or HBSL values, and (2) were detected in more than 10 percent of samples collected from raw ground water used as sources of drinking water (public-supply and (or) domestic wells) and, therefore, are particularly relevant to human health. The occurrence of multiple pesticides and VOCs in individual wells also was evaluated in a human-health context because at least 53 different contaminants were detected in each of the three well types. To assess the relative human-health importance of the occurrence of multiple contaminants in different wells, the BQ values for all contaminants in a given well were summed. The median ratio of the maximum BQ to the sum of all BQ values for each well ranged from 0.83 to 0.93 for all well types, indicating that the maximum BQ makes up the majority of the sum for most wells. Maximum and summed BQ values were statistically greater for individual public-supply wells than for individual domestic and monitoring wells. The HBSL approach is an effective tool for placing water-quality data in a human-health context. For 79 of the 182 compounds analyzed in this study, no USEPA drinking-water standards or guidelines exist, but new HBSL values were calculated for 39 of these 79 compounds. The new HBSL values increased the number of detected pesticides and VOCs with human-health benchmarks from 65 to 77 (of 97 detected compounds), thereby expanding the basis for interpreting contaminant-occu

Scientific Investigations Report

Hydrostratigraphy, soil/sediment chemistry, and water quality, Potomac-Raritan-Magothy aquifer system, Puchack Well Field Superfund site and vicinity, Pennsauken Township, Camden County, New Jersey, 1997-2001

Drinking-water supplies from the Potomac-Raritan-Magothy aquifer system at the Puchack well field in Pennsauken Township, Camden County, New Jersey, have been contaminated by hexavalent chromium-the most toxic and mobile form-at concentrations exceeding the New Jersey maximum contaminant level of 100 micrograms per liter. Also, scattered but widespread instances of volatile organic compounds (primarily trichloroethylene) at concentrations that exceed their respective maximum contaminant levels in the area's ground water have been reported. Because inorganic and organic contaminants are present in the ground water underlying the Puchack well field, no water from there has been withdrawn for public supply since 1998, when the U.S. Environmental Protection Agency (USEPA) added the area that contains the Puchack well field to the National Priorities List. As part of the USEPA's investigation of the Puchack Well Field Superfund site, the U.S. Geological Survey (USGS) conducted a study during 1997-2001 to (1) refine previous interpretations of the hydrostratigraphic framework, hydraulic gradients, and local directions of ground-water flow; (2) describe the chemistry of soils and saturated aquifer sediments; and (3) document the quality of ground water in the Potomac-Raritan-Magothy aquifer system in the area. The four major water-bearing units of the Potomac-Raritan-Magothy aquifer system-the Upper aquifer (mostly unsaturated in the study area), the Middle aquifer, the Intermediate Sand (a local but important unit), and the Lower aquifer-are separated by confining units. The confining units contain areas of cut and fill, resulting in permeable zones that permit water to pass through them. Pumping from the Puchack well field during the past 3 decades resulted in downward hydraulic gradients that moved contaminants into the Lower aquifer, in which the production wells are finished, and caused ground water to flow northeast, locally. A comparison of current (1997-2001) water levels near the site of the former pumping center with data from previous investigations indicates that, since pumping at the Puchack well field ceased, the dominant local ground-water flow direction is to the southeast, aligned with regional flow. Chromium concentrations were highest (8,010 micrograms per liter in 2000-01) in water from the Middle aquifer immediately downgradient from a possible source; the extent of this chromium plume is unknown but appears to be small. A second, unrelated, localized chromium plume also was identified in the Middle aquifer. The Intermediate Sand was found to contain an areally extensive plume of chromium-contaminated water, with concentrations up to 6,310 micrograms per liter in 2000-01, and another plume of about the same size, with concentrations up to 4,810 micrograms per liter in 2000-01, was identified in the Lower aquifer. The previous USGS investigation indicated the approximate extent of the combined plumes; the current delineation indicates that their locations have shifted slightly to the southeast since 1998. Concentrations of chromium in ground water decreased at some well locations by as much as 60 percent between sampling rounds in 1997-98 and 1999-2001. The decrease in chromium concentration at a given well could be the result of the chemical reduction of hexavalent chromium and precipitation of the resulting trivalent chromium, the sorption of hexavalent chromium to aquifer materials, or the physical movement of the plumes. Available data indicate that all three processes likely have affected concentrations. The distribution of hexavalent and total chromium in the soils and sediments of a possible source area indicates that some hexavalent chromium has undergone chemical reduction in the soils, but the degree to which this process takes place in the aquifer currently is not known. Nor is it known whether contaminated soils continue to contribute chromium to the aquifer system. Contamination by vola

Scientific Investigations Report