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At least 559 records · Page 31Linked to original sources

Estimating the effects of forest structure changes from wildfire on snow water resources under varying meteorological conditions

Modeling forest change effects on snow is critical to resource management. However, many models either do not appropriately model canopy structure or cannot represent fine‐scale changes in structure following a disturbance. We applied a 1 m 2 resolution energy budget snowpack model at a forested site in New Mexico, USA, affected by a wildfire, using input data from lidar to represent prefire and postfire canopy conditions. Both scenarios were forced with 37 years of equivalent meteorology to simulate the effect of fire‐mediated canopy change on snowpack under varying meteorology. Postfire, the simulated snow distribution was substantially altered, and despite an overall increase in snow, 32% of the field area displayed significant decreases, resulting in higher snowpack variability. The spatial differences in snow were correlated with the change in several direction‐based forest structure metrics (aspect‐based canopy edginess and gap area). Locations with decreases in snow following the fire were on southern aspects that transitioned to south facing canopy edges, canopy gaps that increased in size to the south, or where large trees were removed. Locations with largest increases in snow occurred where all canopy was removed. Changes in canopy density metrics, typically used in snow models to represent the forest, did not fully explain the effects of fire on snow distribution. This explains why many models are not able to represent greater postfire variability in snow distribution and tend to predict only increases in snowpack following a canopy disturbance event despite observational studies showing both increases and decreases.

New Mexico↗

Accounting for fine-scale forest structure is necessary to model snowpack mass and energy budgets in montane forests

Accurately modeling the effects of variable forest structure and change on snow distribution and persistence is critical to water resource management. The resolution of many snow models is too coarse to represent heterogeneous canopy structure in forests, and therefore, most models simplify forest effects on snowpack mass and energy budgets. To quantify the loss of snowpack prediction from simplifications of forest canopy-mediated processes, we applied a high-resolution energy balance snowpack model at two forested sites at a fine (1 m 2 ) and coarse (100 m 2 ) spatial resolution. Simulating open and forested areas separately, as is done in many land surface models (LSMs), leads to biases between the coarse and fine-scale simulations because there is no representation of areas that are near (e.g., <15 m from) trees but with no overhead canopy, which are common in forests of low to medium tree density. Consistent with previous LSM intercomparisons, the coarser simulations predict greater under-canopy radiation (by 30%–80% at our sites), faster snow ablation (by almost 2×), and earlier snow disappearance (by 1–22 days). Many of these biases are reduced dramatically or eliminated when canopy edge environments are considered in the coarser simulations. Furthermore, remaining disagreement between the 100-m and 1-m models can be partially explained by using a combination of tree height, canopy cover, and canopy edginess (which together can explain 46%–96% of remaining model biases). The lack of information about canopy edges and other fine-scale forest structure characteristics in many current LSMs may limit their reliability for simulating forest disturbance.

California, New Mexico↗

Deep structure of Siletzia in the Puget Lowland: Imaging an obducted plateau and accretionary thrust belt with potential fields

Detailed understanding of crustal components and tectonic history of forearcs is important due to their geological complexity and high seismic hazard. The principal component of the Cascadia forearc is Siletzia, a composite basaltic terrane of oceanic origin. Much is known about the lithology and age of the province. However, glacial sediments blanketing the Puget Lowland obscure its lateral extent and internal structure, hindering our ability to fully understand its tectonic history and its influence on modern deformation. In this study, we apply map-view interpretation and two-dimensional modeling of aeromagnetic and gravity data to the magnetically stratified Siletzia terrane revealing its internal structure and characterizing its eastern boundary. These analyses suggest the contact between Siletzia (Crescent Formation) and the Eocene accretionary prism trends northward under Lake Washington. North of Seattle, this boundary dips east where it crosses the Kingston arch, whereas south of Seattle the contact dips west where it crosses the Seattle uplift (SU). This westward dip is opposite the dip of the Eocene subduction interface, implying obduction of Siletzia upper crust at this southern location. Elongate pairs of high and low magnetic anomalies over the SU suggest imbrication of steeply-dipping, deeply rooted slices of Crescent Formation within Siletzia. We hypothesize these features result from duplication of Crescent Formation in an accretionary fold-thrust belt during the Eocene. The active Seattle fault divides this Eocene fold-thrust belt into two zones with different structural trends and opposite frontal ramp dips, suggesting the Seattle fault may have originated as a tear fault during accretion.

Washington↗

Structural controls on splay fault rupture dynamics during Cascadia megathrust earthquakes

Great subduction earthquakes ( M w ≥ 8.0) can generate devastating tsunamis by rapidly displacing the seafloor and overlying water column. These potentially tsunamigenic seafloor offsets result from coseismic fault slip and deformation beneath or within the accretionary wedge. The mechanics of these shallow rupture phenomena and their dependence on subduction zone properties remain unresolved, partly due to the sparsity of offshore observations of shallow megathrust earthquake deformation. Here, we analyze how offshore structure influences shallow rupture mechanics and slip partitioning using 3D dynamic earthquake simulations of the Cascadia subduction zone (CSZ) megathrust with and without variably dipping seaward- or landward-vergent splay faults in the wedge that sole into the megathrust. Resulting tradeoffs between splay and megathrust slip reveal structural controls on rupture partitioning, with greater splay slip leading to less shallow megathrust slip updip. Gently dipping and seaward-vergent splays host more slip than those with steeper, landward-vergent splays. To isolate the underlying mechanisms, we compare models with Andersonian and plunging principal stresses. Results suggest distinct static and dynamic processes control the dip- and vergence-dependence of splay rupture: static (mis)alignment relative to far-field tectonic loading favors slip on more optimally oriented, shallowly dipping splay faults. In contrast, dynamic stress interactions of an updip-propagating megathrust rupture front with the free surface and potential branch faults favor forward branching onto seaward-vergent splays and inhibit backward branching onto landward-vergent splays. Resulting seafloor displacements suggest splay fault structure may influence coseismic tsunami source processes, highlighting the importance of dynamically viable rupture scenarios in subduction hazard assessments.

Cascadia subduction zone↗

The impact of 3D structure on coseismic coastal land-level change and tsunami generation in the Cascadia Subduction Zone

Estimates of coseismic vertical displacements from past and potential future subduction zone earthquakes provide critical constraints on regional seismic and tsunami hazard. Many studies use elastic homogeneous half-space models to calculate vertical displacements from a specified earthquake slip distribution, neglecting complexities of 3D structure in subduction zone settings. Here, we use 3D ground motion simulations of potential Cascadia Subduction Zone earthquakes to investigate the impact of realistic 3D Earth structure on estimated vertical displacements. We show that offshore uplift increases when including 3D structure due to high fault slip in low-rigidity accretionary wedge sediments and coastal subsidence decreases due to higher rigidity material at depth. These larger offshore uplifts cause increased tsunami maximum wave heights, and coastal subsidence at paleoseismic sites decreases on average by ∼17 cm, or ∼60%, which can have important implications for the amplitude and extent of slip in earthquake scenarios developed based on paleoseismic data constraints.

California, Oregon, Washington↗

From collision to subduction: Thermal-kinematic inversions constrain plate boundary structure and dip-slip activity in southwestern New Zealand

Constraints on three-dimensional fault system geometry and kinematics are required to understand both long-term tectonics and contemporary seismic hazard. In many cases, these parameters must be inferred from a combination of different data or analyses. Here, we invert low-temperature thermochronological data to quantitatively parameterize both the crustal-scale geometry and late Cenozoic dip-slip activity of the plate boundary system in southwest New Zealand. We find that the modern transpressive plate boundary system has accommodated the bulk of Australian-Pacific Plate convergence since establishment in the middle Miocene-early Pliocene. Shortening has occurred via (a) dextral-reverse slip on the moderate angle, listric central Alpine Fault décollement, and (b) reverse-slip on either the sharply curved, anti-listric northern Puysegur subduction interface or low-angle offshore thrust fault system that splays from the high-angle southern Alpine Fault at depth. We resolve late Cenozoic shortening rates on these structures that are indistinguishable, and interpret these to reflect the transfer of convergent deformation outboard of the predominantly strike-slip southern Alpine Fault. Our work helps elucidate the transition from strain localized oblique continental collision to strain partitioned subduction. We also provide an estimate of the across-strike width of the central-southern Alpine Fault section boundary at seismogenic depths. This is the first quantitative constraint on the geometry of a structural feature inferred to have arrested several major prehistoric earthquakes. This study furthers understanding of fault structure and dip-slip kinematics along the greatest sources of seismic hazard in and offshore of southwest New Zealand.

South Island↗

Structural evolution of an arc-basin: The Gravina Belt in central southeastern Alaska

The upper Middle Jurassic-Lower Cretaceous Gravina belt lies along the eastern margin of the Alexander terrane in southeastern Alaska. This group of turbidites and mafic to intermediate volcanic rocks was deformed during mid to Late Cretaceous time during the closing of a basin of unknown size between the Alexander terrane on the west and the Stikine terrane to the east. Therefore structures of Gravina belt rocks largely reflect the final accretion and subsequent transport of the Alexander terrane. Six geologic transects across the central Gravina belt (southern Mitkof Island to northern Douglas Island) define a structural history that includes (1) syndepositional soft-sediment folding and faulting, possibly in conjunction with block tilting and extension; (2) tight to isoclinal folding or thrust faulting, with formation of a slaty cleavage (S 1 ) striking ∼330°; (3) local coaxial refolding with formation of crenulation cleavage (S 2 ); (4) development of domainal crenulation folds and cleavage (S 3 ) oriented at a large angle to the margin of the belt; (5) intrusion of tonalitic plutons around 90 Ma; and (6) right-lateral strike-slip displacement on faults oriented ∼330°. Finite strain measurements on sedimentary rocks suggest the belt was at least twice its present width, normal to the foliation, before deformation. Subhorizontal margin-parallel fold axes, margin-parallel slaty cleavage, and margin-perpendicular stretching lineations suggest orthogonal contraction of the Gravina basin, assuming that oblique plate convergence was not decoupled along strike-slip faults. After contractional deformation, strike-slip faults indicate dextral displacement (probably of the order of several tens of kilometers) of the Alexander terrane with respect to the terranes to the east. Domainal crenulation folds and cleavages at a high angle to the margin of the belt suggest that the change in convergence directions occurred while the rocks (presently at the surface) could still plastically deform. This kinematic interpretation of structures is consistent with changes in plate motions [Engebretson et al., 1985]. Before 100 Ma, the convergence directions between the Kula and North America plates were at a high angle to the continental margin, whereas after 100 Ma, convergence directions were at a small angle to the continental margin. In addition, after 100 Ma, the Kula-North America, and not the Farallon-North America, convergence direction is most compatible with a N-S principal paleostress orientation derived from inversion of strike-slip fault data. This relationship suggests that it may have been the Kula plate that drove northward transport of the Alexander terrane along the margin of North America.

Alaska↗

Identification of hydraulic conductivity structure in sand and gravel aquifers: Cape Cod data set

This study evaluates commonly used geostatistical methods to assess reproduction of hydraulic conductivity (K) structure and sensitivity under limiting amounts of data. Extensive conductivity measurements from the Cape Cod sand and gravel aquifer are used to evaluate two geostatistical estimation methods, conditional mean as an estimate and ordinary kriging, and two stochastic simulation methods, simulated annealing and sequential Gaussian simulation. Our results indicate that for relatively homogeneous sand and gravel aquifers such as the Cape Cod aquifer, neither estimation methods nor stochastic simulation methods give highly accurate point predictions of hydraulic conductivity despite the high density of collected data. Although the stochastic simulation methods yielded higher errors than the estimation methods, the stochastic simulation methods yielded better reproduction of the measured In (K) distribution and better reproduction of local contrasts in In (K). The inability of kriging to reproduce high In (K) values, as reaffirmed by this study, provides a strong instigation for choosing stochastic simulation methods to generate conductivity fields when performing fine-scale contaminant transport modeling. Results also indicate that estimation error is relatively insensitive to the number of hydraulic conductivity measurements so long as more than a threshold number of data are used to condition the realizations. This threshold occurs for the Cape Cod site when there are approximately three conductivity measurements per integral volume. The lack of improvement with additional data suggests that although fine-scale hydraulic conductivity structure is evident in the variogram, it is not accurately reproduced by geostatistical estimation methods. If the Cape Cod aquifer spatial conductivity characteristics are indicative of other sand and gravel deposits, then the results on predictive error versus data collection obtained here have significant practical consequences for site characterization. Heavily sampled sand and gravel aquifers, such as Cape Cod and Borden, may have large amounts of redundant data, while in more common real world settings, our results suggest that denser data collection will likely improve understanding of permeability structure.

Water Resources Research↗

Metamorphic and structural evidence for significant vertical displacement along the Ross Lake fault zone, a major orogen-parallel shear zone in the Cordillera of western North America

Results of an investigation of the petrology and structure of the Skymo complex and adjacent terranes constrain the amount, timing, and sense of motion on a segment of the > 600-km-long Late Cretaceous - early Tertiary Ross Lake fault zone (RLFZ), a major orogen-parallel shear zone in the Cordillera of western North America. In the study area in the North Cascades, Washington state, the RLFZ accommodated significant pre-middle Eocene vertical displacement, and it juxtaposes the Skymo complex with upper amphibolite facies (650°–690°C and 6–7 kbar) Skagit Gneiss of the North Cascades crystalline core to the SW and andalusite-bearing phyllite of the Little Jack terrane (Intermontane superterrane) to the NE. The two main lithologic units of the Skymo complex, a primitive mafic intrusion and a fault-bounded block of granulite facies metasedimentary rocks, are unique in the North Cascades. Granulite facies conditions were attained during high-temperature (> 800°C), low pressure (≤ 4 kbar) contact metamorphism associated with intrusion of the mafic magma. P-T estimates and reaction textures in garnet-orthopyroxene gneiss suggest that contact metamorphism followed earlier, higher pressure regional metamorphism. There is no evidence that the Skagit Gneiss experienced high-T - low-P contact metamorphism. In the Little Jack terrane, however, texturally late cordierite ± spinel and partial replacement of andalusite by sillimanite near the terrane's fault contact with Skymo gabbro suggest that the Little Jack terrane experienced high-T (∼ 600°C) - low-P (≤ 4 kbar) contact metamorphism following earlier low-grade regional metamorphism. Similarities in the protoliths of metasedimentary rocks in the Skymo and Little Jack indicate that they may be part of the same terrane. Differences in pressure estimates for the Little Jack versus Skymo for regional metamorphism that preceded contact metamorphism indicate vertical displacement of ∼ 10 km (west side up) on the strand of the RLFZ that now separates the two structural blocks. High-angle faults in the study area are dextral-reverse mylonitic shear zones that experienced later brittle normal slip. Vertical motion on these shear zones before intrusion of Skymo gabbro can account for metamorphic discontinuities indicated by P-T results. The terranes have also been internally deformed by nonintersecting but coeval dextral and sinistral shear zones that formed after the terranes were brought together in the RLFZ and intruded by Eocene dikes. These results show that the RLFZ has accommodated significant vertical displacement but perhaps no more than tens of kilometers of early Tertiary lateral movement. Structural evidence for earlier, large-magnitude strike-slip displacement is not preserved.

Washington↗

Three-dimensional P-wave velocity structure of Mt. Etna, Italy

The three-dimensional P -wave velocity structure of Mt. Etna is determined to depths of 15 km by tomographic inversion of first arrival times from local earthquakes recorded by a network of 29 permanent and temporary seismographs. Results show a near-vertical low-velocity zone that extends from beneath the central craters to a depth of 10 km. This low-velocity region is coincident with a band of steeply-dipping seismicity, suggesting a magmatic conduit that feeds the summit eruptions. The most prominent structure is an approximately 8-km-diameter high-velocity body located between 2 and 12 km depth below the southeast flank of the volcano. This high-velocity body is interpreted as a remnant mafic intrusion that is an important structural feature influencing both volcanism and east flank slope stability and faulting.

Geophysical Research Letters↗

IASPEI workshop: Seismic modeling of laterally varying structures

During the past 10 years, significant progress has been made in the methods of collection and analysis of seismic reflection and refraction data. This progress has led to the development of new models for the structure and composition of the earth's crust, based on sophisticated analysis of numerous profiles in many areas of geologic importance. The third triannual meeting of the IASPEI (International Association of Seismology and Physics of the Earth's Interior) Commission of Controlled Source Seismology was convened in Park City, Utah, on August 11–17, 1980, to bring together seismologists and geologists to explore and assess the progress of controlled source techniques (controlled sources include explosions, air guns, and Vibroseis‐type sources), and to evaluate its significance in terms of current models of the seismic velocity structure and composition of the crust and upper mantle. Particular attention was paid to the progress and problems in the modeling of two‐ and three‐dimensional structures.

Eos, Transactions, American Geophysical Union↗

Electrical structure of Newberry Volcano, Oregon

From the interpretation of magnetotelluric, transient electromagnetic, and Schlumberger resistivity soundings, the electrical structure of Newberry Volcano in central Oregon is found to consist of four units. From the surface downward, the geoelectrical units are (1) very resistive, young, unaltered volcanic rock, (2) a conductive layer of older volcanic material composed of altered tuffs, (3) a thick resistive layer thought to be in part intrusive rocks, and (4) a lower-crustal conductor. This model is similar to the regional geoelectrical structure found throughout the Cascade Range. Inside the caldera, the conductive second layer corresponds to the steep temperature gradient and alteration minerals observed in the USGS Newberry 2 test hole. Drill hole information on the south and north flanks of the volcano (test holes GEO N-1 and GEO N-3, respectively) indicates that outside the caldera the conductor is due to alteration minerals (primarily smectite) and not high-temperature pore fluids. On the flanks of Newberry the conductor is generally deeper than inside the caldera, and it deepens with distance from the summit. A notable exception to this pattern is seen just west of the caldera rim, where the conductive zone is shallower than at other flank locations. The volcano sits atop a rise in the resistive layer, interpreted to be due to intrusive rocks. The intrusive material has served as a heat source to produce enhanced hydrothermal alteration and, perhaps in the case of the west-flank anomaly, elevated fluid temperatures. While no public drill hole information is available to confirm this hypothesis, the west-flank anomaly appears to be a good geothermal target. In addition to the possibility that a region on the west side of the volcano could be favorable for prospecting, part of the resistive structure under the center of the volcano could be due to a vapor-dominated environment with temperatures above 300°C. In other parts of the Cascades, pervasive alteration has produced mixed layer clays and zeolites, resulting in low-resistivity anomalies. Low resistivities cannot be assumed to indicate high-temperature pore fluids. The use of electrical methods that measure resistivity as a function of excitation frequency, such as spectral induced polarization, may provide a way of obtaining information about the type and extent of alteration.

Journal of Geophysical Research Solid Earth↗

Shallow structure and deformation along the San Andreas Fault in Cholame Valley, California, based on high-resolution reflection profiling

The mapped active traces of the San Andreas fault are separated by a 1-km-wide right-stepping offset in Cholame Valley. The geometry of this offset, defined in other strike-slip systems as a releasing bend or a dilational jog, has resulted in the formation of a pullapart basin. Various researchers have inferred that this offset served as a rupture terminus for earthquakes on both strands of the San Andreas fault (1966 Parkfield and 1857 Fort Tejon); thus, this en echelon offset may represent a barrier to the propagation of rupture between two segments of the San Andreas fault. We collected 18 km of high-resolution seismic reflection data specifically designed to image the San Andreas fault zone in the shallow crust surrounding this offset. Four short profiles (≤ 3.3 km long) of Mini-Sosie reflection data (1 s of two-way travel time ≈ 1.5 km deep) were collected perpendicular to the San Andreas fault; three of these profiles were tied by a 7-km-long profile that trended northwest through Cholame Valley, subparallel to the San Andreas fault. A zone of incoherent energy, narrow at the surface but widening with depth, underlies the mapped active traces of the San Andreas fault and abruptly terminates shallow reflections on both sides. The reflection profiles and available well data indicate that west of the mapped active traces of the San Andreas fault the shallow subsurface structure of the crust consists of thin (≤400 m thick), offset packages of reflections, laterally coherent on the scale of tens of meters, overlying deformed clastic sedimentary rocks. East of the San Andreas fault, the structure of the shallow crust in southern Cholame Valley is characterized by thick packages of reflections, laterally coherent on the scale of kilometers, overlying the Franciscan complex. All of the strata east of the fault (within Cholame Valley) dip toward the San Andreas fault and the offset, into an approximately 1-km-deep sedimentary basin abutting the south strand of San Andreas fault. The offset in Cholame Valley is characterized by a gentle downwarping of sediments into the offset, the presence of many small faults and discontinuous reflections (consistent with areally distributed shear) between the traces of the main fault, localized subsidence abutting the main strike-slip fault, the formation of a basin, near the offset, that is about as deep as the jog is wide, and the southward propagation of the deformation associated with the offset. Strain field modeling based on simple geometries of the San Andreas and associated faults successfully predicts the general features of the observed topography and subsurface structure of southern Cholame Valley, including subsidence and basin formation near the offset, a discontinuous San Andreas fault plane, and at least one fault in southeastern Cholame Valley.

Journal of Geophysical Research↗

Deep crustal structure of the Cascade Range and surrounding regions from seismic refraction and magnetotelluric data

Several regional seismic refraction and magnetotelluric (MT) profiles have been completed across the Cascade Range and surrounding geologic provinces in California, Oregon, and Washington. Analysis of three MT and two seismic refraction profiles in Oregon and a coincident MT and refraction profile in northern California show a high degree of correlation between resistivity and velocity models. The main feature that is evident in both data sets is a highly conductive (2-20 ohm m) zone that occurs at depths of 6-20 km and largely within a midcrustal velocity layer of 6.4-6.6 km/s, overlying a lower crust with velocities of 7.0-7.4 km/s. Accretionary structures in the southern Washington Cascades have been shown to be related to stress release in the area of Mount St. Helens. In order to explain the similar structures in the MT and refraction models for Oregon and California, a model is proposed involving the effects of metamorphic zonation to produce the velocity structure, combined with metamorphically produced fluids and partial melt to produce the deep conductor.

California, Oregon, Washington↗

Does bird community structure vary with landscape patchiness? A Chihuahuan Desert perspective

During the springs of 1995-1997, we studied birds and landscapes at 70 sites in the Chihuahuan Desert to assess relations between bird community structure and landscape patchiness. Within each of two spatial extents (1-kin and 2-km-radius areas centered on each site), we measured the number of patches of individual land-cover types and the total number of patches of all land-cover types. Mean bird richness, and the mean abundance and probability of occurrence of most bird species were significantly correlated with one or more of these variables. Contrary to evidence from other systems, positive association with landscape patchiness did not increase with the degree to which species were habitat generalists, was not negatively related to body size, and did not differ between neotropical migrants and nonmigrants. For the communities' primary constituent species as a group, the strength of positive and negative associations with patchiness did not differ between landscape extents. Within the 1-km but not the 2-km extent, habitat specialists were more positively and negatively associated with patchiness than were habitat generalists. In general, however, neither habitat breadth, body size, nor migratory status seemed to be responsible for associations with landscape patchiness. Mean richness, and the mean abundance and probability of occurrence of most species were significantly correlated with patchiness within one or both extents, and patchiness of all of the most extensive land-cover types was influential. The simplest explanation for most of the bird-patchiness relations we found is that the associations reflected species-specific habitat needs. Through effects on avian richness, abundance, and occurrence, landscape patchiness affected bird community structure. A more complete understanding of the effects of landscape patchiness on bird community structure is likely to emerge when ecologists study the patchiness of major land-cover types at various spatial extents.

Oikos↗

New links between the Chicxulub impact structure and the Cretaceous/Tertiary boundary

The 200-km-diameter Chicxulub structure 1–3 in northern Yucatan, Mexico has emerged as the prime candidate for the Cretaceous/Tertiary (K/T) boundary impact crater 3–6 . Concentric geophysical anomalies associated with enigmatic occurrences of Upper Cretaceous breccias and andesitic rocks led Penfield and Camargo 1 to suspect that this structure was a buried impact basin. More recently, the discovery of shocked quartz grains in a Chicxulub breccia 3 , and chemical similarities between Chicxulub rocks and K/T tektite-like glasses 3–6 have been advanced as evidence that the Chicxulub structure is a K/T impact site. Here we present evidence from core samples that Chicxulub is indeed a K/T source crater, and can apparently account for all the evidence of impact distributed globally at the K/T boundary without the need for simultaneous multiple impacts or comet showers. Shocked breccia clasts found in the cores are similar to shocked lithic fragments found worldwide in the K/T boundary ejecta layer 7,8 . The Chicxulub melt rocks that we studied contain anomalously high levels of iridium (up to 13.5 parts per 10 9 ), also consistent with the iridium-enriched K/T boundary layer 9 . Our best estimate of the crystallization age of these melt rocks, as determined by 40 Ar/< 39 Ar analyses, is 65.2 ±0.4 (1σ) Myr, in good agreement with the mean plateau age of 64.98 ± 0.05 Myr recently reported 10 . Furthermore, these melt rocks acquired a remanent magnetization indicating that they cooled during an episode of reversed geomagnetic polarity. The only such episode consistent with 40 Ar/< 39 Ar constraints is chron 29R, which includes the K/T boundary.

northern Yucatan↗

Trans-crustal structural control of CO2-rich extensional magmatic systems revealed at Mount Erebus Antarctica

Erebus volcano, Antarctica, with its persistent phonolite lava lake, is a classic example of an evolved, CO 2 -rich rift volcano. Seismic studies provide limited images of the magmatic system. Here we show using magnetotelluric data that a steep, melt-related conduit of low electrical resistivity originating in the upper mantle undergoes pronounced lateral re-orientation in the deep crust before reaching shallower magmatic storage and the summit lava lake. The lateral turn represents a structural fault-valve controlling episodic flow of magma and CO 2 vapour, which replenish and heat the high level phonolite differentiation zone. This magmatic valve lies within an inferred, east-west structural trend forming part of an accommodation zone across the southern termination of the Terror Rift, providing a dilatant magma pathway. Unlike H 2 O-rich subduction arc volcanoes, CO 2 -dominated Erebus geophysically shows continuous magmatic structure to shallow crustal depths of < 1 km, as the melt does not experience decompression-related volatile supersaturation and viscous stalling.

Nature Communications↗

Crystal structure of the heptamolybdate(VI)(paramolybdate) ion, [Mo7O24]6–, in the ammonium and potassium tetrahydrate salts

The crystal structures of the isomorphous salts M I 6 [Mo 7 O 24 ],4H 2 O (M = NH 4 or K) have been refined by three-dimensional X -ray diffraction methods. Unit cell dimensions of these monoclinic compounds, space group P 2 1 / C with Z = 4, are, ammonium salt: a = 8·3934 ± 0·0008, b = 36·1703 ± 0·0045, c = 10·4715 ± 0·0011 Å, β= 115·958°± 0·008°; and potassium salt: a = 8·15 ± 0·02, b = 35·68 ± 0·1, c = 10·30 ± 0·02 Å, β= 115·2°± 02°. By use of multiple Weissenberg patterns, 8197 intensity data (Mo- K α radiation) for the ammonium compound and 2178 (Cu- K α radiation) for the potassium compound were estimated visually and used to test and refine Lindqvist's proposed structure in the space group P 2 1 / c . Lindqvist's structure was confirmed and the full matrix least-squares isotropic refinement led to R 0·076 (ammonium) 0·120 (potassium), with direct unambiguous location of the cations and water molecules in the potassium compound.

Journal of the Chemical Society, Dalton Transactio↗