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Water-resources data for the United States: Water year 2011

Water resources data are published annually for use by engineers, scientists, managers, educators, and the general public. These archival products supplement direct access to current and historical water data provided by NWISWeb. Beginning with Water Year 2006, annual water data reports are available as individual electronic Site Data Sheets for the entire Nation for retrieval, download, and localized printing on demand. National distribution includes tabular and map interfaces for search, query, display and download of data. From 1962 until 2005, reports were published by State as paper documents, although most reports since the mid-1990s are also available in electronic form through this web page. Reports prior to 1962 were published in occasional USGS Water-Supply Papers and other reports.

Water Data Report↗

Water-resources data for the United States: water year 2012

Water resources data are published annually for use by engineers, scientists, managers, educators, and the general public. These archival products supplement direct access to current and historical water data provided by NWISWeb. Beginning with Water Year 2006, annual water data reports are available as individual electronic Site Data Sheets for the entire Nation for retrieval, download, and localized printing on demand. National distribution includes tabular and map interfaces for search, query, display and download of data. From 1962 until 2005, reports were published by State as paper documents, although most reports since the mid-1990s are also available in electronic form through this web page. Reports prior to 1962 were published in occasional USGS Water-Supply Papers and other reports.

Water Data Report↗

Hydrologic monitoring in the area of the proposed Yazoo River navigation project, west-central Mississippi, 1978-80

The ground—water level data presented in this report were collected in conjunction with a study of the Mississippi River Valley alluvial aquifer in part of the Yazoo River Basin. Funding for the collection of water—level data was provided by the Vicksburg District, Corps of Engineers, who also drilled the observation wells and surveyed elevations of the top of the casing of each well. The wells were drilled to obtain data on seasonal changes in ground—water levels, areas of recharge and/or discharge, and on direction of movement of water in the alluvial aquifer. This report is intended to document the data.

Mississippi↗

Quality of ground water and surface water in intermontane basins of the northern Rocky Mountains, Montana and Idaho

The Regional Aquifer-System Analysis (RASA) program is a series of studies by the U.S. Geological Survey (USGS) to analyze regional ground-water systems that compose a major portion of the Nations water supply (Sun, 1986). The Northern Rocky Mountains Intermontane Basins is one of the study regions in this national program. The main objectives of the RASA studies are to: (1) describe the ground-water systems as they exist today, (2) analyze the known changes that have led to the system's present condition, (3) combine results of previous studies in a regional analysis, where possible, and (4) provide means by which effects of future ground-water development can be estimated. The purpose of this study, which began in 1990, was to increase understanding of the hydrogeology of the intermontane basins of the Northern Rocky Mountains area. This report is Chapter C of a three-part series and describes the quality of ground water and surface water in the study area. Chapter A (Tuck and others, 1996) describes the geologic history and generalized hydrogeologic units. Chapter B (Briar and others, 1996) describes the general distribution of ground-water levels in basin-fill deposits. Water-quality data illustrated in this report represent the distribution of concentrations and composition of dissolved solids in ground water and surface water in the intermontane areas. The chemistry of ground and surface water in the intermontane areas is influenced by the chemical and physical nature of the rocks in the basin deposits of the valleys and surrounding bedrock in the mountains.

Hydrologic Atlas↗

Ground water supplies of the Camden area, New Jersey

This report is one of several setting forth the results of investigations as to the safe yield of the principal water-bearing formations in certain parts of New Jersey, carried on cooperatively by the New Jersey Department of Conservation and Development and the United States Geological Survey. Other areas in which similar studies have been made are the Atlantic City area; the Asbury Park area; the Runyon area, including the Perth Amboy well field; the area embracing the well fields of the Commonwealth-Water Co., the East Orange Water Department, and other municipalities near the Passaic River in the vicinity of Chatham; and the Garfield Water Department well field and those of several industries in the vicinity of East Paterson. The results of the study in the Camden area are of value for several reasons. The greater part of the water supply of Camden comes from wells in three fields with an estimated capacity of about 30 million gallons a day, distribute1 over a triangular area of less than one square mile. This is one of the largest developments of ground water in so small an area in the United States. During the investigation a number of new wells were drilled in this area, and the type of wells and methods of pumping were changed, and observations were possible that otherwise could seldom be obtained under such favorable circumstances. As a result of the building of the new bridge across the Delaware River between Philadelphia and Camden there has been a considerable increase in population and in consumption of water in the Camden area, and this investigation is valuable in showing the extent to which further development of ground water is possible. The observations on which the report is based were made in the period from July 1, 1923, to the date of writing the report, in the early part of 1928.1 The continuing observations have been confined essentially to the well fields of the Camden Water Department. Certain data in regard to other well fields within a radius of 10 miles of Camden, collected by F. Clark Rule under the direction of the writer in the summer of 1923, and other data obtained from the files of the Department of Conservation and Development are also included in so far as they bear on the problems under consideration. The City of Camden has cooperated heartily through C. P. Sherwood, formerly director of the Department of Streets and Public Improvements, his successor, W. D. Sayrs, Jr., James H. Long, maintenance engineer of the Water Department, and David B. Owen, chief engineer of the Morris pumping station. Much valuable information has been furnished by the Layne-New York Co., which, during the period of the investigation, replaced nearly all the old-type wells of the Camden system with those of the most modern type. The investigation was under the immediate supervision of H. T. Critchlow, then chief of the Division of Waters of the Department of Conservation and Development, and O.E. Meinzer, geologist in charge of the Division of Ground Water of the United States Geological Survey. The late Dr. M. W. Twitchell, assistant State geologist, was consulted on phases relating to the stratigraphy. A number of analyses of water have been made by C. S. Howard, of the United States Geological Survey, and advice in regard to problems arising from the mineral character of the water has been given by W. D. Collins, chemist in charge of the Division of Quality of Water of the same organization. Thanks are also due to those of the other water departments and private well owners in the area who have furnished information.

New Jersey↗

Geology and ground-water conditions of Clark County, Washington, with a description of a major alluvial aquifer along the Columbia River

This report presents the results of an investigation of the ground-water resources of the populated parts of Clark County. Yields adequate for irrigation can be obtained from wells inmost farmed areas in Clark County, Wash. The total available supply is sufficient for all foreseeable irrigation developments. In a few local areas aquifers are fine-grained, and yields of individual wells are low. An enormous ground-water supply is available from a major alluvial aquifer underlying the flood plain of the Columbia River in the vicinity of Vancouver, Camas, and Washougal, where the aquifer is recharged, in part, by infiltration from the river. Yields of individual wells are large, ranging to as much as 4,000 gpm (gallons per minute). Clark County lies along the western flank of the Cascade Range. in the structural lowland (Willamette-Puget trough) between those mountains and the Coast Ranges to the west. The area covered by the report includes the urban, the suburban, and most of the agricultural lands in the county. These lands lie on a Series of nearly fiat plains and benches which rise steplike from the level of the Columbia River (a few feet above sea level) to about 800 feet above sea level. Clark County is-drained by the Columbia River (the trunk stream of the Pacific Northwest) and its tributaries. The Columbia River forms the southern and western boundaries of the county. Although the climate of the county is considered to be humid, the precipitation ranging from about 37 to more than 110 inches annually in various parts of the county, the unequal seasonal distribution (about 1.5 inches total for ;July and August in the agricultural area) makes irrigation highly desirable for most .crops and essential for some specialized crops. Consolidated rocks of Eocene to Miocene age, chiefly volcanic lava flows and pyroclastics but including some sedimentary strata, crop out in the foothills of the Cascades in the eastern part of the county and underlie the younger, unconsolidated rocks in the lowlands to the west At most places small to moderate quantities of water can be obtained from fractures in the older consolidated rocks. However, in the populated parts of the county, these rocks generally are overlain by considerable thicknesses of more permeable materials, and few wells have been drilled in them. Springs and dug wells yield an ample domestic supply at a number of outlying farms in the foothills. The younger (Pliocene to Recent) unconsolidated materials were deposited chiefly by streams in the basin formed by downwarping of the older rocks. However, some lake deposits and glacial drift also are included. The oldest unit of this group, the lower member of the Troutdale formation of Pliocene age, consists chiefly of clay, silt, and fine sand but includes lenses of coarser sand and, rarely, gravel. The maximum known thickness of the lower member of the Troutdale formation is about 660 feet. This unit is not a good aquifer because most of the strata are fine grained. However, at a few places drilled wells have penetrated lenses of coarser grained materials in these deposits and have obtained small to moderate amounts of water from them. The upper member of the Troutdale formation consists almost entirely of lightly to moderately cemented gravel, of which the most striking feature is the presence of a considerable percentage of quartzite pebbles. The average thickness of the upper member of the Troutdale may originally have been 300 to 400 feet. The member crops out over considerable areas in the county and, where conditions of topography and exposure are optimum, has beer very deeply weathered. It is suggested that the upper member of the Troutdale formation may prove to be of early Pleistocene age.

Washington↗

Hydrogeology and ground-water/surface water interactions in the Des Moines River valley, southwestern Minnesota, 1997-2001

Increased water demand in and around Windom led the U.S. Geological Survey, in cooperation with the Minnesota Department of Natural Resources, local water suppliers, and Cottonwood County, to study the hydrology of aquifers in the Des Moines River Valley near Windom. The study area is the watershed of a 30-kilometer (19-mile) reach of the Des Moines River upstream from Windom. Based on stratigraphic analysis, two hydrologically and genetically separate surficial aquifers underlie the study area. The Windom aquifer has a saturated thickness of 34 meters (111 feet), and the Des Moines aquifer has a saturated thickness of 33 meters (108 ft). The surficial aquifers are relatively isolated from deeper aquifers by till, but some leakage probably occurs. Recharge to the aquifers is from areal recharge, from Cottonwood Lake, and from edge recharge. Pumping at the Windom well field induces substantial amounts of Cottonwood Lake water into the aquifer. During this study, the water level in a well located between two Red Rock wells and the river was lower than the river level during two periods. During those periods, water in the Des Moines River had the potential to recharge the aquifer. Discharge from the aquifers is primarily to municipal wells, the Des Moines River, and other surface waters. Most of the ground-water samples collected in the study area consisted of calcium-magnesium bicarbonate waters. Corn and soybean herbicides and their degradates were detected at low concentrations in 14 of 27 ground-water samples and in all 3 river samples. Metolachlor ethane sulfonic acid was the most commonly detected compound and also was detected at the highest concentrations. Nutrient concentrations in ground-water samples were skewed low with high outliers, and nutrient concentrations in river samples generally were less than analytical reporting limits. Nearly all recharge to the aquifer in the ground-water simulation was from edge recharge (80 percent). Calibrated net areal recharge ranged from 17 to 30 percent of the average annual precipitation. Isotopic composition of ground water and Cottonwood Lake water indicated about one-half of the water withdrawn from the Windom aquifer is from Cottonwood Lake. Scenarios tested with the calibrated model involved increased ground-water withdrawals and changes in recharge to simulate drier or wetter weather conditions. Doubling the withdrawals from all wells in the model had a small effect except in the Windom well-field area. Maximum head declines in the Red Rock well field and the Jeffers city well were less than 40 centimeters (15 inches). In the Windom well field, the maximum head decline was 11 meters (36 feet). The Windom well field does not induce recharge from the Des Moines River. The addition of a new well that pumped 2,000 cubic meters per day (0.44 million gallons per day) in the Augusta Lake Valley area caused a 0.83-meter-deep (2.72-foot-deep) cone of depression that extended to the valley walls. The drought scenario and the high-precipitation scenario resulted in head changes in the northern part of the Augusta Lake Valley area, in the southwestern part of the Red Rock area, and near the valley edges. Long-term withdrawals of water for public supplies may cause a net decrease in ground-water discharge to surface water. Water that does not evaporate, or that is not exported, is discharged to the Des Moines River but with changed water quality. Because ground-water and surface-water qualities in the study area are similar, the ground-water discharge probably has little effect on river water quality.

Minnesota↗

Demonstration and validation of a regenerated cellulose dialysis membrane diffusion sampler for monitoring ground-water quality and remediation progress at DoD sites (ER-0313)

This final technical report documents the demonstration and validation of regenerated cellulose dialysis membrane diffusion samplers for use in collecting ground water samples for a range of inorganic and organic water-quality parameters. This project, ER-0313, was funded by the Environmental Security Technology Certification Program (ESTCP). The primary objectives of the project were; (1) to determine the usefulness of dialysis samplers in collecting a range of organic and inorganic water quality constituents from ground water, (2) to determine the optimum equilibration times for these constituents to diffuse into the dialysis sampler, (3) to compare water quality results and sampling costs from samples collected with dialysis samplers to samples collected with a low-flow purging technique and polyethylene diffusion bag (PDB) samplers, and (4) to transfer the technology while gaining regulatory acceptance. Field comparisons were conducted at three Department of Defense (DoD) sites: (1) Naval Air Engineering Station (NAES) Lakehurst, NJ, (2) Naval Base Ventura County (NBVC), Port Hueneme and Pt. Mugu, CA, and (3) Naval Air Warfare Center (NAWC) West Trenton, NJ. Dialysis samplers were found to cost significantly less than samples collected with a low-flow purging procedure. Field sampling time was reduced by a factor of more than six times, compared to low-flow purging. The total sampling costs per sample was estimated to be three times less, compared to low-flow purging.

Technical Report↗

Aquifer tests and simulation of ground-water flow in Triassic sedimentary rocks near Colmar, Bucks and Montgomery Counties, Pennsylvania

This report presents the results of a study by the U.S. Geological Survey in cooperation with the U.S. Environmental Protection Agency to evaluate ground-water flow in Triassic sedimentary rocks near Colmar, in Bucks and Montgomery Counties, Pa. The study was conducted to help the U.S. Environmental Protection Agency evaluate remediation alternatives at the North Penn Area 5 Superfund Site near Colmar, where ground water has been contaminated by volatile organic solvents (primarily trichloroethene). The investigation focused on determining the (1) drawdown caused by separately pumping North PennWater Authority wells NP–21 and NP–87, (2) probable paths of groundwater movement under present-day (2000) conditions (with NP–21 discontinued), and (3) areas contributing recharge to wells if pumping from wells NP-21 or NP–87 were restarted and new recovery wells were installed. Drawdown was calculated from water levels measured in observation wells during aquifer tests of NP–21 and NP–87. The direction of ground-water flow was estimated by use of a three-dimensional ground-water-flow model. Aquifer tests were conducted by pumping NP–21 for about 7 days at 257 gallons per minute in June 2000 and NP–87 for 3 days at 402 gallons per minute in May 2002. Drawdown was measured in 45 observation wells during the NP–21 test and 35 observation wells during the NP–87 test. Drawdown in observation wells ranged from 0 to 6.8 feet at the end of the NP–21 test and 0.5 to 12 feet at the end of the NP–87 test. The aquifer tests showed that ground-water levels declined mostly in observation wells that were completed in the geologic units penetrated by the pumped wells. Because the geologic units dip about 27 degrees to the northwest, shallow wells up dip to the southeast of the pumped well showed a good hydraulic connection to the geologic units stressed by pumping. Most observation wells down dip from the pumping well penetrated units higher in the stratigraphic section that were not well connected to the units stressed by pumping. The best hydraulic connection to the pumped wells was indicated by large drawdown in observation wells that penetrate the water-bearing unit encountered below 400 feet below land surface in wells NP–21 and NP–87. The hydraulic connection between wells NP–21 (or NP–87) and observation wells in the southern area of ground-water contamination near the BAE Systems facility is good because the observation wells probably penetrate this water-bearing unit. A 3-dimensional, finite-difference, groundwater- flow model was used to simulate flow paths and areas contributing recharge to wells for current (2000) conditions of pumping in the Colmar area and for hypothetical situations of pumping suggested by the U.S. Environmental Protection Agency that might be used for remediation. Simulations indicate that under current conditions, ground water in the northern area of contamination near the former Stabilus facility moves to the northwest and discharges mostly to West Branch Neshaminy Creek; in the southern area of contamination near BAE Systems facility, ground water probably moves west and discharges to a tributary of West Branch Neshaminy Creek near well NP–21. Model simulations indicate that if NP–21 or NP–87 are pumped at 400 gallons per minute, groundwater recharge is likely captured from the southern area of contamination, but ground-water recharge from the northern area of contamination is less likely to be captured by the pumping. Simulations also indicate that pumping of a new recovery well near BAE Systems facility at 8 gallons per minute and two new recovery wells near the former Stabilus facility at a total of about 30 gallons per minute probably would capture most of the ground-water recharge in the areas where contamination is greatest.

Water-Resources Investigations Report↗

Water Quality in the Delmarva Peninsula, Delaware, Maryland, and Virginia, 1999-2001

This report contains the major findings of a 1999-2001 assessment of water quality in the Delmarva Peninsula. It is one of a series of reports by the National Water-Quality Assessment (NAWQA) Program that present major findings in 51 major river basins and aquifer systems across the Nation. In these reports, water quality is assessed at many scales?from local ground-water flow paths to regional ground-water networks and in surface water?and is discussed in terms of local, State, and regional issues. Conditions in the Delmarva Peninsula are compared to conditions found elsewhere and to selected national benchmarks, such as those for drinking-water quality and the protection of aquatic organisms. This report is intended for individuals working with water-resource issues in Federal, State, or local agencies; universities; public interest groups; or in the private sector. The information will be useful in addressing a number of current issues, such as the effects of agricultural and urban land use on water quality, human health, drinking water, source-water protection, hypoxia and excessive growth of algae and plants, pesticide registration, and monitoring and sampling strategies. This report is also for individuals who wish to know more about the quality of streams and ground water in areas near where they live, and how that water quality compares to the quality of water in other areas across the Nation. Other products describing water-quality conditions in the Delmarva Peninsula are available. Detailed technical information, data and analyses, methodology, models, graphs, and maps that support the findings presented in this report can be accessed from http://md.water.usgs.gov/delmarva. Other reports in this series and data collected from other basins can be accessed from the national NAWQA Web site (http://water.usgs.gov/nawqa).

Circular↗

Surface-water hydrology of Honey Lake Valley, Lassen County, California, and Washoe County, Nevada

Honey Lake Valley straddles the state line of California and Nevada, about 35 miles north of Reno; about three-fourths of the area is in California. In this report, Honey Lake Valley (also referred to as the "basin") includes the entire area within the hydrographic boundary (fig. 1). Susanville, Calif., in the northwest part of the basin, is the largest town. Population is increasing rapidly both in the Susanville area and in the Reno area of adjacent Washoe County, Nev. Both Lassen and Washoe Counties have identified water resources in Honey Lake Valley as a possible source to meet their needs for future development. An important component of an assessment of the availability of additional long-term supply is an appraisal of surface-water resources. The U.S. Geological Survey, in cooperation with the California Department of Water Resources and the Nevada Division of Water Resources, began a hydrologic assessment of the area in 1987. The study was primarily an appraisal of ground-water resources, but it also included an assessment of surface-water resources. The purpose of this map report is to present the results of the surface-water assessment, including (1) a broad overview of surface-water conditions in the basin, (2) an estimate of mean annual streamflow to the valley floor, and (3) an evaluation of the characteristics of Honey Lake. This report will be republished by the U.S. Geological Survey as a Hydrologic-Investigations Atlas. Results of this study related to ground-water resources of the basin are discussed in a separate report (Handman and others, 1990) and are summarized in a short "Water Fact Sheet" by Handman (1990).

California, Nevada↗

Summary of water-quality data for City of Albuquerque drinking-water supply wells, 1988-97

The City of Albuquerque has collected and analyzed more than 5,000 water-quality samples from 113 water-supply wells in the Albuquerque area, including many drinking-water supply wells, since May of 1988. As a result, a large water-quality data base has been compiled that includes data for major ions, nutrients, trace elements, carbon, volatile organic compounds, radiological constituents, and bacteria. These data are intended to improve the understanding and management of the ground-water resources of the region, rather than demonstrate compliance with Federal and State drinking-water standards. This report gives summary statistics for selected physical properties and chemical constituents for ground water from wells used by the City of Albuquerque for drinking-water supply between 1988 and 1997. Maps are provided to show the general spatial distribution of selected parameters and water types around the region. Although the values of some parameters vary substantially across the city, median values for all parameters included in this report are less than their respective maximum contaminant levels in each drinking-water supply well. The dominant water types are sodium plus potassium / carbonate plus bicarbonate in the western part of the city and calcium / carbonate plus bicarbonate in the eastern part of the city.

Open-File Report↗

Water resources data, New Mexico, water year 1989

This annual hydrologic data report of New Mexico is one of a series of annual reports that document hydrologic data gathered frOm the u.s. Geological Survey's surface- and ground-water data-collection networks in each State, Puerto Rico, and the Trust Territories. These records of streamflow, ground-water levels, and water quality provide the hydrologic information needed by Federal, State, and local agencies and the private sector for developing and managing our Nation's land and water resources. Hydrologic data for New Mexico are contained in this volume. This report is the culmination of a concerted effort by dedicated personnel of the u.S. Geological Survey who collected, compiled, analyzed, verified, and organized the data, and who typed, edited, and assembled the report. The authors had primary responsibility for assuring that the information contained herein is accurate, complete, and adheres to Geological Survey policy and established guidelines. The following individuals contributed significantly to the completion of the report: Linda V. Beal Harriet R. Allen K.M. Lange, M.F. Ortiz, and L.A. Watson processed the text of the report, and H.M. Grossman drafted the illustrations.

New Mexico↗

Water resources data, New Mexico, water year 1990

This annual hydrologic data report of New Mexico is one of a series of annual reports that document hydrologic data gathered from the U.S. Geological Survey's surface- and ground-water data-collection networks in each State, Puerto Rico, and the Trust Territories. These records of streamflow, ground-water levels, and water quality provide the hydrologic information needed by Federal, State, and local. agencies and the private sector for developing and managing our Nation's land and water resources. Hydrologic data for New Mexico are contained in this volume. This report is the culmination of a concerted effort by dedicated personnel of the U.S. Geological Survey who collected, compiled, analyzed; verified, and organiZed the data, and who typed, edited, and assembled the report. The authors had primary responsibility for aSSUring that the information contained herein is accurate, complete, and adheres to Geological Survey policy and established guidelines. The following individuals contributed significantly to the completion of the report: Harriet R. Allen Mary Montano Cynthia J. Shattuck K.M. Lange, M.F. Ortiz, and L.A. Watson processed the text of the report, and H.M. Grossman drafted the illustrations.

New Mexico↗

Environmental overview and hydrogeologic conditions at Aniak, Alaska

The remote Native village of Aniak, on the flood plain of the Kuskokwim River in southwestern Alaska, has long cold winters and short summers that affect both the hydrology of the area and the lifestyle of the residents. Aniak obtains its drinking water from a shallow aquifer in the thick alluvium underlying the village. Surface spills and disposal of hazardous materials combined with annual flooding of the Kuskokwim River may affect the quality of the ground water. Alternative drinking water sources are available but at significantly greater cost than existing supplies. The Federal Aviation Administration (FAA) owns or operates airport support facilities in Aniak. The subsistence lifestyle of the villagers and the quality of the current environment must be taken into consideration when the FAA evaluates options for remediation of environmental contamination at these facilities. This report describes the ground- and surface-water hydrology, geology, climate, vegetation, soils, and flood potential of the areas surrounding the FAA sites.

Open-File Report↗

TopoDrive and ParticleFlow--Two computer models for simulation and visualization of ground-water flow and transport of fluid particles in two dimensions

This report serves as a user?s guide for two computer models: TopoDrive and ParticleFlow. These two-dimensional models are designed to simulate two ground-water processes: topography-driven flow and advective transport of fluid particles. To simulate topography-driven flow, the user may specify the shape of the water table, which bounds the top of the vertical flow section. To simulate transport of fluid particles, the model domain is a rectangle with overall flow from left to right. In both cases, the flow is under steady state, and the distribution of hydraulic conductivity may be specified by the user. The models compute hydraulic head, ground-water flow paths, and the movement of fluid particles. An interactive visual interface enables the user to easily and quickly explore model behavior, and thereby better understand ground-water flow processes. In this regard, TopoDrive and ParticleFlow are not intended to be comprehensive modeling tools, but are designed for modeling at the exploratory or conceptual level, for visual demonstration, and for educational purposes.

Open-File Report↗

Volatile organic compound matrix spike recoveries for ground- and surface-water samples, 1997-2001

The U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program used field matrix spikes (FMSs), field matrix spike replicates (FMSRs), laboratory matrix spikes (LMSs), and laboratory reagent spikes (LRSs), in part, to assess the quality of volatile organic compound (VOC) data from water samples collected and analyzed in more than 50 of the Nation's largest river basins and aquifers (Study Units). The data-quality objectives of the NAWQA Program include estimating the extent to which variability, degradation, and matrix effects, if any, may affect the interpretation of chemical analyses of ground- and surface-water samples. In order to help meet these objectives, a known mass of VOCs was added (spiked) to water samples collected in 25 Study Units. Data within this report include recoveries from 276 ground- and surface-water samples spiked with a 25-microliter syringe with a spike solution containing 85 VOCs to achieve a concentration of 0.5 microgram per liter. Combined recoveries for 85 VOCs from spiked ground- and surface-water samples and reagent water were used to broadly characterize the overall recovery of VOCs. Median recoveries for 149 FMSs, 107 FMSRs, 20 LMSs, and 152 LRSs were 79.9, 83.3, 113.1, and 103.5 percent, respectively. Spike recoveries for 85 VOCs also were calculated individually. With the exception of a few VOCs, the median percent recoveries determined from each spike type for individual VOCs followed the same pattern as for all VOC recoveries combined, that is, listed from least to greatest recovery-FMSs, FMSRs, LRSs, and LMSs. The median recoveries for individual VOCs ranged from 63.7 percent to 101.5 percent in FMSs; 63.1 percent to 101.4 percent in FMSRs; 101.7 percent to 135.0 percent in LMSs; and 91.0 percent to 118.7 percent in LRSs. Additionally, individual VOC recoveries were compared among paired spike types, and these recoveries were used to evaluate potential bias in the method. Variability associated with field spiking, field handling, transport, and analysis was assessed by comparing recoveries between 107 pairs of FMR and FMSR samples. For most VOCs, FMSR recoveries were greater than the paired FMS recoveries. This may result from routinely processing the FMS sample first, allowing a more fluid and efficient technique when processing the FMSR. Degradation was examined by comparing VOC recoveries between 20 pairs of FMS and LMS samples. For all VOCs, the LMS recoveries were greater than FMS recoveries. However, data presented in a previously published VOC stability study were interpreted, and recoveries indicated that VOC degradation should not affect the recovery for most VOCs monitored by the NAWQA Program. Matrix effects were examined by comparing VOC recoveries from 20 pairs of LMS and LRS samples. With the exception of two VOCs, individual recoveries were not significantly different between LMSs and LRSs, indicating that most VOC recoveries are not affected by matrix effects. Additionally, matrix effects should be negligible due to the analytical technique (purge and trap capillary column gas chromatography/mass spectrometry) used for VOC analysis at the U.S. Geological Survey National Water Quality Laboratory (NWQL). The reason for the lower VOC recoveries from FMSs and FMSRs than from LMSs and LRSs may be associated with differences in spiking technique and experience, and to varying environmental conditions at the time of spiking. However, for all spike types, 87 percent of the individual VOC recoveries were within the range of 60 to 140 percent, a range that is considered acceptable by the U.S. Environmental Protection Agency's established analytical method. Additionally, the median recovery for each spike type was within the range of 60 to 140 percent. The excellent VOC recoveries from LMSs and LRSs demonstrate that low VOC concentrations can routinely and accurately be measured by the analytical methods used by the NWQL.

Scientific Investigations Report↗

Method for Estimating Water Withdrawals for Livestock in the United States, 2005

Livestock water use includes ground water and surface water associated with livestock watering, feedlots, dairy operations, and other on-farm needs. The water may be used for drinking, cooling, sanitation, waste disposal, and other needs related to the animals. Estimates of water withdrawals for livestock are needed for water planning and management. This report documents a method used to estimate withdrawals of fresh ground water and surface water for livestock in 2005 for each county and county equivalent in the United States, Puerto Rico, and the U.S. Virgin Islands. Categories of livestock included dairy cattle, beef and other cattle, hogs and pigs, laying hens, broilers and other chickens, turkeys, sheep and lambs, all goats, and horses (including ponies, mules, burros, and donkeys). Use of the method described in this report could result in more consistent water-withdrawal estimates for livestock that can be used by water managers and planners to determine water needs and trends across the United States. Water withdrawals for livestock in 2005 were estimated by using water-use coefficients, in gallons per head per day for each animal type, and livestock-population data. Coefficients for various livestock for most States were obtained from U.S. Geological Survey water-use program personnel or U.S. Geological Survey water-use publications. When no coefficient was available for an animal type in a State, the median value of reported coefficients for that animal was used. Livestock-population data were provided by the National Agricultural Statistics Service. County estimates were further divided into ground-water and surface-water withdrawals for each county and county equivalent. County totals from 2005 were compared to county totals from 1995 and 2000. Large deviations from 1995 or 2000 livestock withdrawal estimates were investigated and generally were due to comparison with reported withdrawals, differences in estimation techniques, differences in livestock coefficients, or use of livestock-population data from different sources. The results of this study were distributed to U.S. Geological Survey water-use program personnel in each State during 2007. Water-use program personnel are required to submit estimated withdrawals for all categories of use in their States to the National Water-Use Information Program for inclusion in a national report describing water use in the United States during 2005. Water-use program personnel had the option of submitting these estimates, a modified version of these estimates, or their own set of estimates or reported data. Estimated withdrawals resulting from the method described in this report are not presented herein to avoid potential inconsistencies with estimated withdrawals for livestock that will be presented in the national report, as different methods used by water-use personnel may result in different withdrawal estimates. Estimated withdrawals also are not presented to avoid potential disclosure of data for individual livestock operations.

Scientific Investigations Report↗