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At least 649 records · Page 36Linked to original sources

Sedimentology and cyclicity in the Lower Permian De Chelly Sandstone on the Defiance Plateau: Eastern Arizona

The Lower Permian (Leonardian) De Chelly Sandstone crops out along a north-south trend on the Defiance Plateau of eastern Arizona. It is divided into lower and upper members separated by a tongue of the Supai Formation that pinches out to the north. Lithofacies in the De Chelly Sandstone consist of (1) a large-scale trough to tabular- and/or wedge-planar cross-stratified sandstone facies of large-scale eolian dune origin, (2) a small- to medium-scale, trough cross-stratified sandstone also of eolian dune origin, (3) a horizontally stratified, wind-rippled sandstone of sand sheet origin, (4) a wavy, horizontally stratified, wind-rippled sandstone of sabkha origin, and (5) a mud-draped ripple-laminated sandstone of mud-flat origin. The De Chelly Sandstone in the northern Defiance Plateau consists mainly of large-scale dune deposits. Stratigraphic sections in the middle of the plateau are dominated by small- to medium-scale dune and sand sheet deposits whereas those along the southern end of the plateau are composed largely of sabkha and supratidal mud-flat deposits. The lateral distribution of these facies suggests a north-south juxtaposition of central-erg, fore-erg, and mixed sabkha-supratidal depositional environments. Repetitive interbedding of facies in the De Chelly indicates at least twelve depositional cycles in which sabkha and/or supratidal to coastal-plain mud-flats were sequentially overridden by eolian sand sheets and cross-stratified dunes. Lateral and vertical facies relations within the lower and upper members of the De Chelly Sandstone record episodic expansion of the De Chelly erg southward, The comparative abundance of large-scale dune deposits in the upper member suggests that progradation was more extensive during latter stages of deposition. The intervening tongue of Supai Formation and the redbeds that overlie the upper member of the De Chelly at Bonito Canyon document northward transgression of sabkha and supratidal to coastal-plain mud-flat environments. Eolian dune deposition was restricted to the northern Defiance Plateau during deposition of these units.

Arizona↗

Chemical characteristics and temporal trends in eight streams of the Catskill Mountains, New York

Discharge to concentration relationships for eight streams studied by the U.S. Geological Survey (USGS) as part of the U.S. Environmental Protection Agency's (U.S. EPA) Long-Term Monitoring Project (1983-89) indicate acidification of some streams by H2SO4 and HNO3 in atmospheric deposition and by organic acids in soils. Concentrations of major ions in precipitation were similar to those reported at other sites in the northeastern United States. Average concentrations of SO42- and NO3- were similar among streams, but base cation concentrations differed widely, and these differences paralleled the differences in acid neutralizing capacity (ANC). Baseflow ANC is not a reliable predictor of stream acidity at high flow; some streams with high baseflow ANC (> 150 ??eq L-1) declined to near zero ANC at high flow, and one stream with low baseflow ANC (< 50 ??eq L-1) did not approach zero ANC as flow increased. Episodic decreases in ANC and pH during peak flows were associated with increased concentrations of NO3- and dissolved organic carbon (DOC). Aluminum concentrations exceeding 300 ??g L-1 were observed during peak flows in headwater streams of the Neversink River and Rondout Creek. Seasonal Kendall Tau tests for temporal trends indicate that SO42- concentrations in streamwater generally decreased and NO3- concentrations increased during the period 1983-1989. Combined acid anion concentrations (SO42- + NO3-) were generally unchanged throughout the period of record, indicating both that the status of these streams with respect to acidic deposition is unchanged, and that NO3- is gradually replacing SO42- as the dominant acid anion in the Catskill streams.Discharge to concentration relationships for eight streams studied by the US Geological Survey (USGS) as part of the Environmental Protection Agency's (US EPA) Long-term monitoring project (19831-89) indicate acidification of some streams by H2SO4 and HNO3 in atmospheric deposition and by organic acids in soils. Concentrations of major ions in precipitations were similar to those reported at other sites in the northeastern United States. Average concentrations of SO42- and No3- were similar among streams, but base cation concentrations differed widely, and these differences parallelel the differences in acid neutralizing capacity (ANC).

Water, Air, & Soil Pollution↗

Oceanic methane hydrate: The character of the Blake Ridge hydrate stability zone, and the potential for methane extraction

Oceanic methane hydrates are mineral deposits formed from a crystalline 'ice' of methane and water in sea-floor sediments (buried to less than about 1 km) in water depths greater than about 500 m; economic hydrate deposits are probably restricted to water depths of between 1.5 km and 4 km. Gas hydrates increase a sediment's strength both by 'freezing' the sediment and by filling the pore spaces in a manner similar to water-ice in permafrost. Concentrated hydrate deposits may be underlain by significant volumes of methane gas, and these localities are the most favourable sites for methane gas extraction operations. Seismic reflection records indicate that trapped gas may blow-out naturally, causing large-scale seafloor collapse. In this paper, we consider both the physical properties and the structural integrity of the hydrate stability zone and the associated free gas deposits, with special reference to the Blake Ridge area, SE US offshore, in order to help establish a suitable framework for the safe, efficient, and economic recovery of methane from oceanic gas hydrates. We also consider the potential effects of the extraction of methane from hydrate (such as induced sea-floor faulting, gas venting, and gas-pocket collapse). We assess the ambient pressure effect on the production of methane by hydrate dissociation, and attempt to predict the likelihood of spontaneous gas flow in a production situation.Oceanic methane hydrates are mineral sits formed from a crystalline `ice' of methane and water in sea-floor sediments (buried to less than about 1 km) in water depths greater than about 500 m; economic hydrate deposits are probably restricted to water depths of between 1.5 km and 4 km. Gas hydrates increase a sediment's strength both by `freezing' the sediment and by filling the pore spaces in a manner similar to water-ice in permafrost. Concentrated hydrate deposits may be underlain by significant volumes of methane gas, and these localities are the most favourable sites for methane gas extraction operations. Seismic reflection records indicate that trapped gas may blow-out naturally, causing large-scale seafloor collapse. In this paper, we consider both the physical properties and the structural integrity of the hydrate stability zone and the associated free gas deposits, with special reference to the Blake Ridge area, SE US offshore, in order to help establish a suitable framework for the safe, efficient, and economic recovery of methane from oceanic gas hydrates. We also consider the potential effects of the extraction of methane from hydrate (such as induced sea-floor faulting, gas venting, and gas-pocket collapse). We assess the ambient pressure effect on the production of methane by hydrate dissociation, and attempt to predict the likelihood of spontaneous gas flow in a production situation.

Journal of Petroleum Geology↗

Geology of the Deep Creek area, Washington, and its regional significance

This report, although primarily concerned with the stratigraphy and structure of a lead-zinc mining district in northern Stevens County, Washington, discusses and integrates the geology of the region about the Deep Creek area. Although the study centers in an area of about 200 square miles immediately south of the International Boundary, the regional background comes from: (1)the previously undescribed Northport quadrangle to the west, (2) published reports and reconnaissance of the Metaline quadrangle to the east, and (3) from published reports and maps of a 16 mile wide area that lies to the north adjacent to these three quadrangles in British Columbia. The report is divided into three parts: (1) descriptions of rocks and structures of the Deep Creek area, (2) descriptions of the regional setting of the Deep Creek area, and (3) an analysis and interpretation of the depositional and tectonic events that produced the geologic features exposed today. In the Deep Creek area surficial deposits of sand and gravel of glacial origin cover much of the consolidated rocks, which range in age from greenschist of the late Precambrlan to albite granite of the Eocene. Three broad divisions of depositional history are represented: (1) Precambrian, (2) lower Paleozoic and (3) upper Paleozoic; the record of the Mesozoic and Eocene is fragmentary. The lower Paleozoic division is the only fossil-controlled sequence; the age of the other two divisions were established by less direct methods. Both Precambrian and upper Paleozoic sequences are dominated by fine-grained detrital sediments, the Precambrian tending towards the alumina-rich and the upper Paleozoic tending towards the black shale facies with high silica. Neither sequence has more than trivial amounts of coarse clastics. Both include limestones, but in minor abundance. The lower Paleozoic sequence, on the other hand, represents a progressive change in deposition. The sequence began during the very late Precambrian with the deposition of clean quartz sand. This was followed by the accumulation of a comparatively thin limestone unit succeeded by a thick shale. The shale grades into a thick carbonate unit which in turn is overlain by black graptolitic slates (Ordovician). This general order of deposition holds for the Cambro-Ordovician throughout the area. Precambrian rocks indigenous to the Deep Creek area, have undergone at least six tectonic events of greatly different intensities. The first three of these events are epeirogentic, the fourth involves intense folding, the fifth, crossfolding, and the sixth, block faulting without folding. These events are dated with varying degrees of precision. The two epeirogentic events of the Precambrian, one gentle folding at the beginning of Windermere time and the other high angle faulting and volcanism in mid-Windermere time, did little to deform or metamorphose the rocks. The third event consists of uplift of northern Idaho and adjacent Montana and westward decollement thrusting of essentially unfolded lower Paleozoic rocks. The decollement faulting is inferred to explain anomalous rock distribution and cannot be accurately dated. It occurred sometime after the Devonian and before the Jurassic. A late Paleozoic age is favored.

British Columbia, Idaho, Washington↗

Biostratigraphy, paleoenvironmental, and paleomagnetic synthesis of the Goban Spur region, Deep Sea Drilling Project Leg 80

A composite stratigraphic section based on the four DSDP-IPOD Leg 80 drill sites provides a nearly complete record of syn-rift and post-rift events in the vicinity of Goban Spur. Syn-rift sediments were deposited in marginal marine to outer shelf environments. Above the "breakup" unconformity (hiatus spanning most of the Aptian), post-rift Albian sediments indicate the development of a deep-water seaway in the Goban Spur region. The latest Campanian/Maestrichtian interval records the initiation of rather uniform, widely distributed marine sedimentation throughout the region. Climatic changes, rather than changes in water depth, became conspicuous during the Tertiary. Widespread, nearly synchronous periods of nondeposition or erosion occurred in the Paleocene, middle Eocene, middle Oligocene, and late Miocene. Differences in the sediment record among sites are due to their varying positions (1) along the margin of the developing Atlantic seaway and (2) within their respective half-graben depositional basins.

Initial reports of the Deep Sea Drilling Project↗

Improved method for correlating late Pleistocene/Holocene records from the Bering Sea: Application of a biosiliceous/geochemical stratigraphy

The combination of high-resolution siliceous biostratigraphy and radiocarbon dating provides a mechanism for detailed assessment of the depositional history in late Pleistocene sediments from the Bering Sea where average accumulation rates are uncharacteristically high compared to rates calculated for most other ocean basins. Vital to the development of this stratigraphy was the recognition that the abundance pattern of the radiolarian species Cycladophora davisiana in Bering Sea cores is quite similar to this species' previously correlated abundance curve in a late Pleistocene/Holocene record from the northwest Pacific. Comparison of this high-resolution stratigraphy with other recently developed floral and lithologic stratigraphies for late Pleistocene Bering Sea sediments shows that the various stratigraphies do not always yield identical results when applied to a particular sediment sequence. With this new stratigraphy based upon a combination of siliceous microfaunal abundance patterns and radiocarbon dating, one can identify reworking, discontinuities and other interruptions in the depositional sequence more precisely than with previously devised stratigraphies, thereby improving the correlation techniques for comparison of late Pleistocene/Holocene records from this marginal sea.

Deep Sea Research Part A, Oceanographic Research P↗

Water levels and ground-water discharge, regional aquifer system of the midwestern Basins and Arches Region, in parts of Indiana, Ohio, Illinois, and Michigan

Aquifers in Quaternary glacial deposits and the underlying Silurian and Devonian carbonate bedrock in parts of Indiana, Ohio, Illinois, and Michigan compose the regional aquifer system under investigation as part of the Midwestern Basins and Arches Regional Aquifer System Analysis (Midwestern Basins and Arches&mdash;RASA) project of the U.S. Geological Survey (USGS). The Midwestern Basins and Arches&mdash;RASA is part of a USGS program to assess the regional hydrology, geology, and water quality of the Nation's most important aquifers (Sun, 1986). An objective specific to the Midwestern Basins and Arches&mdash;RASA project is to conceptualize and describe regional ground-water flow in the glacial-deposit and carbonate-bedrock aquifer system, including regional recharge and discharge areas and regional relations between surface and ground water (Bugliosi, 1990). Water-level and ground-water discharge data were collected and (or) analyzed to help meet the above objective. Specifically, data from the USGS Ground-Water Site Inventory (GWSI) data base were used to determine relations between land-surface altitude and water levels in glacial-deposit aquifers. Water levels in the carbonate-bedrock aquifer were synoptically measured during July 1990, and the data were used to construct a potentiometric surface map of the aquifer. Regional hydraulic gradients and general directions of regional flow in the carbonate-bedrock aquifer can be inferred from this map. Steady-state groundwater discharge to streams that drain the area underlain by the glacial-deposit and carbonate bedrock aquifer system was estimated from base-flow daily values computed from streamflow records. Water-level and ground-water-discharge data collectively form the sample information necessary to develop calibration targets for calibration of a ground-water-flow model (Anderson and Woessner, 1992). Such a ground-water-flow model of the glacial-deposit and carbonate-bedrock aquifer system was constructed to help conceptualize and describe regional ground-water flow in the aquifer system. The model was calibrated to the water-level and ground-water-discharge data presented in this atlas.

Hydrologic Atlas↗

Climate and lake-level history of the northern altiplano, Bolivia, as recorded in holocene sediments of the Rio Desaguadero

Strata exposed in terraces and modern cutbanks along the Rio Desaguadero contain a variety of lithofacies that were deposited in four distinct facies associations. These facies associations document a history of aggradation and downcutting that is linked to Holocene climate change on the Altiplano. Braided-stream, meandering-stream, deltaic and shoreline, and lacustrine sediments preserved in multi-level terraces in the northern Rio Desaguadero Valley record two high-water intervals; one between 4500 and 3900 yr BP and another between 2000 and 2200 yr BP. These wet periods were interrupted by three periods of fluvial downcutting, centered at approximately 4000 yr BP, 3600 yr BP, and after 2000 yr BP. Braided-river sediments preserved in a single terrace level in the southern Rio Desaguadero Valley record a history of nearly continuous fluvial sedimentation from at least 7000 yr BP until approximately 3200 yr BP that was followed by a single episode (post-3210 yr BP) of down-cutting and lateral migration. The deposition and subsequent fluvial downcutting of the northern strata was controlled by changes in effective moisture that can be correlated to Holocene water-level fluctuations of Lake Titicaca. The deposition and dissection of braided-stream sediments to the south are more likely controlled by a combination of base-level change and sediment input from the Rio Mauri.

Journal of Sedimentary Research↗

Paleoseismic Investigations of the Walnut Site on the San Jacinto Fault

The Walnut paleoseismic site is located along the northern San Jacinto fault about 3 km southeast of the San Bernardino, California city center (Figures 1, 2). More than 340 meters of trenches were excavated across the fault zone at this site as part of an Alquist-Priolo fault study (Figure 3). We photographed and logged the SE wall and most of the NE wall of trench 1, both walls of trenches 2 and 7, the NW walls of trenches 3 and 4 and the SE wall of trench 6. After carefully cleaning the trench walls we put up a 1m by 0.5m string and nail grid. For trenches 1, 2, 6, and 7, we photographed each 1m by 0.5m panel individually and photologged on these unrectified photos. These large-scale photos were later rectified to remove the distortion due to irregularities in the trench walls and slight distortion introduced by the camera lens. Field linework was then transferred to the rectified photomosaics. We also took a set of overview photographs for each trench taken from the top of the trench towards the opposite wall. We spliced together these overview photos to make photomosaics of all of the trenches. Because the photos were taken at a downward angle, there is significant distortion. Some of this distortion has been corrected: an attempt was made to keep horizontal grid lines horizontal and there has been some horizontal scaling to align vertical lines between benches. Although the string and nail grid spacing is 1 meter by 0.5 meter, because of the distortion in the photos and subsequent adjustments, the scale is variable along the benches, from bench to bench and from trench to trench for these overview mosaics. This report serves principally as a repository for the overview photomosaics. Sheet 1 shows the overview mosaics for both walls of trenches 1 and 2 along with some linework including most of the fault traces, a prominent unconformity within the fluvial deposits and the larger bodies of liquefied sand. Sheet 2 shows the overview mosaics for the SE wall of trench 3 and the NW wall of trench 4 along with photomosaics of both walls of trench 7 and the SE wall of trench 6 that were complied from the rectified, large scale photos. No linework has been portrayed on these photomosaics. Sheet 3 shows the overview mosaics of both walls of trench 1 with the locations of detrital charcoal samples that were collected. A later version of this report will contain photomosaics for trenches 1 and 2 compiled from the individual, fully rectified photos covering each 1m by 0.5m area with detailed linework superimposed. The trenches exposed a main, Holocene-active, fault zone about 5-12 m wide which juxtaposes Late Pleistocene (?) fluvial sand and gravel southwest of the fault against organic-rich, Holocene fine sand, silt and clay apparently deposited in a marsh. Most of the faults in the main zone appear to rupture to the ground surface making it impossible to resolve individual prehistoric earthquakes along this zone. However, the main fault zone is associated with a slight upwarp and growth strata associated with this folding has recorded evidence for at least 6 late-Holocene earthquakes. Deformation due to liquefaction is further evidence of large earthquakes at these horizons. The fine-grained Holocene deposits contain abundant detrital charcoal. We have so far dated 36 samples from 20 stratigraphic layers. We used 27 of these dates in an Oxcal chronological model in order to constrain the ages of the six earthquakes. Too few samples have so far been dated from the uppermost horizons so the ages of the two youngest earthquakes recorded at the site are poorly constrained. However, it appears that the youngest sediment at the site was deposited about 2000 years ago and the thick surface soil indicate that the two youngest earthquake recorded at the site may be about this old. The radiocarbon dates provide good constraints on the ages of the four older earthquakes (Table 1). The ages of these four earthquakes suggest an aver

Open-File Report↗

MIS 5e sea-level history along the Pacific coast of North America

The primary last interglacial, marine isotope substage (MIS) 5e records on the Pacific coast of North America, from Washington (USA) to Baja California Sur (Mexico), are found in the deposits of erosional marine terraces. Warmer coasts along the southern Golfo de California host both erosional marine terraces and constructional coral reef terraces. Because the northern part of the region is tectonically active, MIS 5e terrace elevations vary considerably, from a few meters above sea level to as much as 70 m above sea level. The primary paleo-sea-level indicator is the shoreline angle, the junction of the wave-cut platform with the former sea cliff, which forms very close to mean sea level. Most areas on the Pacific coast of North America have experienced uplift since MIS 5e time, but the rate of uplift varies substantially as a function of tectonic setting. Chronology in most places is based on uranium-series ages of the solitary coral Balanophyllia elegans (erosional terraces) or the colonial corals Porites and Pocillopora (constructional reefs). In areas lacking corals, correlation to MIS 5e often can be accomplished using amino acid ratios of fossil mollusks, compared to similar ratios in mollusks that also host dated corals. Uranium-series (U-series) analyses of corals that have experienced largely closed-system histories range from ∼124 to ∼118 ka, in good agreement with ages from MIS 5e reef terraces elsewhere in the world. There is no geomorphic, stratigraphic, or geochronological evidence for more than one high-sea stand during MIS 5e on the Pacific coast of North America. However, in areas of low uplift rate, the outer parts of MIS 5e terraces apparently were re-occupied by the high-sea stand at ∼100 ka (MIS 5c), evident from mixes of coral ages and mixes of molluscan faunas with differing thermal aspects. This sequence of events took place because glacial isostatic adjustment processes acting on North America resulted in regional high-sea stands at ∼100 and ∼80 ka that were higher than is the case in far-field regions, distant from large continental ice sheets. During MIS 5e time, sea surface temperatures (SSTs) off the Pacific coast of North America were higher than is the case at present, evident from extralimital southern species of mollusks found in dated deposits. Apparently, no wholesale shifts in faunal provinces took place, but in MIS 5e time, some species of bivalves and gastropods lived hundreds of kilometers north of their present northern limits, in good agreement with SST estimates derived from foraminiferal records and alkenone-based reconstructions in deep-sea cores. Because many areas of the Pacific coast of North America have been active tectonically for much or all of the Quaternary, many earlier interglacial periods are recorded as uplifted, higher-elevation terraces. In addition, from southern Oregon to northern Baja California, there are U-series-dated corals from marine terraces that formed at ∼80 ka, during MIS 5a. In contrast to MIS 5e, these terrace deposits host molluscan faunas that contain extralimital northern species, indicating cooler SST at the end of MIS 5. Here I present a review and standardized database of MIS 5e sea-level indicators along the Pacific coast of North America and the corresponding dated samples. The database is available in Muhs et al. (2021b; https://doi.org/10.5281/zenodo.5903285 ).

Earth System Science Data↗

The use of fluorite geochemistry and machine learning to identify critical mineral systems

Fluorite (CaF 2 ) is a potential pathfinder to critical mineral and rare earth element (REE) deposits but its application has been limited to a narrow range of mineralization types. I show that fluorite is a robust recorder of mineralization fertility by applying statistical and machine-learning methods to a new global fluorite geochemical database. Distinct median rare earth and trace element patterns are observed among deposit types and genetic environments. Fluorite associated with carbonatites and REE deposits are relatively enriched in Sr and have minimal Eu anomalies. These characteristics define new bivariate discrimination diagrams that correctly identify 78% of carbonatite-related fluorite and 88% of fluorite from REE deposits. Random forest classifiers were developed for a wide range of mineralization types and genetic settings. Trained solely on rare earth element patterns, these models achieve accuracies of 77–79%. Higher classification accuracies (up to 88–96%) are obtained when including elements such as Sr, highlighting the significance of trace elements for optimal fluorite classification. The recognition of diagnostic fluorite compositional fingerprints, particularly in REE-fertile systems, underscores its potential as a pathfinder and indicator for critical mineral exploration in F-bearing environments.

Mineralium Deposita↗

The record of major quaternary sea-level changes in a large coastal plain estuary, Chesapeake Bay, Eastern United States

Seismic-reflection surveys of the Chesapeake Bay, combined with geologic mapping and analysis of boreholes on the Delmarva Peninsula, provide evidence of at least three generations of the Susquehanna River system and three generations of the Chesapeake Bay. The evidence for ancient courses of the Susquehanna River is preserved as three distinct paleochannels, and evidence for ancient versions of the Chesapeake Bay is preserved as three sets of paleochannel fill beneath the bay and three generations of barrier-spit deposits on the southern Delmarva Peninsula. The paleochannels represent relative sea-level minima and the channel-fill and barrier-spit deposits represents relative sea-level maxima. A history of three major marine transgressions is recorded in the stratigraphy preserved in the filled paleochannels and in the overlying barrier-spit complexes: three systematic progressions from fluvial to estuarine to bay or nearshore marine environments. This sea-level record seems to be compatible with the saw-toothed pattern of the marine oxygen-isotope record and with the concept of glacial-interglacial terminations. It also seems to have a climax character in which most of the preserved evidence is related to the largest terminations and to the extreme sea-level positions that bound those terminations. The three paleochannel-fill and barrier-spit complexes appear to correspond to oxygen-isotope stages 1,5, and either 7 or 11; the three related paleochannels correspond to stages 2, 6, and either 8 or 12.

Delaware, Maryland, Virginia↗

Critical shallow and deep hydrologic conditions associated with widespread landslides during a series of storms between February and April 2018 in Pittsburgh and vicinity, western Pennsylvania, USA

The potential for widespread landslides is generally increased when extraordinary wet periods occur during times of elevated subsurface hydrologic conditions. A series of storms in early 2018 in Pittsburgh, Pennsylvania, overlapped with a period of increased shallow soil moisture and rising bedrock groundwater levels resulting from seasonally diminished evapotranspiration and induced widespread landslides in the region. Most of the landslides were shallow slope failures in colluvium, landslide deposits, and/or fill. However, deep-seated landslide activity also occurred and corresponded with record cumulative precipitation from late February to April and bedrock groundwater levels rising to an annual high. Landslides blocked or damaged roads, adversely affected multiple houses, disrupted electrical service, crushed vehicles, and resulted in considerable economic losses. The initial landslides occurred during or immediately after a rare period of three successive days of heavy rain that began on February 14. Subsequent landslides between late February and April were induced by multiday storms with smaller rainfall totals. As shallow soil moisture at a monitoring site rose above a volumetric water content of 32%, the mean rainfall intensities necessary to induce slope failure in colluvium and other surficial deposits decreased. Deep-seated landslide movement occurred in the region mostly when the groundwater level in a bedrock observation well was shallower than 1.7 m. The availability of hydrologic and landslide movement monitoring data during this extraordinary series of storms highlighted the evolution of the landslide hazard with changing moisture conditions and yielded insights into potential hydrologic criteria for anticipating future widespread landslides in the region.

Pennsylvania↗

Fluid evolution and timing of the Stibnite-Yellow Pine district, Idaho

Gold, antimony, and tungsten resources of the Stibnite-Yellow Pine district, Idaho, are hosted in complexly faulted Late Cretaceous Atlanta Lobe of the Idaho batholith and surrounding Neoproterozoic-Paleozoic metamorphic rocks. This study utilizes detailed petrography and trace element chemistry of quartz to establish relative timing relationships between successive ore forming events and provide textural constraints for the interpretation of geochronologic data. Textures are discussed in the context of fluid inclusion populations that provide evidence into the P-T-X evolution of the hydrothermal system. Results reveal that the deposits contain multiple overprinting generations of hydrothermal quartz, each with distinct cathodoluminescence (CL) signature, trace element chemistry, and fluid inclusion populations. Quartz textures record a complex history of recrystallization, dissolution, and successive overgrowth as fluids evolved towards lower temperatures and CO2 contents. Quartz associated with the main stage of Au deposition contains relatively high concentrations of Ti, with low concentrations of all other elements measured. Later quartz generations are depleted in Ti, but show elevated Al concentrations, with significant concentrations of Sb measured in quartz associated with stibnite. Textural and geochemical evidence suggests that the system evolved from deeper mesozonal Au-W deposition towards more shallow epizonal Sb-(Ag) deposition during a period of rapid uplift.

Idaho↗

Geologic history of sea water: An attempt to state the problem

Paleontology and biochemistry together may yield fairly definite information, eventually, about the paleochemistry of sea water and atmosphere. Several less conclusive lines of evidence now available suggest that the composition of both sea water and atmosphere may have varied somewhat during the past; but the geologic record indicates that these variations have probably been within relatively narrow limits. A primary problem is how conditions could have remained so nearly constant for so long. It is clear, even from inadequate data on the quantities and compositions of ancient sediments, that the more volatile materials—H 2 O, CO 2 , Cl, N, and S— are much too abundant in the present atmosphere, hydrosphere, and biosphere and in ancient sediments to be explained, like the commoner rock-forming oxides, as the products of rock weathering alone. If the earth were once entirely gaseous or molten, these “excess” volatiles may be residual from a primitive atmosphere. But if so, certain corollaries should follow about the quantity of water dissolved in the molten earth and the expected chemical effects of a highly acid, primitive ocean. These corollaries appear to be contradicted by the geologic record, and doubt is therefore cast on this hypothesis of a dense primitive atmosphere. It seems more probable that only a small fraction of the total “excess” volatiles was ever present at one time in the early atmosphere and ocean. Carbon plays a significant part in the chemistry of sea water and in the realm of living matter. The amount now buried as carbonates and organic carbon in sedimentary rocks is about 600 times as great as that in today's atmosphere, hydrosphere, and biosphere. If only 1/100 of this buried carbon were suddenly added to the present atmosphere and ocean, many species of marine organisms would probably be exterminated. Furthermore, unless CO 2 is being added continuously to the atmosphere-ocean system from some source other than rock weathering, the present rate of its subtraction by sedimentation would, in only a few million years, cause brucite to take the place of calcite as a common marine sediment. Apparently, the geologic record shows no evidence of such simultaneous extinctions of many species nor such deposits of brucite. Evidently the amount of CO 2 in the atmosphere and ocean has remained relatively constant throughout much of the geologic past. This calls for some source of gradual and continuous supply, over and above that from rock weathering and from the metamorphism of older sedimentary rocks. A clue to this source is afforded by the relative amounts of the different “excess” volatiles. These are similar to the relative amounts of the same materials in gases escaping from volcanoes, fumaroles, and hot springs and in gases occluded in igneous rocks. Conceivably, therefore, the hydrosphere and atmosphere may have come almost entirely from such plutonic gases. During the crystallization of magmas, volatiles such as H 2 O and CO 2 accumulate in the remaining melt and are largely expelled as part of the final fractions. Volcanic eruptions and lava flows have brought volatiles to the earth's surface throughout the geologic past; but intrusive rocks are probably a much more adequate source of the constituents of the atmosphere and hydrosphere. Judged by the thermal springs of the United States, hot springs (carrying only 1 per cent or less of juvenile matter) may be the principal channels by which the “excess” volatiles have escaped from cooling magmas below. This mechanism fails to account for a continuous supply of volatiles unless it also provides for a continuous generation of new, volatile-rich magmas. Possibly such local magmas form by a continuous process of selective fusion of subcrustal rocks, to a depth of several hundred kilometers below the more mobile areas of the crust. This would imply that the volume of the ocean has grown with time. On this point, geologic evidence permits differences of interpretation; the record admittedly does not prove, but it seems consistent with, an increasing growth of the continental masses and a progressive sinking of oceanic basins. Perhaps something like the following mechanism could account for a continuous escape of volatiles to the earth's surface and a relatively uniform composition of sea water through much of geologic time: (1) selective fusion of lower-melting fractions from deep-seated, nearly anhydrous rocks beneath the unstable continental margins and geosynclines; (2) rise of these selected fractions (as granitic and hydrous magmas) and their slow crystallization nearer the surface; (3) essentially continuous isostatic readjustment between the differentiating continental masses and adjacent ocean basins; and (4) renewed erosion and sedimentation, with resulting instability of continental margins and mountainous areas and a new round of selective fusion below.

Geological Society of America Bulletin↗

Geohydrology of the lower Verdigris River valley between Muskogee and Catoosa, Oklahoma

Alluvium is the principal aquifer along the Verdigris River between Muskogee and Catoosa, Okla. Yields of 1 to 10 gallons of water per minute, adequate for most domestic and stock uses, are available in almost all areas underlain by alluvium. In places where the proportion of gravel to fine material is high, yields ranging from 10 to 30 gallons per minute are possible from large-diameter wells. Terrace deposits yield small amounts of water (1 to 10 gallons per minute), adequate for most domestic and stock uses. Water-level fluctuations, in response to seasonal changes in recharge and discharge, range from 1 to 5 feet. Long-term fluctuations, measured as changes in seasonal high or low water levels during 8 years of record, are about 10 feet in the alluvium and less than 5 feet in the terrace deposits. Recharge to the alluvium is mainly by precipitation. Recharge maintains groundwater levels above the level of the Verdigris River, which, in turn, is the natural drain of the aquifer. Discharge from the alluvium is by seepage into the river and its tributaries and by evapotranspiration. Generally, the quality of the water in the alluvium and terrace deposits is suitable for domestic, stock, and irrigation uses.

Water Supply Paper↗

Preliminary geologic map of the San Fernando 7.5' quadrangle, southern California: A digital database

The city of San Fernando sits atop a structurally complex, sedimentologically diverse, and tectonically evolving late Tertiary-Quaternary basin situated within the Transverse Ranges of southern California. The surrounding San Fernando Valley (SFV) contains the headwaters of the Los Angeles River and its tributaries. Prior to the advent of flood control, the valley floor was composed of active alluvial fans and floodplains. Seasonal streams emanating from Pacoima and Big Tujunga Canyons drain the complex western San Gabriel Mountains and deposit coarse, highly permeable alluvium that contains generally high-quality ground water. The more shallow western part derives mainly from Tertiary and pre-Tertiary sedimentary rocks, and is underlain by less permeable, fine-grained deposits containing persistent shallow ground water and poorer water quality. Home of the 1971 San Fernando and the 1994 Northridge earthquakes, the SFV experienced near-record levels of strong ground motion in 1994 that caused widespread damage from strong shaking and ground failure. A new map of late Quaternary deposits of the San Fernando area shows that the SFV is a structural trough that has been filled from the sides, with the major source of sediment being large drainages in the San Gabriel Mountains. Deposition on the major alluvial fan of Tujunga Wash and Pacoima Wash, which issues from the San Gabriel Mountains, and on smaller fans, has been influenced by ongoing compressional tectonics in the valley. Late Pleistocene deposits have been cut by active faults and warped over growing folds. Holocene alluvial fans are locally ponded behind active uplifts. The resulting complex pattern of deposits has a major effect on liquefaction hazards. Young sandy sediments generally are highly susceptible to liquefaction where they are saturated, but the distribution of young deposits, their grain size characteristics, and the level of ground water all are complexly dependent on the tectonics of the valley. The San Fernando area lies on the southern slopes of the San Gabriel Mountains. The basement rocks here include high-grade metamorphic rocks of Precambrian age. The mountains are largely composed of crystalline basement that includes the Pelona Scist of probable Mesozoic age that has been overthrust by Precambrian gneisses; the gneisses were subsequently intruded by Mesozoic plutons prior to overthrusting along the latest Cretaceous Vincent thrust. Gneisses of somewhat variable composition and possibly varying ages are found in four terranes, but not all are in contact with Pelona Schist. Large tracts of Precambrian (1.2 billion years old) andesine anorthosite are intrusive into 1.7 billion year-old Mendenhall gneiss, and are found in the western part of the San Gabriels. Mixed with these are younger marble, limestone, and schist of possible Paleozoic age found in association with plutons along the southern margin of the range. The older rocks are intruded by diorite, quartz diorite, and granodiorite of Jurassic age. Also present are siliceous sedimentary rocks of Jurassic age. A thick section of Tertiary sedimentary and volcanic rocks overlie these units. The sediments located south of the San Gabriel Fault are totally different in character from those on the northern range flank, and mostly resemble the western Transverse Ranges due to their deposition in the southeastern Ventura basin; approximately 3,000 m of these sediments are exposed north and west of the city of San Fernando in the Tujunga syncline. Some of the Tertiary rocks are Paleocene and Eocene in age, but the bulk of these rocks are Oligocene and Miocene in age. The Vasquez and Sespe Formations of basal basaltic volcanic and sandstone are Oligocene and lower Miocene in age. These are overlain by clastic rocks of Tick Canyon and Mint Canyon Formations of middle to late Miocene age. Above these rocks are the Castaic, Modelo, and Santa Margarita Formations of fossiliferous marine shale, sand

California↗

Multiple hydrothermal and metamorphic events in the Kidd Creek volcanogenic massive sulphide deposit, Timmins, Ontario: evidence from tourmalines and chlorites

Tourmaline and chlorite are the principal ferromagnesian silicate minerals in the Kidd Creek massive sulphide deposit. Tourmaline is most common in sphalerite-rich peripheral margins of the chalcopyrite stringer zone. Within the north orebody, samples typically contain <1% tourmaline, but small areas (hand-specimen scale) may have 10–20%. Chlorite is more widely distributed and in places constitutes 30–50% of rock volumes. Associated assemblages may include quartz, sulphides (principally chalcopyrite, sphalerite, and (or) pyrite), carbonate, albite, sericite, and rare fluorite, allanite, or zoisite(?).The tourmalines and chlorites record a series of multiple hydrothermal and metamorphic events. Paragenetic studies suggest that tourmaline was deposited during several discrete stages of mineralization, as evidenced by brecciation and cross-cutting relationships. Most of the tourmalines have two concentric growth zones defined by different colours (green, brown, blue, yellow). Some tourmalines also display pale discordant rims that cross-cut and embay the inner growth zones and polycrystalline, multiple-extinction domains. Late sulphide veinlets (chalcopyrite, pyrrhotite) transect the inner growth zones and pale discordant rims of many crystals. The concentric growth zones are interpreted as primary features developed by the main ore-forming hydrothermal system, whereas the discordant rims, polycrystalline domains, and cross-cutting sulphide veinlets reflect post-ore metamorphic processes.Detailed electron microprobe analyses of tourmalines show a wide compositional range, from Fe-rich dravite nearly to end-member schorl, with Fe/(Fe + Mg) ratios varying from 0.33 to 0.92; only minor amounts of Ca are present, yielding uniformly high Na/(Na + Ca) ratios of 0.84–0.99. Two sets of chemical zoning trends are identified in the tourmalines, involving systematic changes in Fe/(Fe + Mg), Na/(Na + Ca), Al, and Ti that are believed to reflect internal coupled substitutions (e.g.,  + Ti = Na + Al) and local mineral equilibria (e.g., tourmaline–chlorite). Analyses of the pale discordant reaction rims show consistent depletion of Fe, Ca, and Ti, presumably by fluid–solid reactions during post-ore metamorphism.Chlorites also show an extensive range in composition, from ripidolite nearly to end-member daphnite, with Fe/(Fe + Mg) ratios of 0.43–0.98 and Si cation values of 5.00–5.39. Chlorites from the fringes of the footwall stringer zone have narrow compositional ranges, whereas chlorites near footwall rhyolite sills in the core of the stringer zone display major variations in Fe/(Fe + Mg) ratios, including one sample with a range of 0.68–0.95. The former group of chlorites has Fe/(Fe + Mg) ratios that correlate well with those of coexisting tourmalines (exclusive of late reaction rims). Data for the latter group, in contrast, fall off equilibrium K D curves, indicating that the tourmalines and chlorites within these samples are not in chemical equilibrium. The chlorites are believed to have been altered (overprinted) by Fe-rich hydrothermal fluids apparently generated during intrusion of the rhyolite sills. The tourmalines, however, are unaffected and retain primary chemical signatures.Variations in mineral proportions and mineral chemistry within the deposit mainly depend on fluctuations in temperature, pH, water/rock ratios, and amounts of entrained seawater. The major proposed control is mixing between high-temperature, Fe-rich end-member hydrothermal fluids and cold, Mg-rich entrained seawater. Fe/(Fe + Mg) variations in footwall tourmalines (and equilibrium chlorites) are believed to largely reflect the progressive infiltration of Mg-rich seawater into the margins and top of the hydrothermal system. The more Fe-rich compositions of Kidd Creek tourmalines relative to those from sediment-hosted massive sulphide deposits (e.g., Sullivan, British Columbia) may be related to the preferential generation of end-member hydrothermal fluids in proximal volcanic environments like that at Kidd Creek.

Ontario↗