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At least 631 records · Page 35Linked to original sources

USGS1988

Microbial and biogeochernical processes Soda Lake, Nevada

Meromictic, alkaline lakes represent modern-day analogues of lacustrine source rock depositional environments. In order to further our understanding of how these lakes function in terms of limnological and biogeochemical processes, we have conducted an interdisciplinary study of Big Soda Lake. Annual mixolimnion productivity (ca. 500 g m -2 ) is dominated by a winter diatom bloom (60% of annual) caused by upward transport of ammonia to the epilimnion. The remainder of productivity is attributable to chemoautotrophs (30%) and photosynthetic bacteria (10%) present at the oxic -anoxic interface from May to November. Studies of bacterial heterotrophy and particulate fluxes in the water column indicate that about 90% of annual productivity is remineralized in the mixolimnion, primarily by fermentative bacteria. However, high rates of sulphate reduction (9-29 mmol m -2 yr -1 ) occur in the monimolimnion waters, which could remineralize most (if not all) of the primary productivity. This discrepancy has not as yet been fully explained. Low rates of methanogenesis also occur in the monimolimnion waters and sediments. Most of the methane is consumed by anaerobic methane oxidation occurring in the monimolimnion water column. Other bacterial processes occurring in the lake are also discussed. Preliminary studies have been made on the organic geochemistry of the monimolimnion sediments. Carbon-14-dating indicates a lower depositional rate prior to meromixis and a downcore enrichment in 13 C of organic carbon and chlorophyll derivatives. Hydrous pyrolysis experiments indicate that the sediment organic matter is almost entirely derived from the water column with little or no contribution from terrestrial sources. The significance of the organics released by hydrous pyrolysis is discussed.

Book chapter↗

USGS2016

Silicic lunar volcanism: Testing the crustal melting model

Lunar silicic rocks were first identified by granitic fragments found in samples brought to Earth by the Apollo missions, followed by the discovery of silicic domes on the lunar surface through remote sensing. Although these silicic lithologies are thought to make up a small portion of the lunar crust, their presence indicates that lunar crustal evolution is more complex than originally thought. Models currently used to describe the formation of silicic lithologies on the Moon include in situ differentiation of a magma, magma differentiation with silicate liquid immiscibility, and partial melting of the crust. This study focuses on testing a crustal melting model through partial melting experiments on compositions representing lithologies spatially associated with the silicic domes. The experiments were guided by the results of modeling melting temperatures and residual melt compositions of possible protoliths for lunar silicic rocks using the thermodynamic modeling software, rhyolite-MELTS. Rhyolite-MELTS simulations predict liquidus temperatures of 950–1040 °C for lunar granites under anhydrous conditions, which guided the temperature range for the experiments. Monzogabbro, alkali gabbronorite, and KREEP basalt were identified as potential protoliths due to their ages, locations on the Moon (i.e., located near observed silicic domes), chemically evolved compositions, and the results from rhyolite-MELTS modeling. Partial melting experiments, using mixtures of reagent grade oxide powders representing bulk rock compositions of these rock types, were carried out at atmospheric pressure over the temperature range of 900–1100 °C. Because all lunar granite samples and remotely sensed domes have an elevated abundance of Th, some of the mixtures were doped with Th to observe its partitioning behavior. Run products show that at temperatures of 1050 and 1100 °C, melts of the three protoliths are not silicic in nature (i.e., they have <63 wt% SiO 2 ). By 1000 °C, melts of both monzogabbro and alkali gabbronorite approach the composition of granite, but are also characterized by immiscible Si-rich and Fe-rich liquids. Furthermore, Th strongly partitions into the Fe-rich, and not the Si-rich glass in all experimental runs. Our work provides important constraints on the mechanism of silicic melt formation on the Moon. The observed high-Th content of lunar granite is difficult to explain by silicate liquid immiscibility, because through this process, Th is not fractionated into the Si-rich phase. Results of our experiments and modeling suggests that silicic lunar rocks could be produced from monzogabbro and alkali gabbronorite protoliths by partial melting at T < 1000 °C. Additionally, we speculate that at higher pressures ( P ≥ 0.005 GPa), the observed immiscibility in the partial melting experiments would be suppressed.

American Mineralogist↗

USGS1976

Water resources of Lincoln County coastal area, Oregon

The Lincoln County coastal area is underlain by Tertiary volcanic and sedimentary rocks of low permeability that store only a small volume of the annual precipitation which averages 68 inches (1,730 millimeters). Consequently, the Tertiary units yield small quantities of water to wells and furnish little ground-water discharge to maintain the base flow of streams. Although streamflow is normally abundant during the wet season, flow decreases greatly during summer when needed most. Quaternary marine terrace deposits of semiconsolidated sand border the western part of the area and are the most productive aquifers. Several wells drilled into the Quaternary deposits are among the highest producing wells of the area, with yields of 25 to 60 gallons per minute (1.6 to 3.8 liters per second). The Siletz River Volcanics is one of the better aquifers in the area and generally yields water in volumes sufficient for domestic use. The average well drilled into these rocks yields 5 to 10 gallons per minute (0.3 to 0.6 liters per second). Locally, this formation is quite permeable and has a producing well in the study area, with a yield of 120 gallons per minute (7.6 liters per second). Other volcanic rocks of small areal extent and largely untested, are the basalts near Depoe Bay, Cape Foulweather, Yachats, and Cape Perpetua. Wells drilled in January 1976 near Depoe Bay indicate that as much as 125 gal/min (10 L/s) of water can be obtained from wells drilled into the basalt. Tertiary marine sedimentary rocks of siltstone and sandstone are widespread throughout the area. Yields of wells drilled in these rocks are generally low (less than 5 gallons per minute, or 0.3 liters per second), and many wells in these formations produce no usable quantities of ground water. Approximately 5,000,000 acre-feet (6,000 cubic hectometers) of water discharges annually into the Pacific Ocean from all streams along the Lincoln County coast. About 85 percent of the annual streamflow occurs from November through April. Minimum streamflaws occur from August through October when, at times, as little as 450 acre-feet (55 hectometers) per day flows from all streams. Most of the ground water, with the exception of water from some wells drilled in the marine siltstone and sandstone, contains relatively small concentrations of dissolved minerals. Wells that tap the marine deposits at low altitudes have high concentrations of dissolved minerals, particularly sodium and chloride. In general, analyses of water from the 14 streams sampled in Lincoln County show very good chemical quality. The iron content of Depoe and Thiel Creeks is above the Environmental Protection Agency's recommended limit of 0.3 milligrams per liter for drinking water. Annual water use totals 6.7 billion gallons, which is less than 0.5 percent of runoff. About 70 percent of the use is for industrial purposes at one lumber products mill, about 25 percent is for public supplies, and less than 5 percent for irrigation. Water supplies for all municipalities in Lincoln County currently (1975) are obtained from surface-water sources. Because of rapid economic development of the coastal area, it is expected that additional water will be needed in the future. Additional water can be supplied (1) by reservoirs on major streams; (2) by the expansion, in some locations, of present surface-water facilities on small streams; and (3) locally, by an additional small volume of supplemental water from ground-water sources.

Oregon↗

USGS1930

Shorter contributions to general geology, 1929

Thin beds that consist almost wholly of euhedral analcite crystals occur at five or more horizons in the upper half of the Green River formation of Utah and Colorado, a series of Eocene lake beds that contain large deposits of oil shale. Most of these beds contain also minute crystals of apophyllite. The analcite crystals in some beds are cemented only by chalcedony, but in other beds that have less analcite the matrix is tuffaceous and consists of chalcedony in which are embedded splinters of feldspar, hornblende, and quartz, laths of biotite, and euhedral crystals of sanidine, apatite, and zircon. Analcite occurs plentifully also, disseminated in many of the oil-shale beds, and locally makes up as much as 16 per cent of weight of the rock. In these beds the analcite is accompanied by apophyllite, euhedral crystals of sanidine and orthoclase, angular fragments of quartz, and a little volcanic glass. The rocks associated with the beds of analcite and analcite-bearing oil shale contain salt-crystal cavities, that strongly suggest the former presence of glauberite and anhydrite. Both clastic and hydrothermal hypotheses for the origin of the zeolites are considered and dismissed in the paper. The field and microscopic evidence presented leads to the conclusion that all the analcite and apophyllite formed in place on the lake bottom as a result of interactions between salts dissolved in the lake water and the dissolution products of volcanic ash that fell into the lake. Meerschaum, or fibrous sepiolite, occurs in several thin beds near the top of the Green River formation in Duchesne County, Utah. It is mixed with structureless organic matter like that in the oil shale and apparently formed in place on the lake bottom. Chemical analyses of the analcite rock and of the sepiolite are given.

Professional Paper↗

USGS1989

Uranium-series nuclides in the Golden fault, Colorado, U.S.A.: Dating latest fault displacement and measuring recent uptake of radionuclides by fault-zone materials

Concentrations and isotopic ratios of U, Th and Ra were measured in a fault zone near Golden, Colorado where major displacement occurred between about 190 and 615 ka. Faulting created new surfaces for leaching and provided the pathways for U-rich ground water. Uranium and 230 Th, the latter produced by the decay of dissolved 234 U, are adsorbed by fault gouge, hematite-stained sand and brecciated sand- and claystones. The observed U enrichment is as much as six times baseline value and the simultaneous enrichment of 230 Th is estimated at about ninefold relative to 238 U. The adsorption of radionuclides chemically analogous to Th, such as Pu (IV) and Np, and 237 Np decay products, on fault-zone materials would contribute to the immobilization of high-level radioactive waste in the vicinity of a repository in the event of leakage from engineered barriers into fractured rock-mass.

Colorado↗

USGS2022

Microbial community response to a bioaugmentation test to degrade trichloroethylene in a fractured rock aquifer, Trenton, N.J

Bioaugmentation is a promising strategy for enhancing trichloroethylene (TCE) degradation in fractured rock. However, slow or incomplete biodegradation can lead to stalling at degradation byproducts such as 1,2-dichloroethene ( cis -DCE) and vinyl chloride (VC). Over the course of 7 years, we examined the response of groundwater microbial populations in a bioaugmentation test where an emulsified vegetable oil solution (EOS ® ) and a dechlorinating consortium (KB-1 ® ), containing the established dechlorinator Dehalococcoides (DHC), were injected into a TCE-contaminated fractured rock aquifer. Indigenous microbial communities responded within 2 days to added substrate and outcompeted KB-1 ® , and over the years of monitoring, several other notable turnover events were observed. Concentrations of ethene, the end product in reductive dechlorination, had the strongest correlations ( P < .05) with members of Candidatus Colwellbacteria but their involvement in reductive dechlorination is unknown and warrants further investigation.DHC never exceeded 0.6% relative abundance of groundwater microbial communities, despite its previously presumed importance at the site. Increased concentrations of carbon dioxide, acetic acid, and methane were positively correlated with increasing ethene concentrations; however, concentrations of cis- DCE and VC remained high by the end of the monitoring period suggesting preferential enrichment of indigenous partial dechlorinators over bioaugmented complete dechlorinators. This study highlights the importance of characterizing in situ microbial populations to understand how they can potentially enhance or inhibit augmented TCE degradation.

New Jersey↗

USGS1959

Ground-water provinces of India

This paper gives a general resume of ground-water utilization and development and describes the occurrence of water in eight ground-water provinces of India. The paper is based in part on observations of the writer during 1951-55 and in part on earlier work of the Geological Survey of India. Ground water has been utilized extensively in India since before the beginning of the Christian era. Currently (1956) ground water is an important source of supply for domestic, stock, municipal, and industrial needs throughout the Republic and is widely used for irrigation in the Peninsular and Ganges-Brahmaputra regions west of longitude 85°. Dug, bored, and drilled wells are the principal means by which ground water is developed, although locally infiltration tunnels or improved springs are used. Methods of lifting or pumping water from wells include the hand line and bucket, the hand-lift pump, the counterpoised sweep, bullocks, and "mote," the water wheel, horizontal and vertical centrifugal pumps, and deep-well turbine pumps. The most common device for lifting water for irrigation is still the time-honored bullock and "mote" (leather bag). However, in modern India there is increasing use of mechanical pumps. With respect to the occurrence of ground water, India can be divided into eight provinces, lying in three major regions, (1) the Peninsular region, (2) the Ganges-Brahmaputra region, and (3) the Himalayan region. The Peninsular region contains six ground-water provinces. Precambrian igneous, metamorphic, and indurated sedimentary rocks and early Tertiary volcanic rocks in three of these provinces yield many small supplies of water, which generally is of good quality but locally is brackish or salty. Cretaceous water-bearing sandstones in another province are moderately productive and in places are developed for large water supplies. Late Tertiary and Quaternary water-bearing sands and gravels in two other provinces sustain many small water supplies and several large water supplies-particularly in the coastal areas of southern India. The Ganges-Brahmaputra region is a single ground-water province in which many tens of thousands of small water supplies and several thousand large supplies are obtained from water-bearing sands and gravels in late Tertiary and Quaternary alluvium. This province constitutes a vast groundwater reservoir, which is the most productive in India. The Himalayan region also is considered as a single province, in which ground water occurs in a series of narrow valleys filled with moderately to highly permeable Quaternary alluvium. These alluvial valleys transmit large quantities of water to the ground-water reservoir in the Ganges-Brahmaputra region.

Economic Geology↗

USGS2001

Alteration and mineralization in the eastern part of the Soldier Mountains, Camas County, Idaho

The eastern part of the Soldier Mountains in Camas County, south-central Idaho, is underlain principally by plutonic rocks of Cretaceous and Eocene age that locally have undergone propylitic, potassic, and muscovite-quartz alteration. Muscovite- quartz alteration is Cretaceous in age and is localized along joints and fractures, some of which are filled with quartz. Associated veins have yielded minor amounts of gold. Potassic alteration is probably both Cretaceous and Eocene in age but is weakly developed and limited in extent. Propylitic alteration is Eocene in age and is pronounced around biotite granite plutons. Despite a clear association between plutons of biotite granite and widespread propylitic alteration, mineralization associated with these rocks was minimal. Mineralized areas within more mafic Eocene plutons are characterized by veins and (or) stockworks(?) enriched in copper, molybdenum, and silver, but these areas are restricted in size and have not been productive.

Bulletin↗

USGS1958

Origin of manganese deposits of Busuanga Island, Philippines

The manganese deposits of Busuanga Island, Palawan, are tabular and broadly lenticular bodies which lie conformably within a thick sequence of deformed abort beds. The purpose of this study is to determine the probable mode of origin of the deposits. Similar deposits in other parts of the world have been described by others as products of several different genetic processes. Field and laboratory methods of research were employed in the course of the investigation. Detailed geologic mapping was done on the surface and underground, and many samples of rocks and ores were obtained. Later, intensive study of samples from four typical deposits and from the rooks in the surrounding areas was undertaken, using a variety of laboratory techniques. Microscopic study of thin sections and polished surfaces was supplemented by X-ray and chemical work. More than one hundred X-ray diffraction powder photographs were made to identify minerals, and qualitative chemical studies were made of a number of aamples by use of the X-ray spectrograph. In addition, quantitative chemical analyses were made of certain samples. Finally, published accounts of the occurrence and geological behavior of manganese and silica were consulted to aid in interpretation of the data at hand. Oherty layers in the manganese deposits are lithologically similar to the chart wallrooks and country rook beds. Radiolarian fossils are common in the chart and are also found in some ore specimens. Manganese content of the wallrocks and the country rock beds, however, in essentially nil. The manganese deposits contain mostly psilomelane-type oxides in their near-surface parts, and in the deepest mines this ore grades downward into siliceous protore. In three of the deposits studied, the protore consists mainly of braanite and quartz; in the fourth deposit, hausmannite and the silicate alleghatvite make up the milk of the protore. Some of the protoro is massive, but cherty stones are commonly well layered parallel to the wall rock structure. Grain size is very small, but, like the silica in the chert beds, becomes relatively coarse where the rocks are much deformed. No evidence of large-scale replacement or cross-cutting veins is found in the protores. It is concluded that the original manganiferous deposits were largely non-clastic or oolloidal marine sediments laid down in a reducing environment. The protorea were developed from these beds by processes of diagenesis and low-grade regional metamorphism. The protores were in turn altered to black oxide ore by near-surface agencies during the present erosion cycle. Particular interest is attached to the occurrence of alleghanyite and traces of pyroxmangite and hubnerite(?) in the protorea.

Busuanga Island↗

USGS2017

Stratigraphic cross sections of the Niobrara interval of the Cody Shale and associated rocks in the Wind River Basin, central Wyoming

The Wind River Basin in Wyoming is one of many structural and sedimentary basins that formed in the Rocky Mountain foreland during the Laramide orogeny. The basin is nearly 200 miles long, 70 miles wide, and encompasses about 7,400 square miles in central Wyoming. The basin is bounded by the Washakie Range, Owl Creek uplift, and southern Bighorn Mountains on the north, the Casper arch on the east, the Granite Mountains on the south, and Wind River Range on the west. Many important conventional oil and gas fields producing from reservoirs ranging in age from Mississippian through Tertiary have been discovered in this basin. In addition, an extensive unconventional overpressured basin-centered gas accumulation has been identified in Cretaceous and Tertiary strata in the deeper parts of the basin. It has long been suggested that various Upper Cretaceous marine shales, including the Cody Shale, are the principal hydrocarbon source rocks for many of these accumulations. With recent advances and success in horizontal drilling and multistage fracture stimulation, there has been an increase in exploration and completion of wells in these marine shales in other Rocky Mountain Laramide basins that were traditionally thought of only as hydrocarbon source rocks. The two stratigraphic cross sections presented in this report were constructed as part of a project carried out by the U.S. Geological Survey to characterize and evaluate the undiscovered continuous (unconventional) oil and gas resources of the Niobrara interval of the Upper Cretaceous Cody Shale in the Wind River Basin in central Wyoming. The primary purpose of the cross sections is to show the stratigraphic relationship of the Niobrara equivalent strata and associated rocks in the lower part of the Cody Shale in the Wind River Basin. These two cross sections were constructed using borehole geophysical logs from 37 wells drilled for oil and gas exploration and production, and one surface section along East Sheep Creek near Shotgun Butte in the northwestern part of the basin. Both lines originate at the East Sheep Creek surface section and end near Clarkson Hill in the extreme southeastern part of the basin. The stratigraphic interval extends from the upper part of the Frontier Formation to the middle part of the Cody Shale. The datum is the base of the “chalk kick” marker bed, a distinctive resistivity peak or zone in the lower part of the Cody Shale. A gamma ray and (or) spontaneous potential (SP) log was used in combination with a resistivity log to identify and correlate units. Marine molluscan index fossils collected from nearby outcrop sections were projected into the subsurface to help determine the relative ages of the strata and aid in correlation.

Wyoming↗

USGS2017

Application of at-site peak-streamflow frequency analyses for very low annual exceedance probabilities

The U.S. Geological Survey (USGS), in cooperation with the U.S. Nuclear Regulatory Commission, has investigated statistical methods for probabilistic flood hazard assessment to provide guidance on very low annual exceedance probability (AEP) estimation of peak-streamflow frequency and the quantification of corresponding uncertainties using streamgage-specific data. The term “very low AEP” implies exceptionally rare events defined as those having AEPs less than about 0.001 (or 1 × 10 –3 in scientific notation or for brevity 10 –3 ). Such low AEPs are of great interest to those involved with peak-streamflow frequency analyses for critical infrastructure, such as nuclear power plants. Flood frequency analyses at streamgages are most commonly based on annual instantaneous peak streamflow data and a probability distribution fit to these data. The fitted distribution provides a means to extrapolate to very low AEPs. Within the United States, the Pearson type III probability distribution, when fit to the base-10 logarithms of streamflow, is widely used, but other distribution choices exist. The USGS-PeakFQ software, implementing the Pearson type III within the Federal agency guidelines of Bulletin 17B (method of moments) and updates to the expected moments algorithm (EMA), was specially adapted for an “Extended Output” user option to provide estimates at selected AEPs from 10 –3 to 10 –6 . Parameter estimation methods, in addition to product moments and EMA, include L-moments, maximum likelihood, and maximum product of spacings (maximum spacing estimation). This study comprehensively investigates multiple distributions and parameter estimation methods for two USGS streamgages (01400500 Raritan River at Manville, New Jersey, and 01638500 Potomac River at Point of Rocks, Maryland). The results of this study specifically involve the four methods for parameter estimation and up to nine probability distributions, including the generalized extreme value, generalized log-normal, generalized Pareto, and Weibull. Uncertainties in streamflow estimates for corresponding AEP are depicted and quantified as two primary forms: quantile (aleatoric [random sampling] uncertainty) and distribution-choice (epistemic [model] uncertainty). Sampling uncertainties of a given distribution are relatively straightforward to compute from analytical or Monte Carlo-based approaches. Distribution-choice uncertainty stems from choices of potentially applicable probability distributions for which divergence among the choices increases as AEP decreases. Conventional goodness-of-fit statistics, such as Cramér-von Mises, and L-moment ratio diagrams are demonstrated in order to hone distribution choice. The results generally show that distribution choice uncertainty is larger than sampling uncertainty for very low AEP values.

Scientific Investigations Report↗

USGS2025

Reconstruction of Holocene and Last Interglacial vegetation dynamics and wildfire activity in Southern Siberia

Wildfires are a rapidly increasing threat to boreal forests. While our understanding of the drivers behind wildfires and their environmental impact is growing, it is mostly limited to the observational period. Here we focus on the boreal forests of southern Siberia and exploit a U–Th-dated stalagmite from Botovskaya Cave, located in the upper Lena region of southern Siberia, to document wildfire activity and vegetation dynamics during parts of two warm periods: the Last Interglacial (LIG; specifically part of the Last Interglacial maximum between 124.1 and 118.8 ka) and the Holocene (10–0 ka). Our record is based on levoglucosan (Lev), a biomarker sensitive to biomass burning, and on lignin oxidation products (LOPs) that discriminate between open and closed forest and hard- or softwood vegetation. In addition, we used carbonate carbon stable isotope ratios ( δ 13 C ), which reflect a dominant control of the host rock, to evaluate soil respiration and local infiltration changes. Our LOP data suggest that, during the Last Interglacial, the region around Botovskaya Cave was characterised by open forest, which by ca. 121.5 ka underwent a transition from fire-resistant hardwood to fire-prone softwood. The Lev record indicates that fire activity was high and increased towards the end of Last Interglacial just before 119 ka. In contrast, the Holocene was characterised by a closed-forest environment with mixed hard- and softwood vegetation. Holocene fire activity varied but at a much lower level than during the Last Interglacial. We attribute the changes in wildfire activity during the intervals of interest to the interplay between vegetation and climate. The open forests of the Last Interglacial were more likely to ignite than their closed Holocene equivalents, and their flammability was aided by warmer and drier summers and a stronger seasonal temperature contrast due to the increase in seasonal insolation difference compared to the Holocene. Our comparison of the last two interglacial intervals suggests that, with increasing global temperatures, the boreal forest of southern Siberia may become progressively more vulnerable to higher wildfire activity.

Botovskaya Cave, Siberia↗

USGS2025

Depth of magma crystallization and fluid exsolution beneath the porphyry-skarn Cu deposits at Santa Rita and Hanover-Fierro, New Mexico, USA

The depth level at which porphyry Cu–forming magmas fractionated and exsolved mineralizing fluids is actively debated. In the classic model, extensive magma fractionation occurs in large, upper crustal magma chambers, and concomitant fluid exsolution leads to forceful expulsion of residual magmas in the form of porphyry dikes, stocks, and breccia pipes, which subsequently serve as pathways for the mineralizing fluids. In contrast, some recent studies highlighting the role of deep crustal magma fractionation in the production of fertile magmas essentially deny the existence of upper crustal magma chambers at the time of mineralization. To address this, we conducted a detailed thermobarometric investigation of 13 intermediate to felsic, porphyritic intrusive rocks related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, United States, representing two premineralization magmas (61–60 Ma), seven synmineralization magmas (60–58 Ma), and four late- to postmineralization magmas (58–57 Ma). For each sample, the pressure of last magma crystallization before final magma ascent to the current exposure level was reconstructed based on Al-in-hornblende barometry of small hornblende inclusions trapped within quartz phenocrysts and through titanium-in-quartz (TitaniQ) thermobarometry of the host quartz phenocrysts themselves. Since quartz is one of the last crystallizing magmatic minerals, and no significant phenocryst growth could have occurred in small dikes and stocks after final magma emplacement, quartz phenocrysts and their contained hornblende inclusions record the depth of last magma crystallization before final magma ascent. When present, hornblende phenocrysts and hornblende inclusions within other major phenocrysts were also analyzed. Both quartz and hornblende barometers return consistent average pressures of 3.2 ± 0.4 kbar for the entire suite of pre- to postmineralization magmas, corresponding to depths of 11 to 14 km. The synmineralization magmas return even more consistent average pressures of 3.1 ± 0.2 kbar, corresponding to a depth of 12 ± 1 km. The volume of the mineralizing porphyry dikes and stocks at the emplacement level is far too small to have provided all the fluids and metals required to form the observed ore deposits. Therefore, the majority of the ore-forming fluids must have originated from the magmas that crystallized at 12 ± 1 km depth. The ore deposits, conversely, formed at ~5-km paleodepth. This implies that most of the mineralizing fluids traveled an average vertical distance of ~7 km from their magmatic source to the eventual site of ore precipitation. The relatively unaltered nature and low veining degree of deeper parts of mineralized porphyry dikes and stocks suggest that the fluid transport through these intrusive bodies occurred mostly at near-solidus conditions by means of fluid percolation along grain boundaries. In summary, our results suggest that (1) a large, upper crustal pluton exists ~7 km beneath the Santa Rita and Hanover-Fierro deposits; (2) abundant phenocryst crystallization occurred at this depth level; and (3) this pluton was the main source for the exsolution of ore-forming fluids. However, the investigated rocks have elevated whole-rock Sr/Y ratios, indicating magma fractionation at deep crustal levels. As a result, our preferred model is a combination of the two end-member models introduced above, with most magma fractionation having occurred in the deep crust and with residual, intermediate to felsic melts having ascended and accumulated at 11 to 14 km paleodepth, where they continued to crystallize with comparatively little crystal-liquid separation, before some of these magmas ascended further to shallow levels and quenched to porphyries.

New Mexico↗

USGS2013

Zirconium

Zirconium is the 20th most abundant element in the Earth’s crust. It occurs in a variety of rock types and geologic environments but most often in igneous rocks in the form of zircon (ZrSiO 4 ). Zircon is recovered as a coproduct of the mining and processing of heavy mineral sands for the titanium minerals ilmenite and rutile. The sands are formed by the weathering and erosion of rock containing zircon and titanium heavy minerals and their subsequent concentration in sedimentary systems, particularly in coastal environments. A small quantity of zirconium, less than 10 kt/a (11,000 stpy), compared with total world production of 1.4 Mt (1.5 million st) in 2012, was derived from the mineral baddeleyite (ZrO 2 ), produced from a single source in Kovdor, Russia.

Mining Engineering↗

USGS2009

A marine biogeochemical perspective on black shale deposition

Deposition of marine black shales has commonly been interpreted as having involved a high level of marine phytoplankton production that promoted high settling rates of organic matter through the water column and high burial fluxes on the seafloor or anoxic (sulfidic) water-column conditions that led to high levels of preservation of deposited organic matter, or a combination of the two processes. Here we review the hydrography and the budgets of trace metals and phytoplankton nutrients in two modern marine basins that have permanently anoxic bottom waters. This information is then used to hindcast the hydrography and biogeochemical conditions of deposition of a black shale of Late Jurassic age (the Kimmeridge Clay Formation, Yorkshire, England) from its trace metal and organic carbon content. Comparison of the modern and Jurassic sediment compositions reveals that the rate of photic zone primary productivity in the Kimmeridge Sea, based on the accumulation rate of the marine fraction of Ni, was as high as 840 g organic carbon m − 2 yr −1 . This high level was possibly tied to the maximum rise of sea level during the Late Jurassic that flooded this and other continents sufficiently to allow major open-ocean boundary currents to penetrate into epeiric seas. Sites of intense upwelling of nutrient-enriched seawater would have been transferred from the continental margins, their present location, onto the continents. This global flooding event was likely responsible for deposition of organic matter-enriched sediments in other marine basins of this age, several of which today host major petroleum source rocks. Bottom-water redox conditions in the Kimmeridge Sea, deduced from the V:Mo ratio in the marine fraction of the Kimmeridge Clay Formation, varied from oxic to anoxic, but were predominantly suboxic, or denitrifying. A high settling flux of organic matter, a result of the high primary productivity, supported a high rate of bacterial respiration that led to the depletion of O 2 in the bottom water. A high rate of burial of labile organic matter, albeit a low percentage of primary productivity, in turn promoted anoxic conditions in the sediment pore waters that enhanced retention of trace metals deposited from the water column.

Earth-Science Reviews↗

USGS2009

Update on subsidence at the Wairakei-Tauhara geothermal system, New Zealand

The total subsidence at the Wairakei field as a result of 50 years of geothermal fluid extraction is 15 ?? 0.5 m. Subsidence rates in the center of the subsidence bowl have decreased from over 450 mm/year during the 1970s to 80-90 mm/year during 2000-2007. The location of the bowl, adjacent to the original liquid outflow zone of the field, has not changed significantly. Subsidence at the Tauhara field due to Wairakei production was not as well documented in the early years but appeared later and has been less intense than at Wairakei. Total subsidence of 2.6 ?? 0.5 m has also occurred close to the original liquid outflow zone of this field, and maximum subsidence rates in this area today are in the 80-100 mm/year range. In the western part of the Wairakei field, near the area of hot upflow, subsidence rates have approximately doubled during the last 20 years to 30-50 mm/year. This increase appears to be have been caused by declining pressure in the underlying steam zone in this area, which is tapped by some production wells. At Tauhara field, two areas of subsidence have developed since the 1990s with rates of 50-65 mm/year. Although less well-determined, this subsidence may also be caused by declining pressure in shallow steam zones. The cause of the main subsidence bowls in the Wairakei-Tauhara geothermal system is locally high-compressibility rocks within the Huka Falls Formation (HFF), which are predominantly lake sediments and an intervening layer of pumice breccia. At Wairakei, casing deformation suggests the greatest compaction is at 150-200 m depth. The cause of the large compressibility is inferred to be higher clay content in the HFF due to intense hydrothermal alteration close to the natural fluid discharge areas. Future subsidence is predicted to add an additional 2-4 m to the Wairakei bowl, and 1-2 m elsewhere, but these estimates depend on the assumed production-injection scenarios.

Geothermics↗

USGS1992

Lake trout spawning habitat in the Six Fathom Bank-Yankee Reef lake trout sanctuary, Lake Huron

Attempts to reestablish self-sustaining stocks of lake trout ( Salvelinus namaycush ) in the lower four Great Lakes, where the species was extinguished in the 1950s and 1960s, have been largely unsuccessful. To avoid many of the problems believed to be contributing to this failure, the fishery management community recently established several sanctuaries in the offshore waters of the Great Lakes where the development and protection of self-sustaining stocks of lake trout would be a primary management objective. One of these, the Six Fathom Bank-Yankee Reef sanctuary, was created in the south-central portion of Lake Huron. This sanctuary covers 168,000 ha and includes the shallower portions of the Six Fathom and Ipperwash scarps, which are major bathymetric features in the southern half of the lake. Historical accounts describe Six Fathom Bank as the most important lake trout spawning ground in the lake. Here we present the results of lake bed surveys conducted in the sanctuary with side-scan sonar, underwater videocamera systems, and a small research submarine. Our observations of the lake bed are consistent with what is known of the bedrock stratigraphy, glacial history, and karst geomorphology of the Lake Huron basin. Most of the loose rock we found seemed to be derived from local carbonate bedrock formations, although non-carbonate rock probably from Precambrian sources to the north was also present in some areas. Much of the bedrock and loose rock displayed karst solution features described for the Bruce Peninsula on the Ontario shoreline. Our surveys revealed substantial areas of lake bed at water depths of 20–36 m that resembled suitable spawning and fry production habitat for the shallow-water strains of lake trout that are the focus of the rehabilitation effort. Low mid-lake nutrient levels documented recently by others and the extremely high abundance of Mysis relicta (an important item in the diet of young lake trout) that we documented on Yankee Reef also contributed to our evaluation of the sanctuary as a site with high potential to support a self-sustaining population of lake trout.

Journal of Great Lakes Research↗

USGS2002

Determination of lithium in rocks by distillation

A method for the quantitative extraction and recovery of lithium from rocks is based on a high temperature volatilization procedure. The sample is sintered with a calcium carbonate-calcium chloride mixture at 1200° C. for 30 minutes in a platinum ignition tube, and the volatilization product is collected in a plug of Pyrex glass wool in a connecting Pyrex tube. The distillate, which consists of the alkali chlorides with a maximum of 5 to 20 mg. of calcium oxide and traces of a few other elements, is removed from the apparatus by dissolving in dilute hydrochloric acid and subjected to standard analytiaal procedures. The sinter residues contained less than 0.0005% lithium oxide. Lithium oxide was recovered from synthetic samples with an average error of 1.1%.

Analytical Chemistry↗