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At least 91 records · Page 5Linked to original sources

Petrologic evolution of divergent peralkaline magmas from the Silent Canyon caldera complex, southwestern Nevada volcanic field

The Silent Canyon volcanic center consists of a buried Miocene peralkaline caldera complex and outlying peralkaline lava domes. Its location has been corroborated by geophysical data and more than 50 drill holes. Two widespread ash flow sheets, the Tub Spring and overlying Grouse Canyon members of the Miocene Belted Range Tuff, were erupted from the caldera complex and have volumes of 60–100 km 3 and 200 km 3 , respectively. Eruption of the ash flows was preceded by widespread extrusion of precaldera comendite domes and was followed by extrusion of postcollapse peralkaline lavas and tuffs within and outside the caldera complex. Lava flows and tuffs were also deposited between the two major ash flow sheets. Rocks of the Silent Canyon center vary significantly in silica content and peralkalinity. The most mafic rocks are precollapse and postcollapse trachytes (65–69% SiO 2 ). Low-silica comendites (69–73% SiO 2 ) were erupted as the mafic upper part of the chemically zoned Grouse Canyon Member and as postcollapse lavas. The lower part of the Grouse Canyon Member and the underlying rhyolite of Split Ridge are moderately peralkaline comendite (PI is molar ratio Na + K/Al is 1.17–1.26). These comendites have major element characteristics and trace element enrichments approaching those of pantellerites. The Tub Spring Member, by contrast, is a weakly peralkaline chemically unzoned silicic comendite (75–76% SiO 2 ) ash flow tuff. Weakly peralkaline silicic comendites (PI 1.0–1.1) are the most abundant precaldera lavas. Postcollapse lavas range from trachyte to silicic comendite; some have anomalous light rare earth element (LREE) enrichments. Silent Canyon rocks follow a common petrologic evolution from trachyte to low-silica comendite; above 73% SiO 2 , compositions of the moderately peralkaline comendites diverge from those of the weakly peralkaline silicic comendites. These contrasting differentiation paths are shown in the behavior of Fe and other transition metals, Al, Na, K; the trace elements Ba, Zr, Nb; and probably F and Cl. Weakly peralkaline silicic comendites show a LREE/heavy REE crossover in early erupted/late erupted rocks; moderately peralkaline comendites are enriched in all REE. The development of divergent peralkaline magmas, toward both pantelleritic and weakly peralkaline compositions, is unusual in a single volcanic center.

Journal of Geophysical Research Solid Earth↗

Multi-stage origin of the Coast Range ophiolite, California: Implications for the life cycle of supra-subduction zone ophiolites

The Coast Range ophiolite of California is one of the most extensive ophiolite terranes in North America, extending over 700 km from the northernmost Sacramento Valley to the southern Transverse Ranges in central California. This ophiolite, and other ophiolite remnants with similar mid-Jurassic ages, represent a major but short-lived episode of oceanic crust formation that affected much of western North America. The history of this ophiolite is important for models of the tectonic evolution of western North America during the Mesozoic, and a range of conflicting interpretations have arisen. Current petrologic, geochemical, stratigraphic, and radiometric age data all favor the interpretation that the Coast Range ophiolite formed to a large extent by rapid extension in the forearc region of a nascent subduction zone. Closer inspection of these data, however, along with detailed studies of field relationships at several locales, show that formation of the ophiolite was more complex, and requires several stages of formation. Our work shows that exposures of the Coast Range ophiolite preserve evidence for four stages of magmatic development. The first three stages represent formation of the ophiolite above a nascent subduction zone. Rocks associated with the first stage include ophiolite layered gabbros, a sheeted complex, and volcanic rocks vith arc tholeiitic or (roore rarely) low-K calc-alkaline affinities. The second stage is characterized by intrusive wehrlite-clinopyroxenite complexes, intrusive gabbros, Cr-rich diorites, and volcanic rocks with high-Ca boninitic or tholeiitic ankaramite affinities. The third stage includes diorite and quartz diorite plutons, felsic dike and sill complexes, and calc-alkaline volcanic rocks. The first three stages of ophiolite formation were terminated by the intrusion of mid-ocean ridge basalt dikes, and the eruption of mid-ocean ridge basalt or ocean-island basalt volcanic suites. We interpret this final magmatic event (MORB dikes) to represent the collision of an active spreading ridge. Subsequent reorganization of relative plate motions led to sinistral transpression, along with renewed subduction and accretion of the Franciscan Complex. The latter event resulted in uplift and exhumation of the ophiolite by the process of accretionary uplift.

California↗

Subaqueous grain flows at the head of Carmel Submarine Canyon, California

The head of Carmel Submarine Canyon lies in 15 m of water about 200 m off a coarse-sand beach in the southeast corner of Carmel Bay, California. Very coarse sand is the predominate material on the beach, adjacent shelf, and upper canyon-head slopes, while silt and clay cover the surface below a water depth of about 35 m. Along a shore-normal transect, median grain size decreases between the beach and canyon rim but increases down the upper canyon-head slope. On angle-of-repose slopes in the upper canyon head, downslope-coarsening deposits, which are everywhere there is active sand movement, are similar to a type of sediment gravity flow deposit formed by grain flows (sand avalanches). Using three sand fractions that were dyed different fluorescent colors, scuba divers generated sand avalanches that produced deposits similar to the natural deposits. The dyed-sand deposits, which extended as far as 25 m below the initiation point, were inversely graded and increased in grain size downslope. Inverse grading was well developed within two m of the initiation point, though the thicknesses of the three layers varied in a nonsystematic manner both across and down slope. The minor amount of native material found within the dyed-sand layers showed that entrainment of the underlying sand was minimal.

Journal of Sedimentary Petrology↗

Pore systems and organic petrology of cretaceous Mowry and Niobrara source-rock reservoirs, Powder River Basin, Wyoming, USA

The Powder River Basin (PRB) is a world-class oil province, in large part thanks to contributions from premier source rocks, Cretaceous Mowry and Niobrara shales. Both formations are also unconventional reservoirs. A critical aspect of evaluating production potential and finding sweet spots is the nature of the pore systems in these fine-grained source-rock reservoirs. Variation by stratigraphic interval is important for selecting optimum target zones for horizontal wells. Understanding variation in pore type, size, and connectivity and relationships with mineralogy and fabric help in determining prospectivity in different parts of the basin. Deciphering controls on pore-system development helps predict intervals and locations of optimum reservoir quality. Imaging of Niobrara and Mowry samples from a range of thermal maturities provided observations and data on pore systems, organic matter (OM) types and associations with mineralogy and fabric, wettability, and microporosity associated with both diagenetic and detrital clays. Imaging techniques included scanning electron microscopy, organic petrography and correlative scanning electron microscopy, and mapping of mineralogy through energy dispersive spectroscopy. Mean solid bitumen (BR o ) and vitrinite reflectance (VR o ) values indicate all samples are in the oil window with values ranging from 0.52 to 1.15%. Organic fluorescence is prominent in amorphous OM, solid bitumen and some vitrinite in the early oil window. The fluorescence is extinguished at higher thermal maturity. Carbonate pellets (in Niobrara) mainly contain migrated solid bitumen and residual live oil and little or no terrigenous OM (vitrinite and inertinite). However, terrigenous OM is common in siliceous/argillaceous laminae in both formations, where it occurs with amorphous OM, some of which has converted in situ to a solid bitumen petroleum residue. One key finding is the widespread presence of migrated OM at very early oil window maturity. Distribution of such OM and associated wettability alteration is fabric-controlled, at all levels of thermal maturity studied. Clay morphology and abundance and supporting rigid mineral grain framework strongly influence pore development, preservation, and connectivity in both formations. Carbonate content is a good proxy for reservoir quality in Niobrara intervals due to association of porous solid bitumen with calcareous fecal pellets. High recrystallized microquartz content is associated with the best reservoir intervals in the Mowry.

Wyoming↗

Minor element abundance in a part of the Brazilian shield

Thirty-nine samples of granitic rocks from the Quadrilátero Ferrifero, Minas Gerais, Brazil, representing "mixed" ages and at least three distinct Pre-Cambrian ages were analysed for seventeen minor elements. The rocks are placed in five groups:, (1) 2400 million year old group;, (2) Bacao complex younger, a group of mixed rocks derived from, (1) and, (3);, (3) 1350 million year old group;, (4) a 500 million year old gneissic group;, (5) a 500 million year old silicic group, a later differentiate of a 500 million year old magma. Compared to granitic rocks elsewhere, these Brazilian rocks are about average in Ba, So, Zr, Pb, Nb, Co, Ni, Be and Mo; above average in La and Y; and below average in Cu, Sr, Ga, Sn, V and Cr. Compared to metasedimentary rocks elsewhere in the world., metasedimentary rocks of this region are about average in all seventeen minor elements. Sr has its greatest abundance in the 2400 million year old rocks; Ba, V, Co, Sc, Cr, Ni and Cu in the 1350 million year; and La, Nb, Sn, Zr, Y and Ga in the 500 million year silicic. These abundances are in accord with the petrology and chemistry of the rocks. The 1350 million year rocks are the most mafic of the group and should logically concentrate Ba, V, Co, So, Or, Ni and Cu which are most abundant in earlier crystallates. The 500 million year old silicic rocks are the most felsic and should concentrate La, Nb, Sn, Zr, Y and Ga, which are all most abundant in the latest fractions of granitic magna crystallization. The trace elements also lend support to the idea that the Bacao complex rocks developed by anatexis of 2400 million year rocks during the 1350 -pillion year orogeny. Cu, Sc, Ga, Zr, Sn and Nb have about the same magnitude in the Bagao and the 2400 million year rocks and Sr, V, Co, Or and Ni are lower in the BagAo than either the 2400 or the 1350 million yoar old rocks. This lower abundance is a probable effect of "debasif-cation" which is also brought out by the analysis of major constituents. The effects of a geochemical migration of the elements in this part of the earth's crust may be indicated by the increased abundance of Y in successivol y younger rock types. The increase of La, Nb, Pb, Sn, Y and Zr in the 1350 million year rocks compared to the 2,100 million year rocks might also be an effect of a secular migration.

southeast Brazil↗

Pressure increases, the formation of chromite seams, and the development of the ultramafic series in the Stillwater Complex, Montana

This paper explores the hypothesis that chromite seams in the Stillwater Complex formed in response to periodic increases in total pressure in the chamber. Total pressure increased because of the positive δ V of nucleation of CO 2 bubbles in the melt and their subsequent rise through the magma chamber, during which the bubbles increased in volume by a factor of 4–6. By analogy with the pressure changes in the summit chambers of Kilauea and Krafla volcanoes, the maximum variation was 0⋅2–0⋅25 kbar, or 5–10% of the total pressure in the Stillwater chamber. An evaluation of the likelihood of fountaining and mixing of a new, primitive liquid that entered the chamber with the somewhat more evolved liquid already in the chamber is based upon calculations using observed and inferred velocities and flow rates of basaltic magmas moving through volcanic fissures. The calculations indicate that hot, dense magma would have oozed, rather than fountained into the chamber, and early mixing of the new and residual magmas that could have resulted in chromite crystallizing alone did not take place.

Journal of Petrology↗

Porphyry copper and other intrusion-related mineralization in Mexico

Intrusion-related copper-bearing ore deposits in Mexico span a wide-range of deposit types and geological settings and formed from the mid-Mesozoic through the Holocene. These deposits include world-class copper porphyry and skarn deposits as well as a continuum of similar skarn, porphyry, vein, and replacement deposits that contain variable quantities of molybdenum, zinc, silver, lead, iron, gold, tungsten, tin, fluorine, and beryllium. Based on a new compilation, this paper reviews data on the full spectrum of intrusion-related deposits, concentrating on copper-rich systems, and attempts to place them in a generalized geological and petrological context. In Mexico, intrusion-related mineral deposits are primarily Mesozoic to middle Tertiary in age. Three broad periods are prominent in the mineralization record: the late Mesozoic, the Laramide, and the middle Tertiary. Jurassic to Late Cretaceous calc-alkalic batholiths with sparse volcanic rocks occur along the Pacific margin mainly on eugeoclinal crust, although locally on continental crust (for example, in Sonora). Latest Cretaceous to Early Tertiary ('Laramide') calc-alkalic batholithic, subvolcanic, and volcanic centers occur in an overlapping but somewhat more easterly band that extends with diminished intensity and somewhat younger ages into the Sierra Madre Oriental. Mid-Tertiary volcanism and local intrusive centers are widely developed, with the greatest abundance of calcalkalic felsic volcanics in the Sierra Madre Occidental and more mafic middle to late Tertiary arc volcanics in the Sierra Madre del Sur in southern Mexico and as a fringe of alkalic volcanic' and sub volcanic centers in northeastern Mexico. Over 600 copper-rich intrusion-related systems can be inferred from the literature; about 100 can be documented with some confidence. Copper-rich deposits occur with both intermediate (dioritic) and felsic (granodioritic) intrusive centers and show a corresponding variety of associated metals and alteration types. Styles include porphyry-type disseminated or stockwork mineralization, skarn, breccia pipes, and pegmatites. Multiple styles commonly occur in the same district. Porphyry copper deposits are best developed in association with the Laramide intrusive centers of northern Mexico and the mid-Tertiary intrusions in southern Mexico. Other intrusion-related deposit types occur within the same magmatic framework, but they have different temporal and spatial correlations related to their igneous composition and exposure level. The continuum of intrusion-related mineralization in Mexico can be divided by geological associations, metal contents, and styles of alteration. Although more than 1,500 intrusion-associated mineral deposits are known, the scarcity of data requires a simplified approach focusing on major districts. We distinguish the following overlapping groups of deposits based on their metal contents and igneous compositions: (1) porphyry or skarn Cu(-Mo-Zn) associated with intermediate to felsic granitoids, (2) porphyry or skarn Cu (-Au-Fe) associated with intermediate intrusions, (3) greisen, skarn, or pegmatite W(-Mo) associated with intermediate to felsic granitoids, (4) replacement or skarn Zn-Pb-Ag(-Cu-F) deposits associated with felsic intrusions, (5) volcanic-hosted vein Ag-Au(-Zn-F-Sn) deposits associated with hypabyssal felsic intrusions, (6) vein ± replacement Ag-Au(-Cu-Zn-Pb) deposits associated with intermediate stocks, (7) volcanichosted Au-Ag(-Cu) systems, (8) rhyolite-related F(-Sn-Be) deposits, (9) diorite-related Fe(-Au-Cu) skarns, and (9) rhyolite-related Fe deposits. Some inferences can be drawn from examination of these patterns: • Igneous compositions vary in time and space in Mexico, but multiple compositions commonly were emplaced at different times in the same region. Temporal variations (as in Sonora) are as important as differences in province (as between Sonora and southern Mexico). • Alteration and metal differences between alkaline and sub alkaline, felsic and mafic magma suites can be partly rationalized from equilibria among igneous minerals (for example, in terms of a Al 2 O 3 vs a CaO [vs a SiO 2 ]), fluid chloride and sulfur contents, and magmatic metal contents which reflect province and process. • Exposure and preservation filter observed Mexican metallogeny. Erosion of the Mesozoic arc superstructure in the west leaves mainly tungsten-skarns, burial of the Laramide arc in central Mexico interrupts porphyry copper patterns, and minimal exhumation of mid-Tertiary intrusive centers preserves distal vein or replacement systems. • The superimposed metallogenic patterns in Mexico have parallels with metallogenic patterns in the western United States in terms of the effects of preservation, process, and province. Future work should focus on increasing the basic geological data on mineral deposits and igneous rocks. Geochronology, petrology, and geochemistry would help better define the temporal, spatial, and compositional interrelationships between tectonism, magmatism, and mineralization.

Book chapter↗

Petrologic and geophysical nature of serpentinites

Mineralogically, serpentinites consist predominantly of lizardite, clinochrysotile, and antigorite. Recent work has shown that these minerals are not polymorphs. Chrysotile is the only mineral recognized as a synthetic product in experimental studies of the system MgO-SiO 2 -H 2 O. Antigorite seems to be stable at higher temperatures than lizardite or chrysotile. The density of individual serpentine species is dependent on their morphology; the low-density serpentinites (<2.55g/cc) consist predominantly of clino-chrysotile. Seismic velocities and magnetic susceptibilities of serpentinites are related to the degree of serpentinization. The transition of massive serpentinites from ductile to brittle behavior in laboratory experiments at high confining pressures and temperatures above 300°C has been related to dehydration which may provide a mechanism for developing deep-focus earthquakes along Benioff zones. Serpentinite is formed by direct hydration of ultramafic protolith in the crust. The most common ultramafic protoliths are harzburgite, dunite, and Iherzolite. The assemblage generally developed from these is lizardite + chrysotile + brucite + magnetite. In areas of high-grade metamorphism, antigorite is the predominant serpentine mineral. The common, large, alpine-type serpentinized ultramafic masses contain brucite and have MgO/SiO 2 ratios similar to those of their protolith, resulting in volume increase during serpentinization. Metamorphic serpentinites and some highly sheared alpine-type serpentinites have lower MgO/SiO 2 ratios than their protolith, lack brucite, and appear t o have been formed by volume-for-volume replacement with concomitant loss of magnesium or addition of silica. Many large, young masses of peridotite appear to be slabs of oceanic mantle over-thrust onto continental edges. Subsequent sedimentation, serpentinization, and tectonism have greatly modified these original slabs so that their recognition in older orogenic zones is equivocal. The concept of the tectonic evolution of ultramafic rocks from oceanic crust-mantle slabs invading continental margins and being incrementally serpentinized and moved by later tectonic events provides a working hypothesis that allows a better explanation of the many peculiar and varied occurrences of serpentinite. The evidence does not support Hess' suggestion that the third layer of the oceanic crust consists of partly serpentinized mantle peridotite.

Bulletin of the Geological Society of America↗

Thermal and petrologic constraints on lower crustal melt accumulation under the Salton Sea Geothermal Field

In the Salton Sea region of southern California (USA), concurrent magmatism, extension, subsidence, and sedimentation over the past 0.5 to 1.0 Ma have led to the creation of the Salton Sea Geothermal Field (SSGF)—the second largest and hottest geothermal system in the continental United States—and the small-volume rhyolite eruptions that created the Salton Buttes. In this study, we determine the flux of mantle-derived basaltic magma that would be required to produce the elevated average heat flow and sustain the magmatic roots of rhyolite volcanism observed at the surface of the Salton Sea region. We use a 2D thermal model to show that a lower-crustal, partially molten mush containing &lt; 20 &#x2013; 40 % "> <20–40% interstitial melt develops over a &#x223C; 10 5 "> ∼105 -yr timescale for basalt fluxes of 0.008 to 0.010 m 3 / m 2 / yr "> 0.010m3/m2/yr (∼0.0008 to ∼0.001 km / 3 yr "> /3yr injection rate) given extension rates at or below the current value of ∼0.01 m/yr ( Brothers et al., 2009 ). These regions of partial melt are a natural consequence of a thermal regime that scales with average surface heat flow in the Salton Trough, and are consistent with seismic observations. Our results indicate limited melting and assimilation of pre-existing rocks in the lower crust. Instead, we find that basalt fractionation in the lower crust produces derivative melts of andesitic to dacitic composition. Such melts are then expected to ascend and accumulate in the upper crust, where they further evolve to give rise to small-volume rhyolite eruptions (Salton Buttes) and fuel local spikes in surface heat flux as currently seen in the SSGF. Such upper crustal magma evolution, with limited assimilation of hydrothermally altered material, is required to explain the slight decrease in &#x3B4; 18 O "> δ18O values of zircons (and melts) that have been measured in these rhyolites.

California↗

Origin of metaluminous and alkaline volcanic rocks of the Latir volcanic field, northern Rio Grande rift, New Mexico

Volcanic rocks of the Latir volcanic field evolved in an open system by crystal fractionation, magma mixing, and crustal assimilation. Early high-SiO2 rhyolites (28.5 Ma) fractionated from intermediate compositionmagmas that did not reach the surface. Most precaldera lavas have intermediate-compositions, from olivine basaltic-andesite (53% SiO2) to quartz latite (67% SiO2). The precaldera intermediate-composition lavas have anomalously high Ni and MgO contents and reversely zoned hornblende and augite phenocrysts, indicating mixing between primitive basalts and fractionated magmas. Isotopic data indicate that all of the intermediate-composition rocks studied contain large crustal components, although xenocrysts are found only in one unit. Inception of alkaline magmatism (alkalic dacite to high-SiO2 peralkaline rhyolite) correlates with, initiation of regional extension approximately 26 Ma ago. The Questa caldera formed 26.5 Ma ago upon eruption of the >500 km3 high-SiO2 peralkaline Amalia Tuff. Phenocryst compositions preserved in the cogenetic peralkaline granite suggest that the Amalia Tuff magma initially formed from a trace element-enriched, high-alkali metaluminous magma; isotopic data suggest that the parental magmas contain a large crustal component. Degassing of water- and halogen-rich alkali basalts may have provided sufficient volatile transport of alkalis and other elements into the overlying silicic magma chamber to drive the Amalia Tuff magma to peralkaline compositions. Trace element variations within the Amalia Tuff itself may be explained solely by 75% crystal fractionation of the observed phenocrysts. Crystal settling, however, is inconsistent with mineralogical variations in the tuff, and crystallization is thought to have occurred at a level below that tapped by the eruption. Spatially associated Miocene (15-11 Ma) lavas did not assimilate large amounts of crust or mix with primitive basaltic magmas. Both mixing and crustal assimilation processes appear to require development of relatively large magma chambers in the crust that are sustained by large basalt fluxes from the mantle. The lack of extensive crustal contamination and mixing in the Miocene lavas may be related to a decreased basalt flux or initiation of blockfaulting that prevented pooling of basaltic magma in the crust. ?? 1988 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Oligocene–Miocene development and evolution of the south Dome Rock Mountains basin, lower Colorado River corridor, Arizona, USA

Sedimentary basins in the Colorado River extensional corridor record large-magnitude Basin and Range extension and younger dextral shear deformation in the evolving Pacific−North America plate boundary. The south Dome Rock Mountains basin is located in west-central Arizona (USA), where the history of basin evolution, style of deformation, and timing of the transition between extension and dextral shear are not well constrained. We integrate new geologic mapping of the south Dome Rock Mountains basin with zircon U-Pb geochronology of six marker beds to characterize the timing of basin evolution and the slip history of the south Dome Rock Mountains normal fault. Structural analysis defines structures consistent with regional extension and younger dextral shear deformation. We use sedimentological and petrological analysis to interpret the depositional environments of three basin sequences. A lower basin sequence consists of fluvial strata deposited in an internally drained intermontane basin from ca. 35 Ma to 24.4 Ma. A sequence of volcanic rocks was emplaced in the basin between 24.4 Ma and 23.3 Ma, before the onset of local extensional faulting. An upper basin sequence of coarse conglomerate and sedimentary breccia was deposited on the hanging wall of a half graben structure after 23.3 Ma and through ca. 12.8 Ma, synchronous with 3−7 km of dip slip on the west-dipping, listric south Dome Rock Mountains fault. The basin was subsequently deformed by dextral shear after 12.8 Ma and before 4.8 Ma. These results document how distributed deformation related to the evolving Pacific−North America plate boundary occurred >100 km from the primary plate boundary.

Arizona, California↗

Coupled interactions between volatile activity and Fe oxidation state during arc crustal processes

Arc magmas erupted at the Earth&rsquo;s surface are commonly more oxidized than those produced at mid-ocean ridges. Possible explanations for this high oxidation state are that the transfer of fluids during the subduction process results in direct oxidation of the sub-arc mantle wedge, or that oxidation is caused by the effect of later crustal processes, including protracted fractionation and degassing of volatile-rich magmas. This study sets out to investigate the effect of disequilibrium crustal processes that may involve coupled changes in H 2 O content and Fe oxidation state, by examining the degassing and hydration of sulphur-free rhyolites. We show that experimentally hydrated melts record strong increases in Fe 3+ /&sum;Fe with increasing H 2 O concentration as a result of changes in water activity. This is relevant for the passage of H 2 O-undersaturated melts from the deep crust towards shallow crustal storage regions, and raises the possibility that vertical variations in f O 2 might develop within arc crust. Conversely, degassing experiments produce an increase in Fe 3+ /&sum;Fe with decreasing H 2 O concentration. In this case the oxidation is explained by loss of H 2 as well as H 2 O into bubbles during decompression, consistent with thermodynamic modelling, and is relevant for magmas undergoing shallow degassing en route to the surface. We discuss these results in the context of the possible controls on f O 2 during the generation, storage and ascent of magmas in arc settings, in particular considering the timescales of equilibration relative to observation as this affects the quality of the petrological record of magmatic f O 2 .

Journal of Petrology↗

The Boulder Creek Batholith, Front Range, Colorado

The Boulder Creek batholith is the best known of several large Precambrian batholiths of similar rock composition that crop out across central Colorado. The rocks in the batholith belong to the calc-alkaline series and range in composition from granodiorite through quartz diorite (tonalite) to gneissic aplite. Two rock types dominate': the Boulder Creek Granodiorite, the major rock unit, and a more leucocratic and slightly younger unit herein named Twin Spruce Quartz Monzonite. Besides mafic inclusions, which occur mainly in hornblende-bearing phases of the Boulder Creek Granodiorite, there are cogenetic older and younger lenses, dikes, and small plutons of hornblende diorite, hornblendite, gabbro, and pyroxenite. Pyroxenite is not found in the batholith. The Boulder Creek Granodiorite in the batholith represents essentially two contemporaneous magmas, a northern body occurring in the Gold Hill and Boulder quadrangles and a larger southern body exposed in the Blackhawk and the greater parts of the Tungsten and Eldorado Springs quadrangles. The two bodies are chemically and mineralogically distinct. The northern body is richer in CaO and poorer in K2O, is more mafic, and has a larger percentage of plagioclase than the southern body. A crude sequence of rock types occurs from west to east in the batholith accompanied by a change in plagioclase composition from calcic plagioclase on the west to sodic on the east. Ore minerals tend to decrease, and the ratio potassium feldspar:plagioclase increases inward from the western contact of the batholith, indicating that the Boulder Creek batholith is similar to granodiorite batholiths the world over. Emplacement of the Boulder Creek batholith was contemporaneous with plastic deformation and high-grade regional metamorphism that folded the country rock and the batholith contact along west-northwest and north-northwest axes. Also, smaller satellitic granodiorite bodies tend to conform to the trends of foliation and fold axes in the country rock, suggesting that emplacement was controlled by preexisting structures in the country rock. On a gross scale, chemical equilibrium in the Boulder Creek Granodiorite is expressed by a near 1:1 ratio, or straight-line relationship in the distribution of iron, magnesium, and manganese in biotite and hornblende. General mineralogical trends in the Boulder Creek Granodiorite indicate that modal biotite, hornblende, and plagioclase tend to increase and quartz and microcline tend to decrease as CaO increases. These trends were not found in the Twin Spruce Quartz Monzonite. Differentiation is believed to have played a major role and assimilation a minor role in the development of the Boulder Creek batholith. The Boulder Creek Granodiorite is of probable mantle or lower crust origin, and, based on the scant data available, the Twin Spruce Quartz Monzonite may be of crustal origin, but the magma was extensively altered by contaminants of ambiguous origin. Mafic inclusions, possibly derived from a dioritic magma which was an early differentiate associated temporally with the Boulder Creek Granodiorite and (or) the Twin Spruce Quartz Monzonite, were in jected into the Boulder Creek Granodiorite during the mush stage and before the batholith was completely crystallized. Biotite, hornblende, and potassium feldspar were studied extensively. Their chemistry and petrology indicate a homogeneity throughout the batholith not believed possible by a casual observance of the batholithic rocks in the field. The accessory minerals, where investigated, also tend to indicate this same pervasive homogeneity.

Professional Paper↗

Special topic—Eruption plumes and clouds

Introduction Explosive eruptions create plumes of volcanic ash and gas that can rise more than 30,000 feet (9.1 kilometers [km]) above sea level within minutes of eruption onset. The resulting clouds disperse under prevailing winds and may cause hazardous conditions hundreds to thousands of kilometers from the volcano, including in international airspace. Rapid detection and characterization of explosive activity is vital to mitigate the wide-ranging effects of volcanic ash. Ashfall thicknesses as small as a millimeter or so on the ground can affect infrastructure, agriculture, and air quality, requiring extensive clean-up procedures (Schuster, 1981; Warrick and others, 1981, U.S. Geological Survey, 2022). Volcanic clouds also pose substantial threats to aircraft. Since 1953, 88 encounters between airplanes and ash clouds have been documented worldwide (International Civil Aviation Organization, 2015, appendix F), resulting in aircraft damage and, in 9 cases, engine failure (Guffanti and others, 2010). In 1982, two large passenger planes suffered complete engine failure owing to eruptions in Indonesia (Global Volcanism Program, 1982) and a similar incident occurred over Alaska in 1989 (Casadevall, 1994). In all three cases, they were able to restart some engine capability and land safely once they emerged from the ash clouds, although with substantial damage (Guffanti and others, 2010). The clear threat to aviation has led to establishment of nine Volcanic Ash Advisory Centers (VAAC) around the world to monitor and rapidly disseminate information about volcanic eruptions to the aviation community. U.S. Geological Survey (USGS) volcano observatories issue the Volcano Observatory Notice for Aviation that informs of preeruptive unrest or eruptive activity. When ash-producing eruptions do occur, volcano observatories work closely with their regional VAAC to ensure consistency and accuracy in eruption onset time, cloud altitude, ash production, and duration as reported in Volcanic Ash Advisories. Explosive volcanism in the United States and Commonwealth of the Northern Mariana Islands prompts 50–100 such advisories in any given year (table J1). This collaborative effort is greatly aided by USGS detection and monitoring of eruption clouds to ensure a timely and coordinated response. To support these efforts to provide guidance on ash transport and fallout, the USGS developed the Ash3d volcanic ash dispersion model ( https://vsc-ash.wr.usgs.gov/ash3d-gui ) (Schwaiger and others, 2012). Automated simulations are run daily by the USGS for volcanoes that are in elevated states of unrest, and in response mode when eruptions occur. During eruptions, the model output is provided to local National Weather Service Weather Forecast Offices to guide them in the issuance of their information products (such as special weather statements, ashfall advisories, or ashfall warnings), as well as to State and local governments and the public. Characterization of the eruption source is needed to estimate the parameters used to initialize the Ash3d model, and by the Anchorage and Washington VAACs to initialize other dispersion models that inform forecasts for the airborne volcanic cloud. The source parameters that can be provided by observation during an eruption include eruption start time, eruption cloud height over time, and eruption duration. Other, nonobservable source parameters, such as mass eruption rate and grain-size distribution, are based on empirical correlations and study of historical deposits. The goal is to provide a time series of cloud heights, mass eruption rates, and particle-size distributions that accurately reflects current conditions. When feasible, the USGS also provides guidance on the nature of ongoing eruptions and forecasts future activity using petrologic monitoring of collected tephra samples. The aims of providing accurate observable parameters are achieved through analysis of (1) near-real-time meteorological satellite data, (2) ground-based cameras (see of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–G, 11 p., https://doi.org/10.3133/sir20245062g.">chapter G , this volume; Orr and others, 2024), (3) weather radar, (4) volcanic lightning detection, and (5) ground-based ash sensors and sampling. Explosive eruptions can be detected by a variety of geophysical monitoring, including infrasound (see of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–C, 11 p., https://doi.org/10.3133/sir20245062c.">chapter C , this volume; Lyons and others, 2024) and seismicity (see of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–B, 9 p., https://doi.org/10.3133/sir20245062b.">chapter B , this volume; Thelen and others, 2024). However, those methods cannot quantify the altitude, ash content, and dispersal dynamics of resulting volcanic clouds. Ideally, all available sources of monitoring data are synthesized to develop a coherent understanding of eruptive activity. The guidance summarized here provides a framework for characterizing volcanic clouds in the atmosphere and tracking the evolution of explosive eruption dynamics.

Scientific Investigations Report↗

Application of Sr and O isotope relations to the petrogenesis of the alkaline rocks of the Red Hill complex, New Hampshire, USA

The Red Hill ring complex in central New Hampshire is composed of apparently cogenetic syenites, nepheline-sodalite syenite, and granite. The ages and petrogenetic relations among five of the six recognized units have been investigated by rubidiumstrontium and oxygen isotope analysis of whole rocks and separated minerals. Whole-rock samples from three syenite units are consistent with a single Rb-Sr isochron which gives an age of 198??3 m.y. and an initial (87Sr/86Sr)o ratio of 0.70330??0.00016 (??2 sigma; ??=1.42?? 10-11y-1). However, Sr isotope data for two other units, nepheline syenite and granite, are not consistent with this isochron but rather indicate higher initial ratios which range from 0.7033 to about 0.707. Whole-rock O isotope analyses give ??18O values which range from+6.2 to+9.3??? Sr and O isotope analyses on mineral separates indicate that observed whole-rock variations in (87Sr/86Sr)o are primary and are not due to any secondary process. The fact that the isotope systematics correlate with rock type, suggests that crustal interaction is likely to have played a significant role in the development of this over-and undersaturated association. Such process(es), while still not fully delineated, could be of fundamental importance to the genesis of associations of critically undersaturated and oversaturated intrusives. The data support the idea that interaction between magmas and crustal materials strongly influenced the compositional relations of similar complexes elsewhere including those of the White Mountain magma series. ?? 1977 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Petrology, mineralogy and geochemistry of mined coals, western Venezuela

Upper Paleocene to middle Miocene coal samples collected from active mines in the western Venezuelan States of Táchira, Mérida and Zulia have been characterized through an integrated geochemical, mineralogical and petrographic investigation. Proximate, ultimate, calorific and forms of sulfur values, major and trace element, vitrinite reflectance, maceral concentrations and mineral matter content have been determined for 16 channel samples from 14 mines. Ash yield generally is low, ranging from < 1 to 17 wt.% (mean = 5 wt.%) on a dry basis (db). Total sulfur content is low to moderate, ranging from 1 to 6 wt.%, db (average = 1.7 wt.%). Calorific value ranges from 25.21 to 37.21 MJ/kg (10,840–16,000 Btu/lb) on a moist, mineral-matter-free basis (average = 33.25 MJ/kg, 14,300 Btu/lb), placing most of the coal samples in the apparent rank classification of high-volatile bituminous. Most of the coal samples exhibit favorable characteristics on the various indices developed to predict combustion and coking behavior and concentrations of possible environmentally sensitive elements (As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, Th and U) generally are similar to the concentrations of these elements in most coals of the world, with one or two exceptions. Concentrations of the liptinite maceral group range from < 1% to 70 vol.%. Five samples contain > 20 vol.% liptinite, dominated by the macerals bituminite and sporinite. Collotelinite dominates the vitrinite group; telinite was observed in quantities of ≤ 1 vol.% despite efforts to better quantify this maceral by etching the sample pellets in potassium permanganate and also by exposure in an oxygen plasma chamber. Inertinite group macerals typically represent < 10 vol.% of the coal samples and the highest concentrations of inertinite macerals are found in distantly spaced (> 400 km) upper Paleocene coal samples from opposite sides of Lago de Maracaibo, possibly indicating tectonic controls on subsidence related to construction of the Andean orogen. Values of maximum reflectance of vitrinite in oil ( R o max ) range between 0.42% and 0.85% and generally are consistent with the high-volatile bituminous rank classification obtained through ASTM methods. X-ray diffraction analyses of low-temperature ash residues indicate that kaolinite, quartz, illite and pyrite dominate the inorganic fraction of most samples; plagioclase, potassium feldspar, calcite, siderite, ankerite, marcasite, rutile, anatase and apatite are present in minor or trace concentrations. Semiquantitative values of volume percent pyrite content show a strong correlation with pyritic sulfur and some sulfide-hosted trace element concentrations (As and Hg). This work provides a modern quality dataset for the western Venezuela coal deposits currently being exploited and will serve as the foundation for an ongoing coal quality research program in Venezuela.

International Journal of Coal Geology↗

Petrology and comparative thermal and mechanical histories of clasts in breccia 62236

Lunar breccia 62236 contains large lithic fragments of troctolite, norite, and anorthosite. The mafic phases, olivine, inverted pigeonite, and augite, fill interstitial areas between larger plagioclases and appear to be cumulate phases with extensive adcumulus growth. Pyroxene compositional homogeneity indicates that cation exchange during cooling was limited to an area of about 1 mm. Primary augite and pigeonite both contain 30 μm-wide lamellae of the other along ‘001’. Pigeonite inverted to orthopyroxene without retaining any crystallographic orientation and subsequently exsolved fine lamellae of augite on (100). Profiles across orthopyroxene-augite interfaces obtained in the analytical transmission electron microscope show an increase of ∼5% wollastonite in augite within 0.5 μm of the interface, suggesting that short-range cation exchange continued to temperatures below 500°C. The entire sample has undergone heterogeneous shock deformation. Shock melting of the troctolitic clast suggests pressures of 200–300 kb and well-developed basal twinning in augite from the norite clasts suggests pressures of 50–300 kbars. The present evidence indicates that 62236 contains parts of a slowly cooled microlayered adcumulate that has been heterogeneously shocked several times and combined into the present breccia.

Journal of Geophysical Research Solid Earth↗

Origin of a South Texas roll-type deposit; II, Sulfide petrology and sulfur isotope studies

Petrologic and sulfur isotopic studies have been carried out on drill core samples from a roll-type uranium deposit in the mid-Tertiary Catahoula Tuff, Webb County, south Texas. Epigenetic iron disulfide minerals formed in two distinct stages. The first stage involved sulfidization of the host rock by sulfide (H 2 S, HS-)-bearing solutions that emanated from a fault about 1.5 km downdip from and subparallel to the orebody. Pyrite was the dominant iron disulfide mineral formed from this fault sulfide. The isotopic composition (delta 34 S) of first-stage iron disulfide is quite heavy (>0 per mil), in part because the fault-derived H 2 S was isotopically heavy. The development of the second-stage sulfides was related to processes that formed the uranium roll. Iron disulfide minerals produced during this second stage commonly occur as rims around the first-stage sulfides. The rims are exclusively marcasite in and adjacent to ore, but the pyrite content in these rims increases with increasing distance from ore. The sulfur of the second-stage sulfides in the vicinity of the roll front is isotopically light (--25 to --40 per mil). The virtual absence of organic carbon in the host sand precludes a bacterial origin for the ore-stage iron disulfide minerals and, therefore, eliminates bacterial metabolism as the mechanism for isotopic fractionation. Instead, the sulfur source for ore-stage sulfides was preore (first stage) sulfides, remobilized via partial oxidation to soluble metastable sulfur oxyanions.

Texas↗