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At least 523 records · Page 29Linked to original sources
USGS2014

Pumping from wells on the floor of the Sevier Desert, Utah

Data collected at the Topaz Relocation Center provide an excellent record of the development and subsequent disappearance of a cone of depression caused by pumping . This Center occupied temporarily an area of natural ground‐water discharge on the floor of the Sevier Desert in west‐central Utah . Water for a population of 6500 was pumped from artesian wells which tapped aquifers of sand. Overlying these sand beds are lake‐bed sediments too impermeable to yield water to wells , but apparently permeable enough to permit slow upward movement of water from the artesian aquifers. The water table is near the surface, and there is natural discharge by evapotranspiration, accumulation of “alkali” in the soil, and a need for drainage of irrigated lands. The wells were abandoned when the Relocation Center was closed, apparently because these handicaps were so great that the ground water could not be used profitably for irrigation.

Utah↗
USGS1967

Water resources inventory of Connecticut Part 2: Shetucket River Basin

The Shetucket River basin has a relatively abundant supply of water of generally good quality which is derived from precipitation that has fallen on the basin. Annual precipitation has ranged from about 30 inches to 75 inches and has averaged about 45 inches over a 35-year period. Approximately 20 inches of water are returned to the atmosphere each year by evaporation and transpiration; the remainder of the annual precipitation either flows overland to streams or percolates downward to the water table and ultimately flows out of the basin in the Shetucket River or as underflow through the deposits beneath. During the autumn and winter months precipitation normally is sufficient to cause a substantial increase in the amount of water stored underground and in surface reservoirs within the basins whereas in the summer most of the precipitation is lost through evaporation and transpiration, resulting in sharply reduced streamflow and lowered groundwater levels. The mean monthly storage of water in the basin on an average is 3.5 inches higher in November than it is in June. The amount of water that flows out of the basin in the Shetucket River represents the total amount of water potentlally available for use by man. Annual runoff from the entire basin above the Quinebaug River has ranged from about 13 to 42 inches since 1929, and has averaged about 23 inches (300 billion gallons). Although runoff indicates the total amount of water potentially available, it is usually not economically or legally feasible for man to use all of it. On the other hand, with increased development, It is possible that some water will be reused several times. The water available may be tapped as it flows through the area or is temporarily stored in streams, lakes, and aquifers. The amounts that can be developed vary from place to place and time to time, depending on the amount of precipitation, on the size of drainage area, on the thickness, permeability and areal extent of aquifers, and on the variations in chemical and physical quality of the water. Differences in streamflow from point to point are due primarily to differences in the proportion of stratified drift in the drainage basin above each point, which affect the timing of streamflow, and to differences in precipitation, which affect the amount of streamflow. Information on streamflow from gaging stations may be extended to ungaged sites by accounting for both of these factors ,in calculations. Future floods on the upper Willimantic River or the Shetucket River are unlikely to cause major damage so long as buildings are not constructed below the highest flood elevations to be expected with the present system of reservoirs for flood control. Ground water can be obtained from wells almost anywhere in the Shetucket River basin, but the amount obtainable from individual wells at any particular point depends upon the type and water-bearing properties of the aquifers present. For practical purposes, the earth materials in the basin comprise three aquifers--stratified drift, till, and bedrock, Stratified drift is the only aquifer generally capable of yielding more than 100 gpm to individual wells. This aquifer covers about 18 percent of the basin and occurs chiefly In lowlands where it overlies till or bedrock. Coefficient of permeability of the coarse-grained unit of stratified drift averages about 1,900 gpd per sq ft. Drilled, screened wells tapping this unit, are known to yield from 200 to 675 gpm. Dug wells in coarse-grained stratified drift should supply at least 2 gpm per foot of drawdown over an 8-hour period. Fine-grained stratified drift has an average coefficient of permeability of about 400 gpd per sq ft and can usually yield to dug wells supplies sufficient for household use. Till and bedrock are widespread in extent but can provide only small to moderate water supplies. Till is tapped chiefly by dug wells; permanent supplies of more than 200 gpd can be obtained from dug wells at a majority of sites in areas of till, but there are many sites where the till is too impermeable or too thin to provide this much water throughout the year. The coefficient of permeability of till ranges from about 0.2 gpd per sq ft to 55 gpd per sq it. Bedrock Is tapped chiefly by drilled wells, about 90 percent of which will supply at least 3 gpm. Very few, however, will supply more than 50 gpm. The amount of ground water potentially available In an area depends upon the amount of groundwater outflow, the amount of ground water in storage, and the quantity of water available by Induced infiltration from streams and lakes. From data on permeability, saturated thickness, recharge, yield from aquifer storage, well performance, and streamflow, preliminary estimates of ground-water availability can be made for any point in the basin. Long-term yields estimated for 15 areas especially favorable for development of large ground-water supplies ranged from 1.3 to 61.8 mgd. Detailed site studies to determine optimum yields, drawdowns, and spacing of individual wells are needed before major ground-water development is undertaken In these or other areas. The chemical quality of water in the Shetucket basin Is generally good to excellent. Samples of naturally occurring surface water collected from 32 sites contained less than 61 ppm of dissolved solids and less than 32 ppm of hardness. Water from wells is more highly mineralized than naturally occurring water from streams. Even so only 7 percent of wells sampled yielded water with more than 200 ppm of dissolved sol-ids and only 9 percent yielded water with more than 120 ppm of hardness. Even in the major rivers, which are used to transport industrial waste, the dissolved mineral content is less than 100 ppm and hardness rarely exceeds 40 ppm. One notable exception occurs in the lower reaches of Little River where an exceptional amount of industrial waste is discharged into the river near Versailles. This waste is particularly noticeable during low streamflow. Iron and manganese In both ground water and surface water are the only constituents whose concentrations commonly exceed recommended limits for domestic and industrial use. Most wells in the basin yield clear water with little or no iron or manganese, but distributed among them are wells with ground water that contains enough of these dissolved constituents to be troublesome for most uses. iron concentrations in naturally occurring stream water exceeded 0.3 ppm under tow-flow conditions at 20 percent of the sites sampled. Large concentrations of iron in stream water result from discharge of iron-bearing ground water or from the discharge of water from swamps. In swamps the iron is released largely from decaying vegetation. Ground water more than 30 feet below the land surface has a relatively constant temperature, usually between 48°F and 50°F. Water temperature in very shallow wells may fluctuate from about 38°F in February or March to about 55°F in late summer. Water temperature in the larger streams fluctuates much more widely, ranging from 32°F at least for brief periods in winter, to about 85°F occasionally during The quantity of suspended sediment transported by streams in the basin is negligible, though amounts large enough to be troublesome may occur locally at times. The total amount of water used In the Shetucket Rlver basin for all purposes during 1961 was about 5,810 million gallons~ which is equivalent to 208 gpd per person, Public water systems supplied the domestic needs of nearly half the population of the basin; 10 systems were sampled, all of which provided water of better quality than the U.S. Public Health Service suggests for drinking water standards.

Connecticut↗
USGS1968

Water resources inventory of Connecticut Part 3: lower Thames and southeastern coastal river basins

The lower Thames and southeastern coastal river basins have a relatively abundant supply of water of generally good quality which is derived from streams entering the area and precipitation that has fallen on the area. Annual precipitation has ranged from about 32 inches to 65 inches and has averaged about 48 inches over a 30-year period. Approximately 22 inches of water are returned to the atmosphere each year by evaporation and transpiration; the remainder of the annual precipitation either flows overland to streams or percolates downward to the water table and ultimately flows out of the report area through estuaries and coastal streams or as underflow through the deposits beneath. During the autumn and winter months precipitation normally is sufficient to cause a substantial increase in the amount of water stored underground and in surface reservoirs within the report area, whereas in the summer most of the precipitation is lost through evaporation and transpiration, resulting in sharply reduced stream-flow and lowered ground-water levels. The mean monthly storage of water on an average is about 3.8 inches higher in November than it is in June. The amount of water that flows through and out of the report area represents the total amount of water potentially available for use by man. For the 30-year period 1931 through 1960, the annual runoff from the report area has averaged nearly 26 inches (200 billion gallons), from the entire Thames River basin above Norwich about 24 inches (530 billion gallons), and from the Pawcatuck River basin about 26 inches (130 billion gallons). A total average annual runoff of 860 billion gallons is therefore available. Although runoff indicates the total amount of water potentially available, it is usually not economically feasible for man to use all of it. On the other hand, with increased development, it is possible that some water will be reused several times. The water available may be tapped as it flows through the area or is temporarily stored in streams, lakes, and aquifers. The amounts that can be developed vary from place to place and time to time, depending on the amount of precipitation, on the size of drainage area, on the thickness, permeability, and areal extent of aquifers, and on the variations in chemical and physical quality of the water. Differences in streamflow from point to point are due primarily to differences in the proportion of stratified drift in the drainage basin above each point, which affect the timing of streamflow, and to differences in precipitation, which affect the amount of streamflow. Ground water can be obtained from wells almost anywhere in the area, but the amount obtainable at any particular point depends upon the type and water-bearing properties of the aquifers. For practical purposes, the earth materials in the report area comprise three aquifers--stratified drift, bedrock, and till. Stratified drift is the only aquifer generally capable of yielding more than 100 gpm (gallons per minute) to individual wells. It covers about 20 percent of the area and occurs chiefly in lowlands where it overlies till and bedrock. The coefficient of permeability of the coarse-grained unit of stratified drift averages about 1,500 gbd (gallons per day) per sq ft. Drilled, screened wells tapping this unit are known to yield from 4 to 88o gpm and average 146 gpm. Dug wells in coarse-grained stratified drift supply about 2 gpm per foot of drawdown over a period of a few hours. Fine-grained stratified drift has an average coefficient of permeability of about 300 gpd per sq ft and can usually yield supplies sufficient for household use to dug wells. Bedrock and till are widespread in extent but generally provide only small water supplies. Bedrock is tapped chiefly by drilled wells, about 90 percent of which will supply at least 3 gpm. Very few, however, will supply more than 50 gpm. Till is tapped in a few places by dug wells which can yield small supplies of only a few hundred gpd throughout all or most of the year. The coefficient of permeability of till ranges from about 0.2 gpd per sq ft to 120 gpd per sq ft. The amount of ground water potentially available in the report area depends upon the amount of ground-water outflow, the amount of ground water in storage, and the quantity of water available by induced infiltration from streams and lakes. From data on permeability, saturated thickness, recharge, yield from aquifer storage, well performance, and streamflow, preliminary estimates of ground-water availability can be made for any point in the report area. Long-term yields estimated for 18 areas of stratified drift especially favorable for development of large ground-water supplies ranged from 1.3 to 66 mgd. Detailed site studies to determine optimum yields, drawdowns, and spacing of individual wells are needed before major ground-water development is undertaken in these or other areas. The chemical quality of water in the report area is generally good to excellent. Samples of naturally occurring surface water collected at 24 sites contained less than 151 ppm (parts per million) of dissolved solids and less than 63 ppm of hardness. Water from wells is more highly mineralized than naturally occurring water from streams. Even so only 12 percent of the wells sampled yielded water with more than 200 ppm of dissolved solids and only 8 percent yielded water with more than 120 ppm of hardness. Even in major streams, which are used to transport industrial waste, hardness rarely exceeds 60 ppm and the dissolved mineral content is generally less than 200 ppm. At a few places in the town of Montville however, waters may contain dissolved mineral concentrations of 2,000 to 4,000 ppm. Iron and manganese in both ground water and surface water are the only constituents whose concentrations commonly exceed recommended limits for domestic and industrial use. Most wells in the report area yield clear water with little or no iron or manganese, but distributed among them are wells yielding ground water that contains enough of these dissolved constituents to be troublesome for most uses. Iron concentrations in naturally occurring stream water exceed 0.3 ppm under low-flow conditions at 33 percent of the sites sampled. Large concentrations of iron in stream water result from discharge of iron-bearing water from aquifers or from swamps where it is released largely from decaying vegetation. Ground water more than 30 feet below the land surface has a relatively constant temperature, usually between 48°F and 52°F. Water temperature in very shallow wells may fluctuate from about 38°F in February or March to about 55°F in late summer. Water temperature in the larger streams fluctuates much more widely, ranging from 32°F at least for brief periods in winter, to about 85°F occasionally during summer. The quality of suspended sediment transported by streams in the area is negligible. Turbidity in streams is generally not a problem although amounts large enough to be troublesome may occur locally at times. The total amount of water used in the report area for all purposes during 1964 was about 118,260 million gallons, of which 105,600 million gallons was estuarine water used for cooling by industry. The average per capita water use, excluding estuarine, temporary summer residence, and institutional water was equivalent to 186 gpd. Public water systems supplied the domestic needs of nearly tw0-thirds the population of the report area. All of the 19 systems, which were sampled, provided water of better quality than the U.S. Public Health Service suggests for drinking water standards.

Connecticut↗
USGS2005

Low summer water temperatures influence occurrence of naturalized salmonids across a mountain watershed

We investigated relationships between the absence of salmonids and low summer water temperatures across a 150-km2 Rocky Mountain watershed. A model predicting maximum July water temperature (MJT) from measurements of perennial stream length, wetted width, and midrange basin elevation was developed from temperature data obtained at 20 sites across the watershed. The model was used to predict MJT in 75 reaches across the watershed where salmonids were sampled. The lowest predicted MJT in reaches where age-0 and juvenile-adult brook trout Salvelinus fontinalis were observed was 9??C. The lowest predicted MJT in reaches where age-0 progeny of the genus Oncorhynchus spp. (i.e., rainbow trout O. mykiss or cutthroat trout O. clarkii) were observed was 13??C and where Oncorhynchus spp. adults where observed was 12??C. The probability of occurrence of both age-0 and adult brook trout and Oncorhynchus spp. increased as MJT increased above these thresholds. Our results indicate that low MJT in some portions of a mountain watershed can be related to the absence of salmonids. Consequently, data on MJT may provide managers with a means of assessing where summer water temperatures are not suitable for establishment of naturalized salmonid populations. ?? Copyright by the American Fisheries Society 2005.

North American Journal of Fisheries Management↗
USGS2021

NASA's surface biology and geology designated observable: A perspective on surface imaging algorithms

The 2017–2027 National Academies' Decadal Survey, Thriving on Our Changing Planet , recommended Surface Biology and Geology (SBG) as a “Designated Targeted Observable” (DO). The SBG DO is based on the need for capabilities to acquire global, high spatial resolution, visible to shortwave infrared (VSWIR; 380–2500 nm; ~30 m pixel resolution) hyperspectral (imaging spectroscopy) and multispectral midwave and thermal infrared (MWIR: 3–5 μm; TIR: 8–12 μm; ~60 m pixel resolution) measurements with sub-monthly temporal revisits over terrestrial, freshwater, and coastal marine habitats. To address the various mission design needs, an SBG Algorithms Working Group of multidisciplinary researchers has been formed to review and evaluate the algorithms applicable to the SBG DO across a wide range of Earth science disciplines, including terrestrial and aquatic ecology, atmospheric science, geology, and hydrology. Here, we summarize current state-of-the-practice VSWIR and TIR algorithms that use airborne or orbital spectral imaging observations to address the SBG DO priorities identified by the Decadal Survey: (i) terrestrial vegetation physiology, functional traits, and health; (ii) inland and coastal aquatic ecosystems physiology, functional traits, and health; (iii) snow and ice accumulation, melting, and albedo; (iv) active surface composition (eruptions, landslides, evolving landscapes, hazard risks); (v) effects of changing land use on surface energy, water, momentum, and carbon fluxes; and (vi) managing agriculture, natural habitats, water use/quality, and urban development. We review existing algorithms in the following categories: snow/ice, aquatic environments, geology, and terrestrial vegetation, and summarize the community-state-of-practice in each category. This effort synthesizes the findings of more than 130 scientists.

Remote Sensing of Environment↗
USGS2009

Geochemistry of inorganic nitrogen in waters released from coal-bed natural gas production wells in the Powder River Basin, Wyoming

Water originating from coal-bed natural gas (CBNG) production wells typically contains ammonium and is often disposed via discharge to ephemeral channels. A study conducted in the Powder River Basin, Wyoming, documented downstream changes in CBNG water composition, emphasizing nitrogen-cycling processes and the fate of ammonium. Dissolved ammonium concentrations from 19 CBNG discharge points ranged from 95 to 527 μM. Within specific channels, ammonium concentrations decreased with transport distance, with subsequent increases in nitrite and nitrate concentrations. Removal efficiency, or uptake, of total dissolved inorganic nitrogen (DIN) varied between channel types. DIN uptake was greater in the gentle-sloped, vegetated channel as compared to the incised, steep, and sparsely vegetated channel and was highly correlated with diel patterns of incident light and dissolved oxygen concentration. In a larger main channel with multiple discharge inputs ( n = 13), DIN concentrations were >300 μM, with pH > 8.5, after 5 km of transport. Ammonium represented 25−30% of the large-channel DIN, and ammonium concentrations remained relatively constant with time, with only a weak diel pattern evident. In July 2003, the average daily large-channel DIN load was 23 kg N day −1 entering the Powder River, an amount which substantially increased the total Powder River DIN load after the channel confluence. These results suggest that CBNG discharge may be an important source of DIN to western watersheds, at least at certain times of the year, and that net oxidation and/or removal is dependent upon the extent of contact with sediment and biomass, type of drainage channel, and time of day.

Wyoming↗
USGS2021

U.S. Geological Survey 21st-Century science strategy 2020–2030

Today’s Earth system challenges are far more complex and urgent than those that existed in 1879 when the USGS was established. Society’s greatest challenges are directly or indirectly linked to major areas of USGS science. Increased pressures on natural resources continue with consequences for national security, food and water availability, natural disasters, human health, and biodiversity loss. As we look forward 10, 20, and 30 years, our mission will be more important than ever before. A broad but coherent view is required for stewardship of the Nation’s land, water, mineral, energy, and ecosystem resources, which involves complex tradeoffs among multiple, often competing objectives. Increasingly, resource managers and decision makers need “the whole USGS”: integrated multidisciplinary Earth and biological science data, geospatial tools, predictive models, decision-support tools, and the expertise to interpret them. This Science Strategy defines a vision and mission for how we will continue to evolve USGS Science to address these Earth system challenges.

Circular↗
USGS2007

Discovery of cyanuric acid during an assessment of natural organic matter in stormflow water of the Santa Ana River, southern California, 2003-2004

A stormflow study of natural organic matter and organic contaminants in the Santa Ana River, the Mill Creek tributary, and an urban drain tributary discovered cyanuric acid in variable concentrations up to 510 g/L. Cyanuric acid was isolated with a hydrophilic natural organic matter (NOM) fraction, and its identity was confirmed by a combination of infrared spectrometry, 13C-nuclear magnetic resonance (13C-NMR) spectrometry, and electrospray ionization/mass spectrometry. Cyanuric acid concentrations, based upon 13C-NMR spectral quantitation, increased during the peak and recessional flows of the storm hydrographs during three storms at three sites. The greatest fluxes of cyanuric acid were observed in the Santa Ana River during the third storm. The most likely source of cyanuric acid is as a metabolite of triazine herbicides, based on hydrographs, land uses of the drainage basins, and the yearly application rates of triazine herbicides. The daily flux of cyanuric acid in Santa Ana River stormflow during the third storm was calculated to be about 1 percent of the yearly application rate for triazine herbicides. Cyanuric acid was not detected in ground water at wells adjacent to the Santa Ana River.

California↗
USGS2018

Regional patterns in the geochemistry of oil-field water, southern San Joaquin Valley, California, USA

Chemical and isotopic data for water co-extracted with hydrocarbons in oil and gas fields are commonly used to examine the source of the formation water and possible impacts on groundwater in areas of oil and gas development. Understanding the geochemical variability of oil-field water could help to evaluate its origin and delineate possible contamination of shallow aquifers in cases where oil-field water is released to the environment. Here we report geochemical and multiple isotope (H, C, O, Sr, Ra) data from 22 oil wells, three sources of produced water that are disposed of in injection wells, and two surface disposal ponds in four oil fields in the southern San Joaquin Valley, California (Fruitvale, Lost Hills, North and South Belridge). Correlations between Cl and δ 18 O, as well as other ions, and gradual increases in salinity with depth, indicate dilution of one or more saline end-members by meteoric water. The saline end-members, represented by deep samples (610 m–2621 m) in three oil-bearing zones, are characterized by Na Cl composition, near-seawater Cl concentrations (median 20,000 mg/L), enriched δ 18 O H 2 O (median 3.4‰), high ammonium(up to 460 mg-N/L), and relatively high radium activity ( 226 Ra+ 228 Ra = 12.3 Bq/L). The deepest sample has low Na/Cl (0.74), high Ca/Mg (5.0), and low 87 Sr/ 86 Sr (0.7063), whereas the shallower samples have higher Na/Cl (0.86–1.2), Ca/Mg near 1, and higher 87 Sr/ 86 Sr (∼0.7083). The data are consistent with an original seawater source being modified by various depth and lithology dependent diagenetic processes. Dilution by meteoric water occurs naturally on the east side of the valley, and in association with water-injectionactivities on the west side. Meteoric-water flushing, particularly on the east side, results in lower solute concentrations (minimum total dissolved solids 2730 mg/L) and total radium (minimum 0.27 Bq/L) in oil-field water, and promotes biodegradation of dissolved organic carbon and hydrocarbon gases like propane. Acetate concentrations and δ 13 C of dissolved inorganic carbon indicate biogenic methane production occurs in some shallow oil zones. Natural and human processes produce substantial variability in the geochemistry of oil-field water that should be considered when evaluating mixing between oil-field waters and groundwater. The variability could result in uncertainty as to detecting the potential source and impact of oil-field water on groundwater.

California↗
USGS2026

Consolidation and permeability of the B1 and D1 gas hydrate bearing sands and associated seal sediments of the extended-duration gas production test site on the Alaska North Slope

Gas hydrate, a solid combination of gas (mostly methane in nature) and water molecules stable at low temperatures and elevated pressures, occurs naturally in marine and permafrost-associated environments. Gas hydrate reservoirs, such as those in the Alaska North Slope, have been considered potential energy resources for gas production. To understand the petrophysical and geo-mechanical characteristics of the reservoir, core samples retrieved from the site of the JOGMEC-DOE-USGS collaborative gas hydrate R&D project have been analyzed in the laboratory for their hydraulic and mechanical properties. This paper focuses on both seal and reservoir samples associated with the B1 and D1 sands, which are evaluated for index properties (including porosity, grain size distribution, liquid and plastic limits, specific surface area, and specific gravity), consolidation, permeability, and water retention. Furthermore, the reservoir core samples were tested with pore-filling, laboratory-grown tetrahydrofuran hydrate, in order to assess reservoir behavior during gas production from hydrates. Under simulated in situ stress conditions, the seal and hydrate-free reservoir cores had a permeability anisotropy ratio of k h / k v = 3.0–5.0, and k h / k v = 2.4–3.0 for the reservoir tetrahydrofuran hydrate-bearing cores. The data suggest that depressurizing the reservoir to induce hydrate dissociation alters the reservoir effective permeability in three ways: permeabilities decrease due to porosity lost (e.g., the initial reservoir thickness can decrease by up to 5% upon 7 MPa depressurization), permeability increases due to the loss of solid hydrate in the pore space, and permeability anisotropy k h / k v decreases in response to the evolving pore-space geometry. We show that given the simulated in situ gas hydrate saturations (i.e., S h = 32% in core 7P-2E and S h = 21% in core 20P-4), gas production from the dissociation of tetrahydrofuran hydrate in the two tested cores results in a net increase in effective permeability and a decrease in k h / k v . This study highlights the importance of investigating seal and reservoir sediments and the impacts of depressurization on the porosity and permeability responses during production.

Alaska↗
USGS2022

Native fish need a natural flow regime

Water development has threatened the ecological integrity of riverine ecosystems. Increasing water demand, persistent drought, and climate change exacerbate the effects of habitat degradation and loss in altered systems such as the Colorado River basin. Today, biologists are challenged to identify management actions that benefit native fishes while not hindering water development or management. Herein, we discuss the importance of the natural flow regime for functioning riverine ecosystems and provide examples from four tributaries to the Green River, a major headwater branch of the Colorado River. These tributaries represent a gradient of impacts ranging from water abstraction to the point of complete seasonal desiccation to a relatively natural flow regime, and consequently have maintained different levels of instream habitat complexity and native fish persistence. Despite decades of management, endangered species lack self-sustaining populations and other native species have been extirpated from over half their ranges, which begs the question: can water development and fish conservation be balanced under current water laws and climate change-driven declines in runoff? Given the continued decline in freshwater biodiversity and abundance occurring across the globe, we contend that immediate designation of rivers with natural flow regimes as freshwater conservation areas will enhance native species recovery.

Arizona, Colorado, Utah, Wyoming↗
USGS1990

Geohydrology and simulation of ground-water flow in the carbonate rocks of the Valley Creek basin, eastern Chester County, Pennsylvania

Sixty-eight percent of the 22.6-square-mile Valley Creek basin is underlain by Cambrian and Ordovician limestone and dolomite. Ground water flows through a network of interconnected secondary openings; primary porosity is virtually nonexistent. Some of these openings have been enlarged by solution. Secondary porosity and permeability exhibit great spatial variability, and the yield and specific capacity of wells are highly variable. The number of water-bearing zones decreases with depth. Fifty percent of water-bearing zones are encountered within 100 feet of the land surface, and 81 percent are within 200 feet. Most ground-water flow in the Valley Creek basin is local and discharges to nearby streams. Ground-water discharge comprised an average of 76 percent of the flow of Valley Creek during 1983--87, including both natural ground- water discharge and quarry pumpage discharged to Valley Creek. Discharge from the Cedar Hollow quarry comprised 21 to 26 percent of the base flow of Valley Creek; the average was 23 percent. The average natural base flow of Valley Creek would be 8 percent lower if the quarry were not operating. Regional ground-water flow is to the northeast to the Schuylkill River. On the western side of the Valley Creek basin, the ground-water divide is 1/2 mile west of the surface-water divide. An estimated 0.75 million gallons per day of ground water flows from the adjacent West Valley Creek basn eastward into the Valley Creek basin. A ground-water divide is not present on the eastern side of the basin; the water table slopes gently eastward toward the Schuylkill River. On the northeaster side, an estimated 1.76 million gallons per day of ground water flows northeastward out of the basin to the Schuylkill River beneath the surface-water divide. On the southeaster side, an estimated 0.85 million gallons per day of ground water flows beneath the surface-water divide into the basin. Annual water budgets and an average water budget were calculated for 1983-87 for the 20.8-square-mile area bove the streamflow-gaging station. Annual precipitation for 1983-87 ranged from 40.61 to 56.55 inches and averaged 47.25 inches; annual streamflow ranged from 15.55 to 28.57 inches and averaged 22.31 inches; annual evapotranspiration ranged from 18.21 to 24.83 inches and averaged 22.90 inches; and annual recharge ranged from 15.89 to 26.84 inches and averaged 21.04 inches. The Valley Creek basin was modeled as a two-dimensional water-table aquifer. Recharge to, ground-water flow through, and discharge from the rocks of Chester valley were simulated. In order to include the natural hydrologic boundaries of the ground-water-flwo system, the 66.4-square-mile area between the Brandywine Creek and the Schuylkill River was modeled. The model was calibrated under stead-state conditions using avareage recharge and evapotranspiration rates. Aquifer hydraulic conductivity was estimated from specific-capacity and quifer-test data. The average (1983-87) annual water budget for hte Valley Creek basin was simualted. The effect of increased ground-water development on base flow and underflow was simulated by locating a hypothetical well field produceing 4 million gallons per day in different parts of the basin. Pumpage from a well field near surface-water divides would induce as much as an additional 1.41 inches per year of underflow from an adjacent surface-water basin. Pumpage from a well field near the center of the basin would affect base flow more than underflow. Increased seepage of ground water into quarries as a result of their expansion was simulated as increased withdrawal by pumping. A 100-percent increase in the pumping rate of the Cedar Hollow quarry, from 3.93 to 7.86 million gallons per day, owuld reduce the natural base flow of Valley Creek by 18 percent. However, the quarry pumpage would be discharged to Valley Creek, thereby increasing the base flow at the gaging station by

Pennsylvania↗
USGS2005

Water-quality trend analysis and sampling design for streams in the Red River of the North Basin, Minnesota, North Dakota, and South Dakota, 1970-2001

The Bureau of Reclamation is considering several alternatives to meet the future municipal, rural, and industrial water-supply needs in the Red River of the North (Red River) Basin, and an environmental impact statement is being prepared to evaluate the potential effects of the various alternatives on the water quality and aquatic health in the basin in relation to the historical variability of streamflow and constituent concentration. Therefore, a water-quality trend analysis was needed to determine the amount of natural water-quality variability that can be expected to occur in the basin, to determine if significant water-quality changes have occurred as a result of human activities, to explore potential causal mechanisms for water-quality changes, and to establish a baseline from which to monitor future water-quality trends. This report presents the results of a study conducted by the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, to analyze historical water-quality trends in two dissolved major ions, dissolved solids, three nutrients, and two dissolved trace metals for nine streamflow-gaging stations in the basin. Annual variability in streamflow in the Red River Basin was high during the trend-analysis period (1970-2001). The annual variability affects constituent concentrations in individual tributaries to the Red River and, in turn, affects constituent concentrations in the main stem of the Red River because of the relative streamflow contribution from the tributaries to the main stem. Therefore, an annual concentration anomaly, which is an estimate of the interannual variability in concentration that can be attributed to long-term variability in streamflow, was used to analyze annual streamflow-related variability in constituent concentrations. The concentration trend is an estimate of the long-term systematic changes in concentration that are unrelated to seasonal or long-term variability in streamflow. Concentrations that have both the seasonal and annual variability removed are called standardized concentrations. Numerous changes that could not be attributed to natural streamflow-related variability occurred in the standardized concentrations during the trend-analysis period. During various times from the late 1970's to the mid-1990's, significant increases occurred in standardized dissolved sulfate, dissolved chloride, and dissolved- solids concentrations for eight of the nine stations for which water-quality trends were analyzed. Significant increases also occurred from the early 1980's to the mid-1990's for standardized dissolved nitrite plus nitrate concentrations for the main-stem stations. The increasing concentrations for the main-stem stations indicate the upward trends may have been caused by human activities along the main stem of the Red River. Significant trends for standardized total ammonia plus organic nitrogen concentrations occurred for most stations. The fitted trends for standardized total phosphorus concentrations for one tributary station increased from the late 1970's to the early 1980's and decreased from the early 1980's to the mid-1990's. Small but insignificant increases occurred for two main-stem stations. No trends were detected for standardized dissolved iron or dissolved manganese concentrations. However, the combination of extreme high-frequency variability, few data, and the number of censored values may have disguised the streamflow-related variability for iron. The time-series model used to detect historical concentration trends also was used to evaluate sampling designs to monitor future water-quality trends. Various sampling designs were evaluated with regard to their sensitivity to detect both annual and seasonal trends during three 4-month seasons. A reasonable overall design for detecting trends for all stations and constituents consisted of eight samples per year, with monthly sampling from April to August and bimonthly sampling from October to February.

Scientific Investigations Report↗
USGS2004

Effects of flow modification on a cattail wetland at the mouth of Irondequoit Creek near Rochester, New York: Water levels, wetland biota, sediment, and water quality

An 11-year (1990-2001) study of the Ellison Park wetland, a 423-acre, predominantly cattail (Typha glauca) wetland at the mouth of Irondequoit Creek, was conducted to document the effects that flow modifications, including installation of a flow-control structure (FCS) in 1997 and increased diversion of stormflows to the backwater areas of the wetland, would have on the wetland's ability to decrease chemical loads transported by Irondequoit Creek into Irondequoit Bay on Lake Ontario. The FCS was designed to raise the water-surface elevation and thereby increase the dispersal and detention of stormflows in the upstream half of the wetland; this was expected to promote sedimentation and microbial utilization of nutrients, and thereby decrease the loads of certain constituents, primarily phosphorus, that would otherwise be carried into Irondequoit Bay. An ecological monitoring program was established to document changes in the wetland's water levels, biota, sedimentation rates, and chemical quality of water and sediment that might be attributable to the flow modifications. Water-level increases during storms were mostly confined to the wetland area, within about 5,000 ft upstream from the FCS. Backwater at a point of local concern, about 13,000 ft upstream, was due to local debris jams or constriction of flow by bridges and was not attributable to the FCS. Plant surveys documented species richness, concentrations of nutrients and metals in cattail tissues, and cattail productivity. Results indicated that observed differences among survey periods and between the areas upstream and downstream from the FCS were due to seasonal changes in water levels—either during the current year or at the end of the previous year's growing season—that reflected the water-surface elevation of Lake Ontario, rather than water-level control by the FCS. Results showed no adverse effects from the naturally high water levels that prevail annually during the spring and summer in the wetland, nor from the short-duration increases in water levels that result from FCS operation. Fish surveys documented the use of the wetland by 44 species, of which 25 to 29 species were found in any given year. Community composition was relatively consistent during the study, but seasonal and year-to-year variations in dominant resident and nonresident species were noted, and probably reflected natural or regional population patterns in Lake Ontario and Irondequoit Bay. The FCS allowed fish passage at all water levels and had no discernible adverse effect on the fish community. Bird surveys documented the use of the wetland by more than 90 species for breeding, feeding, and migration. Ground-nesting birds were unaffected by the FCS. Seasonally high water levels, rather than short-duration increases caused by the FCS, might have caused the scarcity or absence of certain wetland species by limiting the extent of breeding habitat for some species and the exposure of mud flats that attracted other species. Some noticeably scarce or absent species also were rare or absent elsewhere along the south-central shore of Lake Ontario. Benthic-macroinvertebrate studies were of minimal use for evaluating the effect of the FCS because no surveys were conducted after FCS installation. The precontrol results allowed assessment of the ecological quality of the wetland on the basis of biotic indices, and generally indicated moderately to severely impaired conditions. Differences between the macroinvertebrate communities in the southern part of the wetland and those in the northern part were attributed to habitat differences, such as substrate composition, water depth, and density of submerged aquatic vegetation. Sedimentation rates in the areas upstream and downstream from the FCS increased after the flow modifications, more in the area upstream from the FCS than in the downstream area. The concurrent downstream increase and the dynamic patterns of deposition and scour indicated that although the FCS and the other flow modifications undoubtedly were major factors in the postcontrol upstream increase in sedimentation rates, other factors, such as the magnitude, frequency, and the timing (season) of peak flows, might also have contributed. Periodic analyses of sediment samples from three longterm depositional sites in the wetland documented the concentrations of major and trace elements, polycyclic aromatic hydrocarbons, and organochlorine and organophosphate compounds. The concentrations of most constituents showed no substantial fluctuation or consistent upward or downward trend during the years sampled, nor did they identify any change after FCS installation. Comparison of the measured concentrations with sediment-quality guidelines that are used to assess the ecological quality of substrate environments indicated that the wetland was moderately to severely impaired—an assessment consistent with the benthic-macroinvertebrate biotic indices. During the precontrol period (1990–96), the wetland was a sink for particulate constituents (removal efficiencies for total phosphorus and total suspended solids were 28 and 47 percent, respectively), but had little effect on conservative constituents (chloride and sulfate). The wetland was a source of orthophosphate and ammonia (removal efficiencies were -38 and -84 percent, respectively). During the postcontrol period (1997–2001), the wetland continued to be a sink for particulate constituents (removal efficiencies for total phosphorus and total suspended solids were 45 and 52 percent, respectively); the exportation of orthophosphate by the wetland decreased (by 7 percent), whereas that of ammonia increased (by about 70 percent). The outflow loads of orthophosphate and ammonia represented about 15 and 2.3 percent of total phosphorus and total nitrogen loads, respectively. Changes in the loads of conservative constituents were negligible, and the overall removal efficiencies for other constituents during the precontrol period differed from those of the postcontrol period by no more than 5.4 percent. Statistical analyses of monthly inflow and outflow loads indicated significant differences between inflow and outflow loads of most constituents during the pre- and postcontrol periods. Load data were adjusted to remove the effects of dissimilar hydrologic conditions that prevailed during the pre- and postcontrol periods, and to isolate the water-quality-improvement effect that could be attributed solely to the FCS. Results indicated that the FCS contributed significantly to the decrease in total phosphorus loads, and slightly to a decrease in ammonia-plus-organic nitrogen loads, but had little or no significant effect on loads of other constituents.

New York↗
USGS2011

Geophysical and flow-weighted natural-contaminant characterization of three water-supply wells in New Hampshire

Three bedrock water-supply systems in New Hampshire were studied, using borehole geophysics and flow-weighted sampling techniques, to determine the sources and distribution of natural contaminants in water entering the boreholes and to assess whether borehole modifications might be used to reduce contaminant levels. Well water in more than 100 community water-supply systems in New Hampshire have natural contaminants, such as arsenic and uranium, above the U.S. Environmental Protection Agency maximum contaminant levels of 10 and 30 micrograms per liter, respectively. The water-system wells were studied to identify fractional contributions of natural contaminants from specific fracture zones. The yields and flow-weighted contaminant levels of such fracture zones were assessed to determine if a modification of the borehole might lead to a reduction in the system’s contaminant levels. The water-supply systems investigated were typical of small community water systems in New Hampshire where a water system may serve 100 connections or less. Each water system consisted of two wells, approximately 300 to 400 feet deep, in generally low-yielding (about 10 gallons per minute or less) crystalline bedrock. The wells were typically operated a few hours per day to fill a storage tank and had tens of feet of drawdown caused by the low well yields. The systems selected had contaminant concentrations slightly above MCL, or a low-level contamination. One of the water systems investigated had low-level (10 to 24 micrograms per liter) arsenic contamination, and two of the water systems had low-level uranium (30 to 40 micrograms per liter) contamination. The contaminant values were blended-water concentrations from the two wells in a system. Each water system had differences in contaminant concentrations between the two wells. In each case, the well with the greater concentration of the two was selected for investigation. In two of the three systems investigated, there was either not enough variation in the borehole contaminant concentration or not enough water-yielding fractures for borehole modifications to be a viable potential remedy to elevated contamination. However, borehole and contaminant conditions in one of the bedrock supply-well systems may be favorable to potential improvement of supplied water by borehole modification where selected fracture zones are sealed off from supplying water to the well.

New Hampshire↗
USGS2012

The potential effects of sodium bicarbonate, a major constituent from coalbed natural gas production, on aquatic life

The production water from coalbed natural gas (CBNG) extraction contains many constituents. The U.S. Environmental Protection Agency has established aquatic life criteria for some of these constituents, and it is therefore possible to evaluate their risk to aquatic life. However, of the major ions associated with produced waters, chloride is the only one with an established aquatic life criterion (U.S. Environmental Protection Agency, 1988). The focus of this research was NaHCO 3 , a compound that is a major constituent of coalbed natural gas produced waters in the Tongue and Powder River Basins. This project included laboratory experiments, field in situ experiments, a field mixing zone study, and a fishery presence/absence assessment. Though this investigation focuses on the Tongue and Powder River Basins, the information is applicable to other watersheds where sodium bicarbonate is a principle component of product water either from CBNG or from traditional or unconventional oil and gas development. These data can also be used to separate effects of saline discharges from those potentially posed by other constituents. Finally, this research effort and the additional collaboration with USGS Water Resources and Mapping, Bureau of Land Management, US Environmental Protection Agency, State of Montana, State of Wyoming, Montana State University, University of Wyoming, and others as part of a Powder River Aquatic Task Group, can be used as a model for successful approaches to studying landscapes with energy development. The laboratory acute toxicity experiments were completed with a suite of organisms, including 7 species of fish, 5 species of invertebrates, and 1 amphibian species. Experiments performed on these multiple species resulted in LC50s that ranged from 1,120 to greater than (>) 8,000 milligrams sodium bicarbonate per liter (mg NaHCO 3 /L) (also defined as 769 to >8,000 milligrams bicarbonate per liter (mg HCO 3 -/L) or total alkalinity expressed as 608 to >4,181 milligrams calcium carbonate per liter (mg CaCO 3 /L)) that varied across species and lifestage within a species. The age at which fish were exposed to NaHCO 3 significantly affected the severity of toxic responses for some organisms. The chronic toxicity of NaHCO 3 was defined in experiments that lasted from 7—60 days post-hatch. For these experiments, sublethal effects such as growth and reproduction, in addition to significant reductions in survival were included in the final determination of effects. Chronic toxicity was observed at concentrations that ranged from 450 to 800mg NaHCO 3 /L (also defined as 430 to 657 mg HCO 3 -/L or total alkalinity expressed as 354 to 539 mg CaCO 3 /L) and the specific concentration depended on the sensitivity of the four species of invertebrates and fish exposed. Sublethal investigations during chronic studies revealed percent decrease in the activity of sodium-potassium adenosine triphosphatase (Na/K ATPase, an enzyme involved in ionoregulation) and the age of the fish at the onset of the decrease may affect the ability of fathead minnow to survive exposures to NaHCO 3 . A database of toxicity evaluations of NaHCO 3 on aquatic life has been constructed. Using these data, sample acute and chronic criteria of 459 and 381 mg NaHCO 3 /L, respectively, can be calculated for the protection of aquatic life. The final derivation and implementation of such criteria is, of course, left to the discretion of the concerned management agencies. A combination of in situ experiments, static-renewal experiments performed simultaneously with in situ experiments, and static renewal experiments performed with site water in the laboratory, demonstrated that untreated coalbed natural gas (CBNG) product water from the Tongue and Powder River Basins reduces survival of fathead minnow and pallid sturgeon. More precisely, the survival of early-lifestage fathead minnow, especially those less than 6-days post hatch (dph), likely is reduced significantly in the field when concentrations of NaHCO 3 rise above 1,500 mg/L. However, age was not a factor for pallid sturgeon and they were sensitive to product water regardless of age. Treatment with the Higgins Loop™ technology and dilution of untreated water increased survival in the laboratory. Both of these situations reduced ammonia in addition to the concentrations of NaHCO 3 . These experiments addressed the acute toxicity of effluent waters being added to the main stem rivers, but did not address issues related to the volumes of water that may be added to the watershed. Mixing zones of the three outfalls studied ranged from approximately 800—1,200 m below the confluence and the areas within these mixing zones with acutely lethal concentrations of NaHCO 3 (as defined by the presence of concentrated dye) are limited. The areas with concentrations of NaHCO 3 more than the concentrations likely to cause significant mortality, and more than the calculated sample water-quality criteria in the Tongue and Powder River Basins appear to be limited to tributaries and parts of mixing zones with considerable additions of untreated effluent.

Montana;Wyoming↗
USGS2008

Natural and Human Influences on Water Quality in a Shallow Regional Unconsolidated Aquifer, Northern Atlantic Coastal Plain

Data collected from more than 400 wells in the surficial unconfined aquifer in the Northern Atlantic Coastal Plain (New York through North Carolina) were compiled and analyzed to improve understanding of multiple natural and human influences on water quality in such shallow regional aquifers. Geochemical patterns were identified and described through principal components analysis on major ions, and correlation and logistic regression were used to relate observed concentrations of nitrate and selected pesticide compounds (atrazine, metolachlor, simazine, and deethylatrazine, an atrazine degradate) and volatile organic compounds (chloroform, 1,1,1-trichloroethane, tetrachlorethene, and methyl tert-butyl ether) to likely influences, such as observed geochemical patterns, land use, hydrogeology, and soils. Variability in major-ion concentrations is primarily related to ionic strength and redox condition. Concentrations of nitrate, pesticides, and volatile organic compounds are related to natural conditions, as well as the distribution of likely sources reflected in land use. Nitrate is most common in aerobic ground water and in relatively well-drained areas, for example; concentrations greater than 0.4 milligrams per liter may result from a variety of human activities, although concentrations greater than 3 milligrams per liter are more likely in agricultural areas. Atrazine, deethylatrazine, and metolachlor also are related to geochemical patterns, likely because ground-water geochemistry reflects hydrogeologic and soil conditions affecting pesticide transport to the water table. Results demonstrate the value of geochemical information along with the distribution of sources and other influences to understanding the regional occurrence of selected compounds in ground water. Such influences are not unique to the Northern Atlantic Coastal Plain, and thus observations and interpretations are relevant to broader areas.

Scientific Investigations Report↗
USGS2001

Potential contribution of microbial degradation to natural attenuation of MTBE in surface water systems

The potential contribution of in situ biodegradation as a mechanism for natural attenuation of MTBE in surface water was studied. Surface water sediments from streams and lakes at 11 sites throughout the US. Microbial degradation of [U-14C] MTBE was observed in surface-water-sediment microcosms under anaerobic conditions, but the efficiency and products of anaerobic MTBE biodegradation were strongly dependent on the predominant terminal electron accepting conditions. In the presence of substantial methanogenic activity, MTBE biodegradation was nominal and involved reduction of MTBE to t-butanol (TBA). Under more oxidizing conditions, minimal accumulation of 14C-TBA and significant mineralization of [U-14C] MTBE to 14CO2 were observed. Microorganisms inhabiting the bed sediments of streams and lakes could degrade MTBE effectively under a range of anaerobic terminal electron accepting conditions. Thus, anaerobic bed sediment microbial processes also might contribute to natural attenuation of MTBE in surface water systems throughout the US. This is an abstract of a paper presented at the 222nd ACS National Meting (Chicago, IL 8/26-30/2001).

ACS Division of Environmental Chemistry, Preprints↗