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Evaporation control research, 1955-58

One hundred fifty-two compounds and compositions of matter were screened as potential evaporation retardants. The homologous straight-chain fatty alkanols are considered the best materials for retardants. Several methods of application of the alkanols to the reservoir surface were investigated. Although wick-type drippers for the application of liquids and cage rafts for the application of solids appear to be the most promising methods from an economic standpoint, both methods have serious disadvantages. Considerable study was given to reducing biochemical oxidation of the evaporation retardants. Copper in several forms was found adequate as a bacteriostatic agent but posed a potential hazard because of its toxicity. Many other bactericides that were tested were also toxic. Two sets of large-scale field tests have been completed and several others are still in progress. On the larger reservoirs, the reduction of evaporation was not more than 20 percent under the prevailing conditions and the application procedure used. Three major practical problems remain; namely, the effects and action of wind on the monofilm, the effects of biochemical oxidation, and the most effective method of application. Fundamental problems remaining include the effects of various impurities, and the composition of the best evaporation retardant; the long-range effects of monofilms on the limnology of a reservoir, including the transfer of oxygen and carbon dioxide; toxicological aspects of all components of any evaporation-retardant composition, plus toxicology of any composition chosen for large-scale use; and further studies of the calorimetry and thermodynamics involved in the mechanism of evaporation and its reduction by a monofilm.

Water Supply Paper↗

Geology and ground-water resources of the upper Lodgepole Creek drainage basin, Wyoming, with a section on chemical quality of the water

The principal sources of ground-water supply in the upper Lodgepole Creek drainage basin-the part of the basin west of the Wyoming-Nebraska State line-are the Brule formation of Oligocene age, the Arikaree formation of Miocene age, the Ogallala formation of Pliocene age, and the unconsolidated deposits of Quaternary age. The Brule formation is a moderately hard siltstone that generally is not a good aquifer. However, where it is fractured or where the upper part consists of pebbles of reworked siltstone, it will yield large quantities of water to wells. Many wells in the Pine Bluffs lowland, at the east end of the area, derive water from the Brule. The Arikaree formation, which consists of loosely to moderately cemented fine sand, will yield small quantities of water to wells but is not thick enough or permeable enough to supply sufficient water for irrigation. Only a few wells derive water from it. The Ogallala formation consists of lenticular beds of clay, silt, sand, and gravel which, in part, are cemented with calcium carbonate. Only the lower part of the formation is saturated. Nearly all the wells in the upland part of the area tap the Ogallala, but they supply water in amounts sufficient for domestic and stock use only. Two of the wells have a moderately large discharge, and other wells of comparable discharge probably could be drilled in those parts of the upland where the saturated part of the Ogallala is fairly thick. Most of the unconsolidated deposits of Quaternary age are very permeable and, where a sufficient thickness is saturated, will yield large quantities of water to wells. These deposits are a significant source of water supply in the southeastern part of the area. The Chadron formation of Oligocene age, which underlies the Brule formation, is a medium- to coarse-grained sandstone where it crops out in the Islay lowland. No wells tap the Chadron, but it probably would yield small quantities of water to wells. It lies at a relatively shallow depth beneath most of the Islay lowland, near the west end of the area, and at a depth of about 800 feet beneath the Pine Bluffs lowland. In the latter area it probably is finer grained and may not be permeable enough to yield water to wells. All the ground water in the area is derived from precipitation. It is estimated that about 5 percent of the precipitation infiltrates directly to the zone of saturation. The remainder either is evaporated immediately; is retained by the soil, later to be evaporated or transpired; or is discharged by overland flow to the surface drainage courses. Most of the water that reaches the surface drainage courses eventually sinks to the zone of saturation or is evaporated. The slope of the water table and the movement of ground water are generally eastward. The depth to water ranges from less than 10 feet in parts of the valley to about 300 feet in the upland areas. In much of the Pine Bluffs lowland, the depth to water is less than 50 feet. Ground water not pumped from wells within the area is discharged by evapotranspiration where the water table is close to the land surface, by outflow into streams, or by underflow eastward beneath the State line. The chemical quality of ground water from the principal sources is remarkably uniform, and the range in concentration of dissolved constituents is narrow. In general, the water is of the calcium bicarbonate type, is hard (hardness as CaC03 is as high as 246 ppm), and contains less than about 400 parts per million of dissolved solids, which is a moderate mineralization. Silica constitutes a large proportion of the dissolved solids. The water is suitable for irrigation and, except for iron in water from some wells that tap the Ogallala formation, meets the drinking water standards of the U.S. Public Health Service for chemical constituents. Because the water is siliceous, alkaline, and hard, it is unsuitable for many industrial uses unless treated.

Water Supply Paper↗

Geology and ground-water resources of the lower Little Bighorn River Valley, Big Horn County, Montana, with special reference to the drainage of waterlogged lands

The lower Little Bighorn River valley, Montana, is in the unglaciated part of the Missouri Plateau section of the Great Plains physiographic province. The river and its principal tributaries rise in the Bighorn Mountains, and the confluence of this northward-flowing stream with the Bighorn River is near the east edge of Hardin, Mont. The normal annual precipitation ranges from about 12 inches in the northern part of the area to 15 inches in the southern part. The economy of the area is founded principally on farming, much of the low-lying land adjacent to the river being irrigated. The irrigated land is within the Crow Indian Reservation, although a part is privately owned. The bedrock formations exposed in the area are of Cretaceous age and include the Parkman sandstone, Claggett shale, Eagle sandstone, Telegraph Creek shale, and Cody shale. The Cloverly formation, Tensleep sandstone, and Madison limestone, which underlie but are not exposed in the area, and the Parkman sandstone in the southern half of the area appear to be the principal bedrock aquifers. All except the Parkman lie at depths ranging from a few feet to several thousand feet, and all appear to be capable of yielding water in commercial quantities. Some of the other formations arc capable of yielding enough water for domestic and stock needs. The river alluvium of Recent age and the Pleistocene terrace deposits are the principal unconsolidated formations in the area with respect to water supply and drainage. Wells yielding as much as 100 gallons per minute may be developed in favorable areas. Pumping tests reveal that the transmissibility of the coarser unconsolidated materials probably ranges from about 15,000 to 30,000 gallons per day per foot. Two tests of the Parkman sandstone showed transmissibilities of 6,000 and 20,000 gallons per day per foot. Although a test of the Cloverly formation showed a transmissibility of only 3,000 gallons per day per foot, the high artesian pressure--80 pounds per square inch at the land surface--in the Cloverly caused the tested well to yield about 200 gallons per minute by natural flow; this is greater than the yield of any other single well in the area. Textural properties were compared with the hydraulic properties determined by laboratory tests to show the relation between different types of waterbearing materials. Materials classified as heavy soils-normally somewhat dense and impervious-had an average permeability of 7.2 gallons per day per square foot, which was more than expected. One sample of very coarse alluvial material had a permeability of 6,000 gallons per day per square foot. The depth to water beneath irrigation units was mapped, thus showing the waterlogged areas. Waterlogging is not a serious problem where the water table is more than 6 feet below the land surface. For the drainage studies the unconsolidated deposits are classified in two zones-coarse-grained sediments resting on the relatively impermeable bedrock floor and overlying fine-grained sediments which extend to the land surface. The transmissibility of the coarse-sediment zone generally is many times greater than that of the fine-sediment zone. Because in many places drains could not be economically dug deep enough to enter the coarse zone, the study of the effectiveness of drainage completed in the fine zone received much attention. The studies showed that, despite a considerable thickness of fine-grained sediments between the bottom of the drain and the top of the coarse zone, drainage ditches frequently were effective in relieving waterlogging of fields nearby. Pilot relief wells installed in existing drains showed that the effectiveness of some drains could be increased appreciably by installing a series of relief wells. Records of fluctuations of water levels in 196 observation wells and water-level contour maps were studied to show the principal areas of recharge and discharge in the irrigable areas.

Montana↗

The geology and ground-water resources of Calcasieu Parish, Louisiana

Large quantities of fresh ground water are available in Calcasieu Parish. Fresh water is present in sand of Recent, Pleistocene, Pliocene, and Miocene ages, although locally only small supplies for rural or stock use can be obtained from the shallow sand lenses of Recent and Pleistocene ages. The principal fresh-water-bearing sands are the '200-foot,' '500-foot,' and '700-foot' sands of the Chicot aquifer of Pleistocene age, from which 105 million gallons is pumped daily. A yield of as much as 4,500 gpm (gallons per minute) has been obtained from a single well. The sands are typical of the Chicot aquifer throughout southwestern Louisiana in that generally they grade from fine sand at the top to coarse sand and gravel at the base of the aquifer. The coefficient of permeability of the principal sands in Calcasieu Parish ranges from 660 to about 2,000 gpd (gallons per day) per square foot and averages 1,200 gpd per square foot. The permeability of the sands generally varies with textural changes. The maximum depth of occurrence of fresh ground water in Calcasieu Parish ranges from about 700 feet to 2,500 feet below mean sea level; locally, however, where the sands overlie structures associated with oil fields, the maximum depth is less than 300 feet. Pumping has caused water levels to decline, at varying rates, in all the sands. In the '200-foot' sand they are declining at a rate of about 2 feet per year. In the industrial district of Calcasieu Parish, levels in the '500-foot' sand are declining at a rate of about 5 feet per year, and in the '700-foot' sand at a rate of about 3.5 feet per year. Salt-water contamination is accompanying the water-level decline in the '700-foot' sand in the central part of the parish. Quality-of-water data indicate that water from wells screened in the Chicot aquifer generally is suitable for some uses without treatment but would require treatment to be satisfactory for other uses. The temperature of the water ranges from 70° to 79°F. The lenticular sands of Pliocene and Miocene ages have not been used as a source of fresh ground water in Calcasieu Parish; however, north of the Houston River these formations contain fresh water, and the water contained in these formations in other parts of southwestern Louisiana is known to be soft and suitable for most purposes.

Louisiana↗

Geology and ground water in the Platte-Republican Rivers watershed and the Little Blue River basin above Angus, Nebraska, with a section on chemical quality of the ground water

This report describes an area of about 7,300 square miles in south-central Nebraska. Approximately one-fourth of the area, largely at its east end, consists of an undissected southeastward-sloping upland plain and is almost wholly irrigable; the remainder is in various stages of dissection and only parts of it are suitable for irrigation. Although some of the deeper lying bedrock formations are potential sources of water supply, they are not likely to be tapped in the near future because abundant supplies are available at shallower depth from semiconsolidated and unconsolidated deposits. The Ogallala formation of Tertiary (Pliocene) age consists of gravel, sand, silt, and volcanic ash, some layers of which are partly cemented. It was deposited by eastward-flowing streams, which formed a constructional plain above a surface into which the streams had previously eroded broad valleys. In turn, valleys were cut into the surface of the Ogallala before the overlying deposits of gravel, sand, silt, and clay of Quaternary (Pleistocene) age were laid down, also forming a constructional plain. During Recent time, streams have dissected the older deposits and have deposited thin alluvium in their valleys; also, several parts of the area have become mantled by wind-deposited sand. Because during Tertiary and Quaternary time the area repeatedly was the site of deposition and erosion, the thickness of all the stratigraphic units differs markedly from place to place. In general, however, the Ogallala formation thins eastward and in the central and eastern parts of the area is overlain by the eastward-thickening deposits of Pleistocene age. The maximum thickness of the Ogallala formation is about 500 feet, and the maximum thickness of the Pleistocene deposits is a little more than 300 feet. Each thins to a featheredge and is completely absent in parts of the area. The water-bearing part of the combined Tertiary and Pleistocene deposits is considered to be a single zone of saturation because the ground water, as it percolates southeastward beneath the area, moves out of the Tertiary and into the Quaternary deposits without apparent hindrance. The water that enters the area as underflow from the west is augmented within the area by water that infiltrates from the land surface. The principal sources of irrigating water are precipitation, seepage from canals and reservoirs, and applied irrigation water. Except for the water withdrawn through wells or discharged by natural processes where valleys have been cut into the zone of saturation, ground water leaves the area as underflow into the Platte River valley on the north, the Blue River drainage basin on the east, or the Republican River valley on the south. Part of the water used for irrigation and watering livestock and all the water used in rural and urban homes, in public buildings, and for industrial purposes is obtained from wells, To date (1952) there is no indication that the supply of ground water is being depleted faster than it is being replenished; instead, studies indicate that greater quantities can be withdrawn without causing an excessive decline of the water table. An increase of ground-water withdrawals to a sustainable maximum, however, will be possible only if the points of withdrawal are scattered fairly uniformly. It is estimated that annual withdrawals per township should not exceed 2,100 acre-feet where infiltrating precipitation is the only source of recharge, or 3,000 acre-feet where other sources of recharge are significant. Although perennial withdrawals of this amount could be sustained indefinitely, they would cause some lowering of the water table and eventually a decrease in the amount of water discharged from the area by natural means. The ground water is of the calcium bicarbonate type. In much of the area it is hard or very hard, and in places it contains excessive amounts of iron. In all other respects the water is chemically suitable for domesti

Nebraska↗

Geology and ground-water resources of Platte County, Wyoming, with a section on Chemical quality of the water

Platte County, Wyo., has an area of 2,114 square miles and, in 1950, had a population of 7,925; it lies within parts of two major physiographic provinces, the northern extension of the Southern Rocky Mountains and the northwestern part of the Great Plains. The Laramie Range and related structures lie along the western margin of the county and constitute the eastern limit of the Rocky Mountain Front Range. The High Plains section of the Great Plains province extends eastward from the Laramie Range over the remainder of the county. The original surface of the High Plains has been deeply eroded, and in the northeastern part of the county it is broken by the broad uplifted structural platform of the Hartville Hills. The North Platte River and its tributaries have entrenched their channels as much as 1,000 feet into the plains, leaving wide, very flat intervalley areas that are interrupted by a few isolated buttes and outlying ridges. Well-defined terraces, locally called the Wheatland Flats, have been formed in central Platte County. The climate is semiarid, the average annual precipitation being about 15 inches. Farming and stockraising are the principal occupations in the county. Most of the rocks exposed in the county are of Tertiary and Quaternary age, although rocks as old as Precambrian crop out locally. The Arikaree and Brule formations and younger deposits, including Tertiary ( ?) deposits (undifferentiated) and terrace, flood-plain, and other alluvial deposits, underlie more than two-thirds of the county. Mesozoic, Paleozoic, and Precambrian rocks crop out in the other third and underlie the younger rocks at great depths elsewhere. Small supplies of ground water adequate for domestic and stock use can be obtained from shallow wells in the Casper, Hartville, Cloverly, Brule, and Arikaree formations and in the terrace and flood-plain deposits. Small to moderate amounts of ground water can be obtained from the 'Converse sand' of the Hartville formation. Several flowing wells obtain water from this sand near Glendo. Moderate to large supplies of ground water adequate for small-scale irrigation or industrial uses or for public supply can be obtained from properly constructed wells penetrating thick saturated sections of the Arikaree formation and from the terrace and flood-plain deposits. Large supplies of ground water can be obtained from the flood-plain deposits of the North Platte River near Guernsey, where wells commonly yield more than 1,000 gpm (gallons per minute). The aquifers with greatest potential for additional groundwater development in Platte County, in decreasing order of importance, are the flood-plain deposits along the North Platte River and its tributaries, the Arikaree formation and terrace deposits in parts of the Wheatland Flats, and the 'Converse sand' in the general vicinity of Glendo.

Water Supply Paper↗

Geology and ground water in Napa and Sonoma Valleys, Napa and Sonoma Counties, California

Napa and Sonoma Valleys are adjacent alluvium-filled valleys about 40 miles northeast of San Francisco. They occupy alined and structurally controlled depressions in the northern Coast Ranges physiographic province and drain south into San Pablo Bay. The valleys are surrounded and underlain by unconsolidated marine and continental sediments and volcanic rocks of Pliocene and Pleistocene age, which are water bearing in large part and together make up relatively extensive ground-water basins. Napa Valley, the eastern valley, is the larger and has a valley-floor area of about 85 square miles. Sonoma Valley has a valley-floor area of about 35 square miles; in addition, about 10 square miles is unreclaimed tidal marsh. The rock units of Napa and Sonoma Valleys are divided into four classes on the basis of their distribution and relative capacity to yield water: (a) Consolidated virtually non-water-bearing chiefly sedimentary (some metamorphic) rocks that range in age from Jurassic ( ?) to Pliocene; (b) marine shale and sand of the Petaluma formation (Pliocene) and the Merced formation (Pliocene and Pleistocene) that do not crop out within Napa or Sonoma Valleys but perhaps are penetrated by some deep wells drilled in Sonoma Valley; (c) Sonoma volcanics of Pliocene age, parts of which are non-water-bearing and parts of which locally yield large quantities of water; and (d) unconsolidated alluvial deposits mainly of Quaternary age. The deposits of classes (c) and (d) contain the most important aquifers in the area. Most of the water used in these valleys is pumped from wells in the younger and older alluvium in the Huichica and Glen Ellen formations. and in the Sonoma volcanics. The principal aquifers are the younger and older alluvium. but appreciable quantities of water are pumped locally from the Sonoma volcanics. The Huichica and Glen Ellen formations yield water in small quantities and at most places supply water only for limited domestic uses. The younger alluvium COIM3ists of interbedded deposits of unconsolidated gravel. sand, silt. and. locally, peat. These deposits underlie the flood plains and channels of the Napa River. Sonoma Creek, and their tributaries, low alluvial fans or plains graded to these streams. and the tidal marshlands. The older alluvium of Napa and Sonoma Valleys is composed of lenticular deposits of unconsolidated and poorly sorted clay, silt. sand. and gravel. Where exposed, claypan or hardpan soil is characteristically developed at the surface. The Huichica formation is composed of deformed continental beds consisting mostly of yellow silt with some interbedded lenses of silt and gravel, and silt and boulders. At the base are beds of redeposited volcanic material, silt, clay, and lenses of coarse gravel and boulders. The Glen Ellen fcrmation consists of alluvial clay, silt, sand, and gravel in clearly stratified but generally lenticular beds. The Sonoma volcanics constitute a thick and highly variate series of continental volcanic rocks, including andesite, basalt, and minor rhyolite flows and interbedded coarse- to fine-grained pyroclastic tuff and breccia, redeposited tuff and pumice, and diatomaceous mud, silt, and sand. A prominent body of rhyolite flows and tuff with some obsidian and perlitic glass, called the St. Helena rhyolite member, occurs in the upper part. Estimated ground-water pumpage for all uses in the year 1949-50 was about 5,600 acre-feet in Napa Valley and about 2,400 acre-feet in Sonoma Valley. Of this quantity the amounts pumped for irrigation were about 2,900 and 1,900 acre-feet, respectively. Water levels in wells in the central parts of the valleys range from a few feet above the land surface to about 50 feet below, with an average of about 25 feet. The quality of the water in most wells is satisfactory for domestic use and irrigation. Locally at the southern end of the valley some contamination of the native waters is caused by the movement of salty wate

Water Supply Paper↗