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At least 937 records · Page 52Linked to original sources

Analysis of nitrate (NO3-N) concentration trends in 25 ground-water-quality management areas, Idaho, 1961-2001

In Idaho, drinking-water supplies are pumped from relatively shallow ground-water zones where water quality has great potential for degradation by land- and water-use activities. One indicator of water quality, and one of the most widespread contaminants in Idaho ground water related to land and water uses, is dissolved nitrate. In December 2000, the U.S. Geological Survey, in cooperation with the Idaho Department of Environmental Quality, began a study to compile and assess nitrate data for ground water in 25 ground-water-quality management areas in Idaho. The primary objective of the study was to determine whether statistically significant trends in ground-water concentrations were discernible. Data included ground-water analyses but not analyses of water from springs, drains, or thermal water sources. A total of 8,465 nitrate analyses were compiled from 2,931 wells in the 25 priority areas; analyses dates ranged from June 1961 to February 2001. A time-period comparison was used to assess general trends in nitrate concentrations within individual priority areas. A time-series comparison was used to assess trends in nitrate concentrations from selected wells in each priority area. In time-period assessments, general trends in an area were evaluated by compiling nitrate data for selected time intervals to determine whether the population distributions were significantly different between one period and another. Data within each priority area were sorted into decades— 1970s, 1980s, and 1990s—for long-term trend assessment. The 1990s data also were divided into sets of selected years corresponding to Statewide Ambient Ground-Water Quality Program sampling cycles—1991 through 1994, 1995 through 1998, and a partial cycle, 1999 through 2000—for shortterm trend assessment. Data were analyzed by summary statistics, boxplots, and the Mann- Whitney statistical test. Long-term increasing trends in nitrate concentrations were evident for 6 of 25 priority areas, and long-term decreasing trends were evident for 4 of 25 areas. Short-term increasing trends were evident for 7 of 25 areas, and a short-term decreasing trend was evident for only 1 area. No long-term nitrate trends were evident for 7 of 25 areas, and no shortterm trends were evident for 15 of 25 areas. Data were insufficient for long-term trend assessment in 8 areas and for short-term assessment in 2 areas. Time-series trend analyses were conducted on data from wells with 7 or more nitrate analyses and longest periods of record, at least 10 years between oldest and most recent analyses. Because long-term records were available for so few wells and well construction data were not available for several of these wells, time-series analyses were not helpful to the nitrate trend assessment study. Trend results may be strongly affected by well construction, hydrogeologic environments, and changes in density and areal distribution of wells and analyses. The utility of nitrate trend assessments in priority areas would be improved by more consistent and specific well location descriptions between agencies; well construction and major water-yielding zone information to accompany the water-quality data for each well; and addition of historical nitrate data to data bases, particularly analyses prior to about 1990. Investigations of the possible effects of changing priority area boundaries and time periods on both long-term and short-term trend assessments are needed. Addition of these kinds of information would allow assessment of trends associated with hydrology and geology of each area and would provide a much stronger basis for trend assessment than currently possible.

Idaho↗

Summary report of the sediments, structural framework, petroleum potential, and environmental conditions of the United States Mid-Atlantic continental margin in area of proposed Oil & Gas Lease Sale No. 59

This report has been compiled to update and summarize the geological information concerning the area of the Atlantic continental margin off the U.S. Mid-Atlantic proposed for Oil and Gas Lease Sale No. 59 (fig. 1). The region of interest lies between 35° and 41° N and 70.5° and 76° W. The north-south dimension is about 660 km (356 nautical miles, 410 statute miles) and the maximum east-west dimension is approximately 250 km (135 nautical miles, 155 statute miles). The area is centered toward the outer Continental Shelf off Delaware and contains more than 154,000 km2 (38,000,000 acres) off the coasts of North Carolina, Virginia, Maryland, Delaware, New Jersey and New York. Water depths within the region range from 20 to slightly more than 4,000 m (fig. 1). This report begins with a discussion of the regional geology and geophysics, followed by a description of the oil and gas potential and potential environmental hazards.

Delaware, Maryland, New Jersey, New York, North Ca↗

Methods to characterize environmental settings of stream and groundwater sampling sites for National Water-Quality Assessment

Characterization of natural and anthropogenic features that define the environmental settings of sampling sites for streams and groundwater, including drainage basins and groundwater study areas, is an essential component of water-quality and ecological investigations being conducted as part of the U.S. Geological Survey's National Water-Quality Assessment program. Quantitative characterization of environmental settings, combined with physical, chemical, and biological data collected at sampling sites, contributes to understanding the status of, and influences on, water-quality and ecological conditions. To support studies for the National Water-Quality Assessment program, a geographic information system (GIS) was used to develop a standard set of methods to consistently characterize the sites, drainage basins, and groundwater study areas across the nation. This report describes three methods used for characterization-simple overlay, area-weighted areal interpolation, and land-cover-weighted areal interpolation-and their appropriate applications to geographic analyses that have different objectives and data constraints. In addition, this document records the GIS thematic datasets that are used for the Program's national design and data analyses.

Scientific Investigations Report↗

Overview--Development of a geodatabase and conceptual model of the hydrogeologic units beneath Air Force Plant 4 and Naval Air Station-Joint Reserve Base Carswell Field, Fort Worth, Texas

Air Force Plant 4 (AFP4) and adjacent Naval Air Station-Joint Reserve Base Carswell Field (NAS–JRB) at Fort Worth, Tex., constitute a contractor-owned, government-operated facility that has been in operation since 1942. Contaminants from the 3,600-acre facility, primarily volatile organic compounds (VOCs) and metals, have entered the ground-water-flow system through leakage from waste-disposal sites and from manufacturing processes. Environmental data collected at AFP4 and NAS–JRB during 1993–2002 created the need for consolidation of the data into a comprehensive temporal and spatial geodatabase. The U.S. Geological Survey (USGS), in cooperation with the U.S. Air Force Aeronautical Systems Center Environmental Management Directorate, developed a comprehensive geodatabase of temporal and spatial environmental data associated with the hydrogeologic units beneath the facility. A three-dimensional conceptual model of the hydrogeologic units integrally linked to the geodatabase was designed concurrently. Three hydrogeologic units—from land surface downward, the alluvial aquifer, the GoodlandWalnut confining unit, and the Paluxy aquifer—compose the subsurface of interest at AFP4 and NAS–JRB. The alluvial aquifer consists primarily of clay and silt with sand and gravel channel deposits that might be interconnected or interfingered. The Goodland-Walnut confining unit directly underlies the alluvial aquifer and consists of limestone, marl, shale, and clay. The Paluxy aquifer is composed of dense mudstone and fine- to coarse-grained sandstone

Texas↗

Description and evaluation of numerical groundwater flow models for the Edwards Aquifer, south-central Texas

A substantial number of public water system wells in south-central Texas withdraw groundwater from the karstic, highly productive Edwards aquifer. However, the use of numerical groundwater flow models to aid in the delineation of contributing areas for public water system wells in the Edwards aquifer is problematic because of the complex hydrogeologic framework and the presence of conduit-dominated flow paths in the aquifer. The U.S. Geological Survey, in cooperation with the Texas Commission on Environmental Quality, evaluated six published numerical groundwater flow models (all deterministic) that have been developed for the Edwards aquifer San Antonio segment or Barton Springs segment, or both. This report describes the models developed and evaluates each with respect to accessibility and ease of use, range of conditions simulated, accuracy of simulations, agreement with dye-tracer tests, and limitations of the models. These models are (1) GWSIM model of the San Antonio segment, a FORTRAN computer-model code that pre-dates the development of MODFLOW; (2) MODFLOW conduit-flow model of San Antonio and Barton Springs segments; (3) MODFLOW diffuse-flow model of San Antonio and Barton Springs segments; (4) MODFLOW Groundwater Availability Modeling [GAM] model of the Barton Springs segment; (5) MODFLOW recalibrated GAM model of the Barton Springs segment; and (6) MODFLOW–DCM (dual conductivity model) conduit model of the Barton Springs segment. The GWSIM model code is not commercially available, is limited in its application to the San Antonio segment of the Edwards aquifer, and lacks the ability of MODFLOW to easily incorporate newly developed processes and packages to better simulate hydrologic processes. MODFLOW is a widely used and tested code for numerical modeling of groundwater flow, is well documented, and is in the public domain. These attributes make MODFLOW a preferred code with regard to accessibility and ease of use. The MODFLOW conduit-flow model incorporates improvements over previous models by using (1) a user-friendly interface, (2) updated computer codes (MODFLOW–96 and MODFLOW–2000), (3) a finer grid resolution, (4) less-restrictive boundary conditions, (5) an improved discretization of hydraulic conductivity, (6) more accurate estimates of pumping stresses, (7) a long transient simulation period (54 years, 1947–2000), and (8) a refined representation of high-permeability zones or conduits. All of the models except the MODFLOW–DCM conduit model have limitations resulting from the use of Darcy’s law to simulate groundwater flow in a karst aquifer system where non-Darcian, turbulent flow might actually dominate. The MODFLOW–DCM conduit model is an improvement in the ability to simulate karst-like flow conditions in conjunction with porous-media-type matrix flow. However, the MODFLOW–DCM conduit model has had limited application and testing and currently (2008) lacks commercially available pre- and post-processors. The MODFLOW conduit-flow and diffuse-flow Edwards aquifer models are limited by the lack of calibration for the northern part of the Barton Springs segment (Travis County) and their reliance on the use of the calibrated hydraulic conductivity and storativity values from the calibrated Barton Springs segment GAM model. The major limitation of the Barton Springs segment GAM and recalibrated GAM models is that they were calibrated to match measured water levels and springflows for a restrictive range of hydrologic conditions, with each model having different hydraulic conductivity and storativity values appropriate to the hydrologic conditions that were simulated. The need for two different sets of hydraulic conductivity and storativity values increases the uncertainty associated with the accuracy of either set of values, illustrates the non-uniqueness of the model solution, and probably most importantly demonstrates the limitations of using a one-layer model to represent the heterogeneous hydrostratigraphic units composing the Edwards aquifer. In general, the best matches or agreement between groundwater flow directions inferred by numerical model simulation, and by dye-tracer tests, are observed where model outputs accurately reproduce the configuration of the potentiometric surface with regard to the positions of major and minor groundwater troughs and divides. None of the models, with the possible exception of the MODFLOW–DCM conduit model, has a documented capability to accurately simulate travel times for conduit-dominated velocities in the Edwards aquifer. Public water system assessments of wells in the Barton Springs segment of the Edwards aquifer, and elsewhere where conduit-flow conditions are thought to dominate aquifer hydraulic behavior, might be enhanced by use of either the MODFLOW–DCM model or the newly developed U.S. Geological Survey MODFLOW Conduit-Flow Process module for MODFLOW–2005, because each incorporates a type of dual or triple hydraulic conductivity approach and has the capability to explicitly simulate turbulent flow and conduit hydraulic characteristics.

Texas↗

Water-quality assessment of the lower Illinois River Basin: Environmental setting

The lower Illinois River Basin (LIRB) encompasses 18,000 square miles of central and western Illinois. Historical and recent information from Federal, State, and local agencies describing the physiography, population, land use, soils, climate, geology, streamflow, habitat, ground water, water use, and aquatic biology is summarized to describe the environmental setting of the LIRB. The LIRB is in the Till Plains Section of the Central Lowland physiographic province. The basin is characterized by flat topography, which is dissected by the Illinois River. The drainage pattern of the LIRB has been shaped by many bedrock and glacial geologic processes. Erosion prior to and during Pleistocene time created wide and deep bedrock valleys. The thickest deposits and most major aquifers are in buried bedrock valleys. The Wisconsinan glaciation, which bisects the northern half of the LIRB, affects the distribution and characteristics of glacial deposits in the basin. Agriculture is the largest land use and forested land is the second largest land use in the LIRB. The major urban areas are near Peoria, Springfield, Decatur, and Bloomington-Normal. Soil type and distribution affect the amount of soil erosion, which results in sedimentation of lakes and reservoirs in the basin. Rates of soil erosion of up to 2 percent per year of farmland soil have been measured. Many of the 300 reservoirs, lakes, and wetlands are disappearing because of sedimentation resulting from agriculture activities, levee building, and urbanization. Sedimentation and the destruction of habitat appreciably affect the ecosystem. The Illinois River is a large river-floodplain ecosystem where biological productivity is enhanced by annual flood pulses that advance and retreat over the flood plain and temporarily expand backwater and flood-plain lakes. Ground-water discharge to streams affects the flow and water quality of the streams. The water budget of several subbasins show variability in ground-water contribution from runoff and storage. More than half of the drinking water, including domestic and public-supply use, in the LIRB is from ground water. Fifty-two percent of the public-supply water is from surface water. Ground-water withdrawals mostly are from glacial sand and gravel aquifers. Structural features, such as monoclines, synclines, and anticlines, in the buried bedrock affect the water quality of the aquifers. There are five natural environmental divisions in the LIRB. The Grand Prairie covers most of the northeastern half of the basin, and the Western Forest-Prairie covers most of the southwestern half. Implications of environmental setting for water quality in the LIRB are related primarily to land use. The balanced fish community indicates that the lower Illinois River is affected less from urban and industrial waste than the upper Illinois River. A decrease in dissolved oxygen concentrations and turbidity in the lower reaches of the basin in 1993 have resulted from the recent influx of European zebra mussels to the LIRB. Many factors affect water quality in the LIRB. Bedrock and surface topography, type of glacial material, and land use most directly affect water quality in the basin.

Illinois↗

Geologic sources and concentrations of selenium in the West-Central Denver Basin, including the Toll Gate Creek watershed, Aurora, Colorado, 2003-2007

Toll Gate Creek, in the west-central part of the Denver Basin, is a perennial stream in which concentrations of dissolved selenium have consistently exceeded the Colorado aquatic-life standard of 4.6 micrograms per liter. Recent studies of selenium in Toll Gate Creek identified the Denver lignite zone of the non-marine Cretaceous to Tertiary-aged (Paleocene) Denver Formation underlying the watershed as the geologic source of dissolved selenium to shallow ground-water and surface water. Previous work led to this study by the U.S. Geological Survey, in cooperation with the City of Aurora Utilities Department, which investigated geologic sources of selenium and selenium concentrations in the watershed. This report documents the occurrence of selenium-bearing rocks and groundwater within the Cretaceous- to Tertiary-aged Denver Formation in the west-central part of the Denver Basin, including the Toll Gate Creek watershed. The report presents background information on geochemical processes controlling selenium concentrations in the aquatic environment and possible geologic sources of selenium; the hydrogeologic setting of the watershed; selenium results from groundwater-sampling programs; and chemical analyses of solids samples as evidence that weathering of the Denver Formation is a geologic source of selenium to groundwater and surface water in the west-central part of the Denver Basin, including Toll Gate Creek. Analyses of water samples collected from 61 water-table wells in 2003 and from 19 water-table wells in 2007 indicate dissolved selenium concentrations in groundwater in the west-central Denver Basin frequently exceeded the Colorado aquatic-life standard and in some locations exceeded the primary drinking-water standard of 50 micrograms per liter. The greatest selenium concentrations were associated with oxidized groundwater samples from wells completed in bedrock materials. Selenium analysis of geologic core samples indicates that total selenium concentrations were greatest in samples containing indications of reducing conditions and organic matter (dark gray to black claystones and lignite horizons). The Toll Gate Creek watershed is situated in a unique hydrogeologic setting in the west-central part of the Denver Basin such that weathering of Cretaceous- to Tertiary-aged, non-marine, selenium-bearing rocks releases selenium to groundwater and surface water under present-day semi-arid environmental conditions. The Denver Formation contains several known and suspected geologic sources of selenium including: (1) lignite deposits; (2) tonstein partings; (3) organic-rich bentonite claystones; (4) salts formed as secondary weathering products; and possibly (5) the Cretaceous-Tertiary boundary. Organically complexed selenium and/or selenium-bearing pyrite in the enclosing claystones are likely the primary mineral sources of selenium in the Denver Formation, and correlations between concentration of dissolved selenium and dissolved organic carbon in groundwater indicate weathering and dissolution of organically complexed selenium from organic-rich claystone is a primary process mobilizing selenium. Secondary salts accumulated along fractures and bedding planes in the weathered zone are another potential geologic source of selenium, although their composition was not specifically addressed by the solids analyses. Results from this and previous work indicate that shallow groundwater and streams similarly positioned over Denver Formation claystone units at other locations in the Denver Basin also may contain concentrations of dissolved selenium greater than the Colorado aquatic-life standard or the drinking- water standard.

Colorado↗

Surface-water quality in the Lycoming Creek watershed, north-central Pennsylvania, August 1–3, 2011

This report presents the methodology and results for a study of surface-water quality of the Lycoming Creek watershed in north-central Pennsylvania during August 1–3, 2011. The study was done in cooperation with the Williamsport Municipal Water Authority and the Pennsylvania Department of Environmental Protection. Samples of stream water were collected from 31 sites in an area of exploration and production of natural gas from the Marcellus Shale – 5 sites on the main stem of Lycoming Creek and 26 sites on tributary streams. The samples provide a snapshot of the base-flow water-quality conditions, which helps document the spatial variability in water-quality and could be useful for assessing future changes. The 272-square mile Lycoming Creek watershed is located within Lycoming, Tioga, and Sullivan Counties in north-central Pennsylvania. Lycoming Creek flows 37.5 miles to its confluence with the West Branch Susquehanna River in the city of Williamsport. A well field that supplies water for Williamsport captures some water that has infiltrated the streambed of Lycoming Creek. Because the stream provides a source of water to the well field, this study focused on the stream-water quality as it relates to drinking-water standards as opposed to aquatic life. Surface-water samples collected at 20 sites by the U.S. Geological Survey and 11 sites by the Pennsylvania Department of Environmental Protection were analyzed by each agency for a suite of constituents that included major ions, trace metals, nutrients, and radiochemicals. None of the analytical results failed to meet standards set by the U.S. Environmental Protection Agency as maximum contaminant levels for drinking water. Results of the sampling show the substantial spatial variability in base-flow water quality within the Lycoming Creek watershed caused by the interrelated effects of physiography, geology and land use. Dissolved-solids concentrations ranged from less than the laboratory reporting level of 12 milligrams per liter (mg/L) in Wolf Run, a pristine forested watershed, to 202 mg/L in Bottle Run, a watershed with more development near Williamsport. Concentrations of the major ions ranged over at least one order of magnitude; chloride had the largest range from 0.3 to 45.4 mg/L, with nine samples exceeding the natural background level of about 5 mg/L, most likely because of the application of deicing salt to roads. Trace constituents were even more variable, with concentrations for aluminum, cobalt, and manganese ranging over almost four orders of magnitude. Samples from Red Run and Dutchman Run, watersheds that experienced past coal mining activity, had concentrations of 11 metals that were significantly greater than in samples collected from other streams. Samples from Bottle Run, the tributary of Lycoming Creek nearest to Williamsport, contained elevated levels of chloride and boron, constituents associated with urban development.

Pennsylvania↗

Mapping habitat for multiple species in the Desert Southwest

Many utility scale renewable energy projects are currently proposed across the Mojave Ecoregion. Agencies that manage biological resources throughout this region need to understand the potential impacts of these renewable energy projects and their associated infrastructure (for example, transmission corridors, substations, access roads, etc.) on species movement, genetic exchange among populations, and species’ abilities to adapt to changing environmental conditions. Understanding these factors will help managers’ select appropriate project sites and possibly mitigate for anticipated effects of management activities. We used species distribution models to map habitat for 15 species across the Mojave Ecoregion to aid regional land-use management planning. Models were developed using a common 1 × 1 kilometer resolution with maximum entropy and generalized additive models. Occurrence data were compiled from multiple sources, including VertNet ( http://vertnet.org/ ), HerpNET ( http://www.herpnet.org ), and MaNIS ( http://manisnet.org ), as well as from internal U.S. Geological Survey databases and other biologists. Background data included 20 environmental covariates representing terrain, vegetation, and climate covariates. This report summarizes these environmental covariates and species distribution models used to predict habitat for the 15 species across the Mojave Ecoregion.

Mojave Ecoregion↗

Water resources and shale gas/oil production in the Appalachian Basin: critical issues and evolving developments

Unconventional natural gas and oil resources in the United States are important components of a national energy program. While the Nation seeks greater energy independence and greener sources of energy, Federal agencies with environmental responsibilities, state and local regulators and water-resource agencies, and citizens throughout areas of unconventional shale gas development have concerns about the environmental effects of high volume hydraulic fracturing (HVHF), including those in the Appalachian Basin in the northeastern United States (fig. 1). Environmental concerns posing critical challenges include the availability and use of surface water and groundwater for hydraulic fracturing; the migration of stray gas and potential effects on overlying aquifers; the potential for flowback, formation fluids, and other wastes to contaminate surface water and groundwater; and the effects from drill pads, roads, and pipeline infrastructure on land disturbance in small watersheds and headwater streams (U.S. Government Printing Office, 2012). Federal, state, regional and local agencies, along with the gas industry, are striving to use the best science and technology to develop these unconventional resources in an environmentally safe manner. Some of these concerns were addressed in U.S. Geological Survey (USGS) Fact Sheet 2009–3032 (Soeder and Kappel, 2009) about potential critical effects on water resources associated with the development of gas extraction from the Marcellus Shale of the Hamilton Group (Ver Straeten and others, 1994). Since that time, (1) the extraction process has evolved, (2) environmental awareness related to high-volume hydraulic fracturing process has increased, (3) state regulations concerning gas well drilling have been modified, and (4) the practices used by industry to obtain, transport, recover, treat, recycle, and ultimately dispose of the spent fluids and solid waste materials have evolved. This report updates and expands on Fact Sheet 2009–3032 and presents new information regarding selected aspects of unconventional shale gas development in the Appalachian Basin (primarily Virginia, West Virginia, Maryland, Pennsylvania, Ohio, and New York). This document was prepared by the USGS, in cooperation with the U.S. Department of Energy, and reviews the evolving technical advances and scientific studies made in the Appalachian Basin between 2009 and the present (2013), addressing past and current issues for oil and gas development in the region.

Maryl;New York;Ohio;Pennsylvania;Virginia;West Vir↗

Simulated effects of alternative withdrawal strategies on groundwater flow in the unconfined Kirkwood-Cohansey aquifer system, the Rio Grande water-bearing zone, and the Atlantic City 800-foot sand in the Great Egg Harbor and Mullica River Basins, New Jersey

Groundwater is essential for water supply and plays a critical role in maintaining the environmental health of freshwater and estuarine ecosystems in the Atlantic Coastal basins of New Jersey. The unconfined Kirkwood-Cohansey aquifer system and the confined Atlantic City 800-foot sand are major sources of groundwater in the area, and each faces different water-supply concerns. The U.S. Geological Survey (USGS), in cooperation with the New Jersey Department of Environmental Protection (NJDEP), conducted a study to simulate the effects of withdrawals in the Kirkwood-Cohansey aquifer system, the Atlantic City 800-foot sand, and the Rio Grande water-bearing zone and to evaluate potential scenarios. The study area encompasses Atlantic County and parts of Burlington, Camden, Gloucester, Ocean, Cape May, and Cumberland Counties. The major hydrogeologic units affecting water supply in the study area are the surficial Kirkwood-Cohansey aquifer system, a thick diatomaceous clay confining unit in the upper part of Kirkwood Formation; the Rio Grande water-bearing zone; and the Atlantic City 800-foot sand of the Kirkwood Formation. Hydrogeologic data from 18 aquifer tests and specific capacity data from 230 wells were analyzed to provide horizontal hydraulic conductivity of the aquifers. Groundwater withdrawals are greatest from the Kirkwood-Cohansey aquifer system, and 65 percent of the water is used for public supply. Groundwater withdrawals from the Atlantic City 800-foot sand are about half those from the Kirkwood-Cohansey aquifer system. Ninety-five percent of the withdrawals from the Atlantic City 800-foot sand is used for public supply. Data from six streamgaging stations and 51 low-flow partial record sites were used to estimate base flow in the area. Base flow ranges from 60 to 92 percent of streamflow. A groundwater flow model of the Kirkwood-Cohansey aquifer system, the Rio Grande water-bearing zone, and the Atlantic City 800-foot sand was developed and calibrated using water-level data from 148 wells and base-flow data from 22 gaging or low-flow partial record stations. The Kirkwood-Cohansey aquifer system within the Great Egg Harbor River and the Mullica River Basins was simulated on a monthly basis from 1998 through 2006. An existing regional model of the New Jersey Coastal Plain was revised to provide boundary conditions for the Great Egg Harbor and Mullica River Basin model (referred to as the Great Egg-Mullica model). In the Great Egg-Mullica model, monthly groundwater recharge rates used in the model ranged from 10-15 inches per year in 2001 to 20-25 inches per year in 2005. The mean-absolute error for 10 of the 14 long-term hydrographs used in model calibration was less than 5 ft. Groundwater flow budgets for the Great Egg-Mullica model calibration periods, May 2005 and September 2006, and for the entire model calibration period 1998 to 2006, showed that nearly 70 percent of the water entering the Atlantic City 800-foot sand came from the horizontal connection with the Kirkwood-Cohansey aquifer system in updip areas. The groundwater flow model was used to simulate scenarios under three possible conditions: average 1998 to 2006 withdrawals (Average scenario), full-allocation withdrawals (Full Allocation scenario), and projected 2050-demand withdrawals (2050 Demand scenario). Withdrawals in the Full Allocation scenario are nearly twice the withdrawals from the Average scenario, primarily because of the potential for large agricultural withdrawals if all allocations are used. Withdrawals for the 2050 Demand scenario are about 50 percent greater than those for the Average scenario, primarily due to expected increases in withdrawals for public supply. Monthly base-flow depletion criteria were determined using the Low-Flow Margin method, currently under consideration by NJDEP, to estimate available water on an annual basis at the Hydrologic Unit Code 11 (HUC11) level and to determine whether a water-supply deficit exists. Simulations of various groundwater-withdrawal scenarios were made using the calibrated model, and results were compared with baseline conditions (no withdrawals) to determine where and when base-flow deficits may be occurring and may be expected to occur in the future. Scenarios were simulated to assess base-flow depletion that could occur from different groundwater-withdrawal situations. In the Average scenario, deficits occurred in 7 of the 14 subbasins. In the Full Allocation scenario, deficits occurred in 11 of the subbasins. In the 2050 Demand scenario, deficits occurred in 9 of the 14 subbasins. The largest deficits occurred in the Absecon Creek subbasin because the base-flow depletion criteria for this subbasin is small due to the surface-water diversions that are already occurring there and because existing groundwater withdrawals in the subbasin have resulted in base-flow depletion under current (1998-2006) conditions. Three adjusted scenarios, variations of the Average, Full Allocation, and 2050 Demand scenarios, were simulated; for the adjusted scenarios, the withdrawals were modified in stages with the intent to successively eliminate or minimize the base-flow deficits. Modifications included shifting withdrawals to a deeper part of the Kirkwood-Cohansey aquifer system, implementing seasonal conjunctive use of shallow and deep aquifers, and specifying reductions in withdrawals within a HUC11 subbasin in deficit. The adjusted scenarios are intended to show the relative effectiveness of each of the three approaches in reducing the deficits. Most of the deficits under the Average, Full Allocation, and 2050 Demand scenarios were eliminated by reductions in withdrawals or allocations. Shifting withdrawals to a deeper part of the Kirkwood-Cohansey aquifer system or seasonal conjunctive use did not eliminate deficits for any subbasin. Reductions in withdrawals accounted for more than 95 percent of the total reduction of deficits in all but one subbasin.

New Jersey↗

The Penobscot River and environmental contaminants: Assessment of tribal exposure through sustenance lifeways

EPA in collaboration with the Penobscot Indian Nation, U.S. Geological Survey (USGS), Agency for Toxic Substances and Disease Registry (ATSDR), and the U.S. Fish and Wildlife Service (USF&WS) collectively embarked on a four year research study to evaluate the environmental health of the riverine system by targeting specific cultural practices and using traditional science to conduct a preliminary contaminant screening of the flora and fauna of the Penobscot River ecosystem. This study was designed as a preliminary screening to determine if contaminant concentrations in fish, eel, snapping turtle, wood ducks, and plants in Regions of the Penobscot River relevant to where PIN tribal members hunt, fish and gather plants were high enough to be a health concern. This study was not designed to be a statistically validated assessment of contaminant differences among study sites or among species. The traditional methodology for health risk assessment used by the U. S. Environmental Protection Agency (EPA) is based on the use of exposure assumptions (e.g. exposure duration, food ingestion rate, body weight, etc.) that represent the entire American population, either as a central tendency exposure (e.g. average, median) or as a reasonable maximum exposure (e.g. 95% upper confidence limit). Unfortunately, EPA lacked exposure information for assessing health risks for New England regional tribes sustaining a tribal subsistence way of life. As a riverine tribe, the Penobscot culture and traditions are inextricably tied to the Penobscot River watershed. It is through hunting, fishing, trapping, gathering and making baskets, pottery, moccasins, birch-bark canoes and other traditional practices that the Penobscot culture and people are sustained. The Penobscot River receives a variety of pollutant discharges leaving the Penobscot Indian Nation (PIN) questioning the ecological health and water quality of the river and how this may affect the practices that sustain their way of life. The objectives of this Regional Applied Research Effort (RARE) study were to: Develop culturally sensitive methodologies for assessing the potential level of exposure tocontaminants that Penobscot Indian Nation tribal members may have from maintainingtribal sustenance practices. Conduct field surveys and laboratory analysis on targeted flora and fauna for chemicalexposure to dioxins/furans, polychlorinated biphenyls (PCBs), total mercury and methyl-mercury. Assist the Agency for Toxic Substances and Disease Registry (ATSDR) by providing thenecessary data to conduct a Public Health Assessment for the Penobscot Indian Nation. Establish protocols for assessing the level of exposure to PCBs, dioxins/furans and mercuryto PIN tribal members as a consequence of gathering tribal plants for medicinal andnutritional purposes; as well as consuming fish, wood duck, and snapping turtle as a primarysource of nutrition. Survey surface water, drinking water, and sediment from the Penobscot River and IndianIsland to assess the exposure of PIN tribal members to environmental genotoxicants thatcontinue cultural sustenance practices. This research initiative collected and analyzed sediment and biota to determine the level of contaminant exposure to Penobscot tribal members. Natural resource utilization patterns and exposure pathways were identified based on discussions with the Tribal elders. Identification of Tribal exposure factors (exposure pathways and contaminant concentrations) was essential for accurately assessing potential long-term Penobscot Indian Nation tribal members’ exposure. Based on this study, ATSDR’s Public Health Assessment (PHA) concluded that the Penobscot Indian Nation (PIN) tribal members who eat fish and snapping turtle at the ingestion levels suggested in the Wabanaki Traditional Cultural Lifeways Exposure Scenario Report (Wabanaki Exposure Scenario) may be exposed to harmful levels of mercury, dioxins/furans, dioxin-like PCBs, and ot

Maine↗

Low-flow frequency and flow duration of selected South Carolina streams in the Pee Dee River basin through March 2007

Part of the mission of the South Carolina Department of Health and Environmental Control and the South Carolina Department of Natural Resources is to protect and preserve South Carolina's water resources. Doing so requires an ongoing understanding of streamflow characteristics of the rivers and streams in South Carolina. A particular need is information concerning the low-flow characteristics of streams; this information is especially important for effectively managing the State's water resources during critical flow periods such as the severe drought that occurred between 1998 and 2002 and the most recent drought that occurred between 2006 and 2009. In 2008, the U.S. Geological Survey, in cooperation with the South Carolina Department of Health and Environmental Control, initiated a study to update low-flow statistics at continuous-record streamgaging stations operated by the U.S. Geological Survey in South Carolina. Under this agreement, the low-flow characteristics at continuous-record streamgaging stations will be updated in a systematic manner during the monitoring and assessment of the eight major basins in South Carolina as defined and grouped according to the South Carolina Department of Health and Environmental Control's Watershed Water Quality Management Strategy. Depending on the length of record available at the continuous-record streamgaging stations, low-flow frequency characteristics are estimated for annual minimum 1-, 3-, 7-, 14-, 30-, 60-, and 90-day average flows with recurrence intervals of 2, 5, 10, 20, 30, and 50 years. Low-flow statistics are presented for 18 streamgaging stations in the Pee Dee River basin. In addition, daily flow durations for the 5-, 10-, 25-, 50-, 75-, 90-, and 95-percent probability of exceedance also are presented for the stations. The low-flow characteristics were computed from records available through March 31, 2007. The last systematic update of low-flow characteristics in South Carolina occurred more than 20 years ago and included data through March 1987. Of the 17 streamgaging stations included in this study, 15 had low-flow characteristics that were published in previous U.S. Geological Survey reports. A comparison of the low-flow characteristic for the minimum average flow for a 7-consecutive-day period with a 10-year recurrence interval from this study with the most recently published values indicated that 10 of the 15 streamgaging stations had values that were within ±25 percent of each other. Nine of the 15 streamgaging stations had negative percentage differences indicating the low-flow statistic had decreased since the previous study, 4 streamgaging stations had positive percent differences indicating that the low-flow statistic had increased since the previous study, and 2 streamgaging stations had a zero percent difference indicating no change since the previous study. The low-flow characteristics are influenced by length of record, hydrologic regime under which the record was collected, techniques used to do the analysis, and other changes that may have occurred in the watershed.

North Carolina, South Carolina↗

Evaluation of Approaches for Managing Nitrate Loading from On-Site Wastewater Systems near La Pine, Oregon

This report presents the results of a study by the U.S. Geological Survey, done in cooperation with the Oregon Department of Environmental Quality and Deschutes County, to develop a better understanding of the effects of nitrogen from on-site wastewater disposal systems on the quality of ground water near La Pine in southern Deschutes County and northern Klamath County, Oregon. Simulation models were used to test the conceptual understanding of the system and were coupled with optimization methods to develop the Nitrate Loading Management Model, a decision-support tool that can be used to efficiently evaluate alternative approaches for managing nitrate loading from on-site wastewater systems. The conceptual model of the system is based on geologic, hydrologic, and geochemical data collected for this study, as well as previous hydrogeologic and water quality studies and field testing of on-site wastewater systems in the area by other agencies. On-site wastewater systems are the only significant source of anthropogenic nitrogen to shallow ground water in the study area. Between 1960 and 2005 estimated nitrate loading from on-site wastewater systems increased from 3,900 to 91,000 pounds of nitrogen per year. When all remaining lots are developed (in 2019 at current building rates), nitrate loading is projected to reach nearly 150,000 pounds of nitrogen per year. Low recharge rates (2-3 inches per year) and ground-water flow velocities generally have limited the extent of nitrate occurrence to discrete plumes within 20-30 feet of the water table; however, hydraulic-gradient and age data indicate that, given sufficient time and additional loading, nitrate will migrate to depths where many domestic wells currently obtain water. In 2000, nitrate concentrations greater than 4 milligrams nitrogen per liter (mg N/L) were detected in 10 percent of domestic wells sampled by Oregon Department of Environmental Quality. Numerical simulation models were constructed at transect (2.4 square miles) and study-area (247 square miles) scales to test the conceptual model and evaluate processes controlling nitrate concentrations in ground water and potential ground-water discharge of nitrate to streams. Simulation of water-quality conditions for a projected future build-out (base) scenario in which all existing lots are developed using conventional on-site wastewater systems indicates that, at equilibrium, average nitrate concentrations near the water table will exceed 10 mg N/L over areas totaling 9,400 acres. Other scenarios were simulated where future nitrate loading was reduced using advanced treatment on-site systems and a development transfer program. Seven other scenarios were simulated with total nitrate loading reductions ranging from 15 to 94 percent; simulated reductions in the area where average nitrate concentrations near the water table exceed 10 mg N/L range from 22 to 99 percent at equilibrium. Simulations also show that the ground-water system responds slowly to changes in nitrate loading due to low recharge rates and ground-water flow velocity. Consequently, reductions in nitrate loading will not immediately reduce average nitrate concentrations and the average concentration in the aquifer will continue to increase for 25-50 years depending on the level and timing of loading reduction. The capacity of the ground-water system to receive on-site wastewater system effluent, which is related to the density of homes, presence of upgradient residential development, ground-water recharge rate, ground-water flow velocity, and thickness of the oxic part of the aquifer, varies within the study area. Optimization capability was added to the study-area simulation model and the combined simulation-optimization model was used to evaluate alternative approaches to management of nitrate loading from on-site wastewater systems to the shallow alluvial aquifer. The Nitrate Loading Management Model (NLMM) was formulated to find the minimum red

Scientific Investigations Report↗

Environmental geochemical study of Red Mountain--an undisturbed volcanogenic massive sulfide deposit in the Bonnifield District, Alaska range, east-central Alaska: Chapter I in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

The Red Mountain volcanogenic massive sulfide (VMS) deposit exhibits well-constrained examples of acid-generating, metal-leaching, metal-precipitation, and self-mitigation (via co-precipitation, dilution, and neutralization) processes that occur in an undisturbed natural setting, a rare occurrence in North America. The unmined pyrite-rich deposit displays a remarkable environmental footprint of natural acid generation, high metal concentrations, and exceedingly high rare-earth-element (REE) concentrations in surface waters. Dissolution of pyrite and associated secondary reactions under near-surface, oxidizing conditions are the primary causes for the acid generation and metal leaching. The deposit is hosted in Devonian to Mississippian felsic metavolcanic rocks of the Mystic Creek Member of the Totatlanika Schist. Water samples with the lowest pH values, highest specific conductances, and highest major- and trace-element concentrations are from springs and streams within the quartz-sericite-pyrite alteration zone. Aluminum, As, Cd, Co, Cu, Fe, Mn, Ni, Pb, Y, and particularly Zn and the REEs are all found in high concentrations, ranging across four orders of magnitude. Waters collected upstream from the alteration zone have near-neutral pH values, lower specific conductances, lower metal concentrations, and measurable alkalinities. Water samples collected downstream of the alteration zone have pH values and metal concentrations intermediate between these two extremes. Stream sediments are anomalous in Zn, Pb, S, Fe, Cu, As, Co, Sb, and Cd relative to local and regional background abundances. Red Mountain Creek and its tributaries do not support, and probably never have supported, significant megascopic faunal aquatic life.

Alaska;Yukon↗

A new basaltic glass microanalytical reference material for multiple techniques

The U.S. Geological Survey (USGS) has been producing reference materials since the 1950s. Over 50 materials have been developed to cover bulk rock, sediment, and soils for the geological community. These materials are used globally in geochemistry, environmental, and analytical laboratories that perform bulk chemistry and/or microanalysis for instrument calibration and quality assurance testing. To answer the growing demand for higher spatial resolution and sensitivity, there is a need to create a new generation of microanalytical reference materials suitable for a variety of techniques, such as scanning electron microscopy/X-ray spectrometry (SEM/EDS), electron probe microanalysis (EPMA), laser ablation inductively coupled mass spectrometry (LA-ICP-MS), and secondary ion mass spectrometry (SIMS). As such, the microanalytical reference material (MRM) needs to be stable under the beam, be homogeneous at scales of better than 10–25 micrometers for the major to ultra-trace element level, and contain all of the analytes (elements or isotopes) of interest. Previous development of basaltic glasses intended for LA-ICP-MS has resulted in a synthetic basaltic matrix series of glasses (USGS GS-series) and a natural basalt series of glasses (BCR-1G, BHVO-2G, and NKT-1G). These materials have been useful for the LA-ICP-MS community but were not originally intended for use by the electron or ion beam community. A material developed from start to finish with intended use in multiple microanalytical instruments would be useful for inter-laboratory and inter-instrument platform comparisons. This article summarizes the experiments undertaken to produce a basalt glass reference material suitable for distribution as a multiple-technique round robin material. The goal of the analytical work presented here is to demonstrate that the elemental homogeneity of the new glass is acceptable for its use as a reference material. Because the round robin exercise is still underway, only nominal compositional ranges for each element are given in the article.

Microscopy Today↗

Integrating disparate lidar data at the national scale to assess the relationships between height above ground, land cover and ecoregions

With the acquisition of lidar data for over 30 percent of the US, it is now possible to assess the three-dimensional distribution of features at the national scale. This paper integrates over 350 billion lidar points from 28 disparate datasets into a national-scale database and evaluates if height above ground is an important variable in the context of other nationalscale layers, such as the US Geological Survey National Land Cover Database and the US Environmental Protection Agency ecoregions maps. While the results were not homoscedastic and the available data did not allow for a complete height census in any of the classes, it does appear that where lidar data were used, there were detectable differences in heights among many of these national classification schemes. This study supports the hypothesis that there were real, detectable differences in heights in certain national-scale classification schemes, despite height not being a variable used in any of the classification routines.

Photogrammetric Engineering and Remote Sensing↗

Assessment of natural gas pipeline construction on stream temperature and turbidity in southwestern Virginia, 2017—25

The natural gas pipeline network in the United States is extensive and often intersects streams and other sensitive habitats, yet there are limited case studies utilizing a comparative upstream-downstream approach to evaluate potential short- and long-term effects of pipeline stream crossing construction from pre-construction to post-site restoration. In 2017, the U.S. Geological Survey, in cooperation with the Virginia Department of Environmental Quality (DEQ), deployed real-time continuous stream monitoring stations upstream and downstream of six proposed Mountain Valley Pipeline (MVP) stream crossings in southwestern Virginia. Water temperature and turbidity data collected at the upstream and downstream sites were compared across three periods – before crossing construction, during crossing construction, and after crossing construction – to elucidate potential impacts from the stream crossing construction. Additionally, the monitoring network was utilized to notify regulators of potentially anomalous conditions throughout the entire monitoring period. Results of this study indicate (1) at all six monitored streams, pipeline stream crossing construction did not affect long-term or short-term upstream-to-downstream water temperature conditions; (2) pipeline stream crossing construction did not affect long-term upstream-to-downstream turbidity conditions in all six monitored streams. Some short-term anomalously elevated turbidity conditions were observed and attributable to pipeline stream crossing construction; however, the duration and magnitude were not sufficient to alter the long-term turbidity regime of the streams in which they were observed; and (3) the application of the monitoring network as a real-time alert system successfully alerted regulators to potentially anomalous conditions.

EarthArXiv↗