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USGS1998

Occurrence of pesticides in shallow groundwater of the United States: initial results from the National Water-Quality Assessment program

The first phase of intensive data collection for the National Water-Quality Assessment (NAWQA) was completed during 1993−1995 in 20 major hydrologic basins of the United States. Groundwater land-use studies, designed to sample recently recharged groundwater (generally within 10 years) beneath specific land-use and hydrogeologic settings, are a major component of the groundwater quality as sessment for NAWQA. Pesticide results from the 41 land-use studies conducted during 1993−1995 indicate that pesticides were commonly detected in shallow groundwater, having been found at 54.4% of the 1034 sites sampled in agricultural and urban settings across the United States. Pesticide concentrations were generally low, with over 95% of the detections at concentrations less than 1 μg/L. Of the 46 pesticide compounds examined, 39 were detected. The compounds detected most frequently were atrazine (38.2%), deethylatrazine (34.2%), simazine (18.0%), metolachlor (14.6%), and prometon (13.9%). Statistically significant relations were observed between frequencies of detection and the use, mobility, and persistence of these compounds. Pesticides were commonly detected in both agricultural (56.4%; 813 sites) and urban (46.6%; 221 sites) settings. Frequent detections of pesticides in urban areas indicate that, as is the case with agricultural pesticide use in agricultural areas, urban and suburban pesticide use significantly contribute to pesticide occurrence in shallow groundwater. Although pesticides were detected in groundwater sampled in urban areas and all nine of the agricultural land-use categories examined, significant variations in occurrence were observed among these categories. Maximum contaminant levels (MCLs) established by the U.S. Environmental Protection Agency for drinking water were exceeded for only one pesticide (atrazine, 3 μg/L) at a single location. However, MCLs have been established for only 25 of the 46 pesticide compounds examined, do not cover pesticide degradates, and, at present, do not take into account additive or synergistic effects of combinations of pesticide compounds or potential effects on nearby aquatic ecosystems.

Environmental Science & Technology↗

USGS2025

Potential for biological effects of per- and polyfluoroalkyl substances in Great Lakes tributaries and associations with land cover and wastewater effluent

Surface water concentrations of per- and polyfluoroalkyl substances (PFAS) and potential for resulting biological effects were estimated in a study using polar organic chemical integrative samplers (POCIS) from 60 tributary sites within 20 watersheds in the Great Lakes Basin in 2018. Sites represented a range of urban to agricultural, forested, and wetland land uses and included a gradient of wastewater treatment effluent from zero to 44% of annual streamflow. Several sites also had airport influence. Twenty-one of 32 targeted PFAS compounds were detected in POCIS samplers, of which, 16 had available POCIS sampling rates, enabling time-weighted water concentration estimates and comparison with available effects data. Estimated water concentrations were compared with published water quality guidelines (available for nine PFAS), effect concentrations reported in primary literature within the ECOTOX Knowledgebase for apical endpoints (10 PFAS) and nonapical endpoints (10 PFAS), and in vitro high-throughput screening data from the U.S. Environmental Protection Agency Toxicity Forecaster (ToxCast; 14 PFAS). Based on a conservative evaluation approach that was also weighted for persistence and limitations in available toxicological information, five individual PFAS, including perfluorooctanesulfonic acid, perfluorohexanesulfonic acid, perfluorobutanesulfonic acid, perfluorooctanoic acid, and perfluorononanoic acid were identified as warranting additional investigation. Possible increased potency of PFAS mixtures over individual chemical effects, estimated by summation of exposure-activity ratios (EARs) for chemicals that influence common ToxCast assays and specified gene targets, indicated that EAR values increased up to 5.6-fold over individual chemicals, with up to 14 chemicals contributing to mixture effect predictions. Potential for biological effects from PFAS, as estimated by summed exposure-activity ratios, were correlated with urban land use and the proportion of streamflow contributed by wastewater effluent.

Great Lakes tributaries↗

USGS2024

Development and evaluation of public-supply community water service area boundaries for the conterminous United States

The water service area dataset, derived from the National Boundary Dataset for public-supply water systems in the United States, offers a detailed resolution surpassing county-level assessments, emphasizing water-centric land use. Crucial for linking populations and infrastructure to system withdrawals, it supports the creation of a national public-supply water-use model, enhancing accuracy in estimating water use and distinguishing between publicly supplied and self-supplied domestic water use. Integrating tabular water system data strengthens the national water-use model by enabling tracking of withdrawal locations, source water, and water quality. Evaluated against U.S. Census-derived population datasets, 16 state-provided water service area datasets, and two national land use datasets, the study covers 22,849 community water systems, excluding most small systems serving fewer than 1000 people. Robust correlations between water service areas (WSAs) and satellite-sourced urban and exurban land use types facilitate tracking changes over time. A comparison of state and national datasets for population and WSAs reveals discrepancies ranging from 5% to 73% in state-level populations and 0% to 167% in state-level WSAs. Significant differences can be attributed to the exclusion of sizable incorporated and unincorporated areas in the state-based datasets. Additional comparisons of major metropolitan areas exhibit differences ranging from 2% to 56%.

conterminous United States↗

USGS2016

Occupancy dynamics in human-modified landscapes in a tropical island: implications for conservation design

Aim Avian communities in human-modified landscapes exhibit varying patterns of local colonization and extinction rates, determinants of species occurrence. Our objective was to model these processes to identify habitat features that might enable movements and account for occupancy patterns in habitat matrices between the Guanica and Susua forest reserves. This knowledge is central to conservation design, particularly in ever changing insular landscapes. Location South-western Puerto Rico. Methods We used a multiseason occupancy modelling approach to quantify seasonal estimates of occupancy, and colonization and extinction rates of seven resident avian species surveyed over five seasons from January 2010 to June 2011. We modelled parameters by matrix type, expressions of survey station isolation, quality, amount of forest cover and context (embedded in forest patch). Results Seasonal occupancy remained stable throughout the study for all species, consistent with seasonally constant colonization and extinction probabilities. Occupancy was mediated by matrix type, higher in reserves and forested matrix than in the urban and agricultural matrices. This pattern is in accord with the forest affinities of all but an open-habitat specialist. Puerto Rican Spindalis ( Spindalis portoricensis ) exhibited high occupancy in the urban matrix, highlighting the adaptability of some insular species to novel environments. Highest colonization rates occurred when perching structures were at ≤ 500 m. Survey stations with at least three fruiting tree species and 61% forest cover exhibited lowest seasonal extinction rates. Main conclusions Our work identified habitat features that influenced seasonal probabilities of colonization and extinction in a human-modified landscape. Conservation design decisions are better informed with increased knowledge about interpatch distances to improve matrix permeability, and habitat features that increase persistence or continued use of habitat stepping stones. A focus on dynamic processes is valuable because conservation actions directly influence colonization and extinction rates, and thus, a quantitative means to gauge their benefit.

Puerto Rico↗

USGS2002

Water-quality data for pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999-2000

Water-quality data collected during 1999 and 2000 as part of the first nationwide reconnaissance of the occurrence of pharmaceuticals, hormones, and other organic wastewater contaminants (OWCs) are presented in this report. A network of 139 streams in 30 states were sampled and analyzed for 95 different OWCs using five new research methods developed by the U.S. Geological Survey. Site selection was biased toward streams more susceptible to OWC contamination because of proximity to urban areas or livestock production. At least one OWC was detected in 80% of the streams sampled, with 82 of the 95 analyzed OWCs determined in this study detected in at least one sample.

Open-File Report↗

USGS2009

Long-Term Stage, Stage-Residual, and Width Data for Streams in the Piedmont Physiographic Region, Georgia

This report presents the data used to assess geomorphic adjustment of streams over time and to changing land-use conditions. Thirty-seven U.S. Geological Survey streamgages were selected within the Piedmont physiographic region of Georgia. Width, depth, stage, and discharge data from these streams were analyzed to assess channel stability and determine if systematic adjustments of channel morphology could be related to time or land use and land cover. Residual analyses of stage-discharge data were used to infer channel stability, which could then be used as an indicator of habitat stability. Streamgages, representing a gradient of urbanization, were selected to test hypotheses regarding stream stability and adjustment to urban conditions. Results indicate that 14 sites exhibited long-term channel stability, 11 were degrading, 6 were aggrading, and 6 showed variability in response over the study period.

Georgia↗

USGS2017

Factors affecting marsh vegetation at the Liberty Island Conservation Bank in the Cache Slough region of the Sacramento–San Joaquin Delta, California

The Liberty Island Conservation Bank (LICB) is a tidal freshwater marsh restored for the purpose of mitigating adverse effects on sensitive fish populations elsewhere in the region. The LICB was completed in 2012 and is in the northern Cache Slough region of the Sacramento–San Joaquin Delta. The wetland vegetation at the LICB is stunted and yellow-green in color (chlorotic) compared to nearby wetlands. A study was done to investigate three potential causes of the stunted and chlorotic vegetation: (1) improper grading of the marsh plain, (2) pesticide contamination from agricultural and urban inputs upstream from the site, (3) nitrogen-deficient soil, or some combination of these. Water samples were collected from channels at five sites, and soil samples were collected from four wetlands, including the LICB, during the summer of 2015. Real-time kinematic global positioning system (RTK-GPS) elevation surveys were completed at the LICB and north Little Holland Tract, a closely situated natural marsh that has similar hydrodynamics as the LICB, but contains healthy marsh vegetation. The results showed no significant differences in carbon or nitrogen content in the surface soils or in pesticides in water among the sites. The elevation survey indicated that the mean elevation of the LICB was about 26 centimeters higher than that of the north Little Holland Tract marsh. Because marsh plain elevation largely determines the hydroperiod of a marsh, these results indicated that the LICB has a hydroperiod that differs from that of neighboring north Little Holland Tract marsh. This difference in hydroperiod contributed to the lower stature and decreased vigor of wetland vegetation at the LICB. Although the LICB cannot be regraded without great expense, it could be possible to reduce the sharp angle of the marsh edge to facilitate deeper and more frequent tidal flooding along the marsh periphery. Establishing optimal elevations for restored wetlands is necessary for obtaining the full suite of ecosystem services provided by tidal wetlands. A better system of tidal benchmarks throughout the delta is needed to help restoration practitioners correctly grade the elevation of newly restored wetlands.

California↗

USGS2016

Historical water-quality data from the Harlem River, New York

Data specific to the Harlem River, New York, have been summarized and are presented in this report. The data illustrate improvements in the quality of water for the past 65 years and emphasize the importance of a continuous water-quality record for establishing trends in environmental conditions. Although there is a paucity of sediment-quality data, the New York City Department of Environmental Protection (NYCDEP) Bureau of Wastewater Treatment has maintained a water-quality monitoring network in the Harlem River (and throughout the harbor of New York City) to which 61 combined sewer outfalls discharge effluent. In cooperation with the NYCDEP, the U.S. Geological Survey evaluated water-quality data collected by the NYCDEP dating back to 1945, which indicate trends in water quality and reveal improvement following the 1972 passage of the Clean Water Act. These improvements are indicated by the steady increase in median dissolved oxygen concentrations and an overall decrease in fecal indicator bacteria concentrations starting in the late 1970s. Further, the magnitude of the highest fecal indicator bacteria concentrations (that is, the 90th percentile) in samples collected from the Harlem River have decreased significantly over the past four decades. Other parameters of water quality used to gauge the health of a water body include total suspended solids and nutrient (inorganic forms of nitrogen and phosphorus) concentrations—mean concentrations for these indicators have also decreased in the past decades. The limited sediment data available for one sample in the Harlem River indicate concentrations of copper, zinc, and lead are above sediment-quality thresholds set by the New York State Department of Environmental Conservation. However, more data are needed to better understand the changes in both sediment and water quality in the Harlem River, both as the tide cycles and during precipitation events. As a partner in the Urban Waters Federal Partnership, the U.S. Geological Survey has worked to address the chronic water-quality concerns of the Harlem River by compiling relevant data and studies, which is an important component for understanding and rectifying water-quality problems within a watershed.

New York↗

USGS2018

Geomorphic characteristics of Tenmile Creek, Montgomery County, Maryland, 2014–16

Data collected from April 2014 through September 2016 were used to assess geomorphic characteristics and geomorphic changes over time in a selected reach of Tenmile Creek, a small rural watershed near Clarksburg, Maryland. Longitudinal profiles of the channel bed, water surface, and bank features were developed from field surveys. Changes in cross-section geometry between field surveys were documented. Grain-size distributions for the channel bed were developed from pebble counts. Continuous-record streamflow and precipitation data were also collected in the Tenmile Creek watershed and used to supplement the geomorphic analyses. The Rosgen system of stream classification was used to classify the stream channel according to morphological measurements of slope, entrenchment ratio, width-to-depth ratio, sinuosity, and median particle diameter of the channel materials. Boundary shear stress near the U.S. Geological Survey (USGS) streamflow-gaging station was assessed by using hydraulic variables computed from the cross-section surveys and slope measurements derived from crest-stage gages and temporary data loggers installed along the study reach. Analysis of the longitudinal profiles indicated relatively small changes in the percentage and distribution of riffles, pools, and runs in the study reach between April 2014 and March 2015. More noticeable changes were observed during surveys conducted in March 2016 and September 2016. The channel-bed slope showed a net reduction over time from 0.0072 to 0.0040 feet per foot (ft/ft). The low-flow water-surface slope also showed a net reduction over time from 0.0065 to 0.0045 ft/ft. Net aggradation in the lower section of the study reach combined with net degradation in the upper section of the study reach contributed to the net reduction in channel-bed and water-surface slope. The large storm and resulting flood on July 30, 2016 was a major factor in observed changes in the longitudinal profiles between the March 2016 and September 2016 surveys. Comparison of data from the cross-sectional surveys indicated vertical changes in all cross sections, with more extreme changes observed between surveys in the lower section of the study reach due in part to alternating periods of net storage and transport of sand. Lateral erosion was not a major factor in the study reach, with the exception of cross section Dd, where considerable lateral erosion was documented during the study period. The flood that resulted from the large storm on July 30, 2016 was a major factor in some of the vertical changes observed in the channel bed of the study reach cross sections. Particle-size analyses of the channel bed from pebble counts indicated median particle diameters ranging from 15.5 millimeters (mm) to 23.1 mm, which is characterized as medium to coarse gravel. Sand percentages ranging from 3.4 percent to 16.4 percent of the total counts were observed over time. Net increases in storage of fine sediment in the reach were observed between April 2014 and March 2016, and a considerable reduction in storage was observed between March 2016 and September 2016. The Tenmile Creek stream channel was classified as a C4 channel, based on morphological descriptions from the Rosgen system of stream classification. The C4 classification describes a single-thread channel with a slight entrenchment ratio; a moderate to high width-to-depth ratio; moderate to high sinuosity; a water-surface slope of less than 2 percent; and a median particle diameter in the gravel range of 2 to 64 mm. The analysis of boundary shear stress indicated a range of 0.35 to 1.18 pounds per square foot for instantaneous streamflow ranging from 79 to 2,860 cubic feet per second during the study period. The relation between discharge and boundary shear stress for Tenmile Creek was compared to similar relations that were previously developed for Minebank Run, a small, urban watershed in the eastern section of the Piedmont Physiographic Province in Baltimore County, Md. that was physically restored during 2004–05. The comparison indicated a much flatter slope in the relation for Minebank Run in both its unrestored and restored conditions. This difference in the relations indicates that the erosive power in the urban watershed of Minebank Run is much more sensitive to increases in discharge magnitude than in the non-urban watershed of Tenmile Creek.

Maryland↗

USGS2003

Nutrients in Shallow Ground Waters Beneath Relatively Undeveloped Areas in the Conterminous United States

Nutrient concentrations in shallow (well depth of 30 meters or less) ground waters of relatively undeveloped areas were evaluated to determine background conditions relative to agricultural and urban land uses. Lands comprising 67 percent or greater forest or range, 10 percent or less agricultural land, and 10 percent or less urban land were used to represent relatively undeveloped areas. Data subsets from the U.S. Geological Survey's National Water-Quality Assessment Program (81 wells) and retrospective studies (320 wells) yielded 75th percentile nitrate concentrations of 0.51 and 1.1 milligrams per liter, respectively, in shallow ground water beneath relatively undeveloped areas. The value of 1.1 milligrams per liter is a reasonable upper bound estimate of relative background concentration of nitrate in shallow ground waters in the United States and incorporates effects of nominal nitrogen load to susceptible aquifers. Relative background concentration of nitrate is variable and depends in part on land use, rock type, and climate. Median nitrate concentration was significantly greater in ground water beneath rangeland (1.20 milligrams per liter) than beneath forest land (0.06 milligram per liter). Median nitrate concentration in ground water beneath rangeland was 1.4-2.7 milligrams per liter in susceptible aquifers, which consist of coarse-textured deposits or fractured rock. Increased relative background concentration of nitrate in rangeland areas likely results from evaporative concentration of nominal nitrogen load associated with natural organic and inorganic sources in hydrogeologically susceptible settings.

Water-Resources Investigations Report↗

USGS2008

Quality of Shallow Ground Water in Three Areas of Unsewered Low-Density Development in Wyoming and Montana, 2001

The quality of shallow ground water underlying unsewered low-density development outside of Sheridan and Lander, Wyo., and Red Lodge, Mont., was evaluated. In 2001, 29 wells (10 each in Sheridan and Lander and 9 in Red Lodge) were installed at or near the water table and sampled for a wide variety of constituents to identify potential effects of human activities on shallow ground-water quality resulting from development on the land surface. All wells were completed in unconfined aquifers in unconsolidated deposits of Quaternary age with shallow water tables (less than 50 feet below land surface). Land use and land cover was mapped in detail within a 500-meter radius surrounding each well, and potential contaminant sources were inventoried within the radii to identify human activities that may affect shallow ground-water quality. This U.S. Geological Survey National Water-Quality Assessment ground-water study was conducted to examine the effects of unsewered low-density development that often surrounds cities and towns of many different sizes in the western United States?a type of development that often is informally referred to as ?exurban? or ?rural ranchette? development. This type of development has both urban and rural characteristics. Residents in these developments typically rely on a private ground-water well for domestic water supply and a private septic system for sanitary waste disposal. Although the quality of shallow ground water generally was suitable for domestic or other uses without treatment, some inorganic constituents were detected infrequently in ground water in the three study areas at concentrations larger than U.S. Environmental Protection Agency drinking-water standards or proposed standards. Natural factors such as geology, aquifer properties, and ground-water recharge rates likely influence most concentrations of these constituents. These inorganic constituents generally occur naturally in the study areas and were more likely to limit suitability of water for drinking or other intended uses rather than any constituents suspected of being introduced as a result of human activities. Effects of human activities associated with low-density development, such as septic systems; fertilizer and pesticide use on pastures, lawns and gardens; manure from horses, cattle, and pets; and increases in road construction and vehicular traffic, were minimal at the time of sampling (2001) but were apparent in the presence of a few types of constituents in shallow ground water. Concentrations of nitrate generally were less than a national background level (1.1 milligrams per liter) assumed to indicate effects from human activities. Total coliform bacteria were detected infrequently (in samples from three wells), and Escherichia coli were not detected in samples from a subset of wells. Trace concentrations of methylene blue active substances (ingredients in laundry detergents) were detected at concentrations slightly greater than laboratory reporting levels in samples from 11 wells, but it is unclear if the detections are indicative of natural sources or possible aquifer contamination from septic-tank effluent. Pesticides were detected in both the Sheridan and Lander, Wyo., study areas. Volatile organic compounds were detected very infrequently in all three study areas. Most pesticides and volatile organic compounds were found in water from a few wells in each study area, and commonly as mixtures. The primary exception to this generalization was the relatively widespread detection of the pesticide prometon at trace levels in the Sheridan and Lander study areas. Concentrations of pesticides and volatile organic compounds generally were small and always were smaller than applicable drinking-water standards. Detections of all constituents indicating possible human effects on shallow ground-water quality were consistent with overlying land use mapped during the study, and potential sources of contamination inventoried du

Scientific Investigations Report↗

USGS2007

Biological conditions in streams of Johnson County, Kansas, and nearby Missouri, 2003 and 2004

Johnson County is one of the fastest growing and most populated counties in Kansas. Urban development affects streams by altering stream hydrology, geomorphology, water chemistry, and habitat, which then can lead to adverse effects on fish and macroinvertebrate communities. In addition, increasing sources of contaminants in urbanizing streams results in public-health concerns associated with exposure to and consumption of contaminated water. Biological assessments, or surveys of organisms living in aquatic environments, are crucial components of water-quality programs because they provide an indication of how well water bodies support aquatic life. This fact sheet describes current biological conditions of Johnson County streams and characterizes stream biology relative to urban development. Biological conditions were evaluated by collecting macroinvertebrate samples from 15 stream sites in Johnson County, Kansas, in 2003 and 2004 (fig. 1). Data from seven additional sites, collected as part of a separate study with similar objectives in Kansas and Missouri (Wilkison and others, 2005), were evaluated to provide a more comprehensive assessment of watersheds that cross State boundaries. Land-use and water- and streambed-sediment-quality data also were used to evaluate factors that may affect macroinvertebrate communities. Metrics are indices used to measure, or evaluate, macroinvertebrate response to various factors such as human disturbance. Multimetric scores, which integrated 10 different metrics that measure various aspects of macroinvertebrate communities, including organism diversity, composition, tolerance, and feeding characteristics, were used to evaluate and compare biological health of Johnson County streams. This information is useful to city and county officials for defining current biological conditions, evaluating conditions relative to State biological criteria, evaluating effects of urbanization, developing effective water-quality management plans, and documenting changes in biological conditions and water quality.

Kansas, Missouri↗

USGS2010

Effects of selected low-impact-development (LID) techniques on water quality and quantity in the Ipswich River Basin, Massachusetts: Field and modeling studies

During the months of August and September, flows in the Ipswich River, Massachusetts, dramatically decrease largely due to groundwater withdrawals needed to meet increased residential and commercial water demands. In the summer, rates of groundwater recharge are lower than during the rest of the year, and water demands are higher. From 2005 to 2008, the U.S. Geological Survey, in a cooperative funding agreement with the Massachusetts Department of Conservation and Recreation, monitored small-scale installations of low-impact-development (LID) enhancements designed to diminish the effects of storm runoff on the quantity and quality of surface water and groundwater. Funding for the studies also was contributed by the U.S. Environmental Protection Agency’s Targeted Watersheds Grant Program through a financial assistance agreement with Massachusetts Department of Conservation and Recreation. The monitoring studies examined the effects of (1) replacing an impervious parking lot surface with a porous surface on groundwater quality, (2) installing rain gardens and porous pavement in a neighborhood of 3 acres on the quantity and quality of stormwater runoff, and (3) installing a 3,000-square foot (ft2) green roof on the quantity and quality of stormwater runoff. In addition, the effects of broad-scale implementation of LID techniques, reduced water withdrawals, and water-conservation measures on streamflow in large areas of the basin were simulated using the U.S. Geological Survey’s Ipswich River Basin model. From June 2005 to 2007, groundwater quality was monitored at the Silver Lake town beach parking lot in Wilmington, MA, prior to and following the replacement of the conventional, impervious-asphalt surface with a porous surface consisting primarily of porous asphalt and porous pavers. Changes in the concentrations of the water-quality constituents, phosphorus, nitrogen, cadmium, chromium, copper, lead, nickel, zinc, and total petroleum hydrocarbons, were monitored. Increased infiltration of precipitation did not result in discernible increases in concentrations of these potential groundwater contaminants. Concentrations of dissolved oxygen increased slightly in groundwater profiles following the removal of the impervious asphalt parking lot surface. In Wilmington, MA, in a 3-acre neighborhood, stormwater runoff volume and quality were monitored to determine the ability of selected LID enhancements (rain gardens and porous paving stones) to reduce flows and loads of the above constituents to Silver Lake. Flow-proportional water-quality samples were analyzed for nutrients, metals, total petroleum hydrocarbons, and total-coliform and Escherichia coli bacteria. In general, when all storms were considered, no substantial decreases were observed in runoff volume as a result of installing LID enhancements. However, the relation between rainfall and runoff did provide some insight into how the LID enhancements affected the effective impervious area for the neighborhood. A decrease in runoff was observed for storms of 0.2 inches (in.) or less of precipitation, which indicated a reduction in effective impervious area from approximately 10 percent to about 4.5 percent for the 3-acre area. Water-quality-monitoring results were inconclusive; there were no statistically significant differences in concentrations or loads when the pre- and post-installation-period samples were compared. Three factors were probably most important in minimizing differences: (1) the small decrease in effective impervious area, (2) the differences in the size of storms sampled for water-quality constituents before and after installation of the infiltration enhancing measures, and (3) small sample sizes. In a third field study, the characteristics of runoff from a vegetated “green” roof and a conventional, rubber-membrane roof were compared. The amount of precipitation and the length of the antecedent dry period were the two primary factors affecting the green roof’s water-storage capacity. The green roof retained more than 50 percent of the precipitation from storms with 0.04 to 1.0 in. of rain. Approximately 95 percent of the precipitation from one storm of nearly 2 in. was retained by the green roof. On the rubber-membrane roof, only a small, shallow puddle of insubstantial volume ever remained after a storm. Bulk precipitation from 10 storms was monitored for the same constituents (nutrients, metals, and total petroleum hydrocarbons) as the roof runoff, and the results were compared with those for roof-runoff samples. The use of fertilizers to help establish the vegetation during the study probably distorted any effect the plants and growing medium may have had on the retention of target analytes. As a result of the fertilizer and growing medium chemistry, median concentrations of total nitrogen, total phosphorus, cadmium, copper, and nickel in runoff from the green roof were greater than in the runoff from the conventional roof or in bulk precipitation. Concentrations of lead and zinc were greater in runoff from the conventional roof, probably a result of passage through the old, metal drainpipes. Simulations of the effects of LID on streamflow in the Ipswich River Basin were conducted with a previously calibrated Hydrological Simulation Program-FORTRAN (HSPF) precipitation-runoff model. Simulations were conducted at multiple spatial scales to evaluate the effects of (1) updated water withdrawals for the towns of Reading and Wilmington; (2) potential land-use changes at buildout (potential future development); (3) effective impervious area reductions upstream from the South Middleton streamgage to represent the effects of widespread implementation of LID retrofit techniques; (4) basin-scale water withdrawal reductions scaled up (expanded to the town level) from water-conservation pilot programs conducted by the Massachusetts Department of Conservation and Recreation; and (5) land-use change and LID techniques at a local scale, which is smaller than the HSPF subbasin. Effects on streamflow generally were evaluated by comparing results of two or more related simulations for selected reaches in the basin; thus, relative rather than absolute changes in simulated flow were the focus of the assessment. Simulations indicated that reduced withdrawals for the towns of Reading and Wilmington led to substantially higher medium and low flows in most of the reaches upstream from the South Middleton streamgage. Simulations of water-conservation measures resulted in negligible effects on streamflow. Overall, simulations indicated that spatial scale is an important factor in determining the effects of land-use change and LID practices on streamflow. Potential land-use changes at buildout had modest (percent differences of less than 20 percent) effects on streamflow in most subbasins because relatively little land in the basin was available for development (about 17 percent); moreover, most of the available open land is zoned for low-density residential development, and this land-use category was simulated to contain relatively little effective impervious area and to be similar hydrologically to the forested land in place prior to development. Results of the simulations conducted to evaluate widespread effective impervious area reductions upstream from the South Middleton streamgage indicated that the percentage of urban land use and associated effective impervious area was too small for a 50-percent reduction of effective impervious area to appreciably affect streamflow (percent differences of less than 20 percent) in most subbasins. In contrast, the results of the hypothetical local-scale simulations indicated that for smaller streams, where the percentage of urban land use and associated effective impervious area in the drainage area may be substantially higher, land-use change, development patterns, and LID practices potentially have much greater effects on streamflow. Modeling results also indicated that LID was potentially most beneficial for minimizing streamflow alteration when applied to dense urban development, largely because larger tracts of effective impervious area were available for reduction than were available for other land-use categories. For example, commercial-industrial-transportation land use is composed of 37 percent pervious area and 63 percent effective impervious area in the HSPF model, whereas low-density residential area is composed of 97.5 percent pervious area and only 2.5 percent effective impervious area. Field and modeling studies concurred in the assessment that LID enhancements would likely have the greatest effect on decreasing stormwater runoff when broadly applied to highly impervious urban areas. A measurable effect for small rainfall events (less than 0.25 inch) was determined in the small, highly pervious area that was monitored in this study, but the volume difference was not great.

Massachusetts↗

USGS2024

Intra-urban variations in land surface phenology in a semi-arid environment

Urban vegetation is growing in importance as cities use 'green infrastructure' to mitigate the impacts of climate change, reduce extreme heat, and improve human health and comfort. However, due to the heterogeneity of city landscapes, urban vegetation experiences a diverse range of environmental conditions, potentially leading to differences in growing season timing and length within cities. Here, we investigate physical drivers of urban land surface phenology and timing within a semi-arid city (Denver, CO, USA) using four years (2018–2021) of remotely sensed vegetation indices, modelled air temperature, and land cover datasets. Within the metropolitan region study area, satellite-based vegetation index measurements indicate that growing season length is variable on sub-neighborhood spatial scales. This variability is largely due to differences in the timing of fall senescence, as opposed to early season growth. Areas with substantial fractions of irrigated land cover tend to remain greener for longer, while unirrigated and cooler areas are correlated with an earlier end to the growing season (up to ∼two months shorter). These findings complement those from non-arid cities where surface and air temperature are the dominant environmental control on phenological timing. Results here indicate the importance of soil moisture for phenology in semi-arid regions and suggest unique semi-arid urban growing season dynamics and temperature-vegetation feedbacks. These interactions have implications for water, heat, and vegetation management strategies to maximize ecosystem services in water-limited environments.

Colorado↗

USGS1990

Hydrogeology of the Cliff House Sandstone in the San Juan structural basin, New Mexico, Colorado, Arizona, and Utah

This report is one in a series resulting from the U.S. Geological Survey's Regional Aquifer-System Analysis (RASA) study of the San Juan structural basin that began in October 1984. Previous reports in the series describe the hydrogeology of the Dakota Sandstone (Craigg and others, 1989), Point Lookout Sandstone (Craigg and others, 1990), Morrison Formation (Dam and others, 1990), Gallup Sandstone (Kernodle and others, 1989), and Menefee Formation (Levings and others, 1990) in the San Juan structural basin. The purposes of the RASA (Welder, 1986) are to: (1) Define and evaluate the aquifer system; (2) assess the effects of past, present, and potential ground-water use on aquifers and streams; and (3) determine the availability and quality of ground water. This report summarizes information on the geology and the occurrence and quality of water in the Cliff House Sandstone, one of the primary water-bearing units in the regional aquifer system. Data used in this report were collected during the study or were derived from existing records in the U.S. Geological Survey's computerized National Water Information System (NWIS) data base, the Petroleum Information Corporation's data base, and the Dwight's ENERGYDATA Inc. BRIN data base. Although all data available for the Cliff House Sandstone were considered in formulating the discussions in the text, not all those data could be plotted on the illustrations. The San Juan structural basin is in New Mexico, Colorado, Arizona, and Utah and has an area of about 21,600 square miles (fig. 1). The structural basin is about 140 miles wide and about 200 miles long. The study area is that part of the structural basin that contains rocks of Triassic or younger age and, therefore, is less extensive than the structural basin. Triassic through Tertiary sedimentary rocks are emphasized in this study because the major aquifers in the basin are present in these rocks. The study area is about 140 miles wide (about the same as the structural basin), 180 miles long, and has an area of about 19,400 square miles. Altitudes in the study area range from about 4,500 feet in San Juan County, Utah, to about 11,000 feet in Cibola County, New Mexico. Annual precipitation in the high mountainous areas along the north and east margins of the basin is as much as 45 inches, whereas annual precipitation in the lower altitude, central basin is generally less than 8 inches. Mean annual precipitation in the study area is about 12 inches. Data obtained from documents published by the U.S. Bureau of the Census, 1980 and 1985, were used to estimate the population of the study area. The population of the study area in 1970 was estimated to be about 134,000. The population rose to about 194,000 in 1980, 212,000 in 1982, 221,000 in 1984, and then fell to about 210,000 in 1985. The economy of the basin is supported by exploration and development of petroleum, natural gas, coal, and uranium resources; urban enterprise, farming and ranching; tourism; and recreation. The rise and fall in population were related to changes in the economic strength of the mining, petroleum, and natural-gas industries, and support services. Uranium mining and milling activities grew rapidly until the late 1970's when most uranium-mining activity ended in the study area. Likewise, the oil and gas industry prospered until about 1983 and then declined rapidly, also affecting many jobs in support industries.

Arizona, Colorado, New Mexico, Utah↗

USGS1990

Hydrogeology of the Point Lookout Sandstone in the San Juan structural basin, New Mexico, Colorado, Arizona, and Utah

This report is one in a series resulting from the U.S. Geological Survey's Regional Aquifer-System Analysis (RASA) study of the San Juan structural basin that began in October 1984. Previous reports in the series describe the hydrogeology of the Dakota Sandstone (Craigg and others, 1989), Morrison Formation (Dam and others, 1990), Gallup Sandstone (Kernodle and others, 1989), Menefee Formation (Levings and others, 1990), and Cliff House Sandstone (Thorn and others, 1990), in the San Juan structural basin. The purposes of the RASA (Welder, 1986) are to: (1) Define and evaluate the aquifer system; (2) assess the effects of past, present, and potential ground-water use on aquifers and streams; and (3) determine the availability and quality of ground water. This report summarizes information on the geology and the occurrence and quality of water in the Point Lookout Sandstone, one of the primary water-bearing units in the regional aquifer system. Data used in this report were collected during the study or were derived from existing records in the U.S. Geological Survey's computerized National Water Information System (NWIS) data base, the Petroleum Information Corporation's database, and the Dwight's ENERGYDATA Inc. BRIN data base. Although all data available for the Point Lookout Sandstone were considered in formulating the discussions in the text, not all those data could be plotted on the illustrations. The San Juan structural basin is in New Mexico, Colorado, Arizona, and Utah and has an area of about 21,600 square miles (fig. 1). The structural basin is about 140 miles wide and about 200 miles long. The study area is that part of the structural basin that contains rocks of Triassic or younger age and, therefore, is less areally extensive than the structural basin. Triassic through Tertiary sedimentary rocks are emphasized in this study because the major aquifers in the basin are present in these rocks. The study area is about 140 miles wide (about the same as the structural basin), 180 miles long, and has an area of about 19,400 square miles. Altitudes in the study area range from about 4,500 feet in San Juan County, Utah, to about 11,000 feet in Cibola County, New Mexico. Annual precipitation in the high mountainous areas along the north and east margins of the basin is as much as 45 inches, whereas annual precipitation in the lower altitude, central basin is generally less than 8 inches. Mean annual precipitation in the study area is about 12 inches. Data obtained from documents published by the U.S. Bureau of the Census, 1980 and 1985, were used to estimate the population of the study area. The population of the study area in 1970 was estimated to be about 134,000. The population rose to about 194,000 in 1980, 212,000 in 1982, 221,000 in 1984, and then fell to about 210,000 in 1985. The economy of the basin is supported by exploration and development of petroleum, natural gas, coal, and uranium resources; urban enterprise, farming "and ranching; tourism; and recreation. The rise and fall in population were related to changes in the economic strength of the mining, petroleum, and natural-gas industries, and support services. Uranium mining and milling activities grew rapidly until the late 1970's when most uranium-mining activity ended in the study area. Likewise, the oil and gas industry prospered until about 1983 and then declined rapidly, also affecting many jobs in support industries.

Arizona, Colorado, New Mexico, Utah↗

USGS2016

Development of ion-exchange collectors for monitoring atmospheric deposition of inorganic pollutants in Alaska parklands

Between 2010 and 2014, the U.S. Geological Survey completed a series of laboratory and field experiments designed to develop methodology to support the National Park Service’s long-term atmospheric pollutant monitoring efforts in parklands of Arctic Alaska. The goals of this research were to develop passive sampling methods that could be used for long-term monitoring of inorganic pollutants in remote areas of arctic parklands and characterize relations between wet and dry deposition of atmospheric pollutants to that of concentrations accumulated by mosses, specifically the stair-step, splendid feather moss, Hylocomium splendens. Mosses and lichens have been used by National Park Service managers as atmospheric pollutant biomonitors since about 1990; however, additional research is needed to better characterize the dynamics of moss bioaccumulation for various classes of atmospheric pollutants. To meet these research goals, the U.S. Geological Survey investigated the use of passive ionexchange collectors (IECs) that were adapted from the design of Fenn and others (2004). Using a modified IEC configuration, mulitple experiments were completed that included the following: (a) preliminary laboratory and development testing of IECs, (b) pilot-scale validation field studies during 2012 with IECs at sites with instrumental monitoring stations, and (c) deployment of IECs in 2014 at sites in Alaska having known or suspected regional sources of atmospheric pollutants where samples of Hylocomium splendens moss also could be collected for comparison. The targeted substances primarily included ammonium, nitrate, and sulfate ions, and certain toxicologically important trace metals, including cadmium, cobalt, copper, nickel, lead, and zinc. Deposition of atmospheric pollutants is comparatively low throughout most of Alaska; consequently, modifications of the original IEC design were needed. The most notable modification was conversion from a single-stage mixed-bed column to a two-stage arrangement. With the modified IEC design, ammonium, nitrate, and sulfate ions were determined with a precision of between 5 and 10 percent relative standard deviation for the low loads that happen in remote areas of Alaska. Results from 2012 field studies demonstrated that the targeted ions were stable and fully retained on the IEC during field deployment and could be fully recovered by extraction in the laboratory. Importantly, measurements of annual loads determined by combining snowpack and IEC sampling at sites near National Atmospheric Deposition Program monitoring stations was comparable to results obtained by the National Atmospheric Deposition Program. Field studies completed in 2014 included snowpack and IEC samples to measure depositional loads; the results were compared to concentrations of similar substances in co-located moss samples. Analyses of constituents in snow and IECs included ammonium, nitrate, and sulfate ions; and a suite of trace metals. Constituent measurements in Hylocomium splendens moss included total nitrogen, phosphorous, and sulfur, and trace metals. To recover ammonium ions and metal ions from the upper cation-exchange column, a two-step extraction procedure was developed from laboratory spiking experiments. The 2014 studies determined that concentrations of certain metals, nitrogen, and sulfur in tissues of Hylocomium splendens moss reflected differences in presumptive deposition from local atmospheric sources. Moss tissues collected from two sites farthest from urban locales had the lowest levels of total nitrogen and sulfur, whereas tissues collected from three of the urban sites had the greatest concentrations of many of the trace metals. Moss tissue concentrations of three trace metals (cobalt, chromium, and nickel) were strongly (positively) Spearman’s rank correlated ( p <0.05) with annual depositional loads of those metals. In addition, moss sulfur concentrations were positively rank correlated with annual depositional loads of sulfate ( p <0.07). Exploratory models indicated linear uptake of the three metals by Hylocomium splendens moss and nonlinear uptake of sulfur from sulfate. Our results provided useful preliminary models for several of the targeted substances; however, our ability to characterize relations between concentrations in moss and loadings for many of the metals was precluded by several factors. The few test sites, small concentration gradients, and generally low concentrations hampered model developments. In addition, the weather was unusually warm throughout Alaska during the winter of 2013–14, which caused intermittent melting of the snowpack at some of the test sites; consequently, our measurements of overwinter loads based on snowpack samples (obtained in late March) probably underestimated the actual loads. Regardless of these potential limitations, these studies have established a foundation to support further studies that can improve our understanding of how mosses accumulate inorganic substances and ultimately how mosses might be used as biomonitors of atmospheric pollutants; moreover, the successful development and validation of the IECs during this research documents how the methodology can be used for future monitoring efforts in remote regions of Alaska and elsewhere.

Alaska↗

USGS2012

Groundwater quality in the Columbia Plateau, Snake River Plain, and Oahu basaltic-rock and basin-fill aquifers in the Northwestern United States and Hawaii, 1992-2010

This assessment of groundwater-quality conditions of the Columbia Plateau, Snake River Plain, and Oahu for the period 1992–2010 is part of the U.S. Geological Survey’s National Water Quality Assessment (NAWQA) program. It shows where, when, why, and how specific water-quality conditions occur in groundwater of the three study areas and yields science-based implications for assessing and managing the quality of these water resources. The primary aquifers in the Columbia Plateau, Snake River Plain, and Oahu are mostly composed of fractured basalt, which makes their hydrology and geochemistry similar. In spite of the hydrogeologic similarities, there are climatic differences that affect the agricultural practices overlying the aquifers, which in turn affect the groundwater quality. Understanding groundwater-quality conditions and the natural and human factors that control groundwater quality is important because of the implications to human health, the sustainability of rural agricultural economies, and the substantial costs associated with land and water management, conservation, and regulation. The principal regional aquifers of the Columbia Plateau, Snake River Plain, and Oahu are highly vulnerable to contamination by chemicals applied at the land surface; essentially, they are as vulnerable as many shallow surficial aquifers elsewhere. The permeable and largely unconfined character of principal aquifers in the Columbia Plateau, Snake River Plain, and Oahu allow water and chemicals to infiltrate to the water table despite depths to water commonly in the hundreds of feet. The aquifers are essentially unconfined over large areas, having few extensive clay layers to impede infiltration through permeable volcanic rock and alluvial sediments. Agriculture is intensive in all three study areas, and heavy irrigation has imposed large artificial flows of irrigation recharge that rival or exceed natural recharge rates. Fertilizers and pesticides applied at land surface are leached from soil and transported to deep water tables with the infiltrating irrigation recharge, resulting in a layer of degraded water quality overlying better quality regional groundwater beneath. This “irrigation-recharge layer” is best known on Oahu, where it has been studied since the 1960s; however, the extent of nitrate and pesticide contamination in the Columbia Plateau and Snake River Plain indicate that the same situation exists in those areas. Contamination from agricultural and urban activities is present not only at shallow depths in surficial materials of the three areas, but extends regionally in the deep, principal bedrock aquifers that are tapped for drinking water by domestic and public-supply wells. Naturally occurring constituents and nitrate concentrations above human-health benchmarks—Maximum Contaminant Levels (MCLs), and Health-Based Screening Levels (HBSLs)—were more common in the Columbia Plateau and the Snake River Plain than in Oahu. Concentrations of anthropogenic constituents (constituents related to human activities) above human-health benchmarks were more common in Oahu. Naturally occurring contaminants, such as arsenic and radon, may be present in groundwater at concentrations of potential concern for human health in relatively undeveloped settings that otherwise may not be perceived as susceptible to contamination. Even though the median depth to groundwater in Oahu is more than 300 feet, the common occurrence of anthropogenic compounds in groundwater indicates that Oahu has a high susceptibility to contamination. Nitrate concentrations in groundwater were above the national background concentrations of 1 milligram per liter (mg/L) in all three study areas. In the Columbia Plateau, nitrate exceeded the human-health benchmark of 10 mg/L in 20 percent of the wells sampled. In the Snake River Plain, nitrate exceeded the human-health benchmark of 10 mg/L in 3 percent of the wells sampled. Nitrate can persist in groundwater for years and even decades in the oxygen-rich groundwater of the Columbia Plateau and the Snake River Plain, so prudent groundwater protection measures are critical to protect drinking water resources by reducing nitrate leaching from the land surface. Nitrate logistic regression models indicated that areas with a high percentage of land in crops (such as potatoes or sugarcane) and soils with low amounts of organic matter are most likely to have elevated nitrate concentrations in the groundwater. Areas where agricultural activities were absent had much lower probabilities of detecting elevated nitrate concentrations. The Columbia Plateau had a much higher probability of having elevated nitrate concentrations, with most of the land area having greater than a 50 percent probability of elevated nitrate concentrations. Oahu and the Snake River Plain had a much lower probability of having elevated nitrate concentrations because of their lower percentage of agricultural land. Pesticides were detected at many sites in groundwater of the Columbia Plateau, Snake River Plain, and Oahu but generally at low concentrations below human-health benchmarks. Atrazine and its degradate (a compound produced from the breakdown of a parent pesticide), deethylatrazine, were the most commonly detected pesticides in groundwater sampled in the Columbia Plateau and Snake River Plain. Bromacil was the most commonly detected pesticide on Oahu. The other pesticides most commonly detected in the study areas include simazine, hexazinone, metribuzin, diuron, prometon, metolachlor, p,p’ -DDE, dieldrin, 2-4-D, and alachlor. DDE (a degradate of DDT) and dieldrin are still being detected in groundwater despite having been banned for more than 30 years. Codetection of multiple pesticides in water from a single well was common. The widespread occurrence of pesticides in groundwater in the study areas indicates that the groundwater is highly susceptible to pesticide contamination. Some pesticides were detected in groundwater samples from all three study areas, but other pesticides were detected only in samples from Oahu, or only in samples from the Columbia Plateau and Snake River Plain. This is because some pesticides (such as atrazine) are broad-spectrum pesticides that are used on many crops in many different areas of the United States. Other pesticides (such as simazine, metribuzin, and metolachlor) are used on row crops (such as potatoes, barley, and alfalfa) grown in the Columbia Plateau and Snake River Plain, but not on pineapple or sugarcane grown in Oahu. Atrazine logistic-regression models indicate that areas with a high percentage of land in crops (such as potatoes or sugarcane), a low percentage of fallow land, and highly permeable soils with low amounts of organic matter are most likely to have atrazine detected in the groundwater. Areas where agricultural activities were absent had much lower probabilities of atrazine being detected. The Snake River Plain had a much higher probability of atrazine detections, with more than 50 percent of the land area having greater than a 50 percent probability of atrazine contamination. Oahu had a much lower probability of atrazine contamination, with only 24 percent of the land area having greater than a 50 percent probability of atrazine contamination. Oahu and the Columbia Plateau had some of the highest percentages of soil fumigant detections in groundwater in the United States. Soil fumigants are volatile organic compounds (VOCs) used as pesticides, which are applied to soils to reduce populations of plant parasitic nematodes (harmful rootworms), weeds, fungal pathogens, and other soil-borne microorganisms. They are used in Oahu and the Columbia Plateau on crops such as pineapple and potatoes. All three areas (Columbia Plateau, Snake River Plain, and Oahu) had fumigant concentrations exceeding human-health benchmarks for drinking water.

Hawai'i, Idaho, Nevada, Oregon, Utah, Washington, ↗