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At least 631 records · Page 35Linked to original sources

Origins of seawater intrusion in a coastal aquifer - A case study of the Pajaro Valley, California

Seawater may enter and contaminate stratified coastal aquifers through a number of different pathways. These pathways and their relative contribution are examined in the Pajaro Valley, California, a coastal area with extensive groundwater development. This study considers three pathways of possible intrusion of the primary confined aquifer: (1) onshore leakage from brackish sources, the estuary and sloughs, through the confining layer; (2) near-shore leakage from the ocean through the confining layer; and (3) offshore flow from the ocean through the submarine canyon outcrop of the aquifer. Groundwater flow and seawater intrusion are simulated using an areal, two-dimensional solute-transport computer model. This analysis indicates that leakage through confining layers is the principal mechanism of recharge to the aquifer. Although lateral flow through the offshore outcrop contaminates the aquifer, as a whole, at a higher rate, vertical leakage through the sea floor initially is the main pathway of seawater intrusion to the onshore portion of the aquifer. It is likely that leakage generally is the dominant mechanism of recharge and initial cause of seawater intrusion for poorly-confined, stratified coastal aquifers. This analysis suggests that a significant time interval follows the initial observation of seawater intrusion, during which remedial action can be taken to control lateral flow through the offshore outcrop, which ultimately will be the largest component of future intrusion in these aquifers.

California↗

Ground-water resource assessment of the Montauk area, Long Island, New York

The water resources of the Montauk area were investigated from October 1980 through September 1983 to assess the availability of fresh groundwater. The principal aquifer, which consists of fine- to coarse-grained stratified glacial drift, is the sole source of freshwater. The freshwater/saltwater interface lies as much as 150 ft below sea level, but the till unit and the marine-clay unit limit the thickness of the zone from which freshwater may easily be withdrawn to < 100 ft in most places. Precipitation, the sole source of freshwater in the Montauk area , averages about 42 in/yr. Direct runoff is approximately 1 in/yr, and evapotranspiration about 20 in/yr; the remaining 21 inches is the net recharge to the principal aquifer. The horizontal hydraulic conductivity, as calculated from specific-capacity data, ranges from 130 to 350 ft/d. Analysis of an aquifer pumping test indicates that horizontal hydraulic conductivity of the principal aquifer is approximately 275 ft/d and the vertical hydraulic conductivity is approximately 90 ft/d; the storage coefficient ranges from 1.1 x .001 to 2.2 x .001. A numerical two-dimensional flow model that simulates the areal flow of fresh- and saltwater was developed to evaluate the effects of the present level of groundwater development and the potential effects of increased future withdrawals. Model results indicate that the principal aquifer is capable of producing several times more than the 0.6 mil gal/d now being withdrawn for public supply. Examination of well design and pumping rates, and analysis of analog-model studies of saltwater upconing to wells, indicate that the peak pumping rate of public supply wells exceeds the limit necessary to avoid contamination from saltwater. With proper well design and distribution of pumping stress, the aquifer system would be capable of supplying enough water to meet the needs of the population projected through 1995.

New York↗

Geochemistry of tectonically expelled fluids from the northern Coast ranges, Rumsey Hills, California, USA

Tectonic compression has created abnormally high pressure on deep basinal fluids causing their expulsion from areally exposed Upper Cretaceous rock along the eastern margin of the California Coast ranges. The fluids emerge as near-neutral, perennial sodium chloride springs at high elevations with flow rates as high as 10 L per min. Higher spring discharges are more common around the exposure of a west-vergent fault propagation fold axis. Spring waters range from ~1000 to 27,000 mg/L TDS. The least saline water ( &#x3B4; 18 O = &#x2212;7.5&#x2030; "> δ 18 O = −7.5‰ ) closely represents local meteoric water that mixes with saline fluid ( &#x3B4; 18 O = +5.3&#x2030; "> δ 18 O = +5.3‰ ) and forms a slope of ~3.5 on a δD vs. δ 18 O plot. A Na (125 to 8000 mg/L) vs. Cl (150 to 17,000 mg/L) plot shows a linear dilution trend that extends close to, but below, the values for modern seawater. Calcium (75–3000 mg/L) is considerably enriched relative to seawater and forms a nonlinear trend with chloride. In detail, the “Na deficit,” defined by the difference between the measured Na content and the Na concentration on a hypothetical seawater dilution line, is approximately balanced by the Ca excess, similarly defined by the seawater dilution line. This relationship strongly suggests that the fluid is diluted seawater that is being modified by active albitization of plagioclase at different depths. Simultaneous B and 18 O enrichment of the fluids, accompanied by deuterium depletion, further suggest that the seawater modification is influenced by clay diagenesis. Bicarbonate and SiO 2 concentrations show an inverse correlation with Cl, with most waters being saturated or slightly oversaturated with calcite and quartz at the discharge temperatures. Some freshwater springs with near-meteoric stable isotope values may represent mixing of young groundwater from perched aquifers, but in many cases, the freshwater springs emerge along the same structures and have the same perennial nature as the saline fluids, and expulsion of an older fresh groundwater component that is under abnormal fluid pressures cannot be ruled out. Basinal fluids elsewhere commonly show dilution trends with local meteoric water, and in the case of the Rumsey Hills, some of the dilute saline waters may indicate deep penetration of meteoric water (> 1 km) in the Pleistocene before the latest tectonic uplift. Geothermometry of the spring waters (maximum ~90°C) suggest an origin from as deep as 4.0 km. This depth is consistent with the depth of the core of a fault propagation anticline below the surface of the Rumsey Hills developed by active internal deformation of an east-tapering wedge beneath the southwestern Sacramento Valley. Active tectonic compression causes near-lithostatic fluid pressures in the shallow subsurface below the Rumsey Hills and volume strain within the core of the anticline that results in upward expulsion of the saline fluids from the indicated depths.

California↗

Assessment of the quality of groundwater and the Little Wind River in the area of a former uranium processing facility on the Wind River Reservation, Wyoming, 1987 through 2010

In 2010, the U.S Geological Survey (USGS), in cooperation with the Wind River Environmental Quality Commission (WREQC), began an assessment of the effectiveness of the existing monitoring network at the Riverton, Wyoming, Uranium Mill Tailings Remedial Action (UMTRA) site. The USGS used existing data supplied by the U.S. Department of Energy (DOE). The study was to determine (1) seasonal variations in the direction of groundwater flow in the area of the former uranium processing facility toward the Little Wind River, (2) the extent of contaminated groundwater among the aquifers and between the aquifers and the Little Wind River, (3) whether current monitoring is adequate to establish the effectiveness of natural attenuation for the contaminants of concern, and (4) the influence of groundwater discharged from the sulfuric-acid plant on water quality in the Little Wind River.

Wyoming↗

Submarine groundwater discharge to Tampa Bay: Nutrient fluxes and biogeochemistry of the coastal aquifer

To separately quantify the roles of fresh and saline submarine groundwater discharge (SGD), relative to that of rivers, in transporting nutrients to Tampa Bay, Florida, we used three approaches (Darcy's Law calculations, a watershed water budget, and a 222 Rn mass-balance) to estimate rate of SGD from the Pinellas peninsula. Groundwater samples were collected in 69 locations in the coastal aquifer to examine biogeochemical conditions, nutrient concentrations and stoichiometry, and salinity structure. Salinity structure was also examined using stationary electrical resistivity measurements. The coastal aquifer along the Pinellas peninsula was chemically reducing in all locations sampled, and that condition influences nitrogen (N) form and mobility of N and PO 4 3− . Concentrations of NH 4 + , PO 4 3− and ratio of dissolved inorganic N (DIN) to PO 4 3− were all related to measured oxidation/reduction potential (pε) of the groundwater. Ratio of DIN: PO 4 3− was below Redfield ratio in both fresh and saline groundwater. Nitrogen occurred almost exclusively in reduced forms, NH 4 + and dissolved organic nitrogen (DON), suggesting that anthropogenic N is exported from the watershed in those forms. In comparison to other SGD studies, rate of PO 4 3− flux in the seepage zone (μM m − 2 d − 1 ) in Tampa Bay was higher than previous estimates, likely due to 1) high watershed population density, 2) chemically reducing conditions, and 3) high ion concentrations in fresh groundwater. Estimates of freshwater groundwater flux indicate that the ratio of groundwater discharge to stream flow is ∼ 20 to 50%, and that the magnitudes of both the total dissolved nitrogen and PO 4 3− loads due to fresh SGD are ∼ 40 to 100% of loads carried by streams. Estimates of SGD based on radon inventories in near-shore waters were 2 to 5 times greater than the estimates of freshwater groundwater discharge, suggesting that brackish and saline SGD is also an important process in Tampa Bay and results in flux of regenerated N and P from sediment to surface water.

Florida↗

A steady-state groundwater flow model for the Des Moines River alluvial aquifer near Prospect Park, Des Moines, Iowa

The Des Moines River alluvial aquifer is an important source of water for Des Moines Water Works, the municipal water utility that provides residential and commercial water resources to the residents of Des Moines, Iowa, and surrounding municipalities. As an initial step in developing a better understanding of the groundwater resources of the Des Moines River alluvial aquifer, the U.S. Geological Survey constructed a steady-state numerical groundwater flow model in cooperation with Des Moines Water Works to simulate water-table elevations in the Des Moines River alluvial aquifer near Prospect Park in Des Moines under winter low-flow conditions. A simple conceptual model consisting of a hydrogeologic framework, water budget, and inferred water-table elevation map was developed for the model area. The inferred water-table elevation map was constructed based on general knowledge of hydrogeology within the model area and was used to set calibration targets for numerical model calibration. A steady-state numerical model was constructed based on the conceptual model using MODFLOW-NWT to simulate an area of about 15 square kilometers near Prospect Park in Des Moines. Parameter ESTimation software was used for model calibration to assess and optimize performance of the horizontal hydraulic conductivity and recharge parameters. The numerical groundwater flow model and supporting data are available in the USGS data release associated with this report, which contains the model archive. Performance of the calibrated steady-state model was assessed by comparing observed and simulated water-table elevations, as well as estimated and simulated contributions to streamflow within the model area. The difference between observed water-table elevations and simulated water-table elevations was −0.1 meter at the majority of calibration targets, with the negative value indicating an overestimation of the simulated water-table elevation value compared to the observed water-table elevation value, and the root mean square error was 0.13 meter, which represents about 20 percent of the difference in observed water-table elevations. The simulated value of contributions to streamflow within the model area was considered similar to the estimated value, increasing confidence in the ability of the model to accurately represent the groundwater flow system in the Des Moines River alluvial aquifer in the model area during winter low-flow conditions.

Iowa↗

Acetylene-fueled trichloroethene reductive dechlorination in a groundwater enrichment culture

In aquifers, acetylene (C 2 H 2 ) is a product of abiotic degradation of trichloroethene (TCE) catalyzed by in situ minerals. C 2 H 2 can, in turn, inhibit multiple microbial processes including TCE dechlorination and metabolisms that commonly support dechlorination, in addition to supporting the growth of acetylenotrophic microorganisms. Previously, C 2 H 2 was shown to support TCE reductive dechlorination in synthetic, laboratory-constructed cocultures containing the acetylenotroph Pelobacter sp. strain SFB93 and Dehalococcoides mccartyi strain 195 or strain BAV1. In this study, we demonstrate TCE and perchloroethene (PCE) reductive dechlorination by a microbial community enriched from contaminated groundwater and amended with C 2 H 2 as the sole electron donor and organic carbon source. The metagenome of the stable, enriched community was analyzed to elucidate putative community functions. A novel anaerobic acetylenotroph in the phylum Actinobacteria was identified using metagenomic analysis. These results demonstrate that the coupling of acetylenotrophy and reductive dechlorination can occur in the environment with native bacteria and broaden our understanding of biotransformation at contaminated sites containing both TCE and C 2 H 2 .

mBio↗

Probability of Elevated Volatile Organic Compound (VOC) Concentrations in Groundwater in the Eagle River Watershed Valley-Fill Aquifer, Eagle County, North-Central Colorado, 2006-2007

This raster data set delineates the predicted probability of elevated volatile organic compound (VOC) concentrations in groundwater in the Eagle River watershed valley-fill aquifer, Eagle County, North-Central Colorado, 2006-2007. This data set was developed by a cooperative project between the U.S. Geological Survey, Eagle County, the Eagle River Water and Sanitation District, the Town of Eagle, the Town of Gypsum, and the Upper Eagle Regional Water Authority. This project was designed to evaluate potential land-development effects on groundwater and surface-water resources so that informed land-use and water management decisions can be made. This groundwater probability map and its associated probability maps was developed as follows: (1) A point data set of wells with groundwater quality and groundwater age data was overlaid with thematic layers of anthropogenic (related to human activities) and hydrogeologic data by using a geographic information system to assign each well values for depth to groundwater, distance to major streams and canals, distance to gypsum beds, precipitation, soils, and well depth. These data then were downloaded to a statistical software package for analysis by logistic regression. (2) Statistical models predicting the probability of elevated nitrate concentrations, the probability of unmixed young water (using chlorofluorocarbon-11 concentrations and tritium activities), and the probability of elevated volatile organic compound concentrations were developed using logistic regression techniques. (3) The statistical models were entered into a GIS and the probability map was constructed.

Data Series↗

Groundwater/surface-water interactions and sources of nitrogen and uranium in an irrigated area of Nebraska, USA

The effects of irrigation canals and the North Platte River on groundwater in western Nebraska, USA, were evaluated using chemical and isotopic data. The data indicated that groundwater in the associated alluvium generally is <20 years old with estimated recharge rates from about 10 to >100 cm year -1 . Most groundwater is derived from surface water, as shown by H 2 O and U isotope analyses. Seasonal losses of canal water to the aquifer cause changes in groundwater quality. In the deepest parts of the alluvium, some water quality may reflect precipitation recharge, older river water, or cross-formational flow. The distribution and isotopic composition of NO 3 - are consistent with increased fertilizer use over time. Relatively high U concentrations in groundwater may be attributed to dissolution of volcanic ash or other minerals in underlying bedrocks. The relatively high concentration of U in surface water at times is attributed to seepage from U-rich groundwater and flow of U-rich surface water from a tributary. The effects of irrigation canals and the North Platte River on groundwater in western Nebraska, USA, were evaluated using chemical and isotopic data. The data indicated that groundwater in the associated alluvium generally is <20 years old with estimated recharge rates from about 10 to >100 cm year -1 . Most groundwater is derived from surface water, as shown by H 2 O and U isotope analyses. Seasonal losses of canal water to the aquifer cause changes in groundwater quality. In the deepest parts of the alluvium, some water quality may reflect precipitation recharge, older river water, or cross-formational flow. The distribution and isotopic composition of NO 3 - are consistent with increased fertilizer use over time. Relatively high U concentrations in groundwater may be attributed to dissolution of volcanic ash or other minerals in underlying bedrock. The relatively high concentration of U in surface water at times is attributed to seepage from U-rich groundwater and flow of U-rich surface water from a tributary.

IAHS-AISH Publication↗

Groundwater observation network design for the Kansas groundwater management districts, U.S.A.

Concerns about the efficiency and economic soundness of the Kansas groundwater monitoring program led to a systematic redesign of this network, a tentative phase of which is presented in this study. The objectives of this paper include monitoring of major aquifers within each groundwater management district at a spatially more uniform level of accuracy, elimination of redundant measurements and optimization of the information gained from each observation well. The theory of regionalized variables is employed to estimate the amount of spatial variability of the water table, on which the network design is based. This study shows that it is not practical to attempt to reduce the already existing level of uncertainty uniformly throughout the various districts; to do so would tremendously increase the cost of well monitoring, which is already very high. Assuming that the currently existing network is satisfactory for the State's objectives, a reduced network consisting of one well every 6.4 km is equally satisfactory. The reduced network yields district-wide maps that do not differ significantly from those produced using the present network and at the same time it reduces the already-existing network by 18–47%. Therefore, adoption of a rearranged square well network is recommended, which is reduced to a 6.4-km spacing to achieve both a uniform level of information about the water table and a minimum required accuracy.

Kansas↗

Geology and hydrogeology of the Caribbean Islands aquifer system of the Commonwealth of Puerto Rico and the U.S. Virgin Islands

Poorly lithified to unconsolidated carbonate and clastic sedimentary rocks of Tertiary (Oligocene to Pliocene) and Quaternary (Pleistocene to Holocene) age compose the South Coast aquifer and the North Coast limestone aquifer system of Puerto Rico; poorly lithified to unlithified carbonate rocks of late Tertiary (early Miocene to Pliocene) age make up the Kingshill aquifer of St. Croix, U.S. Virgin Islands. The South Coast aquifer, North Coast limestone aquifer system, and Kingshill aquifer are the most areally extensive and function as the major sources of ground water in the U.S. Caribbean Islands Regional Aquifer-System Analysis (CI-RASA) study area. In Puerto Rico's South Coast ground-water province, more than 1,000 meters of clastic and carbonate rocks of Oligocene to Pliocene age infill the South Coast Tertiary Basin. The pattern of lithofacies within this basin appears to have been controlled by changes in base level that were, at times, dominated by tectonic movement (uplift and subsidence), but were also influenced by eustasy. Deposition of the 70-kilometer long and 3- to 8-kilometer wide fan-delta plain that covers much of the South Coast ground-water province occurred largely in response to glacially-induced changes in sea level and climate during the Quaternary period. Tectonic movement played a much less important role during the Quaternary. The North Coast ground-water province of Puerto Rico is underlain by homoclinal coastal plain wedge of carbonate and siliciclastic rocks that infill the North Coast Tertiary Basin and thicken to more than 1,700 meters. A thin basal siliciclastic sequence of late Oligocene age is overlain by a thick section of mostly carbonate rocks of Oligocene to middle Miocene age. Globigerinid limestone of late Miocene to Pliocene age crops out and lies in the shallow subsurface areas of northwestern Puerto Rico. Oligocene to middle Miocene age rocks tentatively can be divided into five depositional sequences and associated systems tracts; these rocks record carbonate and minor siliciclastic deposition that occurred in response to changes in relative sea level. The Cibao Formation represents the most complex of these sequences and contains a varied facies of carbonate, mixed carbonate-siliciclastic, and siliciclastic rocks that reflect differential uplift, subsidence, and transgression of the sea. Uplift, graben formation, and gradual shallowing of the sea are reflected within the bathyal-dominated sedimentary facies of the Kingshill Limestone in St. Croix, U.S. Virgin Islands. Reef-tract limestone beds of Pliocene age were subject to exposure, resubmergence, and meteoric leaching of aragonitic skeletal debris; these beds contain patchy lenses of dolomite that are restricted to a small, structurally-controlled embayment. The South Coast aquifer, the principal water-bearing unit of Puerto Rico's South Coast ground-water province, consists of boulder- to silt-size detritus formed by large and small coalescing fan deltas of Pleistocene to Holocene age. Deep well data indicates that it is possible to vertically separate and group a highly complex and irregular-bedded detrital sequence that underlies distal parts of the fan-delta plain into discrete water-bearing units if correlated with 30- to 40-meter thick, eustatically-controlled depositional cycles. Lithofacies maps show that greatest hydraulic conductivity within the fan-delta plain is generally associated with proximal fan and midfan areas. Distal and interfan areas are least permeable. Alluvial valley aquifers located in the western part of the South Coast ground-water province are important local sources of water supply and appear to contain some of the same physical and hydraulic characteristics as the South Coast aquifer. Older sedimentary rocks within the basin are poor aquifers; conglomeratic beds are well-cemented, and carbonate beds do not contain well-developed solution features, except locally where the beds are overlain by alluvium. Ground-water occurs under unconfined conditions in proximal and midfan areas. Confined conditions within deeper parts of the system and in interfan and some midfan areas are created largely by the intercalated nature of discontinuous fine-grained beds that retard vertical ground-water movement. The development of water resources in southern Puerto Rico has modified the hydrologic system of the South Coast aquifer considerably. Under predevelopment conditions, the South Coast aquifer was recharged in the unconfined, proximal fan and some midfan areas by infrequent rainfall and seepage from streams near the fan apex. Discharge occurred as seabed seepage, baseflow discharge along the lower coastal reach of streams, seepage to coastal wetlands, or evapotranspiration in areas underlain by a shallow water table. Under development conditions, seepage from irrigation canals and areal recharge from furrow irrigation represented a principal mechanism for recharge to the aquifer. Increased ground-water withdrawals in the 1960's and 1970's resulted in declines in the water table to below sea level in some places and intrusion of salt water into the aquifer. By the middle 1980's, a reduction in ground-water withdrawals and a shift from furrow irrigation to drip-irrigation techniques resulted in the recovery of water levels. Under present-day (1986) conditions, regional ground-water flow is coastward but with local movement to some well fields. In addition to the discharge mechanisms described above, ground-water discharges also to coastal canals. The North Coast limestone aquifer system consists of limestone, lesser amounts of dolomite, and minor clastic detritus of Oligocene to Pliocene age that form an unconfined upper aquifer and a confined lower aquifer; these aquifers are separated by a clay, mudstone, and marl confining unit. Topographic relief and incision of carbonate coastal plain rocks by streams are the principal factors controlling the direction of ground-water flow. The North Coast limestone aquifer system is recharged principally by precipitation that enters the upper and lower aquifers where they crop out. Regional groundwater movement from the upper aquifer is to the major rivers, wells, coastal wetlands, coastal, nearshore, and offshore springs, or as seabed seepage. Regional discharge from the lower aquifer is to the major rivers along its unconfined parts or where the confining unit has been breached by streams. Discharge from the lower aquifer also occurs in the San Juan area where the Mucarabones Sand provides an avenue for diffuse upward ground-water flow. Transmissivity within the upper limestone aquifer appears to be largely regulated by the thickness of the freshwater lens. The lens is thickest and transmissivity is greatest in interstream areas that lie in a zone that closely corresponds to the landwardmost extent of the underlying saltwater wedge. Hydraulic conductivity of the upper aquifer generally increases in a coastward direction and reflects lithologic control, karstification in the upper 30 to 100 meters of the section, and enhanced permeability in a zone of freshwater and saltwater mixing. Transmissivity of the lower aquifer is an order of magnitude smaller than that of the upper aquifer; highest transmissivities in the lower aquifer largely correspond to a coarse grainstone-packstone and coral-patch-reef depositional facies contained within the outcropping parts of the Montebello Limestone Member and its subsurface equivalents. Porosity within the North Coast limestone aquifer system is high in grainstone-packstones and low in wackestone and marl. Dolomitized zones and moldic grainstone-packstone strata are the most porous carbonate rocks, but occur in thin beds that usually are only a few meters thick. Processes of karstification that include the development of caverous zones and large vugs, and dissolution along possible regional fracture sets has enhanced permeability within the upper part of the aquifer system. Stratigraphic and lithologic control play an important role controlling permeability within the lower part of the system. The Kingshill aquifer of St. Croix, in large part, is composed of deepwater limestone that contains only microscopic pores and is poorly permeable; however, the upper part of the aquifer, a shallow-water skeletal and reef limestone, is fairly permeable, but restricted in areal extent. Permeability within these uppermost beds of the aquifer has been enhanced by meteoric leaching, dissolution within a mixing zone of saltwater and fresh water, and dolomitization. However, most large-yield wells completed in the Kingshill aquifer are also screened in alluvium that overlies or infills incised channels. The alluvial deposits serve as a temporary storage zone for rainfall, runoff, and ground water slowly entering the Kingshill aquifer.

Puerto Rico↗

Hydrology and numerical simulation of groundwater movement and heat transport in Snake Valley and surrounding areas, Juab, Miller, and Beaver Counties, Utah, and White Pine and Lincoln Counties, Nevada

Snake Valley and surrounding areas, along the Utah-Nevada state border, are part of the Great Basin carbonate and alluvial aquifer system. The groundwater system in the study area consists of water in unconsolidated deposits in basins and water in consolidated rock underlying the basins and in the adjacent mountain blocks. Most recharge occurs from precipitation on the mountain blocks and most discharge occurs from the lower altitude basin-fill deposits mainly as evapotranspiration, springflow, and well withdrawals. The Snake Valley area regional groundwater system was simulated using a three-dimensional model incorporating both groundwater flow and heat transport. The model was constructed with MODFLOW-2000, a version of the U.S. Geological Survey’s groundwater flow model, and MT3DMS, a transport model that simulates advection, dispersion, and chemical reactions of solutes or heat in groundwater systems. Observations of groundwater discharge by evapotranspiration, springflow, mountain stream base flow, and well withdrawals; groundwater-level altitudes; and groundwater temperatures were used to calibrate the model. Parameter values estimated by regression analyses were reasonable and within the range of expected values. This study represents one of the first regional modeling efforts to include calibration to groundwater temperature data. The inclusion of temperature observations reduced parameter uncertainty, in some cases quite significantly, over using just water-level altitude and discharge observations. Of the 39 parameters used to simulate horizontal hydraulic conductivity, uncertainty on 11 of these parameters was reduced to one order of magnitude or less. Other significant reductions in parameter uncertainty occurred in parameters representing the vertical anisotropy ratio, drain and river conductance, recharge rates, and well withdrawal rates. The model provides a good representation of the groundwater system. Simulated water-level altitudes range over almost 2,000 meters (m); 98 percent of the simulated values of water-level altitudes in wells are within 30 m of observed water-level altitudes, and 58 percent of them are within 12 m. Nineteen of 20 simulated discharges are within 30 percent of observed discharge. Eighty-one percent of the simulated values of groundwater temperatures in wells are within 2 degrees Celsius (°C) of the observed values, and 55 percent of them are within 0.75 °C. The numerical model represents a more robust quantification of groundwater budget components than previous studies because the model integrates all components of the groundwater budget. The model also incorporates new data including (1) a detailed hydrogeologic framework, and (2) more observations, including several new water-level altitudes throughout the study area, several new measurements of spring discharge within Snake Valley which had not previously been monitored, and groundwater temperature data. Uncertainty in the estimates of subsurface flow are less than those of previous studies because the model balanced recharge and discharge across the entire simulated area, not just in each hydrographic area, and because of the large dataset of observations (water-level altitudes, discharge, and temperatures) used to calibrate the model and the resulting transmissivity distribution. Groundwater recharge from precipitation and unconsumed irrigation in Snake Valley is 160,000 acre-feet per year (acre-ft/yr), which is within the range of previous estimates. Subsurface inflow from southern Spring Valley to southern Snake Valley is 13,000 acre-ft/yr and is within the range of previous estimates; subsurface inflow from Spring Valley to Snake Valley north of the Snake Range, however, is only 2,200 acre-ft/yr, which is much less than has been previously estimated. Groundwater discharge from groundwater evapotranspiration and springs is 100,000 acre-ft/yr, and discharge to mountain streams is 3,300 acre-ft/yr; these are within the range of previous estimates. Current well withdrawals are 28,000 acre-ft/yr. Subsurface outflow from Snake Valley moves into Pine Valley (2,000 acre-ft/yr), Wah Wah Valley (23 acre-ft/yr), Tule Valley (33,000 acre-ft/yr), Fish Springs Flat (790 acre-ft/yr), and outside of the study area towards Great Salt Lake Desert (8,400 acre-ft/yr); these outflows, totaling about 44,000 acre-ft/yr, are within the range of previous estimates. The subsurface flow amounts indicate the degree of connectivity between hydrographic areas within the study area. The simulated transmissivity and locations of natural discharge, however, provide a better estimate of the effect of groundwater withdrawals on groundwater resources than does the amount and direction of subsurface flow between hydrographic areas. The distribution of simulated transmissivity throughout the study area includes many areas of high transmissivity within and between hydrographic areas. Increased well withdrawals within these high transmissivity areas will likely affect a large part of the study area, resulting in declining groundwater levels, as well as leading to a decrease in natural discharge to springs and evapotranspiration.

Nevada, Utah↗

Groundwater flow and water budget in the surficial and Floridan aquifer systems in east-central Florida

A numerical transient model of the surficial and Floridan aquifer systems in east-central Florida was developed to (1) increase the understanding of water exchanges between the surficial and the Floridan aquifer systems, (2) assess the recharge rates to the surficial aquifer system from infiltration through the unsaturated zone and (3) obtain a simulation tool that could be used by water-resource managers to assess the impact of changes in groundwater withdrawals on spring flows and on the potentiometric surfaces of the hydrogeologic units composing the Floridan aquifer system. The hydrogeology of east-central Florida was evaluated and used to develop and calibrate the groundwater flow model, which simulates the regional fresh groundwater flow system. The U.S. Geological Survey three-dimensional groundwater flow model, MODFLOW-2005, was used to simulate transient groundwater flow in the surficial, intermediate, and Floridan aquifer systems from 1995 to 2006. The east-central Florida transient model encompasses an actively simulated area of about 9,000 square miles. Although the model includes surficial processes-rainfall, irrigation, evapotranspiration, runoff, infiltration, lake water levels, and stream water levels and flows-its primary purpose is to characterize and refine the understanding of groundwater flow in the Floridan aquifer system. Model-independent estimates of the partitioning of rainfall into evapotranspiration, streamflow, and aquifer recharge are provided from a water-budget analysis of the surficial aquifer system. The interaction of the groundwater flow system with the surface environment was simulated using the Green-Ampt infiltration method and the MODFLOW-2005 Unsaturated-Zone Flow, Lake, and Streamflow-Routing Packages. The model is intended to simulate the part of the groundwater system that contains freshwater. The bottom and lateral boundaries of the model were established at the estimated depths where the chloride concentration is 5,000 milligrams per liter in the Floridan aquifer system. Potential flow across the interface represented by this chloride concentration is simulated by the General Head Boundary Package. During 1995 through 2006, there were no major groundwater withdrawals near the freshwater and saline-water interface, making the general head boundary a suitable feature to estimate flow through the interface. The east-central Florida transient model was calibrated using the inverse parameter estimation code, PEST. Steady-state models for 1999 and 2003 were developed to estimate hydraulic conductivity (K) using average annual heads and spring flows as observations. The spatial variation of K was represented using zones of constant values in some layers, and pilot points in other layers. Estimated K values were within one order of magnitude of aquifer performance test data. A simulation of the final two years (2005-2006) of the 12-year model, with the K estimates from the steady-state calibration, was used to guide the estimation of specific yield and specific storage values. The final model yielded head and spring-flow residuals that met the calibration criteria for the 12-year transient simulation. The overall mean residual for heads, defining residual as simulated minus measured value, was -0.04 foot. The overall root-mean square residual for heads was less than 3.6 feet for each year in the 1995 to 2006 simulation period. The overall mean residual for spring flows was -0.3 cubic foot per second. The spatial distribution of head residuals was generally random, with some minor indications of bias. Simulated average evapotranspiration (ET) over the 1995 to 2006 period was 34.5 inches per year, compared to the calculated average ET rate of 36.6 inches per year from the model-independent water-budget analysis. Simulated average net recharge to the surficial aquifer system was 3.6 inches per year, compared with the calculated average of 3.2 inches per year from the model-independent waterbudget analysis. Groundwater withdrawals from the Floridan aquifer system averaged about 800 million gallons per day, which is equivalent to about 2 inches per year over the model area and slightly more than half of the simulated average net recharge to the surficial aquifer system over the same period. Annual net simulated recharge rates to the surficial aquifer system were less than the total groundwater withdrawals from the Floridan aquifer system only during the below-average rainfall years of 2000 and 2006.

Florida↗

Groundwater flow and water budget in the surficial and Floridan aquifer systems in east-central Florida

A numerical transient model of the surficial and Floridan aquifer systems in east-central Florida was developed to (1) increase the understanding of water exchanges between the surficial and the Floridan aquifer systems, (2) assess the recharge rates to the surficial aquifer system from infiltration through the unsaturated zone and (3) obtain a simulation tool that could be used by water-resource managers to assess the impact of changes in groundwater withdrawals on spring flows and on the potentiometric surfaces of the hydrogeologic units composing the Floridan aquifer system. The hydrogeology of east-central Florida was evaluated and used to develop and calibrate the groundwater flow model, which simulates the regional fresh groundwater flow system. The U.S. Geological Survey three-dimensional groundwater flow model, MODFLOW-2005, was used to simulate transient groundwater flow in the surficial, intermediate, and Floridan aquifer systems from 1995 to 2006. The East-Central Florida Transient model encompasses an actively simulated area of about 9,000 square miles. Although the model includes surficial processes-rainfall, irrigation, evapotranspiration (ET), runoff, infiltration, lake water levels, and stream water levels and flows-its primary purpose is to characterize and refine the understanding of groundwater flow in the Floridan aquifer system. Model-independent estimates of the partitioning of rainfall into ET, streamflow, and aquifer recharge are provided from a water-budget analysis of the surficial aquifer system. The interaction of the groundwater flow system with the surface environment was simulated using the Green-Ampt infiltration method and the MODFLOW-2005 Unsaturated-Zone Flow, Lake, and Streamflow-Routing Packages. The model is intended to simulate the part of the groundwater system that contains freshwater. The bottom and lateral boundaries of the model were established at the estimated depths where the chloride concentration is 5,000 milligrams per liter in the Floridan aquifer system. Potential flow across the interface represented by this chloride concentration is simulated by the General Head Boundary Package. During 1995 through 2006, there were no major groundwater withdrawals near the freshwater and saline-water interface, making the general head boundary a suitable feature to estimate flow through the interface. The east-central Florida transient model was calibrated using the inverse parameter estimation code, PEST. Steady-state models for 1999 and 2003 were developed to estimate hydraulic conductivity (K) using average annual heads and spring flows as observations. The spatial variation of K was represented using zones of constant values in some layers, and pilot points in other layers. Estimated K values were within one order of magnitude of aquifer performance test data. A simulation of the final two years (2005-2006) of the 12-year model, with the K estimates from the steady-state calibration, was used to guide the estimation of specific yield and specific storage values. The final model yielded head and spring-flow residuals that met the calibration criteria for the 12-year transient simulation. The overall mean residual for heads, defining residual as simulated minus measured value, was -0.04 foot. The overall root-mean square residual for heads was less than 3.6 feet for each year in the 1995 to 2006 simulation period. The overall mean residual for spring flows was -0.3 cubic foot per second. The spatial distribution of head residuals was generally random, with some minor indications of bias. Simulated average ET over the 1995 to 2006 period was 34.47 inches per year, compared to the calculated average ET rate of 36.39 inches per year from the model-independent water-budget analysis. Simulated average net recharge to the surficial aquifer system was 3.58 inches per year, compared with the calculated average of 3.39 inches per year from the model-independent water-budget analysis. Groundwater withdrawals from the Floridan aquifer system averaged about 920 million gallons per day, which is equivalent to about 2 inches per year over the model area and slightly more than half of the simulated average net recharge to the surficial aquifer system over the same period. Annual net simulated recharge rates to the surficial aquifer system were less than the total groundwater withdrawals from the Floridan aquifer system only during the below-average rainfall years of 2000 and 2006.

Florida↗

Hydrogeologic framework, groundwater movement, and water budget in the Chimacum Creek basin and vicinity, Jefferson County, Washington

This report presents information used to characterize the groundwater flow system in the Chimacum Creek basin. It includes descriptions of the geology and hydrogeologic framework; groundwater recharge and discharge; groundwater levels and flow directions; seasonal fluctuations in groundwater level; interactions between aquifers and the surface-water system; and a groundwater budget. The study area covers 124 square miles in northeastern Jefferson County, Washington, and includes the Chimacum Creek basin, which drains an area of about 37 square miles. The area is underlain by a north-thickening sequence of unconsolidated glacial and interglacial deposits that overlie sedimentary and igneous bedrock units that crop out along the margins and western interior of the study area. Six hydrogeologic units consisting of unconsolidated aquifers and confining units, along with an underlying bedrock unit, were identified. A surficial hydrogeologic map was developed and used with well information from 187 drillers' logs to construct 4 hydrogeologic sections, and maps showing the extent and thickness of the units. Natural recharge was estimated using precipitation-recharge relation regression equations developed for western Washington, and estimates were calculated for return flow from data on domestic indoor and outdoor use and irrigated agriculture. Results from synoptic streamflow measurements and water table elevations determined from monthly measurements at monitoring wells are presented and compared with those from a study conducted during 2002-03. A water budget was calculated comprising long-term average recharge, domestic public-supply withdrawals and return flow, self-supplied domestic withdrawals and return flow, and irrigated agricultural withdrawals and return flow.

Washington↗

Ambient water quality in aquifers used for drinking-water supplies, Gem County, southwestern Idaho, 2015

In recent years, the rapid population growth in Gem County, Idaho, has been similar to other counties in southwestern Idaho, increasing about 54 percent from 1990 to 2015. Because the entire population of the study area depends on groundwater for drinking water supply (either from self-supplied domestic, community, or municipal-supply wells), this population growth, along with changes in land use (including potential petroleum exploration and development), indicated to the public and local officials the need to assess the quality of groundwater used for human consumption. To this end, the U.S. Geological Survey, in cooperation with Gem County and the Idaho Department of Environmental Quality, assessed the quality of groundwater from freshwater aquifers used for domestic supply in Gem County. A total of 47 domestic or municipal wells, 1 spring, and 2 surface-water sites on the Payette River were sampled during September 8–November 19, 2015. The sampled water was analyzed for a variety of constituents, including major ions, trace elements, nutrients, bacteria, radionuclides, dissolved gasses, stable isotopes of water and methane, and either volatile organic compounds (VOCs) or pesticides. To better understand analytical results, a conceptual hydrogeologic framework was developed in which three hydrogeologic units were described: Quaternary-Tertiary deposits (QTd), Tertiary Idaho Group rocks (Tig), and Tertiary-Cretaceous igneous rocks (TKi). Water levels were measured in 30 wells during sampling, and a groundwater-level altitude map was constructed for the QTd and Tig units showing groundwater flow toward the Emmett Valley and Payette River. Analytical results indicate that groundwater in Gem County is generally of good quality. Samples collected from two wells contained water with fluoride concentrations greater than the U.S. Environmental Protection Agency (EPA) Maximum Contaminant Level (MCL) of 4 milligrams per liter (mg/L), six wells contained arsenic at concentrations greater than the EPA MCL of 10 micrograms per liter, and a sample from one well exceeded the MCL of 15 picocuries per liter for alpha particles. Although previous samples collected from some wells in Gem County contained nitrate concentrations greater than the MCL of 10 mg/L, the largest concentration detected in the current study was 5.2 mg/L. Total coliform bacteria was detected in four groundwater samples. Three volatile organic compounds (VOCs) were detected in samples collected from five wells, and five compounds of the triazine class of herbicides were detected in samples from five wells; no concentrations were greater than applicable EPA MCLs. Methane was detected in samples from 36 wells, with the concentration in 1 well large enough to be considered an explosion hazard by U.S. Office of Surface Mining guidelines. Stable isotope signatures of methane in six samples suggest that naturally occurring methane in Gem County is probably of both thermogenic and biogenic origin.

Idaho↗

Conceptual and numerical groundwater flow model of the Iowa River alluvial aquifer near Tama County, Iowa, 1980 through 2022

The Iowa River alluvial aquifer is an important source of water on the Meskwaki Settlement in Tama County, Iowa, which is land owned by the Sac & Fox Tribe of the Mississippi in Iowa (commonly known as the Meskwaki Nation). The U.S. Geological Survey constructed a groundwater flow model, including a conceptual and numerical model, of the Iowa River alluvial aquifer and underlying hydrogeologic units near the Meskwaki Settlement in Tama County, Iowa, for the period of January 1980–August 2022 to estimate the fraction of water pumped from the Iowa River alluvial aquifer by Meskwaki Settlement wells that is derived from streamflow depletion in the Iowa River and its tributaries. Streamflow depletion is a reduction in streamflow caused by groundwater pumping and includes the interception by groundwater production wells of water that otherwise would have been discharged to streams (called “captured groundwater discharge”) and induced infiltration of streamflow to the production wells. Calibrated model runs were performed with no simulated pumping and simulated pumping only at Meskwaki Settlement wells, and the change in simulated flow rates between the groundwater system and streams for the two model runs represents the amount of streamflow depletion in the Iowa River and tributary streams resulting from pumping at the Meskwaki Settlement wells. Streamflow depletion in the Iowa River and its tributaries as a percentage of simulated pumping at the Meskwaki Settlement wells was calculated by dividing this difference by the total simulated pumping rate for the Meskwaki Settlement wells. The model results demonstrate that the mean monthly streamflow depletion, including induced infiltration and captured discharge, in the Iowa River and its tributary streams as a percentage of mean monthly pumping at the Meskwaki Settlement wells was 97.4 percent and ranged from 65.4 to 112 percent. Of the total streamflow depletion, mean monthly induced recharge was 20.9 percent and ranged from 4.9 to 37.2 percent. Mean monthly captured discharge was 76.5 percent and ranged from 57.1 to 97.1 percent. These results indicate that most of the water pumped from the Meskwaki Settlement wells is the result of streamflow depletion, in the form of both induced infiltration and captured discharge.

Iowa↗

Geostatistical analysis of tritium, groundwater age and other noble gas derived parameters in California

Key characteristics of California groundwater systems related to aquifer vulnerability, sustainability, recharge locations and mechanisms, and anthropogenic impact on recharge are revealed in a spatial geostatistical analysis of a unique data set of tritium, noble gases and other isotopic analyses unprecedented in size at nearly 4000 samples. The correlation length of key groundwater residence time parameters varies between tens of kilometers ( 3 H; age) to the order of a hundred kilometers ( 4 He ter ; 14 C; 3 He trit ). The correlation length of parameters related to climate, topography and atmospheric processes is on the order of several hundred kilometers (recharge temperature; δ 18 O). Young groundwater ages that highlight regional recharge areas are located in the eastern San Joaquin Valley, in the southern Santa Clara Valley Basin, in the upper LA basin and along unlined canals carrying Colorado River water, showing that much of the recent recharge in central and southern California is dominated by river recharge and managed aquifer recharge. Modern groundwater is found in wells with the top open intervals below 60 m depth in the southeastern San Joaquin Valley, Santa Clara Valley and Los Angeles basin, as the result of intensive pumping and/or managed aquifer recharge operations.

California↗