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At least 721 records · Page 40Linked to original sources

Hard rock uranium potential in Alaska

Discussing the potential of "hardrock" (i.e., non-sedimentary type) uranium deposits in a 586,000 mi 2 portion of the North America Cordillera is a difficult task compounded by the fact that the remoteness of much of the region and the logistical difficulties have resulted in only reconnaissance geologic information being available for large parts of the state. Cobb (1970) has listed known occurrences of uranium and thorium minerals in the state and a somewhat modified version of his compilation showing chiefly hardrock occurrences is given in figure 1; it should be emphasized that these are occurrences only and not necessarily deposits of possible economic significance. The distribution pattern shows a concentration of occurrences in southeastern Alaska and particularly in the interior. The only production of uranium in Alaska from any type of deposit has been from a hardrock deposit, that being the roughly 120,000 tons of ore averaging about one percent U 3 0 8 from the Ross-Adams mine near Bokan Mountain on Prince of Wales Island close to the southern tip of southeastern Alaska. The Bokan Mountain uranium-thorium area includes about 71 mi 2 and is largely underlain by plutonic rocks (MacKevett, 1963). The plutonic rocks range from pyroxenite to peralkaline granite and syenite, but they consist chiefly of diorite, quartz diorite, granodiorite, and quartz monzonite. The peralkaline granite, a small pluton about 3 mi2 in area, is Late Triassic or Early Jurassic in age while the other plutonic rocks are early Paleozoic.

Alaska↗

Geologic setting of the proposed West Flank Forge Site, California: Suitability for EGS research and development

The proposed West Flank FORGE site is within the China Lake Naval Air Weapons Station (NAWS), China Lake, CA. The West Flank is west of the Coso geothermal field, an area of China Lake NAWS dominated by the Quaternary Coso volcanic field largely comprised of rhyolite domes and their volcaniclastic and epiclastic horizons. The largest dome flow complex, Sugarloaf Mountain, marks the northwestern margin of the geothermal field. The West Flank is situated due west of Sugarloaf. The geologic setting of the West Flank was determined from one deep well (83-11) drilled as a potential production hole in 2009. The bottom-hole temperature (BHT) of well 83-11 approaches 600 oF (315˚C), but flow tests demonstrate very low, non-commercial permeabilities. With the exception of the upper 600 feet of volcaniclastic alluvium, well 83-11 is completed in granitic basement. The West Flank possesses the primary attributes of a FORGE site: non-commercial permeability ( <10 -16 m 2 ), a 175˚ to 225˚C temperature range in crystalline rocks, and a location outside an existing geothermal field The Coso Mountains host the Coso volcanic field and are within a right-releasing stepover between the dextral Airport Lake (ALF) and Little Lake fault zones (LLFZ) and the Wild Horse Mesa and Owens Valley faults. Two distinct fault populations have been identified at Coso: WNW-trending and antithetical, NE-trending strike-slip faults and N- to NNE-trending normal faults. These faults are both high permeability drilling targets at depth within the main (productive) geothermal field and they locally segment the field into distinct hydrothermal regimes. The West Flank may be segmented from the rest of the field by one such northerly trending fault. The overall minimum principal stress orientation in the main geothermal field varies from 103˚ to 108˚; however, the minimum horizontal principal stress in 83-11 is rotated to 081˚.

California↗

Geology and regional setting of the Al Masane ancient mine area, southeastern Arabian Shield, Kingdom of Saudi Arabia

Stratiform zinc-copper massive-sulfide deposits at Al Masane occur in thin dolomitic interbeds within Proterozoic felsic crystal tuff and mafic flows and volcaniclastics. These strata dip steeply westward and are underlain by shale and shaly graywacke to the east and overlain by lapilli crystal tuff to the west. This section is part of the Habawnah fold or mineral belt that extends from the Wadi Wassat area southward into Yemen. Western parts of the Habawnah fold belt, including the Al Masane area, are characterized by a bimodal assemblage of of phenocryst-poor basalts and sodic rhyolite crystal tuff, and by zinc-copper mineral deposits. Strata in the eastern part of the belt, mostly east of the Ashara fault zone, contain abundant phenocryst-rich mafic volcanic rocks, little felsic crystal tuff, and barren or locally nickeliferous massive pyrite deposits. Stratified rocks and gabbro sills of the Al Masane area were isoclinally folded and metamorphosed to the greenschist facies. Structural analysis indicates that foliation, lineation, joints, major and minor folds, and one of three sets of faults formed during a single east-west compressional deformational episode. Axial-plane foliation dips steeply westward and is usually coincident with bedding. Lineation plunges steeply to the northwest throughout the map area and is parallel to the intersection of joints of two major sets and to the intersection of these joints with foliation. Major folds have north-trending, gently plunging axes to which the axis of a minor fold set is essentially parallel. A second minor fold-set has a steeply plunging axis parallel to lineation. The Saadah massive-sulfide body is elongated by a fold of this system. Unmetamorphosed Proterozoic felsic sills, quartz monzonite and gabbro plutons, porphyritic diorite dikes, mafic dikes, and basalt dikes, in that apparent order, have intruded the stratified section. Basalt dikes are offset by southwestward-dipping reverse faults and by faults parallel to bedding. Malachite and metal-oxide-bearing gossans in the Al Masane area were mined in ancient times. Radiocarbon dating of charcoal in slag indicates that the ores were smelted about 1,200 years ago. Gossans are depleted in copper, silver, and zinc, relative to underlying sulfide, by factors of about 0.33, 0.2, and 0.08, respectively. Evaluation of numerous analyses of gossans, carbonates, and silicate rocks indicates that exploration for zinc-copper massive-sulfide deposits in the region should center on detailed geochemical studies of dolomitic beds. Dolomitization of host siliceous shales and tuffs and the formation of the massive-sulfide bodies at Al Masane probably caused by submarine fumarolic hydrothermal activity during periods of relative volcanic quiescence. Further work in the Al Masane region should include a study of the dolomitized areas and a search for other potential alteration "pipe" products (e.g. chlorite) as a guide to location of proximal deposits. Zinc-copper deposits at Al Masane and in the Dhahar-Al Hajrah and Kutam-Farah Garan areas have characteristics in common and are associated with felsic volcanic centers in the western bimodal part of the Habawnah mineral belt. They probably have parallel origins related to sea-floor volcanism. Deposits at Al Masane and Dhahar-Al Hajrah are possibly in the same general stratigraphic interval. Characteristics and distribution of altered rocks at Kutam suggest that the observed structural control of mineralization may represent remobilization. Chemical characteristics of volcanic rocks at Al Masane and elsewhere, along with features such as zinc-copper-iron sulfide mineralization, rhyolite-basalt bimodality, and the quartz phenocryst-rich nature of the felsic rocks, are compatible with an unusually primitive tholeiitic island-arc origin for the strata and mineral deposits of the Habawnah mineral belt.

Open-File Report↗

On the in situ aqueous alteration of soils on Mars

Early (>3 Gy) wetter climate conditions on Mars have been proposed, and it is thus likely that pedogenic processes have occurred there at some point in the past. Soil and rock chemistry of the Martian landing sites were evaluated to test the hypothesis that in situ aqueous alteration and downward movement of solutes have been among the processes that have transformed these portions of the Mars regolith. A geochemical mass balance shows that Martian soils at three landing sites have lost significant quantities of major rock-forming elements and have gained elements that are likely present as soluble ions. The loss of elements is interpreted to have occurred during an earlier stage(s) of weathering that may have been accompanied by the downward transport of weathering products, and the salts are interpreted to be emplaced later in a drier Mars history. Chemical differences exist among the sites, indicating regional differences in soil composition. Shallow soil profile excavations at Gusev crater are consistent with late stage downward migration of salts, implying the presence of small amounts of liquid water even in relatively recent Martian history. While the mechanisms for chemical weathering and salt additions on Mars remain unclear, the soil chemistry appears to record a decline in leaching efficiency. A deep sedimentary exposure at Endurance crater contains complex depth profiles of SO4, Cl, and Br, trends generally consistent with downward aqueous transport accompanied by drying. While no model for the origin of Martian soils can be fully constrained with the currently available data, a pedogenic origin is consistent with observed Martian geology and geochemistry, and provides a testable hypothesis that can be evaluated with present and future data from the Mars surface. ?? 2008 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗

Using saline or brackish aquifers as reservoirs for thermal energy storage, with example calculations for direct-use heating in the Portland Basin, Oregon, USA

Tools to evaluate reservoir thermal energy storage (RTES; heat storage in slow-moving or stagnant geochemically evolved permeable zones in strata that underlie well-connected regional aquifers) are developed and applied to the Columbia River Basalt Group (CRBG) beneath the Portland Basin, Oregon, USA. The performance of RTES for heat storage and recovery in the Portland Basin is strongly dependent on the operational schedule of heat injection and extraction. We examined the effects of the operational schedule, based on an annual solar hot water supply pattern and a building heating demand model, using heat and fluid flow simulations with SUTRA. We show RTES to be feasible for supply of heating energy for a large combined research/teaching building on the Oregon Health and Science University South Waterfront expansion, an area of planned future development. Initially, heat is consumed to increase the reservoir temperature, and conductive heat loss is high due to high temperature gradients between the reservoir and surrounding rock. Conductive heat loss continues into the future, but the rate of heat loss decreases, and heat recovery efficiency of the RTES system increases over time. Simulations demonstrate the effects of varying heat-delivery rate and temperature on the heat production history of the reservoir. If 100% of building heating needs are to be supplied by combined solar/RTES, then the solar system must be sized to meet building needs plus long-term thermal losses (i.e., conductive losses once the system is heated to pseudo-steady state) from the RTES system. If the solar heating system barely meets these criteria, then during early years, less than 100% of the building demand will be supplied until the reservoir is fully-heated. The duration of supplying less than 100% of building demand can be greatly shortened by pre-heating the reservoir before building heating operations or by adding extra heat from external sources during early years. Analytic solutions are developed to evaluate efficacy and to help design RTES systems (e.g., well-spacing, thermal source sizing, etc.). A map of thermal energy storage capacity is produced for the CRBG beneath the Portland Basin. The simulated building has an annual heat load of ∼1.9 GWh, and the total annual storage capacity of the Portland Basin is estimated to be 43,400 GWh assuming seasonal storage of heat yields water from which 10 °C can be extracted via heat exchange, indicating a tremendous heating capacity of the CRBG.

Oregon↗

Petrologic and experimental evidence for the etching of garnets by organic acids in the upper Jurassic Morrision Formation, northwestern New Mexico

The upper Jurassic Morrison Formation in the southern part of the San Juan Basin contains uniquely etched detrital garnets characterized by smooth, crystallographically controlled faceted surfaces. The etched garnets occur in relatively homogeneous Morrison sandstones in discrete stratigraphic zones that are bounded above and below by sandstones bearing unetched garnets. Diagenetic alterations associated with etched garnets include etched staurolite, skeletal plagioclase, regularly interstratified illite-smectite, iron-rich chlorite, ankerite, albite, diagenetically altered (organic-poor) uranium ore, and extensive secondary porosity. Etching of garnets and partial to complete dissolution of other aluminosilicate minerals were caused by high concentrations of organic acids generated during the maturation of epigenetic organic matter (predominantly type-III kerogen) in the Morrison Formation. The presence of authigenic phases that form near 100 degrees C indicates that temperatures were high enough during diagenesis to cause the thermal degradation of kerogen. The subsequent release of reactive organic acids promoted a variety of water-rock reactions. This hypothesis was corroborated by experiments in which dicarboxylic acid solutions created facets on garnets identical to those developed on naturally etched Morrison garnets. The excellent complexing ability of organic acid anions accounts for the characteristic lack of alteration products on etched surfaces.

Journal of Sedimentary Petrology↗

Assessment of the undiscovered oil and gas of the Senegal province, Mauritania, Senegal, the Gambia, and Guinea-Bissau, northwest Africa

Undiscovered, conventional oil and gas resources were assessed in the Senegal Province as part of the U.S. Geological Survey World Petroleum Assessment 2000 (U.S. Geological Survey World Energy Assessment Team, 2000). Although several total petroleum systems may exist in the province, only one composite total petroleum system, the Cretaceous-Tertiary Composite Total Petroleum System, was defined with one assessment unit, the Coastal Plain and Offshore Assessment Unit, having sufficient data to allow quantitative assessment. The primary source rocks for the Cretaceous-Tertiary Composite Total Petroleum System are the Cenomanian-Turonian marine shales. The Turonian shales can be as much as 150 meters thick and contain Type II organic carbon ranging from 3 to 10 weight percent. In the Senegal Province, source rocks are mature even when situated at depths relatively shallow for continental passive margin basins. Reservoir rocks consist of Upper Cretaceous sandstones and lower Tertiary clastic and carbonate rocks. The Lower Cretaceous platform carbonate rocks (sealed by Cenomanian shales) have porosities ranging from 10 to 23 percent. Oligocene carbonate rock reservoirs exist, such as the Dome Flore field, which contains as much as 1 billion barrels of heavy oil (10? API, 1.6 percent sulfur) in place. The traps are a combination of structural closures and stratigraphic pinch-outs. Hydrocarbon production in the Senegal Province to date has been limited to several small oil and gas fields around Cape Verde (also known as the Dakar Peninsula) from Upper Cretaceous sandstone reservoirs bounded by normal faults, of which three fields (two gas and one oil) exceed the minimum size assessed in this study (1 MMBO; 6 BCFG). Discovered known oil resources in the Senegal Province are 10 MMBO, with known gas resources of 49 BCFG (Petroconsultants, 1996). This study estimates that 10 percent of the total number of potential oil and gas fields (both discovered and undiscovered) of at least the minimum size have been discovered. The estimated mean size and number of assessed, undiscovered oil fields are 13 MMBO and 13 fields, respectively, whereas the mean size and number of undiscovered gas fields are estimated to be 50 BCFG and 11 fields. The mean estimates for undiscovered conventional petroleum resources are 157 MMBO, 856 BCFG, and 43 MMBNGL (table 2). The mean sizes of the largest anticipated undiscovered oil and gas fields are 66 MMBO and 208 BCFG, respectively. The Senegal Province is underexplored considering its large size. The province has hydrocarbon potential in both the offshore and onshore, and undiscovered gas resources may be significant and accessible in areas where the zone of oil generation is relatively shallow.

Bulletin↗

Assessment of Undiscovered Technically Recoverable Oil and Gas Resources of the Bakken Formation, Williston Basin, Montana and North Dakota, 2008

The U.S. Geological Survey (USGS) has completed an assessment of the undiscovered oil and associated gas resources of the Upper Devonian to Lower Mississippian Bakken Formation in the U.S. portion of the Williston Basin of Montana and North Dakota and within the Williston Basin Province. The assessment is based on geologic elements of a total petroleum system (TPS), which include (1) source-rock distribution, thickness, organic richness, maturation, petroleum generation, and migration; (2) reservoir-rock type (conventional or continuous), distribution, and quality; and (3) character of traps and time of formation with respect to petroleum generation and migration. Framework studies in stratigraphy and structural geology and modeling of petroleum geochemistry, combined with historical exploration and production analyses, were used to estimate the undiscovered, technically recoverable oil resource of the Bakken Formation. Using this framework, the USGS defined a Bakken-Lodgepole TPS and seven assessment units (AU) within the system. For the Bakken Formation, the undiscovered oil and associated gas resources were quantitatively estimated for six of these AUs.

Open-File Report↗

The duration and characteristics of magmatic differentiation from basalt to trachyte within the Matan volcanic center, northern Harrat Rahat, Kingdom of Saudi Arabia

A fundamental goal of igneous petrology is to quantify the durations required to produce evolved magmas following influx of basalt into the crust. However, in many cases, complex field relations and (or) the presence of a long-lived magmatic system make it difficult to assess how basaltic inputs relate to more evolved magmas, therefore precluding calculation of meaningful timescales. Here we present field relations, geochemistry, 40 Ar/ 39 Ar ages, and 36 Cl surface-exposure ages for volcanic rocks from the Matan volcanic center, located in the northern part of the Harrat Rahat volcanic field, in the Kingdom of Saudi Arabia. These data document a systematic and repeated temporal progression from alkali basalt to trachyte for the youngest eruptive products. From ~155–17 thousand years ago, the following eruptive sequence occurred four times: (1) alkali basalt, (2) hawaiite, mugearite, or benmoreite, and (3) trachyte. We interpret each eruptive sequence to result from injection of basalt into the crust, and its subsequent differentiation and eruption of progressively evolved magmas. We use the interval time between successive eruptions within a given sequence to calculate the timespans required to produce trachyte from alkali basalt. Differentiation from alkali basalt to intermediate compositions (hawaiite, mugearite, and benmoreite) took ≤3 thousand years (k.y.) on average. Differentiation from intermediate compositions to trachyte took a maximum of 6.7±3.6 to 22.9±1.7 k.y. Thus, the total duration of differentiation was ~10–25 k.y. Timescales presented here are independent of the processes evoked to drive differentiation because they are based solely on the ages and compositions of eruptive products from a system characterized by a simple, repeated differentiation sequence.

northern Harrat Rahat↗

Mantle melting in regions of thick continental lithosphere: Examples from Late Cretaceous and younger volcanic rocks, Southern Rocky Mountains, Colorado (USA)

Major- and trace-element data together with Nd and Sr isotopic compositions and 40 Ar/ 39 Ar age determinations were obtained for Late Cretaceous and younger volcanic rocks from north-central Colorado, USA, in the Southern Rocky Mountains to assess the sources of mantle-derived melts in a region underlain by thick (≥150 km) continental lithosphere. Trachybasalt to trachyandesite lava flows and volcanic cobbles of the Upper Cretaceous Windy Gap Volcanic Member of the Middle Park Formation have low εNd(t) values from −3.4 to −13, 87 Sr/ 86 Sr(t) from ~0.705 to ~0.707, high large ion lithophile element/high field strength element ratios, and low Ta/Th (≤0.2) values. These characteristics are consistent with the production of mafic melts during the Late Cretaceous to early Cenozoic Laramide orogeny through flux melting of asthenosphere above shallowly subducting and dehydrating oceanic lithosphere of the Farallon plate, followed by the interaction of these melts with preexisting, low εNd(t), continental lithospheric mantle during ascent. This scenario requires that asthenospheric melting occurred beneath continental lithosphere as thick as 200 km, in accordance with mantle xenoliths entrained in localized Devonian-age kimberlites. Such depths are consistent with the abundances of heavy rare earth elements (Yb, Sc) in the Laramide volcanic rocks, which require parental melts derived from garnet-bearing mantle source rocks. New 40 Ar/ 39 Ar ages from the Rabbit Ears and Elkhead Mountains volcanic fields confirm that mafic magmatism was reestablished in this region ca. 28 Ma after a hiatus of over 30 m.y. and that the locus of volcanism migrated to the west through time. These rocks have εNd(t) and 87 Sr/ 86 Sr(t) values equivalent to their older counterparts (−3.5 to −13 and 0.7038–0.7060, respectively), but they have higher average chondrite-normalized La/Yb values (~22 vs. ~10), and, for the Rabbit Ears volcanic field, higher and more variable Ta/Th values (0.29–0.43). The latter are general characteristics of all other post– 40 Ma volcanic rocks in north-central Colorado for which literature data are available. Transitions from low to intermediate Ta/Th mafic volcanism occurred diachronously across southwest North America and are interpreted to have been a consequence of melting of continental lithospheric mantle previously metasomatized by aqueous fluids derived from the underthrusted Farallon plate. Melting occurred as remnants of the Farallon plate were removed and the continental lithospheric mantle was conductively heated by upwelling asthenosphere. A similar model can be applied to post–40 Ma magmatism in north-central Colorado, with periodic, east to west, removal of stranded remnants of the Farallon plate from the base of the continental lithospheric mantle accounting for the production, and western migration, of volcanism. The estimated depth of the lithosphere-asthenosphere boundary in north-central Colorado (~150 km) indicates that the lithosphere remains too thick to allow widespread melting of upwelling asthenosphere even after lithospheric thinning in the Cenozoic. The preservation of thick continental lithospheric mantle may account for the absence of oceanic-island basalt–like basaltic volcanism (high Ta/Th values of ~1 and εNd[t] > 0), in contrast to areas of southwest North America that experienced larger-magnitude extension and lithosphere thinning, where oceanic-island basalt–like late Cenozoic basalts are common.

Geosphere↗

Is there a basin-centered gas accumulation in Cotton Valley group sandstones, Gulf Coast basin, U.S.A.?

The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, is reevaluating the resource potential of selected domestic basin-centered gas accumulations. Basin-centered gas accumulations are characterized by presence of gas in extensive low-permeability (tight) reservoirs in which conventional seals and trapping mechanisms are absent, abnormally high or low reservoir pressures exist, and gas-water contacts are absent. In 1995, the USGS assessed one basin-centered gas play and two conventional plays within the trend of Jurassic and Cretaceous Cotton Valley Group fluvial-deltaic and barrier island/strand plain sandstones across the onshore northern Gulf of Mexico Basin. Detailed evaluation of geologic and production data provides new insights into these Cotton Valley plays. Two Cotton Valley sandstone trends are identified based on reservoir properties and gas-production characteristics. Transgressive blanket sandstones across northern Louisiana have relatively high porosity and permeability and do not require fracture stimulation to produce gas at commercial rates. South of this trend, and extending westward into eastern Texas, massive sandstones of the Cotton Valley trend exhibit low porosity and permeability and require fracture stimulation. The high permeability of Cotton Valley blanket sandstones is not conducive to the presence of basin-centered gas, but low permeability massive sandstones provide the type of reservoir in which basin-centered gas accumulations commonly occur. Data on source rocks, including burial and thermal history, are consistent with the interpretation of potential basin centered gas within Cotton Valley sandstones. However, pressure gradients throughout most of the blanket- and massive sandstone trends are normal or nearly normal, which is not characteristic of basin-centered gas accumulations. The presence of gas-water contacts in at least seven fields across the blanket-sandstone trend together with relatively high permeabilities and high gas-production rates without fracture stimulation indicate that fields in this trend are conventional. Within the tight massive-sandstone trend, permeability is sufficiently low that gas-water transition zones are vertically extensive and gas-water contacts either have not been encountered or are poorly defined. With increasing depth through these transition zones, gas saturation decreases and water saturation increases until eventually gas saturations become sufficiently low that, in terms of ultimate cumulative production, wells are noncommercial. Such progressive increase in water saturation with depth suggests that poorly defined gas-water contacts probably are present below the depth at which wells become noncommercial. The interpreted presence of gas-water contacts within the tight, Cotton Valley massive-sandstone trend suggests that gas accumulations in this trend, too, are conventional, and that a basin-centered gas accumulation does not exist within Cotton Valley sandstones in the northern Gulf Basin.

Louisiana, Texas↗

Evaporite encrustations and sulphide oxidation products from the southern Antarctic peninsula.

White evaporite encrustations collected from 66 sites scattered over 30 000km2 of S.Antarctic Peninsula are dominantly gypsum and calcite, and subordinate aragonite and thenardite. Natrojarosite occurs as locally developed yellow surface stains on c30% of the white encrustations examined. Water, which forms by the melting of snow blown into cracks in highly fractured rocks by ground blizzards, dissolves soluble ions from minerals in these rocks as it percolates into them. The white encrustations appear to be deposited when this water later rises to the surface by capillary action and evaporates.-from Author Antarctica chemical weathering evaporites sulphide oxidation.

New Zealand Journal of Geology and Geophysics↗

Using high-resolution aeromagnetic surveys to map subsurface hydrogeology in sediment-filled basins: A case study over the Rio Grande Rift, Central New Mexico, USA

High-resolution aeromagnetic surveys were acquired for the Albuquerque basin in the central Rio Grande rift, a basin filled with poorly consolidated sediments. The surveys proved successful in efficiently and economically mapping previously unknown hydrogeologic features of the shallow subsurface. This success suggests that aeromagnetic methods may be useful in hydrogeologic studies of other sediment-filled basins. The aeromagnetic surveys were used primarily to delineate buried igneous rocks and to locate faults within the basin fill, both important for understanding the subsurface hydrogeology. Buried igneous rocks were recognized from their high-frequency, high-amplitude magnetic responses and characteristic map patterns. The horizontal-gradient and local wavenumber methods were used to obtain estimates of their source depths. The aeromagnetic surveys were also successfully used to locate faults within the basin fill. Magnetic signatures associated with faults are produced by the juxtaposition of sediments having differing magnetic properties rather than the products of secondary processes. Expression of faults is abundant throughout the basin, revealing patterns that cannot be mapped at the surface due to widespread cover. A fault signature recognized in the high-resolution data that has multiple inflection points is best explained by a fault with a thin magnetic layer on the upthrown block and thick magnetic layer on the downthrown block, called the thin-thick layers model. Geologically, this signature indicates erosion of the upthrown block or a growth-faulting scenario: fault-controlled sedimentation for faults that offset sediments, and successive accumulation of basalt on the downthrown block for faults that offset volcanic rocks.

New Mexico↗

A transient laboratory method for determining the hydraulic properties of 'tight' rocks-II. Application

In Part I a general analytical solution for the transient pulse test was presented. Part II presents a graphical method for analyzing data from a test to obtain the hydraulic properties of the sample. The general solution depends on both hydraulic conductivity and specific storage and, in theory, analysis of the data can provide values for both of these hydraulic properties. However, in practice, one of two limiting cases may apply in which case it is possible to calculate only hydraulic conductivity or the product of hydraulic conductivity times specific storage. In this paper we examine the conditions when both hydraulic parameters can be calculated. The analyses of data from two tests are presented. In Appendix I the general solution presented in Part I is compared with an earlier analysis, in which compressive storage in the sample is assumed negligible, and the error in calculated hydraulic conductivity due to this simplifying assumption is examined.

International Journal of Rock Mechanics and Mining↗

Chesapeake Bay impact structure—Development of "brim" sedimentation in a multilayered marine target

The late Eocene Chesapeake Bay impact structure was formed in a multilayered target of seawater underlain sequentially by a sediment layer and a rock layer in a continental-shelf environment. Impact effects in the “brim” (annular trough) surrounding and adjacent to the transient crater, between the transient crater rim and the outer margin, primarily were limited to the target-sediment layer. Analysis of published and new lithostratigraphic, biostratigraphic, sedimentologic, petrologic, and mineralogic studies of three core holes, and published studies of a fourth core hole, provided information for the interpretation of the impact processes, their interactions and relative timing, their resulting products, and sedimentation in the brim. Most studies of marine impact-crater materials have focused on those found in the central crater. There are relatively few large, complex marine craters, of which most display a wide brim around the central crater. However, most have been studied using minimal data sets. The large number of core holes and seismic profiles available for study of the Chesapeake Bay impact structure presents a special opportunity for research. The physical and chronologic records supplied by study of the sediment and rock cores of the Chesapeake Bay impact indicate that the effects of the initial, short-lived contact and compression and excavation stages of the impact event primarily were limited to the transient crater. Only secondary effects of these processes are evident in the brim. The preserved record of the brim was created primarily in the subsequent modification stage. In the brim, the records of early impact processes (e.g., outgoing tsunamis, overturned flap collapse) were modified or removed by later processes. Transported and rotated, large and small clasts of target sediments, and intervals of fluidized sands indicate that seismic shaking fractured and partially fluidized the Cretaceous and Paleogene target sediments, which led to their inward transport by collapse and lateral spreading toward the transient crater. The succeeding inward seawater-resurge flow quickly overtook and interacted with the lateral spreading, further facilitating sediment transport across the brim and into the transient crater. Variations in the cohesion and relative depth of the target sediments controlled their degree of disaggregation and redistribution during these events. Melt clasts and shocked and unshocked rock clasts in the resurge sediments indicate fallout from the ejecta curtain and plume. Basal parautochthonous remnant sections of target Cretaceous sediments in the brim thin toward the collapsed transient crater. Overlying seawater-resurge deposits consist primarily of diamictons that vary laterally in thickness, and vertically and laterally in maximum grain size. After cessation of resurge flow and re-establishment of pre-impact sea level, sandy sediment gravity flows moved from the margin to the center of the partially filled impact structure (shelf basin). The uppermost unit consists of stratified sediments deposited from suspension. Postimpact clayey silts cap the crater fill and record the return to shelf sedimentation at atypically large paleodepths within the shelf basin. An unresolved question involves a section of gravel and sand that overlies Neoproterozoic granite in the inner part of the brim in one core hole. This section may represent previously unrecognized, now parautochthonous Cretaceous sediments lying nonconformably above basement granite, or it may represent target sediments that were moved significant distances by lateral spreading above basement rocks or above a granite megaclast from the overturned flap. The Chesapeake Bay impact structure is perhaps the best documented example of the small group of multilayer, marine-target impacts formed in continental shelves or beneath epeiric seas.

Chesapeake Bay↗

Niobium and tantalum

Niobium and tantalum are transition metals that are almost always found together in nature because they have very similar physical and chemical properties. Their properties of hardness, conductivity, and resistance to corrosion largely determine their primary uses today. The leading use of niobium (about 75 percent) is in the production of high-strength steel alloys used in pipelines, transportation infrastructure, and structural applications. Electronic capacitors are the leading use of tantalum for high-end applications, including cell phones, computer hard drives, and such implantable medical devices as pacemakers. Niobium and tantalum are considered critical and strategic metals based on the potential risks to their supply (because current production is restricted to only a few countries) and the significant effects that a restriction in supply would have on the defense, energy, high-tech industrial, and medical sectors. The average abundance of niobium and tantalum in bulk continental crust is relatively low—8.0 parts per million (ppm) niobium and 0.7 ppm tantalum. Their chemical characteristics, such as small ionic size and high electronic field strength, significantly reduce the potential for these elements to substitute for more common elements in rock-forming minerals and make niobium and tantalum essentially immobile in most aqueous solutions. Niobium and tantalum do not occur naturally as pure metals but are concentrated in a variety of relatively rare oxide and hydroxide minerals, as well as in a few rare silicate minerals. Niobium is primarily derived from the complex oxide minerals of the pyrochlore group ((Na,Ca,Ce) 2 (Nb,Ti,Ta) 2 (O,OH,F) 7 ), which are found in some alkaline granite-syenite complexes (that is, igneous rocks containing sodium- or potassium-rich minerals and little or no quartz) and carbonatites (that is, igneous rocks that are more than 50 percent composed of primary carbonate minerals, by volume). Tantalum is derived mostly from the mineral tantalite ((Fe,Mn)(Ta,Nb) 2 O 6 ), which is found as an accessory mineral in rare-metal granites and pegmatites that are also enriched in lithium and cesium (termed lithium-cesium-tantalum (LCT)-type pegmatites). Brazil and Canada are the leading nations that produce niobium mineral concentrates, but Brazil is by far the leading producer, accounting for about 90 percent of production, which comes mostly from weathered material derived from carbonatites. Brazil and Canada also have the largest identified niobium resources; additional resources, although they are less well reported, occur in Angola, Australia, China, Greenland, Malawi, Russia, and South Africa. Australia and Brazil have been the leading producers of tantalum mineral concentrates, although recently Ethiopia and Mozambique have also been significant suppliers of tantalum. Artisanal mining of columbite-tantalite (also called coltan) is practiced in many countries, particularly Burundi, the Democratic Republic of the Congo (Congo [Kinshasa]), Nigeria, Rwanda, and Uganda. Brazil has about 40 percent of the identified tantalum resources; other countries and regions with identified tantalum resources include, in decreasing order of resources, Australia, Asia, Russia and the Middle East, Africa, North America, and Europe. Identified niobium and tantalum resources in the United States are small, low grade, and difficult to recover and process, and are thus not commercially recoverable at current prices. Consequently, the United States meets its current and expected future needs for niobium and tantalum through imports of primary mineral concentrates and alloys and through recovery from foreign and domestic alloy scrap that contain the metals. Environmentally, the main issues related to niobium and tantalum mining are land disruptions, the volume of waste materials and their disposal, and the radioactivity of some tailings and waste materials that contain thorium and uranium. Because of the relative biological inertness of niobium and tantalum, human and ecological health concerns are generally minimal under most natural conditions. Demand for both niobium and tantalum is expected to increase as the world economy continues to recover from the downturn that began in 2008. Increased demand for niobium is linked to increased consumption of microalloyed steel, which is used in the manufacture of cars, buildings, ships, and refinery equipment. Demand for these steels will likely increase with continued economic development in such countries as Brazil, China, and India. In addition, increased global demand for cars, cell phones, computers, superconducting magnets, and other high-tech devices will likely spur increased demand for both niobium and tantalum. The estimated global reserves and resources of niobium and tantalum are large and appear more than sufficient to meet global demand for the foreseeable future, possibly the next 500 years. The sale of “conflict coltan” attributed to rebel forces waging a civil war in Congo (Kinshasa) has been of recent concern and has highlighted the need for a transparent and traceable global supply chain that can exclude illegal columbite-tantalite from the conventional market while discerning legitimate artisanal mine production in central Africa.

Professional Paper↗

Ancient wet aeolian environments on Earth: Clues to presence of fossil/live microorganisms on Mars

Ancient wet aeolian (wet-sabkha) environments on Earth, represented in the Entrada and Navajo sandstones of Utah, contain pipe structures considered to be the product of gas/water release under pressure. The sediments originally had considerable porosity allowing the ingress of living plant structures, microorganisms, clay minerals, and fine-grained primary minerals of silt and sand size from the surface downward in the sedimentary column. Host rock material is of a similar size and porosity and presumably the downward migration of fine-grained material would have been possible prior to lithogenesis and final cementation. Recent field emission scanning electron microscopy (FESEM) and EDS (energy-dispersive spectrometry) examination of sands from fluidized pipes in the Early Jurassic Navajo Sandstone reveal the presence of fossil forms resembling fungal filaments, some bearing hyphopodium-like structures similar to those produced by modern tropical leaf parasites. The tropical origin of the fungi is consistent with the paleogeography of the sandstone, which was deposited in a tropical arid environment. These fossil fungi are silicized, with minor amounts of CaCO3 and Fe, and in some cases a Si/Al ratio similar to smectite. They exist as pseudomorphs, totally depleted in nitrogen, adhering to the surfaces of fine-grained sands, principally quartz and orthoclase. Similar wet aeolian paleoenvironments are suspected for Mars, especially following catastrophic sediment-charged floods of enormous magnitudes that are believed to have contributed to rapid formation of large water bodies in the northern plains, ranging from lakes to oceans. These events are suspected to have contributed to a high frequency of constructional landforms (also known as pseudocraters) related to trapped volatiles and water-enriched sediment underneath a thick blanket of materials that were subsequently released to the martian surface, forming piping structures at the near surface and constructional landforms at the surface. This constructional process on Mars may help unravel the complex history of some of the piping structures observed on Earth; on Earth, evidence for the constructional landforms has been all but erased and the near-surface piping structures exposed through millions of years of differential erosion and topographic inversion now occur as high-standing promontories. If the features on both Earth and Mars formed by similar processes, especially involving water and other volatiles, and since the piping structures of Earth provided suitable environments for life to thrive in, the martian features in the northern plains should be considered as prime targets for physico/mineral/chemical/microbiological analyses once the astrobiological exploration of the red planet begins in earnest. ?? 2004 Elsevier Inc. All rights reserved.

Icarus↗

Nordstrandite from Guam

NORDSTRANDITE (Al 2 O 3 ·3H 2 O), previously reported only as a synthetic product 1,2 , occurs in Miocene limestone on Guam. In south Guam this limestone forms a cap several hundred feet thick, on the Mount Alifan–Mount Lamlan ridge, and overlies late Eocene and early Miocene basalt flows and volcanic conglomerates. The volcanic rocks below the limestone are deeply weathered. The nordstrandite occurs in secondary solution cavities and is concentrated mainly in the basal part of the limestone near its contact with the weathered basalt. In thin section the nordstrandite crystals are seen as flamboyant aggregates reaching lengths of as much as 0.4 mm. The optical properties of the mineral are as follows: The hardness is about 3 and the specific gravity was determined by Edward J. Young to be 2.436.

Guam↗