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At least 1,063 records · Page 59Linked to original sources

Hydrogeologic characterization of part of the Lower Floridan aquifer at the South District Wastewater Treatment Plant, Miami-Dade County, Florida

The South District Wastewater Treatment Plant in southeastern Miami-Dade County, Florida, includes a Class I treated wastewater injection well system. The detection of ammonia in monitoring zones above the injection zone in the Lower Floridan aquifer has elicited a need to understand the nature of confinement within the Lower Floridan aquifer as it pertains to the vertical migration of injectate out of the injection zone upward into the Underground Source of Drinking Water in the upper part of the Floridan aquifer system. Geologic and geophysical data, borehole video imagery, and aquifer performance data were used to refine and clarify the geologic and hydrogeologic frameworks of part of the Lower Floridan aquifer at the treatment plant. The data provide evidence for zones of enhanced dissolution permeability, extensive secondary porosity, fractures, karst collapse structures, and faults that could provide vertical cross-formational fluid pathways that transect the Lower Floridan aquifer.

Florida↗

Hydrogeology and water quality of the West Valley Creek Basin, Chester County, Pennsylvania

The West Valley Creek Basin drains 20.9 square miles in the Piedmont Physiographic Province of southeastern Pennsylvania and is partly underlain by carbonate rocks that are highly productive aquifers. The basin is undergoing rapid urbanization that includes changes in land use and increases in demand for public water supply and wastewater disposal. Ground water is the sole source of supply in the basin. West Valley Creek flows southwest in a 1.5-mile-wide valley that is underlain by folded and faulted carbonate rocks and trends east-northeast, parallel to regional geologic structures. The valley is flanked by hills underlain by quartzite and gneiss to the north and by phyllite and schist to the south. Surface water and ground water flow from the hills toward the center of the valley. Ground water in the valley flows west-southwest parallel to the course of the stream. Seepage investigations identified losing reaches in the headwaters area where streams are underlain by carbonate rocks and gaining reaches downstream. Tributaries contribute about 75 percent of streamflow. The ground-water and surface-water divides do not coincide in the carbonate valley. The ground-water divide is about 0.5 miles west of the surface-water divide at the eastern edge of the carbonate valley. Underflow to the east is about 1.1 inches per year. Quarry dewatering operations at the western edge of the valley may act partly as an artificial basin boundary, preventing underflow to the west. Water budgets for 1990, a year of normal precipitation (45.8 inches), and 1991, a year of sub-normal precipitation (41.5 inches), were calculated. Streamflow was 14.61 inches in 1990 and 12.08 inches in 1991. Evapotranspiration was estimated to range from 50 to 60 percent of precipitation. Base flow was about 62 percent of streamflow in both years. Exportation by sewer systems was about 3 inches from the basin and, at times, equaled base flow during the dry autumn of 1991. Recharge was estimated to be 18.5 inches in 1990 and 13.7 inches in 1991. Ground-water quality in the basin reflects differences in lithology and has been affected by human activities. Ground water in the carbonate rocks is naturally hard, has a near neutral pH, and contains more dissolved solids and less dissolved iron, manganese, and radon-222 than ground water in the noncarbonate rocks, which is soft, with moderately acidic to acidic pH. Regional contamination by chloride and nitrate and local contamination by organic compounds and metals was detected. Natural background concentrations are estimated to be about 1 milligram per liter for nitrate as nitrogen and less than 3 milligrams per liter for chloride. Ground water in unsewered areas and agricultural areas of the basin has median concentrations of nitrate that are greater than those in ground water from other areas; septic system effluent and fertilizer are probable sources of elevated nitrate. Water samples from wells in urbanized areas contain greater concentrations of chloride than samples from wells in residential areas; road salt is the probable source of elevated chloride. Organic solvents, especially trichloroethylene, were detected in 30 percent of the wells sampled in the urbanized carbonate valley. Most of the organic solvents and some of the metals in ground water were detected near old industrial sites. Base-flow stream quality of West Valley Creek was determined at 15 sites from monthly sampling for 1 year. Differences in stream quality reflect differences in lithology, land use, and point sources in tributary subbasins and mainstem reaches. The chemical composition of base flow in the mainstem is dominated by ground-water discharge from carbonate rocks. Elevated concentrations of nitrate (greater than 3 milligrams per liter as nitrogen) in base flow were measured in a tributary draining agricultural land and in a tributary draining an unsewered residential area. Elevated concentrations of phosphate (greater than 0.5 milligrams per liter as phosphorus) were measured in a stream that receives treated sewage effluent. Discharge of water containing elevated sulfate (about 250 milligrams per liter) from quarry dewatering operations contributes to die increase in sulfate concentration (of 10 to 40 milligrams per liter) in base flow downstream from the quarry. The chloride load at all stream sites is greater than the load contributed by precipitation and mineral weathering to the basin, indicating anthropogenic sources of chloride throughout the basin. The diversity index of the benthic invertebrate community has increased since 1973 at the longterm biological monitoring site on West Valley Creek, indicating an improvement in stream quality. The improvement probably is related to controls on discharges and banning of pesticides, such as DOT, in the 1970's. Concentrations of dissolved constituents, except for chloride, determined for base flow in the autumn do not appear to have changed since 1971. Application of the seasonal Kendall test for trend indicates that concentrations of chloride in base flow have increased since 1971; this increase may be related to the increase in urbanization in the basin. The benthic community structure at the West Valley Creek site in 1991 indicates slight nutrient enrichment. Lithium was detected in ground water and surface water downgradient from two lithiumprocessing facilities. Until 1991, lithium was discharged into a losing reach of West Valley Creek, thus introducing lithium into the ground-water system. The potential for cross-contamination between the ground-water and surface-water systems is great, as demonstrated by the detection of lithium in ground water and surface water downstream and downgradient from the two lithium-processing facilities. The lithium that was discharged into the creek acts as a conservative tracer in gaining reaches of West Valley Creek, maintaining a mass balance and characteristic isotopic signature. Lithium-7/lithium-6 ratios were greater in streams that are affected by sewage and by lithium-processing discharges and in ground water downgradient from the lithium-processing facilities than natural background lithium isotopic ratios.

Pennsylvania↗

Accounting for temporal variability of streamflow in estimates of travel time

Retention, processing, and transport of solutes and particulates in stream corridors are influenced by the travel time of streamflow through stream channels, which varies dynamically with discharge. The effects of streamflow variability across sites and over time cannot be addressed by time-averaged models if parameters are based solely on the characteristics of mean streamflow. We develop methods to account for the effects of streamflow variability on travel time and compare our estimates to flow-weighted (“effective”) travel time at 100 streams in the southeastern United States. Velocity time series were generated for each stream from multiple-year (median 15.5 years), high-frequency (15 min interval) records of instantaneous streamflow and field measurements of velocity and inverted to produce time series of specific travel time [T/L]. The effective travel times for streams are 60–90% of the specific travel time of mean streamflow because a large fraction of the total streamflow volume is discharged during higher flows with higher velocities. We find that adjusting the specific travel time of mean streamflow at a site by a factor of 0.81 generally accounts for the effect of a skewed streamflow distribution, but at-site estimates of the coefficient of variation of streamflow are necessary to resolve differences in streamflow variability between streams or changes in variability over time. For example, the effective travel time of urban streams is less than the effective travel of forested streams in the southeastern United States as a result of increased streamflow variability in urban streams. Effective travel time accounts for both the variation in velocity with streamflow and the large fraction of streamflow discharged during high flows in most streams and provides time-averaged models with limited capability to account for effects of streamflow variability that otherwise they lack. This capability is needed for continental-scale modeling where streamflow variability is not uniform because of heterogeneous surficial geology, hydro-climatology, and vegetation and for applications where streamflow variability is not stationary as a response to climate change or hydrologic alteration.

Alabama, Georgia, North Carolina, Virginia, South ↗

Spatial and temporal distribution of sinuous ridges in southeastern Terra Sabaea and the northern region of Hellas Planitia, Mars

Sinuous ridges are an important yet understudied component of Mars' hydrologic history. We have produced a map of sinuous ridges, valleys and channels, and tectonic ridges across southeastern Terra Sabaea and into northern Hellas Planitia (10°-45° S, 35°-80° E) using a CTX mosaic. Although we mapped different types of ridges and negative relief features, the focus of this paper are the sinuous ridges. We present here a new dataset of sinuous ridges that includes basic morphometry (e.g., length, width, sinuosity), morphology, and the types of terrains they are located on. We chose our region of interest because it includes surface ages spanning Mars' geologic history, with emphasis on Noachian and Hesperian terrains. The shift from either a warm and wet or a cold and icy environment to our modern cold and dry climate occurred towards the end of the Noachian and into the Hesperian, a critical temporal window to characterize fluvial landforms. Our CTX-based mapping significantly improved the documentation of fluvial landforms within the study region, with over an order of magnitude increase in the number of valley networks and channels, and nearly 1700 sinuous ridges. Sinuous ridges are found in concentrated settings, with the majority (∼80%) located within impact craters and relatively few (∼20%) on the intercrater plains. Fluvial features are prevalent on Early and Middle Noachian-aged terrain but are relatively rare in the Late Noachian, signifying a shift in fluvial activity that likely led to a decrease in channel incision and subsequent inversion of relief. A subset of sinuous ridges—radial ridges in high-elevation, degraded craters— are possible records of ancient proglacial lakes. The youngest sinuous ridges are associated with intracrater alluvial fans in a narrow zone (∼12°S to 30°S and ∼ 62°E to 77°E). These formed in the Late Hesperian into the Amazonian, reflecting a later epoch of punctuated fluvial events driven by pre-existing topography and solar insolation.

Icarus↗

Distribution of fluorine in unaltered silicic volcanic rocks of the western conterminous United States

An investigation of more than 170 samples of glass-rich volcanic rocks of rhyolitic or rhyodacitic composition shows marked regional variations in the fluorine content. The uniformity of the class of rocks was controlled by index of refraction determinations on fused beads and by chemical analyses of about one-seventh of the total number. The fluorine content ranges from 20 to 4,900 ppm. The frequency distribution closely approaches a log-normal one; the median value is 520 ppm, the 90 percentile 1,820 ppm. The mean for 167 samples is 820 ppm. These correspond fairly well with earlier averages for similar types of rocks . The highest values are predominantly from a belt in central Colorado and west-central New Mexico, from the Big Bend region of Texas, and from southeastern Idaho and western Utah and northeastern Nevada. The distribution of the fluorine in these rocks correlates well with the distribution of significant fluorspar deposits and somewhat less well with areas where volcanic rocks are prevalent and ground waters carry large amounts of fluorine .

Economic Geology↗

Characterization of peak streamflows and flood inundation of selected areas in southeastern Texas and southwestern Louisiana from the August and September 2017 flood resulting from Hurricane Harvey

Hurricane Harvey made landfall near Rockport, Texas, on August 25, 2017, as a Category 4 hurricane with wind gusts exceeding 150 miles per hour. As Harvey moved inland, the forward motion of the storm slowed down and produced tremendous rainfall amounts over southeastern Texas, with 8-day rainfall amounts exceeding 60 inches in some locations, which is about 15 inches more than average annual amounts of rainfall for eastern Texas and the Texas coast. Historic flooding occurred in Texas as a result of the widespread, heavy rainfall; wind and flood damages were estimated to be $125 billion, and the storm resulted in at least 68 direct fatalities. In the immediate aftermath of the Harvey-related flood event, the U.S. Geological Survey (USGS) and the Federal Emergency Management Agency initiated a cooperative study to evaluate the magnitude of the flood, determine the probability of occurrence, and map the extent of the flood in Texas. Seventy-four USGS streamflow-gaging stations in Texas with at least 15 years of record and no large data gaps in the period of record had a 2017 annual peak streamflow related to Harvey ranking in the top five of all annual peaks for each given station. New peaks of record streamflow were recorded at 40 of the 74 USGS streamflow-gaging stations. The number of years of peak streamflow record for the 74 analyzed streamflow-gaging stations ranged from 18 to 105, with a mean number of 55 years. The annual exceedance probability estimates for the analyzed streamflow-gaging stations ranged from less than 0.2 to 14.0 percent. USGS field crews surveyed 2,123 high-water marks to obtain water-surface elevations, in feet above the North American Vertical Datum of 1988. In some locations, several water-surface elevations were averaged to obtain 1 water-surface elevation, resulting in 1,258 water-surface elevations. Some of these high-water marks were used, along with peak-stage data from USGS streamflow-gaging stations, to create 19 inundation maps to document the areal extent of the maximum depth of the flooding. Digital datasets of the inundation area, modeling boundary, water-depth rasters, and final map products are available from the USGS data release associated with this report ( https://doi.org/10.5066/F7VH5N3N ).

Arkansas, Louisiana, Texas↗

Chapter 39 The Edwardsburg Formation and related rocks, Windermere Supergroup, central Idaho, USA

In central Idaho, Neoproterozoic stratified rocks are engulfed by the Late Cretaceous Idaho batholith and by Eocene volcanic and plutonic rocks of the Challis event. Studied sections in the Gospel Peaks and Big Creek areas of west-central Idaho are in roof pendants of the Idaho batholith. A drill core section studied from near Challis, east-central Idaho, lies beneath the Challis Volcanic Group and is not exposed at the surface. Metamorphic and deformational overprinting, as well as widespread dismembering by the younger igneous rocks, conceals many primary details. Despite this, these rocks provide important links for regional correlations and have produced critical geochronological data for two Neoproterozoic glacial periods in the North American Cordillera. At the base of the section, the more than 700-m-thick Edwardsburg Formation (Fm.) contains interlayered diamictite and volcanic rocks. There are two diamictite-bearing members in the Edwardsburg Fm. that are closely related in time. Each of the diamictites is associated with intermediate composition tuff or flow rocks and the diamictites are separated by mafic volcanic rocks. SHRIMP U–Pb dating indicates that the lower diamictite is about 685±7 Ma, whereas the upper diamictite is 684±4 Ma. The diamictite units are part of a cycle of rocks from coarse clastic, to fine clastic, to carbonate rocks that, by correlation to better preserved sections, are thought to record an older Cryogenian glacial to interglacial period in the northern US Cordillera. The more than 75-m-thick diamictite of Daugherty Gulch is dated at 664±6 Ma. This unit is preserved only in drill core and the palaeoenvironmental interpretation and local stratigraphic relations are non-unique. Thus, the date for this diamictite may provide a date for a newly recognized glaciogenic horizon or may be a minimum age for the diamictite in the Edwardsburg Fm. The c. 1000-m-thick Moores Lake Fm. is an amphibolite facies diamictite in which glacial features have not been observed. However, it is part of a sedimentary cycle from unsorted siliclastic deposits to mud and carbonate deposits. Using lithostratigraphy and available geochronology, the Moores Lake Fm. is correlated with a younger succession of Cryogenian glaciogenic rocks in southeastern Idaho. Traditional correlations of Neoproterozoic rocks in the Cordillera recognize two levels of Cryogenian diamictites. The Edwardsburg and Moores Lake diamictites along the middle Cordillera fit well into the scenario of two glacial events. Because of the correlations, dates that provide ages for the diamictites in central Idaho (and corroborated in southeastern Idaho, Link & Fanning 2008) could constrain the age of correlated glaciogenic deposits elsewhere in the Cordillera. However, in the absence of dates for the glaciogenic diamictites in Canadian and southern US Cordilleran sections, the correlations are considered possible but uncertain.

Idaho↗

The subsurface geology of the Florida-Hatteras shelf, slope, and inner Blake Plateau

The structure and stratigraphy of the Florida-Hatteras Slope and inner Blake Plateau was studied by means of 4,780 km of single-channel air gun seismic reflection profiles. Control for the seismic stratigraphy is provided by correlating reflecting units and paleontologically dated stratigraphic units identified in offshore wells and dredge hauls. Many Tertiary unconformities exist, and major regional unconformities at the end of the Oligocene and in the late Paleocene are mapped. Reflecting surfaces believed to represent the tops of the Cretaceous, Paleocene, and Oligocene extend throughout the region. Upper Cretaceous (pre-Maastrichtian) rocks on the southeastern side of the Carolina Platform form a large seaward-facing progradational wedge. The Upper Cretaceous rocks in the Southeast Georgia Embayment, are seismically transparent and on the inner Blake Plateau are cut by numerous small faults, perhaps due to compaction. Within the survey area relatively flat-lying Maastrichtian and Paleocene strata show no evidence that a feature similar to the present Florida-Hatteras Slope existed at the beginning of the Tertiary. Late Paleocene erosion, related to the initiation of the Gulf Stream flow, probably developed this regional unconformity. Eocene and Oligocene sediments landward of the present Gulf Stream form a thick sequence of seaward-dipping progradational beds. A seaward progradational wedge of Miocene to Holocene age covers a regionally traceable unconformity, which separates the Oligocene from the Miocene sediments. Under and seaward of the present Gulf Stream, the Eocene and younger sediment supply was much smaller and the buildup is comparatively insignificant. The difference in accumulation rates in the Eocene and younger sediments, landward and seaward of the Gulf Stream, is responsible for the Florida-Hatteras Slope. Tertiary isopach maps suggest that there is a well developed triangular depocenter under the shelf. The edges of the depocenter correspond with magnetic anomalies and it is suggested that the depocenter is related to differential subsidence during the Tertiary across older crustal structures. The Eocene and Oligocene units contain the aquifer onshore, and the aquifer probably remains in these units offshore. With this assumption the potential aquifer has been identified and traced under the shelf and slope.

Florida-Hatteras shelf, slope, and inner Blake Pla↗

Uranium-series dating of fossil corals from marine sediments of southeastern United States Atlantic Coastal Plain

Extensive low-lying marine deposits border the southeastern United States Atlantic Coastal Plain. Some units are fossiliferous and contain corals as isolated fragments in sediments of a detrital character. These corals are subject to alteration processes such that suites of related samples must be examined to determine the suitability of these coral samples for reliable uranium-series dating. With the exception of those from one location, most samples appear to have remained closed systems with respect to the isotopes of uranium and thorium throughout their geologic history. Extraneous 230 Th has been detected in some of the corals due to incorporation of some detrital materials into their skeletons. For these samples, different methods are applied to correct for the initial 230 Th contamination. Continued sampling and analyses have resulted in 55 individual uranium-thorium determinations. The average 230 Th ages of samples from the Norfolk Formation, and from later- and earlier-deposited sediments of the Wando Formation are ∼71,000, 87,000, and 129,000 yr, and they appear to correlate with oxygen isotope substages 5a, 5c, and 5e, respectively. The average 230 Th age of samples from beds of the Rappahannock River, Ponzer, and Ten Mile Hill localities is ∼212,000 yr, and they correlate with oxygen isotope stage 7. The sediment of the Canepatch Formation is ∼460,000, yr old, and it is tentatively correlated with oxygen isotope stage 11. There is general agreement between uranium-series and uranium-trend dates and between the quantitative trends of the amino acid data and uranium-series dates. The amino acid values, however, ure unacceptably high in at least two groups of samples, those from localities near Charleston, South Carolina, and from central Virginia.

Geological Society of America Bulletin↗

USGS analysis of the Australian UNCLOS submission

In November 2004, the Government of Australia made a submission to the Commission on the Limits of the Continental Shelf (CLCS) for 10 extended continental shelf (ECS) regions, utilizing Article-76 of the United Nations Convention on the Law of the Sea (UNCLOS). With information provided in the Australian Executive Summary, the USGS examined the 10 regions of the submission from geological, morphological, and resource perspectives. By their own request, the Australians asked that CLCS take no action on the Australian-Antarctic Territory. The major limitation in this analysis is that no bathymetric soundings or detailed hydrographic profiles were provided in the Australian Executive Summary that might show why the Foot of the Slope (FOS) was chosen or where the 2,500-m contour is located. This represents a major limitation because more than half of the 4,205 boundary points utilize the bathymetric formula line and more than one-third of them utilize the bathymetric constraint line. CLCS decisions on the components of this submission may set a precedent for how ECSs are treated in future submissions. Some of the key decisions will cover (a) how a 'natural prolongation' of a continental margin is determined, particularly if a bathymetric saddle that appears to determine the prolongation is in deep water and is well outside of the 200-nm limit (Exmouth Plateau), (b) defining to what extent that plateaus, rises, caps, banks and spurs that are formed of oceanic crust and from oceanic processes can be considered to be 'natural prolongations' (Kerguelen Plateau), (c) to what degree UNCLOS recognizes reefs and uninhabited micro-islands (specifically, rocks and/or sand shoals) as islands that can have an EEZ (Middleton and Elizabeth Reefs north of Lord Howe Island), and (d) how the Foot of the Slope (FOS) is chosen (Great Australian Bight). The submission contains situations that are relevant to potential future U.S. submissions and are potentially analogous to certain features of the US margins. The Australian margin has significant geological and morphological variety, similar to the US margin and gives a good idea of the complexity of issues related to the U.S. margin. Decisions about basins and ridges in the Lord Howe Rise and Three Kings Ridge regions will likely bear on the status of ridges in the Arctic, such as Lomonosov Ridge. The Naturaliste Plateau and the South Tasman Rise appear to have parallels with the Chukchi Plateau in the Arctic and the Blake Plateau off the southeastern U.S. The ECS on Macquarie Island/Ridge may determine how boundaries along ridges such as the Mariannas are treated.

Open-File Report↗

Shorter contributions to general geology, 1917

Contents: A. Baked shale and slag formed by the burning of coal beds / G.S. Rogers B. The Newington moraine, Maine, New Hampshire, and Massachusetts / F.J. Katz and Arthur Keith C.A comparison of Paleozoic sections in southern New Mexico / N.H. Darton D. Wasatch fossils in so-called Fort Union beds of the Powder River Basin, Wyo., and their bearing on the stratigraphy of the region / C.H. Wegemann E. Geologic history indicated by the fossiliferous deposits of the Wilcox group at Meridian, Miss. / E.W. Berry F.A fossil flora from the Frontier formation of southwestern Wyoming / F.H. Knowlton G. The stratigraphic position and faunal associates of the orbitoid Foraminifera of the genus Orthophragmina from Georgia and Florida / C.W. Cooke G. Orbitoid Foraminifera of the genus Orthophragmina from Georgia and Florida / J.A. Cushman H. The Pliocene history of northern and central Mississippi / E.W. Shaw I. Stratigraphy in northwestern Maine and southeastern New Hampshire / F.J. Katz J. The Flaxville gravel and its relation to other terrace gravels of the northern Great Plains / A.J. Collier K. The Helderberg limestone of central Pennsylvania / J.B. Reeside L. Stratigraphy of the Hanna Basin, Wyo. / C.F. Bowen

Professional Paper↗

Availability of ground water in the northern part, Tenmile and Taunton River basins, southeastern Massachusetts

The northern part of the Tenmile and Taunton River basins occupies an area of about 195 square miles. It includes some of the rapidly growing suburbs of Boston, Attleboro, and Brockton and lies along major highways connecting Boston with Fall River and Providence, Rhode Island. (See location map.) The purpose of this report is to delineate the extent of and to estimate the annual sustained yield and pumpage of the principal aquifers that are suitable for exploration for high-yielding wells to meet the needs of municipal water systems and industry. Lesser aquifers providing water for industrial, commercial, domestic, and some municipal supplies are also outlined. This report is based on geologic mapping, records of about 2,200 wells and test borings, seismic records, and discussion of water problems with municipal and corporate officials, drillers, and consulting engineers. Selected test borings and wells, including most municipal and industrial wells, are located on the map. They indicate areas from which water is pumped, saturated thickness and texture of materials, yield of wells, and areas in which exploratory work has already been done. Additional subsurface data are listed in a separate report (Williams and Willey, 1967).

Massachusetts↗

Selected ground-water quality data for the southern part of the Fort Hall Indian Reservation, southeastern Idaho, July 1989

Concentrations of nitrogen compounds were analyzed in groundwater in the southern part of the Fort Hall Indian Reservation, Idaho. The study area included that part of the reservation southeast of American Falls Reservoir and north of the Owl Canal. The scope of the study was limited to inventorying 56 wells and making onsite determinations of depth to water, specific conductance, pH, water temperature, and concentrations of total alkalinity, dissolved chloride, and dissolved nitrite plus nitrate as nitrogen. When onsite nitrite plus nitrate concentrations exceeded about 4 mg/L nitrogen, groundwater samples were collected for nitrite plus nitrate as nitrogen ammonia, and ammonia plus organic nitrogen as nitrogen analyes at the U.S. Geological Survey National Water Quality Laboratory. Selected well-inventory and water-quality data for the 56 groundwater samples collected in July 1989, and a statistical summary of selected water quality data are also presented. (USGS)

Idaho↗

Determining CO 2 storage potential during miscible CO 2 enhanced oil recovery: Noble gas and stable isotope tracers

Rising atmospheric carbon dioxide (CO 2 ) concentrations are fueling anthropogenic climate change. Geologic sequestration of anthropogenic CO 2 in depleted oil reservoirs is one option for reducing CO 2 emissions to the atmosphere while enhancing oil recovery. In order to evaluate the feasibility of using enhanced oil recovery (EOR) sites in the United States for permanent CO 2 storage, an active multi-stage miscible CO 2 flooding project in the Permian Basin (North Ward Estes Field, near Wickett, Texas) was investigated. In addition, two major natural CO 2 reservoirs in the southeastern Paradox Basin (McElmo Dome and Doe Canyon) were also investigated as they provide CO 2 for EOR operations in the Permian Basin. Produced gas and water were collected from three different CO 2 flooding phases (with different start dates) within the North Ward Estes Field to evaluate possible CO 2 storage mechanisms and amounts of total CO 2 retention. McElmo Dome and Doe Canyon were sampled for produced gas to determine the noble gas and stable isotope signature of the original injected EOR gas and to confirm the source of this naturally-occurring CO 2 . As expected, the natural CO 2 produced from McElmo Dome and Doe Canyon is a mix of mantle and crustal sources. When comparing CO 2 injection and production rates for the CO 2 floods in the North Ward Estes Field, it appears that CO 2 retention in the reservoir decreased over the course of the three injections, retaining 39%, 49% and 61% of the injected CO 2 for the 2008, 2010, and 2013 projects, respectively, characteristic of maturing CO 2 miscible flood projects. Noble gas isotopic composition of the injected and produced gas for the flood projects suggest no active fractionation, while δ 13 C CO 2 values suggest no active CO 2 dissolution into formation water, or mineralization. CO 2 volumes capable of dissolving in residual formation fluids were also estimated along with the potential to store pure-phase supercritical CO 2 . Using a combination of dissolution trapping and residual trapping, both volumes of CO 2 currently retained in the 2008 and 2013 projects could be justified, suggesting no major leakage is occurring. These subsurface reservoirs, jointly considered, have the capacity to store up to 9 years of CO 2 emissions from an average US powerplant.

International Journal of Greenhouse Gas Control↗

Toxicity of Sodium Bicarbonate to Fish from Coal-Bed Natural Gas Production in the Tongue and Powder River Drainages, Montana and Wyoming

This study evaluates the sensitivity of aquatic life to sodium bicarbonate (NaHCO3), a major constituent of coal-bed natural gas-produced water. Excessive amounts of sodium bicarbonate in the wastewater from coal-bed methane natural gas production released to freshwater streams and rivers may adversely affect the ability of fish to regulate their ion uptake. The collaborative study focuses on the acute and chronic toxicity of sodium bicarbonate on select fish species in the Tongue and Powder River drainages in southeastern Montana and northeastern Wyoming. Sodium bicarbonate is not naturally present in appreciable concentrations within the surface waters of the Tongue and Powder River drainages; however, the coal-bed natural gas wastewater can reach levels over 1,000 milligrams per liter. Large concentrations have been shown to be acutely toxic to native fish (Mount and others, 1997). In 2003, with funding and guidance provided by the U.S. Environmental Protection Agency, the Montana Fish, Wildlife, and Parks and the U.S. Geological Survey initiated a collaborative study on the potential effects of coal-bed natural gas wastewater on aquatic life. A major goal of the study is to provide information to the State of Montana Water Quality Program needed to develop an aquatic life standard for sodium bicarbonate. The standard would allow the State, if necessary, to establish targets for sodium bicarbonate load reductions.

Fact Sheet↗

Approximate inland extent of saltwater intrusion at the base of the Biscayne aquifer, Miami-Dade County, Florida, 2022

Miami-Dade County is part of a densely populated urban corridor in southeastern Florida. The Biscayne aquifer serves as Miami-Dade County’s primary drinking water source and is characterized by highly permeable karstic limestone and carbonate sand. The aquifer’s coastal location and permeable nature make it susceptible to saltwater intrusion. Monitoring the current inland extent and the rate of movement of the saltwater front in the aquifer can inform management strategies for conserving the long-term sustainability of the county’s water supply. In the 1950s, the U.S. Geological Survey published a map of the inland extent of saltwater intrusion in the Biscayne aquifer and has continued to update this map to monitor changes over time, with the most recent update published in 2018. An updated map has been created showing the approximate inland extent of saltwater intrusion in the Biscayne aquifer in eastern Miami-Dade County in 2022, with the 2018 extent shown for comparison. The inland extent of saltwater intrusion was mapped through the interpretation of borehole electromagnetic induction logs and measurements of chloride and specific conductance in groundwater samples. The location of the saltwater interface at the base of the Biscayne aquifer was represented by the 1,000-milligram-per-liter isochlor. This report describes changes in the location of the saltwater interface from 2018 to 2022. By 2022, the saltwater interface had moved farther inland in both the northern and southern parts of the county, advancing by as much as 0.3 kilometer in the north and up to 0.8 kilometer in the Model Land Area to the south. However, it remained relatively unchanged from its 2018 position in the east-central part of the county.

Florida↗

Swatara Creek basin of southeastern Pennsylvania: An evaluation of its hydrologic system

Local concentrations of population in the Swatara Creek basin of Pennsylvania find it necessary to store, transport, and treat water because local supplies are either deficient or have been contaminated by disposal of wastes in upstream areas. Water in the basin is available for the deficient areas and for dilution of the coal-mine drainage in the northern parts and the sewage wastes in the southern parts. Swatara Creek drains 576 square miles just east of Harrisburg, Pa., and is the largest tributary to the Susquehanna River from the north side below Harrisburg. It rises in the southern Pocono Mountains and flows southwestward across the Lebanon Plateau. On an average day Swatara Creek discharges more than 630 million gallons into the Susquehanna River at Middletown, Pa. In a year this amounts to about 23 inches of water over the entire basin and is the residual from an average annual precipitation of 45.5 inches. During an average year the flow in Swatara Creek from the upper third of the basin above Harper Tavern is always greater than 1,300 mgd (million gallons per day) for at least 15 days and is always greater than 25 mgd for at least 350 days. The daily streamflow from the basin averages 1.1 mgd per sq mi, but yields from different areas range from 0.97 to 1.22 mgd per sq mi. These variations are caused chiefly by differences in precipitation and land cover. The area of lowest yield is in the valleys west of Tremont, and the highest yields are in the Upper and Lower Little Swatara Creek subbasins. At high and medium stages the chemical character of the water in the streams is suitable for public and private supplies. At lower stages, defending on the areas and the amounts of contamination by coal-mine drainage and sewage pollution, the natural flow may require some treatment. At low stages the chemical characteristics of the natural flow not affected by man is almost identical with that of the ground water in the area drained by the stream. In general, the total dissolved solids range from about 25 to 400 parts per million and the hardness is as much as about 300 parts per million. The ground-water increment to the base flow of Swatara Creek averages about 240 mgd, or about 8.8 inches annually, for the basin. Generally, ground-water supplies in amounts of less than 0.5 mgd can be developed south of Blue Mountain. Supplies of several million gallons per day have been developed for industrial use from the permeable limestones in the south-central part of the basin. More intensive investigation in other parts of the basin would indicate areas where supplies of more than 0.5 mgd could be developed from properly spaced wells. The chemical character of water from wells depends largely on the host rock. In highly soluble rocks water contains large amount of dissolved solids; in more resistant rocks concentrations are lower. The chemical character of unpolluted ground water generally reflects the composition of the more readily soluble minerals in the local geologic environment. Areas contaminated by septic- tank effluent may have above normal amounts of nitrate and detergent products. Except where polluted, most ground water is suitable for public and industrial uses without extensive treatment. Sites for storage of surface water exist in the part of the basin lying in the valley and ridge area. As much as 30 to 40 percent of the annual flow could be impounded for release as low-flow augmentation for dilution of mine drainage and other wastes in the basin. Low sediment yields of supplying drainage areas would ensure a long life expectancy of reservoirs at these sites. Overbank flooding of the main stem of the Swatara Creek and its tributaries has occurred many times in the past. However, it has not been a hazard because urban development has not encroached on the flood plain. An inundation map of the August 1933 flood provides a basis that urban planners may use to avoid future damage. As water in the Swatara Creek moves downstream to the Susquehanna River, the flow is influenced consecutively by a large annual rainfall on the northern valley and ridge area, the wastes of surface and subsurface coal-mining activities, and less annual rainfall on the part of the basin lying in the Lebanon Plateau area; the flow is supplemented and further influenced by many tributaries and by the industrial and domestic wastes that are carried by these secondary streams. The annual precipitation ranges from 52 inches at the east edge and 49 inches at the west edge of the mountainous part of the basin to about 41 inches at the southwestern part at Middletown. The rainfall generally is adequate during the growing season to mature the crops. The mean annual temperature at Lebanon is about 52°F, and the growing season is about 180 days. In this report the basin has been divided into eight hydrologic zones, leased on runoff, natural use of water, and chemical character of water. Four zones lie in the valley and ridge area, three lie in the Lebanon Plateau area, and one lies in the highland along the southeastern basin boundary. In each of the zones the hydrologic characteristics are virtually the same, but they may be completely different from those in adjacent zones. The boundaries of the zones generally coincide with boundaries between geologic formations, and the areas in each zone include rocks of similar influence on water. Streams in zone 4 at the northeast edge of the plateau have the highest average surface runoff from 1.2 to 1.1 mgd per sq mi whereas those in zone 2 at the northwest edge of the valley and ridge area have the lowest, about 1.0 mgd. Streams in zone 8, along the southeast edge of the basin, have the largest sustained low-flow yield, about 0.26 to 0.19 mgd per sq mi; those in zone 5 overlying the Martinsburg Shale east of Harrisburg have the smallest sustained low-flow yields, 0.03 to 0.01 mgd. Streams in the limestone area of zone 7 have the greatest range in low-flow yields in any one zone from 0.60 to 0 mgd per sq mi. Low-flow yields in zones 1 through 4 range from 0.13 to 0.03 mgd per sq mi. Surface flows from zones 1 and 2 are generally acidic and contain high concentrations of sulfate, iron, and total dissolved solids especially where contaminated with mine wastes. Surface flows from zones 3 and 4 are dilute, slightly alkaline, and suitable for public water supplies. Surface flows from zones 5, 6, and 7 are alkaline and contain moderate concentrations of dissolved solids with waters of highest hardness occurring in zone 7. Surface flows from zone 8 are dilute to moderately mineralized and are relatively high in silica concentration. Nitrate concentrations are high in surf Fee flows below sewage outfalls and in ground water contaminated by septic tank effluent and industrial wastes. Average annual sediment yields of 550 to 650 tons per square mile are characteristic of zones 1 and 2 where strip mining has destroyed the forest cover and coal culm is carried into the streams. From agricultural lands on the Martinsburg Shale in zones 5 and 6, annual sediment yields range from 300 to 350 tons per square mile; but from agricultural lands on the siliceous rocks in zone 8 and zones 3 and 4 in the valley and ridge area, the sediment yield ranges from 200 to 250 tons annually per square mile. Lowest annual sediment yields in the basin are in the forested areas of siliceous rocks in zones 2, 3, 4, and 5, and in the sinkhole topography of the limestones in zone 7 where the yield ranges from 30 to 35 tons and 50 to 60 tons per square mile, respectively. The amount of ground water that can be developed in the basin is dependent on the ability of the underlying rocks to yield water to wells. More than 300 gpm (gallons per minute) can be obtained from wells in alluvial materials in the valley bottoms and in some of the limestones where large solution channels and fractures are penetrated by the wells. From 50 to 300 gpm can be obtained from wells in loosely cemented sandstones and in fractured limestones. From 10 to 50 gpm can be developed from wells in the shales and harder sandstones. The most dense rocks will yield from 1 to 10 gpm from fractures and crevices. Most wells yield water from the upper 350 feet of the formation, for this part contains the most fractures or solution channels. Studies show that the velocity at which a contaminant will move downstream in the basin is related to the discharge of the stream at the time. At a stream discharge of about 400 mgd at Pine Grove, a contaminant in Swatara Creek would require about 40 hours to move from Pine Grove to Middletown. As a result of dispersion and dilution, the maximum concentration of the contaminant at Middletown would be less than 20 percent the concentration at Pine Grove under these conditions. An evaluation of the availability of water in the basin indicates that about I,239 mgd enters as precipitation, 630 mgd leaves as streamflow, 580 mgd is evaporated and transpired, and 56 mgd is diverted for use by man. Not all the diversions for man's use are lost to the basin, as about 27 mgd is returned as sewage for reuse. About one-fourth of the waste water is returned to the ground and the remainder to stream drainageways. Of that diverted by man, 11.6 mgd is used for public supply and 44.4 mgd for industrial and private supplies. Diversions of streamflow furnish 86 percent of the public supply and 27 percent of the industrial supply, and ground-water sources yield the remainder. Municipal and private sewage treatment plants are upgrading the waste water in many places, but no provisions are being made for treatment other than natural dilution and assimilation for the 15 mgd of coal-nine drainage in the northern part of the basin. Technology for economic treatment of mine water is not available at this time, although research in this field is being done. Urbanization eastward from Harrisburg and around Lebanon has increased the population density of the basin. Densities of 500 people per square mile and water use exceeding 2.0 mgd per sq mi can be expected in the future. By the year 2000 the population of the basin may increase 60 percent; and if the per capita rate of use increases 0.5 percent per year the domestic requirements for water will be about two times the present use, or 23 mgd. Similarly, if the present 1:4 ratio of domestic use to industrial use of water continues, at least 89 mgd will be needed for industry in the future. Although an increase to twice the present use of water can be foreseen, or 112 mgd, water for the dilution and assimilation of wastes from treatment systems are not included. Providing water for dilution of wastes from treatment plants has not been a problem, but in the future the amounts needed for this purpose will be greater as the population increases. As water becomes more valuable, treatment of sewage wastes to reduce the biochemical-oxygen-demand load by at least 80 to 90 percent will be necessary to conserve water for more productive uses. As much as 100 mgd may be needed for waste dilution in the basin by year 2000. The present trends in suburban and light industrial development will probably persist in the basin. Problems arising through changes in economic value of water, conflicts in use, and alternatives in development are typical of those confronting the manager of a water-resource system.

Pennsylvania↗

Tertiary landslides, northwestern South Dakota and Southeastern Montana

Landslide blocks of latest Oligocene or earliest Miocene age are preserved at several localities in northwestern South Dakota and southeastern Montana. These tilted blocks contain Late Cretaceous to late Oligocene rocks and are unconformably overlain by nearly horizontal strata of the Arikaree Formation of Miocene age. Undisturbed rocks of late Oligocene age were completely stripped from the area by pre-Arikaree erosion. More than 100 landslide blocks are preserved in the Slim Buttes, Harding County, South Dakota. Some of the blocks are several miles long, 600 feet wide, and contain a thickness of 300 feet or more of relatively unbroken or unjumbled strata which have been displaced downward as much as 250 feet. The strike of the tilted blocks is about N. 60° W., and the dip of the bedding in the blocks at most places is to the southwest and ranges from a few to more than 60°. Most of the rock in the blocks consists of coarse arkosic sandstone, tuffaceous siltstone, claystone, and thick beds of bentonite of the Chadron and Brule formations of Oligocene age. In a few places, small sections of the underlying Paleocene strata are tilted. The blocks formed along northwest-trendingpre-Arikaree valley walls and escarpments. The major joint system of underlying rocks apparently controlled the orientation of the slides, and the dip of these older rocks facilitated the downward and outward movement of the landslide blocks. The Short Pine Hills, Harding County, South Dakota, and the Long Pine Hills, Carter County, Montana, contain numerous landslide blocks that are similar in orientation and geologic setting to those of the Slim Buttes. In contrast, the Finger Buttes of Carter County, Montana, contain landslide blocks that strike about N. 70° E. and dip to the southeast. This lack of parallelism with blocks of nearby areas is apparently due to the lack of a well-developed joint system in underlying rocks of this area. The presence of the complete sequence of Oligocene rocks in the downdropped blocks indicates that before pre-Arikaree erosion the area was covered by 500 feet or more of beds of the Chadron and Brule formations. These landslide blocks show that the time interval represented by the unconformity at the base of the Arikaree Formation was of relatively short duration.

Montana, South Dakota↗