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At least 1,009 records · Page 56Linked to original sources

Early post-fire succession in California chaparral: Changes in diversity, density, cover and biomass

For four consecutive years, following the fires in November 1993, temporal variations in species richness, cover and biomass of component plant groups in early post-fire chaparral succession were monitored on different aspects at the Stunt Ranch Santa Monica Mountains Reserve, southern California. Plant groups were categorized based on growth form, life form, ability to fix nitrogen, geographic origin and regeneration strategies. North-facing slopes exhibited higher species richness, higher species turnover rate over time and faster vegetation recovery in terms of biomass accumulation and return to pre-fire species composition. This was probably due to higher species richness and biomass of nitrogen-fixing species found on north-facing slopes in comparison to south-facing slopes. On both north- and south-facing slopes, annuals had the highest species turnover rate, followed by herbaceous perennials and shrubs. In the first four post-fire years, annual species were the largest floristic group, but herbaceous perennials and shrubs were the major contributors to community biomass. Nitrogen-fixing species and exotics contributed significantly to early post-fire community structure. Although the general trends in post-fire succession are clear in terms of temporal changes in the relative proportions of different plant groups, environmental variation and the nature of plant life histories of component species, especially dominant species, could alter such trends significantly.

Ecological Research↗

The Nitrogen Footprint Tool network: A multi-institution program to reduce nitrogen pollution

Anthropogenic sources of reactive nitrogen have local and global impacts on air and water quality and detrimental effects on human and ecosystem health. This paper uses the nitrogen footprint tool (NFT) to determine the amount of nitrogen (N) released as a result of institutional consumption. The sectors accounted for include food (consumption and upstream production), energy, transportation, fertilizer, research animals, and agricultural research. The NFT is then used for scenario analysis to manage and track reductions, which are driven by the consumption behaviors of both the institution itself and its constituent individuals. In this paper, the first seven completed institution nitrogen footprint results are presented. The institution NFT network aims to develop footprints for many institutions to encourage widespread upper-level management strategies that will create significant reductions in reactive nitrogen released to the environment. Energy use and food purchases are the two largest sectors contributing to institution nitrogen footprints. Ongoing efforts by institutions to reduce greenhouse gas emissions also help to reduce the nitrogen footprint, but the impact of food production on nitrogen pollution has not been directly addressed by the higher-ed sustainability community. The NFT Network found that institutions could reduce their nitrogen footprints by optimizing food purchasing to reduce consumption of animal products and minimize food waste, as well as reducing dependence on fossil fuels for energy.

Sustainability↗

Selection of hyperspectral narrowbands (HNBs) and composition of hyperspectral twoband vegetation indices (HVIs) for biophysical characterization and discrimination of crop types using field reflectance and Hyperion/EO-1 data

The overarching goal of this study was to establish optimal hyperspectral vegetation indices (HVIs) and hyperspectral narrowbands (HNBs) that best characterize, classify, model, and map the world's main agricultural crops. The primary objectives were: (1) crop biophysical modeling through HNBs and HVIs, (2) accuracy assessment of crop type discrimination using Wilks' Lambda through a discriminant model, and (3) meta-analysis to select optimal HNBs and HVIs for applications related to agriculture. The study was conducted using two Earth Observing One (EO-1) Hyperion scenes and other surface hyperspectral data for the eight leading worldwide crops (wheat, corn, rice, barley, soybeans, pulses, cotton, and alfalfa) that occupy ~70% of all cropland areas globally. This study integrated data collected from multiple study areas in various agroecosystems of Africa, the Middle East, Central Asia, and India. Data were collected for the eight crop types in six distinct growth stages. These included (a) field spectroradiometer measurements (350-2500 nm) sampled at 1-nm discrete bandwidths, and (b) field biophysical variables (e.g., biomass, leaf area index) acquired to correspond with spectroradiometer measurements. The eight crops were described and classified using ~20 HNBs. The accuracy of classifying these 8 crops using HNBs was around 95%, which was ~ 25% better than the multi-spectral results possible from Landsat-7's Enhanced Thematic Mapper+ or EO-1's Advanced Land Imager. Further, based on this research and meta-analysis involving over 100 papers, the study established 33 optimal HNBs and an equal number of specific two-band normalized difference HVIs to best model and study specific biophysical and biochemical quantities of major agricultural crops of the world. Redundant bands identified in this study will help overcome the Hughes Phenomenon (or “the curse of high dimensionality”) in hyperspectral data for a particular application (e.g., biophysi- al characterization of crops). The findings of this study will make a significant contribution to future hyperspectral missions such as NASA's HyspIRI.

Africa;Central Asia;Middle East↗

Informing the network: Improving communication with interface communities during wildland fire

An interagency research team studied fire communications that took place during different stages of two wildfires in southern California: one small fire of short duration and one large fire of long duration. This "quick- response" research showed that pre-fire communication planning was particularly effective for smaller fire events and parts of that planning proved invaluable for the large fire event as well. Information seeking by the affected public relied on locally convenient sources during the small fire. During the large fire, widespread evacuations disrupted many of the local informal communication networks. Residents' needs were for "real-time, " place-specific information: precise location, severity, size, and direction of spread of the fires. Fire management agencies must contribute real-time, place-specific fire information when it is most needed by the affected public, as they try to make sense out of the chaos of a wildland fire. Disseminating fire information as broadly as possible through multiple pathways will maximize the probability of the public finding the information they need. ?? Society for Human Ecology.

Human Ecology Review↗

Description and identification of American Black Duck, Mallard, and hybrid wing plumage

We developed a key to identify wings of hybrids between American Black Ducks (Anas rubripes) and Mallards (A. platyrhynchos). Material for analysis included review of historical descriptions dating from the late 1700's, older museum collections in Europe and North America, wings collected from hunters in North America and Great Britain, birds banded in Canada and the United States, and a flock of propagated hybrids. All first filial generation (F1) American Black Duck - Mallard hybrids were identified correctly with the key. A lower proportion of other hybrid cohorts (i.e., backcrosses of F1 to parental forms (P1), and second and third filial generations (F2, F3, etc.) were identified. We successfully identified a larger portion of male than female hybrids for all hybrid progeny cohorts examined except F1. The new key identified 2.37 times more hybrids in the 1977 U.S. Fish and Wildlife Service Parts Collection Survey (annual determination of the species, age, and sex composition of the waterfowl harvest using detached wings contributed by hunters) than were identified by standard techniques. The proportion of American Black Duck - Mallard hybrids to the American Black Duck parental population (the ratio: hybrids/[hybrids + American Black Ducks]) may therefore be closer to 0.132 than 0.056, the historically reported value. The hybrid key is suggested for use from North Carolina north in the Atlantic Flyway and Arkansas and Tennessee north in the Mississippi Flyway (areas where other members of the Mallard group will not confound assessment). We provide suggestions for further research that would assist identification of wings in parts collection surveys and permit estimation of the proportional representation of Mallard genes in the American Black Duck gene pool.

Report↗

EAARL coastal topography-western Florida, post-Hurricane Charley, 2004: seamless (bare earth and submerged.

Project Description These remotely sensed, geographically referenced elevation measurements of lidar-derived seamless (bare-earth and submerged) topography were produced as a collaborative effort between the U.S. Geological Survey (USGS), Coastal and Marine Geology Program (CMGP), St. Petersburg, FL, and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of a portion of the western Florida coastline beachface, acquired post-Hurricane Charley on August 17 and 18, 2004. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website. Selected References Brock, J.C., Wright, C.W., Sallenger, A.H., Krabill, W.B., and Swift, R.N., 2002, Basis and methods of NASA airborne topographic mapper Lidar surveys for coastal studies: Journal of Coastal Research, v. 18, no. 1, p. 1-13. Crane, Michael, Clayton, Tonya, Raabe, Ellen, Stoker, Jason, Handley, Larry, Bawden, Gerald, Morgan, Karen, and Queija, Vivian, 2004, Report of the U.S. Geological Survey Lidar workshop sponsored by the Land Remote Sensing Program and held in St. Petersburg, FL, November 2002: U.S. Geological Survey Open-File Report 2004-1456, 72 p. Nayegandhi, Amar, Brock, J.C., and Wright, C.W., 2009, Small-footprint, waveform-resolving Lidar estimation of submerged and sub-canopy topography in coastal environments: International Journal of Remote Sensing, v. 30, no. 4, p. 861-878. Sallenger, A.H., Wright, C.W., and Lillycrop, Jeff, 2005, Coastal impacts of the 2004 hurricanes measured with airborne Lidar; initial results: Shore and Beach, v. 73, nos. 2-3, p. 10-14. Resources Included Readme.txt File

Data Series↗

Review and development of best practices for toxicity tests with dreissenid mussels

Since their introduction to North America in the 1980s, research to develop effective control tools for invasive mussels ( Dreissena polymorpha and D. rostriformis bugensis ) has been ongoing across various research institutions using a range of testing methods. Inconsistencies in experimental methods and reporting present challenges for comparing data, repeating experiments, and applying results. The Invasive Mussel Collaborative established the Toxicity Testing Work Group (TTWG) in 2019 to identify “best practices” and guide development of a standard framework for dreissenid mussel toxicity testing protocols. We reviewed the literature related to laboratory-based dreissenid mussel toxicity tests and determined the degree to which standard guidelines have been used and their applicability to dreissenid mussel testing. We extracted detailed methodology from 99 studies from the peer-reviewed and gray literature and conducted a separate analysis for studies using presettlement and postsettlement mussels. We identified specific components of methods and approaches that could be refined or standardized for dreissenid mussels. These components included species identification, collection methods, size/age class distinction, maintenance practices, testing criteria, sample size, response measures, reporting parameters, exposure methods, and mortality criteria. We consulted experts in the field of aquatic toxicology and dreissenid mussel biology on our proposed. The final recommendations contained in the present review are based on published standard guidelines, methods reported in the published and gray literature, and the expertise of TTWG members and an external panel. In addition, our review identifies research needs for dreissenid mussel testing including improved methods for early–life stage testing, comparative data on life stages and between dreissenid mussel species, inclusion of a reference toxicant, and additional testing of nontarget species (i.e., other aquatic organisms). Environ Toxicol Chem 2023;42:1649–1666. © 2023 His Majesty the King in Right of Canada. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC. Reproduced with the permission of the Minister of Environment and Climate Change Canada. This article has been contributed to by U.S. Government employees and their work is in the public domain in the USA.

Environmental Toxicology and Chemistry↗

Magnetic monitoring of earth and space

For centuries, navigators of the world’s oceans have been familiar with an effect of Earth’s magnetic field: It imparts a directional preference to the needle of a compass. Although in some settings magnetic orientation remains important, the modern science of geomagnetismhas emerged from its romantic nautical origins and developed into a subject of great depth and diversity. The geomagnetic field is used to explore the dynamics of Earth’s interior and its surrounding space environment, and geomagnetic data are used for geophysical mapping, mineral exploration, risk mitigation, and other practical applications. A global distribution of ground-based magnetic observatories supports those pursuits by providing accurate records of the magnetic-field direction and intensity at fixed locations and over long periods of time. Magnetic observatories were first established in the early 19th century in response to the influence of Alexander von Humboldt and Carl Friedrich Gauss. Since then, magnetic measurement has advanced significantly, progressing from simple visual readings of magnetic survey instruments to include automatic photographic measurement and modern electronic acquisition. To satisfy the needs of the scientific community, observatories are being upgraded to collect data that meet ever more stringent standards, to achieve higher acquisition frequencies, and to disseminate data in real time. To appreciate why data from magnetic observatories can be used for so many purposes, one needs only to recall that the geomagnetic field is a continuum, connecting the different parts of Earth to each other and to nearby space. Beneath our feet and above our heads, electric currents generate magnetic fields that contribute to the totality of the geomagnetic field measured at an observatory on Earth’s surface. The many physical processes that operate in each geophysical domain give rise to a complicated field that exhibits a wide variety of time-dependent behavior. In this article I review the status of the global community of magnetic observatories, show how Earth and space can be monitored for purposes of scientific understanding and practical application, and highlight the role played by magnetic observatories in the history of geomagnetism research.

Physics Today↗

Review and synthesis: Changing permafrost in a warming world and feedbacks to the Earth System

The permafrost component of the cryosphere is changing dramatically, but the permafrost region is not well monitored and the consequences of change are not well understood. Changing permafrost interacts with ecosystems and climate on various spatial and temporal scales. The feedbacks resulting from these interactions range from local impacts on topography, hydrology, and biology to complex influences on global scale biogeochemical cycling. This review contributes to this focus issue by synthesizing its 28 multidisciplinary studies which provide field evidence, remote sensing observations, and modeling results on various scales. We synthesize study results from a diverse range of permafrost landscapes and ecosystems by reporting key observations and modeling outcomes for permafrost thaw dynamics, identifying feedbacks between permafrost and ecosystem processes, and highlighting biogeochemical feedbacks from permafrost thaw. We complete our synthesis by discussing the progress made, stressing remaining challenges and knowledge gaps, and providing an outlook on future needs and research opportunities in the study of permafrost–ecosystem–climate interactions.

Environmental Research Letters↗

Tectonics of the Maryland Piedmont along the Potomac River; insight since 1960 and potential transfer to the Pennsylvania Piedmont

This is a summary of a half century of research in the Mary land Piedmont and how it may or may not have implications for the Piedmont of Pennsylvania. Much of the field mapping and all of the isotopic analyses of rocks and minerals of the Maryland Piedmont have been conducted since the 1960 Field Conference of Pennsylvania Geologists “Some tectonic and structural problems of the Appalachian Piedmont along the Susquehanna River”. The Piedmont rocks of Maryland and Pennsylvania occur in a critical place within the central Appalachian Pennsylvania embayment (Thomas, 1977), which likely contributed to the distribution of lithologies and structures.

Maryl;Pennsylvania↗

Characterizing wave- and current- induced bottom shear stress: U.S. middle Atlantic continental shelf

Waves and currents create bottom shear stress, a force at the seabed that influences sediment texture distribution, micro-topography, habitat, and anthropogenic use. This paper presents a methodology for assessing the magnitude, variability, and driving mechanisms of bottom stress and resultant sediment mobility on regional scales using numerical model output. The analysis was applied to the Middle Atlantic Bight (MAB), off the U.S. East Coast, and identified a tidally-dominated shallow region with relatively high stress southeast of Massachusetts over Nantucket Shoals, where sediment mobility thresholds are exceeded over 50% of the time; a coastal band extending offshore to about 30 m water depth dominated by waves, where mobility occurs more than 20% of the time; and a quiescent low stress region southeast of Long Island, approximately coincident with an area of fine-grained sediments called the “Mud Patch”. The regional high in stress and mobility over Nantucket Shoals supports the hypothesis that fine grain sediment winnowed away in this region maintains the Mud Patch to the southwest. The analysis identified waves as the driving mechanism for stress throughout most of the MAB, excluding Nantucket Shoals and sheltered coastal bays where tides dominate; however, the relative dominance of low-frequency events varied regionally, and increased southward toward Cape Hatteras. The correlation between wave stress and local wind stress was lowest in the central MAB, indicating a relatively high contribution of swell to bottom stress in this area, rather than locally generated waves. Accurate prediction of the wave energy spectrum was critical to produce good estimates of bottom shear stress, which was sensitive to energy in the long period waves.

Continental Shelf Research↗

Understanding the water resources of a mountain-block aquifer: Tucson Mountains, Arizona

Water resources are limited in arid locations such as Tucson Basin. Residential development in the Tucson Mountains to the west of Tucson, Arizona, is limited by groundwater resources. Groundwater samples were collected from fractured bedrock and alluvial aquifers surrounding the Tucson Mountains to assess water quality and recharge history through measurement of stable O, H, and S isotopes; tritium; and 14 C. Most groundwater is a mixture of different ages but is commonly several thousand years old. A few sampling locations indicated a component of water recharged after the above-ground nuclear testing of the mid 1950s, and these sites may represent locations near where the aquifer receives present-day recharge. The Tucson Mountains also host sulfide deposits associated with fractures and replacement zones; these locally contribute to poor-quality groundwater. Projections of future climate predict intensifying drought in southwestern North America. In the study area, a combination of strategies such as rainwater harvesting, exploitation of renewable water, and low groundwater use could be used for sustainable use of the groundwater supply.

Arizona↗

Don Swanson: A field volcanology career worth celebrating

Don Swanson has profoundly influenced generations of volcanologists and has made major contributions to our understanding of both silicic and basaltic volcanic systems. He provides an exceptional example of how a gifted scientist can develop entirely new paradigms related to large-scale problems on the basis of decades of study, as exemplified by his work on the emplacement of flood basalts, monitoring and forecasting volcanic eruptions, the development of lava flows and domes, and the explosive nature of Kīlauea Volcano. Don has maintained exceptional productivity even while playing major leadership and management roles in science, and his research is intrinsically geological and rooted in painstaking fieldwork that is both collaborative and interdisciplinary. This volume recognizes Don’s career accomplishments by emphasizing his careful approach to volcanology and highlighting meticulous field observations as the basis for better understanding how volcanoes work.

Special Papers of the Geological Society of Americ↗

Field volcanology: A tribute to the distinguished career of Don Swanson

Don Swanson has profoundly influenced generations of volcanologists and has made major contributions to our understanding of both silicic and basaltic volcanic systems. He provides an exceptional example of how a gifted scientist can develop entirely new paradigms related to large-scale problems on the basis of decades of study, as exemplified by his work on the emplacement of flood basalts, monitoring and forecasting volcanic eruptions, the development of lava flows and domes, and the explosive nature of Kīlauea Volcano. Don has maintained exceptional productivity even while playing major leadership and management roles in science, and his research is intrinsically geological and rooted in painstaking fieldwork that is both collaborative and interdisciplinary. This volume recognizes Don’s career accomplishments by emphasizing his careful approach to volcanology and highlighting meticulous field observations as the basis for better understanding how volcanoes work.

Special Papers of the Geological Society of Americ↗

Geohydrologic Framework of the Edwards and Trinity Aquifers, South-Central Texas

This five-year USGS project, funded by the National Cooperative Geologic Mapping Program, is using multidisciplinary approaches to reveal the surface and subsurface geologic architecture of two important Texas aquifers: (1) the Edwards aquifer that extends from south of Austin to west of San Antonio and (2) the southern part of the Trinity aquifer in the Texas Hill Country west and south of Austin. The project's principal areas of research include: Geologic Mapping, Geophysical Surveys, Geochronology, Three-dimensional Modeling, and Noble Gas Geochemistry. The Edwards aquifer is one of the most productive carbonate aquifers in the United States. It also has been designated a sole source aquifer by the U.S. Environmental Protection Agency and is the primary source of water for San Antonio, America's eighth largest city. The Trinity aquifer forms the catchment area for the Edwards aquifer and it intercepts some surface flow above the Edwards recharge zone. The Trinity may also contribute to the Edwards water budget by subsurface flow across formation boundaries at considerable depths. Dissolution, karst development, and faulting and fracturing in both aquifers directly control aquifer geometry by compartmentalizing the aquifer and creating unique ground-water flow paths.

Fact Sheet↗

Abstracts for the October 2012 meeting on volcanism in the American Southwest, Flagstaff, Arizona

Though volcanic eruptions are comparatively rare in the American Southwest, the States of Arizona, Colorado, New Mexico, Nevada, and Utah host Holocene volcanic eruption deposits and are vulnerable to future volcanic activity. Compared with other parts of the western United States, comparatively little research has been focused on this area, and eruption probabilities are poorly constrained. Monitoring infrastructure consists of a variety of local seismic networks, and ”backbone“ geodetic networks with little integration. Emergency response planning for volcanic unrest has received little attention by either Federal or State agencies. On October 18–20, 2012, 90 people met at the U.S. Geological Survey campus in Flagstaff, Arizona, providing an opportunity for volcanologists, land managers, and emergency responders to meet, converse, and begin to plan protocols for any future activity. Geologists contributed data on recent findings of eruptive ages, eruption probabilities, and hazards extents (plume heights, ash dispersal). Geophysicists discussed evidence for magma intrusions from seismic, geodetic, and other geophysical techniques. Network operators publicized their recent work and the relevance of their equipment to volcanic regions. Land managers and emergency responders shared their experiences with emergency planning for earthquakes. The meeting was organized out of the recognition that little attention had been paid to planning for or mitigation of volcanic hazards in the American Southwest. Moreover, few geological meetings have hosted a session specifically devoted to this topic. This volume represents one official outcome of the meeting—a collection of abstracts related to talks and poster presentations shared during the first two days of the meeting. In addition, this report includes the meeting agenda as a record of the proceedings. One additional intended outcome will be greater discussion and coordination among emergency responders, geologists, geophysicists, and land managers regarding geologic hazards in the Southwest.

Arizona, Colorado, New Mexico, Nevada, Utah↗

Does resolution of flow field observation influence apparent habitat use and energy expenditure in juvenile coho salmon?

This study investigated how the resolution of observation influences interpretation of how fish, juvenile Coho Salmon ( Oncorhynchus kisutch ), exploit the hydraulic environment in streams. Our objectives were to evaluate how spatial resolution of the flow field observation influenced: (1) the velocities considered to be representative of habitat units; (2) patterns of use of the hydraulic environment by fish; and (3) estimates of energy expenditure. We addressed these objectives using observations within a 1:1 scale physical model of a full-channel log jam in an outdoor experimental stream. Velocities were measured with Acoustic Doppler Velocimetry at a 10 cm grid spacing, whereas fish locations and tailbeat frequencies were documented over time using underwater videogrammetry. Results highlighted that resolution of observation did impact perceived habitat use and energy expenditure, as did the location of measurement within habitat units and the use of averaging to summarize velocities within a habitat unit. In this experiment, the range of velocities and energy expenditure estimates increased with coarsening resolution (grid spacing from 10 to 100 cm), reducing the likelihood of measuring the velocities locally experienced by fish. In addition, the coarser resolutions contributed to fish appearing to select velocities that were higher than what was measured at finer resolutions. These findings indicate the need for careful attention to and communication of resolution of observation in investigating the hydraulic environment and in determining the habitat needs and bioenergetics of aquatic biota.

Water Resources Research↗

The estuarine chemistry and isotope systematics of 234,238U in the Amazon and Fly Rivers

Natural concentrations of 238U and ??234U values were determined in estuarine surface waters and pore waters of the Amazon and Fly (Papua New Guinea) Rivers to investigate U transport phenomena across river-dominated land-sea margins. Discharge from large, tropical rivers is a major source of dissolved and solid materials transported to the oceans, and are important in defining not only oceanic mass budgets, but also terrestrial weathering rates. On the Amazon shelf, salinity-property plots of dissolved organic carbon, pH and total suspended matter revealed two vastly contrasting water masses that were energetically mixed. In this mixing zone, the distribution of uranium was highly non-conservative and exhibited extensive removal from the water column. Uranium removal was most pronounced within a salinity range of 0-16.6, and likely the result of scavenging and flocculation reactions with inorganic (i.e., Fe/Mn oxides) and organic colloids/particles. Removal of uranium may also be closely coupled to exchange and resuspension processes at the sediment/water interface. An inner-shelf pore water profile indicated the following diagenetic processes: extensive (???1 m) zones of Fe(III) - and, to a lesser degree, Mn(IV) - reduction in the absence of significant S(II) concentrations appeared to facilitate the formation of various authigenic minerals (e.g., siderite, rhodocrosite and uraninite). The pore water dissolved 238U profile co-varied closely with Mn(II). Isotopic variations as evidenced in ??234U pore waters values from this site revealed information on the origin and history of particulate uranium. Only after a depth of about 1 m did the ??234U value approach unity (secular equilibrium), denoting a residual lattice bound uranium complex that is likely an upper-drainage basin weathering product. This suggests that the enriched ??234U values represent a riverine surface complexation product that is actively involved in Mn-Fe diagenetic cycles and surface complexation reactions. In the Fly River estuary, 238U appears to exhibit a reasonably conservative distribution as a function of salinity. The absence of observed U removal does not necessarily imply non-reactivity, but instead may record an integration of concurrent U removal and release processes. There is not a linear correlation between ??234U vs. 1/ 238U that would imply simple two component mixing. It is likely that resuspension of bottom sediments, prolonged residence times in the lower reaches of the Fly River, and energetic particle-colloid interactions contribute to the observed estuarine U distribution. The supply of uranium discharged from humid, tropical river systems to the sea appears to be foremost influenced by particle/water interactions that are ultimately governed by the particular physiographic and hydrologic characteristics of an estuary. ?? 2004 Elsevier Ltd. All rights reserved.

Continental Shelf Research↗