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Hydrologic models of modern and fossil geothermal systems in the Great Basin: Genetic implications for epithermal Au-Ag and Carlin-type gold deposits

The Great Basin region in the western United States contains active geothermal systems, large epithermal Au-Ag deposits, and world-class Carlin-type gold deposits. Temperature profiles, fluid inclusion studies, and isotopic evidence suggest that modern and fossil hydrothermal systems associated with gold mineralization share many common features, including the absence of a clear magmatic fluid source, discharge areas restricted to fault zones, and remarkably high temperatures (>200 ??C) at shallow depths (200-1500 m). While the plumbing of these systems varies, geochemical and isotopic data collected at the Dixie Valley and Beowawe geothermal systems suggest that fluid circulation along fault zones was relatively deep (>5 km) and comprised of relatively unexchanged Pleistocene meteoric water with small (<2.5%) shifts from the meteoric water line (MWL). Many fossil ore-forming systems were also dominated by meteoric water, but usually exhibit ??18O fluid-rock interactions with larger shifts of 5???-20??? from the MWL. Here we present a suite of two-dimensional regional (100 km) and local (40-50 km) scale hydrologic models that we have used to study the plumbing of modern and Tertiary hydrothermal systems of the Great Basin. Geologically and geophysically consistent cross sections were used to generate somewhat idealized hydrogeologic models for these systems that include the most important faults, aquifers, and confining units in their approximate configurations. Multiple constraints were used, including enthalpy, ??18O, silica compositions of fluids and/or rocks, groundwater residence times, fluid inclusion homogenization temperatures, and apatite fission track anomalies. Our results suggest that these hydrothermal systems were driven by natural thermal convection along anisotropic, subvertical faults connected in many cases at depth by permeable aquifers within favorable lithostratigraphic horizons. Those with minimal fluid ?? 18O shifts are restricted to high-permeability fault zones and relatively small-scale (???5 km), single-pass flow systems (e.g., Beowawe). Those with intermediate to large isotopic shifts (e.g., epithermal and Carlin-type Au) had larger-scale (???15 km) loop convection cells with a greater component of flow through marine sedimentary rocks at lower water/rock ratios and greater endowments of gold. Enthalpy calculations constrain the duration of Carlin-type gold systems to probably <200 k.y. Shallow heat flow gradients and fluid silica concentrations suggest that the duration of the modern Beowawe system is <5 k.y. However, fluid flow at Beowawe during the Quaternary must have been episodic with a net duration of ???200 k.y. to account for the amount of silica in the sinter deposits. In the Carlin trend, fluid circulation extended down into Paleozoic siliciclastic rocks, which afforded more mixing with isotopically enriched higher enthalpy fluids. Computed fission track ages along the Carlin trend included the convective effects, and ranged between 91.6 and 35.3 Ma. Older fission track ages occurred in zones of groundwater recharge, and the younger ages occurred in discharge areas. This is largely consistent with fission track ages reported in recent studies. We found that either an amagmatic system with more permeable faults (10-11 m2) or a magmatic system with less permeable faults (10-13 m2) could account for the published isotopic and thermal data along the Carlin trend systems. Localized high heat flow beneath the Muleshoe fault was needed to match fl uid inclusion temperatures at Mule Canyon. However, both magmatic and amagmatic scenarios require the existence of deep, permeable faults to bring hot fluids to the near surface. ?? 2008 Geological Society of America.

Geosphere↗

Watershed Effects on Streamflow Quantity and Quality in Six Watersheds of Gwinnett County, Georgia

Watershed management is critical for the protection and enhancement of streams that provide multiple benefits for Gwinnett County, Georgia, and downstream communities. Successful watershed management requires an understanding of how stream quality is affected by watershed characteristics. The influence of watershed characteristics on stream quality is complex, particularly for the nonpoint sources of pollutants that affect urban watersheds. The U.S. Geological Survey (USGS), in cooperation with Gwinnett County Department of Water Resources (formerly known as Public Utilities), established a water-quality monitoring program during late 1996 to collect comprehensive, consistent, high-quality data for use by watershed managers. Between 1996 and 2003, more than 10,000 analyses were made for more than 430 water-quality samples. Continuous-flow and water-quality data have been collected since 1998. Loads have been computed for selected constituents from 1998 to 2003. Changing stream hydrology is a primary driver for many other water-quality and aquatic habitat effects. Primary factors affecting stream hydrology (after watershed size and climate) within Gwinnett County are watershed slope and land uses. For the six study watersheds in Gwinnett County, watershedwide imperviousness up to 12 percent does not have a well-defined influence on stream hydrology, whereas two watersheds with 21- and 35-percent impervious area are clearly impacted. In the stream corridor, however, imperviousness from 1.6 to 4.4 percent appears to affect baseflow and stormflow for all six watersheds. Relations of concentrations to discharge are used to develop regression models to compute constituent loads using the USGS LOAD ESTimator model. A unique method developed in this study is used to calibrate the model using separate baseflow and stormflow sample datasets. The method reduced model error and provided estimates of the load associated with the baseflow and stormflow parts of the hydrograph. Annual load of total suspended sediment is a performance criterion in Gwinnett County's Watershed Protection Plan. Median concentrations of total suspended solids in stormflow range from 30 to 180 times greater than in baseflow. This increase in total suspended solids concentration with increasing discharge has a multiplied effect on total suspended solids load, 97 to 99 percent of which is transported during stormflow. Annual total suspended solids load is highly dependent on annual precipitation; between 1998 and 2003 load for the wettest year was up to 28 times greater than for the driest year. Average annual total suspended solids yield from 1998-2003 in the six watersheds increased with high-density and transportation/utility land uses, and generally decreased with low-density residential, estate/park, and undeveloped land uses. Watershed characteristics also were related to annual loads of total phosphorus, dissolved phosphorus, total nitrogen, total dissolved solids, biochemical oxygen demand, and total zinc, as well as stream alkalinity. Flow-adjusted total suspended solids, total phosphorus, and total zinc stormflow concentrations between 1996 and 2003 have a seasonal pattern in five of the six watersheds. Flow-adjusted concentrations typically peak during late summer, between July and August. The seasonal pattern is stronger for more developed watersheds and may be related to seasonal land-disturbance activities and/or to seasonal rainfall intensity, both of which increase in summer. Adjusting for seasonality in the computation of constituent load caused the standard error of annual total suspended solids load to improve by an average of 11 percent, and increased computed summer total suspended solids loads by an average of 45 percent and decreased winter total suspended solids loads by an average of 40 percent. Total annual loads changed by less than 5 percent on the average. Graphical and statistical analyses do not indicate a time tre

Georgia↗

Reply to “Comment on ‘An efficient numerical solution of the transient storage equations for solute transport in small streams" by R. L. Runkel and S. C. Chapra

We thank Dawes and Short [this issue] for presenting an alternate technique for the efficient solution of the transient storage solute transport equations. After reading their comment, it is clear that several points in our original manuscript are in need of clarification. In this reply we provide additional information on our solution technique and comment briefly on the alternate scheme of Dawes and Short.

Water Resources Research↗

Evaluating acid-aluminum stress in streams of the Northeastern U.S. at watershed, fish community and physiological scales

In spite of overall improvements in air and water quality, biological stress from low pH and high concentrations of inorganic aluminum continue to impact fish and fish habitat in northeastern North America, with independent and interactive effects on individuals, populations and communities. Integrative indicators can therefore be useful in monitoring both impact and recovery across multiple scales. Using coupled water chemistry (pH, conductivity, and base cation and inorganic aluminum concentration), geographic (site elevation and watershed area) and biological (fish diversity, fish abundance, gill aluminum concentration and gill physiology) data, we developed an integrated indicator of acid aluminum stress across the White and Green mountains in central New England, USA. As has been established in a number of previous studies, preliminary analysis clearly indicated that across all sites, inorganic aluminum concentration was consistently greatest during the spring season. Structural Equation modelling (SEM) revealed that toxic conditions (concurrent low pH and high concentrations of inorganic aluminum) were well summarized with an integrated toxicity score, related to both base cation concentrations and elevation, with sites at higher elevations more likely to experience toxic conditions as well as low base cation concentrations. As hypothesized, fish diversity and abundance were negatively related to toxicity score. In spite of considerable variation among individuals, gill aluminum was positively related to toxicity score for both Atlantic salmon and brook trout. Observed elevated gill aluminum levels associated with reduced gill metabolic activity in Atlantic salmon smolts from impacted systems likely result in impaired osmoregulatory function and seawater tolerance. Overall, our results suggest that the integrated toxicity score metric is strongly associated with a syndrome of physiological stress, reduced abundance, and low species diversity for stream fishes in New England and can likely serve as a reliable indicator of continued impairment or recovery of acid-aluminum vulnerable systems in this ecoregion.

New Hampshire, Vermont↗

An overview of mining-related environmental and human health issues, Marinduque Island, Philippines: observations from a joint U.S. Geological Survey - Armed Forces Institute of Pathology reconnaissance field evaluation, May 12-19, 2000

This report summarizes results of a visit by the report authors to Marinduque Island, Philippines, in May 2000. The purpose of the visit was to conduct a preliminary examination of environmental problems created by a 1996 tailings spill from the Marcopper open-pit copper mine. The mine was operated from 1969-1996 by Macropper Mining Corperation, under 39.9% ownership, and design and management control of Placer Dome, Inc. Our trip expenses to and from the Philippines were funded by the USGS. In-country expenses were paid by the offices of Congressman Reyes and the Governor of Marinduque, Carmencita O. Reyes. This report includes observations we made based on our relatively short visit to the island, and observations based upon a preliminary review of the literature available on the islanda??s mining-environmental issues. In addition, we have included preliminary interpretations and analytical results of some water, sediment, and mine waste samples collected during our trip. We also highlight the environmental and human health issues we fell are in need of further study and consideration for mitigation or remediation. This report is preliminary and is not intended to be a comprehensive or final review of the islanda??s mining-environmental issues; many areas of further study are clearly neededa?|

Open-File Report↗

Laboratory evaluation of the Sea-Bird Scientific HydroCycle-PO4 phosphate sensor

Sea-Bird Scientific’s HydroCycle-PO 4 phosphate sensor is a single-analyte wet-chemistry sensor designed for in situ environmental monitoring. The unit was evaluated at the U.S. Geological Survey Hydrologic Instrumentation Facility to assess the accuracy of the sensor in solutions with known phosphorous concentration and to test the effects of chromophoric (colored) dissolved organic matter (CDOM) and natural water matrixes on sensor accuracy. Accuracy was tested with three standards: 0.110, 0.174, and 0.260 milligram per liter, as phosphorous (mg/L as P). The 0.110- and 0.260-mg/L standards were made from a dilution of a National Institute of Standards and Technology-traceable phosphate-phosphorous standard with Type I deionized water (DIW). Average measured phosphate concentrations of the tested standards (0.110, 0.174, and 0.260 mg/L as P) in DIW were 0.132, 0.181, and 0.310 mg/L as P, for differences of 20, 4, and 19 percent, respectively. Measured phosphate concentration of a tested standard was biased by the addition of tea water filtered through a 0.45-micrometer pore size filter (filtered tea water [FTW]) simulating the effect of CDOM. An aliquot of the filtered tea solution was sent to a certified environmental laboratory, which reported a less than reporting level (<0.004 mg/L as P) phosphate concentration. True color of the FTW was measured at 380 platinum-cobalt units by using Standard Methods 8025. For this FTW test, the measured phosphate concentration for the clear 0.260 mg/L as P standard averaged 0.366 mg/L as P. This concentration increased to an average of 0.653 mg/L as P with the addition of 10 percent FTW, and to an average of 0.859 mg/L as P with the addition of 20 percent FTW. These test results indicate a positive bias of up to 40 percent of the concentrations of the measured phosphate concentrations when CDOM is present and indicate a proportional increase in an apparent concentration of phosphorus instrument response as CDOM concentration increases.

Open-File Report↗

HiRISE observations of Recurring Slope Lineae (RSL) during southern summer on Mars

Recurring Slope Lineae (RSL) are active features on Mars that might require flowing water. Most examples observed through 2011 formed on steep, equator-facing slopes in the southern mid-latitudes. They form and grow during warm seasons and fade and often completely disappear during colder seasons, but recur over multiple Mars years. They are recognizable by their incremental growth, relatively low albedo and downhill orientation. We examined all images acquired by HiRISE during L s 250–10° (slightly longer than southern summer, L s 270–360°) of Mars years 30–31 (03/2011–10/2011), and supplemented our results with data from previous studies to better understand the geologic context and characteristics of RSL. We also confirmed candidate and likely sites from previous studies and discovered new RSL sites. We report 13 confirmed RSL sites, including the 7 in McEwen et al. (McEwen et al. [2011]. Science 333(6043), 740–743]. The observed seasonality, latitudinal and slope orientation preferences, and THEMIS bright- ness temperatures indicate that RSL require warm temperatures to form. We conclude that RSL are a unique phenomenon on Mars, clearly distinct from other slope processes that occur at high latitudes associated with seasonal CO 2 frost, and episodic mass wasting on equatorial slopes. However, only 41% (82 out of 200) of the sites that present apparently suitable conditions for RSL formation (steep, equator-facing rocky slopes with bedrock exposure) in the southern mid-latitudes (28–60°S) contain any candidate RSL, with confirmed RSL present only in 7% (13 sites) of those locations. Significant variability in abundance, size and exact location of RSL is also observed at most sites, indicating additional controls such as availability of water or salts that might be playing a crucial role.

Icarus↗

A note on the relationships between organic matter and some geotechnical properties of a marine sediment

An analysis of the relationship between organic matter and liquid and plastic limits, and grain‐specific gravity of a marine sediment was accomplished by making a stepwise adjustment in the organic content of that sediment. The sample used was from Santa Barbara Basin (off southern California) and is typical of fine‐grained marine sediments: it is a clayey silt with a common suite of minerals and other constituents. During the experiment, texture and composition (except organic content) were constant; only the quantity of natural, indigenous organic matter was changed. A strong linear relationship exists between the independent variable, the amount of organic carbon present in the sample, and the dependent variables. Liquid limit, plastic limit, and plasticity index all increased with increasing organic content over the range studied (0.57&ndash;3.20% organic carbon). Grain‐specific gravity decreased. All had linear correlation coefficients ( r ) greater than |0.90| and r 2 values greater than 90%, except the plasticity index (83%). Comparing the results of regression analyses from this and several similar studies shows that although there is good qualitative agreement, there are quantitative inconsistencies. In particular there is considerable overall variability in the regression coefficients. Among studies on marine sediments the inconsistencies are less pronounced, yet still evident. The increase in liquid limit as organic carbon increased by 1 % sediment dry weight ranged from 9 to 28% water content; in the plastic limit the range was from 4 to 18%. However, in these marine studies regression coefficients are relatively close in value in some cases, levels of significance of the regressions are high in most cases, and in all cases the relationships appear to be linear over the range of organic carbon percentage studied. Finally, we believe that a relatively clear relationship between plasticity and organic carbon begins to emerge when the latter exceeds a value of 2%.

Marine Geotechnology↗

Scaling roads and wildlife: The Cinderella principle

It is clear that a reduction in both direct and indirect effects of roads and road networks must be the goal of management agencies. However, increased permeability of roaded landscapes can only be achieved by up-front planning and subsequent mitigative actions. The key is to understand that roads must be made permeable to the movement of animals. More profoundly, ecosystem services, i.e., clean water, clean air, uncontaminated soil, natural landscapes, recreation opportunities, abundant wildlife, and life sustaining ecological processes must not be seriously impacted. In other words, quality of life as measured by ecosystem services should be a major component of the planning process when roads are constructed or improved. Mitigative structures exist to increase permeability of roads. Wildlife overpasses and underpasses, often referred to as ecoducts or green bridges, with associated structures to enable larger animals to exit the road right of way, e.g., earthen escape ramps (BISSONETTE and HAMMER, 2001), various culvert designs for smaller animals including badger pipes and amphibian and reptile tunnels, and fish ladders are but a small sampling of the structures already in place around the world. What is needed is attention to the big picture. Landscapes need to be reconnected and made more permeable. Responsible agencies and organizations need to be aggressive about promoting mitigations and a conservation ethic into road planning. Only with a broad based effort between a concerned public, a database to work from, and a willingness of responsible agencies, will the now very large virtual footprint of roads and road networks be reduced to more closely approximate the physical footprint. By embracing the Cinderella Principle of making the virtual shoe fit more closely the actual physical footprint of roads, we will be able to achieve a closer connection with ecological harmony with its resultant effect of abundant wildlife.

Conference Paper↗

Transient effects on groundwater chemical compositions from pumping of supply wells at the Nevada National Security Site, 1951-2008

Nuclear testing and support activities at the Nevada National Security Site have required large amounts of water for construction, public consumption, drilling, fire protection, hydraulic and nuclear testing, and dust control. To supply this demand, approximately 20,000 million gallons of water have been pumped from 23 wells completed in 19 boreholes located across the Nevada National Security Site starting as early as the 1950s. As a consequence of more or less continuous pumping from many of these wells for periods as long as 58 years, transient groundwater flow conditions have been created in the aquifers that supplied the water. To evaluate whether long-term pumping caused changes in water compositions over time, available chemical analyses of water samples from these 19 boreholes were compiled, screened, and evaluated for variability including statistically significant temporal trends that can be compared to records of groundwater pumping. Data used in this report have been extracted from a large database (Geochem08, revision 3.0, released in September 2008) containing geochemical and isotopic information created and maintained by primary contractors to the U.S. Department of Energy, National Nuclear Security Administration, Nevada Site Office. Data extracted from this source were compiled for the entire period of record, converted to uniform reporting units, and screened to eliminate analyses of poor or unknown quality, as well as clearly spurious values. The resulting data are included in accompanying spreadsheets that give values for (1) pH and specific conductance, (2) major ion concentrations, (3) trace element concentrations and environmental isotope ratios, and (4) mean, median, and variance estimates for major ion concentrations. The resulting data vary widely in quality and time-series density. An effort has been made to establish reasonable ranges of analytical uncertainty expected for each analyte and eliminate analyses that are obvious outliers. Analysis of chemical trends in this report primarily rely on specific conductance measurements and major ion concentrations, data considered to be the most accurate and reliable over the entire time span of investigation. The analysis uses parametric and non-parametric evaluations to provide a statistical basis for trend identification. Trace element and isotope data are examined for consistency, but typically are too inaccurate or infrequent to provide a reliable long term basis for trend evaluation. Groundwater withdrawal records compiled in a companion report are included graphically in this report to allow qualitative comparisons between water quality and pumping history. Data for each supply well include (1) a borehole description and summary of pumping history, (2) a description of water-quality parameters, (3) an evaluation of temporal variations of specific conductance and major ion concentrations, and (4) an examination of supporting information from trace element and isotope data. A range of responses are observed for individual supply wells that likely include the effects of both aquifer dynamics and changing borehole conditions. Data from most wells show little or no evidence for temporal variation in water-quality parameters indicating that aquifers at the Nevada National Security Site are capable of producing large volumes of compositionally uniform water over many years of pumping. A smaller number of wells show evidence of transient changes. Wells that have ceased pumping commonly show compositions that shift toward lower concentrations in subsequent bailed samples, which indicates that more dilute water entered the well over time due to either leakage of meteoric water into the well casing or more wide-spread recharge into the shallow phreatic zone. Wells that show systematic changes in water compositions during episodes of pumping commonly have multiple open intervals whose contributions to water in the well may change over time due to hydraulic conditions or well dynamics.

Nevada↗

Multi-scale temporal and spatial variation in genotypic composition of Cladophora-borne Escherichia coli populations in Lake Michigan

High concentrations of Escherichia coli in mats of Cladophora in the Great Lakes have raised concern over the continued use of this bacterium as an indicator of microbial water quality. Determining the impacts of these environmentally abundant E. coli, however, necessitates a better understanding of their ecology. In this study, the population structure of 4285 Cladophora-borne E. coli isolates, obtained over multiple three day periods from Lake Michigan Cladophora mats in 2007-2009, was examined by using DNA fingerprint analyses. In contrast to previous studies that have been done using isolates from attached Cladophora obtained over large time scales and distances, the extensive sampling done here on free-floating mats over successive days at multiple sites provided a large dataset that allowed for a detailed examination of changes in population structure over a wide range of spatial and temporal scales. While Cladophora-borne E. coli populations were highly diverse and consisted of many unique isolates, multiple clonal groups were also present and accounted for approximately 33% of all isolates examined. Patterns in population structure were also evident. At the broadest scales, E. coli populations showed some temporal clustering when examined by year, but did not show good spatial distinction among sites. E. coli population structure also showed significant patterns at much finer temporal scales. Populations were distinct on an individual mat basis at a given site, and on individual days within a single mat. Results of these studies indicate that Cladophora-borne E. coli populations consist of a mixture of stable, and possibly naturalized, strains that persist during the life of the mat, and more unique, transient strains that can change over rapid time scales. It is clear that further study of microbial processes at fine spatial and temporal scales is needed, and that caution must be taken when interpolating short term microbial dynamics from results obtained from weekly or monthly samples.

Water Research↗

Distribution of an invasive aquatic pathogen (viral hemorrhagic septicemia virus) in the Great Lakes and its relationship to shipping

Viral hemorrhagic septicemia virus (VHSV) is a rhabdovirus found in fish from oceans of the northern hemisphere and freshwaters of Europe. It has caused extensive losses of cultured and wild fish and has become established in the North American Great Lakes. Large die-offs of wild fish in the Great Lakes due to VHSV have alarmed the public and provoked government attention on the introduction and spread of aquatic animal pathogens in freshwaters. We investigated the relations between VHSV dispersion and shipping and boating activity in the Great Lakes by sampling fish and water at sites that were commercial shipping harbors, recreational boating centers, and open shorelines. Fish and water samples were individually analyzed for VHSV using quantitative reverse transcription-polymerase chain reaction (qRT-PCR) and cell culture assays. Of 1,221 fish of 17 species, 55 were VHSV positive with highly varied qRT-PCR titers (1 to 5,950,000 N gene copies). The detections of VHSV in fish and water samples were closely associated and the virus was detected in 21 of 30 sites sampled. The occurrence of VHSV was not related to type of site or shipping related invasion hotspots. Our results indicate that VHSV is widely dispersed in the Great Lakes and is both an enzootic and epizootic pathogen. We demonstrate that pathogen distribution information could be developed quickly and is clearly needed for aquatic ecosystem conservation, management of affected populations, and informed regulation of the worldwide trade of aquatic organisms.

PLoS ONE↗

Resistivity profiling for mapping gravel layers that may control contaminant migration at the Amargosa Desert Research Site, Nevada

Gaseous contaminants, including CFC 113, chloroform, and tritiated compounds, move preferentially in unsaturated subsurface gravel layers away from disposal trenches at a closed low-level radioactive waste-disposal facility in the Amargosa Desert about 17 kilometers south of Beatty, Nevada. Two distinct gravel layers are involved in contaminant transport: a thin, shallow layer between about 0.5 and 2.2 meters below the surface and a layer of variable thickness between about 15 and 30 meters below land surface. From 2003 to 2005, the U.S. Geological Survey used multielectrode DC and AC resistivity surveys to map these gravel layers. Previous core sampling indicates the fine-grained sediments generally have higher water content than the gravel layers or the sediments near the surface. The relatively higher electrical resistivity of the dry gravel layers, compared to that of the surrounding finer sediments, makes the gravel readily mappable using electrical resistivity profiling. The upper gravel layer is not easily distinguished from the very dry, fine-grained deposits at the surface. Two-dimensional resistivity models, however, clearly identify the resistive lower gravel layer, which is continuous near the facility except to the southeast. Multielectrode resistivity surveys provide a practical noninvasive method to image hydrogeologic features in the arid environment of the Amargosa Desert.

Nevada↗

Metals transport in the Sacramento River, California, 1996-1997; Volume 2: Interpretation of metal loads

Metals transport in the Sacramento River, northern California, from July 1996 to June 1997 was evaluated in terms of metal loads from samples of water and suspended colloids that were collected on up to six occasions at 13 sites in the Sacramento River Basin. Four of the sampling periods (July, September, and November 1996; and May-June 1997) took place during relatively low-flow conditions and two sampling periods (December 1996 and January 1997) took place during high-flow and flooding conditions, respectively. This study focused primarily on loads of cadmium, copper, lead, and zinc, with secondary emphasis on loads of aluminum, iron, and mercury. Trace metals in acid mine drainage from abandoned and inactive base-metal mines, in the East and West Shasta mining districts, enter the Sacramento River system in predominantly dissolved form into both Shasta Lake and Keswick Reservoir. The proportion of trace metals that was dissolved (as opposed to colloidal) in samples collected at Shasta and Keswick dams decreased in the order zinc ≈ cadmium > copper > lead. At four sampling sites on the Sacramento River--71, 256, 360, and 412 kilometers downstream of Keswick Dam--trace-metal loads were predominantly colloidal during both high- and low-flow conditions. The proportion of total cadmium, copper, lead, and zinc loads transported to San Francisco Bay and the Sacramento-San Joaquin Delta estuary (referred to as the Bay-Delta) that is associated with mineralized areas was estimated by dividing loads at Keswick Dam by loads 412 kilometers downstream at Freeport and the Yolo Bypass. During moderately high flows in December 1996, mineralization-related total (dissolved + colloidal) trace-metal loads to the Bay-Delta (as a percentage of total loads measured downstream) were cadmium, 87 percent; copper, 35 percent; lead, 10 percent; and zinc, 51 percent. During flood conditions in January 1997 loads were cadmium, 22 percent; copper, 11 percent; lead, 2 percent; and zinc, 15 percent. During irrigation drainage season from rice fields (May-June 1997) loads were cadmium, 53 percent; copper, 42 percent; lead, 20 percent; and zinc, 75 percent. These estimates must be qualified by the following factors: (1) metal loads at Colusa in December 1996 and at Verona in May-June 1997 generally exceeded those determined at Freeport during those sampling periods. Therefore, the above percentages represent maximum estimates of the apparent total proportion of metals from mineralized areas upstream of Keswick Dam; and (2) for logistics reasons, the Sacramento River was sampled at Tower Bridge instead of at Freeport during January 1997. Available data suggest that trace metal loads from agricultural drainage may be significant during certain flow conditions in areas where metals such as copper and zinc are added as agricultural amendments. Copper loads for sampling periods in July and September 1996 and in May-June 1997 show increases of dissolved and colloidal copper and in colloidal zinc between Colusa and Verona, the reach of the Sacramento River along which the Colusa Basin Drain, the Sacramento Slough, and other agricultural return flows are tributaries. Monthly sampling of these two agricultural drains by the USGS National Water-Quality Assessment Program shows seasonal variations in metal concentrations, reaching maximum concentrations of 4 to 6 micrograms per liter in "dissolved" (0.45-micrometer filtrate) copper concentrations in May 1996, December 1996, and June 1997. The total (dissolved plus colloidal) load of copper from the Colusa Basin Drain in June 1997 was 18 kilograms per day, whereas the copper load in Spring Creek, which drains the inactive mines on Iron Mountain, was 20 kilograms per day during the same sampling period. For comparison, during the January 1997 flood, the copper load in Spring Creek was about 1,100 kilograms per day and the copper load in the Yolo Bypass was about 7,300 kilograms per day. The data clearly indicate that most copper and zinc loads during the January 1997 flood entered the Sacramento River upstream of Colusa, and upstream of the influence of the most intense agricultural drainage return flows in the Sacramento River watershed. This study has demonstrated that some trace metals of environmental significance (cadmium, copper, and zinc) in the Sacramento River are transported largely in dissolved form at upstream sites (below Shasta Dam, below Keswick Dam, and at Bend Bridge) proximal to the mineralized areas of the West Shasta and East Shasta mining districts. In contrast, these trace metals are transported largely in colloidal form at downstream sites (Colusa, Verona, Freeport, and Yolo Bypass). Aluminum, iron, and lead were observed to be transported predominantly in the colloidal phase at all mainstem Sacramento River sampling sites during all sampling periods in this study. Despite continuous water treatment, which has removed 85 to 90 percent of the cadmium, copper, and zinc from the mine drainage at Iron Mountain, Spring Creek remains a significant source of these metals to the Sacramento River system.

California↗

Ungaged inflow and loss patterns in urban and agricultural sub‐reaches of the Logan River Observatory

Streams in semi‐arid urban and agricultural environments are often heavily diverted for anthropogenic purposes. However, they simultaneously receive substantial inflows from a variety of ungaged sources including stormwater returns, tile drainage, and irrigation runoff that help sustain flow during dry periods. Due to the inability to identify sources or directly gage many of these inflows, there is a clear need for methods to understand source origination while quantifying potential gains and losses over highly impacted reaches. In the context of the Logan River Observatory, historical gage data illustrate the importance of ungaged and unidentified inflows on maintaining or enhancing flows in both urban and agricultural reaches containing large diversions. To understand the inflows in this portion of the Logan River, we first analysed water samples for ions collected from a subset of representative inflow sources and applied clustering analyses to establish inflow source classifications and associated ion concentration ranges. These representative concentration ranges, combined with mainstem flow and river ion samples taken at sub‐reach scales, allow for the application of flow and mass balances to quantify inflow rates from different sources as well as any losses. These calculations demonstrate significant gains and losses occurring in many sub‐reaches during three sampling events. The dominant land use (urban or agriculture) and flow regime at the time of sampling were the primary drivers of gains and losses. These exchanges were found to be most important below large diversions during low flow conditions. This highlights the need to classify inflow sources (urban or agriculture, surface or groundwater) and estimate their contributions to anticipate instream consequences of land use and water management decisions. As irrigation and water conveyance practices become more efficient, a portion of these ungaged inflows could be diminished or eliminated, thus further depleting streamflow during dry periods.

Utah↗

Variability in hydrologic response to wildfire between snow zones in forested headwaters

Rising temperatures and shifting fire regimes in the western United States are pushing fires upslope into areas of deep winter snowpack, where we have little knowledge of the likely hydrologic impacts of wildfire. We quantified differences in the timing and magnitude of stormflow responses to summer rainstorms among six catchments of varying levels of burn severity and seasonal snowpack cover for years 1–3 after the 2020 Cameron Peak fire. Our objectives were to (1) examine whether responsiveness, magnitude, and timing of stormflow responses to rainfall vary between burned and unburned catchments and between snow zones, and (2) identify the factors that affect these responses. We evaluated whether differences in storm hydrograph peak flow, total flow, stage rise, and lag to peak time differed by snow zone and burn category using generalised linear models. Additional predictors in these models are the maximum 60-min rainfall intensity for each storm, the cumulative potential water deficit prior to the storm, and the year post-fire. These models showed that the high snow zone (HSZ) has higher total stormflow than the low snow zone (LSZ), likely due to the higher soil moisture content in that area. In both snow zones, the biggest driver of the magnitude of the stormflow response was MI 60 . Burn category did not have a clear impact on stormflow response in the HSZ, but it did impact stage rise at the severely burned catchment in the LSZ. This was the only site that had widespread overland flow post-fire. These results demonstrate that the stormflow responses to fire vary between snow zones, indicating a need to account for elevation and snow persistence in post-fire risk assessments.

Colorado↗

Global variability of the composition and temperature at the 410-km discontinuity from receiver function analysis of dense arrays

Seismic boundaries caused by phase transitions between olivine polymorphs in Earth's mantle provide thermal and compositional markers that inform mantle dynamics. Seismic studies of the mantle transition zone often use either global averaging with sparse arrays or regional sampling from a single dense array. The intermediate approach of this study utilizes many densely spaced seismic arrays distributed around the globe. We systematically compute teleseismic P-to-S receiver functions for each seismic array and invert for the 1-D seismic velocity structure of the mantle transition zone beneath each array to facilitate a comparison between densely sampled regions. We stack 3,600 receiver functions on average at 67 arrays in total. The stack is used in a probabilistic inversion to estimate the mantle transition zone interface depths and velocities beneath each array. We focus on the 410-km discontinuity (410) because it is a prominent seismic interface that is clearly linked to a single mineral phase transition between olivine and wadsleyite. The depths and velocity contrasts of the 410 are mapped to temperatures and compositions using mineral physics constraints. The depth of the 410 ranges from ∼405–440 km, which is consistent with a ∼360 K temperature range in a dry mantle and a ∼260 K temperature range in a wet mantle (2 wt. % water). The Vs contrast across the 410 ranges from ∼2.5–8 %, which is consistent with ∼20–70 vol. % olivine composition in a dry mantle and ∼25–80 vol. % in a wet mantle. The bulk composition of the upper mantle near the 410-km discontinuity is typically considered to be well-mixed because there is no thermodynamic impediment to convection at the olivine to wadsleyite phase transition. However, the wide range of inferred olivine content from our study suggests that there are large lateral variations in the bulk composition of the upper mantle near the 410-km discontinuity.

Earth and Planetary Science Letters↗

Subsurface transport of orthophosphate in five agricultural watersheds, USA

Concentrations of dissolved orthophosphate (ortho P) in the unsaturated zone, groundwater, tile drains, and groundwater/stream water interfaces were assessed in five agricultural watersheds to determine the potential for subsurface transport. Concentrations of iron oxides were measured in the aquifer material and adsorption of ortho P on oxide surfaces was assessed by geochemical modeling. Attenuation of ortho P in these aquifers was attributed primarily to sorption onto iron oxides, and in one location onto clay minerals. Only one location showed a clear indication of phosphorus transport to a stream from groundwater discharge, although groundwater did contribute to the stream load elsewhere. Subsurface ortho P movement at a site in California resulted in a plume down gradient from orchards, which was attenuated by a 200 m thick riparian zone with natural vegetation. Iron oxides had an effect on phosphorus movement and concentrations at all locations, and groundwater chemistry, especially pH, exerted a major control on the amount of phosphorus adsorbed. Groundwater pH at a site in Maryland was below 5 and that resulted in complete sequestration of phosphorus and no movement toward the stream. Geochemical modeling indicated that as the surfaces approached saturation, groundwater concentrations of ortho P rise rapidly.

Journal of Hydrology↗