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At least 109 records · Page 6Linked to original sources

A geologic history of the north-central Appalachians, part 3. The Alleghany orogeny

The north-central Appalachians occupy a critical position within the 3000+ km-long Appalachian orogen, lying southwest of the boundary between the central and northern Appalachians (CNAB). The one-billion-year-long history of tectonic activity in eastern Laurentia includes the creation and evolution of the Appalachian orogen during the Paleozoic and the Mesozoic transformation of the orogen into a passive margin during Pangea's disassembly. A most important ingredient in the evolution of the orogen was the Alleghany orogeny, which was driven by the convergence and collision between Laurentia (Laurussia) and West Gondwana (Africa). The Alleghany orogeny in the central and southern Appalachians was a decollement tectonism that involved a larger part of eastern Laurentia than had the previous three orogenies. The fundamental element was a very low-angle thrust (decollement) that originated in mid-crustal levels east of the presently-exposed Appalachians and rose westwardly to progressively higher levels in the upper crust and the supra-crustal Paleozoic section. Alleghany deformation was widely developed in the hanging-wall block (allochthon), primarily in the form of thrust faults and fold-and-thrust structures, both of which splayed upward from the basal decollement. The youngest manifestations of the Alleghany orogeny were northeast-trending strike-slip faults and dextral shear zones in the Piedmont. In the north-central Appalachians, the exposed allochthon consists of two parts: the sedimentary externides (Appalachian Plateau and Valley and Ridge provinces) and the crystalline externides (Reading Prong, Blue Ridge belt, and Piedmont province). Long, thrust-cored anticlines predominate in the sedimentary externides. A widespread layer-parallel shortening preceded the folding; it is largely coaxial with the folding but extends considerably farther to the northwest toward the craton. It is hypothesized that the folding developed in reverse order, sequentially from the northwest to the southeast. The crystalline externides are dominated by low-angle thrust faults and upright folds trending east-northeast. The first-order Valley and Ridge folds on the northwest side acted as a buttress and diverted the crystalline externides rocks north-northwestwardly, onto the topographic low area over the Anthracite region. This thrusting of the crystalline externides caused anthracitization of the coals within the Pennsylvanian rocks there. Metamorphism and magmatism were significant events during the earlier phase of the Alleghany orogeny in the southern Appalachians. Whatever magmatism and medium-to high-grade metamorphism developed in the north-central Appalachians are in the covered internides to the southeast. The Alleghany orogeny of the north-central Appalachians occurred during the Early Permian. Erosion of anticlinal crests probably began as the folds grew, with accumulation of this locally-derived sediment in the intervening synclines. A regional alluvial plain coalesced above the partially-eroded externides structures as erosion of the pre-Alleghany highland and the Alleghany hinterland mountains continued to the southeast, spreading sediment to the northwest. This erosion and northwest transport probably persisted, with diminishing intensity, throughout the remainder of the Permian and into the Mesozoic, and changed only with the beginning of crustal extension during the Late Triassic.

American Journal of Science↗

Deducing growth mechanisms for minerals from the shapes of crystal size distributions

Crystal size distributions (CSDs) of natural and synthetic samples are observed to have several distinct and different shapes. We have simulated these CSDs using three simple equations: the Law of Proportionate Effect (LPE), a mass balance equation, and equations for Ostwald ripening. The following crystal growth mechanisms are simulated using these equations and their modifications: (1) continuous nucleation and growth in an open system, during which crystals nucleate at either a constant, decaying, or accelerating nucleation rate, and then grow according to the LPE; (2) surface-controlled growth in an open system, during which crystals grow with an essentially unlimited supply of nutrients according to the LPE; (3) supply-controlled growth in an open system, during which crystals grow with a specified, limited supply of nutrients according to the LPE; (4) supply- or surface-controlled Ostwald ripening in a closed system, during which the relative rate of crystal dissolution and growth is controlled by differences in specific surface area and by diffusion rate; and (5) supply-controlled random ripening in a closed system, during which the rate of crystal dissolution and growth is random with respect to specific surface area. Each of these mechanisms affects the shapes of CSDs. For example, mechanism (1) above with a constant nucleation rate yields asymptotically-shaped CSDs for which the variance of the natural logarithms of the crystal sizes (??2) increases exponentially with the mean of the natural logarithms of the sizes (??). Mechanism (2) yields lognormally-shaped CSDs, for which ??2 increases linearly with ??, whereas mechanisms (3) and (5) do not change the shapes of CSDs, with ??2 remaining constant with increasing ??. During supply-controlled Ostwald ripening (4), initial lognormally-shaped CSDs become more symmetric, with ??2 decreasing with increasing ??. Thus, crystal growth mechanisms often can be deduced by noting trends in ?? versus ??2 of CSDs for a series of related samples.

American Journal of Science↗

Interpretation of ages of arc magmatism, metamorphism, and collisional tectonics in the Taconian orogen of western New England

Available geochronologic ages of volcanic and intrusive rocks of the Taconian arc complex of western New England suggest that the Shelburne Falls and Bronson Hill arcs are not temporally or spatially discrete. Arc activity ranges from earliest Ordovician to Silurian. Activity in the Early and Middle Ordovician coincided with outboard accretionary tectonics and metamorphism that was contemporaneous with the older igneous activity in the Shelburne Falls arc and Bronson Hill arcs. Activity at about 455 to 445 Ma coincides with the collisional stage of the Taconian orogeny that affected Caradocian and older rocks of the Laurentian margin. The 455 to 445 Ma range for the collisional stage of Taconian orogeny in western New England is bracketed by biostratigraphic ages of sedimentary rocks formed on the Laurentian margin and 40Ar/39Ar ages of prograde hornblende formed during Taconian metamorphism. The previous 40Ar/39Ar age estimate of 465 Ma for this collisional and metamorphic event is now known to be too old because this age violates the age of metasedimentary rocks involved in the collisional tectonics. Acceptance of the newer 40Ar/39Ar age estimates of 445 to 450 Ma for Taconian metamorphism during collision establishes the contemporaneity with arc activity in the Bronson Hill arc. Taken together these data support the concept of a long-lived volcanic arc terrane(s) that prograded oceanward. Collision with this time-composite arc terrane(s) in the Caradocian produced the Taconian orogeny rather than the collision of a separate and smaller arc called the "Shelburne Falls arc" by Karabinos and others (1998).

American Journal of Science↗

U-Pb zircon age of metafelsite from the Pinney Hollow formation: Implications for the development of the Vermont Appalachians

The Pinney Hollow Formation of central Vermont is part of a rift-clastic to drift-stage sequence of cover rocks deposited on the Laurentian margin during the development of the Iapetan passive margin in Late Proterozoic to Cambrian time. Conventional U-Pb zircon data indicate an age of 571+ or -5 Ma for a metafelsite from the Pinney Hollow Formation. Geochemical data indicate that the protolith for the metafelsite, now a quartz-albite gneiss or granofels, was rhyolite from a source that was transitional between a within-plate granite and ocean-ridge granite setting and probably came through partially distended continental crust. The transitional setting is consistent with previous data from metabasalts in the Pinney Hollow Formation and supports the idea that the source magma came through continental crust on the rifted margin of the Laurentian craton. The 571+ or -5 Ma age provides the first geochronologic age from the rift-clastic cover sequence in New England and establishes a Late Proterozoic age for the Pinney Hollow Formation. The Late Proterozoic age of the Pinney Hollow confirms the presence of a significant mapped thrust fault between the autochthonous and para-autochthonous rocks of the cover sequence. These findings support the interpretation that the Taconic root zone is located in the hinterland of the Vermont Appalachians on the eastern side of the Green Mountain massif.

Vermont↗

Distinguishing Grenvillian basement from pre-Taconian cover rocks in the Northern Appalachians

Distinguishing Grenvillian basement rocks from pre-Taconian cover sequences in the Appalachians is a first-order problem essential for accurate structural interpretations. The Cavendish Formation in southeastern Vermont presents a classic example of this problem. Doll and others (1961) showed the Cavendish Formation as younger than the Middle Proterozoic Mount Holly Complex but older than the lithologically similar Cambrian Tyson and Hoosac Formations. More recently, the name Cavendish Formation has been informally abandoned, and its metasedimentary units have been mapped as the Tyson and Hoosac Formations of Late Proterozoic to Cambrian age. In a radical departure from these interpretations, Ratcliffe and others (1997) reassigned metasedimentary rocks of the Cavendish Formation to the Mount Holly Complex based on an inferred intrusive relationship between them and a 1.42 Ga tonalite. This new age assignment, if correct, requires a completely new structural interpretation of the region. SHRIMP and Pb evaporation ages of detrital zircons extracted from a quartzite layer from Cavendish Gorge near the proposed intrusive contact with the tonalite constrain the time of deposition of the Cavendish Formation. Grain shapes of the zircons vary from euhedral to nearly spherical. Virtually all the grains have pitted surfaces and show at least some rounding of edges and terminations; grains exhibit oscillatory zoning typical of zircons that crystallized from a magma. Single-grain Pb evaporation analyses of ten zircons and SHRIMP analyses of 15 zircons all yield ages less than 1.42 Ga. Seven of the grains are consistent with derivation from the Bull Hill Gneiss that postdates the Grenville orogenic cycle and predates deposition of the Cavendish Formation. Thus, the metasedimentary units of the Cavendish Formation should not be assigned to the Mount Holly Complex.

northern Appalachians↗

The geology of a part of Acadia and the nature of the Acadian orogeny across Central and Eastern Maine

The zone of Acadian collision between the Medial New England and Composite Avalon terranes is well preserved in Maine. A transect from northwest (Rome) to southeast (Camden) crosses the eastern part of Medial New England comprising the Central Maine basin, Liberty-Orrington thrust sheet, and Fredericton trough, and the western part of Composite Avalon, including the Graham Lake, Clarry Hill, and Clam Cove thrust sheets. U-Pb geochronology of events before, during, and after the Acadian orogeny helps elucidate the nature and distribution of tectonostratigraphic belts in this zone and the timing of some Acadian events in the Northern Appalachians. The Central Maine basin consists of sedimentary and volcanic rocks of Middle Ordovician (∼470 to ∼460 Ma) age overlain with probable conformity by latest Ordovician(?) through earliest Devonian marine rift and flysch sedimentary rocks; these are intruded by weakly to undeformed plutonic rocks of Early and Middle Devonian age (∼399–378 Ma). The Fredericton trough consists of Early Silurian gray pelite and sandstone to earliest Late Silurian calcareous turbidite, deformed and variably metamorphosed prior to the emplacement of Late Silurian (∼422 Ma) and Early to Late Devonian (∼418 to ∼368 Ma) plutons. The Liberty-Orrington thrust sheet consists of Cambrian(?)-Ordovician (>∼474 to ∼469 Ma and younger) clastic sedimentary and volcanic rocks intruded by highly deformed Late Silurian (∼424 to ∼422 Ma) and Devonian (∼418 to ∼389 Ma) plutons, possibly metamorphosed in Late Silurian time (prior to ∼417 Ma), and metamorphosed to amphibolite facies in Early to Middle Devonian time (∼400 to ∼381 Ma). The Graham Lake thrust sheet contains possible Precambrian rocks, Cambrian sedimentary rocks with a volcanic unit dated at ∼503 Ma, and Ordovician rocks with possible Caradocian Old World fossils, metamorphosed and deformed in Silurian time and intruded by mildly to undeformed Late Silurian (∼421 Ma) and Late Devonian (∼371 to ∼368 Ma) plutons. The Clarry Hill thrust sheet consists of poorly studied, highly metamorphosed Cambrian (?) rocks. The Clam Cove thrust sheet contains highly deformed Precambrian limestone, shale, sandstone, and conglomerate, metamorphosed to epidote amphibolite facies and intruded by a mildly deformed pluton dated at ∼421 Ma. Metamorphism, deformation, and voluminous intrusive igneous activity of Silurian age are common to both the most southeastern parts of Medial New England and the thrust sheets of Composite Avalon. In contrast to Medial New England, the thrust sheets of Composite Avalon show only modest effects of Devonian deformation and metamorphism. Regional stratigraphic relations, paleontologic findings, and U-Pb geochronology suggest that the Graham Lake, Clarry Hill, and Clam Cove thrust sheets are far-traveled allochthons that were widely separated from Medial New England in the Silurian. One hundred nine (109) new U-Pb analyses of zircon, monazite, and sphene from 25 samples of metamorphosed, stratified, and intrusive igneous rocks are used to decipher the history of events along the transect. In our view, many of the structures within Medial New England were formed during the closing of the back-arc ocean during the waning stages of the Taconian orogeny. These features include the precursors to the upright folds found in Silurian sedimentary rocks, the west-facing Liberty-Orrington thrust sheet, and the Silurian plutons of Medial New England. Acadian tectonic features, including flysch sedimentation, igneous activity, deformation with nappe emplacement, and metamorphism record the progressive loading of Medial New England by a stack of thrust nappes emplaced in latest Silurian to Middle Devonian time. The Acadian orogeny is a prolonged event, lasting from earliest Late Silurian to the Late Devonian, whose evolution involved: (1) convergence between Medial New England and Composite Avalon along an east-dipping subduction zone from earliest Late Silurian to Early Devonian time; (2) collision and concurrent delamination of lithospheric mantle beneath Medial New England in Early Devonian time resulting in deformation, high-grade metamorphism, and intrusive igneous activity in the most eastern part of Medial New England and the western parts of Composite Avalon; (3) Early to Middle Devonian northwest-migrating penetrative deformations of the Acadian Main stage, including northwest-directed thrusting and recumbent folding followed by tightening of folds possibly produced in the waning stages of the Taconian orogeny and forming folded wave trains of isoclinal folds (∼419 to ∼404 Ma), (4) asymmetrical folds produced by east-west shortening (∼399 to ∼380 Ma); and (5) final westward emplacement of Composite Avalon thrust sheets onto Medial New England in Late Devonian time (∼380 to ∼371 Ma). The present boundary between rocks of Medial New England and Composite Avalon at the surface is the Sennebec Pond fault, a high-angle fault that cuts the Graham Lake and Clarry Hill thrusts, and is intruded by the Mt. Waldo pluton (∼371), one of several Late Devonian plutons (∼371 to ∼367 Ma) that mark the end of the Acadian orogeny in coastal Maine. The thrust sheets of Composite Avalon carried rocks of peri-Gondwanan affinity and with possible Old World fauna many kilometers to the west over Medial New England, thus potentially hiding the original suture at depth under the Gulf of Maine.

Maine↗

Spatial patterns of diagenesis during geothermal circulation in carbonate platforms

Geothermal convection of seawater deep in carbonate platforms could provide the necessary supply of magnesium for dolomitization at temperatures high enough to overcome kinetic limitations. We used reactive-transport simulations to predict the rates and spatial patterns of dolomitization during geothermal convection in a platform that was 40 km across and 2 km thick. In the simulations, porosity and permeability decrease with depth to account for sediment compaction. Dolomitization of a platform consisting of medium grained (∼0.05 mm) sediments occurred in a broad band ranging from ∼2.5 km depth near the margin to ∼1.5 km depth near the platform center. The area of dolomitization is deep enough that temperatures exceed ∼50°C but not so deep that low permeabilities restrict mass transport. Complete dolomitization in the center of this zone is estimated to require at least 60 my. Incorporation of permeability contrasts, permeable beds, and reactive beds focused dolomitization strongly and reduced the estimated time required for dolomitization by as much as 50 percent. Dolomitization created magnesium-depleted, calcium-rich fluids in less than 10 ky, and results support a link between dolomitization and anhydrite precipitation where adequate sulfate is available.

American Journal of Science↗

SHRIMP and Conventional UPb ages of Ordovician granites and tonalites in the central Appalachian Piedmont: Implications for Paleozoic tectonic events

Discordant Cambrian U-Pb ages of questionable reliability for metamor-phosed plutonic rocks in the central Appalachian Piedmont of northern Virginia, Maryland, and the District of Columbia have led to different regional geologic interpretations and controversies. In this study, we use the sensitive high resolution ion microprobe (SHRIMP) for dating 25-m diameter areas on individual zircons from Piedmont granitoids in an effort to resolve previous controversial ages. Cathodoluminescence images of zoning within the zircons are used to select pristine areas of cores and overgrowths for dating and to help interpret the results. For comparison, hand-picked fractions of zircons from most of the samples were also dated by the conventional isotope dilution thermal ionization mass spectrometry (TIMS) U-Pb method. The combined SHRIMP and TIMS results of this study demonstrate that the Dale City Quartz Monzonite, Norbeck Intrusive Suite, Kensington Tonalite, Goldvein pluton, Lake Jackson pluton, Falls Church Intrusive Suite, Occoquan Granite (main batholith and satellite Bull Run Marina pluton), Georgetown Intrusive Suite, Dalecarlia Intrusive Suite, and related granitoids are parts of an extensive Early to Middle Ordovician magmatic arc. Emplacement of these plutons from about 485 to 450 Ma generally was contemporaneous with major regional deformation and metamorphism, called the Taconic orogeny in rocks of the northern Appalachians. The Ordovician ages supersede most of the discordant Cambrian(?) to Neoproterozoic dates that previously suggested a Potomac or Penobscot orogeny in Piedmont rocks of the Potomac Valley, raising questions about the nature and timing of that event. The Devonian Guilford Granite crosscuts all structures, providing a minimum age for these Paleozoic events.

Virginia, Maryland↗

P-T-t paths and differential Alleghanian loading and uplift of the Bronson Hill terrane south central New England

Late Paleozoic U-Pb ages of sphene and 40 Ar/ 39 Ar cooling ages of amphibole and muscovite from rocks of the Bronson Hill terrane in Connecticut and central Massachusetts reflect a late Paleozoic (Alleghanian) overprint on Acadian metamorphic rocks. Prograde Alleghanian sphenes crystallized during the Late Pennsylvanian, and eliminate the possibility that amphibole ages reflect delayed Permian cooling from Devonian Acadian metamorphism. Fourteen new amphibole ages from Connecticut form a north-to-south trend of decreasing age from 294 to 245 Ma, while in Massachusetts four new amphibole ages together with three others from the literature produce a random Carboniferous pattern. Seven new muscovite ages support existing data indicating uniform cooling throughout the Bronson Hill terrane through ∼350°C in the Early Triassic. The rate of Permian cooling defined by amphibole-muscovite pairs increases from ∼4°C/my in northern Connecticut to ∼50°C/my near Long Island Sound. Hinged loading and hinged but delayed exhumation in the southern part of the Bronson Hill terrane (with the hinge in central Connecticut) explain these ages and cooling rates as well as a southerly increasing metamorphic field gradient. One-dimensional thermal modeling indicates that loading of Bronson Hill rocks must have begun by the Late Mississippian. The time of peak Alleghanian metamorphic temperature decreases southward from Early Permian in northern Connecticut to Late Permian to the south. These results demonstrate that the metamorphic effects of the Alleghanian orogeny are not restricted to the Avalon terrane of southeastern New England. On the contrary, the Alleghanian orogeny reset 40 Ar/ 39 Ar mineral ages, recrystallized minerals, partially melted felsic rocks, and transposed fabrics at least as far west as the Bronson Hill terrane in south-central New England.

American Journal of Science↗

Erosion of an ancient mountain range, the Great Smoky Mountains, North Carolina and Tennessee

Analysis of 10 Be and 26 Al in bedrock (n=10), colluvium (n=5 including grain size splits), and alluvial sediments (n=59 including grain size splits), coupled with field observations and GIS analysis, suggest that erosion rates in the Great Smoky Mountains are controlled by subsurface bedrock erosion and diffusive slope processes. The results indicate rapid alluvial transport, minimal alluvial storage, and suggest that most of the cosmogenic nuclide inventory in sediments is accumulated while they are eroding from bedrock and traveling down hill slopes. Spatially homogeneous erosion rates of 25 - 30 mm Ky −1 are calculated throughout the Great Smoky Mountains using measured concentrations of cosmogenic 10 Be and 26 Al in quartz separated from alluvial sediment. 10 Be and 26 Al concentrations in sediments collected from headwater tributaries that have no upstream samples (n=18) are consistent with an average erosion rate of 28 ± 8 mm Ky −1 , similar to that of the outlet rivers (n=16, 24 ± 6 mm Ky −1 ), which carry most of the sediment out of the mountain range. Grain-size-specific analysis of 6 alluvial sediment samples shows higher nuclide concentrations in smaller grain sizes than in larger ones. The difference in concentrations arises from the large elevation distribution of the source of the smaller grains compared with the narrow and relatively low source elevation of the large grains. Large sandstone clasts disaggregate into sand-size grains rapidly during weathering and downslope transport; thus, only clasts from the lower parts of slopes reach the streams. 26 Al/ 10 Be ratios do not suggest significant burial periods for our samples. However, alluvial samples have lower 26 Al/ 10 Be ratios than bedrock and colluvial samples, a trend consistent with a longer integrated cosmic ray exposure history that includes periods of burial during down-slope transport. The results confirm some of the basic ideas embedded in Davis’ geographic cycle model, such as the reduction of relief through slope processes, and of Hack’s dynamic equilibrium model such as the similarity of erosion rates across different lithologies. Comparing cosmogenic nuclide data with other measured and calculated erosion rates for the Appalachians, we conclude that rates of erosion, integrated over varying time periods from decades to a hundred million years are similar, the result of equilibrium between erosion and isostatic uplift in the southern Appalachian Mountains.

Tennessee, North Carolina↗

Spatial and temporal variation of Cenozoic surface elevation in the Great Basin and Sierra Nevada

The surface uplift of mountain belts caused by tectonism plays an important role in determining the long-term climate evolution of the Earth. However, the general lack of information on the paleotopography of mountain belts limits our ability to identify the links and feedbacks between topography, tectonics, and climate change on geologic time-scales. Here, we present a δ 18 O and δD record of authigenic minerals for the northern Great Basin that captures the timing and magnitude of regional surface uplift and subsidence events in the western United States during the Cenozoic. Authigenic calcite, smectite, and chert δ 18 O values suggest the northern Great Basin region experienced ~2km of surface uplift between the middle Eocene and early Oligocene followed by ~1 to 2km of surface subsidence in the southern Great Basin and/or Sierra Nevada since the middle Miocene. These data when combined with previously published work show that the surface uplift history varied in both space and time. Surface uplift migrated from north to south with high elevations in southern British Columbia and northeastern Washington in the middle Eocene and development of surface uplift in north and central Nevada in the Oligocene. This pattern of north to south surface uplift is similar to the timing of magmatism in the western Cordillera, a result that supports tectonic models linking magamtism with removal of mantle lithosphere and/or a subducting slab.

California, Idaho, Nevada, Oregon, Utah↗

U-Pb zircon constraints on the tectonic evolution of southeastern Tibet, Namche Barwa area

The eastern syntaxis of the Himalayas is expressed in the crust as a pronounced southward bend in the orogen. The change in strike of geologic features coincides with the high topography of the Namche Barwa region, the exposure of granulite-grade metamorphic rocks, and a 180-degree bend in the Yalu Tsangpo. We have conducted a geochronologic and geochemical investigation of several suites of granitoids collected from the Namche Barwa massif and subjacent terranes of southeastern Tibet, ranging from cm-scale dikes and sills to larger, outcrop-scale intrusions. U-Pb SHRIMP-RG zircon ages establish at least five magmatic episodes: ∼400 to 500 Ma, ∼120 Ma, 40 to 70 Ma, 18 to 25 Ma, and 3 to 10 Ma . These episodes broadly correlate to spatial patterns in sample localities, as follows: 400 to 500 Ma ages occur in zircon cores collected from within the massif proper; ∼120 Ma granites, related to early Gangdese arc plutonism, are primarily located northeast of Namche Barwa; later (40-70 Ma) Gangdese activity is expressed in granites west of Namche Barwa. 18 to 25 Ma granites occur both along the suture zone west of Gyala Peri, and directly north of Namche Barwa along the area of the Jiali fault zone, and are attributed both to shearing within the Jiali fault zone and to an early Miocene Gangdese Thrust event. Exceptionally young (<10 Ma) zircon ages are clustered near the core of the massif, along the Yalu Tsangpo gorge. Trace-element geochemical data indicates the presence of both fluid-present and fluid absent melts, with a fluid-absent (decompression) melting regime dominating near the core of Namche Barwa.

Tibet↗

Numerical analysis of seawater circulation in carbonate platforms: II. The dynamic interaction between geothermal and brine reflux circulation

Density-driven seawater circulation may occur in carbonate platforms due to geothermal heating and / or reflux of water of elevated salinity. In geothermal circulation lateral contrasts in temperature between seawater and platform groundwaters warmed by the geothermal heat flux result in upward convective flow, with colder seawater drawn into the platform at depth. With reflux circulation, platform-top waters concentrated by evaporation flow downward, displacing less dense underlying groundwaters. We have used a variable density groundwater flow model to examine the pattern, magnitude and interaction of these two different circulation mechanisms, for mesosaline platform-top waters ( 50 ‰ ) and brines concentrated up to saturation with respect to gypsum ( 150 ‰ ) and halite ( 246 ‰ ). Geothermal circulation, most active around the platform margin, becomes restricted and eventually shut-off by reflux of brines from the platform interior towards the margin. The persistence of geothermal circulation is dependent on the rate of brine reflux, which is proportional to the concentration of platform-top brines and also critically dependent on the magnitude and distribution of permeability. Low permeability evaporites can severely restrict reflux whereas high permeability units in hydraulic continuity enhance brine transport. Reduction in permeability with depth and anisotropy of permeability (kv < < kh) focuses flow laterally in the shallow subsurface (<1 km), resulting in a horizontally elongated brine plume. Aquifer porosity and dispersivity are relatively minor controls on reflux. Platform brines can entrain surficial seawater when brine generating conditions cease but the platform-top remains submerged, a variant of reflux we term "latent reflux". Brines concentrated up to gypsum saturation have relatively long residence times of at least 100 times the duration of the reflux event. They thus represent a long-term control on post-reflux groundwater circulation, and consequently on the rates and spatial patterns of shallow burial diagenesis, such as dolomitization.

American Journal of Science↗

Dating Plio-Pleistocene glacial sediments using the cosmic-ray-produced radionuclides 10Be and 26Al

We use the cosmic-ray-produced radionuclides 26 Al and 10 Be to date Plio-Pleistocene glacial sediment sequences. These two nuclides are produced in quartz at a fixed ratio, but have different decay constants. If a sample is exposed at the surface for a time and then buried by overburden and thus removed from the cosmic-ray flux, the 26 Al/ 10 Be ratio is related to the duration of burial. We first attempted to date pre-Wisconsinan tills by measuring 26 Al and 10 Be in fluvial sediments beneath them and applying the method of “burial dating,” which previous authors have used to date river sediment carried into caves. This method, however, requires simplifying assumptions about the 26 Al and 10 Be concentrations in the sediment at the time of burial. We show that these assumptions are not valid for river sediment in glaciated regions. 26 Al and 10 Be analyses of such sediment do not provide accurate ages for these tills, although they do yield limiting ages in some cases. We overcome this difficulty by instead measuring 26 Al and 10 Be in quartz from paleosols that are buried by tills. We use a more general mathematical approach to determine the initial nuclide concentrations in the paleosol at the time it was buried, as well as the duration of burial. This technique provides a widely applicable improvement on other means of dating Plio-Pleistocene terrestrial glacial sediments, as well as a framework for applying cosmogenic-nuclide dating techniques in complicated stratigraphic settings. We apply it to pre-Wisconsinan glacial sediment sequences in southwest Minnesota and eastern South Dakota. Pre-Wisconsinan tills underlying the Minnesota River Valley were deposited 0.5 to 1.5 Ma, and tills beneath the Prairie Coteau in eastern South Dakota and adjacent Minnesota were deposited 1 to 2 Ma.

American Journal of Science↗

A universal surface complexation framework for modeling proton binding onto bacterial surfaces in geologic settings

Adsorption onto bacterial cell walls can significantly affect the speciation and mobility of aqueous metal cations in many geologic settings. However, a unified thermodynamic framework for describing bacterial adsorption reactions does not exist. This problem originates from the numerous approaches that have been chosen for modeling bacterial surface protonation reactions. In this study, we compile all currently available potentiometric titration datasets for individual bacterial species, bacterial consortia, and bacterial cell wall components. Using a consistent, four discrete site, non-electrostatic surface complexation model, we determine total functional group site densities for all suitable datasets, and present an averaged set of 'universal' thermodynamic proton binding and site density parameters for modeling bacterial adsorption reactions in geologic systems. Modeling results demonstrate that the total concentrations of proton-active functional group sites for the 36 bacterial species and consortia tested are remarkably similar, averaging 3.2 ?? 1.0 (1??) ?? 10-4 moles/wet gram. Examination of the uncertainties involved in the development of proton-binding modeling parameters suggests that ignoring factors such as bacterial species, ionic strength, temperature, and growth conditions introduces relatively small error compared to the unavoidable uncertainty associated with the determination of cell abundances in realistic geologic systems. Hence, we propose that reasonable estimates of the extent of bacterial cell wall deprotonation can be made using averaged thermodynamic modeling parameters from all of the experiments that are considered in this study, regardless of bacterial species used, ionic strength, temperature, or growth condition of the experiment. The average site densities for the four discrete sites are 1.1 ?? 0.7 ?? 10-4, 9.1 ?? 3.8 ?? 10-5, 5.3 ?? 2.1 ?? 10-5, and 6.6 ?? 3.0 ?? 10-5 moles/wet gram bacteria for the sites with pKa values of 3.1, 4.7, 6.6, and 9.0, respectively. It is our hope that this thermodynamic framework for modeling bacteria-proton binding reactions will also provide the basis for the development of an internally consistent set of bacteria-metal binding constants. 'Universal' constants for bacteria-metal binding reactions can then be used in conjunction with equilibrium constants for other important metal adsorption and complexation reactions to calculate the overall distribution of metals in realistic geologic systems.

American Journal of Science↗

Early chromite mining and agricultural clearance: Opportunities for the investigation of agricultural sediment dynamics in the Eastern Piedmont (USA)

Many flood plains in the Eastern Piedmont (USA) are buried under deposits of sediment resulting from European agricultural clearance. Classic radioisotopic dating techniques cover temporal periods too short (137Cs, 210Pb) or too long (14C) to reliably date sediments deposited during periods of local European activity (1660-1900). Moreover, many potential biomarkers, such as pollen, degrade in oxic flood plain sediments. In the Baltimore, Maryland (USA) region, early chromite mining (1820 - 1880) occurred during periods of rapid agricultural clearance. Use of chromium (Cr) chemostratigraphic profiles in flood plain sediments tied to historical mining activity can provide improved precision in overbank accumulation rates and timing. Sediment cores were collected from the Red Run basin, which is part of the Baltimore Ecosystem Study, an urban Long-Term Ecological Research site. Trace metal chemostratigraphic profiles were measured and peaks in Cr concentration tied to historic mining activity. Dates from Cr chemostratigraphic profiles were combined with 137Cs dating to reconstruct flood plain sedimentation rates. Red Run early sedimentation rates (1820 - 1880) were higher (0.45 - 1.19 cm/yr) than more recent (1880 - 1963) rates (0.08 - 0.46 cm/yr). This indicates that Piedmont flood plain vertical sediment accumulation might have peaked before the peak in agricultural clearance, earlier than assumed by regional models. The Cr chemostratigraphy is applicable to a wider region including much of the Maryland and Pennsylvania (USA) Piedmont.

American Journal of Science↗

An episode of rapid bedrock channel incision during the last glacial cycle, measured with 10Be

We use 10Be to infer when, how fast, and why the Susquehanna River incised through bedrock along the U.S. Atlantic seaboard, one of the world's most prominent and ancient passive margins. Although the rate at which large rivers incise rock is a fundamental control on the development of landscapes, relatively few studies have directly measured how quickly such incision occurs either in tectonically active environments or along passive margins. Exposure ages of fluvially carve d, bedrock strath terraces, preserved along the lower Susquehanna River, demonstrate that even along a passive margin, large rivers are capable of incising through rock for short periods of time at rates approaching those recorded in tectonically active regions, such as the Himalayas. Over eighty samples, collected along and between three prominent levels of strath terraces within Holtwood Gorge, indicate that the Susquehanna River incised more than 10 meters into the Appalachian Piedmont during the last glacial cycle. Beginning ???36 ka, incision rates increased dramatically, and remained elevated until ???14 ka. The northern half of the Susquehanna basin was glaciated during the late Wisconsinan; however, similar rates and timing of incision occurred in the unglaciated Potomac River basin immediately to the south. The concurrence of incision periods on both rivers suggests that glaciation and associated meltwater were not the primary drivers of incision. Instead, it appears that changing climatic conditions during the late Pleistocene promoted an increase in the frequency and magnitude of flood events capable of exceeding thresholds for rock detachment and bedrock erosion, thus enabling a short-lived episode of rapid incision into rock. Although this study has constraine d the timing and rate of bedrock incision along the largest river draining the Atlantic passive margin, the dates alone cannot explain fully why, or by what processes, this incision occurred. However, cosmogenic dating offers compelling evidence that episodes of rapid incision into bedrock are tied to glacial cycles and changes in global climate. These results, and the methods we employ, provide valuable insights into the nature of bedrock channel incision, not only along the Susquehanna River and passive margins, but also across a wide range of settings around the globe. Because river incision into bedrock transmits the effects of changing climate and tectonics through fluvial networks to hillslopes, comprehending when, where, and why rivers incise has important implications for the evolution of landscapes.

American Journal of Science↗