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Methods for determination of inorganic substances in water and fluvial sediments

Chapter Al of the laboratory manual contains methods used by the U.S. Geological Survey to analyze samples of water, suspended sediments, and bottom material for their content of inorganic constituents. Included are methods for determining the concentration of dissolved constituents in water, the total recoverable and total of constituents in water-suspended sediment samples, and the recoverable and total concentrations of constituents in samples of bottom material. The introduction to the manual includes essential definitions and a brief discussion of the use of significant figures in calculating and reporting analytical results. Quality control in the water-analysis laboratory is discussed, including the accuracy and precision of analyses, the use of standard-reference water samples, and the operation of an effective quality-assurance program. Methods for sample preparation and pretreatment are given also. A brief discussion of the principles of the analytical techniques involved and their particular application to water and sediment analysis is presented. The analytical methods of these techniques are arranged alphabetically by constituent. For each method, the general topics covered are the application, the principle of the method, the interferences, the apparatus and reagents required, a detailed description of the analytical procedure, reporting results, units and significant figures, and analytical precision data, when available. More than 126 methods are given for the determination of 70 inorganic constituents and physical properties of water, suspended sediment, and bottom material.

Techniques of Water-Resources Investigations↗

Associations among land-use, habitat characteristics, and invertebrate community structure in nine streams on the island of Oahu, Hawaii

The island of Oahu is one of 51 study units established as part of the U.S. Geological Surveys National Water-Quality Assessment (NAWQA) program to assess the status and trends of the Nations surface and ground-water resources, and to link status and trends with an understanding of the natural and human factors that affect water quality. As part of the NAWQA program, benthic invertebrate communities were surveyed at ten sites in nine streams representing the three main types of land use on Oahu: urban, agriculture, and forested. At each sampling site, habitat characteristics were determined at a range of spatial scales including drainage basin, segment, reach, transect, and point. Associations among land use, habitat characteristics, and benthic invertebrate community structure were examined. The rapid population growth and increasing urbanization on Oahu has resulted in substantial stream habitat alteration. Instream habitat characteristics at the urban and mixed (urban and agriculture) land-use sites were markedly different from those at the forested sites. Urban and mixed land-use sites, most of which were channelized, tended to have less riparian vegetation, higher water temperatures, smaller substrate, and higher levels of embeddedness and siltation than sites in forested watersheds. The majority of invertebrate taxa identified during this study were non-native. Invertebrate abundance was lower at urban and mixed land-use sites than at forested sites, while species richness (the number of different species) showed the opposite pattern. Multivariate analyses indicated that invertebrate species composition was similar at sites with similar land use. Aquatic insects of the orders Diptera and Trichoptera were the most common insects in all samples. The ratio of Diptera to Trichoptera abundance varied with urbanization. Forested sites were dominated by Trichoptera, and urban and mixed land-use sites were dominated by Diptera. Molluscs typically occurred in channelized urban streams although no native molluscs were collected during this study. The most abundant molluscs were pan-tropical thiarid snails, the introduced clam Corbicula fluminea, and the limpet Ferrissia sharpi. Two native and four introduced species of Crustacea were collected at the sampling sites. To effectively manage Hawaiian watersheds for native species and the communities they form, the ways in which these species respond to human-induced changes needs to be understood. This report provides important information describing the usefulness of invertebrates as indicators of stream quality conditions and how an integrated assessment of stream quality will allow for the development of appropriate monitoring and management strategies.

Water-Resources Investigations Report↗

WATEQF; a FORTRAN IV version of WATEQ : a computer program for calculating chemical equilibrium of natural waters

WATEQF is a FORTRAN IV computer program that models the thermodynamic speciation of inorganic ions and complex species in solution for a given water analysis. The original version (WATEQ) was written in 1973 by A. H. Truesdell and B. F. Jones in Programming Language/one (PL/1.) With but a few exceptions, the thermochemical data, speciation, coefficients, and general calculation procedure of WATEQF is identical to the PL/1 version. This report notes the differences between WATEQF and WATEQ, demonstrates how to set up the input data to execute WATEQF, provides a test case for comparison, and makes available a listing of WATEQF. (Woodard-USGS)

Water-Resources Investigations Report↗

Maps showing ground-water levels, springs, and depth to ground water, Basin and Range Province, Southern California

This report on ground-water levels, springs and depth to ground water in the Basin and Range province of southern California (see index map) was prepared as part of a program of the U.S. Geological Survey to identify prospective regions for further study relative to isolation of high-level nuclear waste (Bedinger, Sargent, and Reed, 1984), utilizing program guidelines defined in Sargent and Bedinger (1984). Also included in this report are selected references on pertinent geologic and hydrologic studies of the region. Other map reports in this series contain detailed data on ground-water quality, surface distribution of selected rock types, tectonic conditions, areal geophysics, Pleistocene lakes and marshes, and mineral and energy resources.

California↗

Water resources of Ponape, Caroline Islands

Ponape is the third largest island in the western Pacific, with a land area of 129 square miles. The island is volcanic, nearly circular in shape, and covered with lush tropical vegetation. The mountainous interior has the highest peaks in the western Pacific. Annual rainfall at Kolonia and other coastal areas is 191 inches. Inland at higher elevations, the rainfall is considerably higher. The upper Nanpil River basin averages about 340 inches annually. Runoff-to-rainfall ratios for Ponapean streams show that about two thirds of the rain falling on the island runs off. Flow-duration curves show the similarity of the geology, vegetation, and rainfall of the drainage basins and indicate little ground-water contribution to surface runoff. Surface-water quality is excellent as shown by 53 chemical anlyses of water from 19 streams. Water of the Nanpil River, the source of water for the central water system, is especially low in dissolved elements and solids. This report summarizes in one volume all the hydrologic data collected and provides analyses that may be used by planning and public works officials as a basis for making decisions on the development and management of their water resources. (USGS)

Water-Resources Investigations Report↗

Water-quality characteristics of urban runoff and estimates of annual loads in the Tampa Bay area, Florida, 1975-80

Rainfall, runoff, and water quality data were collected at nine urban watersheds in the Tampa Bay area from 1975 to 1980. Watershed drainage area ranged from 0.34 to 0.45 sq mi. Land use was mixed. Development ranged from a mostly residential watershed with a 19% impervious surface, to a commercial-residential watershed with a 61% impervious surface. Average biochemical oxygen demand concentrations of base flow at two sites and of stormwater runoff at five sites exceeded treated sewage effluent standards. Average coliform concentrations of stormwater runoff at all sites were several orders of magnitude greater than standards for Florida Class III receiving water (for recreation or propagation and management of fish and wildlife). Average concentrations of lead and zinc in stormwater runoff were consistently higher than Class III standards. Stormwater-runoff loads and base-flow concentrations of biochemical oxygen demand, chemical oxygen demand, total nitrogen, total organic nitrogen, total phosphorus, and lead were related to runoff volume, land use, urban development, and antecedent daily rainfall by multiple linear regression. Stormwater-runoff volume was related to pervious area, hydraulically connected impervious surfaces, storm rainfall, and soil-infiltration index. Base-flow daily discharge was related to drainage area and antecedent daily rainfall. The flow regression equations of this report were used to compute 1979 water-year loads of biochemical oxygen demand, chemical oxygen demand, total nitrogen, total organic nitrogen, total phosphorus , and total lead for the nine Tampa Bay area urban watersheds. (Lantz-PTT)

Water-Resources Investigations Report↗

Water-quality characteristics of five tributaries to the Chesapeake Bay at the Fall Line, Virginia, July 1988 through June 1993

Development in the Chesapeake Bay region has adversely affected the water quality of the Bay. The general degradation in the Bay has resulted in the decline of commercial fishing industries and has reduced the area of aquatic vegetation that provides food and habitat for fish and shellfish. In order to assess the effectiveness of programs aimed at reducing the effects of excess nutrients and suspended solids on Chesapeake Bay, it is necessary to quantify the loads of these constituents into the Bay, and to evaluate the trends in water quality. This report presents the results of a study funded by the Virginia Department of Environmental Quality Chesapeake Bay and Coastal Programs and the U.S. Geological Survey, to monitor and estimate loads of selected nutrients and suspended solids discharged to Chesapeake Bay from five major tributaries in Virginia. The water-quality data and load estimates provided in this report also will be used to calibrate computer models of Chesapeake Bay. Water-quality constituents were monitored in the James and Rappahannock Rivers over a 5-year period, and in the Pamunkey, Appomattox, and Mattaponi Rivers over a 4-year period. Water-quality samples were collected from July 1, 1988 through June 30, 1993, for the James and Rappahannock Rivers; from July 1, 1989 through June 30, 1993, for the Pamunkey and Appomattox Rivers; and from September 1,1989 through June 30, 1993, for the Mattaponi River. Water-quality samples were collected on a scheduled basis and during stormflow to cover a range in discharge conditions. Monitore water-quality constituents, for which loads were estimated include total suspended solids (residue, total at 105° Celsius), dissolved nitrite-plus-nitrate nitrogen, dissolved ammonia nitrogen, total Kjeldahl nitrogen, total nitrogen, total phosphorus, dissolved orthophosphorus, total organic carbon, and dissolved silica. Organic nitrogen concentrations were calculated from measurements of ammonia and total Kjeldahl nitrogen, and organic nitrogen loads were estimated using these calculations. Other selected water-quality constituents were monitored for which loads were not calculated. Daily mean load estimates of each constituent were computed by use of a seven-parameter log-linear regression model that uses variables of time, discharge, and seasonality. Concentration of total nitrogen ranged from less than 0.14 to 3.41 mg/L (milligrams per liter), with both extreme values occurring at the Rappahannock River. Concentration of total Kjeldahl nitrogen ranged from less than 0.1 mg/L in the James, Rappahannock, and Appomattox Rivers to 3.0 mg/L in the James River. Organic nitrogen was the predominant form of nitrogen at all stations except the Rappahannock River, where nitrite plus-nitrate nitrogen was predominant, and organic nitrogen comprised the majority of the measured total Kjeldahl nitrogen at all stations, ranging from 0.01 mg/L in the Appomattox River to 2.86 mg/L in the James River. Concentration of dissolved ammonia nitrogen ranged from 0.01 mg/L in the Pamunkey River to 0.54 mg/L at the James River. Concentration of nitrite-plusnitrate nitrogen ranged from 0.02 to 1.05 mg/L in the James River. Concentrations of total phosphorus ranged from less than 0.01 mg/L in the Rappahannock and the Mattaponi Rivers to 1.4 mg/L in the James River. Dissolved orthophosphorus ranged from less than 0.01 mg/L in all five rivers to 0.51 mg/L in the James River. Total suspended solids ranged from a concentration of less than 1 mg/L in all five rivers to 844 mg/L in the Rappahannock River. Total organic carbon ranged from 1.1 mg/L in the Appomattox River to 110 mg/L in the Rappahannock River. Dissolved silica ranged from 2.4 mg/L in the James River to 18 mg/L in the Appomattox River. The James and Rappahannock Rivers had high median concentrations and large ranges in concentrations for most constituents, probably because of a greater number of point and nonpoint sources of nutrients and suspended solids, and differences in land use when compared with the other basins. A significantly higher median concentration and greater range of dissolved orthophosphorus generally occurred at the James River than in all other rivers, which primarily is due to the greater number of point sources, such as municipal waste-water treatment plants. The Rappahannock River had significantly higher median concentrations and greater ranges of dissolved nitrite-plus-nitrate nitrogen and total nitrogen than other rivers, probably derived from agricultural sources. Total organic carbon was highest in the Mattaponi and Pamunkey River Basins that contain expanses of wetlands. The Appomattox River had the highest concentration of dissolved silica. The median monthly load of total nitrogen ranged from 16,500 kg (kilogram) in the Mattaponi River to 371,000 kg in the James River. Total Kjeldahl nitrogen ranged from a median monthly load of 12,500 kg in the Mattaponi River to 205,500 kg, also in the James River. Organic nitrogen comprised the majority of the total Kjeldahl nitrogen load in all five rivers, ranging from a median monthly load of 11,251 kg in the Mattaponi River to 3,299,500 kg in the James River. The median monthly load of dissolved ammonia nitrogen was 1,130 kg in the Mattaponi River and was as much as 21,050 kg in the James River, whereas nitrite-plus-nitrate nitrogen ranged from a median monthly load of 4,065 kg in the Mattaponi River to 156,500 kg in the James River. The median monthly load of total phosphorus ranged from 1,670 kg in the Mattaponi River to 61,600 kg in the James River, whereas the median monthly load of dissolved orthophosphorus ranged from 350 kg in the Mattaponi River to 25,900 kg in the James River. Total suspended solids ranged from a median monthly load of 241,500 kg in the Mattaponi River to 20,050,000 kg in the James River. Total organic carbon ranged from a median monthly load of 167,000 kg in the Mattaponi River to 2,100,000 kg in the James River. The median monthly load of dissolved silica ranged from 209,500 kg in the Mattaponi River to 3,625,000 kg in the James River. In general, annual loads for complete years of data collection were greatest at the James River for all constituents, probably because of the much higher discharge, greater basin size, and higher rates of runoff. Yields, or computations of loads per square mile of basin area, were generally highest at the Rappahannock River for total suspended solids, total Kjeldahl nitrogen, nitrite-plusnitrate nitrogen, and total nitrogen. Dissolved orthophosphorus was the only constituent with a yield consistently greater at the James River. Yields of total phosphorus were highest for the James and Rappahannock River basins, whereas yields of dissolved ammonia nitrogen, total organic carbon, and dissolved silica were similar for all five river basins. Quality-assurance analyses that compare the results of the Virginia Division of Consolidated Laboratory Services and the U.S. Geological Survey Laboratory indicate that there are statistically significant differences between the laboratories for several constituents. Differences between laboratories were found to be caused by differences in analytical reporting limits, differences in analytical technique, or a slight bias at both laboratories. Quality-assurance data were used to address analytical technique problems, and to qualify final concentrations and loads.

Virginia↗

Ground-water conditions in Utah, spring of 2007

This is the forty-fourth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2006. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights.utah. gov/ and http://ut.water.usgs.gov/newUTAH/GW2007.pdf.

Utah↗

Developing a state water plan: Ground-water conditions in Utah, spring of 1971

This report is the eighth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series are prepared cooperatively by the U.S. Geological Survey and the Utah Division of Water Resources and are designed to provide data to enable interested parties such as legislators, administrators, and planners to keep abreast of changing ground-water conditions. This report, like the others (see references, p. 21), contains information on well construction, ground-water withdrawals, water-level changes, and related changes in precipitation and streamflow. It also contains supplementary data that are related to ground-water use in some areas. In reports of this series, the inclusion of such supplementary data as graphs showing chemical quality of water and maps showing water-table configuration is intended only for those years or areas for which applicable data are available and are important to a discussion of changing ground-water conditions. The report includes individual discussions of the most important areas of ground-water withdrawal in the State for the calendar year 1970. Water-level fluctuations, however, are described for the period spring 1970 to spring 1971. Many of the data used in the report were collected by the Geological Survey in cooperation with the Division of Water Rights, Utah Department of Natural Resources.

Utah↗

Developing a state water plan: Ground-water conditions in Utah, spring of 1976

This report is the thirteenth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, prepared cooperatively by the U.S. Geological Survey and the Utah Division of Water Resources, provide data to enable interested parties to keep abreast of changing ground-water conditions. This report, like the others (see references, p. 16), contains information on well construction, ground-water withdrawals, water-level changes, and related changes in precipitation and streamflow. Supplementary data such as graphs showing chemical quality of water and maps showing water-table configuration are included in reports of this series only for those years or areas for which applicable data are available and are important to a discussion of changing ground-water conditions. This report includes individual discussions of selected major areas of ground-water withdrawal in the State for the calendar year 1975. Water-level fluctuations, however, are described for the period spring 1975 to spring 1976. Much of the data used in this report were collected by the U.S. Geological Survey in cooperation with the Division of Water Rights, Utah Department of Natural Resources.

Utah↗

Peak-flow variability, peak-flow informational needs, and consideration of regional regression analyses in managing the crest-stage gage network in Montana

The U.S. Geological Survey (USGS), in cooperation with the Montana Department of Transportation (MDT), has operated a crest-stage gage (CSG) network in Montana to collect peak-flow data since 1955. The CSG network is vital to collecting peak-flow data on small drainage basins that typically are not addressed by continuous streamflow operations. Discussions between USGS and MDT identified a need for evaluating the CSG network to allow for better decision making in the management of the network. The purpose of this report is to (1) generally describe peak-flow variability in Montana, (2) assess peak-flow informational needs relevant to MDT activities, and (3) consider the characteristics of the active CSG network in relation to addressing the informational needs. The evaluation of the CSG network is intended to assist in prioritization for discontinuation of CSGs and other activities involving changes to the CSG network. Peak-flow variability was investigated by analysis of selected peak-flow characteristics of 659 unregulated streamgages in or near Montana. A generalized peak-flow variability index ( PFVI ) was developed to provide large-scale representation of peak-flow variability in Montana. For unregulated Montana streamgages, PFVI generally monotonically decreases with increasing drainage area, although there is somewhat large (but generally consistent) variability about the locally weighted scatterplot smooth line. Presumably, highly variable small-scale hydroclimatic processes are integrated with increasing drainage area such that variability in many hydrologic characteristics is reduced. PFVI also decreases with increasing mean basin elevation and mean annual precipitation. Presumably, higher elevation and wetter hydroclimatic settings in Montana contribute to reduced variability in hydrologic characteristics. Intuitively, PFVI might be expected to generally decrease with increasing years of record because the standard deviation might typically be expected to decrease with increasing sample size. However, relations among PFVI and years of record are more complex and variable than drainage area, elevation, and precipitation. PFVI variably increases from 10 to about 40 years of record and then generally monotonically decreases from about 40 to about 105 years of record. Relations among PFVI and the years of record might be confounded by effects of drainage area because streamgages with long periods of record (greater than about 60 years) generally have large drainage areas (greater than about 100 square miles). The relations between PFVI and drainage area, mean basin elevation, mean annual precipitation, and years of record substantially differ among the eight hydrologic regions in Montana. As such, the PFVI relations were further investigated within each hydrologic region. A major use of peak-flow information by MDT is for design of road and highway infrastructure, including bridges, culverts, and roadside drainage ditches. As such, basin characteristics (including drainage area, mean basin elevation, and mean annual precipitation) of the Montana streamgage network (735 regulated and unregulated streamgages) were statistically investigated in relation to basin characteristics of 12,639 road and stream intersections in Montana. Both regulated and unregulated streamgages were investigated because the road and stream intersections are on both regulated and unregulated streams. Exploratory analyses indicated that the various relations substantially differ among the hydrologic regions. As such, the relations between the Montana streamgage network and the road and stream intersections were further investigated within each hydrologic region. An important objective of the CSG network is to provide data for developing regional regression equations (RREs) for estimating frequencies at ungaged sites in Montana. Various characteristics of the RREs substantially differ among the eight hydrologic regions in Montana. As such, the RRE characteristics were further investigated within each hydrologic region. For each of the eight hydrologic regions, various characteristics of peak-flow variability, peak-flow informational needs, and regional regression analyses were investigated in detail. Possible shortcomings of the streamgage network in each hydrologic region are identified and possible future improvements to the CSG network are presented.

Montana↗

U.S. Geological Survey research in radioactive waste disposal - Fiscal years 1986-1990

The report summarizes progress on geologic and hydrologic research related to the disposal of radioactive wastes. The research efforts are categorized according to whether they are related most directly to: (1) high-level wastes, (2) transuranic wastes, (3) low-level and mixed low-level and hazardous wastes, or (4) uranium mill tailings. Included is research applicable to the identification and geohydrologic characterization of waste-disposal sites, to investigations of specific sites where wastes have been stored, to development of techniques and methods for characterizing disposal sites, and to studies of geologic and hydrologic processes related to the transport and/or retention of waste radionuclides.

Water-Resources Investigations Report↗

Evaluation of models and data for assessing whooping crane habitat in the central Platte River, Nebraska

The primary objectives of this evaluation were to improve the performance of the Whooping Crane Habitat Suitability model (C4R) used by the U.S. Fish and Wildlife Service (Service) for defining the relationship between river discharge and habitat availability, and to assist the Service in implementing improved model(s) with existing hydraulic files. The C4R habitat model is applied at the scale of individual river cross-sections, but the model outputs are scaledup to larger reaches of the river using a decision support “model” comprised of other data and procedures. Hence, the validity of the habitat model depends at least partially on how its outputs are incorporated into this larger context. For that reason, we also evaluated other procedures including the PHABSIM data files, the FORTRAN computer programs used to implement the model, and other parameters used to simulate the relationship between river flows and the availability of Whooping Crane roosting habitat along more than 100 miles of heterogeneous river channels. An equally important objective of this report was to fully document these related procedures as well as the model and evaluation results so that interested parties could readily understand the technical basis for the Service’s recommendations.

Nebraska↗

Assessment of Lower Missouri River physical aquatic habitat and its use by adult sturgeon ( Genus Scaphirhynchus ), 2005-07

This report presents an exploratory analysis of habitat availability and use by adult Scaphirhynchus sturgeon on the Lower Missouri River from Gavins Point Dam, South Dakota, to the junction with the Mississippi River. The analysis is based on two main data sources collected from 2005 to 2007: (1) a compilation of 153 reach-scale habitat maps (mean reach length, 2.4 kilometers) derived from boat-collected hydroacoustic data and (2) a sturgeon location dataset from which 378 sturgeon telemetry locations are associated with the maps (within 7 days of the mapping and within 10 percent of the discharge). The report focuses on: (1) longitudinal patterns of geomorphic and hydraulic characteristics revealed by the collection of reach maps; (2) assessment of environmental characteristics at sturgeon locations in the context of the mapped reaches; and (3) consideration of spatial distribution of habitat conditions that sturgeon appear to select. Longitudinal patterns of geomorphology, hydraulics, and associated habitats relate strongly to the engineered state of the river. Reaches within each of the following river sections tended to share similar geomorphic, hydrologic, and hydraulic characteristics: the Minimally Engineered section (Gavins Point Dam to Sioux City, Iowa), the Upstream Channelized section (Sioux City, Iowa, to the junction with the Kansas River), and the Downstream Channelized section (Kansas River to the junction with the Mississippi River). Adult sturgeon occupy nearly the full range of available values for each continuous variable assessed: depth, depth slope, depth-averaged velocity, velocity gradient, and Froude number (a dimensionless number relating velocity to depth). However, in the context of habitat available in a reach, sturgeon tend to select some areas over others. Reproductive female shovelnose sturgeon (Scaphirhynchus platorynchus), in particular, were often found in parts of the reach with one or more of the following characteristics: high velocity gradient, high depth slope, low Froude number, and low (though not necessarily the lowest) depth-averaged velocity. Depths used by sturgeon varied considerably. We explored spatial patterns representing the variable ranges that reproductive female shovelnose sturgeon most strongly and consistently selected by mapping areas within reaches meeting the following criteria: greater than the 80th percentile of depth slope, greater than the 80th percentile of velocity gradient, and less than the 20th percentile of Froude number. Our data exploration indicates that areas meeting these criteria have some predictive value regarding sturgeon habitat selection. Of all sturgeon locations that fall on maps from the same year (sample size = 2,013), about 63 percent fall within about 35 percent of the area where at least one variable meets the above criteria and 18 percent of locations fall within 4 percent of the area where all three variables meet the above criteria. The spatial patterns of these mapped areas show distinct differences among the sections of the Lower Missouri River. For example, the areas of predicted selection exhibit a relatively complex mosaic with multiple interconnected pathways in reaches of the Minimally Engineered section. In contrast, areas of predicted selection are concentrated along the channel margins in reaches of the Upstream Channelized section. Because the patterns described in this report represent habitat use in the context of the available habitat in a highly altered river system, selection may not necessarily indicate preferred habitats or habitats sufficient for reproduction and survival of sturgeon species.

Scientific Investigations Report↗

Coastal habitats of the Elwha River, Washington- Biological and physical patterns and processes prior to dam removal

This report includes chapters that summarize the results of multidisciplinary studies to quantify and characterize the current (2011) status and baseline conditions of the lower Elwha River, its estuary, and the adjacent nearshore ecosystems prior to the historic removal of two long-standing dams that have strongly influenced river, estuary, and nearshore conditions. The studies were conducted as part of the U.S. Geological Survey Multi-disciplinary Coastal Habitats in Puget Sound (MD-CHIPS) project. Chapter 1 is the introductory chapter that provides background and a historical context for the Elwha River dam removal and ecosystem restoration project. In chapter 2, the volume and timing of sediment delivery to the estuary and nearshore are discussed, providing an overview of the sediment stored in the two reservoirs and the expected erosion mechanics of the reservoir sediment deposits after removal of the dams. Chapter 3 describes the geological background of the Olympic Peninsula and the geomorphology of the Elwha River and nearshore. Chapter 4 details a series of hydrological data collected by the MD-CHIPS Elwha project. These include groundwater monitoring, surface water-groundwater interactions in the estuary, an estimated surface-water budget to the estuary, and a series of temperature and salinity measurements. Chapter 5 details the work that has been completed in the nearshore, including the measurement of waves, tides, and currents; the development of a numerical hydrodynamic model; and a description of the freshwater plume entering the Strait of Juan de Fuca. Chapter 6 includes a characterization of the nearshore benthic substrate developed using sonar, which formed a habitat template used to design scuba surveys of the benthic biological communities. Chapter 7 describes the ecological studies conducted in the lower river and estuary and includes characterization of juvenile salmon diets and seasonal estuary utilization patterns using otolith analysis to determine habitat specific and hatchery compared with wild patterns in juvenile Chinook salmon, assessment of benthic and terrestrial macroinvertebrate communities, and seasonal patterns of water nutrients. In Chapter 8, the vegetation communities of the eastern estuary are characterized by mapped vegetation cover types and samples collected for vegetation composition and diversity. Chapter 9 summarizes the existing conditions of the study area as detailed in this report and describes some of the possible outcomes of river restoration on the coastal ecosystems of the Elwha River. Together, these different scientific perspectives form a basis for understanding the Elwha River ecosystem, an environment that has and will undergo substantial change. A century of change began with the start of dam construction in 1910; additional major change will result from dam removal scheduled to begin in September 2011. This report provides a scientific snapshot of the lower Elwha River, its estuary, and adjacent nearshore ecosystems prior to dam removal that can be used to evaluate the responses and dynamics of various system components following dam removal.

Scientific Investigations Report↗

Glacial geology of the Shingobee River headwaters area, north-central Minnesota

During middle and late Wisconsin time in the Shingobee River headwaters area, the Laurentide Wadena lobe, Hewitt and Itasca phases, produced terminal and ground moraine along with a variety of associated glacial features. The stratigraphic record is accessible and provides details of depositional mode as well as principal glacial events during the advance and retreat of middle and late Wisconsin ice tongues. Geomorphic features such as tunnel valleys, stream terraces, and postglacial stream cuts formed by erosional events persist to the present day. Middle Wisconsin Hewitt phase deposits are the oldest and include drumlins, ground moraine, boulder pavements, and outwash. Together, these deposits suggest a wet-based, periodically surging glacier in a subpolar thermal state. Regional permafrost and deposition from retreating ice are inferred between the end of the Hewitt phase and the advance of late Wisconsin Itasca phase ice. Itasca phase glaciation occurred as a contemporaneous pair of adjacent ice tongues whose contrasting moraine styles suggest independent flow modes. The western (Shingobee) portion of the Itasca moraine contains composite ridges, permafrost phenomena, hill-hole pairs, and debris flows. By contrast, eastern (Onigum) moraine deposits generally lack glaciotectonic features and consist almost exclusively of mud and debris flows. Near the end of the Itasca phase, large-scale hill-hole pairs developed in the Shingobee division, and debris flows from the Onigum division blocked the preexisting Shingobee tunnel valley to form glacial lake Willobee. Postglacial streams formed deep valleys as glacial lake Willobee catastrophically drained. Dates based on temperature trends in Greenland ice cores are proposed for prominent glacial events in the Shingobee area. This report proposes that Hewitt phase glaciation occurred between 27.2 and 23.6 kiloannum and Itasca phase glaciation between 22.8 and 14.7 kiloannum. Des Moines lobe (Younger Dryas) glaciation, which had only secondary effects on the Shingobee headwaters area, occurred between 13.5 and 11.6 kiloannum.

Minnesota↗

Evaluation of quality-control data collected by the U.S. Geological Survey for routine water-quality activities at the Idaho National Laboratory and vicinity, southeastern Idaho, 2002-08

Quality-control (QC) samples were collected from 2002 through 2008 by the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, to ensure data robustness by documenting the variability and bias of water-quality data collected at surface-water and groundwater sites at and near the Idaho National Laboratory. QC samples consisted of 139 replicates and 22 blanks (approximately 11 percent of the number of environmental samples collected). Measurements from replicates were used to estimate variability (from field and laboratory procedures and sample heterogeneity), as reproducibility and reliability, of water-quality measurements of radiochemical, inorganic, and organic constituents. Measurements from blanks were used to estimate the potential contamination bias of selected radiochemical and inorganic constituents in water-quality samples, with an emphasis on identifying any cross contamination of samples collected with portable sampling equipment. The reproducibility of water-quality measurements was estimated with calculations of normalized absolute difference for radiochemical constituents and relative standard deviation (RSD) for inorganic and organic constituents. The reliability of water-quality measurements was estimated with pooled RSDs for all constituents. Reproducibility was acceptable for all constituents except dissolved aluminum and total organic carbon. Pooled RSDs were equal to or less than 14 percent for all constituents except for total organic carbon, which had pooled RSDs of 70 percent for the low concentration range and 4.4 percent for the high concentration range. Source-solution and equipment blanks were measured for concentrations of tritium, strontium-90, cesium-137, sodium, chloride, sulfate, and dissolved chromium. Field blanks were measured for the concentration of iodide. No detectable concentrations were measured from the blanks except for strontium-90 in one source solution and one equipment blank collected in September and October 2004, respectively. The detectable concentrations of strontium-90 in the blanks probably were from a small source of strontium-90 contamination or large measurement variability, or both. Order statistics and the binomial probability distribution were used to estimate the magnitude and extent of any potential contamination bias of tritium, strontium-90, cesium-137, sodium, chloride, sulfate, dissolved chromium, and iodide in water-quality samples. These statistical methods indicated that, with (1) 87 percent confidence, contamination bias of cesium-137 and sodium in 60 percent of water-quality samples was less than the minimum detectable concentration or reporting level; (2) 92‒94 percent confidence, contamination bias of tritium, strontium-90, chloride, sulfate, and dissolved chromium in 70 percent of water-quality samples was less than the minimum detectable concentration or reporting level; and (3) 75 percent confidence, contamination bias of iodide in 50 percent of water-quality samples was less than the reporting level for iodide. These results support the conclusion that contamination bias of water-quality samples from sample processing, storage, shipping, and analysis was insignificant and that cross-contamination of perched groundwater samples collected with bailers during 2002–08 was insignificant.

Idaho↗

Summary of the analyses for recovery factors

Introduction In order to determine the hydrocarbon potential of oil reservoirs within the U.S. sedimentary basins for which the carbon dioxide enhanced oil recovery (CO 2- EOR) process has been considered suitable, the CO 2 Prophet model was chosen by the U.S. Geological Survey (USGS) to be the primary source for estimating recovery-factor values for individual reservoirs. The choice was made because of the model’s reliability and the ease with which it can be used to assess a large number of reservoirs. The other two approaches—the empirical decline curve analysis (DCA) method and a review of published literature on CO 2 -EOR projects—were deployed to verify the results of the CO 2 Prophet model. This chapter discusses the results from CO 2 Prophet (chapter B, by Emil D. Attanasi, this report) and compares them with results from decline curve analysis (chapter C, by Hossein Jahediesfanjani) and those reported in the literature for selected reservoirs with adequate data for analyses (chapter D, by Ricardo A. Olea). To estimate the technically recoverable hydrocarbon potential for oil reservoirs where CO 2 -EOR has been applied, two of the three approaches—CO 2 Prophet modeling and DCA—do not include analysis of economic factors, while the third approach—review of published literature—implicitly includes economics. For selected reservoirs, DCA has provided estimates of the technically recoverable hydrocarbon volumes, which, in combination with calculated amounts of original oil in place (OOIP), helped establish incremental CO 2 -EOR recovery factors for individual reservoirs. The review of published technical papers and reports has provided substantial information on recovery factors for 70 CO 2 -EOR projects that are either commercially profitable or classified as pilot tests. When comparing the results, it is important to bear in mind the differences and limitations of these three approaches.

Scientific Investigations Report↗