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Hydrogeologic framework of the Virginia coastal plain

This report defines the hydrogeologic framework of the Virginia Coastal Plain and is a product of a comprehensive regional study to define the geology, hydrology, and geochemistry of the northern Atlantic Coastal Plain aquifer system extending from North Carolina to Long Island, New York. The Virginia Coastal Plain consists of an eastward-thickening wedge of generally unconsolidated, interbedded sands and clays, ranging in age from Early Cretaceous to Holocene. These sediments range in thickness from more than 6,000 feet beneath the northeastern part of the Eastern Shore Peninsula to nearly 0 feet along the Fall Line. Eight confined aquifers, eight confining units, and an uppermost water table aquifer are delineated as the hydrogeologic framework of the Coastal Plain sediments in Virginia. The nine regional aquifers, from oldest to youngest, are lower, middle, and upper Potomac, Brightseat, Aquia, Chickahominy-Piney Point, St. Marys-Choptank, Yorktown-Eastover, and Columbia. The Brightseat is a newly identified and correlated aquifer of early Paleoceneage. This study is one of other, similar studies of the Coastal Plain areas in North Carolina, Maryland-Delaware, New Jersey, and Long Island, New York. These combined studies provide a system of hydrogeologic units that can be identified and correlated throughout the northern Atlantic Coastal Plain. Data for this study were collected and analyzed from October 1979 to May 1983. The nine aquifers and eight confining units are identified and delineated by use of geophysical logs, drillers' information, and stratigraphic and paleontologic data. By correlating geophysical logs with hydrologic, stratigraphic, and paleontologic data throughout the Coastal Plain, a comprehensive multilayered framework of aquifers and confining units, each with distinct lithologic properties, was developed. Cross sections show the stratigraphic relationships of aquifers and confining units in the hydrogeologic framework of the Virginia Coastal Plain. Maps show confining-unit thicknesses and altitudes of aquifer tops, provide the basis for assigning aquifers to screened intervals of observation and production wells, and are used for the development of a comprehensive observation-well network in the Virginia Coastal Plain.

Virginia↗

Conceptualization and analysis of ground-water flow system in the Coastal Plain of Virginia and adjacent parts of Maryland and North Carolina

This report presents the results of a study of the ground-water flow system in the Coastal Plain of Virginia and adjacent parts of Maryland and North Carolina. The ground-water flow system consists of water-table aquifer and an underlying sequence of confined aquifers and intervening confining units composed of unconsolidated sand and clay .Water levels have declined steadily, and cones of depression have expanded and coalesced around major ground-water withdrawal centers. A digital flow model was developed to enhance knowledge of the behavior of the ground-water flow system in response to its development. Transmissivity and vertical leakance maps were developed for each aquifer and confining unit. The model was calibrated to simulate ground-water flow within the system under both prepumping and pumping conditions. Simulated prepumping potentiometric-surface maps indicate that regional movement of ground water was from the Fall Line toward coastal areas and that local movement of ground water was from interfluves toward major river valleys. Maps of simulated prepumping flow across confining units show that most recharge occurred in narrow bands approximately parallel to the Fall Line and under interfluves and that discharge was toward major river valleys and coastal water. Simulated prepumping rates of recharge into the confined aquifer system from the water-table aquifer varied up to 3 .2 inches per year (in/yr), and rates of discharge out of the confined system varied up to 2.8 in/yr. Ten pumping periods covering 90 years (yr) of withdrawal simulated the history of ground-water development. Simulated potentiometric-surface maps for 1980 show lowered water levels and the development of coalescing cones of depression around the cities of Franklin, Suffolk, and Williamsburg and the town of West Point, all in Virginia. The largest simulated decline in water level, about 210 feet (ft) ,was near Franklin. Water budgets indicate that over the period of simulation (1891-1980) (1) pumpage from the model area increased by about 105 million gallons per day (Mgal/d), (2) lateral boundary outflow increased by about 5 Mgal/d, (3) ground-water flow to streams and coastal water decreased by about 107.5 Mgal/d, (4) lateral boundary inflow increased by about0.7 Mgal/d, and (5) water released from aquifer storage increased by about 1 .6 Mgal/d. The difference between total inflow and total outflow is the numerical truncation error of the digital simulation. Analysis of water budgets for individual confined aquifers shows that the major source of water supplied to wells was vertical leakage induced through confining units by pumping. Simulated rates of recharge into the confined aquifer system at the end of the final pumping period (1980) varied up to 3.8in/yr,and simulated rates of discharge out of the confined system varied up to 2.2in/yr. Results of simulations show an increase of about 110Mgal/d into the confined system from the unconfined system over the period of simulation. This increase in flow into the confined system affected local discharge of ground water to streams and regional discharge to coastal water. Withdrawal of groundwater from the confined aquifers also induced brackish water from Chesapeake Bay into the confined system. Results of sensitivity analyses indicate that simulated water levels are more sensitive to decreases in aquifer transmissivity and confining unit vertical hydraulic conductivity than to increases in these properties. Lowering the storage coefficient of an aquifer had minimal effect on simulated water levels, whereas increasing the storage coefficient had a much more significant effect. The effect of confining unit storage is shown to be insignificant if it is assumed that the water released from confining unit storage is attributable to the compressibility of water only.

Maryland, North Carolina, Virginia↗

Ground-water flow in the New Jersey Coastal Plain

Ground-water flow in 10 aquifers and 9 intervening confining units of the New Jersey Coastal Plain was simulated as part of the Regional Aquifer System Analysis. Data on aquifer and confining unit characteristics and on pumpage and water levels from 1918 through 1980 were incorporated into a multilayer finite-difference model. The report describes the conceptual hydrogeologic model of the unstressed flow systems, the methods and approach used in simulating flow, and the results of the simulations.

Delaware, New Jersey↗

Hydrogeologic framework of the North Carolina coastal plain

The hydrogeologic framework of the North Carolina Coastal Plain aquifer system consists of 10 aquifers separated by 9 confining units. From top to bottom, the aquifers are the surficial aquifer, Yorktown aquifer, Pungo River aquifer, Castle Hayne aquifer, Beaufort aquifer, Peedee aquifer, Black Creek aquifer, upper Cape Fear aquifer, lower Cape Fear aquifer, and Lower Cretaceous aquifer. The uppermost aquifer (the surficial aquifer in most places) is a water-table aquifer, and the bottom of the system is underlain by crystalline bedrock. The sedimentary deposits forming the aquifers are of Holocene to Cretaceous age and are composed mostly of sand, with lesser amounts of gravel and limestone. The confining units between the aquifers are composed primarily of clay and silt. The thickness of the aquifers ranges from zero along the Fall Line to more than 10,000 feet at Cape Hatteras. Prominent structural features are the increasing easterly homoclinal dip of the sediments and the Cape Fear arch, the axis of which trends in a southeast direction. Stratigraphic continuity was determined from correlations of 161 geophysical logs along with data from drillers? and geologists? logs. Aquifers were defined by means of these logs as well as water-level and water-quality data and evidence of the continuity of pumping effects. Eighteen hydrogeologic sections depict the correlation of these aquifers throughout the North Carolina Coastal Plain.

North Carolina↗

Simulation of ground-water flow of the coastal plain aquifers in parts of Maryland, Delaware, and the District of Columbia

Geomorphic processes and the aquatic habitat of the Redwood Creek basin were studied extensively between 1973 and 1983. This volume contains 22 separate articles by 32 investigators who studied geology, major storms, timber harvesting and its role on accelerating erosion, mass movement, fluvial erosion, sediment transport and storage, stream channel response to storms and landuse, stream habitat, and stream chemistry. This research describes a rapidly eroding landscape that is sensitive to effects of both landuse and major storms.

Delaware, District of Columbia, Maryland↗

Geochemistry of the northern Atlantic Coastal Plain aquifer system

Sediments of the northern Atlantic Coastal Plain comprise a complex multiaquifer flow system. On a large scale (greater than 500 square miles) ground water in this system evolves from predominantly calcium magnesium bicarbonate water with a low dissolved-solids content and low pH, near outcrop-recharge areas, to predominantly sodium bicarbonate water with a high-dissolved solids content and high pH, downgradient. This sodium bicarbonate water then grades into a sodium chloride water. This large-scale predictable progression of hydrochemical facies results from the summation of many smaller scale geochemical processes that chiefly depend on the sedimentary depositional environments of the aquifers.

Northern Atlantic coastal plain↗

Simulation of ground-water flow in the Coastal Plain aquifer system of North Carolina

A three-dimensional finite-difference digital model was used to simulate ground-water flow in the 25,000-square-mile aquifer system of the North Carolina Coastal Plain. The model was developed from a hydrogeologic framework that is based on an alternating sequence of 10 aquifers and 9 confining units, which make up a seaward-thickening wedge of sediments that form the Coastal Plain aquifer system in the State of North Carolina. The model was calibrated by comparing observed and simulated water levels. The model calibration was achieved by adjusting model parameters, primarily leakance of confining units and transmissivity of aquifers, until differences between observed and simulated water levels were within acceptable limits, generally within 15 feet. The maximum transmissivity of an individual aquifer in the calibrated model is 200,000 feet squared per day in a part of the Castle Hayne aquifer, which consists predominantly of limestone. The maximum value for simulated vertical hydraulic conductivity in a confining unit was 2.5 feet per day, in a part of the confining unit overlying the upper Cape Fear aquifer. The minimum value was 4.1x10-6 feet per day, in part of the confining unit overlying the lower Cape Fear aquifer. Analysis indicated the model is highly sensitive to changes in transmissivity and leakance near pumping centers; away from pumping centers, the model is only slightly sensitive to changes in transmissivity but is moderately sensitive to changes in leakance. Recharge from precipitation to the surficial aquifer ranges from about 12 inches per year in areas having clay at the surface to about 20 inches per year in areas having sand at the surface. Most of this recharge moves laterally to streams, and only about 1 inch per year moves downward to the confined parts of the aquifer system. Under predevelopment conditions, the confined aquifers were generally recharged in updip interstream areas and discharged through streambeds and in downdip coastward areas. Hydrologic analysis of the flow system using the calibrated model indicated that, because of ground-water withdrawals, areas of ground-water recharge have expanded and encroached upon some major stream valleys and into coastal area. Simulations of pumping conditions indicate that by 1980 large parts of the former coastal discharge areas had become areas of potential or actual recharge. Declines of ground-water level, which are the result of water taken from storage, are extensive in some areas and minimal in others. Hydraulic head declines of more than 135 feet have occurred in the northern Coastal Plain since 1940 primarily due to withdrawals in the Franklin area in Virginia. Declines of ground-water levels greater than 110 feet have occurred in aquifers in the central Coastal Plain due to combined effects of pumpage for public and industrial water supplies. Water-level declines exceeding 100 feet have occurred in the Beaufort County area because of withdrawals for a mining operation and water supplies for a chemical plant. Head declines have been less than 10 feet in the shallow surficial and Yorktown aquifers and in the updip parts of the major confined aquifers distant from areas of major withdrawals. In 1980, contribution from aquifer storage was 14 cubic feet per second, which is about 4.8 percent of pumpage and about 0.05 percent of ground-water recharge. A water-budget analysis using the model simulations indicates that much of the water removed from the ground-water system by pumping ultimately is made up by a reduction in water leaving the aquifer system, which discharges to streams as base flow. The reduction in stream base flow was 294 cubic feet per second in 1980 and represents about 1.1 percent of the ground-water recharge. The net reduction to streamflow is not large, however, because most pumped ground water is eventually discharged to streams. In places, such as at rock quarries in Onslow and Craven Counties, water is lost from st

North Carolina↗

Summary of ground-water hydrology of the Cambrian-Ordovician aquifer system in the northern Midwest, United States

The Cambrian-Ordovician aquifer system contains very productive aquifers throughout an area of about 161,000 square miles in the northern Midwest. The aquifer system is used extensively for industrial and rural water supplies and is the primary source of water for many municipalities in most of its area of occurrence, except in Indiana, central and southern Illinois, and western Iowa, where the aquifer system contains saline water. About 680 million gallons per day was withdrawn from drilled wells in the aquifer system in 1980. Rocks of Cambrian and Ordovician age, mainly marine sandstones and carbonate rocks, constitute most of the bedrock and subcrop beneath glacial drift in southeastern Minnesota, northeastern Iowa, Wisconsin, northern Illinois, and extreme northwestern Indiana. These strata dip generally to the south and east off the Transcontinental arch in Minnesota and the Wisconsin arch, which are structurally high areas of the Precambrian basement, into the structural lows of the Forest City basin of southwestern Iowa, the Illinois basin, and the Michigan basin. The Cambrian and Ordovician rocks are buried by younger rocks in the remainder of Iowa, Illinois, and Indiana and in most of northern Missouri. Silurian and Devonian carbonate rocks immediately overlie the Cambrian and Ordovician rocks in those areas and are termed the "Silurian-Devonian aquifer" in this study. The balance of the Devonian rocks and the overlying Mississippian and Pennsylvanian rocks generally are fine-grained sediment or dense carbonate rocks and collectively are considered to be a regional confining unit. Most of the area is covered by a veneer of glacial drift, which, along with Cretaceous sandstone in northwestern Iowa, is treated as a regional water-table aquifer. The Cambrian-Ordovician aquifer system is composed of six hydrogeologic units, which are, in descending order, the Maquoketa confining unit, St. Peter-Prairie du Chien-Jordan aquifer, St. Lawrence- Franconia confining unit, Ironton-Galesville aquifer, Eau Claire confining unit, and Mount Simon aquifer. The uppermost confining unit is the least permeable; it consists primarily of the Maquoketa Shale but includes the dense carbonate rocks of the Galena Dolomite and the Decorah, Platteville, and Glenwood Formations where they are overlain by the Maquoketa Shale. The presence of the Maquoketa in Iowa, eastern Wisconsin, northeastern Illinois, and Indiana effectively confines the entire aquifer system below. The aquifer system is a leaky-artesian system in which movement of ground water is controlled partly by the internal confining units. In the northern outcrop area, unconfined conditions prevail in shallow parts of the aquifer system and where the system is thin. Much of the recharge in upland areas discharges to streams through local flow systems, which are no more than a few miles in length. The remainder of the recharge moves slowly downward to deeper formations and downgradient to form or join the regional flow system. Computer simulations of regional ground-water flow improve understanding of the regional character of the Cambrian-Ordovician aquifer system. Ground-water flow in the confined part of the aquifer system is mainly horizontal, away from the structural highs in the north, toward the structural basins in the south and east. The rate of ground-water movement is very slow, and the flux along flow paths into the basins decreases because of a progressive loss of head and small but widespread upward leakage. Saline water in the basins restricts movement of freshwater into the deeper parts of the basins, thereby forcing flow upward through confining units. Principal regional discharge areas are the Mississippi and Missouri Rivers, the Illinois and Michigan structural basins, and Lake Michigan. However, the lake is not in direct hydraulic connection with the Cambrian-Ordovician aquifer system and receives flow primarily from the Silurian-Devonian aquifer, which it directly overlies. The longest regional flow paths originate in recharge areas in northwestern Iowa and extend southeastward as much as 400 miles toward the Illinois basin. Simulated predevelopment recharge and discharge for the Cambrian- Ordovician aquifer system balance at 351 million gallons per day. Development of the aquifer system began in various parts of the northern Midwest in the 1860's and 1870's with the drilling of deep, generally flowing artesian wells near Lake Michigan in eastern Wisconsin and northeastern Illinois and along the valleys of the Mississippi River and its tributaries. Initial heads of 186 and 130 feet above Lake Michigan at Milwaukee and Chicago, respectively, have been reported. Large-scale pumping has produced cones of depression in these two areas, with respective head declines of as much as 375 and 900 feet. Other major pumping centers generally have had much smaller declines. The largest withdrawals from the aquifer system were about 180 million gallons per day in each of the major metropolitan areas of Chicago and Minneapolis-St. Paul (Twin Cities). However, the total decline in head in the St. Peter-Prairie du Chien-Jordan aquifer in the Twin Cities by 1980 was only 90 feet because the aquifer is unconfined. Most of the eastern two-thirds of Iowa, where the aquifer system is tightly confined, is characterized by more than 50 feet of head decline, with 200 feet or more at Mason City and the Quad Cities. Pumpage from the Cambrian-Ordovician aquifer system throughout the study area averaged 683 million gallons per day for the period 1976-80. Results of a transient-model simulation show that recharge increased over predevelopment recharge by 447 million gallons per day. Natural discharge decreased by 99 million gallons per day, and 137 million gallons per day was released from aquifer storage. Mineralization of ground water in the aquifer system increases from slightly mineralized calcium magnesium bicarbonate water in the northern recharge areas, through more mineralized, mixed water types with increased sodium and sulfate, to highly mineralized sodium chloride brines in the deeper parts of the structural basins.

Iowa, Illinois, Indiana, Michigan, Minnesota, Miss↗

Hydrogeology of the Cambrian-Ordovician aquifer system in the northern Midwest, United States with a section on ground-water quality

The Cambrian-Ordovician aquifer system contains the most extensive and continuous aquifers in the northern Midwest of the United States. It is the source of water for many municipalities, industries, and rural water users. Since the beginning of ground-water development from the aquifer system in the late 1800's, hydraulic heads have declined hundreds of feet in the heavily pumped Chicago-Milwaukee area and somewhat less in other metropolitan areas. The U.S. Geological Survey has completed a regional assessment of this aquifer system within a 161,000-square-mile area encompassing northern Illinois, northwestern Indiana, Iowa, southeastern Minnesota, northern Missouri, and Wisconsin. Consolidated sedimentary rocks in the northern Midwest range in age from Precambrian to Cretaceous and crop out in generally concentric, arcuate patterns, dipping away from structural highs (arches) on the Precambrian basement in northern Minnesota and Wisconsin toward structural lows (basins) to the south and east. The sedimentary bedrock is generally overlain by a veneer of glacial drift. Thickness of the sedimentary sequence increases to about 5,000 feet in the Forest City basin of southwestern Iowa and to about 14,000 and more than 15,000 feet in the Illinois and Michigan basins, respectively. Cambrian and Ordovician age rocks, mainly marine sandstone and carbonate rocks, compose much of the sedimentary sequence and form the Cambrian-Ordovician aquifer system. The aquifer system lies on the Precambrian basement, regarded as a regional confining unit. Six hydrogeologic units are defined; they are arranged as alternating pairs of an aquifer and an overlying confining. unit. The units are named using the predominant geologic nomenclature of the upper Mississippi Valley, which includes most of the study area. In the southern quarter of the area, the hydrogeologic units consist of equivalent formations of the Ozark area (mostly carbonate rocks). The uppermost part of the aquifer system is the Maquoketa confining unit, which consists of the Maquoketa Shale and the underlying dolomite and shale of the Galena Dolomite and the Decorah, Platteville, and Glenwood Formations. The underlying St. Peter-Prairie du Chien-Jordan aquifer is an important source of ground water in the western part of the area in Iowa and Minnesota, where the uniform Jordan Sandstone is hydraulically connected to overlying fractured dolomite of the Prairie du Chien Group. The unit is less important in the eastern part of Wisconsin and Illinois because the Jordan Sandstone is absent and the Prairie du Chien Group is thin or absent due to pre-St. Peter Sandstone erosion. Equivalent rocks in northern Missouri-the Roubidoux Formation and the Gasconade and Eminence Dolomites-are mainly carbonate rocks that are somewhat permeable and contain some sandstone. The St. Lawrence and Franconia Formations underlying the St. Peter-Prairie du Chien-Jordan aquifer consist generally of silty and shaly, fine-grained, poorly sorted, and dolomitic sandstones that restrict vertical movement of ground water and form a regional confining unit. In the southern and eastern parts of the area, the Potosi and Derby-Doerun Dolomites and the upper part of the Davis Formation are the equivalent rocks (mainly carbonate rocks). In the east-central part of the area in Illinois and Wisconsin, the Ironton-Galesville aquifer forms the most important aquifer of the Cambrian-Ordovician aquifer system, contributing about one-third of the yield from wells in the aquifer system in the Chicago area. The aquifer terminates to the west, south, and east, where the sandstones grade into less permeable carbonate rocks in central Iowa, central Illinois, and northwestern Indiana, respectively. The underlying Eau Claire Formation and its partial equivalent to the southwest, the Bonneterre Formation, form an important confining unit above the Mount Simon aquifer throughout much of the study area. Siltstone and shale are fairly common in the upper part of the Eau Claire Formation but less so in its northernmost extent in Wisconsin. Dolomite content increases southward and westward, where a middle dolomite facies grades laterally into the Bonneterre in Missouri, southwestern Minnesota, extreme south-central Wisconsin, and possibly in western Iowa. The basal unit in the Cambrian-Ordovician aquifer system, the Mount Simon aquifer, is present throughout the study area, except where it is absent over local highs of the Precambrian basement. It consists primarily of the Mount Simon Sandstone in the north and its equivalent in northern Missouri, the Lamotte Sandstone. The underlying Hinckley Sandstone of Precambrian age is included in Minnesota, as is the overlying Elmhurst Sandstone Member of the Eau Claire Formation in northern Illinois. The aquifer increases greatly in thickness and the water is progressively more saline away from the northern structural highs toward the basins. Much of the movement and discharge of ground water in the northern Midwest occurs in local, unconfined, shallow flow systems within a few miles of points of recharge. The rest of the water is semiconfined or confined in intermediate or regional flow systems within the bedrock, where flow is deeper, slower, and traverses much longer distances from recharge areas to discharge areas. The major areas of recharge to regional confined flow are in northwestern Iowa, southeastern Minnesota, western, southern, and eastern Wisconsin, and northern Illinois. Although the rate of flow is small, significant recharge to the Cambrian-Ordovician aquifer system also occurs as leakage through the Maquoketa confining unit, where the vertical hydraulic gradient is downward. Ground water in much of the confined aquifer system moves laterally from recharge areas toward the major river valleys and Lake Michigan or down dip toward the structural basins. The longest flow paths extend as much as 400 miles from northwestern Iowa southeast toward the Illinois basin or to the Mississippi River and Missouri River valleys near their confluence. Other major confined flow is from eastern Wisconsin toward the Michigan basin and southward flow from northeastern Illinois toward the Illinois basin. Regional ground-water discharge from the aquifer system is mainly diffuse upward leakage from confined aquifers along flow paths toward the structural basins. Very saline water around and brines within the basins restrict regional flow into the basins, forcing ground water to discharge upward. Water in intermediate flow systems discharges upward to the major river valleys. Original heads of more than 100 feet above land surface were recorded in the aquifer system near Lake Michigan in eastern Wisconsin and at Dubuque, Iowa, along the Mississippi River. The Cambrian-Ordovician aquifer system was developed rapidly in the late 1800's after the first deep well was drilled in Chicago in 1864. Many flowing wells were not controlled, which caused water levels in deep wells to decline, and many no longer flowed by the early 1900's. Heads in the aquifers have declined very little in most of the recharge or unconfined areas since ground-water withdrawal began, but major declines have occurred in confined areas. The largest declines in head are at Chicago, Illinois, Milwaukee and Green Bay, Wisconsin, and Mason City, Iowa, where the aquifer system is confined by the Maquoketa confining unit. The composite head in the aquifer system declined more than 900 feet in the deepest cones of depression in the Chicago area from 1864 to 1980 and about 375 feet in the cone at Milwaukee from 1880 to 1980. More than 200 feet of decline has occurred at Mason City. The head declined as much as 440 feet in Green Bay from 1886 to 1957, when the city discontinued use of its deep wells and began using water from Lake Michigan. The largest centers of pumping are in the Chicago and Twin Cities (Minneapolis-St. Paul, Minnesota) metropolitan areas about 180 million gallons per day each in 1980. Pumpage exceeded 10 million gallons per day in only a few other areas in 1980. Ground water in the Cambrian-Ordovician aquifer system in the northern Midwest is characterized by an extreme range of mineralization, but its quality in most of the area is good. The major cations are calcium, magnesium, and sodium, and the major anions are bicarbonate, sulfate, and chloride. Sodium, sulfate, and chloride distributions are closely related to the distribution pattern of dissolved solids but not in the same proportion. Dissolved-solids concentration is generally less than 1,000 milligrams per liter in the recharge areas of Wisconsin, southern Minnesota, northeastern Iowa, and north-central Illinois where the aquifer system crops out or subcrops beneath glacial drift. Ground water there is the Ca-Mg-HC03 type, derived from and identical to that in the overlying glacial drift. In northwestern Iowa and southwestern Minnesota, the water in both the glacial drift and the Cambrian-Ordovician aquifer system is a Ca-Na-S04HC03 type, derived from oxidation of pyrite in the overlying Cretaceous Dakota Formation. Transition to higher dissolved solids in the confined areas commonly is accompanied by increased sulfate concentration and· the occurrence of Ca-Na-S04-type water. Salinity of the ground water increases progressively toward the .basins, where dissolved solids exceed 200,000 milligrams per liter. Saline water is present in the Mount Simon aquifer near Lake Michigan in eastern Wisconsin and northeastern Illinois but occurs in successively younger rocks to the east and south as they dip toward the basins. Similarly, salinity increases down dip in Iowa to the southwest and south; however, regional ground-water flow in Iowa is from northwest to southeast. Much of the ground water in the confined aquifer system is isotopically depleted in 0180 and OD with respect to modern precipitation-an indication that the water originated as precipitation in a much colder climate than the present and probably was derived from recharge of glacial meltwater. On the basis of o34S values for sulfur in sulfate, it is believed that isostatic loading from glacial ice over the Michigan basin reversed the hydraulic gradient to trend westward, opposite from the present gradient, causing saline water in the Michigan basin to discharge westward through the present recharge areas. Natural water-quality problems in the Cambrian-Ordovician aquifer system are mainly the high dissolved-solids concentrations and associated high concentrations of sulfate and chloride, which limit the use of the water for municipal and domestic purposes in much of the confined aquifer system in central and southern Illinois, Indiana, southern and western Iowa, and northern Missouri. Another concern is that radium activity exceeds normal background concentrations of a few picocuries per liter in much of the confined aquifer system in eastern Wisconsin, northeastern Illinois, and central Iowa. Other common problems are high hardness and locally excessive concentrations of iron and hydrogen sulfide.

Iowa, Illinois, Indiana, Michigan, Minnesota, Miss↗

Simulation of regional ground-water flow in the Cambrian-Ordovician aquifer system in the northern Midwest, United States: in Regional aquifer-system analysis

A six-State area in the northern Midwest of the United States has become increasingly dependent on ground water from the Cambrian-Ordovician aquifer system, which consists of a sequence of sandstones, carbonate rocks, and shales. Ground-water withdrawals from the aquifer system began in the late 1800's and increased to approximately 684 million gallons per day (1,058 cubic feet per second) by 1980. This withdrawal has caused more than 900 feet of decline in the potentiometric surface of the aquifer system in parts of the Chicago, Ill., area. Pumping in Minneapolis-St. Paul, Minn., Milwaukee, Wis., and central Iowa has produced a few hundreds of feet of water-level decline. A quasi-three-dimensional ground-water flow model was developed to improve understanding of the regional ground-water flow system by simulating the aquifer system under the conditions that existed before and during ground-water development. The Cambrian-Ordovician aquifer system and the overlying rocks were incorporated in the conceptual model as five aquifer layers with four intervening confining layers. The aquifer layers, from top to bottom, are as follows: Quaternary deposits and Cretaceous rocks (aquifer layer 5); basal Devonian carbonate rocks and underlying Silurian carbonate rocks (aquifer layer 4); Middle Ordovician St. Peter Sandstone, Lower Ordovician Prairie du Chien Group, and Upper Cambrian Jordan Sandstone (aquifer layer 3); Upper Cambrian Ironton and Galesville Sandstones (aquifer layer 2); and Upper Cambrian Mount Simon Sandstone and Precambrian Hinckley Sandstone (aquifer layer 1). The effects on the flow system of ground water having variable density and the individual aquifer layer contribution of flow to wells open to several aquifer layers were simulated by incorporating appropriate terms in the ground-water flow equation and corresponding modifications in the ground-water flow model. Results of steady-state simulations are shown as maps of freshwater head and as flow-rate vectors. A comparison was made of available predevelopment head data and simulated predevelopment heads for the Mount Simon, St. Peter-Prairie du Chien-Jordan, and Silurian-Devonian aquifers. The root mean square of the differences between observed and simulated heads for these aquifers was 53, 36, and 44 feet, respectively. Steady-state model simulation indicates that regional recharge areas are located in northwestern Iowa, southeastern Minnesota, much of Wisconsin, northern Illinois, and central Missouri. Regional discharge areas are located near the Mississippi River and its tributaries, the Missouri River, Lake Michigan, and the Illinois basin. Results of a transient simulation of the period 1861 to 1980 are shown as maps of freshwater head and freshwater-head decline. The root mean square of the differences between observed and simulated heads for the St. Peter-Prairie du Chien-Jordan aquifer was 63 feet. In addition, hydrographs of simulated hydraulic head were compared with hydrographs of observed head in wells open to various combinations of aquifers. The numerous head measurements within a model node display a wide range in magnitude; however, their historical trend generally follows the trend of the simulated heads. The simulated recharge from the glacial drift to the immediately underlying bedrock aquifers averages 0.03, 0.06, 0.24, and 0.02 inch per year, respectively, to the Mount Simon, Ironton-Galesville, St. Peter- Prairie du Chien-Jordan, and Silurian-Devonian aquifers for predevelopment conditions and 0.03, 0.07, 0.45, and 0.07 inch per year, respectively, to the same aquifers for 1976-80. These recharge rates are less than 1.5 percent of average annual precipitation of about 30 inches per year. Most of the recharge from precipitation discharges to streams as base flow through local and intermediate ground-water flow systems. Only a small fraction of the precipitation recharges the deeper, regional flow system. The simulated predevelopment recharge of 571 cubic feet per second is balanced by an equivalent discharge. For the period 1976-80, simulated recharge increased to 1,398 cubic feet per second. Total discharge, including pumpage from the four bedrock aquifers, increased to 1,619 cubic feet per second. The difference in recharge and discharge during this period is from aquifer storage. Results of variable-density simulations indicate that the rate of ground-water movement is small in areas where ground water is highly mineralized. The rates and directions are controlled by the intrinsic permeability of the rock, freshwater head gradients, and gravitational force.

Iowa, Illinois, Indiana, Michigan, Minnesota, Miss↗

Geochemistry of the Cambrian-Ordovician aquifer system in the northern Midwest, United States: D in Regional aquifer-system analysis

Distributions of solutes in aquifers of Cambrian and Ordovician age were studied in Minnesota, Wisconsin, Iowa, Illinois, northwestern Indiana, and northern Missouri to determine the sources of solutes and the probable chemical mechanisms that control regional variations in water quality. This work is part of the Northern Midwest Regional Aquifer-System Analysis project, whose objective is to describe and model the regional hydrogeology of the Cambrian- Ordovician aquifer system in the study region. The data base used included more than 3,000 ground-water-quality analyses from all major aquifers, but especially from the St. Peter, Jordan, and Mount Simon Sandstones and their equivalents. Regional variations in the water chemistry of glacial drift and other sedimentary units that overlie the Cambrian-Ordovician aquifer system in recharge areas in Minnesota, Iowa, Wisconsin, and Illinois were also studied, but to a lesser degree. The most important chemical variation in the aquifer is the change in water type from calcium-sodium-sulfate-bicarbonate water to sodium-calcium-sulfate-bicarbonate and sodium-chloride waters along the longest regional flow path from northwestern Iowa to the Illinois basin. Sodium predominance downgradient from the recharge area is probably related to mechanisms of ion exchange and shalemembrane filtration near the Illinois and Forest City basins. The most striking aspect of the distribution of dissolved solids and carbon isotopic content of bicarbonate is the increase in concentration and isotopic enrichment from southwestern Wisconsin, southern Minnesota, and northwestern Illinois south toward Missouri. This trend is perpendicular to the present hydraulic gradient that trends from northwestern Iowa southeastward to the Illinois basin. The distribution of dissolved solids defines a "plume" of dilute water having a dissolved-solids concentration of about 500 milligrams per liter, compared with surrounding concentrations more than twice as large. Distribution of the isotopic content of oxygen (<518O) and hydrogen (5D) in water closely parallels that of dissolved solids and shows covariance similar to modern meteoric water. The isotopic contents are more depleted (lighter) toward the south, perpendicular to the direction of current hydraulic gradients. The degree of depletion, compared with the isotopic content of modern recharge water, indicates that the plume and a significant fraction of the ground water in Iowa, northern Missouri, and possibly central Illinois may have originated as recharge during Pleistocene time. Distributions of dissolved trace constituents in the aquifers probably are related to the proximity to mineralogic sources as well as chemical and hydraulic mechanisms. For example, concentrations of some constituents, such as cadmium and arsenic, are largest in the vicinity of the Dakota Formation in northwestern Iowa. Other constituents, such as beryllium and vanadium, have larger concentrations near the edge of the Forest City basin in southwestern Iowa and northwestern Missouri. Strontium and fluoride concentrations generally increase from north to south, which suggests the input of these trace constituents during the recharge events. However, concentrations of bromide, radium-226, and lithium show distribution patterns similar to the "plume" defined by dissolved solids and isotopes of water, suggesting dilution of concentrations of trace constituents by Pleistocene recharge. Concentrations of other constituents are partly controlled by aquifer temperature, such as silica in south-central Iowa, and solubility controls, such as barium in northeastern Illinois. Additional information on the chemical and mineralogical composition of the aquifer matrix and the isotopically lightest ground water is needed to evaluate the hypothesis of Pleistocene mixing before more quantitative studies can be done to evaluate the different proposed mechanisms that have controlled and modified the water chemistry over time. This study, however, indicates that the ground water in the region is thousands of years old. The study also indicates that the major chemical trends in the aquifers probably are related as much to paleohydrogeologic flow systems during Pleistocene time as to the present flow system, which may postdate the retreat of the last ice sheet about 12,000 years ago.

Iowa, Indiana, Illinois, Michigan, Minnesota, Miss↗

Summary of the Southwest Alluvial Basins, Regional Aquifer-System Analysis, south-central Arizona and parts of adjacent states

The 72 basins of the 82,000-square-mile study area were grouped into five broad categories on the basis of their geohydrologic characteristics. Water-resources development has resulted in depletion of surface flow in several basins and overdraft of ground water in most developed basins. In places, water levels have declined more than 400 feet; declines of 50 to 200 feet are common in developed basins. Ground-water flow and geochemical models were developed for representative basins.

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Geochemistry of ground water in alluvial basins of Arizona and adjacent parts of Nevada, New Mexico, and California

Chemical and isotope analyses of ground water from 28 basins in the Basin and Range physiographic province of Arizona and parts of adjacent States were used to evaluate ground-water quality, determine processes that control ground-water chemistry, provide independent insight into the hydrologic flow system, and develop information transfer. The area is characterized by north- to northwest-trending mountains separated by alluvial basins that form a regional topography of alternating mountains and valleys. On the basis of ground-water divides or zones of minimal basin interconnection, the area was divided into 72 basins, each representing an individual aquifer system. These systems are joined in a dendritic pattern and collectively constitute the major water resource in the region. Geochemical models were developed to identify reactions and mass transfer responsible for the chemical evolution of the ground water. On the basis of mineralogy and chemistry of the two major rock associations of the area, a felsic model and a mafic model were developed to illustrate geologic, climatic, and physiographic effects on ground-water chemistry. Two distinct hydrochemical processes were identified: (1) reactions of meteoric water with minerals and gases in recharge areas and (2) reactions of ground water as it moves down the hydraulic gradient. Reactions occurring in recharge and downgradient areas can be described by a 13-component system. Major reactions are the dissolution and precipitation of calcite and dolomite, the weathering of feldspars and ferromagnesian minerals, the formation of montmorillonite, iron oxyhydroxides, and probably silica, and, in some basins, ion exchange. The geochemical modeling demonstrated that relatively few phases are required to derive the ground-water chemistry; 14 phases-12 mineral and 2 gas-consistently account for the chemical evolution in each basin. The final phases were selected through analysis of X-ray diffraction and fluorescence data, aqueous speciation and saturation data, and mass-balance and isotopic constraints and through chemical models developed from mineral combinations among the 27 phases that were considered realistic in these geologically and mineralogically complex basins. X-ray diffraction of basin-fill sediments confirm the presence of the postulated minerals and their weathering sequences. High partial pressures of soil CO2 and large concentrations of dissolved CO2 in recharge areas, and the rapid depletion of CO2 downgradient, accompanied by high weathering rates of the silicates which also decrease downgradient, indicate that carbonic acid is the impetus in the weathering process. Reactions in the soil zone and the unsaturated zone are influential and, in some instances, are as important as the mineralogy of the source rock in determining ground-water compositions. The basins can be divided geochemically into two general categories-closed systems, which evolve under closed hydrologic conditions, and open systems, which are open to CO2 and other constituents along the flow path. The ground-water chemistry of the unconfined aquifers in the eastern part of the study area and of the aquifers underlying the flood plain along the Colorado River generally evolves under open conditions. The ground-water chemistry of most basins in the central and western parts and of the confined aquifers in the eastern part evolves under closed conditions. The factors that determine whether a basin is an open or closed system are the amount of and the spatial and seasonal distribution of annual precipitation and the presence or absence of fine-grained confining units. The basins along the Colorado River are unique among basins in the region. Virtually all ground water underlying the flood plain originated as seepage or overbank flow from the Colorado River. Initial deuterium content of about -120 per mil is indicative of precipitation from the central part of Colorado. Using chemical m

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