SEARCH · USGS Science

Results for “Atmosphere”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6Linked to original sources

USGS1992

Consumption of atmospheric methane by desert soils

Atmospheric concentrations of methane, a greenhouse gas, are increasing at a rate of about 1% yr -1 (refs 1–4). Oxidation by methylotrophic bacteria in soil is the largest terrestrial sink for atmospheric CH 4 , and is estimated to consume about 30 x 10 12 g CH 4 yr -1 (refs 4–6). Spatial and temporal variability in the rate of soil CH 4 consumption are incompletely understood 6–19 , as are the apparent inhibitory 12,13,18 or enhancing 20 effects of changes in land use. Dry deserts, which constitute 20% of total land surface, are not currently included in global soil uptake estimates. Here we describe measurements of the rate of uptake of atmospheric CH 4 by undisturbed desert soils. We observed rates as great as 4.38 mg CH 4 m -2 day -1 ; 50% of the measured rates were between 0.24 and 0.92 mg CH 4 m -2 d -1 . Uptake of CH 4 by desert soil is enhanced by rainfall after an initial soil-drainage period—opposite to the response of temperate forest soils 12 . Methane is consumed to a depth of about 2 m, allowing for deep removal of atmospheric CH 4 if near-surface conditions are unfavourable for consumption. On the basis of an annual average CH 4 consumption rate of 0.66 mg CH 4 m -2 d -1 , we estimate that the global CH 4 sink term needs to be increased by about 7 x 10 12 g yr -1 to account for the contribution of desert soils.

Nevada↗

USGS2016

Observed decrease in atmospheric mercury explained by global decline in anthropogenic emissions

Observations of elemental mercury (Hg 0 ) at sites in North America and Europe show large decreases (&sim;1–2% y −1 ) from 1990 to present. Observations in background northern hemisphere air, including Mauna Loa Observatory (Hawaii) and CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container) aircraft flights, show weaker decreases (<1% y −1 ). These decreases are inconsistent with current global emission inventories indicating flat or increasing emissions over that period. However, the inventories have three major flaws: ( i ) they do not account for the decline in atmospheric release of Hg from commercial products; ( ii ) they are biased in their estimate of artisanal and small-scale gold mining emissions; and ( iii ) they do not properly account for the change in Hg 0 /Hg II speciation of emissions from coal-fired utilities after implementation of emission controls targeted at SO 2 and NO x . We construct an improved global emission inventory for the period 1990 to 2010 accounting for the above factors and find a 20% decrease in total Hg emissions and a 30% decrease in anthropogenic Hg 0 emissions, with much larger decreases in North America and Europe offsetting the effect of increasing emissions in Asia. Implementation of our inventory in a global 3D atmospheric Hg simulation [GEOS-Chem (Goddard Earth Observing System-Chemistry)] coupled to land and ocean reservoirs reproduces the observed large-scale trends in atmospheric Hg 0 concentrations and in Hg II wet deposition. The large trends observed in North America and Europe reflect the phase-out of Hg from commercial products as well as the cobenefit from SO 2 and NO x emission controls on coal-fired utilities.

Proceedings of the National Academy of Sciences↗

USGS2009

Characterization of clouds in Titan's tropical atmosphere

Images of Titan's clouds, possible over the past 10 years, indicate primarily discrete convective methane clouds near the south and north poles and an immense stratiform cloud, likely composed of ethane, around the north pole. Here we present spectral images from Cassini's Visual Mapping Infrared Spectrometer that reveal the increasing presence of clouds in Titan's tropical atmosphere. Radiative transfer analyses indicate similarities between summer polar and tropical methane clouds. Like their southern counterparts, tropical clouds consist of particles exceeding 5 ??m. They display discrete structures suggestive of convective cumuli. They prevail at a specific latitude band between 8??-20?? S, indicative of a circulation origin and the beginning of a circulation turnover. Yet, unlike the high latitude clouds that often reach 45 km altitude, these discrete tropical clouds, so far, remain capped to altitudes below 26 km. Such low convective clouds are consistent with the highly stable atmospheric conditions measured at the Huygens landing site. Their characteristics suggest that Titan's tropical atmosphere has a dry climate unlike the south polar atmosphere, and despite the numerous washes that carve the tropical landscape. ?? 2009. The American Astronomical Society.

Astrophysical Journal↗

USGS2009

Nutrient availability and phytoplankton nutrient limitation across a gradient of atmospheric nitrogen deposition

Atmospheric nitrogen (N) deposition to lakes and watersheds has been increasing steadily due to various anthropogenic activities. Because such anthropogenic N is widely distributed, even lakes relatively removed from direct human disturbance are potentially impacted. However, the effects of increased atmospheric N deposition on lakes are not well documented, We examined phytoplankton biomass, the absolute and relative abundance of limiting nutrients (N and phosphorus [P]), and phytoplankton nutrient limitation in alpine lakes of the Rocky Mountains of Colorado (USA) receiving elevated (>6 kg N??ha -1 ??yr -1 ) or low (<2 kg N??ha -1 ??yr -1 ) levels of atmospheric N deposition. Highdeposition lakes had higher NO 3 -N and total N concentrations and higher total N : total P ratios. Concentrations of chlorophyll and seston carbon (C) were 2-2.5 times higher in highdeposition relative to low-deposition lakes, while high-deposition lakes also had higher seston C:N and C:P (but not N:P) ratios. Short-term enrichment bioassays indicated a qualitative shift in the nature of phytoplankton nutrient limitation due to N deposition, as highdeposition lakes had an increased frequency of primary P limitation and a decreased frequency and magnitude of response to N and to combined N and P enrichment. Thus elevated atmospheric N deposition appears to have shifted nutrient supply from a relatively balanced but predominantly N-deficient regime to a more consistently P-limited regime in Colorado alpine lakes. This adds to accumulating evidence that sustained N deposition may have important effects on lake phytoplankton communities and plankton-based food webs by shifting the quantitative and qualitative nature of nutrient limitation. ?? 2009 by the Ecological Society of America.

Ecology↗

USGS2007

Investigating atmospheric mercury with the U.S. Geological Survey Mobile Mercury Laboratory

Atmospheric mercury is thought to be an important source of mercury present in fish, resulting in numerous local, statewide, tribal, and province-wide fish consumption advisories in the United States and Canada (U.S. Environmental Protection Agency, 2007a). To understand how mercury occurs in the atmosphere and its potential to be transferred from the atmosphere to the biosphere, the U.S. Geological Survey (USGS) has been investigating sources and forms of atmospheric mercury, especially in locations where the amount of mercury deposited from precipitation is above average.

Fact Sheet↗

USGS2007

SCIAMACHY’s View of the Polar Atmosphere

The instrument SCIAMACHY onboard the European ENVISAT mission provides unique capabilities for deriving atmospheric geophysical parameters. Since its launch in early 2002 it has operated successfully in orbit. Due to ENVISAT’s high inclination orbit the polar regions are monitored continuously. We report here results about the status of the polar atmosphere in the past 5 years with special emphasis on the southern hemisphere. This part of the atmosphere is considered to be highly sensitive to anthropogenic impacts on the Earth system and thus to climate change. The acquired data permit retrieving information on the Earth’s atmosphere from troposphere up to the mesosphere

Open-File Report↗

USGS2003

Water resources of Monroe County, New York, water years 1997-99, with emphasis on water quality in the Irondequoit Creek basin—Atmospheric deposition, ground water, streamflow, trends in water quality, and chemical loads to Irondequoit Bay

Irondequoit Creek drains 169 square miles in the eastern part of Monroe County. Over time, nutrients transported by Irondequoit Creek to Irondequoit Bay on Lake Ontario have contributed to the eutrophication of the bay. Sewage-treatment-plant effluent, a major source of nutrients to the creek and its tributaries, was eliminated from the basin in 1979 by diversion to a regional wastewater-treatment facility, but sediment and contaminants from nonpoint sources continue to enter the creek and Irondequoit Bay. This report, the fourth in a series of reports that present interpretive analyses of the hydrologic data collected in Monroe County since 1984, interprets data from four surface-water monitoring sites in the Irondequoit Creek basin—Irondequoit Creek at Railroad Mills, East Branch Allen Creek at Pittsford, Allen Creek near Rochester, and Irondequoit Creek at Blossom Road. It also interprets data from three sites in the the Genesee River basin—Oatka Creek at Garbutt, Honeoye Creek at Honeoye Falls, and Black Creek at Churchville—as well as the Genesee River at Charlotte Pump Station, and also from a site on Northrup Creek at North Greece. The Northrup Creek site drains a 23.5-square-mile basin in western Monroe County, and provides information on surface-water quality in streams west of the Genesee River and on loads of nutrients delivered to Long Pond, a small eutrophic embayment of Lake Ontario. The report also includes water-level and water-quality data from nine observation wells in Ellison Park, and atmospheric-deposition data from a collection site at Mendon Ponds County Park. Average annual loads of some chemical constituents in atmospheric deposition for 1997–99 differed considerably from those for the long-term period 1984–96. Ammonia and potassium loads for 1997-99 were 144 and 118 percent greater, respectively, than for the previous period. Sodium and ammonia + organic nitrogen loads were 87 and 60 percent greater, respectively. Average annual loads of sulfate and orthophosphate for 1997-99 were 36 and 30 percent lower, respectively, than for the previous period. Loads of all nutrients deposited on the Irondequoit basin from atmospheric sources during 1997–99 greatly exceeded those transported by Irondequoit Creek. The ammonia load deposited on the basin was 139 times the load transported at Blossom Road (the most downstream site); the ammonia + organic nitrogen load was 6.3 times greater, orthophosphate 7.5 times greater, total phosphorus 1.3 times greater and nitrite + nitrate 1.5 times greater. Average yields of dissolved chloride and dissolved sulfate from atmospheric sources were much smaller than those transported by streamflow at Blossom Road.chloride was about 2 percent and sulfate about 8 percent of the amount transported. Trends in concentration of chemical constituents in surface water generally can be attributed to changes in land use, annual and seasonal variations in streamflow, and annual variations in the application of road salt to county highways and roads. Concentrations of several constituents in streams of the Irondequoit Creek basin showed statistically significant (α=0.05) trends from the beginning of their period of record through 1999. The constituent with the greatest number of significant trends was ammonia + organic nitrogen, with downward trends ranging from 4.1 to 5.6 percent per year at Allen Creek, Irondequoit Creek at Blossom Road, and East Branch Allen Creek. Orthophosphate showed an upward trend of 4.1 percent per year at Irondequoit Creek at Railroad Mills (the most upstream site). Dissolved chloride showed upward trends at Railroad Mills, Allen Creek, and Blossom Road. No trends in volatile suspended solids were noted at any of the four Irondequoit basin sites. Northrup Creek showed significant downward trends in concentrations of ammonia + organic nitrogen (3.3 percent per year), total phosphorus (3.4 percent per year), and orthophosphate (5.5 percent per year), and an upward trend for dissolved sulfate (1.8 percent per year). The Genesee River at Charlotte Pump Station showed downward trends of 6.1 percent per year for ammonia + organic nitrogen and 0.1 percent per year for chloride, and upward trends of 1.7 percent per year for total phosphorus and 6.6 percent per year for orthophosphate. Mean annual yields (mass per unit area) of most constituents at the Irondequoit Creek basin sites were similar to those noted for the previous report period (1994–96). East Branch Allen Creek showed lower yields of all constituents during 1997–99 than previously, even though runoff during 1997–99 was greater. These lower yields are attributed to the construction of an upstream detention basin on East Branch Allen Creek in 1995. Statistical analysis of long-term (greater than 12 years) streamflow records for unregulated streams in Monroe County indicated that annual mean flows for water years 1997–99 were in the normal range (75th to 25th percentile), although Allen Creek continues to show a significant downward trend in mean monthly streamflow during the 1984–99 water years.

New York↗

USGS2003

Atmospheric deposition of nutrients, pesticides, and mercury in Rocky Mountain National Park, Colorado, 2002

Nutrients, current-use pesticides, and mercury were measured in atmospheric deposition during summer in Rocky Mountain National Park in Colorado to improve understanding of the type and magnitude of atmospheric contaminants being deposited in the park. Two deposition sites were established on the east side of the park: one at an elevation of 2,902 meters near Bear Lake for nutrients and pesticides, and one at an elevation of 3,159 meters in the Loch Vale watershed for mercury. Concentrations of nutrients in summer precipitation at Bear Lake ranged from less than 0.007 to 1.29 mg N/L (milligrams of nitrogen per liter) for ammonium and 0.17 to 4.59 mg N/L for nitrate and were similar to those measured at the Loch Vale National Atmospheric Deposition Network station, where nitrogen concentrations in precipitation are among the highest in the Rocky Mountains. Atrazine, dacthal, and carbaryl were the most frequently detected pesticides at Bear Lake, with carbaryl present at the highest concentrations (0.0079 to 0.0952 ?g/L (micrograms per liter), followed by atrazine (less than 0.0070 to 0.0604 ?g/L), and dacthal (0.0030 to 0.0093 ?g/L). Mercury was detected in weekly bulk deposition samples from Loch Vale in concentrations ranging from 2.6 to 36.2 ng/L (nanograms per liter). Concentrations in summer precipitation were combined with snowpack data from a separate study to estimate annual deposition rates of these contaminants in 2002. Annual bulk nitrogen deposition in 2002 was 2.28 kg N/ha (kilograms of nitrogen per hectare) at Bear Lake and 3.35 kg N/ha at Loch Vale. Comparison of wet and bulk deposition indicated that dry deposition may account for as much as 28 percent of annual nitrogen deposition, most of which was deposited during the summer months. Annual deposition rates for three pesticides were estimated as 45.8 mg/ha (milligrams per hectare) of atrazine, 14.2 mg/ha of dacthal, and 54.8 mg/ha of carbaryl. Because of much higher pesticide concentrations in summer precipitation than in winter snow, between 80 to 90 percent of the annual pesticide deposition occurs during summer. Mercury deposition to Loch Vale was estimated at 7.1 ?g/m2 (micrograms per square meter) of which nearly 70 percent of the annual mercury deposition occurred during summer. Despite the fact that most precipitation at high-elevations falls during winter, these results emphasize the importance of monitoring precipitation chemistry during summer to improve estimates of contaminant deposition to high-elevation ecosystems in Rocky Mountain National Park. Air-parcel back trajectories were calculated using an atmospheric transport model to identify potential source regions for contaminants reaching the park. The results indicate that during the winter, the most likely source of contami-nants is from areas northwest of the park, but during summer, contaminants are most likely coming from sources to the southwest and east.

Colorado↗

USGS1999

Evaluation of water quality and bulk atmospheric deposition in the Guanella Pass area, Clear Creek and Park Counties, Colorado, water year 1995

A study of water quality and bulk atmospheric deposition in the Guanella Pass area during water year 1995 (October 1994 to September 1995) has provided information to characterize conditions in the South Clear Creek and Geneva Creek Basins about 40 miles west of Denver, Colorado, prior to a possible roadreconstruction project. Analytical results of water samples collected from streams, ground water, and lakes and reservoirs indicate that water in the study area generally contained small concentrations of dissolved solids (low-flow stream sample median, 43 milligrams per liter; ground-water median, 104 milligrams per liter) and suspended sediment (high-flow stream sample median, 115 milligrams per liter). Nutrient, trace-element, and organic-carbon concentrations also were small. Acidic pH and large trace-element concentrations were associated with areas affected by natural acid-sulfate weathering or mining. Increases in particulate nutrients, total recoverable trace elements, and suspended sediment were related to seasonal snowmelt and thunderstorms. Benthic macroinvertebrate and periphyton (algae) samples collected from selected sites in August 1995 indicated large variability in characteristics among sites. Macroinvertebrate density ranged from 6.5 to 1,300 organisms per square meter, and periphyton biovolume ranged from 0.023 to 4,700 x 10 6 cubic microns per square centimeter. The discharge of road runoff from any single drainage feature (ditch or culvert) was small compared to streamflows. Analytical results from samples of road runoff indicated a large range in specific conductance, pH in a neutral range, large values of turbidity, and calcium bicarbonate type water. Sodium or magnesium and chloride, however, were predominant in some samples and were probably related to applications of sodium and magnesium chloride to the roads. Although dissolved nutrients and trace elements were detected in samples of road runoff, particulate forms had the largest concentrations. Suspended-sediment concentrations in road runoff were large, and the sediment was primarily fine grained. Large concentrations of dissolved and total recoverable nutrients, total recoverable trace elements, total organic carbon, and suspended sediment in road runoff could cause increased concentrations in streams, lakes, and reservoirs. Ground-water concentrations of chloride, nitrite plus nitrate, and dissolved iron and manganese·could increase if the large concentrations present in road runoff infiltrate shallow aquifers. Bulk atmospheric deposition was collected at three sites with a paved road surface, five sites with a gravel or dirt surface, and five sites with collectors at least 500 feet away from a road. The median bulk -atmospheric-deposition rate for gravel (or dirt) roads was 106 times the median rate at a reference site (located at least 500 feet away from a road) and 39 times the median rate at a typical paved road site. If a stream, lake, or reservoir is located near the road, bulk-atmospheric- deposition products may settle directly onto open water or be washed in by surface runoff. Because the predominant road-runoff trace-element phase is particulate, potential toxic effects on receiving water may be minimal when compared to aquatic-life standards and regulations in the State of Colorado, which are primarily based on dissolved concentrations. U.S. Environmental Protection Agency primary maximum contaminant levels for drinking water were exceeded for dissolved uranium (proposed) in one ground-water sample.

Colorado↗

USGS2022

Impacts of ocean-atmosphere teleconnection patterns on the south-central United States

Recent research has linked the climate variability associated with ocean-atmosphere teleconnections to impacts rippling throughout environmental, economic, and social systems. This research reviews recent literature through 2021 in which we identify linkages among the major modes of climate variability, in the form of ocean-atmosphere teleconnections, and the impacts to temperature and precipitation of the South-Central United States (SCUSA), consisting of Arkansas, Louisiana, New Mexico, Oklahoma, and Texas. The SCUSA is an important areal focus for this analysis because it straddles the ecotone between humid and arid climates in the United States and has a growing population, diverse ecosystems, robust agricultural and other economic sectors including the potential for substantial wind and solar energy generation. Whereas a need exists to understand atmospheric variability due to the cascading impacts through ecological and social systems, our understanding is complicated by the positioning of the SCUSA between subtropical and extratropical circulation features and the influence of the Pacific and Atlantic Oceans, and the adjacent Gulf of Mexico. The Southern Oscillation (SO), Pacific-North American (PNA) pattern, North Atlantic Oscillation (NAO) and the related Arctic Oscillation (AO), Atlantic Multidecadal Oscillation/Atlantic Multidecadal Variability (AMO/AMV), and Pacific Decadal Oscillation/Pacific Decadal Variability (PDO/PDV) have been shown to be important modulators of temperature and precipitation variables at the monthly, seasonal, and interannual scales, and the intraseasonal Madden-Julian Oscillation (MJO) in the SCUSA. By reviewing these teleconnection impacts in the region alongside updated seasonal correlation maps, this research provides more accessible and comparable results for interdisciplinary use on climate impacts beyond the atmospheric-environmental sciences.

Arkansas, Louisiana, New Mexico, Oklahoma, Texas↗

USGS2013

Atmospheric deposition and critical loads for nitrogen and metals in Arctic Alaska: Review and current status

To protect important resources under their bureau’s purview, the United States National Park Service’s (NPS) Arctic Network (ARCN) has developed a series of “vital signs” that are to be periodically monitored. One of these vital signs focuses on wet and dry deposition of atmospheric chemicals and further, the establishment of critical load (CL) values (thresholds for ecological effects based on cumulative depositional loadings) for nitrogen (N), sulfur, and metals. As part of the ARCN terrestrial monitoring programs, samples of the feather moss Hylocomium splendens are being col- lected and analyzed as a cost-effective means to monitor atmospheric pollutant deposition in this region. Ultimately, moss data combined with refined CL values might be used to help guide future regulation of atmospheric contaminant sources potentially impacting Arctic Alaska. But first, additional long-term studies are needed to determine patterns of contaminant deposition as measured by moss biomonitors and to quantify ecosystem responses at particular loadings/ ranges of contaminants within Arctic Alaska. Herein we briefly summarize 1) current regulatory guidance related to CL values 2) derivation of CL models for N and metals, 3) use of mosses as biomonitors of atmospheric deposition and loadings, 4) preliminary analysis of vulnerabilities and risks associated with CL estimates for N, 5) preliminary analysis of existing data for characterization of CL values for N for interior Alaska and 6) implications for managers and future research needs.

Alaska↗

USGS1998

Ground-water age and atmospheric tracers: Simulation studies and analysis of field data from the Mirror Lake site, New Hampshire

The use of environmental tracers in characterization of ground-water systems is investigated through mathematical modeling of ground-water age and atmospheric tracer transport, and by a field study at the Mirror Lake site, New Hampshire. Theory is presented for modeling ground-water age using the advective-dispersive transport equation. The transport equation includes a zero-order source of unit strength, corresponding to the rate of aging, and can accommodate matrix diffusion and other exchange processes. The effect of temperature fluctuations and layered soils on transport of atmospheric gases to the water table is investigated using a one-dimensional numerical model of chlorofluorocarbon (CFC-11) transport. The nonlinear relation between temperature and Henry's Law coefficient (reflecting air/water phase partitioning) can cause the apparent recharge temperature to be elevated above the annual mean temperature where the water table is shallow. In addition, fine-grained soils can isolate the air phase in the unsaturated zone from the atmosphere. At the USGS' Mirror Lake, New Hampshire fractured-rock research site CFC concentrations near the water table are depleted where dissolved oxygen is low. CFC-11 and CFC-113 are completely absent under anaerobic conditions, while CFC-12 is as low as one-third of modern concentrations. Anaerobic biodegradation apparently consumes CFC's near the water table at this site. One area of active degradation appears to be associated with streamflow loss to ground water. Soil gas concentrations are generally close to atmospheric levels, although some spatial correlation is observed between depleted concentrations of CFC-11 and CFC-113 in soil gas and water-table samples. Results of unsaturated-zone monitoring indicate that recharge occurs throughout the year in the watershed, even during summer evapotranspiration periods, and that seasonal temperature fluctuations occur as much as 5 meters below land surface. Application of ground-water age and CFC-11 transport models to the large-scale ground-water system at Mirror Lake illustrates the similarities between age and chemical transport. Generally, bedrock porosities required to match observed apparent ages from CFC concentrations are high relative to porosities measured on cores. Although matrix diffusion has no effect on steady-state age, it can significantly reduce CFC concentrations in fractured rock in which the effective porosity is low.

New Hampshire↗

USGS2014

A Great Lakes atmospheric mercury monitoring network: evaluation and design

As many as 51 mercury (Hg) wet-deposition-monitoring sites from 4 networks were operated in 8 USA states and Ontario, Canada in the North American Great Lakes Region from 1996 to 2010. By 2013, 20 of those sites were no longer in operation and approximately half the geographic area of the Region was represented by a single Hg-monitoring site. In response, a Great Lakes Atmospheric Mercury Monitoring (GLAMM) network is needed as a framework for regional collaboration in Hg-deposition monitoring. The purpose of the GLAMM network is to detect changes in regional atmospheric Hg deposition related to changes in Hg emissions. An optimized design for the network was determined to be a minimum of 21 sites in a representative and approximately uniform geographic distribution. A majority of the active and historic Hg-monitoring sites in the Great Lakes Region are part of the National Atmospheric Deposition Program (NADP) Mercury Deposition Network (MDN) in North America and the GLAMM network is planned to be part of the MDN. To determine an optimized network design, active and historic Hg-monitoring sites in the Great Lakes Region were evaluated with a rating system of 21 factors that included characteristics of the monitoring locations and interpretations of Hg data. Monitoring sites were rated according to the number of Hg emissions sources and annual Hg emissions in a geographic polygon centered on each site. Hg-monitoring data from the sites were analyzed for long-term averages in weekly Hg concentrations in precipitation and weekly Hg-wet deposition, and on significant temporal trends in Hg concentrations and Hg deposition. A cluster analysis method was used to group sites with similar variability in their Hg data in order to identify sites that were unique for explaining Hg data variability in the Region. The network design included locations in protected natural areas, urban areas, Great Lakes watersheds, and in proximity to areas with a high density of annual Hg emissions and areas with high average weekly Hg wet deposition. In a statistical analysis, relatively strong, positive correlations in the wet deposition of Hg and sulfate were shown for co-located NADP Hg-monitoring and acid-rain monitoring sites in the Region. This finding indicated that efficiency in regional Hg monitoring can be improved by adding new Hg monitoring to existing NADP acid-rain monitoring sites. Implementation of the GLAMM network design will require Hg-wet-deposition monitoring to be: (a) continued at 12 MDN sites active in 2013 and (b) restarted or added at 9 NADP sites where it is absent in 2013. Ongoing discussions between the states in the Great Lakes Region, the Lake Michigan Air Directors Consortium (a regional planning entity), the NADP, the U.S. Environmental Protection Agency, and the U.S. Geological Survey are needed for coordinating the GLAMM network.

Great Lakes↗

USGS2016

Atmospheric inputs of organic matter to a forested watershed: Variations from storm to storm over the seasons

The objectives of this study were to determine the quantity and chemical composition of precipitation inputs of dissolved organic carbon (DOC) to a forested watershed; and to characterize the associated temporal variability. We sampled most precipitation that occurred from May 2012 through August 2013 at the Susquehanna Shale Hills Critical Zone Observatory (Pennsylvania, USA). Sub-event precipitation samples (159) were collected sequentially during 90 events; covering various types of synoptic meteorological conditions in all climatic seasons. Precipitation DOC concentrations and rates of wet atmospheric DOC deposition were highly variable from storm to storm, ranging from 0.3 to 5.6 mg C L −1 and from 0.5 to 32.8 mg C m −2 h −1 , respectively. Seasonally, storms in spring and summer had higher concentrations of DOC and more optically active organic matter than in winter. Higher DOC concentrations resulted from weather types that favor air advection, where cold frontal systems, on average, delivered more than warm/stationary fronts and northeasters. A mixed modeling statistical approach revealed that factors related to storm properties, emission sources, and to the chemical composition of the atmosphere could explain more than 60% of the storm to storm variability in DOC concentrations. This study provided observations on changes in dissolved organic matter that can be useful in modeling of atmospheric oxidative chemistry, exploring relationships between organics and other elements of precipitation chemistry, and in considering temporal changes in ecosystem nutrient balances and microbial activity.

Atmospheric Environment↗

USGS2018

Spatial and temporal variation in sources of atmospheric nitrogen deposition in the Rocky Mountains using nitrogen isotopes

Variation in source areas and source types of atmospheric nitrogen (N) deposition to high-elevation ecosystems in the Rocky Mountains were evaluated using spatially and temporally distributed N isotope data from atmospheric deposition networks for 1995-2016. This unique dataset links N in wet deposition and snowpack to mobile and stationary emissions sources, and enhances understanding of the impacts of anthropogenic activities and environmental policies that mitigate effects of accelerated N cycling across the Rocky Mountain region. δ 15 N−NO 3 − at 50 U.S. Geological Survey Rocky Mountain Snowpack (Snowpack) sites ranged from −3.3‰ to +6.5‰, with a mean value of +1.4‰. At 15 National Atmospheric Deposition Program (NADP)/National Trends Network wet deposition (NADP Wetfall) sites, summer δ 15 N−NO 3 − is significantly lower ranging from −7.6‰ to −1.3‰ while winter δ 15 N−NO 3 − ranges from −2.6‰ to +5.5‰, with a mean value of +0.7‰ during the cool season. The strong seasonal difference in NADP Wetfall δ 15 N−NO 3 − is due in part to variation in the proportion of N originating from source regions at different times of the year due to seasonal changes in weather patterns. Snowpack NO 3 − and δ 15 N−NO 3 − are significantly related to NADP Wetfall (fall and winter) suggesting that bulk snowpack samples provide a reliable estimate at high elevations. Spatial trends show higher NO 3 − concentrations and δ 15 N−NO 3 − in the Southern Rocky Mountains located near larger anthropogenic N emission sources compared to the Northern Rocky Mountains. NADP Wetfall δ 15 N−NH 4 + ranged from −10‰ to 0‰, with no observed spatial pattern. However, the lowest δ 15 N−NH 4 + (−9‰), and the highest NH 4 + concentration (35 μeq/L) were observed at a Utah site dominated by local agricultural activities, whereas the higher δ 15 N−NH 4 + observed in Colorado and Wyoming are likely due to mixed sources, including fossil fuel combustion and agricultural sources. These findings show spatial and seasonal variation in N isotope data that reflect differences in sources of anthropogenic N deposition to high-elevation ecosystems and have important implications for environmental policy across the Rocky Mountain region.

Rocky Mountains↗

USGS2001

Atmospheric regime of dust and salt through 75,000 years of Taylor Dome ice core: Refinement by measurement of major, minor, and trace metal suites

Measurement of absolute and relative amounts of dust and salt deposited in the polar ice record is central to several fields of study, including nutrient delivery, atmospheric deposition of trace elements, past wind strengths, dust provenance, and other aspects of climate and geochemical history. We present a method intended to give a more accurate picture than has been possible before of the total amounts and relative proportions of the dust and salt deposited by the atmosphere into polar ice. It also permits us to distinguish different compositional types of dust in the ice. The method is based on precise measurement of a suite of several metals whose proportions contrast strongly between dust and salt and vary substantially between dust types. We apply the method to a small suite of ice samples from the Taylor Dome core in coastal West Antarctica. In full glacial times, when total impurities were high and dust dominated over salt, wind strength in the West Antarctic region was apparently high, and extensive sea-ice cover prevented incorporation of salt into the atmospheric load. At the termination of the glacial period, increased salt in the dust-salt mixture indicates that sea ice diminished, but wind strength continued high, and unchanged dust composition indicates unchanged source areas. At about 10,000-11,000 y.B.P., sea-ice cover appears to have briefly returned to glacial conditions, but wind conditions remained in the milder postglacial condition. Soon after, sea ice retreated, and an abrupt change in dust composition indicates changed source materials or terranes. If extended by analysis of more samples from more sites, such information on salt and dust could provide firm constraints on past wind strengths, extent of sea-ice cover, deposition fluxes of salt and dust, and changing continental source areas of dust, for both polar regions of the Earth.

Journal of Geophysical Research D: Atmospheres↗

USGS2003

Multiple oxygen and sulfur isotopic analyses on water-soluble sulfate in bulk atmospheric deposition from the southwestern United States

Sulfate is a major component of bulk atmospheric deposition (including dust, aerosol, fog, and rain). We analyzed sulfur and oxygen isotopic compositions of water-soluble sulfate from 40 sites where year-round dust traps collect bulk atmospheric deposition in the southwestern United States. Average sulfur and oxygen isotopic compositions (δ 34 S and δ 18 O) are 5.8 ± 1.4 (CDT) and 11.2 ± 1.9 (SMOW) (n = 47), respectively. Samples have an oxygen 17 anomaly (Δ 17 O), with an average value of 1.0 ± 0.6‰. Except for a weak positive correlation between δ 18 O and Δ 17 O values (r 2 ≈ 0.4), no correlation exists for δ 18 O versus δ 34 S, Δ 17 O versus δ 34 S, or any of the three isotopic compositions versus elevation of the sample site. Exceptional positive Δ 17 O values (up to 4.23‰) are found in samples from sites in the vicinity of large cities or major highways, and near-zero Δ 17 O values are found in samples close to dry lakes. Comparison of isotopic values of dust trap sulfate and desert varnish sulfate from the region reveals that varnish sulfate has average isotopic values that are ∼4.8‰ lower for δ 18 O, ∼2.1‰ higher for δ 34 S, and ∼0.3‰ lower for Δ 17 O than those of the present-day bulk deposition sulfate. Although other factors could cause the disparity, this observation suggests a possibility that varnish sulfate may have recorded a long-term atmospheric sulfate deposition during the Holocene or Pleistocene, as well as the differences between sulfur and oxygen isotopic compositions of the preindustrial bulk deposition sulfate and those of the industrial era.

Journal of Geophysical Research D: Atmospheres↗

USGS2024

Microplastic and associated black particles from road-tire wear: Implications for radiative effects across the cryosphere and in the atmosphere

The environmental effects of airborne micro- and nano-size plastic particles are poorly understood. Microscopy and chemical analyses of atmospherically deposited particles on snow surfaces at high elevation (2,865–3,690 m) in the Upper Colorado River basin (UCRB; Colorado Rocky Mountains) revealed the presence of black substances intimately associated with microplastic fibers, particles interpreted to have originated as tire matter. Identical and similar particles occur in shredded tires and road-surface samples. The substance responsible for the black color of all tires is carbon black, a graphitic light-absorbing tire additive produced by hydrocarbon combustion that homogeneously permeates the mixture of tire polymers and other additives. Such black tire matter may thus exert radiative effects closely similar to those of black carbon. The presence in snow of many organic compound types common to tires, measured by two-dimensional gas chromatography, suggests that atmospherically deposited black road-tire-wear matter is among the light-absorbing particulates that advance the onset and rate of snow melt in the UCRB. The mass of road-tire-wear particles shed from vehicles may be estimated by multiplying measured amounts of eroded tire-per-distance traveled by vehicular distances. Under a combination of measurements and assumptions about the amounts and radiative properties of atmospheric tire-wear particles, the radiative effects of these particles might add about 10%–30% to those effects from black carbon, an estimate ripe for revision. On regional and global scales, the amounts and effects of emitted and deposited tire-wear matter likely vary by factors of geographic source, transport pathway, and depositional setting.

JGR - Atmospheres↗