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Ground-water and surface-water flow and estimated water budget for Lake Seminole, southwestern Georgia and northwestern Florida

Lake Seminole is a 37,600-acre impoundment formed at the confluence of the Flint and Chattahoochee Rivers along the Georgia?Florida State line. Outflow from Lake Seminole through Jim Woodruff Lock and Dam provides headwater to the Apalachicola River, which is a major supply of freshwater, nutrients, and detritus to ecosystems downstream. These rivers,together with their tributaries, are hydraulically connected to karst limestone units that constitute most of the Upper Floridan aquifer and to a chemically weathered residuum of undifferentiated overburden. The ground-water flow system near Lake Seminole consists of the Upper Floridan aquifer and undifferentiated overburden. The aquifer is confined below by low-permeability sediments of the Lisbon Formation and, generally, is semiconfined above by undifferentiated overburden. Ground-water flow within the Upper Floridan aquifer is unconfined or semiconfined and discharges at discrete points by springflow or diffuse leakage into streams and other surface-water bodies. The high degree of connectivity between the Upper Floridan aquifer and surface-water bodies is limited to the upper Eocene Ocala Limestone and younger units that are in contact with streams in the Lake Seminole area. The impoundment of Lake Seminole inundated natural stream channels and other low-lying areas near streams and raised the water-level altitude of the Upper Floridan aquifer near the lake to nearly that of the lake, about 77 feet. Surface-water inflow from the Chattahoochee and Flint Rivers and Spring Creek and outflow to the Apalachicola River through Jim Woodruff Lock and Dam dominate the water budget for Lake Seminole. About 81 percent of the total water-budget inflow consists of surface water; about 18 percent is ground water, and the remaining 1 percent is lake precipitation. Similarly, lake outflow consists of about 89 percent surface water, as flow to the Apalachicola River through Jim Woodruff Lock and Dam, about 4 percent ground water, and about 2 percent lake evaporation. Measurement error and uncertainty in flux calculations cause a flow imbalance of about 4 percent between inflow and outflow water-budget components. Most of this error can be attributed to errors in estimating ground-water discharge from the lake, which was calculated using a ground-water model calibrated to October 1986 conditions for the entire Apalachicola?Chattahoochee?Flint River Basin and not just the area around Lake Seminole. Evaporation rates were determined using the preferred, but mathematically complex, energy budget and five empirical equations: Priestley-Taylor, Penman, DeBruin-Keijman, Papadakis, and the Priestley-Taylor used by the Georgia Automated Environmental Monitoring Network. Empirical equations require a significant amount of data but are relatively easy to calculate and compare well to long-term average annual (April 2000?March 2001) pan evaporation, which is 65 inches. Calculated annual lake evaporation, for the study period, using the energy-budget method was 67.2 inches, which overestimated long-term average annual pan evaporation by 2.2 inches. The empirical equations did not compare well with the energy-budget method during the 18-month study period, with average differences in computed evaporation using each equation ranging from 8 to 26 percent. The empirical equations also compared poorly with long-term average annual pan evaporation, with average differences in evaporation ranging from 3 to 23 percent. Energy budget and long-term average annual pan evaporation estimates did compare well, with only a 3-percent difference between estimates. Monthly evaporation estimates using all methods ranged from 0.7 to 9.5 inches and were lowest during December 2000 and highest during May 2000. Although the energy budget is generally the preferred method, the dominance of surface water in the Lake Seminole water budget makes the method inaccurate and difficult to use, because surface water makes up m

Florida, Georgia↗

Water-quality response to changes in phosphorus loading of the Winnebago Pool Lakes, Wisconsin, with special emphasis on the effects of internal loading in a chain of shallow lakes

The Winnebago Pool is a chain of four shallow lakes (Lake Poygan, Lake Winneconne, Lake Butte des Morts, and Lake Winnebago) that are fed primarily by the Fox and Wolf Rivers, two large agriculturally dominated rivers in Wisconsin, United States. Because the lakes have received extensive phosphorus inputs from their watershed, they have become highly eutrophic with much phosphorus in the water column as well as trapped in their sediments. Each of the four Winnebago Pool lakes has been included on the Wisconsin Department of Natural Resources impaired waters list because of their high total phosphorus concentrations, water-quality use restrictions, and excess algal growth. The study described in this report is part of a Total Maximum Daily Load investigation to determine what actions are needed to improve the water quality (trophic status) of these lakes and thus be able to be removed from the impaired waters list and restore their designated uses. As part of this study, data were collected to describe the existing water quality of the lakes, detailed phosphorus budgets were developed for each of the lakes to describe the different sources of the phosphorus, and two eutrophication models (BATHTUB and Jensen models) were used to determine how much of the phosphorus being input to the lakes needs to be reduced for the lakes to be removed from the impaired waters list and restore their designated uses. In-lake water-quality data indicated that each of the lakes had extensive vertical mixing that resulted in their water quality deteriorating throughout summer. Each of the lakes had mean summer total phosphorus concentrations exceeding 0.088 milligram per liter (mg/L), well above the 0.040 mg/L criterion for the lakes. Detailed phosphorus budgets for the lakes indicated that the primary sources of phosphorus were from their tributaries (for the most upstream lake in the Winnebago Pool–Lake Poygan) or from a combination of input from the upstream lakes and phosphorus release from the bottom sediment when only the summer months were considered (for the other three lakes). Model simulations with the BATHTUB and Jensen models indicated that (1) the lakes should have almost linear response in their total phosphorus concentrations to changes in their phosphorus inputs; (2) phosphorus inputs need to be reduced by about 60 percent to the Upper Pool Lakes and 69–73 percent to Lake Winnebago to reduce their mean summer total phosphorus concentrations to 0.040 mg/L; and (3) if all the anthropogenic phosphorus inputs to the lakes could be eliminated, their best possible mean summer total phosphorus concentrations should decrease to about 0.022–0.028 mg/L in the Upper Pool Lakes and to 0.032–0.033 mg/L in Lake Winnebago. The effects of any reduction in phosphorus loading will take many years (50 to more than 75 years) to be fully realized in lake water quality because of phosphorus release from the lake sediments. The effects of nutrient reductions in the watershed of a chain of lakes, such as the Winnebago Pool, gradually cascades down the chain, which has beneficial and detrimental effects. Any action made in the watershed of upstream lakes to reduce phosphorus inputs should improve the water quality of all downstream lakes; however, the upstream lakes delay the response in the downstream lakes, especially in lakes where internal phosphorus loading is important.

Wisconsin↗

The source of groundwater and solutes to Many Devils Wash at a former uranium mill site in Shiprock, New Mexico

The Shiprock Disposal Site is the location of the former Navajo Mill (Mill), a uranium ore-processing facility, located on a terrace overlooking the San Juan River in the town of Shiprock, New Mexico. Following the closure of the Mill, all tailings and associated materials were encapsulated in a disposal cell built on top of the former Mill and tailings piles. The milling operations, conducted at the site from 1954 to 1968, created radioactive tailings and process-related wastes that are now found in the groundwater. Elevated concentrations of constituents of concern—ammonium, manganese, nitrate, selenium, strontium, sulfate, and uranium—have also been measured in groundwater seeps in the nearby Many Devils Wash arroyo, leading to the inference that these constituents originated from the Mill. These constituents have also been reported in groundwater that is associated with Mancos Shale, the bedrock that underlies the site. The objective of this report is to increase understanding of the source of water and solutes to the groundwater beneath Many Devils Wash and to establish the background concentrations for groundwater that is in contact with the Mancos Shale at the site. This report presents evidence on three working hypotheses: (1) the water and solutes in Many Devils Wash originated from the operations at the former Mill, (2) groundwater in deep aquifers is upwelling under artesian pressure to recharge the shallow groundwater beneath Many Devils Wash, and (3) the groundwater beneath Many Devils Wash originates as precipitation that infiltrates into the shallow aquifer system and discharges to Many Devils Wash in a series of springs on the east side of the wash. The solute concentrations in the shallow groundwater of Many Devils Wash would result from the interaction of the water and the Mancos Shale if the source of water was upwelling from deep aquifers or precipitation. In order to compare the groundwater from various wells to groundwater that has been affected by Mill activities, a classification system was developed to determine which wells were most likely to have been affected. Affects to groundwater by the Mill were determined by using the reported uranium alpha activity ratios measured in groundwater samples, along with the concentration of the uranium and the location of the wells relative to the Mill. Activity ratios of 1.2 or less were determined to be the most reliable indicator of Mill-affected groundwater. Wells with samples that had a reported activity ratio of 1.2 or less were classified as Mill affected. To compare groundwater with background water-quality, data from groundwater seeps and springs in the Upper Eagle Nest Arroyo and Salt Creek Wash, located north of the San Juan River, are also presented and analyzed. Based on groundwater elevations and tritium concentrations measured in wells located between the disposal cell and Many Devils Wash, Mill water is not likely to reach Many Devils Wash. The tritium concentrations also indicate that groundwater from the Mill has not substantially affected Many Devils Wash in the past. Upwelling from deep aquifers was also determined to be an unlikely source, primarily by comparing the composition of the stable isotopes of water in the shallow groundwater with those reported in groundwater samples from the deeper aquifers. The stable-isotope compositions of the shallow groundwater around the site are enriched relative to the San Juan River and local meteoric lines, which suggests that most of the shallow groundwater has been influenced by evaporation and therefore was recharged at the surface. Several observations indicate that focused recharge is the likely source of groundwater in the area of Many Devils Wash. The visible erosional features in Many Devils Wash provide evidence of piping and groundwater sapping, and the distribution and type of vegetation in Many Devils Wash suggest that the focused recharge of precipitation is occurring. The estimated recharge from precipitation was calculated to be 0.0008 inches per year (in/yr) by using the mass-balance approach from reported seep discharge and 0.0011 in/yr using the chloride mass-balance approach. A conceptual model of groundwater quality beneath Many Devils Wash is presented to explain the source of solutes in the groundwater beneath Many Devils Wash. The major-ion concentrations and geochemical evolution in the groundwater beneath Many Devils Wash and across the study area support the conceptual model that the underlying Mancos Shale is the source of solutes. Differences in the major-ion composition between groundwater samples collected around the site, result from the degree of weathering to the Mancos Shale. The cation distribution appears to be an indicator of effects from the Mill, with samples from the Mill-affected wells largely having a calcium/magnesium-sulfate composition that resembles the reported compositions of more weathered shale; however, that composition could change if the Mill-processed water flowed into areas where the Mancos Shale was less weathered. On the basis of the widespread presence of uranium in the Mancos Shale and the distribution of aqueous uranium in the analog sites and other sites in the region, it appears likely that uranium in the groundwater of Many Devils Wash is naturally sourced from the Mancos Shale.

New Mexico↗

Controls on spatial and temporal variations of brine discharge to the Dolores River in the Paradox Valley, Colorado, 2016–18

The Paradox Valley in southwestern Colorado is a collapsed anticline formed by movement of the salt-rich Paradox Formation at the core of the anticline. The salinity of the Dolores River, a tributary of the Colorado River, increases substantially as it crosses the valley because of discharge of brine-rich groundwater derived from the underlying salts. Although the brine is naturally occurring, it increases the salinity of the Colorado River, which is a major concern to downstream agricultural, municipal, and industrial water users. The U.S. Geological Survey in cooperation with the Bureau of Reclamation conducted a study to improve the characterization of processes controlling spatial and temporal variations in brine discharge to the Dolores River. For the study, three geophysical surveys were conducted in March, May, and September 2017, and water levels were monitored in selected ponds and groundwater wells from November 2016 to May 2018. The study also utilized streamflow and specific conductance data from two U.S. Geological Survey streamflow-gaging stations on the Dolores River to estimate salt load to the river. River-based continuous resistivity profiling and frequency domain electromagnetic induction surveys made during low-flow conditions indicated a zone of brine-rich groundwater close to the riverbed along an approximately 4-kilometer reach of the river. Under high-flow conditions, the brine was depressed as much as 2 meters below the riverbed, and brine discharge to the river was reduced to a minimum. Direct current electrical resistivity surveys show that the freshwater lens overlying the brine is much thicker (up to 10 meters) on the west bank than on the east bank (less than 5 meters). A large low-conductivity anomaly at river distance 6,800 meters was observed in all surveys and may represent a freshwater discharge zone or a losing reach of the river. Filling and draining of the wildlife ponds on the west side of the river had a negligible effect on salt loads in the river during the study period. Groundwater monitoring showed there was active exchange of water between the river and the adjacent alluvial aquifer. When river stage was low, groundwater flowed towards the river, and brine discharge to the river increased. When the river stage was high, the gradient was reversed, and fresh surface water recharged the alluvial aquifer minimizing brine discharge. Most of the salt load to the river occurred during the winter and appeared to be enhanced by diurnal stage fluctuations. A conceptual model of brine discharge to the river is presented at three scales. Groundwater at the regional scale drives dissolution of salt in the Paradox Formation and flow of brine into the base of the alluvial aquifer. Surface water–groundwater interactions at the scale of the alluvial aquifer control brine discharge to the river seasonally and interannually. At the finest scale, diurnal fluctuations in river stage drive exchange of freshwater with saltier pore water in the hyporheic zone, which appears to increase brine discharge to the river during winter.

Colorado↗

Water-Table Levels and Gradients, Nevada, 1947-2004

In 1999, the U.S. Environmental Protection Agency began a program to protect the quality of ground water in areas other than ground-water protection areas. These other sensitive ground water areas (OSGWA) are areas that are not currently, but could eventually be, used as a source of drinking water. The OSGWA program specifically addresses existing wells that are used for underground injection of motor-vehicle waste. To help determine whether a well is in an OSGWA, the Nevada Division of Environmental Protection needs statewide information on depth to water and the water table, which partly control the susceptibility of ground water to contamination and contaminant transport. This report describes a study that used available maps and data to create statewide maps of water-table and depth-to-water contours and surfaces, assessed temporal changes in water-table levels, and characterized water-table gradients in selected areas of Nevada. A literature search of published water-table and depth-to-water contours produced maps of varying detail and scope in 104 reports published from 1948 to 2004. Where multiple maps covered the same area, criteria were used to select the most recent, detailed maps that covered the largest area and had plotted control points. These selection criteria resulted in water-table and depth-to-water contours that are based on data collected from 1947 to 2004 being selected from 39 reports. If not already available digitally, contours and control points were digitized from selected maps, entered into a geographic information system, and combined to make a statewide map of water-table contours. Water-table surfaces were made by using inverse distance weighting to estimate the water table between contours and then gridding the estimates. Depth-to-water surfaces were made by subtracting the water-table altitude from the land-surface altitude. Water-table and depth-to-water surfaces were made for only 21 percent of Nevada because of a lack of information for 49 of 232 basins and for most consolidated-rock hydrogeologic units. Depth to water is commonly less than 50 feet beneath valley floors, 50 to 500 feet beneath alluvial fans, and more than 500 feet in some areas such as north-central and southern Nevada. In areas without water-table information, greasewood and mapped ground-water discharge areas are good indicators of depth to water less than 100 feet. The average difference between measured depth to water and depth to water estimated from surfaces was 90 feet. More recent and detailed information may be needed than that presented in this report to evaluate a specific site. Temporal changes in water-table levels were evaluated for 1,981 wells with 10 or more years between the first depth-to-water measurement and last measurement made since 1990. The greatest increases in depth to water occurred where the first measurement was less than 200 feet, where the time between first and last measurements was 40 years or less, and for wells between 100 and 600 feet deep. These characteristics describe production wells where ground water is fairly shallow in recently developing areas such as the Las Vegas and Reno metropolitan areas. In basins with little pumping, 90 percent of the changes during the past 100 years are within ?20 feet, which is about the natural variation in the water table due to changes in the climate and recharge. Gradients in unconsolidated sediments of the Great Basin are generally steep near mountain fronts, shallow beneath valley floors, and depend on variables such as the horizontal hydraulic conductivity of adjacent consolidated rocks and recharge. Gradients beneath alluvial fans and valley floors at 58 sites were correlated with selected variables to identify those variables that are statistically related. Water-table measurements at three sites were used to characterize the water table between the valley floor and consolidated rock. Water-table gradients beneath alluvial fan

Scientific Investigations Report↗

Equations for estimating bankfull channel geometry and discharge for streams in Massachusetts

Regression equations were developed for estimating bankfull geometry—width, mean depth, cross-sectional area—and discharge for streams in Massachusetts. The equations provide water-resource and conservation managers with methods for estimating bankfull characteristics at specific stream sites in Massachusetts. This information can be used for the adminstration of the Commonwealth of Massachusetts Rivers Protection Act of 1996, which establishes a protected riverfront area extending from the mean annual high-water line corresponding to the elevation of bankfull discharge along each side of a perennial stream. Additionally, information on bankfull channel geometry and discharge are important to Federal, State, and local government agencies and private organizations involved in stream assessment and restoration projects. Regression equations are based on data from stream surveys at 33 sites (32 streamgages and 1 crest-stage gage operated by the U.S. Geological Survey) in and near Massachusetts. Drainage areas of the 33 sites ranged from 0.60 to 329 square miles (mi2). At 27 of the 33 sites, field data were collected and analyses were done to determine bankfull channel geometry and discharge as part of the present study. For 6 of the 33 sites, data on bankfull channel geometry and discharge were compiled from other studies done by the U.S. Geological Survey, Natural Resources Conservation Service of the U.S. Department of Agriculture, and the Vermont Department of Environmental Conservation. Similar techniques were used for field data collection and analysis for bankfull channel geometry and discharge at all 33 sites. Recurrence intervals of the bankfull discharge, which represent the frequency with which a stream fills its channel, averaged 1.53 years (median value 1.34 years) at the 33 sites. Simple regression equations were developed for bankfull width, mean depth, cross-sectional area, and discharge using drainage area, which is the most significant explanatory variable in estimating these bankfull characteristics. The use of drainage area as an explanatory variable is also the most commonly published method for estimating these bankfull characteristics. Regional curves (graphic plots) of bankfull channel geometry and discharge by drainage area are presented. The regional curves are based on the simple regression equations and can be used to estimate bankfull characteristics from drainage area. Multiple regression analysis, which includes basin characteristics in addition to drainage area, also was used to develop equations. Variability in bankfull width, mean depth, cross-sectional area, and discharge was more fully explained by the multiple regression equations that include mean-basin slope and drainage area than was explained by equations based on drainage area alone. The Massachusetts regional curves and equations developed in this study are similar, in terms of values of slopes and intercepts, to those developed for other parts of the northeastern United States. Limitations associated with site selection and development of the equations resulted in some constraints for the application of equations and regional curves presented in this report. The curves and equations are applicable to stream sites that have (1) less than about 25 percent of their drainage basin area occupied by urban land use (commercial, industrial, transportation, and high-density residential), (2) little to no streamflow regulation, especially from flood-control structures, (3) drainage basin areas greater than 0.60 mi2 and less than 329 mi2, and (4) a mean basin slope greater than 2.2 percent and less than 23.9 percent. The equations may not be applicable where streams flow through extensive wetlands. The equations also may not apply in areas of Cape Cod and the Islands and the area of southeastern Massachusetts close to Cape Cod with extensive areas of coarse-grained glacial deposits where none of the study sites are located. Regardless of the setting, the regression equations are not intended for use as the sole method of estimating bankfull characteristics; however, they may supplement field identification of the bankfull channel when used in conjunction with field verified bankfull indicators, flood-frequency analysis, or other supporting evidence.

Massachusetts↗

Evaluation of the effects of precipitation on ground-water levels from wells in selected alluvial aquifers in Utah and Arizona, 1936-2005

Increased withdrawals from alluvial aquifers of the southwestern United States during the last half-century have intensified the effects of drought on ground-water levels in valleys where withdrawal for irrigation is greatest. Furthermore, during wet periods, reduced withdrawals coupled with increased natural recharge cause rising ground-water levels. In order to manage water resources more effectively, analysis of ground-water levels under the influence of natural and anthropogenic stresses is useful. This report evaluates the effects of precipitation patterns on ground-water levels in areas of Utah and Arizona that have experienced different amounts of ground-water withdrawal. This includes a comparison of water-level records from basins that are hydrogeologically and climatologically similar but have contrasting levels of ground-water development. Hydrologic data, including records of ground-water levels, basin-wide annual ground-water withdrawals, and precipitation were examined from two basins in Utah (Milford and central Sevier) and three in Arizona (Aravaipa Canyon, Willcox, and Douglas). Most water-level records examined in this study from basins experiencing substantial ground-water development (Milford, Douglas, and Willcox) showed strong trends of declining water levels. Other water-level records, generally from the less-developed basins (central Sevier and Aravaipa Canyon) exhibited trends of increasing water levels. These trends are likely the result of accumulating infiltration of unconsumed irrigation water. Water-level records that had significant trends were detrended by subtraction of a low-order polynomial in an attempt to eliminate the variation in the water-level records that resulted from ground-water withdrawal or the application of water for irrigation. After detrending, water-level residuals were correlated with 2- to 10-year moving averages of annual precipitation from representative stations for the individual basins. The water-level residual time series for each well was matched with the 2- to 10-year moving average of annual precipitation with which it was best correlated and the results were compared across basins and hydrologic settings. Analysis of water-level residuals and moving averages of annual precipitation indicate that ground-water levels in the Utah basins respond more slowly to precipitation patterns than those from the Arizona basins. This is attributed to the dominant mechanism of recharge that most directly influences the respective valley aquifers. Substantial recharge in the Utah basins likely originates as infiltrating snowmelt in the mountain block far from the valley aquifer, whereas mountain-front recharge and streambed infiltration of runoff are the dominant recharge mechanisms operating in the Arizona basins. It was determined that the fraction of water-level variation caused by local precipitation patterns becomes more difficult to resolve with increasing effects of ground-water pumping, especially from incomplete records. As the demand for ground water increases in the southwestern United States, long-term records of ground-water levels have the potential to provide valuable information about the precipitation-driven variation in water levels, which has implications to water management related to water availability.

Arizona, Utah↗

Simulation of Multiscale Ground-Water Flow in Part of the Northeastern San Joaquin Valley, California

The transport and fate of agricultural chemicals in a variety of environmental settings is being evaluated as part of the U.S. Geological Survey (USGS) National Water-Quality Assessment Program. One of the locations being evaluated is a 2,700-km2 (square kilometer) regional study area in the northeastern San Joaquin Valley surrounding the city of Modesto, an area dominated by irrigated agriculture in a semi-arid climate. Ground water is a key source of water for irrigation and public supply, and exploitation of this resource has altered the natural flow system. The aquifer system is predominantly alluvial, and an unconfined to semiconfined aquifer overlies a confined aquifer in the southwestern part of the study area; these aquifers are separated by the lacustrine Corcoran Clay. A regional-scale 16-layer steady-state model of ground-water flow in the aquifer system in the regional study area was developed to provide boundary conditions for an embedded 110-layer steady-state local-scale model of part of the aquifer system overlying the Corcoran Clay along the Merced River. The purpose of the local-scale model was to develop a better understanding of the aquifer system and to provide a basis for simulation of reactive transport of agricultural chemicals. The heterogeneity of aquifer materials was explicitly incorporated into the regional and local models using information from geologic and drillers? logs of boreholes. Aquifer materials were differentiated in the regional model by the percentage of coarse-grained sediments in a cell, and in the local model by four hydrofacies (sand, silty sand, silt, and clay). The calibrated horizontal hydraulic conductivity values of the coarse-grained materials in the zone above the Corcoran Clay in the regional model and of the sand hydrofacies used in the local model were about equal (30?80 m/d [meter per day]), and the vertical hydraulic conductivity values in the same zone of the regional model (median of 0.012 m/d), which is dominated by the finer-grained materials, were about an order of magnitude less than that for the clay hydrofacies in the local model. Data used for calibrating both models included long-term hourly water-level measurements in 20 short-screened wells installed by the USGS in the Modesto and Merced River areas. Additional calibration data for the regional model included water-level measurements in 11 wells upslope and 17 wells downslope from these areas. The root mean square error was 2.3 m (meter) for all wells in the regional model and 0.8 m for only the USGS wells; the associated average errors were 0.9 m and 0.3 m, respectively. The root mean square error for the 12 USGS wells along a transect in the local model area was 0.08 m; the average error was 0.0 m. Particle tracking was used with the local model to estimate the concentration of an environmental tracer, sulfur hexafluoride, in 10 USGS transect wells near the Merced River that were sampled for this constituent. Measured and estimated concentrations in the mid-depth and deepest wells, which would be most sensitive to errors in hydraulic conductivity estimates, were consistent. The combined results of particle tracking and sulfur hexafluoride analysis suggest that most water sampled from the transect wells was recharged less that 25 years ago.

Scientific Investigations Report↗

Discharge and dissolved-solids characteristics of Blacks Fork above Smiths Fork, Wyoming, April 2018 through September 2019

The Colorado River Basin Salinity Control Forum was formed in 1973 to coordinate salinity control efforts among the States in the Colorado River Basin, including Wyoming. The Colorado River Salinity Control Act of 1974 (Public Law 93–320) authorized “the construction, operation, and maintenance of certain works in the Colorado River Basin to control the salinity of water delivered to users in the United States and Mexico.” Water-quality standards for salinity in the lower Colorado River Basin were adopted in 1975. To help meet these standards, the Bureau of Reclamation, Natural Resource Conservation Service, and States within the Colorado River Basin have implemented salinity control projects that focus on reducing salt loading associated with irrigated agriculture by improving water delivery systems and water management practices. The term salinity is synonymous with dissolved solids in this report. The Bureau of Reclamation, in conjunction with the Colorado River Basin Salinity Control Forum, was interested in determining the contribution of dissolved solids from Blacks Fork above Smiths Fork to the Colorado River and initiated a study of Blacks Fork above Smiths Fork in 2018. In early 2018, the U.S. Geological Survey installed a streamgage at the most downstream location on the Blacks Fork, upstream from the convergence with Smiths Fork, to characterize the stream. The Blacks Fork above Smiths Fork, near Lyman, Wyoming, streamgage (U.S. Geological Survey identifier 09219200) was operated from April 4, 2018, through September 30, 2019, collecting continuous stream stage and specific-conductance data, from which continuous discharge, dissolved-solids concentrations, and dissolved-solids loads were calculated. Seven sites were selected on Blacks Fork and a tributary to describe a snapshot of the discharge and dissolved-solids characteristics. These sites were sampled during July, August, and September 2018 and June, July, August, and September 2019 report. Discharge at the Blacks Fork above Smiths Fork, near Lyman, Wyo., streamgage (09219200) from April through September in 2018 was lower and less variable than during the same period in 2019. The mean daily (mean of the daily means) discharge during those 6 months in 2018 (15.1 cubic feet per second [ft 3 /s]) was about one-tenth of the discharge during the same period in 2019 (152 ft 3 /s). The cumulative monthly discharge during April through September in 2018 was 5,360 acre-feet, about one-tenth of the discharge during the same period in 2019 which was 54,700 acre-feet. Similar differences in discharge between the 2018 and 2019 periods also are noted at other Blacks Fork streamgages in the area. Continuous specific conductance data and the statistical relation between specific conductance and dissolved-solids concentrations were used to calculate the daily mean dissolved-solids concentrations. Dissolved solids often have an inverse relation with discharge because higher discharges typically have a diluting effect that lowers the dissolved-solids concentrations. In general, when discharges at the Blacks Fork above Smiths Fork streamgage (09219200) are higher, dissolved-solids concentrations are generally lower. However, the high dissolved-solids concentrations that are measured during high discharges indicate that the system has natural variability and the dissolved-solids concentrations are determined by more factors than just discharge. The mean daily dissolved-solids concentration during April through September 2018 was 1,630 milligrams per liter and during the same period in 2019 was 1,100 milligrams per liter. Dissolved-solids loads were calculated as the product of the discharge and dissolved-solids concentration. The daily mean dissolved-solids loads during 2018 were typically lower than during 2019. This result is primarily because the discharge was much lower in 2018 than in 2019. Therefore, although the daily mean dissolved-solids concentrations tended to be higher in 2018, the substantially higher discharges in 2019 had more of an effect on the dissolved-solids loads than the dissolved-solids concentrations. The cumulative dissolved-solids load at the Blacks Fork above Smiths Fork, near Lyman, Wyo., streamgage (09219200) during the 18-month study was 81,200 tons, with a mean daily load of 149 tons per day. During the 6-month period from April through September 2018, the cumulative dissolved-solids load at the streamgage was estimated to be 8,740 tons and, during the same 6 months in 2019, the cumulative dissolved-solids load was estimated to be 60,900 tons. During the fall and winter between the two periods, the cumulative dissolved-solids load was 11,600 tons. Discharge and dissolved-solids concentrations from samples collected during the synoptic sampling events were highly variable among most sites during most synoptic sampling events and also highly variable at most sites among different sampling events. The two sites upstream from the tributary input from Threemile Creek had lower dissolved-solids concentrations than sites including and downstream from the tributary. Sites including and downstream from the tributary had similar values and variability of dissolved-solids loads, with the exception of the farthest downstream site at the Blacks Fork above Smiths Fork, near Lyman, Wyo., streamgage (09219200) that tended to have larger dissolved-solids loads and higher variability among synoptic sampling events.

Scientific Investigations Report↗

Water-quality trend analysis and sampling design for the Devils Lake Basin, North Dakota, January 1965 through September 2003

This report presents the results of a study conducted by the U.S. Geological Survey, in cooperation with the North Dakota State Water Commission, the Devils Lake Basin Joint Water Resource Board, and the Red River Joint Water Resource District, to analyze historical water-quality trends in three dissolved major ions, three nutrients, and one dissolved trace element for eight stations in the Devils Lake Basin in North Dakota and to develop an efficient sampling design to monitor the future trends. A multiple-regression model was used to detect and remove streamflow-related variability in constituent concentrations. To separate the natural variability in concentration as a result of variability in streamflow from the variability in concentration as a result of other factors, the base-10 logarithm of daily streamflow was divided into four components-a 5-year streamflow anomaly, an annual streamflow anomaly, a seasonal streamflow anomaly, and a daily streamflow anomaly. The constituent concentrations then were adjusted for streamflow-related variability by removing the 5-year, annual, seasonal, and daily variability. Constituents used for the water-quality trend analysis were evaluated for a step trend to examine the effect of Channel A on water quality in the basin and a linear trend to detect gradual changes with time from January 1980 through September 2003. The fitted upward linear trends for dissolved calcium concentrations during 1980-2003 for two stations were significant. The fitted step trends for dissolved sulfate concentrations for three stations were positive and similar in magnitude. Of the three upward trends, one was significant. The fitted step trends for dissolved chloride concentrations were positive but insignificant. The fitted linear trends for the upstream stations were small and insignificant, but three of the downward trends that occurred during 1980-2003 for the remaining stations were significant. The fitted upward linear trends for dissolved nitrite plus nitrate as nitrogen concentrations during 1987-2003 for two stations were significant. However, concentrations during recent years appear to be lower than those for the 1970s and early 1980s but higher than those for the late 1980s and early 1990s. The fitted downward linear trend for dissolved ammonia concentrations for one station was significant. The fitted linear trends for total phosphorus concentrations for two stations were significant. Upward trends for total phosphorus concentrations occurred from the late 1980s to 2003 for most stations, but a small and insignificant downward trend occurred for one station. Continued monitoring will be needed to determine if the recent trend toward higher dissolved nitrite plus nitrate as nitrogen and total phosphorus concentrations continues in the future. For continued monitoring of water-quality trends in the upper Devils Lake Basin, an efficient sampling design consists of five major-ion, nutrient, and trace-element samples per year at three existing stream stations and at three existing lake stations. This sampling design requires the collection of 15 stream samples and 15 lake samples per year rather than 16 stream samples and 20 lake samples per year as in the 1992-2003 program. Thus, the design would result in a program that is less costly and more efficient than the 1992-2003 program but that still would provide the data needed to monitor water-quality trends in the Devils Lake Basin.

North Dakota↗

Physical habitat, water quality, and riverine biological assemblages of selected reaches of the Sheyenne River, North Dakota, 2010

In 2010, data on physical habitat, water quality, and riverine biological assemblages were collected at selected reaches in four locations (Kleven, Sheyenne, Cooperstown, and West Fargo) on the Sheyenne River in east-central North Dakota. Three of the locations (Kleven, Sheyenne, and Cooperstown) are above Baldhill Dam and one location (West Fargo) is below Baldhill Dam on the Sheyenne River. The 2010 data provide information to establish a better understanding of the water-quality and ecological conditions of the Sheyenne River. Concerns were raised about the water-quality and ecological conditions of the Sheyenne River because of the interbasin transfer of water from nearby Devils Lake. The transfer of water from Devils Lake to the Sheyenne River occurs through the Devils Lake State Outlet near Peterson Coulee or, if lake elevations exceed 1,459 feet above National Geodetic Vertical Datum of 1929 (NGVD 29), through a natural outlet, Tolna Coulee. The field measurements of water-quality characteristics and results of chemical analyses generally are comparable to summary statistics calculated for Sheyenne River for 1980 through 2006. Overall, water-quality results show differences between the Kleven, Sheyenne, Cooperstown, and West Fargo reaches. Sulfate concentrations were less than the State of North Dakota criterion of 750 milligrams per liter for the upper Sheyenne River above Baldhill Dam and less than the criterion of 450 milligrams per liter for the lower Sheyenne River below Baldhill Dam. Arsenic concentrations at most reaches exceeded the U.S. Environmental Protection Agency drinking-water standard of 10 micrograms per liter. Nutrient concentrations (nitrogen, phosphorus) were higher in the upper Sheyenne River above Baldhill Dam than below Baldhill Dam where concentrations decreased by about half. In 2010, 35 families and 44 genera of benthic macroinvertebrates were collected and identified. On the basis of the index of biotic intergrity scores for benthic macroinvertebrate communities present in the Sheyenne River, all the reaches were determined to have condition classes of moderately disturbed to most disturbed. The benthic macroinvertebrate communities at the Cooperstown reaches were classed as moderately disturbed, whereas benthic macroinvertebrate communities at the Kleven, Sheyenne, West and Fargo reaches were most disturbed. During data collection, 37 genera and 165 species of periphyton (diatoms and soft-bodied algae) were collected and identified. In periphyton communities, similar taxa species were dominant in the Kleven, Sheyenne, and Cooperstown reaches, and different taxa species were dominant in the West Fargo reaches. For diatoms, the Kleven 3 reach had the lowest species richness value of 33.0, whereas the Cooperstown 8 reach had the highest species richness value of 57.0. For soft-bodied algae, the species richness values ranged from 8.0 at the Sheyenne 4 reach to 20.0 at the West Fargo 10 reach. During the fish collection, 32 species, representing 10 families, were collected in the Sheyenne River. All but two species are native to the Sheyenne River system. Common carp and white crappie are the two introduced species. Of the 32 species, 29 are tolerant to moderately tolerant to changes in water quality and habitat degradation, 16 species are tolerant to moderately tolerant to turbidity, and 16 species are tolerant to moderately tolerant to sensitivity to total dissolved solids, sulfate, and chloride. All fish species were categorized into four trophic groups. The largest group of 19 species was the insectivores (both benthic and general). The predator group consisted of seven species, and the omnivores consisted of six species. More fish were found in the lower Sheyenne River below Baldhill Dam than in the upper Sheyenne River above Baldhill Dam.

North Dakota↗

Development of a Precipitation-Runoff Model to Simulate Unregulated Streamflow in the Salmon Creek Basin, Okanogan County, Washington

Surface water has been diverted from the Salmon Creek Basin for irrigation purposes since the early 1900s, when the Bureau of Reclamation built the Okanogan Project. Spring snowmelt runoff is stored in two reservoirs, Conconully Reservoir and Salmon Lake Reservoir, and gradually released during the growing season. As a result of the out-of-basin streamflow diversions, the lower 4.3 miles of Salmon Creek typically has been a dry creek bed for almost 100 years, except during the spring snowmelt season during years of high runoff. To continue meeting the water needs of irrigators but also leave water in lower Salmon Creek for fish passage and to help restore the natural ecosystem, changes are being considered in how the Okanogan Project is operated. This report documents development of a precipitation-runoff model for the Salmon Creek Basin that can be used to simulate daily unregulated streamflows. The precipitation-runoff model is a component of a Decision Support System (DSS) that includes a water-operations model the Bureau of Reclamation plans to develop to study the water resources of the Salmon Creek Basin. The DSS will be similar to the DSS that the Bureau of Reclamation and the U.S. Geological Survey developed previously for the Yakima River Basin in central southern Washington. The precipitation-runoff model was calibrated for water years 1950-89 and tested for water years 1990-96. The model was used to simulate daily streamflows that were aggregated on a monthly basis and calibrated against historical monthly streamflows for Salmon Creek at Conconully Dam. Additional calibration data were provided by the snowpack water-equivalent record for a SNOTEL station in the basin. Model input time series of daily precipitation and minimum and maximum air temperatures were based on data from climate stations in the study area. Historical records of unregulated streamflow for Salmon Creek at Conconully Dam do not exist for water years 1950-96. Instead, estimates of historical monthly mean unregulated streamflow based on reservoir outflows and storage changes were used as a surrogate for the missing data and to calibrate and test the model. The estimated unregulated streamflows were corrected for evaporative losses from Conconully Reservoir (about 1 ft3/s) and ground-water losses from the basin (about 2 ft3/s). The total of the corrections was about 9 percent of the mean uncorrected streamflow of 32.2 ft3/s (23,300 acre-ft/yr) for water years 1949-96. For the calibration period, the basinwide mean annual evapotranspiration was simulated to be 19.1 inches, or about 83 percent of the mean annual precipitation of 23.1 inches. Model calibration and testing indicated that the daily streamflows simulated using the precipitation-runoff model should be used only to analyze historical and forecasted annual mean and April-July mean streamflows for Salmon Creek at Conconully Dam. Because of the paucity of model input data and uncertainty in the estimated unregulated streamflows, the model is not adequately calibrated and tested to estimate monthly mean streamflows for individual months, such as during low-flow periods, or for shorter periods such as during peak flows. No data were available to test the accuracy of simulated streamflows for lower Salmon Creek. As a result, simulated streamflows for lower Salmon Creek should be used with caution. For the calibration period (water years 1950-89), both the simulated mean annual streamflow and the simulated mean April-July streamflow compared well with the estimated uncorrected unregulated streamflow (UUS) and corrected unregulated streamflow (CUS). The simulated mean annual streamflow exceeded UUS by 5.9 percent and was less than CUS by 2.7 percent. Similarly, the simulated mean April-July streamflow exceeded UUS by 1.8 percent and was less than CUS by 3.1 percent. However, streamflow was significantly undersimulated during the low-flow, baseflow-dominated months of November through F

Scientific Investigations Report↗

Hydrogeology, Chemical Characteristics, and Transport Processes in the Zone of Contribution of a Public-Supply Well in York, Nebraska

In 2001, the U.S. Geological Survey, as part of the National Water Quality Assessment (NAWQA) Program, initiated a topical study of Transport of Anthropogenic and Natural Contaminants (TANC) to PSW (public-supply wells). Local-scale and regional-scale TANC study areas were delineated within selected NAWQA study units for intensive study of processes effecting transport of contaminants to PSWs. This report describes results from a local-scale TANC study area at York, Nebraska, within the High Plains aquifer, including the hydrogeology and geochemistry of a 108-square-kilometer study area that contains the zone of contribution to a PSW selected for study (study PSW), and describes factors controlling the transport of selected anthropogenic and natural contaminants to PSWs. Within the local-scale TANC study area, the High Plains aquifer is approximately 75 m (meter) thick, and includes an unconfined aquifer, an upper confining unit, an upper confined aquifer, and a lower confining unit with lower confined sand lenses (units below the upper confining unit are referred to as confined aquifers) in unconsolidated alluvial and glacial deposits overlain by loess and underlain by Cretaceous shale. From northwest to southeast, land use in the local-scale TANC study area changes from predominantly irrigated agricultural land to residential and commercial land in the small community of York (population approximately 8,100). For the purposes of comparing water chemistry, wells were classified by degree of aquifer confinement (unconfined and confined), depth in the unconfined aquifer (shallow and deep), land use (urban and agricultural), and extent of mixing in wells in the confined aquifer with water from the unconfined aquifer (mixed and unmixed). Oxygen (delta 18O) and hydrogen (delta D) stable isotopic values indicated a clear isotopic contrast between shallow wells in the unconfined aquifer (hereinafter, unconfined shallow wells) and most monitoring wells in the confined aquifers (hereinafter, confined unmixed wells). Delta 18O and delta D values for a minority of wells in the confined aquifers were intermediate between those for the unconfined shallow wells and those for the confined unmixed wells. These intermediate values were consistent with mixing of water from unconfined and confined aquifers (hereinafter, confined mixed wells). Oxidation-reduction conditions were primarily oxic in the unconfined aquifer and variably reducing in the confined aquifers. Trace amounts of volatile organic compounds (VOC), particularly tetrachloroethylene (PCE) and trichloroethylene (TCE), were widely detected in unconfined shallow urban wells and indicated the presence of young urban recharge waters in most confined mixed wells. The presence of degradation products of agricultural pesticides (acetochlor and alachlor) in some confined mixed wells suggests that some fraction of the water in these wells also was the result of recharge in agricultural areas. In the unconfined aquifer, age-tracer data (chlorofluorocarbon and sulfur hexafluoride data, and tritium to helium-3 ratios) fit a piston-flow model, with apparent recharge ages ranging from 7 to 48 years and generally increasing with depth. Age-tracer data for the confined aquifers were consistent with mixing of 'old' water, not containing modern tracers recharged in the last 60 years, and exponentially-mixed 'young' water with modern tracers. Confined unmixed wells contained less than (<) 3 percent (%) young water mixed with a much larger fraction greater than or equal to (>=) 97% of old water. Confined mixed wells contained >30% young water and mean ages ranged from 12 to 14 years. Median concentrations of nitrate (as nitrogen, hereinafter, nitrate-N) were 17.3 and 16.0 mg/L (milligram per liter) in unconfined shallow urban and agricultural wells, respectively, indicating a range of likely nitrate sources. Septic systems are most numerous near the edge of the urban area and appear to be

Scientific Investigations Report↗

Simulation of groundwater flow, 1895–2010, and effects of additional groundwater withdrawals on future stream base flow in the Elkhorn and Loup River Basins, central Nebraska—Phase three

The U.S. Geological Survey, in cooperation with the Lewis and Clark, Lower Elkhorn, Lower Loup, Lower Platte North, Lower Niobrara, Middle Niobrara, Upper Elkhorn, and the Upper Loup Natural Resources Districts, designed a study to refine the spatial and temporal discretization of a previously modeled area. This updated study focused on a 30,000-square-mile area of the High Plains aquifer and constructed regional groundwater-flow models to evaluate the effects of groundwater withdrawal on stream base flow in the Elkhorn and Loup River Basins, Nebraska. The model was calibrated to match groundwater-level and base-flow data from the stream-aquifer system from pre-1940 through 2010 (including predevelopment [pre-1895], early development [1895–1940], and historical development [1940 through 2010] conditions) using an automated parameter-estimation method. The calibrated model then was used to simulate hypothetical development conditions (2011 through 2060). Predicted changes to stream base flow based on simulated changes to groundwater withdrawal will aid in developing strategies for management of hydrologically connected water supplies. Additional wells were simulated throughout the model domain and pumped for 50 years to assess the effect of wells on aquifer depletions, including stream base flow. The percentage of withdrawal for each well after 50 years, which was compensated by aquifer reductions to stream base flow, storage, or evapotranspiration, was computed and mapped. These depletions are influenced by aquifer properties, time, and distance from the well. Stream base-flow depletion results showed that the closer the added well was to a stream, the greatest the effect on the stream base flow. Areas of stream base-flow depletion percentages greater than 80 percent were generally within 1 mile (mi) from the stream. The distance increased to 6 mi near the confluence of the Dismal and Middle Loup Rivers, and the North Loup and Calamus Rivers. The percentage of stream base-flow depletion decreased as the distance from the stream increased. Areas more than 10 mi from the stream generally had a stream base-flow depletion of 10 percent or less. Evapotranspiration depletion was largest in areas closest to streams, specifically in the Elkhorn River watershed. It was also larger in areas of interdunal wetlands within the Sand Hills. Evapotranspiration depletion was negligible in areas greater than 5 mi from a stream, with the exception of interdunal areas in Cherry, Grant, and Arthur Counties. The storage depletion percentage increased as the distance from a stream increased. Storage depletion was largest in areas between streams. Areas experiencing the smallest amount of storage depletion were adjacent to streams. Calibrated model outputs and streamflow depletion analysis are publicly available online. Accuracy of the simulations is affected by input data limitations, system simplifications, assumptions, and resources available at the time of the simulation construction and calibration. Most of the important limitations relate either to data used as simulation inputs or to data used to estimate simulation inputs. Development of the regional simulations focused on generalized hydrogeologic characteristics within the study area and did not attempt to describe variations important to local-scale conditions. These simulations are most appropriate for analyzing groundwater-management scenarios for large areas and during long periods and are not suitable for analysis of small areas or short periods.

Nebraska↗

Bathymetric contour maps, surface area and capacity tables, and bathymetric change maps for selected water-supply lakes in northeastern Missouri, 2021

Bathymetric data were collected at 12 water-supply lakes in northeastern Missouri by the U.S. Geological Survey (USGS) in cooperation with the Missouri Department of Natural Resources (MoDNR) and various local agencies, as part of a multiyear effort to establish or update the surface area and capacity tables for the surveyed lakes. The lakes were surveyed in March through May 2021. Ten of the lakes had been surveyed previously by the USGS, and the recent surveys were compared to the earlier surveys to document the changes in the bathymetric surface and capacity of the lakes. Bathymetric data were collected using a high-resolution multibeam mapping system mounted on a boat. Supplemental depth data at five of the lakes were collected in shallow areas with an acoustic Doppler current profiler on a remote-controlled boat. Data points from the various sources were exported at a gridded data resolution appropriate to each lake, either 0.82 foot, 1.64 feet, or 3.28 feet. Data outside the multibeam survey extent and greater than the surveyed water-surface elevation were obtained from data collected using aerial light detection and ranging (lidar) point cloud data. A linear enforcement technique was used to add points to the dataset in areas of sparse data (the upper ends of coves where the water was shallow or aquatic vegetation precluded data acquisition) based on surrounding multibeam and upland data values. The various point datasets were used to produce a three-dimensional triangulated irregular network surface of the lake-bottom elevations for each lake. A surface area and capacity table was produced from the three-dimensional surface for each lake showing surface area and capacity at specified lake water-surface elevations. Various quality-assurance tests were conducted to ensure quality data were collected with the multibeam, including beam angle checks and patch tests. Additional quality-assurance tests were conducted on the gridded bathymetric data from the survey, the bathymetric surface created from the gridded data, and the contours created from the bathymetric survey. If there were data from a previous bathymetric survey for a given lake, a bathymetric change map was generated from the elevation difference between the previous survey and the 2021 bathymetric survey data points. After reconciling any vertical datum disagreement between the previous survey data and the 2021 survey datum, coincident points between the surveys were identified, and a bathymetric change map was generated using the coincident point data. The mean elevation change between all repeat surveys at most lakes was positive, indicating sedimentation. Relative to previous surveys, the change in capacity at the primary spillway elevation ranged from a 7.7-percent decrease at Memphis Reservoir to a 3.9-percent increase at Old Lake (Bowling Green West). The mean bathymetric change ranged from 0.03 foot at Hazel Creek and 0.07 foot at Shelbina Lake and Bowling Green Reservoir (Jack Floyd Memorial Lake) to 0.63 at Memphis Lake (Lake Showme) and 0.88 at Memphis Reservoir. The time-averaged mean bathymetric change ranged from 0.002 foot per year at Hazel Creek Lake to 0.044 foot per year at Memphis Reservoir. The computed volumetric sedimentation rate generally ranged from 0.14 to 6.80 acre-feet per year at Shelbina Lake and Memphis Lake (Lake Showme), respectively; however, Forest Lake had a substantially larger sedimentation rate of 17.0 acre-feet per year. Some changes observed in some bathymetric change maps are believed to result from the difference in data collection equipment and techniques between the previous and present bathymetric surveys, whereas other erosional features around the perimeter of certain lakes may be the result of wave action during low-water years.

Missouri↗

Geologic map and borehole stratigraphy of Hinkley Valley and vicinity, San Bernardino County, California

Hinkley Valley, in the central to western Mojave Desert of southeastern California, has a long historical record owing to its position as a crossroads for rail and road traffic and its position adjacent to the Mojave River. Subflow in the Mojave River provided groundwater recharge that maintained water consumption and demand by way of shallow wells for local agriculture in the valley. Its crossroads position led to construction of several power-transmission lines, pipeline, and communications cable routes that transect Hinkley Valley. One of these, a natural gas pipeline and its associated compressor station, was the locus of hexavalent chromium, Cr(VI), released into, and consequent contamination of, groundwater. Understanding the movement and fate of the contaminants is a complex hydrologic and geochemical problem. Geologic mapping of the Hinkley Valley area provides framework elements for use in resolving this problem. This report provides new information on surface and subsurface geology to better constrain the origin and geometry of hydrologically important deposits in the Hinkley Valley area and describes youthful faults that may control sediment distribution and groundwater flow. The geologic map (sheet 1) presents substantial new information on surficial geology, including Pliocene deposits, but does not contain significant new work on bedrock. Bedrock investigations were specific to identifying youthful faults and representative outcrops for rocks that were penetrated by boreholes in the valley. Special attention was placed on locating and describing youthful faults. In addition, we analyzed gravity data to (1) map horizontal gradients that we interpret to reflect long-term fault traces and to (2) estimate the depth to bedrock, which is defined as Miocene and older intrusive and metamorphic rocks for the purposes of this report. The subsurface geology of Hinkley Valley was investigated by examining borehole sediment cores and rock encountered at the base of the sediment section. We analyzed the core to determine depositional environments, provenance, and age of the sediment that infilled the valley. Valleys, mountains, and basins in the Hinkley Valley area are topographically complex and incompletely named. The nearly flat floored Hinkley Valley slopes gently northward. It is framed by Mount General and the informally named “Hinkley hills” (southeast of Mount General) on the northeast and by Iron Mountain and Lynx Cat Mountain on the southwest, although breaks in the western mountains allow stream connections between Hinkley Valley and another valley to the west that is herein referred to as Hawes valley. At its south end, Hinkley Valley is traversed by the entrenched Mojave River, which passes east out of the valley past Barstow. North of Hinkley Valley, a few low hills (including Red Hill) separate the valley from a broad west-sloping piedmont that is part of the physiographic Harper Basin (of which the Harper Lake playa is the center). The lower part of this piedmont, however, is referred to as Water Valley, although it is not a distinct valley. The name derives from groundwater sourced from subflow in the Mojave River, which caused shallow water and even artesian flow in Water Valley but not in other parts of the Harper Basin. When water filled the Harper Basin to form Pleistocene Lake Harper it not only submerged Water Valley but also northern Hinkley Valley.

California↗

The Connecticut Streamflow and Sustainable Water Use Estimator—A decision-support tool to estimate water availability at ungaged stream locations in Connecticut

Freshwater streams in Connecticut are subject to many competing demands, including public water supply; agricultural, commercial, and industrial water use; and ecosystem and habitat needs. In recent years, drought has further stressed Connecticut’s water resources. To sustainably allocate and manage water resources among these competing uses, Federal, State, and local water-resource managers require data and modeling tools to estimate the water availability at a variety of temporal and spatial scales for planning purposes. The Connecticut Streamflow and Sustainable Water Use Estimator (CT SSWUE), developed by the U.S. Geological Survey in cooperation with the Connecticut Department of Energy and Environmental Protection, is a decision-support tool for estimating daily unaltered streamflow and sustainable water use at ungaged sites in Connecticut. The CT SSWUE estimates unaltered daily mean streamflow and water-use-adjusted streamflow for the period from October 1, 1960, to September 30, 2015, and the monthly sustainable net withdrawal at ungaged sites in Connecticut. Unaltered streamflow is the estimated daily mean streamflow in a drainage basin in the absence of any water withdrawals or wastewater discharges and with minimal human development. Sustainable net withdrawal is the maximum net withdrawal (withdrawal minus wastewater discharges) that can be drawn from a basin without critically depleting the water available through natural streamflow patterns. Sustainable net withdrawal is defined for this study as the difference between the unaltered daily mean streamflow and a user-defined target minimum streamflow. Weighted least squares and Tobit regression techniques were used to develop equations for estimating streamflow at ungaged sites at 19 streamflow quantiles with exceedance probabilities ranging from 0.005 to 99.995 percent. Regressions were based on streamflow quantiles and basin characteristics from 36 reference streamgages in and around Connecticut. Four basin characteristics—drainage area, mean of the soil permeability, mean of the average annual precipitation, and ratio of the length of streams that overlay sand and gravel deposits to the total length of streams in the basin—are used as explanatory variables in the equations. At an ungaged site, interpolation between the streamflow quantiles estimated from the regression equations produces a continuous flow-duration curve. A time series of daily mean streamflow at an ungaged site is then estimated by assuming that for each day, the streamflow quantile occurs on the same date at both a reference streamgage and the ungaged site. In a remove-one cross validation, estimated unaltered daily mean streamflow agreed well with observed values at reference streamgages, with a few exceptions. Nash Sutcliffe efficiency ranged from −0.43 to 0.97 with a median value of 0.88. The normalized root-mean-square error ranged from 16.6 to 120.4 percent with a median value of 34.5 percent. An empirical method for estimating 95-percent prediction intervals for unaltered daily and monthly mean streamflow was developed and tested by using the cross-validation data. Prediction intervals for unaltered daily mean streamflow at the cross-validation reference streamgages performed well in most cases. Gaged streamflow values from the cross-validation data fell within the prediction intervals a median 96.6 percent of the time for daily mean time series and 93.9 percent of the time for monthly mean time series. The CT SSWUE computes water-use-adjusted streamflow using spatially referenced water-use information provided by the Connecticut Department of Energy and Environmental Protection. Available water-use information included permitted and registered water withdrawals and permitted wastewater discharges during 1998 to 2015 for the Thames River Basin and central coastal drainage basins. Water-use information was incorporated into the U.S. Geological Survey StreamStats web application for Connecticut and can be used for computing water-use-adjusted streamflow and sustainable net withdrawal at selected points of interest. Altered daily streamflow is computed by applying average daily withdrawals and wastewater discharges to the water balance equation. Average daily surface water withdrawals and wastewater discharges are applied directly to the daily water balance equation. Time-lagged alterations on streamflow from groundwater withdrawals or wastewater discharges are estimated by using a response-coefficient method developed from results of previously published, calibrated groundwater models.

Connecticut↗

Arsenic, Boron, and Fluoride Concentrations in Ground Water in and Near Diabase Intrusions, Newark Basin, Southeastern Pennsylvania

During an investigation in 2000 by the U.S. Environmental Protection Agency (USEPA) of possible contaminant releases from an industrial facility on Congo Road near Gilbertsville in Berks and Montgomery Counties, southeastern Pennsylvania, concentrations of arsenic and fluoride above USEPA drinking-water standards of 10 ?g/L and 4 mg/L, respectively, and of boron above the USEPA health advisory level of 600 ?g/L were measured in ground water in an area along the northwestern edge of the Newark Basin. In 2003, the USEPA requested technical assistance from the U.S. Geological Survey (USGS) to help identify sources of arsenic, boron, and fluoride in the ground water in the Congo Road area, which included possible anthropogenic releases and naturally occurring mineralization in the local bedrock aquifer, and to identify other areas in the Newark Basin of southeastern Pennsylvania with similarly elevated concentrations of these constituents. The USGS reviewed available data and collected additional ground-water samples in the Congo Road area and four similar hydrogeologic settings. The Newark Basin is the largest of the 13 major exposed Mesozoic rift basins that stretch from Nova Scotia to South Carolina. Rocks in the Newark Basin include Triassic through Jurassic-age sedimentary sequences of sandstones and shales that were intruded by diabase. Mineral deposits of hydrothermal origin are associated with alteration zones bordering intrusions of diabase and also occur as strata-bound replacement deposits of copper and zinc in sedimentary rocks. The USGS review of data available in 2003 showed that water from about 10 percent of wells throughout the Newark Basin of southeastern Pennsylvania had concentrations of arsenic greater than the USEPA maximum contaminant level (MCL) of 10 ?g/L; the highest reported arsenic concentration was at about 70 ?g/L. Few data on boron were available, and the highest reported boron concentration in well-water samples was 60 ?g/L in contrast to concentrations over 5,000 ?g/L in the Congo Road area. Although concentrations of fluoride up to 4 mg/L were reported for a few well-water samples collected throughout the Newark Basin, about 90 percent of the samples had concentrations of 0.5 mg/L or less. The USGS sampled 58 wells primarily in 5 areas in the Newark Basin, southeastern Pennsylvania, from February 2004 through April 2005 to identify other possible areas of elevated arsenic, boron, and fluoride and to characterize the geochemical environment associated with elevated concentrations of these constituents. Sampled wells included 12 monitor wells at an industrial facility near Congo Road, 45 private-supply wells in Berks, Montgomery, and Bucks Counties, and 1 private-supply well near Dillsburg, York County, an area where elevated fluoride in ground water had been reported in the adjacent Gettysburg Basin. Wells were sampled in transects from the diabase through the adjacent hornfels and into the unaltered shales of the Brunswick Group. Field measurements were made of pH, temperature, dissolved oxygen concentration, and specific conductance. Samples were analyzed in the laboratory for major ions, nutrients, total organic carbon, dissolved and total concentrations of selected trace elements, and boron isotopic composition. Generally, the ground water from the 46 private-supply wells had relatively neutral to alkaline pH (ranging from 6.1 to 9.1) and moderate concentrations of dissolved oxygen. Most water samples were of the calcium-bicarbonate type. Concentrations of arsenic up to 60 ?g/L, boron up to 3,950 ?g/L, and fluoride up to 0.70 mg/L were measured. Drinking-water standards or health advisories (for constituents that do not have standards established) were exceeded most frequently (about 20 percent of samples) for arsenic and boron and less frequently (6 percent or less of samples) for total iron, manganese, sulfate, nitrate, lead, molybdenum, and strontium. In water from 12 monitor

Scientific Investigations Report↗