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At least 631 records · Page 35Linked to original sources

Estimations of evapotranspiration and water balance with uncertainty over the Yukon River Basin

In this study, the revised Remote Sensing-Penman Monteith model (RS-PM) was used to scale up evapotranspiration (ET) over the entire Yukon River Basin (YRB) from three eddy covariance (EC) towers covering major vegetation types. We determined model parameters and uncertainty using a Bayesian-based method in the three EC sites. The 95 % confidence interval for the aggregate ecosystem ET ranged from 233 to 396 mm yr −1 with an average of 319 mm yr −1 . The mean difference between precipitation and evapotranspiration ( W ) was 171 mm yr −1 with a 95 % confidence interval of 94–257 mm yr −1 . The YRB region showed a slight increasing trend in annual precipitation for the 1982–2009 time period, while ET showed a significant increasing trend of 6.6 mm decade −1 . As a whole, annual W showed a drying trend over YRB region.

Alaska↗

An evaluation of methods for estimating decadal stream loads

Effective management of water resources requires accurate information on the mass, or load of water-quality constituents transported from upstream watersheds to downstream receiving waters. Despite this need, no single method has been shown to consistently provide accurate load estimates among different water-quality constituents, sampling sites, and sampling regimes. We evaluate the accuracy of several load estimation methods across a broad range of sampling and environmental conditions. This analysis uses random sub-samples drawn from temporally-dense data sets of total nitrogen, total phosphorus, nitrate, and suspended-sediment concentration, and includes measurements of specific conductance which was used as a surrogate for dissolved solids concentration. Methods considered include linear interpolation and ratio estimators, regression-based methods historically employed by the U.S. Geological Survey, and newer flexible techniques including Weighted Regressions on Time, Season, and Discharge (WRTDS) and a generalized non-linear additive model. No single method is identified to have the greatest accuracy across all constituents, sites, and sampling scenarios. Most methods provide accurate estimates of specific conductance (used as a surrogate for total dissolved solids or specific major ions) and total nitrogen – lower accuracy is observed for the estimation of nitrate, total phosphorus and suspended sediment loads. Methods that allow for flexibility in the relation between concentration and flow conditions, specifically Beale’s ratio estimator and WRTDS, exhibit greater estimation accuracy and lower bias. Evaluation of methods across simulated sampling scenarios indicate that (1) high-flow sampling is necessary to produce accurate load estimates, (2) extrapolation of sample data through time or across more extreme flow conditions reduces load estimate accuracy, and (3) WRTDS and methods that use a Kalman filter or smoothing to correct for departures between individual modeled and observed values benefit most from more frequent water-quality sampling.

Journal of Hydrology↗

Estimating groundwater recharge

Understanding groundwater recharge is essential for successful management of water resources and modeling fluid and contaminant transport within the subsurface. This book provides a critical evaluation of the theory and assumptions that underlie methods for estimating rates of groundwater recharge. Detailed explanations of the methods are provided - allowing readers to apply many of the techniques themselves without needing to consult additional references. Numerous practical examples highlight benefits and limitations of each method. Approximately 900 references allow advanced practitioners to pursue additional information on any method. For the first time, theoretical and practical considerations for selecting and applying methods for estimating groundwater recharge are covered in a single volume with uniform presentation. Hydrogeologists, water-resource specialists, civil and agricultural engineers, earth and environmental scientists and agronomists will benefit from this informative and practical book. It can serve as the primary text for a graduate-level course on groundwater recharge or as an adjunct text for courses on groundwater hydrology or hydrogeology.

Book↗

Not all water becomes wine: Sulfur inputs as an opportune tracer of hydrochemical losses from vineyards

California's widespread and economically important vineyards offer substantial opportunities to understand the interface between hydrology and biogeochemistry in agricultural soils. The common use of native sulfur (S) as a fumigant or soil additive provides a novel way to isotopically differentiate among sulfate (SO 4 2− ) pools, allowing the estimation of water and SO 4 2− budgets. The objectives of this study were (1) to characterize the near‐surface hydrological flow paths in a vineyard during irrigation and storm events and (2) to determine how those flow paths affect the fate and transport of SO 4 2− across seasons. Integrating hydrological theory with measurements of SO 4 2− concentration and sulfate‐S isotopic ratios (expressed as [SO 4 2− ] and δ 34 S, respectively) in inputs, soil water, and leachate provided a means of determining flow paths. Low [SO 4 2− ] and δ 34 S in leachate during 4‐h irrigation events reflect minimal engagement of the soil matrix, indicating that preferential flow was the dominant path for water in the near surface. In contrast, high [SO 4 2− ] and δ 34 S values during 8‐h irrigation and storm events reflect near‐complete engagement of the soil matrix, indicating that lateral flow was the dominant pathway. Because hydrologic response and SO 4 2− mobility are tightly coupled in these soils, the magnitude of water fluxes through the near surface controls S cycling both on and off site. These results indicate that preferential flow is an important loss pathway to consider in managing both water resources and water quality (reactive elements) in vineyard land use systems.

Water Resources Research↗

A method for physically based model analysis of conjunctive use in response to potential climate changes

Potential climate change effects on aspects of conjunctive management of water resources can be evaluated by linking climate models with fully integrated groundwater-surface water models. The objective of this study is to develop a modeling system that links global climate models with regional hydrologic models, using the California Central Valley as a case study. The new method is a supply and demand modeling framework that can be used to simulate and analyze potential climate change and conjunctive use. Supply-constrained and demand-driven linkages in the water system in the Central Valley are represented with the linked climate models, precipitation-runoff models, agricultural and native vegetation water use, and hydrologic flow models to demonstrate the feasibility of this method. Simulated precipitation and temperature were used from the GFDL-A2 climate change scenario through the 21st century to drive a regional water balance mountain hydrologic watershed model (MHWM) for the surrounding watersheds in combination with a regional integrated hydrologic model of the Central Valley (CVHM). Application of this method demonstrates the potential transition from predominantly surface water to groundwater supply for agriculture with secondary effects that may limit this transition of conjunctive use. The particular scenario considered includes intermittent climatic droughts in the first half of the 21st century followed by severe persistent droughts in the second half of the 21st century. These climatic droughts do not yield a valley-wide operational drought but do cause reduced surface water deliveries and increased groundwater abstractions that may cause additional land subsidence, reduced water for riparian habitat, or changes in flows at the Sacramento-San Joaquin River Delta. The method developed here can be used to explore conjunctive use adaptation options and hydrologic risk assessments in regional hydrologic systems throughout the world.

Water Resources Research↗

Water, water everywhere, but every drop unique: Emerging challenges in the science to understand the role of contaminants in management of drinking water supplies

The protection and management of water resources continues to be challenged by multiple and ongoing factors such as shifts in demographic, social, economic, and public health requirements. Physical limitations placed on access to potable supplies include natural and human-caused factors such as aquifer depletion, aging infrastructure, saltwater intrusion, floods, and drought. These factors, although varying in magnitude, spatial extent, and timing, can exacerbate the potential for contaminants of concern (CECs) to be present in sources of drinking water, infrastructure, premise plumbing and associated tap water. This monograph examines how current and emerging scientific efforts and technologies increase our understanding of the range of CECs and drinking water issues facing current and future populations. It is not intended to be read in one sitting, but is instead a starting point for scientists wanting to learn more about the issues surrounding CECs. This text discusses the topical evolution CECs over time (Section 1), improvements in measuring chemical and microbial CECs, through both analysis of concentration and toxicity (Section 2) and modeling CEC exposure and fate (Section 3), forms of treatment effective at removing chemical and microbial CECs (Section 4), and potential for human health impacts from exposure to CECs (Section 5). The paper concludes with how changes to water quantity, both scarcity and surpluses, could affect water quality (Section 6). Taken together, these sections document the past 25 years of CEC research and the regulatory response to these contaminants, the current work to identify and monitor CECs and mitigate exposure, and the challenges facing the future.

GeoHealth↗

Going beyond low flows: Streamflow drought deficit and duration illuminate distinct spatiotemporal drought patterns and trends in the U.S. during the last century

Streamflow drought is a recurring challenge, and understanding spatiotemporal patterns of past droughts is needed to manage future water resources. We examined regional patterns in streamflow drought metrics and compared these metrics to low flow timing and magnitude using long-term daily records for 555 minimally disturbed watersheds. For each streamgage, we calculated streamflow drought duration (number of days) and deficit (flow volume below a specified threshold) for each climate year (April 1–March 31). We identified drought using five thresholds (2%–30%) and two approaches: variable thresholds with unique values for each day of the year, and a fixed threshold based on all period-of-record flows. We then analyzed drought trends using the Mann-Kendall test with persistence adjustment for 1921–2020, 1951–2020, and 1981–2020, and computed correlations between annual streamflow drought metrics and climate metrics using values from a monthly water balance model. Spatial patterns in drought metrics were consistent between variable and fixed approaches, though fixed threshold durations were typically longer and variable threshold deficits larger. High interannual variability in drought duration emerged in the central, interior west, and southwestern U.S., with high deficit variability in the interior west. Drought metrics were weakly correlated with low flow magnitude and timing, providing unique information. Drought duration and deficit increased in the southern and western U.S. for both 1951–2020 and 1981–2020, particularly using fixed thresholds, and paralleled trends in aridity. Projections of continued aridification for the southern and western U.S. may increase drought durations and deficits and intensify water availability impacts.

Water Resources Research↗

Relation of carbon 14 concentrations to saline water contamination of coastal aquifers

Naturally occurring stable or radioactive isotopes may be used in some places to identify the origin of saline water that contaminates some coastal aquifers. In a recent study to determine the origin of saline water in the Ocala Limestone aquifer near Brunswick, Georgia, the following sources were analyzed for C 14 and deuterium concentrations: potable water from the Ocala Limestone, contaminated water from the Ocala Limestone, saune water from the underlying Claiborne Group, and nearby ocean water. The chloride concentration of the groundwater ranges from about 25 ppm in the potable water to more than 2000 ppm in the deeper part of the Claiborne Group. From an interpretation of piezometric maps and other hydrologic data, previous investigators had concluded that the source of the contaminating water was the Claiborne Group and not the nearby ocean. The essentially uniform range of low values of −965 to −987‰ of the modern standard (National Bureau Standard C 14 oxalic acid) for the C 14 activity of the groundwater samples (regardless of the degree of contamination) is in agreement with this conclusion. If recent ocean water, which had a C 14 value of +285‰, were the source of contamination, the contaminated water would have had a C 14 activity higher than the activity of the fresh water. Deuterium analyses are not inconsistent with the interpretation that water from the Claiborne Group, rather than recent ocean water, is the source of the contaminating water. The concurrence of the hydrologic and the isotopic data in this area where the hydrology is well known suggests that isotopic analysis may be used to identify the origin of water in different portions of a hydrologic environment.

Georgia↗

Geochemical Modeling of the Madison Aquifer in Parts of Montana, Wyoming, and South Dakota

Stable isotope data for dissolved carbonate, sulfate, and sulfide are combined with water composition data to construct geochemical reaction models along eight flow paths in the Madison aquifer in parts of Wyoming, Montana, and South Dakota. The sulfur isotope data are treated as an isotope dilution problem, whereas the carbon isotope data are treated as Rayleigh distillations. All reaction models reproduce the observed chemical and carbon and sulfur isotopic composition of the final waters and are partially validated by predicting the observed carbon and sulfur isotopic compositions of dolomite and anhydrite from the Madison Limestone. The geochemical reaction models indicate that the dominant groundwater reaction in the Madison aquifer is dedolomitization (calcite precipitation and dolomite dissolution driven by anhydrite dissolution). Sulfate reduction, [Ca 2+ + Mg 2+ ]/Na + cation exchange, and halite dissolution are locally important, particularly in central Montana. The groundwater system is treated as closed to CO 2 gas from external sources such as the soil zone or cross‐formational leakage but open to CO 2 from oxidation of organic matter coupled with sulfate reduction and other redox processes occurring within the aquifer. The computed mineral mass transfers and modeled sulfur isotopic composition of Madison anhydrites are mapped throughout the study area. Carbon 14 groundwater ages, adjusted for the modeled carbon mass transfer, range from modern to about 23,000 years B.P. and indicate flow velocities of 7–87 ft/yr (2.1–26.5 m/yr). Most horizontal hydraulic conductivities calculated from Darcy's Law using the average 14 C flow velocities are within a factor of 5 of those based on digital simulation. The calculated mineral mass transfer and adjusted 14 C groundwater ages permit determination of apparent rates of reaction in the aquifer. The apparent rate of organic matter oxidation is typically 0.12 μmol/L/yr. Sulfate and, to a lesser extent, ferric iron are the predominant electron acceptors. The (kinetic) biochemical fractionation of 34 S between sulfate and hydrogen sulfide is approximately −44‰ at 25°C, with a temperature variation of −0.4‰ per °C. The rates of precipitation of calcite and dissolution of dolomite and anhydrite typically are 0.59, 0.24, and 0.95 μmol/L/yr, respectively. This paper is not subject to U.S. copyright. Published in 1990 by the American Geophysical Union.

Montana, Wyoming, South Dakota↗

The saline groundwater legacy of a large buried coastal paleo-estuary

Elevated groundwater salinity in coastal regions threatens the beneficial use of fresh groundwater. Coastal groundwater management typically focuses on preventing intrusion from modern sources of seawater; however, past geological processes can also leave a legacy of saline groundwater now hidden in the subsurface. Here, multiple extensive airborne electromagnetic surveys provide detailed evidence of residual salinity from a paleo-estuary filling a late Pleistocene incised valley impacting more than 10,000 km 2 that is now hidden beneath coastal Louisiana’s deltaic plain. Our results show that the three-dimensional pattern of saline groundwater beneath Louisiana mimics that of near-surface aquifers surrounding the modern Delaware Bay estuary, fingerprinting the signature of the past drowning of a large, incised valley of the Mississippi River following post-glacial sea-level rise. These findings demonstrate a new framework for understanding legacy sources of saltwater critical for managing stressed water resources along global coastlines.

Louisiana↗

Updating estimates of low-streamflow statistics to account for possible trends

Accurate estimators of streamflow statistics are critical to the design, planning, and management of water resources. Given increasing evidence of trends in low-streamflow, new approaches to estimating low-streamflow statistics are needed. Here we investigate simple approaches to select a recent subset of the low-flow record to update the commonly used statistic of 7 Q 10, the annual minimum 7-day streamflow exceeded in 9 out of 10 years on average. Informed by low-streamflow records at 174 US Geological Survey streamgages, Monte Carlo simulation experiments evaluate competing approaches. We find that a strategy which estimates 7 Q 10 using the most recent 30 years of record when a trend is detected, reduces error and bias in 7 Q 10 estimators compared to use of the full record. This simple rule-based approach has potential as the basis for a framework for updating frequency-based statistics in the context of possible trends.

Hydrologic Sciences Journal↗

A novel approach for next generation water use mapping using Landsat and Sentinel-2 satellite data

Evapotranspiration (ET) is needed in a range of applications in hydrology, climatology, ecology, and agriculture. Remote sensing-based estimation is the only viable and economical method for ET estimation over large areas. The current Landsat satellites provide images every 16 days limiting the ability to capture biophysical changes affecting ET. Thus, we explored the potential integration of Landsat 8 and Sentinel-2 data for estimating ET using a surface energy balance model. The results indicate the proposed Landsat-Sentinel data fusion approach substantially reduced relative errors from 48% to 10% on area-wide and from 49% to 17% on pixel-wide compared to linear interpolation between two Landsat images. The proposed approach had a better agreement with expected actual ET maps across high-vegetation conditions than in low-vegetation conditions. The finer temporal resolution and better accuracy of ET maps based on Landsat-Sentinel integration is of great importance in managing limited water resources.

Arizona, California↗

Nutrient delivery to Lake Winnipeg from the Red-Assiniboine River Basin – A binational application of the SPARROW model

Excessive phosphorus (TP) and nitrogen (TN) inputs from the Red–Assiniboine River Basin (RARB) have been linked to eutrophication of Lake Winnipeg; therefore, it is important for the management of water resources to understand where and from what sources these nutrients originate. The RARB straddles the Canada–United States border and includes portions of two provinces and three states. This study represents the first binationally focused application of SPAtially Referenced Regressions on Watershed attributes (SPARROW) models to estimate loads and sources of TP and TN by jurisdiction and basin at multiple spatial scales. Major hurdles overcome to develop these models included: (1) harmonization of geospatial data sets, particularly construction of a contiguous stream network; and (2) use of novel calibration steps to accommodate limitations in spatial variability across the model extent and in the number of calibration sites. Using nutrient inputs for a 2002 base year, a RARB TP SPARROW model was calibrated that included inputs from agriculture, forests and wetlands, wastewater treatment plants (WWTPs) and stream channels, and a TN model was calibrated that included inputs from agriculture, WWTPs and atmospheric deposition. At the RARB outlet, downstream from Winnipeg, Manitoba, the majority of the delivered TP and TN came from the Red River Basin (90%), followed by the Upper Assiniboine River and Souris River basins. Agriculture was the single most important TP and TN source for each major basin, province and state. In general, stream channels (historically deposited nutrients and from bank erosion) were the second most important source of TP. Performance metrics for the RARB SPARROW model are similarly robust compared to other, larger US SPARROW models making it a potentially useful tool to address questions of where nutrients originate and their relative contributions to loads delivered to Lake Winnipeg.

Manitoba, Minnesota, Saskatchewan↗

Baseflow and snowmelt sustained streamflow in the Upper Colorado River Basin, 1986-2020

The Upper Colorado River Basin (UCRB) faces substantial water availability limitations. Although most streamflow originates as snowmelt, the partitioning of snowmelt between surface runoff and groundwater recharge and subsequent groundwater discharge to streams is highly uncertain. On average, over half of the streamflow in the UCRB is estimated to originate from groundwater discharge to streams, highlighting the importance of baseflow in sustaining surface water. However, the historical patterns of baseflow and streamflow, along with their variability over space and time and their specific sources, remain unknown at the basin scale. This study addresses those gaps by characterizing the sources and transport pathways of both baseflow and streamflow in the UCRB at a seasonal timestep from 1986 to 2020, including the lagged delivery of subsurface water to streams beyond the current season, using coupled models of baseflow and streamflow. Between 1986 and 2020, on average 63% of UCRB streamflow originated from baseflow. About half of this baseflow took longer than one season to reach streams, and outside the snowmelt season, baseflow was the dominant source of streamflow. Snowmelt was a key source of both baseflow and streamflow. Current season snowmelt contributed 33% of streamflow via runoff, and 22% of the 29% of streamflow that originated as current season baseflow via subsurface flow to streams. Over the study period, baseflow index (BFI) declined in headwaters and increased at mid-elevations. Springtime increases in BFI demonstrate the increasingly important role baseflow plays in water supply. Identifying the sources, locations, and timing of water that contributed to the UCRB outlet can inform management of water resources in the basin.

Arizona, Colorado, New Mexico, Utah, Wyoming↗

Land management impacts on dairy-derived dissolved organic carbon in ground water

Dairy operations have the potential to elevate dissolved organic carbon (DOC) levels in ground water, where it may interact with organic and inorganic contaminants, fuel denitrification, and may present problems for drinking water treatment. Total and percent bioavailable DOC and total and carbon-specific trihalomethane (THM) formation potential (TTHMFP and STHMFP, respectively) were determined for shallow ground water samples from beneath a dairy farm in the San Joaquin Valley, California. Sixteen wells influenced by specific land management areas were sampled over 3 yr. Measured DOC concentrations were significantly elevated over the background as measured at an upgradient monitoring well, ranging from 13 to 55 mg L-1 in wells downgradient from wastewater ponds, 8 to 30 mg L-1 in corral wells, 5 to 12 mg L-1 in tile drains, and 4 to 15 mg L-1 in wells associated with manured fields. These DOC concentrations were at the upper range or greatly exceeded concentrations in most surface water bodies used as drinking water sources in California. DOC concentrations in individual wells varied by up to a factor of two over the duration of this study, indicating a dynamic system of sources and degradation. DOC bioavailability over 21 d ranged from 3 to 10%, comparable to surface water systems and demonstrating the potential for dairy-derived DOC to influence dissolved oxygen concentrations (nearly all wells were hypoxic to anoxic) and denitrification. TTHMFP measurements across all management units ranged from 141 to 1731 ??g L-1, well in excess of the maximum contaminant level of 80 ??g L-1 established by the Environmental Protection Agency. STHMFP measurements demonstrated over twofold variation (???4 to ???8 mmol total THM/mol DOC) across the management areas, indicating the dependence of reactivity on DOC composition. The results indicate that land management strongly controls the quantity and quality of DOC to reach shallow ground water and hence should be considered when managing ground water resources and in any efforts to mitigate contamination of ground water with carbon-based contaminants, such as pesticides and pharmaceuticals. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗

Arsenic speciation and sorption in natural environments

Aqueous arsenic speciation, or the chemical forms in which arsenic exists in water, is a challenging, interesting, and complicated aspect of environmental arsenic geochemistry. Arsenic has the ability to form a wide range of chemical bonds with carbon, oxygen, hydrogen, and sulfur, resulting in a large variety of compounds that exhibit a host of chemical and biochemical properties. Besides the intriguing chemical diversity, arsenic also has the rare capacity to capture our imaginations in a way that few elements can duplicate: it invokes images of foul play that range from sinister to comedic (e.g., “inheritance powder” and arsenic-spiked elderberry wine). However, the emergence of serious large-scale human health problems from chronic arsenic exposure in drinking water has placed a high priority on understanding environmental arsenic mobility, toxicity, and bioavailability, and chemical speciation is key to these important questions. Ultimately, the purpose of arsenic speciation research is to predict future occurrences, mitigate contamination, and provide successful management of water resources.

Reviews in Mineralogy and Geochemistry↗

Occurrence of selected pharmaceutical and non-pharmaceutical compounds, and stable hydrogen and oxygen isotope ratios, in a riverbank filtration study, Platte River, Nebraska, 2001 to 2003, Volume 1

Although studied extensively in recent years in Europe, the occurrence of endocrine disrupters and other organic wastewater compounds in the environment in the United States is not well documented. To better understand the efficiency of riverbank filtration with respect to endocrine disrupting compounds and to evaluate the use of riverbank filtration as an effective means of drinking-water treatment, a study was conducted during 2001-2003 by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the City of Lincoln, at an established riverbank-filtration well field with horizontal collector wells and vertical wells. This study provides information that will be useful for (1) increased understanding of the processes and factors important in controlling the transport of endocrine disrupters, such as pesticides and pharmaceuticals during riverbank filtration, (2) better understanding of the physical and chemical processes that affect riverbank-filtration efficiency, and (3) managing the water resources of the eastern Platte River Basin. This report presents analytical methods and data collected during the study. Data are presented as generalized statistics and in figures showing temporal variations. Sites from which water-quality samples were collected for this study included wastewater sites (a cattle feedlot lagoon, a hog confinement lagoon, and wastewater-treatment plant effluent), surface-water sites (Platte River, Salt Creek, and Loup Power Canal), ground-water sites (one collector well and three vertical wells), and drinking-water sites (raw and finished). Field water-quality properties were measured in samples from these sites. Pharmaceutical compounds were detected often in the wastewater-treatment plant effluent. Surface and ground water showed low-level concentrations of pharmaceuticals. Finished drinking-water samples did not contain detectable concentrations of pharmaceuticals except for low levels of cotinine and caffeine. Antibiotics were found in some of the wastewater samples and twice in Salt Creek. Antibiotics were not detected in any samples from the Platte River or the well field. Surface-water samples were analyzed for total organic carbon and ground-water samples were analyzed for dissolved organic carbon. Samples from all sites were analyzed for major ions. Herbicides commonly detected in surface, ground, and drinking water included acetachlor, alachlor, atrazine, and metolachlor as well as degradates of these compounds. Most of the samples from wastewater sites were found to contain predominantly acetamide degradates. High concentrations of several organic wastewater indicator compounds were detected at the wastewater sites and in Salt Creek. Several organic wastewater indicator compounds were detected multiple times in samples from the Platte River. Bromoform, a by-product of disinfection in the treatment plant, was found in samples from the finished drinking water. Stable hydrogen isotope ratios show a range in seasonal variation of -73.6 per mill to -38.1 per mill relative to Vienna Standard Mean Ocean Water (VSMOW) reference water and -69.2 per mill to -46.5 per mill for surface water and ground water, respectively. Oxygen isotope ratios for surface-water samples varied between -9.86 per mill and -5.05 per mill. Stable oxygen isotope ratios of ground waters varied between -9.62 per mill and -5.81 per mill.

Nebraska↗