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A synthesis engine for constructing geologic maps of the United States

The geologic history of the United States is cataloged in thousands of geologic maps produced during many decades. However, the disparate nature of these individual maps makes it challenging to assess resources, research geologic histories, or characterize natural hazards holistically across the Nation. The U.S. House of Representatives 2020 appropriations bill for the U.S. Department of the Interior (H.R. 116-100) requires the U.S. Geological Survey to “bring together detailed national and continental-resolution [two-dimensional] and [three-dimensional] information produced throughout the Survey and by [F]ederal and [S]tate partners.” In response to this directive, this report presents a compilation and synthesis of geologic maps across the United States in the form of a relational database. The synthesis database includes thematic maps that synthesize the Nation’s geology, and retains the original input maps as well as linkages to standardized vocabularies to aid the discoverability of geologic information. Specifically, the synthesis database is targeted toward producing four National-resolution maps for the conterminous United States: Quaternary geology, the geology at the Earth’s surface, pre-Quaternary geology, and Precambrian geology. In addition, the synthesis database includes the infrastructure necessary to expand to additional resolutions in the future.

conterminous United States

Projected sea-level rise and high tide flooding at Timucuan Ecological and Historic Preserve, Florida

Introduction National parks and preserves in the South Atlantic-Gulf Region contain valuable coastal habitats such as tidal wetlands and mangrove forests, as well as irreplaceable historic buildings and archeological sites located in low-lying areas. These natural and cultural resources are vulnerable to accelerated sea-level rise and escalating high tide flooding events. Through a Natural Resources Preservation Program-funded project during 2021–23, the U.S. Geological Survey, in collaboration with the National Park Service, estimated the probability of inundation at Timucuan Ecological and Historic Preserve, Florida, and several other parks under various sea-level rise scenarios and contemporary high tide flooding thresholds. The maps produced for this effort can be used to assess potential habitat change and explore how infrastructure and cultural resources within the park may be exposed to future flooding-related hazards.

Florida

Estimating earthquake source depth using teleseismic broadband waveform modeling at the USGS National Earthquake Information Center

The U.S. Geologic Survey National Earthquake Information Center (NEIC) monitors global seismicity, producing a catalog of earthquake source parameters in near-real-time to provide information that can help mitigate the societal impact of earthquakes. The NEIC commonly relies on teleseismic observations to constrain earthquake source parameters (e.g., location, depth, magnitude, and mechanism) due to a lack of local and regional observations. For these ‘teleseismic’ events, depth phase (i.e., pP , sP ) arrival time observations provide the best estimate on source depth. However, depth phases are often difficult to accurately identify and/or pick. Therefore, NEIC relies on waveform modeling, such as those determined from W-phase ( M ww ), body wave ( M wb ), and regional ( M wr ) moment tensor estimations, to provide constraints on source depth. While depth estimates from these approaches are informative, higher frequency observations provide more precise estimates because depth phases are more prominently observed at higher frequencies. Here, we present NEIC’s relatively high-frequency (~0.04 to 1 Hz) teleseismic waveform modeling approach, termed Synthetic Depth Phase Modeling (SynDepth), for determining source depth. SynDepth was developed to provide NEIC with a tool that enables rapid, accurate, and quantifiable estimates of earthquake source depth in cases where locator depths are not reliable. This relatively simple and fast procedure searches over 1 km-incremented source depths and an expanding triangular source-time function to find the best-fitting solution. We compare automatic SynDepth solutions for a dataset of 1,216 earthquakes (M5.5-M7.6) between 2017 and 2021 to NEIC-derived depth estimates from other methods. Our approach provides a robust depth estimate for earthquakes lacking local arrival time data, and it minimizes the need for analyst review of depth-phase picks ( pP , sP ) or using predefined ‘fixed’ depths.

Seismological Research Letters

Will there be water? Climate change, housing needs, and future water demand in California

Climate change in California is expected to alter future water availability, impacting water supplies needed to support future housing growth and agriculture demand. In groundwater-dependent regions like California's Central Coast, new land-use related water demand and decreasing recharge is already stressing depleted groundwater basins. We developed a spatially explicit state-and-transition simulation model that integrates climate, land-use change, water demand, and groundwater gain-loss to examine the impact of future climate and land use change on groundwater balance and water demand in five counties along the Central Coast from 2010 to 2060. The model incorporated downscaled groundwater recharge projections based on a Warm/Wet and a Hot/Dry climate future from a spatially explicit hydrological process-based model. Two urbanization projections from a parcel-based, regional urban growth model representing 1) recent historical and 2) state-mandated housing growth projections were used as alternative spatial targets for future urban growth. Agricultural projections were based on recent historical trends from remote sensing data. Annual projected changes in groundwater balance were calculated as the difference between land-use related water demand, based on historical estimates, and climate-driven recharge plus agriculture return flows. Results indicate that future changes in climate-driven groundwater recharge, coupled with cumulative increases in agricultural water demand, result in overall declines in future groundwater balance, with a Hot/Dry future resulting in cumulative groundwater decline in all but Santa Cruz County. Cumulative declines by 2060 are especially prominent in San Luis Obispo (−2.9 to −5.1 Bm 3 ) and Monterey counties (−6.5 to −8.7 Bm 3 ), despite limited changes in agricultural water demand over the model period. These two counties show declining groundwater reserves in a Warm/Wet future as well, while San Benito and Santa Barbara County barely reach equilibrium. These results suggest future groundwater supplies may not be able to keep pace with regional demand and declining climate-driven recharge, resulting in a potential reduction in water security in the region. However, our county-scale projections showed new housing and associated water demand does not conflict with California's groundwater sustainability goals. Rather, future climate coupled with increasing agricultural groundwater demand may reduce water security in some counties, potentially limiting available groundwater supplies for new housing.

California

ShakeAlert® version 3: Expected performance in large earthquakes

The ShakeAlert earthquake early warning (EEW) system partners along with U.S. Geological Survey (USGS) licensed operators deliver EEW alerts to the public and trigger automated systems when a significant earthquake is expected to impact California, Oregon, or Washington. ShakeAlert’s primary goal is to provide usable warning times before the arrival of damaging shaking. EEW is most likely to achieve this goal in large‐magnitude earthquakes. In recent years, ShakeAlert has gone through a series of upgrades to its underlying scientific algorithms aimed at improved performance during large earthquakes. Version 3 of this software recently went live in the production system and includes improvements to all algorithms. The main seismic algorithms that detect an earthquake and characterize its location, magnitude, and fault rupture orientation are faster than older versions. Other key changes include: using real‐time geodetic data to characterize the magnitude growth in large earthquakes; the introduction of an alert pause procedure to compromise between speed near the epicenter and improved accuracy at larger distances; and the inclusion of a nonergodic site‐response model in the ground‐motion predictions. ShakeAlert has achieved its primary goal of usable warning times before strong shaking at some locations in real‐time operations in recent M 6 earthquakes. Using offline tests, we demonstrate usable warning times are possible for many sites with peak shaking values of modified Mercalli intensity (MMI) 7–8 in M 7+ earthquakes and also for many MMI 8–9 sites in M 8+ earthquakes. ShakeAlert partners use a variety of MMI and magnitude thresholds in deciding when to alert their users within bounds set by the USGS. Our study shows that there is room to raise the magnitude thresholds up to about M 5.5 without adversely affecting performance in large earthquakes. The ground‐motion criteria are more complex owing to a significant drop‐off in warning times between the MMI 4 and 5 levels of predicted shaking. However, widely used ShakeAlert products, such as the MMI 3 and 4 contour products, can provide sufficiently long warning times before strong shaking in moderate‐to‐great earthquakes to enable a range of protective actions.

Bulletin of the Seismological Society of America

Cajon Pass and the southern San Andreas Fault System: Earthquake cycle stress accumulation and present-day loading

With over a century since the last major rupture affecting the wider Los Angeles region, tectonic stress has steadily built along the southern San Andreas and San Jacinto fault systems, raising concerns of an imminent large earthquake. Cajon Pass, located at the junction of these faults, represents a critical site for potential through-going ruptures in Southern California. We constructed new 4D earthquake cycle simulations using a 1000-year paleoseismic rupture history of the San Andreas Fault System (SAFS) to assess spatial and temporal variations in stress. A semi-analytic Fourier transform model was used to compute stress from 3D dislocations in an elastic plate overlying a Maxwell viscoelastic half-space, assuming a complete coseismic reset of resolved shear stress on ruptured elements. Results show highest stress accumulation north of Cajon Pass (∼1.8 MPa/100 years) due to greater slip rates, and lower rates south of Cajon Pass (∼1.0–1.5 MPa/100 years). By 2025, Coulomb stress is estimated at 2.8 MPa on the Mojave South (MOS) segment, 1.8 MPa on the North San Bernardino (NSB1) segment and 3.6 MPa on the San Jacinto Bernardino (SJB) segment. Segments accumulate stresses with characteristic ranges of pre-event stress interpreted as failure thresholds: 1.2–2.7 MPa for MOS, 0.4–1.6 MPa for NSB1, and 1.2–2.9 MPa for SJB. When the stress disparity between segments SJB and MOS narrows, the faults appear to rupture jointly, suggesting that stress levels may control how Cajon Pass acts as an earthquake gate. These results may inform seismic hazard assessments by linking stress evolution to fault interactions.

California

Implications of physics-based M9 ground motions on liquefaction-induced damage in the Cascadia Subduction Zone: Looking forward and backward

Given the likelihood of future M9 Cascadia Subduction Zone (CSZ) earthquakes, various estimates of the resulting, regional ground motions have been made, including a suite of 30 physics-based simulations that reflect key modeling uncertainties. However, because the last CSZ interface rupture occurred in 1700 CE, the shaking expected in such an event is especially uncertain, as are the impacts to the built and living environments. Like other coseismic impacts, soil liquefaction poses a significant threat and must be considered by any scenario study used to inform planning and response, or to focus mitigation resources. Liquefaction is also notable for its potential to “ground truth” ground-motion estimates, given that its presence or absence in the geologic record can provide constraint on the intensities of shaking in past events. It is thus an important phenomenon looking both forward and backward. Accordingly, using recent physics-based simulations, this study (1) predicts liquefaction in M9 CSZ ruptures at 400 locations in Oregon, Washington, and British Columbia (BC) using an array of cone-penetration-test based models and (2) uses paleoliquefaction evidence at ten sites spanning from Southern Oregon to Vancouver, BC to constrain possible ground-motion intensities experienced in the 1700 CE earthquake. The forward predictions indicate that liquefaction in M9 events could be pervasive in the region and affect numerous population hubs, with the potential for damage across hundreds of square kilometers. The backward analyses suggest that 1700 CE ground-motion intensities may have been less than expected from M9 simulations in some northern portions of the CSZ (e.g. Seattle), given the paucity of 1700 CE liquefaction evidence in these areas. Ultimately, further discovery and analysis of CSZ paleoliquefaction, or lack thereof, will confirm or modify this possibility and the conclusions drawn herein.

Oregon, Washington

On-demand global Landsat evapotranspiration product: Development, evaluation, and dissemination

Global actual evapotranspiration (ET) is one of the essential climate variables needed to understand and manage the relationships among food, energy, and water resources. The U.S. Geological Survey Earth Resources Observation and Science (EROS) Center launched a provisional ET product in 2020, offering on-demand, field-scale global coverage derived from Landsat data through the EROS Science Processing Architecture (ESPA) platform. The ESPA interface provides ET data for cloud-free Landsat overpasses starting in 1982 with Landsat 4 through the current Landsat 9. The ET data are delivered as a Provisional Level-3 Science product created using the Operational Simplified Surface Energy Balance (SSEBop) model. Landsat surface temperature and reference ET are the main model drivers along with vegetation index and net radiation for model parameterization. A large volume of Landsat-based ET orders (e.g., over 1,200,000 images from June 2020 through December 2025) around the world indicate increasing awareness and application of the ET data. The ESPA platform enables land and water resource managers and researchers to access a first-order ET product without requiring advanced knowledge of remote sensing technology or evapotranspiration modeling. We present the methodology and workflow of the on-demand Landsat ET product and its performance evaluations over diverse hydro-climatic settings. The product can help estimate field-scale consumptive water use and thus quickly and consistently assess historical water use, allocation, and budget to inform water management under changing environments. Future ET data aggregated to monthly and seasonal time scales are expected to enhance integration with decision-making tools and procedures.

Remote Sensing of Environment

Measurement of in situ-produced cosmogenic nuclides in fine-grained quartz from shale

In situ -produced 10 Be in quartz is widely used to constrain exposure ages and denudation rates, traditionally measured in sand-sized grains. Here we report a new method for isolating fine-grained quartz from shale and demonstrate its reliability for grain sizes down to single microns. Sequential dissolution tests and analyses of grain size separates show that meteoric 10 Be is eliminated and that recoil losses during cosmogenic nuclide production are balanced by implantation from other mineral grains. High-temperature combustion leads to diffusion of meteoric 10 Be into fine-grained quartz and must be used with caution.

Nuclear Instruments and Methods in Physics Researc

Near-surface geophysics: Environmental applications

The field of geophysics encompasses a broad and diverse compilation of methodologies that employs principles of physics to characterize properties of earth materials within the subsurface. While geophysical methods have a long history in resource exploration and studies of Earth’s interior, the subdiscipline of “near-surface geophysics” has evolved in recent decades for examination of the shallow, near-surface environment for a range of purposes ranging from archaeological or forensic investigations to assessment of geologic, hydrologic, biologic, and geochemical properties and processes. “Environmental geophysics” are near-surface geophysical studies and methods that focus on understanding natural systems (e.g., watershed hydrology, groundwater–surface water connections, biophysical processes) as well as research pertaining to anthropogenic impacts and land management, (e.g., contamination and remediation, saltwater intrusion, agricultural practices). This field can be further subdivided into subdisciplines focused on specific topics and applications, such as water resources and hydrology (hydrogeophysics) or biologic and microbial processes (biogeophysics). Studies in environmental geophysics span a range of scales, from pore-scale laboratory tests to watershed-scale or regional field experiments. Methods vary by the nature of physics employed, the specific measurement acquired, and how that data is ultimately processed and analyzed to produce interpretable results. There exists further diversity in the acquisition logistics, geometry, and timing of data collection. Geophysical data can be collected in boreholes (one-dimensional, 1-D, vertical profiles), along survey lines (two-dimensional, 2-D, cross-sections), or in dense sensor arrays or gridded profiles (three-dimensional, 3-D, models). Regarding the temporal aspect, studies can conduct one-time geophysical surveys to obtain detailed imaging of subsurface structure or use timelapse and continuous monitoring to investigate variations in subsurface properties over time. The cumulation of all possible permutations of these factors (method, acquisition geometry, survey design, and target application) results in an immense diversity among environmental geophysical studies. Nevertheless, this field remains unified in the pursuit of understanding natural and human-impacted near-surface environments through geophysical investigations. Here we highlight some key references within environmental geophysics. Resources on geophysical theory, acquisition logistics, processing and inversion workflows, and example case studies are categorized into the most common geophysical classes within Geophysical Methods. Lastly, example references for the dominant types of applications in environmental geophysical studies are catalogued in Environmental Applications.

Book chapter

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials changed very little in areas isolated from active ground-water flow paths. These stable areas in the karst aquifer had geochemical conditions and bacteria conducive to reductive dechlorination of chlorinated ethenes. Other areas of the karst aquifer were associated with active ground-water flow paths and fluctuated between anaerobic and aerobic conditions in response to rain events. Associated with this dynamic environment were bacteria and geochemical conditions conducive to cometabolism. In summary, multiple lines of evidence developed from chemical, biological, and hydrologic data demonstrate that a variety of biodegradation processes are active in this karst aquifer.

Tennessee

Spatial variation in effectiveness and costs of sagebrush restoration treatments across the western United States

Natural resource managers strive to improve restoration efficiency across the vast network of public lands of the United States, seeking the best return on investment through innovation, geographic prioritization, and adaptive management. This challenge is exemplified by ecosystems dominated by sagebrush ( Artemisia spp.), which occur across the western United States and have been degraded by increasing wildfire frequency driven by invasive plant spread, among other factors. However, both costs and effectiveness of sagebrush restoration can vary spatially due to management practices in addition to biotic and abiotic factors, and characterizing this variation could inform broad-scale planning. We leveraged published models of sagebrush recovery and treatment costs to predict and evaluate cost-effectiveness of aerial and drill seeding Artemisia spp. across 429 718 km 2 that overlapped 12 US states. Compared to natural recovery, effectiveness for both methods was generally low, yet effectiveness was often greater, and costs were always greater, for drill than aerial seeding, resulting in slightly higher cost-effectiveness on average for drill seeding. Cost-effectiveness for both treatments increased near major roads and in areas with more repeated burns. Cost-effectiveness also increased with predisturbance cover of sagebrush but decreased with herbaceous cover. However, we also identified areas where aerial seeding was more cost-effective than drill seeding, particularly with greater slope. Our results provide spatially explicit estimates and potential mechanisms of cost-effectiveness for two common seeding methods for sagebrush, which can help prioritize limited resources, guide land use, and improve restoration efficiency and effectiveness across public rangelands of the western United States.

western United States

Metaproteomics and metagenomics reveal microbial pathways of organic matter degradation and methanogenesis in a marginally producing natural gas well

The expansion of natural gas production and utilization worldwide has led to the decline of many once-productive wells, eventually resulting in costly well-plugging and unused infrastructure. However, in areas like the Michigan basin, MI, where the majority of natural gas is biogenically produced, microbial communities could potentially be stimulated to generate additional methane, increasing gas supply and reducing the need to drill new wells. In this study, we performed metaproteomic, metagenomic, and geochemical analyses of Antrim Shale formation water from a marginally producing natural gas well to evaluate resident microbial community functions in the context of potential bioenergy production. Functional proteins involved in methanogenesis, degradation/catabolism (including organic matter degradation), biosynthesis, energy utilization, transmembrane transport, and stress response were among the most commonly identified groups. Three metagenome-assembled genomes (MAGs) were characterized, including Methanomicrobiaceae, Methanothrix , and Smithella . For each, the identified proteins involved in methanogenesis and the degradation of diverse organic compounds, strongly suggest their role in utilizing shale-derived organic matter. These findings provide an increased understanding of the microorganisms and their metabolisms generating natural gas in the Antrim Shale and establish a foundation for future stimulation efforts aimed at enhancing biogenic methane production in marginal gas wells.

Michigan

Simulated mean monthly groundwater-transported nitrogen loads in watersheds on the north shore of Long Island Sound, 1993–2022

Elevated nitrogen loads are pervasive in the Long Island Sound, an estuary that receives freshwater and nutrients from both surface-water and groundwater discharge. Surface-water nitrogen loads to the Long Island Sound are relatively well characterized, but less is known about groundwater-transported nitrogen loads. Prior work on the northern shore of Long Island Sound (Connecticut and areas of New York and Rhode Island) suggested that groundwater travel times are relatively short (median less than 2 years) and that decade-long nutrient legacies are not widespread. Because the travel times are short, groundwater flow and nutrient loads likely vary substantially between months. In the current study, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency’s Long Island Sound Study and the Connecticut Department of Energy and Environmental Protection, developed a set of models to better characterize spatial and temporal patterns of groundwater-transported nitrogen loading from atmospheric deposition, septic systems, and fertilizers within the study area. The models provide an estimate, with uncertainty, of groundwater-transported nitrogen loads in the study area, filling a key gap in the nitrogen budget for Long Island Sound. The models also highlight the spatial and temporal variation in nitrogen loading throughout the study area. The modeling workflow involved four models. (1) A soil-water-balance model was developed by using the Soil-Water-Balance software to simulate groundwater recharge across the study area for water years 2005 through 2022. The simulated mean monthly recharge from the soil-water-balance model was used as input into a groundwater-flow model. (2) The groundwater-flow model was developed by using the MODFLOW 6 software and data for water years 1993 through 2022 and simulates average monthly hydrologic conditions. The groundwater-flow model was calibrated by using the Iterative Ensemble Smoother method within the PEST++ software. The Iterative Ensemble Smoother method generates an ensemble of sets of parameter values, with each set producing reasonable simulated hydrologic parameter values. (3) An ensemble of MODPATH particle-tracking simulations were run to generate particle flow paths and travel times, with each simulation using a different set of the flow model parameters. (4) A nitrogen load model uses the MODPATH simulation outputs to track nitrogen from the land surface through multiple attenuation zones until it discharges into fresh or saline surface water. As with the groundwater-flow model, the nitrogen model simulated average monthly groundwater-transported nitrogen loads for water years 1993 through 2022. One novel aspect of the nitrogen load model is that the nitrogen attenuation parameters were calibrated to observed nitrogen loads. Across the ensemble of simulated nitrogen loads, the median study-area-wide monthly simulated nitrogen loads from the aquifer to Long Island Sound throughout the year ranged from 900 to 18,600 kilograms of nitrogen per day, with a median load of 5,100 kilograms of nitrogen per day. The simulated loads were based on average monthly conditions for water years 1993 through 2022. Loads were highest during the winter and early spring and lowest during the late summer. However, simulated travel times for groundwater and nitrogen loads discharged to Long Island Sound during summer were longer than travel times for groundwater and loads discharged during the winter, indicating that, on average, groundwater discharged during summer traveled along different, and longer, flow paths, than groundwater discharged during winter. This indicates that summer loads would respond more slowly to changes in nitrogen inputs at the water table than winter loads. Over the entire study area, approximately 15 percent of the simulated load is from atmospheric deposition sources, 30 to 40 percent is from fertilizer, and 50 to 60 percent is from septic systems. The final analysis of the study involved simulating the change in groundwater-transported nitrogen load in response to upgrading septic systems or reducing fertilizing inputs to areas of turf grass. Both management interventions reduced the groundwater-transported nitrogen load, and reductions were greater in areas with greater loads from septic systems or turf-grass fertilizers. The delay between management actions and substantial reductions in groundwater-transported nitrogen loads varied seasonally; loads during the late summer months remained elevated longer than the winter loads.

Connecticut, Rhode Island

The impact of 3D structure on coseismic coastal land-level change and tsunami generation in the Cascadia Subduction Zone

Estimates of coseismic vertical displacements from past and potential future subduction zone earthquakes provide critical constraints on regional seismic and tsunami hazard. Many studies use elastic homogeneous half-space models to calculate vertical displacements from a specified earthquake slip distribution, neglecting complexities of 3D structure in subduction zone settings. Here, we use 3D ground motion simulations of potential Cascadia Subduction Zone earthquakes to investigate the impact of realistic 3D Earth structure on estimated vertical displacements. We show that offshore uplift increases when including 3D structure due to high fault slip in low-rigidity accretionary wedge sediments and coastal subsidence decreases due to higher rigidity material at depth. These larger offshore uplifts cause increased tsunami maximum wave heights, and coastal subsidence at paleoseismic sites decreases on average by ∼17 cm, or ∼60%, which can have important implications for the amplitude and extent of slip in earthquake scenarios developed based on paleoseismic data constraints.

California, Oregon, Washington

Fully contained laboratory earthquakes: The effect of asperity aspect ratio and free surfaces

Corner frequency ( f c ) and seismic moment ( M 0 ) are key parameters derived from seismic signals that are used to characterize earthquake stress drop, rupture area, and slip. These parameters are also affected by fault geometry and boundary conditions. However, the systematic study of these effects in laboratory settings has been challenging. This study presents laboratory earthquake experiments that examine how rupture dynamics are influenced by (a) the aspect ratio of rectangular PMMA velocity-weakening (VW) asperities surrounded by the Teflon velocity-strengthening (VS) patches, and (b) whether the sides of a VW asperity are confined with VS patches or are free surfaces. We found that increasing confinement by reducing free surfaces or increasing the VW asperity aspect ratio stabilizes fault slip, so that higher normal stress is required to transition from aseismic to seismic slip. Increased confinement and high aspect ratios also reduced M 0 and increased f c , both of which were determined from the radiated seismic waves. M 0 and f c were primarily controlled by the shorter dimension of the VW asperity. Analysis of high-frequency acoustic emission signals revealed that ruptures on high-aspect-ratio VW asperities propagated more unidirectionally, whereas ruptures on square VW asperities were more complex. Further, the high-aspect-ratio asperities were more likely to be eroded by surrounding VS regions while low-aspect-ratio asperities were more likely to rupture into the VS surroundings. These results demonstrate that both the confinement from surrounding stable areas and the geometry of the seismogenic patch can affect rupture nucleation, propagation, and seismic source characteristics.

JGR Solid Earth

Effect of deicing chemicals on the hydrologic environment in Massachusetts; evaluation of surface-water data collection

The objective of this study is to develop predictive relationships that can be used to describe the impact of highway deicing salts on the hydrologic environment. A method, presented in an earlier report, for estimating yearly mean chloride concentrations from estimated or actual runoff and salt-application data was applied to the period 1971 through1974 and the results compared with yearly mean chloride concentrations computed from records of specific conductance. Estimates were found to be from minus 63 percent to plus 56 percent in error when the error was expressed as the difference between estimated and computed values as a percentage of the computed values. Chloride concentrations used in this study are computed from specific conductance/chloride concentration relationships and records of specific conductance. Preliminary results from graphic analyses and least-squares regression analysis show that relationships between measured values of specific conductance and chloride concentration have correlation coefficients ranging from 0.30 to 0.97. Analysis of streamflow for all major dissolved constituents is recommended with the purpose of attempting to describe the variations in the specific conductance/chloride concentration relationships.

Massachusetts

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–23, California Groundwater Ambient Monitoring and Assessment Program, Priority Basin Project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–23. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban-and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert -butyl ether showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in total dissolved solids by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and methyl tert -butyl ether are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

California