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USGS2002

Unconventional shallow biogenic gas systems

Unconventional shallow biogenic gas falls into two distinct systems that have different attributes. Early-generation systems have blanketlike geometries, and gas generation begins soon after deposition of reservoir and source rocks. Late-generation systems have ringlike geometries, and long time intervals separate deposition of reservoir and source rocks from gas generation. For both types of systems, the gas is dominantly methane and is associated with source rocks that are not thermally mature. Early-generation biogenic gas systems are typified by production from low-permeability Cretaceous rocks in the northern Great Plains of Alberta, Saskatchewan, and Montana. The main area of production is on the southeastern margin of the Alberta basin and the northwestern margin of the Williston basin. The huge volume of Cretaceous rocks has a generalized regional pattern of thick, non-marine, coarse clastics to the west and thinner, finer grained marine lithologies to the east. Reservoir rocks in the lower part tend to be finer grained and have lower porosity and permeability than those in the upper part. Similarly, source beds in the units have higher values of total organic carbon. Patterns of erosion, deposition, deformation, and production in both the upper and lower units are related to the geometry of lineament-bounded basement blocks. Geochemical studies show that gas and coproduced water are in equilibrium and that the fluids are relatively old, namely, as much as 66 Ma. Other examples of early-generation systems include Cretaceous clastic reservoirs on the southwestern margin of Williston basin and chalks on the eastern margin of the Denver basin. Late-generation biogenic gas systems have as an archetype the Devonian Antrim Shale on the northern margin of the Michigan basin. Reservoir rocks are fractured, organic-rich black shales that also serve as source rocks. Although fractures are important for production, the relationships to specific geologic structures are not clear. Large quantities of water are coproduced with the gas, and geochemical data indicate that the water is fairly fresh and relatively young. Current thinking holds that biogenic gas was generated, and perhaps continues to be, when glacial meltwater descended into the plumbing system provided by fractures. Other examples of late-generation systems include the Devonian New Albany Shale on the eastern margin of the Illinois basin and the Tertiary coalbed methane production on the northwestern margin of the Powder River basin. Both types of biogenic gas systems have a similar resource development history. Initially, little technology is used, and gas is consumed locally; eventually, sweet spots are exploited, widespread unconventional reservoirs are developed, and transport of gas is interstate or international. However, drilling and completion techniques are very different between the two types of systems. Early-generation systems have water-sensitive reservoir rocks, and consequently water is avoided or minimized in drilling and completion. In contrast, water is an important constituent of late-generation systems; gas production is closely tied to dewatering the system during production. Existing production and resource estimates generally range from 10 to 100 tcf for both types of biogenic gas systems. Although both system types are examples of relatively continuous accumulations, the geologic frameworks constrain most-economic production to large geologic structures on the margins of basins. Shallow biogenic gas systems hold important resources to meet the increased domestic and international demands for natural gas.

American Association of Petroleum Geologists Bulle↗

USGS1999

The dependence of permeability on effective stress from flow tests at hot dry rock reservoirs at Rosemanowes (Cornwall) and Fenton Hill (New Mexico)

Effective stress is the primary control on permeability and thus on flow and water loss for two-well hot dry rock systems involving injection and production that have been tested to date. Theoretical relations are derived for the flow between an injector and producer, including the dependence of permeability on effective stress. Four relations for permeability as a function of effective stress are used to match field data for the hot dry rock systems at Rosemanowes, Cornwall, and Fenton Hill, New Mexico. The flow and water loss behavior of these systems are well explained by the influence of effective stress on permeability. All four relations for permeability as a function of effective stress are successful in matching the field data, but some have difficulty in determining unique values for elastic and hydrologic parameters.Effective stress is the primary control on permeability and thus on flow and water loss for two-well hot dry rock systems involving injection and production that have been tested to date. Theoretical relations are derived for the flow between an injector and producer, including the dependence of permeability on effective stress. Four relations for permeability as a function of effective stress are used to match field data for the hot dry rock systems at Rosemanowes, Cornwall, and Fenton Hill, New Mexico. The flow and water loss behavior of these systems are well explained by the influence of effective stress on permeability. All four relations for permeability as a function of effective stress are successful in matching the field data, but some have difficulty in determining unique values for elastic and hydrologic parameters.

Geothermics↗

USGS2006

Geologic map of the Yacolt quadrangle, Clark County, Washington

The Yacolt 7.5' quadrangle is situated in the foothills of the western Cascade Range of southwestern Washington approximately 35 km northeast of Portland, Oregon. Since late Eocene time, the Cascade Range has been the locus of an active volcanic arc associated with underthrusting of oceanic lithosphere beneath the North American continent along the Cascadia Subduction Zone. Volcanic and shallow-level intrusive rocks emplaced early in the history of the arc underlie most of the Yacolt quadrangle, forming a dissected and partly glaciated terrain with elevations between 250 and 2180 ft (75 and 665 m). The bedrock surface slopes irregularly but steeply to the southwest, forming the eastern margin of the Portland Basin, and weakly consolidated Miocene and younger basin-fill sediments lap up against the bedrock terrain in the southern part of the map area. A deep canyon, carved by the East Fork Lewis River that flows westward out of the Cascade Range, separates Yacolt and Bells Mountains, the two highest points in the quadrangle. Just west of the quadrangle, the river departs from its narrow bedrock channel and enters a wide alluvial floodplain. Bedrock of the Yacolt quadrangle consists of near-horizontal strata of Oligocene volcanic and volcaniclastic rocks that comprise early products of the Cascade volcanic arc. Basalt and basaltic andesite flows predominate. Most were emplaced on the flanks of a large mafic shield volcano and are interfingered with crudely bedded sections of volcanic breccia of probable lahar origin and a variety of well bedded epiclastic sedimentary rocks. At Yacolt Mountain, the volcanogenic rocks are intruded by a body of Miocene quartz diorite that is compositionally distinct from any volcanic rocks in the map area. The town of Yacolt sits in a north-northwest-trending valley apparently formed within a major fault zone. Several times during the Pleistocene, mountain glaciers moved down the Lewis River valley and spread southward into the map area. The largest glacier(s) covered the entire map area north of the East Fork Lewis River except for the summit of Yacolt Mountain. As the ice receded, it left behind a sculpted bedrock topography thickly mantled by drift, and deposited outwash in the fault-bounded valley at Yacolt and along the East Fork Lewis River valley. This map is a contribution to a program designed to improve geologic knowledge of the Portland Basin region of the Pacific Northwest urban corridor, the densely populated Cascadia forearc region of western Washington and Oregon. More detailed information on the bedrock and surficial geology of the basin and its surrounding area is necessary to refine assessments of seismic risk, ground-failure hazards and resource availability in this rapidly growing region.

Scientific Investigations Map↗

USGS2015

Results of mineral, chemical, and sulfate isotopic analyses of water, soil, rocks, and soil extracts from the Pariette Draw Watershed, Uinta Basin, Utah

In 2010, Utah Department of Environmental Quality (DEQ) Division of Water Quality (UDWQ, 2010) determined that water quality in Pariette Draw was in violation of Federal and State water quality criteria for total dissolved solids (TDS), selenium (Se), and boron (B). The measure of total dissolved solids is the sum of all the major ion concentrations in solution and in this case, the dominant ions are sodium (Na) and sulfate (SO4), which can form salts like thenardite (Na2SO4) and mirabilite (Na2SO4⋅H2O). The Utah Department of Environmental Quality (2010) classified the contamination as natural background and from nonpoint sources related to regional lithology and irrigation practices. Although the daily loads of the constituents of concern and water chemistry have been characterized for parts of the watershed, little is known about the controls that bedrock and soil mineralogy have on salt, Se, and B storage and the water-rock interactions that influence the mobility of these components in ground and surface waters. Studies in the Uncompahgre River watershed in Colorado by Tuttle and others (2014a, 2014b) show that salt derived from weathering of shale in a semiarid climate is stored in a variety of minerals that contribute solutes to runoff and surface waters based on a complex set of conditions such as water availability, geomorphic position (for example, topography controls the depth of salt accumulation in soils), water-table fluctuations, redox conditions, mineral dissolution kinetics, ion-exchange reactions, and secondary mineral formation. Elements like Se and B commonly reside in soluble salt phases, so knowledge of the behavior of salt minerals also sheds light on the behavior of associated contaminants. The goal of this study was to establish a process-based understanding of salt, Se, and B behavior to address whether these contaminants can be better managed, or if uncontrollable natural processes will overwhelm any attempts to bring Pariette Draw into compliance with respect to recently established total maximum daily limits (TMDLs). We collected data to refine our knowledge about the role of rock weathering and soil formation in the transport and storage of salt in the watershed and to show how salt is cycled under irrigated and natural conditions. Our approach was to sample rock, soils, and sediment on irrigated and natural terrain for mineralogical analysis to determine the residence of salt and associated Se and B, classify minerals as primary (related to rock formation) or secondary weathering products, and characterize mineral dissolution kinetics. Mineral and chemical analyses and selective extractions of rocks and soils provide useful information in understanding solute movement and mineral dissolution/ formation. The resulting data are critical in determining residence of salt, Se, and B in weathered rock and soil and understanding the mobility during water-rock-soil interactions. This report summarizes our methods for sample and data collection and tabulates the mineral, chemical, and isotopic data collected.

Utah↗

USGS1997

Hydrogeology and water quality of the West Valley Creek Basin, Chester County, Pennsylvania

The West Valley Creek Basin drains 20.9 square miles in the Piedmont Physiographic Province of southeastern Pennsylvania and is partly underlain by carbonate rocks that are highly productive aquifers. The basin is undergoing rapid urbanization that includes changes in land use and increases in demand for public water supply and wastewater disposal. Ground water is the sole source of supply in the basin. West Valley Creek flows southwest in a 1.5-mile-wide valley that is underlain by folded and faulted carbonate rocks and trends east-northeast, parallel to regional geologic structures. The valley is flanked by hills underlain by quartzite and gneiss to the north and by phyllite and schist to the south. Surface water and ground water flow from the hills toward the center of the valley. Ground water in the valley flows west-southwest parallel to the course of the stream. Seepage investigations identified losing reaches in the headwaters area where streams are underlain by carbonate rocks and gaining reaches downstream. Tributaries contribute about 75 percent of streamflow. The ground-water and surface-water divides do not coincide in the carbonate valley. The ground-water divide is about 0.5 miles west of the surface-water divide at the eastern edge of the carbonate valley. Underflow to the east is about 1.1 inches per year. Quarry dewatering operations at the western edge of the valley may act partly as an artificial basin boundary, preventing underflow to the west. Water budgets for 1990, a year of normal precipitation (45.8 inches), and 1991, a year of sub-normal precipitation (41.5 inches), were calculated. Streamflow was 14.61 inches in 1990 and 12.08 inches in 1991. Evapotranspiration was estimated to range from 50 to 60 percent of precipitation. Base flow was about 62 percent of streamflow in both years. Exportation by sewer systems was about 3 inches from the basin and, at times, equaled base flow during the dry autumn of 1991. Recharge was estimated to be 18.5 inches in 1990 and 13.7 inches in 1991. Ground-water quality in the basin reflects differences in lithology and has been affected by human activities. Ground water in the carbonate rocks is naturally hard, has a near neutral pH, and contains more dissolved solids and less dissolved iron, manganese, and radon-222 than ground water in the noncarbonate rocks, which is soft, with moderately acidic to acidic pH. Regional contamination by chloride and nitrate and local contamination by organic compounds and metals was detected. Natural background concentrations are estimated to be about 1 milligram per liter for nitrate as nitrogen and less than 3 milligrams per liter for chloride. Ground water in unsewered areas and agricultural areas of the basin has median concentrations of nitrate that are greater than those in ground water from other areas; septic system effluent and fertilizer are probable sources of elevated nitrate. Water samples from wells in urbanized areas contain greater concentrations of chloride than samples from wells in residential areas; road salt is the probable source of elevated chloride. Organic solvents, especially trichloroethylene, were detected in 30 percent of the wells sampled in the urbanized carbonate valley. Most of the organic solvents and some of the metals in ground water were detected near old industrial sites. Base-flow stream quality of West Valley Creek was determined at 15 sites from monthly sampling for 1 year. Differences in stream quality reflect differences in lithology, land use, and point sources in tributary subbasins and mainstem reaches. The chemical composition of base flow in the mainstem is dominated by ground-water discharge from carbonate rocks. Elevated concentrations of nitrate (greater than 3 milligrams per liter as nitrogen) in base flow were measured in a tributary draining agricultural land and in a tributary draining an unsewered residential area. Elevated concentrations of phosphate (greater than 0.5 milligrams per liter as phosphorus) were measured in a stream that receives treated sewage effluent. Discharge of water containing elevated sulfate (about 250 milligrams per liter) from quarry dewatering operations contributes to die increase in sulfate concentration (of 10 to 40 milligrams per liter) in base flow downstream from the quarry. The chloride load at all stream sites is greater than the load contributed by precipitation and mineral weathering to the basin, indicating anthropogenic sources of chloride throughout the basin. The diversity index of the benthic invertebrate community has increased since 1973 at the longterm biological monitoring site on West Valley Creek, indicating an improvement in stream quality. The improvement probably is related to controls on discharges and banning of pesticides, such as DOT, in the 1970's. Concentrations of dissolved constituents, except for chloride, determined for base flow in the autumn do not appear to have changed since 1971. Application of the seasonal Kendall test for trend indicates that concentrations of chloride in base flow have increased since 1971; this increase may be related to the increase in urbanization in the basin. The benthic community structure at the West Valley Creek site in 1991 indicates slight nutrient enrichment. Lithium was detected in ground water and surface water downgradient from two lithiumprocessing facilities. Until 1991, lithium was discharged into a losing reach of West Valley Creek, thus introducing lithium into the ground-water system. The potential for cross-contamination between the ground-water and surface-water systems is great, as demonstrated by the detection of lithium in ground water and surface water downstream and downgradient from the two lithium-processing facilities. The lithium that was discharged into the creek acts as a conservative tracer in gaining reaches of West Valley Creek, maintaining a mass balance and characteristic isotopic signature. Lithium-7/lithium-6 ratios were greater in streams that are affected by sewage and by lithium-processing discharges and in ground water downgradient from the lithium-processing facilities than natural background lithium isotopic ratios.

Pennsylvania↗

USGS2008

Net Acid Production, Acid Neutralizing Capacity, and Associated Mineralogical and Geochemical Characteristics of Animas River Watershed Igneous Rocks Near Silverton, Colorado

This report presents results from laboratory and field studies involving the net acid production (NAP), acid neutralizing capacity (ANC), and magnetic mineralogy of 27 samples collected in altered volcanic terrain in the upper Animas River watershed near Silverton, Colo., during the summer of 2005. Sampling focused mainly on the volumetrically important, Tertiary-age volcanic and plutonic rocks that host base- and precious-metal mineralization in the study area. These rocks were analyzed to determine their potential for neutralization of acid-rock drainage. Rocks in the study area have been subjected to a regional propylitic alteration event, which introduced calcite, chlorite (clinochlore), and epidote that have varying amounts and rates of acid neutralizing capacity (ANC). Locally, hydrothermal alteration has consumed any ANC and introduced minerals, mainly pyrite, that have a high net acid production (NAP). Laboratory studies included hydrogen pyroxide (H2O2) acid digestion and subsequent sodium hydroxide (NaOH) titration to determine NAP, and sulfuric acid (H2SO4) acid titration experiments to determine ANC. In addition to these environmental rock-property determinations, mineralogical, chemical, and petrographic characteristics of each sample were determined through semiquantitative X-ray diffractometry (Rietveld method), optical mineralogy, wavelength dispersive X-ray fluorescence, total carbon-carbonate, and inductively coupled plasma?mass spectrometric analysis. An ANC ranking was assigned to rock samples based on calculated ANC quantity in kilograms/ton (kg/t) calcium carbonate equivalent and ratios of ANC to NAP. Results show that talus near the southeast Silverton caldera margin, composed of andesite clasts of the Burns Member of the Silverton Volcanics, has the highest ANC (>100 kg/t calcium carbonate equivalent) with little to no NAP. The other units found to have moderate to high ANC include (a) andesite lavas and volcaniclastic rocks of the San Juan Formation, west and northwest of the Silverton caldera, and (b) the Picayune Megabreccia Member of Sapinero Mesa Tuff along the western San Juan caldera margin. Sultan Mountain stock, composed of granitoid intrusive rocks, was shown to have low ANC and moderate NAP. Sequential leachate analyses on a suite of whole-rock samples from the current and a previous study indicate that host rock composition and mineralogy control leachate compositions. The most mafic volcanic samples had high leachate concentrations for Mg, Fe, and Ca, whereas silicic volcanic samples had lower ferromagnesiun compositions. Samples with high chlorite abundance also had high leachable Mg concentrations. Trace-element substitution, such as Sr for Ca in plagioclase, controls high Sr concentrations in those samples with high plagioclase abundance. High Ti abundance in leachate was observed in those samples with high magnetite concentrations. This is likely due to samples containing intergrown magnetite-ilmenite. Whole rocks having high trace-element concentrations have relatively high leachate trace-element abundances. Some lavas of the San Juan Formation and Burns Member of the Silverton Volcanics had elevated Zn-, Cd-, and Pb-leachate concentrations. Manganese was also elevated in one San Juan Formation sample. Other San Juan Formation and Burns Member lavas had low to moderate trace-element abundances. One sample of the pyroxene andesite member of the Silverton Volcanics had elevated concentrations for As and Mo. Most other pyroxene andesite member samples had low leachate trace-element abundances. Mine-waste-leachate analyses indicated that one mine-waste sample had elevated concentrations of Cu (1.5 orders of magnitude), Zn (1 order of magnitude), As (1 order of magnitude), Mo (1.5 to 2 orders of magnitude), Cd (1 to 2 orders of magnitude), and Pb (2 to 3 orders of magnitude) compared to whole rocks. These data indicate the importance of whole-rock geochemistry or leachate analys

Scientific Investigations Report↗

USGS1883

Geology of Wisconsin: Survey of 1873-1879, Volume I

The leading purpose df this volume was determined by the following enactment, being section 1, chapter 121, of the Laws of 1876. " The people of the State of Wisconsin, represented in Senate and Assembly, do enact as follows: Section 1. That in the preparation of his final report, the chief geologist be, and he is hereby authorized to collate the general geology and the leading facts and principles relating to the material resources of the State, together with practical suggestions as to the methods of detecting and utilizing the same, so as to constitute the material for a volume suited to the wants of explorers, miners, land owners, and manufacturers, who use crude native products, and to the needs of the schools of the State, and the masses of intelligent people who are not familiar with the principles of geology; said volume to be written in clear, plain language, with explanations of technical terms, and to be properly illustrated with maps and diagrams, and to be so arranged as to constitute a key to the more perfect understanding of the whole report." To subserve the purposes thus legally defined, the volume will be found to consist of three distinct portions; Part I, embracing the General Geology of the State, with explanatory matter; Part II, consisting of lists of the minerals, rocks and life-products of the State, with descriptions and auxiliary discussions; and Part III, embracing industrial descriptions and practical suggestions with reference to the leading natural resources of the State.

Wisconsin↗

USGS2021

The critical minerals initiative of the U.S. Geological Survey’s mineral deposit database project: USMIN

The objective of the US Geological Survey’s mineral deposit database project (USMIN) is to develop a comprehensive twenty-first century geospatial database that is the authoritative source of the most important mines, mineral deposits, and mineral districts of the US. Since May 2017, the project has focused on critical minerals. Data for critical minerals that are produced as products are relatively robust, whereas data for critical minerals that may be recovered as byproducts are commonly of much poorer quality. Similarly, more is known about critical minerals that occur in conventional deposits than where those critical minerals occur in unconventional deposits. For example, rare earth elements occur principally in deposits hosted by alkaline igneous rocks, but there is potential for their production from phosphate rock mining, which is less documented. Lithium (Li) has been recovered from pegmatites and brines, but other Li-bearing deposit types have been delineated that may go into production. Cobalt may be produced as a byproduct or coproduct from a wide range of mineral deposit types, whereas rhenium is a byproduct of copper ore. Significant opportunities for research exist that could help identify new sources of critical minerals, and may also help increase production and recovery from existing sources.

Mining, Metallurgy & Exploration (MME)↗

USGS1961

Structure and stratigraphy of the Pybus-Gambier area, Alaska

The Pybus-Gambier area comprises about 215 square miles of uninhabited land on the southeastern coast of Admiralty Island, southeastern Alaska. The section consists of more than 20,000 feet of intensely folded sedimentary, volcanic, and metamorphic rocks, all probably of marine origin, ranging in age from Silurian(?) to Early Cretaceous, unconformably overlain by more than 10,000 feet of gently dipping nonmarine, coarse-grained sedimentary rocks, and basalt and andesite flows of Eocene age. Diorite plutons and associated contact metamorphic rocks occur in the little-know northwestern part of the area. The section here is subdivided into nine formations, eight of which are named for the first time, as follows: Gambier Bay formation of Middle(?) Devonian age, composed of greenschist, phyllite, marble, and metachert; Hood Bay formation or Silurian and Devonian age, composed of dark, carbonaceous, thin-bedded chert, argillite, limestone, and graywacke; Cannery formation of Permian age, composed of thin-bedded chert, argillite, and graywacke; Pybus dolomite of Permian age, composed of fossiliferous, cherty dolomite; Hyd formation of Late Triassic age, composed of a basal chert breccia, a limestone member, a thin-bedded argillite member, and a spilitic volcanic member; Seymour Canal formation of Late Cretaceous and Early Cretaceous age, composed of argillite, graywacke, and conglomerate; Brothers volcanic of Early Cretaceous age, composed of andesitic flows and breccia; unnamed conglomerate and sandstone of Eocene age, and Admiralty Island volcanics of Eocene age, composed of basaltic and andesitic flows. A marked angular unconformity occurs at the base of the Tertiary section, and unconformities of less angularity occur as follows: at the base of the Cannery formation; at the base of the Hyd formation, and at the base of the Seymour Canal formation. In general, pre-Seymour Canal deformation seems to have been mild, but the intensity of the post-Gambier Bay - pre-Cannery deformation is uncertain. The complex structure of the pre-Tertiary rocks seem to be the product chiefly of the post-Seymour Canal - pre-Eocene formation. The structure of the pre-Tertiary rocks is studied by graphical statistical analysis of the preferred orientation of the planar and linear structural elements. This analysis indicates that the post-Seymour Canal - pre-Eocene deformation consisted chiefly of three episodes of folding, all of which appear to have resulted from sub-horizontal, northeast-southwest compression. The first episode produced isoclinal folds in bedding, and in places associated axial plane foliation, that had north-northwesterly striking axial planes in eastern Pybus-Gambier area, but generally northeasterly striking axial planes west of False Point Pybus. Compression during the second episode deformed the first folds in the west where their axial planes were oriented about parallel to the compression into complex second folds in both bedding and axial plane foliation, having northwesterly striking axial planes. The second folds are absent in the east where the axial planes and limbs of the first folds were oriented about normal to the second compression. The divergence of the axial planes of the first folds in the west from those in the east may have been caused by the crowding of the first folds in the west against the irregular western margin of the geosyncline during the first compression. Northweststriking thrust and reverse faults occur between domains in which the axial planes of the first folds are strongly divergent. The third episode produced kink folds, having axial planes with subvertical dips but widely varying strikes, that are confined to the thinly fissile schists and phyllites of the Gambier Bay formation. The episodes of folding in the Gambier Bay formation are accompanied by metamorphic recrystallization not found in either younger or possibly coeval (Hood Bay formation) pre-Tertiary rocks. If these episodes are contemporaneous with those in nonmetamorphic pre-Tertiary rocks, then the metamorphism dies out both vertically and laterally, and may be part of the regional decrease in metamorphism westward away from the Coast Range batholith, located about 25 miles to the east. The gently dipping Tertiary strata have been broken into fault blocks by subvertical, north-and north-east striking, normal and reverse faults.

Alaska↗

USGS2015

Estimates of hydraulic fracturing (Frac) sand production, consumption, and reserves in the United States

The practice of fracturing reservoir rock in the United States as a method to increase the flow of oil and gas from wells has a relatively long history and can be traced back to 1858 in Fredonia, New York, when a gas well situated in shale of the Marcellus Formation was successfully fractured using black powder as a blasting agent. Nearly all domestic hydraulic fracturing, often referred to as hydrofracking or fracking, is a process where fluids are injected under high pressure through perforations in the horizontal portion of a well casing in order to generate fractures in reservoir rock with low permeability (“tight”). Because the fractures are in contact with the well bore they can serve as pathways for the recovery of gas and oil. To prevent the fractures generated by the fracking process from closing or becoming obstructed with debris, material termed “proppant,” most commonly high-silica sand, is injected along with water-rich fluids to maintain or “prop” open the fractures. The first commercial application of fracking in the oil and gas industry took place in Oklahoma and Texas during the 1940s. In 1949, over 300 wells, mostly vertical, were fracked (ALL Consulting, LLC, 2012; McGee, 2012; Veil, 2012) and used silica sand as a proppant (Fracline, 2011). The resulting increase in well productivity demonstrated the significant potential that fracking might have for the oil and gas industry.

Rock Products↗

USGS2022

Bulk and intramolecular carbon isotopic compositions of hydrocarbon gases from laboratory pyrolysis of oil shale of the Green River Formation: Implications for isotope structures of kerogens

Evaluation of intramolecular isotope distributions within organic compounds can provide important insights into gas formation processes and structural properties of gas-generating precursors, such as kerogen, bitumen, and oil, in natural reservoirs. Until recently, little has been known about the intramolecular isotope distributions within kerogens. In this study, we conducted systematic pyrolysis experiments of gas generation from a lacustrine oil shale of the Eocene Green River Formation under hydrous and anhydrous conditions (equivalent maturity or Easy %R o : 0.76 to 3.27 at 310 to 480 °C for 3 to 50 days), measuring gas yields and compositions, as well as bulk and position-specific (PS) carbon isotope compositions. Gas generation processes were investigated in combination with kinetic Monte Carlo (kMC) simulations on a model Type I kerogen based on the chemical structures of oil shale of the Green River Formation. The comparison of our experimental results with kMC modelling indicates a series of β-scission, radical isomerization, and recombination reactions better represent the bulk isotope compositions of propane in the pyrolysis of the oil shale of the Green River Formation, but the ΔC c-t (= δ 13 C cen – δ 13 C ter ) values of propane at Easy %R o > 1.5 can be better simulated by a simple combination of propyl groups with H radicals. Combining our previous works on marine shale of the Woodford Formation and Springfield Coal Member of the Carbondale Formation, PS carbon isotopes of propane indicate that in the lacustrine shales of the Green River Formation and the marine Woodford Shale, propane is sourced from C C bond cleavage, while C O bond cracking generates propane from coal at the initial kerogen cracking stage. At high maturity, the differences of late-stage propane production among the source rocks lead to the different bulk and PS C kinetic isotope effects of propane. Our findings suggest that the δ 13 C at the terminal position of propane precursors is likely up to 3.6‰ higher than at the central position in the Green River kerogen, while they are similar in the marine shale of Woodford Formation. In addition, the δ 13 C at the central position of propyl groups attached to heteroatom compounds is relatively more positive in the Springfield Coal Member of the Carbondale Formation than in Green River kerogen. A comparison of intramolecular C isotopes of propyl groups in the kerogens with their bulk δ 13 C, based on the PS δ 13 C of early-generated propane, contributes to our understanding of heterogeneities of isotopic structures of sedimentary organic matter.

International Journal of Coal Geology↗

USGS2022

Rock-to-metal ratio: A foundational metric for understanding mine wastes

The quantity of ore mined and waste rock (i.e., overburden or barren rock) removed to produce a refined unit of a mineral commodity, its rock-to-metal ratio (RMR), is an important metric for understanding mine wastes and environmental burdens. In this analysis, we provide a comprehensive examination of RMRs for 25 commodities for 2018. The results indicate significant variability across commodities. Precious metals like gold have RMRs in the range of 10 5 –10 6 , while iron ore and aluminum are on the order of 10 1 . The results also indicate significant variability across operations for a single commodity. The interquartile range of RMRs for individual cobalt operations, for example, varies from 465 to 2157, with a global RMR of 859. RMR variability is mainly driven by ore grades and revenue contribution. The total attributable ore mined and waste rock removed in the production of these 25 commodities sums to 37.6 billion metric tons, 83% of which is attributable to iron ore, copper, and gold. RMRs provide an additional dimension for evaluating the impact of materials and material choice trade-offs. The results can enhance life cycle inventories and be extended to evaluate areas of surface disturbances, mine tailings, energy requirements, and associated greenhouse gas emissions.

Environmental Science & Technology↗

USGS2026

Corundum discovered by SuperCam and the Perseverance rover at Jezero crater, Mars

Mars is primarily composed of mafic mineral assemblages and their alteration products, but small, scattered rocks strewn across the landscape offer clues to greater petrological diversity. While traversing the Jezero crater rim, the Perseverance rover encountered several plagioclase-rich light-toned float rocks. SuperCam identified the distinctive signature of corundum (α-Al 2 O 3 ) in these rocks using time-resolved luminescence spectroscopy. Two strong peaks (692.7 and 694.1 nm) with millisecond lifetimes, and additional supporting lines, are consistent with Cr 3+ substitution for Al 3+ in corundum. Corundum forms in Al-rich, Si-depleted environments through magmatic or metamorphic processes. Given the rocks' small size, association with plagioclase, and location on the crater rim, we interpret the most plausible formation scenario to be impact induced metamorphism at the interface of a felsic and a mafic/ultramafic member with the likely action of fluids at some stage, although other possibilities are not excluded.

Geophysical Research Letters↗

USGS2012

Lithology and evolution of the crust-mantle boundary region in the southwestern Basin and Range Province

Mantle and crustal xenoliths from volcanic rocks in the southwestern Basin and Range province and Colorado Plateau Transition Zone reveal histories of episodic magmatism and deformation that have profoundly influenced the crustal structure of this region. Seismic transects in this area show a strongly reflective Moho of generally low relief, which, in the area of modern transects, consists of a thin zone (<2 km thick) of short reflectors. The upper mantle is transparent and has a P n of 7.8–8.0 km/s similar to much of the western United States. A lower crustal zone, 2–13 km thick, has variable internal reflectivity and a relatively low velocity of 6.6–6.8 km/s. Upper mantle peridotite xenoliths show both ductile and brittle deformational features and have structures and compositions affected by magmatic intrusion; intrusions form complex dike systems and extensive zones of grain boundary infiltration in peridotite xenoliths. Whereas melt infiltration preceded and followed ductile deformation, brittle deformation, represented by closely spaced joint systems and faults, followed ductile deformation and is related to the youngest magmatic episodes. These structural characteristics and high uppermost mantle temperature (∼1000°C) may combine to explain the relatively low P n . Alternating layers of ductily deformed and undeformed peridotites, with or without igneous intrusions, may contribute to the reflectivity of the Moho. Lower crustal xenoliths are dominantly igneous-textured pyroxenites and mafic to intermediate gabbros identical to the dikes in peridotite xenoliths. The crustal xenoliths also commonly are jointed, and in addition many show partial melting and have abundant cavities that probably were filled with CO 2 -rich fluids. These rocks are interpreted as products of underplated magmas that were fed through the mantle dike systems and may represent the lowest crustal unit identified in the seismic records. The mafic compositions and high densities of the crustal xenoliths indicate that the low velocity of the lower crust may be caused in part by fracture systems, partial melts, and high temperatures. Garnet granulite xenoliths from a locality with no mantle peridotite xenoliths probably represent crust of the region before late Miocene extension. Felsic granulite xenoliths from two localities have velocities like those of the two lower crustal units identified seismically and could be present in the modern crust as unequilibrated remnants of old crust. The preferred model for the evolution of the lower lithosphere is one in which extension affects the upper mantle as well as the crust and is overlapped in time by multiple magmatic episodes. The earliest magmatic events preceded extension, and later events accompanied and followed extension.

Arizona, California, Nevada↗

USGS2023

Eruptive history of northern Harrat Rahat—Volume, timing, and composition of volcanism over the past 1.2 million years

Harrat Rahat, one of several large, basalt-dominated volcanic fields in the western part of the Kingdom of Saudi Arabia, is a prime example of continental, intraplate volcanism. Excellent exposure makes this an outstanding site to investigate changing volcanic flux and composition through time. We present 93 40 Ar/ 39 Ar ages and 6 36 Cl surface-exposure ages for volcanic deposits throughout northern Harrat Rahat that, integrated with a new geologic map, define 12 eruptive stages. Exposed volcanic deposits in the study area erupted less than 1.2 million years ago (Ma), and 214 of 234 identified eruptions occurred less than 570 thousand years ago (ka). Two eruptions were in the Holocene, including a historically described basaltic eruption in 1256 C.E. and a trachyte eruption newly recognized as Holocene (4.2±5.2 ka). An estimated approximately 82 cubic kilometers (km 3 ; dense rock equivalent) of volcanic products can be documented as having erupted since 1.2 Ma, though this is a lower limit because of concealment of deposits older than 570 ka. Over the last 570 thousand years (k.y.), the average eruption rate was 0.14 cubic kilometers per thousand years (km 3 /k.y.), but volcanism was episodic with periods alternating between low (0.04–0.06 km 3 /k.y.) and high (0.1–0.3 km 3 /k.y.) effusion rates. Before 180 ka, eruptions vented from the volcanic field’s dominant eastern vent axis and from a subsidiary, diffuse, western vent axis. After 180 ka, volcanism focused along the eastern vent axis, and the composition of volcanism varied systematically along its length from basalt dominated in the north to trachyte dominated in the south. We hypothesize that these compositional variations younger than 180 k.y. reflect the growth of a mafic intrusive complex beneath the southern part of the vent axis, which led to the development of evolved magmas. Lastly, these new age data allow for a reassessment of the volcanic recurrence interval at northern Harrat Rahat. Based on available data, volcanism in northern Harrat Rahat over the last 180 k.y. is poorly described using a Poisson distribution with a single recurrence interval. Instead, data for northern Harrat Rahat are better described using a mixed exponential distribution that is applicable for volcanic systems characterized by two different eruptive states, where one state with a longer recurrence interval corresponding to periods of low eruption frequency and one state with a shorter recurrence interval corresponding to periods of high eruption frequency. The preferred model for northern Harrat Rahat over the last 180 k.y. uses a long recurrence interval of 4.0 k.y. and a short recurrence interval of 0.22 k.y.

Professional Paper↗

USGS1993

Edoylerite, Hg32+Cr6+O4S2 a new mineral from the Clear Creek claim, San Benito County, California

Edoylerite is a rare constituent of a small prospect near the long-abandoned Clear Creek mercury mine, New Idria district, San Benito County, California. It is most closely associated with cinnabar, from which it is a primary alteration product, in a host rock composed predominantly of quartz, chalcedony and ferroan magnesite. Edoylerite typically occurs as acicular to stellate crystal groups on and around corroded masses of cinnabar. The mineral is canary yellow to orangish yellow, and possesses a yellow streak and an adamantine luster. The crystallographic, physical and optical properties of edoylerite are described. -after Authors

Mineralogical Record↗

USGS1996

Geologic framework for the coal-bearing rocks of the Central Appalachian Basin

Coal production has been an important economic factor in the Central Appalachian Basin. However, regional stratigraphic and structural relationships of the coal-bearing rocks of the basin have been poorly understood due to numerous separate nomenclatural schemes employed by various states. In order to estimate coal resources and understand mechanisms controlling the distribution of coal within the basin, a reliable geologic framework is necessary. Seven detailed cross sections across the Central Appalachian Basin were constructed in order to examine the stratigraphic and structural framework of the coal-bearing rocks in the basin. The cross sections were based on more than 1000 oil and gas well logs, measured sections, and borehole information from Kentucky, Ohio, Tennessee, Virginia and West Virginia.

International Journal of Coal Geology↗

USGS2003

Total petroleum systems of the Paleozoic and Jurassic, Greater Ghawar Uplift and adjoining provinces of central Saudi Arabia and northern Arabian-Persian Gulf

The greater Paleozoic and Jurassic petroleum systems of the Arabian Peninsula form two of the most prolific petroleum-producing systems in the world. Source rocks of these systems extend throughout the eastern Arabian Peninsula and Arabian-Persian Gulf. Primary elements of these Paleozoic and Jurassic petroleum systems - source, reservoir, and seal rocks - are of great areal extent and exceptional quality. The combination of these regionally extensive, exceptional petroleum-system elements, and the formation of large subtle structural closures prior to, or coincident with, peak oil generation and migration, have produced oil and gas fields with reserve volumes second to none. Two total petroleum systems (TPS), one of Paleozoic age and one of Jurassic age, in the central part of the Arabian Peninsula are identified in this report. The Central Arabia Qusaiba-Paleozoic TPS and the Arabian Sub-Basin Tuwaiq/Hanifa-Arab TPS of Jurassic age encompass the Greater Ghawar Uplift Province (USGS Province 2021) and portions of adjoining geologic provinces. Structures that trap hydrocarbons in these systems are mostly (1) large, gentle anticlines formed from reactivated basement fault blocks, (2) salt domes that resulted from halokinesis, or (3) structural traps resulting from a combination of these two processes. Major tectonic events that created these structures resulted from early Zagros rifting during the Early Triassic and two Alpine tectonic episodes that occurred during the Late Cretaceous and middle to late Tertiary. Hydrocarbons of the Central Arabia Qusaiba-Paleozoic TPS are sourced mainly by organic-rich, so-called "hot shale" that occurs in the basal part of the Lower Silurian Qusaiba Member of the Qalibah Formation. Oil and gas are produced mainly from sandstones of the Permian Unayzah and Devonian Jauf Formations, and from basal transgressive marine sandstones and cyclic, dolomitic shelf-carbonates of the Late Permian Khuff Formation. Two assessment units (AU) are recognized in the Central Arabia Qusaiba-Paleozoic TPS that are related to type of structural trap and presence of underlying Infracambrian salt: (1) the onshore Central Arch Horst-Block Anticlinal Oil and Gas AU, and (2) the mostly offshore North Gulf Salt Basin Structural Gas AU. The mean total volume of undiscovered resource for the Central Arabia Qusaiba-Paleozoic TPS is estimated at about 108 billion barrels of oil equivalent (BBOE). Oil of the Arabian Sub-Basin Tuwaiq/Hanifa-Arab TPS is sourced by organic-rich, marine carbonates of the Jurassic Tuwaiq Mountain and Hanifa Formations. These source rocks were deposited in two of three intraplatform basins during the Jurassic and, where thermally mature, have generated a superfamily of oils with distinctive geochemical characteristics. Oils were generated and expelled from these source rocks beginning in the Cretaceous at about 75 Ma. Hydrocarbon production is from 3 cyclic carbonate-rock reservoirs of the Arab Formation that are sealed by overlying anhydrite. Several giant and supergiant fields, including the world's largest oil field at Ghawar, Saudi Arabia, produce mostly from the Arab carbonate-rock reservoirs. Two assessment units are also recognized in the Arabian Sub-Basin Tuwaiq/Hanifa-Arab TPS that are similarly related to structural trap style and presence of underlying Infracambrian salt: (1) an onshore Horst-Block Anticlinal Oil AU, and (2) a mostly offshore Salt-Involved Structural Oil AU. The mean total volume of undiscovered resource for the Arabian Sub-Basin Tuwaiq/Hanifa-Arab TPS is estimated at about 49 billion barrels of oil equivalent (42 billion barrels of oil, 34 trillion feet of gas, and 1.4 billion barrels of natural gas liquids).

Arabian-Persian Gulf↗