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USGS1989

Ground-water-quality-monitoring program in Iowa: Nitrate and pesticides in shallow aquifers

Concern exists about the occurrence of agricultural chemicals, primarily nitrate and pesticides, in shallow ground water. In response to this concern, the focus of the Iowa ground-water-quality-monitoring program has shifted to emphasize nonpoint contaminants. The program, which began in 1982, is operated by the U.S. Geological Survey in cooperation with the University of Iowa Hygienic Laboratory and the Iowa Department of Natural Resources, Geological Survey Bureau and Environmental Protection Division. The objectives are to describe and assess the long-term chemical quality of the principal aquifers in Iowa and to direct water-quality assessment and sampling toward regional ground-water-quality concerns. In the spring of 1985, emphasis was placed on the analysis of pesticides in water samples collected from wells completed in surficial aquifers in Quaternary deposits or from wells less than 200 feet deep or both. Samples from these wells were analyzed for nitrate and selected pesticides. In water samples collected from 515 individual shallow wells, 6 percent had nitrate concentrations larger than the maximum contaminant level for public drinking water of 10 milligrams per liter as nitrogen. The concentrations ranged from less than 0.1 to 53 milligrams per liter as nitrogen. Eighteen percent of the samples had concentrations of nitrate between 5 and 10 milligrams per liter as nitrogen. Water samples from 355 individual municipal wells less than 200 feet deep have been analyzed for pesticides at least once. Detectable concentrations of at least one pesticide, including alachlor, atrazine, cyanazine, dicamba, metolachlor, or metribuzin, were detected in 20 percent of the samples. Atrazine was the most prevalent pesticide; concentrations, which ranged from 0.10 to 21 micrograms per liter, were detected in 18 percent of the samples. The results of the monitoring program indicate a relation between decreasing well depth and the presence of detectable concentrations of nitrate and pesticides. Most nitrate and pesticide detection was in areas where surficial aquifers in Quaternary deposits are the principal source of ground water. Pesticides were detected in samples collected throughout the year; samples collected in late spring and early summer more frequently contained pesticides than the other samples.

Iowa↗

USGS1961

Geologic control of mineral composition of stream waters of the eastern slope of the Southern Coast Ranges, California

Chemical analyses of waters of streams that drain the semiarid eastern slope of the southern Coast Ranges in California demonstrate that differences in the anion composition, especially in the ratio of bicarbonate to sulfate, are related chiefly to the lithologic character of the rocks exposed in the tributary drainage area. Where more than hall the drainage area of a typical eastern-slope stream is underlain by clastic marine sedimentary rocks of Jurassic and Cretaceous age, bicarbonate generally predominates over sulfate; the ratio of bicarbonate to sullate, both expressed in equivalents per million, in samples of the streams at low-flow stage ranges from 0.8 to 6. Conversely, where more than hall the drainage area is underlain by marine and continental deposits of Tertiary age and continental deposits of Quaternary age, sulfate predominates over bicarbonate, and the ratio of bicarbonate to sulfate in samples taken during the low-flow stage ranges from 0.02 to 0.7. Organic siliceous marine shale of Tertiary age deposited in a reducing environment is probably the primary source of sullate in the region. Secondary deposits of sulfate minerals, chiefly gypsum, which are abundant in the continental deposits of late Tertiary and Quaternary age, also contribute sullate to the stream waters.

Water Supply Paper↗

USGS2013

History and evaluation of national-scale geochemical data sets for the United States

Six national-scale, or near national-scale, geochemical data sets for soils or stream sediments exist for the United States. The earliest of these, here termed the ‘Shacklette’ data set, was generated by a U.S. Geological Survey (USGS) project conducted from 1961 to 1975. This project used soil collected from a depth of about 20 cm as the sampling medium at 1323 sites throughout the conterminous U.S. The National Uranium Resource Evaluation Hydrogeochemical and Stream Sediment Reconnaissance (NURE-HSSR) Program of the U.S. Department of Energy was conducted from 1975 to 1984 and collected either stream sediments, lake sediments, or soils at more than 378,000 sites in both the conterminous U.S. and Alaska. The sampled area represented about 65% of the nation. The Natural Resources Conservation Service (NRCS), from 1978 to 1982, collected samples from multiple soil horizons at sites within the major crop-growing regions of the conterminous U.S. This data set contains analyses of more than 3000 samples. The National Geochemical Survey, a USGS project conducted from 1997 to 2009, used a subset of the NURE-HSSR archival samples as its starting point and then collected primarily stream sediments, with occasional soils, in the parts of the U.S. not covered by the NURE-HSSR Program. This data set contains chemical analyses for more than 70,000 samples. The USGS, in collaboration with the Mexican Geological Survey and the Geological Survey of Canada, initiated soil sampling for the North American Soil Geochemical Landscapes Project in 2007. Sampling of three horizons or depths at more than 4800 sites in the U.S. was completed in 2010, and chemical analyses are currently ongoing. The NRCS initiated a project in the 1990s to analyze the various soil horizons from selected pedons throughout the U.S. This data set currently contains data from more than 1400 sites. This paper (1) discusses each data set in terms of its purpose, sample collection protocols, and analytical methods; and (2) evaluates each data set in terms of its appropriateness as a national-scale geochemical database and its usefulness for national-scale geochemical mapping.

Conterminous United States↗

USGS1980

Quality of ground water in Routt County, northwestern Colorado

Chemical and bacteriological data were collected to describe the quality of water from selected geologic units in Routt County, Colo. Calcium bicarbonate was the dominant water-chemistry type; magnesium, sodium, and sulfate frequently occurred as codominant ions. Specific conductance values ranged from 50 to 6,000 micromhos. Mean values of specific conductance, dissolved solids , and hardness from the sampled aquifers were generally greatest in waters from the older sedimentary rocks of the Lance Formation, Lewis Shale, Mesaverde Group, and Mancos Shale, and least in the ground waters from the alluvial deposits, Browns Park Formation, and the basement complex. Correlations of specific conductance with dissolved solids and specific conductance with hardness were found within specified concentration ranges. On the basis of water-quality analyses, water from the alluvial desposits, Browns Park Formation, and the basement complex generally is the most suitable for domestic uses. Chemical constituents in water from wells or springs exceeded State and Federal standards for public-water supplies or State criteria for agricultural uses were pH, arsenic, boron, chloride, iron, fluoride, manganese, nitrite plus nitrate, selenium, sulfate, or dissolved solids. Total-coliform bacteria were detected in water from 29 sites and fecal-coliform bacteria were detected in water from 6 of the 29 sites. (USGS)

Water-Resources Investigations Report↗

USGS2015

Chemical concentrations and instantaneous loads, Green River to the Lower Duwamish Waterway near Seattle, Washington, 2013–15

In November 2013, U.S. Geological Survey streamgaging equipment was installed at a historical water-quality station on the Duwamish River, Washington, within the tidal influence at river kilometer 16.7 (U.S. Geological Survey site 12113390; Duwamish River at Golf Course at Tukwila, WA). Publicly available, real-time continuous data includes river streamflow, stream velocity, and turbidity. Between November 2013 and March 2015, the U.S. Geological Survey collected representative samples of water, suspended sediment, or bed sediment from the streamgaging station during 28 periods of differing flow conditions. Samples were analyzed by Washington-State-accredited laboratories for a large suite of compounds, including metals, dioxins/furans, semivolatile compounds including polycyclic aromatic hydrocarbons, pesticides, butytins, polychlorinated biphenyl (PCB) Aroclors and the 209 PCB congeners, volatile organic compounds, hexavalent chromium, and total and dissolved organic carbon. Metals, PCB congeners, and dioxins/furans were frequently detected in unfiltered-water samples, and concentrations typically increased with increasing suspended-sediment concentrations. Chemical concentrations in suspendedsediment samples were variable between sampling periods. The highest concentrations of many chemicals in suspended sediment were measured during summer and early autumn storm periods. Median chemical concentrations in suspended-sediment samples were greater than median chemical concentrations in fine bed sediment (less than 62.5 µm) samples, which were greater than median chemical concentrations in paired bulk bed sediment (less than 2 mm) samples. Suspended-sediment concentration, sediment particle-size distribution, and general water-quality parameters were measured concurrent with the chemistry sampling. From this discrete data, combined with the continuous streamflow record, estimates of instantaneous sediment and chemical loads from the Green River to the Lower Duwamish Waterway were calculated. For most compounds, loads were higher during storms than during baseline conditions because of high streamflow and high chemical concentrations. The highest loads occurred during dam releases (periods when stored runoff from a prior storm is released from the Howard Hanson Dam into the upper Green River) because of the high river streamflow and high suspended-sediment concentration, even when chemical concentrations were lower than concentrations measured during storm events.

Washington↗

USGS2011

Endocrine active chemicals, pharmaceuticals, and other chemicals of concern in surface water, wastewater-treatment plant effluent, and bed sediment, and biological characteristics in selected streams, Minnesota: Design, methods, and data, 2009

This report presents the study design, environmental data, and quality-assurance data for an integrated chemical and biological study of selected streams or lakes that receive wastewater-treatment plant effluent in Minnesota. This study was a cooperative effort of the U.S. Geological Survey, the Minnesota Pollution Control Agency, St. Cloud State University, the University of St. Thomas, and the University of Colorado. The objective of the study was to identify distribution patterns of endocrine active chemicals, pharmaceuticals, and other organic and inorganic chemicals of concern indicative of wastewater effluent, and to identify biological characteristics of estrogenicity and fish responses in the same streams. The U.S. Geological Survey collected and analyzed water, bed-sediment, and quality-assurance samples, and measured or recorded streamflow once at each sampling location from September through November 2009. Sampling locations included surface water and wastewater-treatment plant effluent. Twenty-five wastewater-treatment plants were selected to include continuous flow and periodic release facilities with differing processing steps (activated sludge or trickling filters) and plant design flows ranging from 0.002 to 10.9 cubic meters per second (0.04 to 251 million gallons per day) throughout Minnesota in varying land-use settings. Water samples were collected from the treated effluent of the 25 wastewater-treatment plants and at one point upstream from and one point downstream from wastewater-treatment plant effluent discharges. Bed-sediment samples also were collected at each of the stream or lake locations. Water samples were analyzed for major ions, nutrients, trace elements, pharmaceuticals, phytoestrogens and pharmaceuticals, alkylphenols and other neutral organic chemicals, carboxylic acids, and steroidal hormones. A subset (25 samples) of the bed-sediment samples were analyzed for carbon, wastewater-indicator chemicals, and steroidal hormones; the remaining samples were archived. Biological characteristics were determined by using an in-vitro bioassay to determine total estrogenicity in water samples and a caged fish study to determine characteristics of fish from experiments that exposed fish to wastewater effluent in 2009. St. Cloud State University deployed and processed caged fathead minnows at 13 stream sites during September 2009 for the caged fish study. Measured fish data included length, weight, body condition factor, and vitellogenin concentrations.

Minnesota↗

USGS1975

Descriptions and chemical analyses for selected wells in the Tehama-Colusa Canal Service Area, Sacramento Valley, California

The Tehama-Colusa Canal Service Area is in the northwestern part of the Sacramento Valley, in parts of Yolo, Colusa, Glenn, and Tehama Counties. The area includes 450 square miles (1,160 square kilometres). The boundaries are: West, the eastern slopes of the Coast Ranges; north, Elder Creek; northeast, the Sacramento River and the Glenn-Colusa Canal; east and southeast, the Colusa Basin Drainage Canal; and south, Oat Creek. Between April and July 1974, 393 wells were selectively canvassed and between August and October 1974, water samples were collected for chemical analysis from 222 wells of the 393 wells canvassed. Field determinations of alkalinity, conductance, pH, and temperature were made on the site at the time of sampling. The samples were then field prepared for shipment and analysis for individual constituents at the Geological Survey Central Laboratory, Salt Lake City, Utah. Descriptive data for water wells are listed in table 1, chemical data in tables 2 and 3, and the location of these wells is shown on maps 1-28.

California↗

USGS1908

Water resources of Beaver Valley, Utah

Location and extent of area examined. Beaver Valley is located in Beaver County, in southwestern Utah, about 175 miles south of Salt Lake. It lies between the Tushar Mountains on the east and the Beaver Mountains on the west. The principal town of the valley is Beaver, which is most conveniently reached from Milford, a station on the San Pedro, Los Angeles and Salt Lake Railroad. The valley, together with its neighboring highlands, occupies the eastern third of Beaver County, an area of about 1,200 square miles. A large part of this area, however, is rocky upland and unproductive desert, the tillable land comprising a comparatively small area in the immediate vicinity of the streams. Purpose and scope of work . The purpose of this paper is to present information concerning the waters of Beaver Valley and to point out ways and means of increasing their usefulness. The presence of a large amount of water in Beaver Valley results from local topograhic conditions, the water being supplied by precipitation in the highland to the east. Its conservation and distribution result from geologic conditions, the water being held in loose gravel and sand, which are more or less confined between ridges of consolidated rocks. The rock basins were formed partly by erosion and partly by faulting and surface deformation. In order to accomplish the purpose in view it is therefore necessary to describe the geographic and geologic conditions in Beaver Valley and neighboring regions. The investigation included the determination of the flow of streams and springs, of the manner of occurrence and quantity of the underground waters as shown by the geologic and geographic conditions of the region and by the distribution of springs and wells, and of the chemical character of the waters with reference to their adaptability to domestic use and to irrigation. The chemical data were obtained (a) by field assays, which are approximately correct and probably of sufficient accuracy to be of value in comparing the various waters; (b) by more exact analyses, some of which were made in the laboratory of the United States Geological Survey by W. M. Barr, and others by Herman Harms, State chemist of Utah, for the San Pedro, Los Angeles and Salt Lake Railroad; and (c) by sanitary analyses, made also by Herman Harms. Cooperation . The work was done during the summer of 1906, the United States Geological Survey cooperating with the State of Utah through Caleb Tanner, State engineer, and with the county of Beaver through the supervisors of the county. In collecting the information the writer was assisted by J. F. Hoyt, of Nephi, Utah.

Utah↗

USGS1986

The Schwarzwalder uranium deposit, III: Alteration, vein mineralization, light stable isotopes, and genesis of the deposit

The Schwartzwalder uranium deposit formed at 69.3 + or - 1.1 m.y. in a complex fracture system during the inception of Laramide uplift of the Front Range in Colorado. Geologic and isotopic evidence demonstrates that the ore-forming fluids were in chemical equilibrium with the Proterozoic metavolcanic and metasedimentary host-rock terrane at depth and that the metals, sulfur, and carbonate deposited in the fractures were derived from the metamorphic rocks. The data are not consistent with chemical contributions from an unrecognized magma or from the overlying Phanerozoic sedimentary rocks. The protoliths for the metamorphic rocks were submarine volcanic rocks and related volcanogenic exhalative iron-formations and chert. Water trapped along the basement faults and in the regolith between the basement and the overlying Paleozoic sedimentary rocks interacted with the metavolcanic rocks to produce isotopically heavy fluids containing high concentrations of dissolved metals and carbonate. Calculated delta 18 O values for this fluid range from 4.3 to 8.2 per mil, indicating a low water/rock ratio in the source terrane.Two stages of alteration and three stages of vein mineralization are recorded in the Schwartzwalder deposit. At the onset of Laramide faulting, fluids migrated along the fracture systems to zones of low hydraulic potential. These fluids contained CO 2 and had a metastably large K/Na ratio; they altered the gneissic wall rocks to a carbonate-sericite assemblage, adding K (super +) and CO 2 and removing SiO 2 with little or no change in volume. As the fractures continued to open, CO 2 was evolved from the fluids, increasing the pH and superimposing a hematite-adularia alteration assemblage on the earlier alteration.The veins record three stages of mineralization, the second of which generated the high-grade uranium veins. Evidence for the stage I sulfide-carbonate mineralization is poorly preserved, but isotopic and temperature data from this stage are consistent with a trend in fluid composition culminating in stage II pitchblende deposition. Sudden, large movements along the faults caused episodic evolution of CO 2 from the fluid. This loss of CO 2 decreased the solubilities of carbonates and adularia and the stabilities of sulfur species in solution. Uranyl carbonate complexes dissociated and sulfur species in solution likely reduced the uranyl ions to produce stage II pitchblende. Carbonate, adularia, and sulfides dominated the vein mineralogy after deposition of pitchblende. Progressively lower delta 18 O values in vein carbonates suggest the mixing of cooler, less evolved, perhaps meteoric, waters during the later stages of mineralization. However, the fluid pressure remained high, as indicated by explosion breccias and inward collapse features which formed as fault movements produced sudden decreases in the confining pressure. Only the stage III carbonate-iron disulfide assemblage in the major postore segment of the Illinois fault may be the product of meteoric water alone.

Economic Geology↗

USGS2020

Hydrogeologic characterization, groundwater chemistry, and vulnerability assessment, Ute Mountain Ute Reservation, Colorado and Utah

The U.S. Geological Survey, in cooperation with the Ute Mountain Ute Tribe (UMUT), initiated a study in 2016 to increase understanding of the hydrogeology and chemistry of groundwater within select areas of the Ute Mountain Ute Reservation (UMUR) in Colorado and Utah, identify vulnerabilities to the system and other natural resources, and outline information needs to aid in the understanding and protection of groundwater resources. The results presented for this study can be used to support the UMUT’s goal of protecting their vital groundwater resources on the UMUR. Hydrogeologic conditions were characterized for the surficial aquifer contained in Quaternary-age unconsolidated surficial deposits and the Dakota aquifer contained in the Cretaceous-age Dakota Sandstone. In the surficial aquifer, median depth to water ranges from about 5.4 to 17.2 feet below land surface in the Farm and Ranch Enterprise area and 11 to 34 feet below land surface in the Towaoc area, and the water table slopes generally southwest or south. A map of depth to the top of the Dakota Sandstone was constructed from existing well data. Depths range from zero in outcrop areas to more than 3,000 feet below land surface on mesas in the southeastern part of the UMUR. Groundwater-chemistry data were collected by the UMUT from 13 springs and 31 wells from 1996 through 2017. Specific conductance was much lower for samples from springs than from wells; median values were 512 and 6,024 microsiemens per centimeter at 25 degrees Celsius, respectively. Spring samples were well oxygenated. A few well samples were anoxic (dissolved oxygen concentrations less than 0.5 milligrams per liter [mg/L]), indicating reducing conditions in the aquifer. About 75 percent of spring samples had fresh water (total dissolved solids concentrations less than 1,000 mg/L), and about 85 percent of well samples had brackish or highly saline water (total dissolved solids concentrations greater than 1,000 mg/L). Water type for springs on the Ute Mountains was calcium bicarbonate. Lower-altitude springs had a calcium-sulfate water type. Most well samples had sodium as the dominant cation, and sulfate, bicarbonate, and chloride as the dominant anions. Fluoride concentrations in about 45 percent of well samples were greater than an agricultural-use standard of 2 mg/L. Nitrate plus nitrite concentrations in most spring and well samples were less than about 1.6 mg/L per liter. Concentrations in samples from wells in the irrigated agricultural area were elevated; the maximum concentration was 78.5 mg/L. About one-half of the trace-element samples had concentrations that were less than laboratory reporting limits. Only aluminum, arsenic, and selenium in spring samples, and boron and selenium in well samples, were detected at concentrations greater than surface-water standards or water-quality standards for agricultural use of groundwater. Only three organic compounds, the pesticides alachlor and atrazine and the volatile organic compound di(2-ethylhexyl) phthalate, were detected in well samples. The Escherichia coli bacteria was detected in 47 and 23 percent of samples from wells and springs, respectively. The E. coli detections included samples from three culturally significant springs, which did not meet the UMUT cultural-use standard of total absence of E. coli. Tritium and carbon-14 were the primary environmental tracers used for interpreting groundwater ages for Lopez 2 Spring and five wells (AP–1, 5000 Block, Cottonwood Spring, Goodknight, and SE Toe). Water from the AP–1 well contained a mixture of pre- and post-1950s recharge. Tritium and carbon-14 recharge ages for Lopez 2 Spring (post-1950s in age), Goodknight and SE Toe wells (pre-1950s in age), and Cottonwood Spring well (primarily pre-1950s in age) are supported by helium-4 data. The helium-4 data for the 5000 Block well are inconsistent with the tritium and carbon-14 age of pre-1950s recharge because of interference caused by high methane concentrations in the water. Springs and surficial deposits are more vulnerable to contamination from anthropogenic chemicals than deeper bedrock wells. Bedrock aquifers are vulnerable in areas where the geologic formations containing the aquifers are exposed at the land surface. Groundwater in deep bedrock aquifers is likely thousands of years old and is not currently affected by present-day land uses. Both shallow and deep groundwater are vulnerable to naturally occurring salts and minerals, such as of total dissolved solids, major ions, nitrate, and trace elements. Effects of a changing climate on water resources and other ecological characteristics of the UMUR could include changes in evapotranspiration, a decrease in snowpack, decreased aquifer recharge and flow of springs, a decrease in soil moisture, and increased occurrence of wildfires and forest mortality. Of particular interest for the UMUT are possible effects of a changing climate on medicinal and culturally important plants and springs Several information needs were identified during this study that would aid in the understanding and protection of groundwater resources on the UMUR. These include well-completion information for bedrock wells, the collection of environmental tracer data at additional wells, the addition of methane and hydrocarbon analysis to well sampling plans, and the resampling of springs and wells that were last sampled in 2002 or earlier.

Colorado↗

USGS1979

Chemical and biological quality of selected lakes in Ohio, 1976 and 1977

Twenty-eight Ohio lakes (14 per year) were sampled by the U.S. Geological Survey and Ohio Environmental Protection Agency for the water-quality characteristics during the spring and summer of 1976 and 1977. Data items included: profiles of temperature, dissolved oxygen, pH, and specific conductance; physical, biological, nutrient, and organic characteristics; major and minor constituents; and physical and chemical data associated with major inflows. Light penetration (secchi disk) was greatest (21 feet) in Mogadore Reservoir and least (0.8 foot) in Stonelick Lake. Seasonal thermal gradients developed in most lakes greater than 17 feet in depth. Dissolved-oxygen saturation ranged from 220 percent in Summit Lake to zero percent in the bottom waters of all lakes having stable thermal gradients. Five-day BOD ranged from 0.3 milligrams per liter im Michael J. Kirwan Reservoir to more than 17 milligrams per liter in Nimisilia Reservoir. Anaerobic zones were frequently characterized by hydrogen sulfide and high concentrations of ammonia. All lakes had moderately hard to very hard waters. Calcium, bicarbonate, and sulfate were the principal constituents. Specific conductance ranged from 130 micromhos (Lake Logan) to 1250 micromhos (Summit Lake). Because of nutrient uptake and recycling, significant chemical and physical differences developed in different thermal strata. Pesticide residues and trace elements were not above the limits recommended by the Ohio Environmental Protection Agency. All counts of fecal colifrom bacteria were within State standards. Blue-green algae (Cyanophyta) dominated the phytoplankton communities of 18 lakes in spring and 26 lakes in summer. Algal counts from euphotic-zone composite samples ranged from 180 cells per milliliter in Killdeer Reservoir to 3,400,000 cells per milliliter in Kiser Lake. Maximum algal counts were greater than 100,000 cells per milliliter in 19 lakes. Streams ate a major source of macronutrients in Ohio lakes. The estimated discharge-weighted mean concentration for nitrite and total phosphorus in 62 inflow samples was 1.22 milligrams per liter as N and 0.12 milligrams per liter as P.

Ohio↗

USGS1981

Map showing general chemical quality of ground water in the Alton-Kolob coal-fields area, Utah

This is one of a series of maps that describes the geology and related natural resources of the Alton-Kolob coal-fields area, Utah. The purpose of this map is to show regional variations in ground-water quality as depicted by its dissolved-solids concentration. The map is based on chemical analyses of water samples from springs, streams during base flow, and wells less than 1.000 feet deep. There are significant areal and vertical variations in the ground-water quality – especially in those areas where the dissolved-solids concentrations range from 100 to 1,000 and from 500 to 3,000 mg/L (milligrams per liter). Consequently, determination of the actual chemical quality of the ground-water, including concentrations of specific ions in any given locality, can be made only by special investigation.

Utah↗

USGS2012

Presence of selected chemicals of emerging concern in water and bottom sediment from the St. Louis River, St. Louis Bay, and Superior Bay, Minnesota and Wisconsin, 2010

The St. Louis Bay of Lake Superior receives substantial urban runoff, wastewater treatment plant effluent, and industrial effluent. In 1987, the International Joint Commission designated the St. Louis Bay portion of the lower St. Louis River as one of the Great Lakes Areas of Concern. Concerns exist about the potential effects of chemicals of emerging concern on aquatic biota because many of these chemicals, including endocrine active chemicals, have been shown to affect the endocrine systems of fish. To determine the occurrence of chemicals of emerging concern in the St. Louis River, the St. Louis Bay, and Superior Bay, the U.S. Geological Survey in cooperation with the Minnesota Pollution Control Agency and the Wisconsin Department of Natural Resources collected water and bottom-sediment samples from 40 sites from August through October 2010. The objectives of this study were to (1) identify the extent to which chemicals of emerging concern, including pharmaceuticals, hormones, and other organic chemicals, occur in the St. Louis River, St. Louis Bay, and Superior Bay, and (2) identify the extent to which the chemicals may have accumulated in bottom sediment of the study area. Samples were analyzed for selected wastewater indicators, hormones, sterols, bisphenol A , and human-health pharmaceuticals. During this study, 33 of 89 chemicals of emerging concern were detected among all water samples collected and 56 of 104 chemicals of emerging concern were detected in bottom-sediment samples. The chemical N,N -diethyl- meta -toluamide (DEET) was the most commonly detected chemical in water samples and 2,6-dimethylnaphthalene was the most commonly detected chemical in bottom-sediment samples. In general, chemicals of emerging concern were detected at a higher frequency in bottom-sediment samples than in water samples. Estrone (a steroid hormone) and hexahydrohexamethyl cyclopentabensopyran (a synthetic fragrance) were the most commonly detected endocrine active chemicals in water samples; beta -sitosterol (a plant sterol), estrone, and 4- tert -octylphenol (an alkylphenol) were the most commonly detected endocrine active chemicals in bottom-sediment samples. The greater detection frequency of chemicals in bottom-sediment samples compared to the detection frequency in water samples indicates that bottom sediment is an important sink for chemicals of emerging concern. At least one polycyclic aromatic hydrocarbon was detected in every sample; and in most samples, all nine polycyclic aromatic hydrocarbons included in analyses were detected. Bottom sediment collected from Superior Bay had the most polycyclic aromatic hydrocarbon detections of the sediment sampling locations.

Minnesota;Wisconsin↗

USGS2005

Using cosmogenic nuclides to contrast rates of erosion and sediment yield in a semi-arid, arroyo-dominated landscape, Rio Puerco Basin, New Mexico

Analysis of in-situ-produced 10Be and 26Al in 52 fluvial sediment samples shows that millennial-scale rates of erosion vary widely (7 to 366 m Ma-1) through the lithologically and topographically complex Rio Puerco Basin of northern New Mexico. Using isotopic analysis of both headwater and downstream samples, we determined that the semi-arid, Rio Puerco Basin is eroding, on average, about 100 m Ma-1. This rapid rate of erosion is consistent with estimates made using other techniques and is likely to result from a combination of easily eroded lithologies, sparse vegetation, and monsoon-dominated rainfall. Data from 331 stream water samples collected by the US Geological Survey between 1960 and 1995 are consistent with basin-wide, average chemical denudation rates of only about 1??4 m Ma-1; thus, the erosion rates we calculate may be considered rates of sediment generation because physical weathering accounts for almost 99 per cent of mass loss. The isotopic data reveal that sediment is generally well mixed downstream with the area-weighted average sediment generation rate for 16 headwater samples (234 ton km-2 a-1 for basin area 170 to 1169 km2) matching well that estimated from a single sample collected far downstream (238 ton km-2 a-1, basin area = 14 225 km2). A series of 15 samples, collected from an arroyo wall and representing deposition through the late Holocene, indicates that 10Be concentration in sediment delivered by the fluvial system has not changed appreciably over the last 1200 years despite at least two cycles of arroyo cutting and filling. Other samples (n = 21) were collected along the drainage network. Rio Puerco erosion rates scale directly with a variety of metrics describing vegetation, precipitation, and rock erodibility. Using the headwater basins for calibration, the erosion rates for both the downstream samples and also the data set as a whole, are best modelled by considering a combination of relief and vegetation metrics, both of which co-vary with precipitation and erodibility as inferred from lithology. On average, contemporary sediment yields, determined by monitoring suspended-sediment discharge, exceed cosmogenically determined millennial-scale erosion rates by nearly a factor of two. This discrepancy, between short-term rates of sediment yield and long-term rates of erosion, suggests that more sediment is currently being exported from the basin than is being produced. Because the failure of incised channel walls and the head cutting of arroyo complexes appear to be the main sources of channel sediment today, this incongruence between rates of sediment supply and sediment yield is likely to be transitory, reflecting the current states of the arroyo cycle and perhaps the influence of current or past land-use patterns. Copyright ?? 2005 John Wiley & Sons, Ltd.

Earth Surface Processes and Landforms↗

USGS1984

Use of partial dissolution techniques in geochemical exploration

Application of partial dissolution techniques to geochemical exploration has advanced from an early empirical approach to an approach based on sound geochemical principles. This advance assures a prominent future position for the use of these techniques in geochemical exploration for concealed mineral deposits. Partial dissolution techniques are classified as single dissolution or sequential multiple dissolution depending on the number of steps taken in the procedure, or as “nonselective” extraction and as “selective” extraction in terms of the relative specificity of the extraction. The choice of dissolution techniques for use in geochemical exploration is dictated by the geology of the area, the type and degree of weathering, and the expected chemical forms of the ore and of the pathfinding elements. Case histories have illustrated many instances where partial dissolution techniques exhibit advantages over conventional methods of chemical analysis used in geochemical exploration.

Journal of Geochemical Exploration↗

USGS1968

On the maintenance of anomalous fluid pressures: II. Source layer at depth

Physico-chemical mechanisms have been suggested to account for anomalous fluid pressures in the geologic environment which require a fluid source at depth. The persistence of anomalous pressure is a problem that involves nonsteady fluid flow. The hydrodynamics and particular boundary conditions control the time rate of pressure change and its maintenance. A series of mathematical solutions germane to the maintenance of anomalous pressure caused by the injection of fluids into the system from a source layer are presented. The phase change, gypsum to anhydrite plus water, is used as an example of a fluid source at depth. The thermodynamics of the gypsum-dehydration reaction indicates that conversion will probably occur at shallow depths and produce fluid at a constant rate. The dehydration of montmorillonite will also produce fluids at a constant rate under geologic conditions where the reaction can occur. If horizons of material of low permeability are missing or scarce, it is doubtful that anomalous pore pressures can be maintained for more than a geologic instant. The creation and continuation of anomalous pressure depend largely upon the hydraulic conductivity and, to a lesser extent, upon the specific storage of clay layers within the system. © 1968, The Geological Society of America, Inc.

Geological Society of America Bulletin↗

USGS1974

Chemical weathering of serpentinite in the eastern Piedmont of Maryland

Weathering processes in a small watershed (Soldiers Delight) underlain by Serpentinite in the Piedmont of Maryland were studied by means of a mass balance technique and were compared with the processes operative in a watershed uncertain by schist. The two terranes are downwasting at a rate of 2.4 m per m.y., but chemical weathering much more strongly affects the Serpentinite (2.2 m per m.y.) than the schist (1.2 m per m.y.). The serpentinite lacks a saprolite cover because resistate minerals are absent and alumina in the bedrock is scarce. In contrast, the schist contains both quartz and a source of alumina in the alumino-silicate minerals and, as a result, has a thick saprolite mantle. Relatively small amounts of secondary quartz, chalcedony, and 14Å clay minerals are synthesized in the serpentinite watershed, but relatively large amounts of gibbsite and clay minerals (kaolinite and vermiculite) are formed during the weathering of the schist. The hydrologic consequences in the serpentinite terrane compared with the schist watershed are increased flood-flow discharge, greater fluctuation in seasonal, instantaneous base-flow discharge, and pronounced seasonal fluctuations in total discharge. The serpentinite stream water averaged 205 ppm of total dissolved solids in the base flow compared to 25 ppm in the schist. Stream water from the serpentinite is of the magnesium bicarbonate type; that from the schist is sodium-calcium bicarbonate type. On the serpentinite, substantial land-surface reduction (denudation) is effected by chemical weathering; mechanical weathering is secondary. On the schist terrane, mechanical weathering is the primary agent that lowers the land surface, even though chemical weathering has reduced the rock mass ay almost one-half. © 1974 Geological Society of America.

Geological Society of America Bulletin↗

USGS2009

Petrographic and geochemical comparisons between the lower crystalline basement-derived section and the granite megablock and amphibolite megablock of the Eyreville B core, Chesapeake Bay impact structure, USA

The Eyreville B core from the Chesapeake Bay impact structure, Virginia, USA, contains a lower basement-derived section (1551.19 m to 1766.32 m deep) and two megablocks of dominantly (1) amphibolite (1376.38 m to 1389.35 m deep) and (2) granite (1095.74 m to 1371.11 m deep), which are separated by an impactite succession. Metasedimentary rocks (muscovite-quartz-plagioclase-biotite-graphite ± fibrolite ± garnet ± tourmaline ± pyrite ± rutile ± pyrrhotite mica schist, hornblende-plagioclase-epidote-biotite-K-feldspar-quartz-titanite-calcite amphibolite, and vesuvianite-plagioclase-quartz-epidote calc-silicate rock) are dominant in the upper part of the lower basement-derived section, and they are intruded by pegmatitic to coarse-grained granite (K-feldspar-plagioclase-quartz-muscovite ± biotite ± garnet) that increases in volume proportion downward. The granite megablock contains both gneissic and weakly or nonfoliated biotite granite varieties (K-feldspar-quartz-plagioclase-biotite ± muscovite ± pyrite), with small schist xenoliths consisting of biotite-plagioclase-quartz ± epidote ± amphibole. The lower basement-derived section and both megablocks exhibit similar middle- to upper-amphibolite-facies metamorphic grades that suggest they might represent parts of a single terrane. However, the mica schists in the lower basement-derived sequence and in the megablock xenoliths show differences in both mineralogy and whole-rock chemistry that suggest a more mafic source for the xenoliths. Similarly, the mineralogy of the amphibolite in the lower basement-derived section and its association with calc-silicate rock suggest a sedimentary protolith, whereas the bulk-rock and mineral chemistry of the megablock amphibolite indicate an igneous protolith. The lower basement-derived granite also shows bulk chemical and mineralogical differences from the megablock gneissic and biotite granites.

Virginia↗