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Vulnerability assessment of groundwater influenced ecosystems in the Northeastern United States

Groundwater-influenced ecosystems (GIEs) are increasingly vulnerable due to groundwater extraction, land-use practices, and climate change. These ecosystems receive groundwater inflow as a portion of their baseflow or water budget, which can maintain water levels, water temperature, and chemistry necessary to sustain the biodiversity that they support. In some systems (e.g., springs, seeps, fens), this connection with groundwater is central to the system’s integrity and persistence. Groundwater management decisions for human use often do not consider the ecological effects of those actions on GIEs. This disparity can be attributed, in part, to a lack of information regarding the physical relationships these systems have with the surrounding landscape and climate, which may influence the environmental conditions and associated biodiversity. We estimate the vulnerability of areas predicted to be highly suitable for the presence of GIEs based on watershed (U.S. Geological Survey Hydrologic Unit Code 12 watersheds: 24–100 km 2 ) and pixel (30 m × 30 m pixels) resolution in the Atlantic Highlands and Mixed Wood Plains EPA Level II Ecoregions in the northeastern United States. We represent vulnerability with variables describing adaptive capacity (topographic wetness index, hydric soil, physiographic diversity), exposure (climatic niche), and sensitivity (aquatic barriers, proportion urbanized or agriculture). Vulnerability scores indicate that ~26% of GIEs were within 30 m of areas with moderate vulnerability. Within these GIEs, climate exposure is an important contributor to vulnerability of 40% of the areas, followed by land use (19%, agriculture or urbanized). There are few areas predicted to be suitable for GIEs that are also predicted to be highly vulnerable, and of those, climate exposure is the most important contributor to their vulnerability. Persistence of GIEs in the northeastern United States may be challenged as changes in the amount and timing of precipitation and increasing air temperatures attributed to climate change affect the groundwater that sustains these systems.

Connecticut, Delaware, District of Columbia, Maine

Continuous monitoring and temporal variability of fluorescence of dissolved organic matter in karst groundwater of the Edwards aquifer, south-central Texas, 2019–24

Widespread urbanization on the Edwards aquifer recharge zone in south-central Texas has prompted the development of new approaches and tools for evaluating the current and future status of water quality in the San Antonio and Barton Springs segments of the Edwards aquifer. The U.S. Geological Survey, in cooperation with the San Antonio Water System and the City of Austin, applied continuous monitoring of fluorescence of dissolved organic matter (fDOM) to characterize the sources and transport of dissolved organic matter and associated constituents in the Edwards aquifer. Continuous fDOM time-series data were adjusted using empirically derived temperature, turbidity, and inner-filter-effect correction factors prior to analysis and interpretation. Fully corrected fDOM time-series data from the study sites were evaluated for short- and long-term temporal variability in fDOM in the context of the hydrologic and climatic conditions that occurred during the 5-year study period to understand vulnerability of the aquifer to potential contaminants in recharge. Study results indicate that fDOM is an effective proxy for dissolved organic carbon that, in turn, is indicative of the influx of recent surface water and associated contaminants, and thus, aquifer vulnerability to those contaminants. Although other continuously monitored water-quality parameters provide insights into changes in water quality in response to varying hydrologic conditions, the quantitative relation between fDOM and dissolved organic carbon directly indicates the timing and magnitude of pulses of organic constituents derived from the land surface, whereas other water-quality parameters do not.

Texas

Ecohydrological response of a forested headwater catchment to a flash drought in the Southeastern U.S.

Flash droughts differ from traditionally defined droughts in their rapidity of intensification and often associated high vapor-pressure deficit. These droughts can lead to declines in streamflow and water table depth and induce water stress to vegetation at a greater rate than droughts that manifest over longer periods. However, little is known regarding the response of forested environments to flash drought because most studies of impacts have been conducted in agricultural settings. In this study we investigated water-use patterns of riparian trees using sap flow methods and examined the role of groundwater as a source of moisture over three periods that were delimited by antecedent soil moisture conditions. For a longer-term perspective we also examine monthly streamflow over the 35-year record. We observed that trees at only one monitoring plot showed a decrease in water use relative to evaporative demand during a flash drought. Total reverse sap flow (flow toward the roots rather than the canopy) greatly increased during the flash drought period, suggesting the likely occurrence of hydraulic redistribution to the excessively dry soils. Over the drought period groundwater became a more dominant source of moisture for sustaining forest water use. Monthly mean streamflow during the flash drought approached levels observed in past multiyear droughts. This is the first study, to our knowledge, to specifically investigate the response of multiple water budget components to flash drought in a humid forest. As more studies are conducted, a better understanding of the range of expected responses are likely to emerge.

Georgia

Status and understanding of groundwater quality in the San Joaquin Valley Kern County subbasin domestic-supply aquifer study unit, 2022—California GAMA Priority Basin Project

The quality of water accessed by domestic wells (here referred to as domestic groundwater resources) in the San Joaquin Valley Kern County subbasin (basin number 5-022.14) was assessed as part of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project (GAMA-PBP), in cooperation with the California State Water Resources Control Board. Kern County is at the southern end of the San Joaquin Valley in California, and about 30,000 residents are estimated to use privately owned domestic wells for drinking water. Domestic wells typically draw from shallower parts of the aquifer system than public-supply wells and can be more vulnerable to effects from surface activities. Kern County is host to a highly productive agricultural industry, with Bakersfield as the main urban center. The Kern River runs through Bakersfield from the southern Sierra Nevada and intersects the Kern Water Bank, one of the largest groundwater banking operations in California, at the Kern River Intertie. The section of the Kern River running through the Kern Water Bank is dry most years. Kern County also encompasses some of the most productive oil and gas basins in California, with extensive underground and surface disposal of oil-field wastewater. This study was based on data collected from 33 sites sampled by the U.S. Geological Survey for the GAMA-PBP in 2022. To provide context for the water quality assessment, measured concentrations were compared to regulatory and non-regulatory health-based and aesthetic benchmarks. A grid-based method was used to estimate the proportions of the groundwater resources used for domestic-supply wells that have water-quality constituents below (low relative concentration), approaching (moderate relative concentration), or above (high relative concentration) benchmark concentrations. At least one measured constituent with a regulatory benchmark was categorized as having a high relative concentration in 72 percent of the aquifer area used for domestic groundwater resources. Inorganic constituents were detected at high concentrations in 45 percent of the domestic groundwater resources, and the constituents detected above regulatory benchmarks were arsenic, nitrate, and uranium. At least one organic constituent was detected at high concentrations in 41 percent of the domestic groundwater resources, and the constituents exceeding regulatory benchmarks were the fumigants 1,2,3-trichloropropane (1,2,3-TCP), 1,2-dibromo-3-chloropropane (dibromochloropropane [DBCP]), 1,2-dibromoethane (EDB), and the per-and polyfluoroalkyl substance (PFAS) perfluorooctanesulfonate. The disinfection by-product chloroform, the fumigant 1,2-dichloropropane, the herbicides atrazine and hexazinone, and the herbicide degradates 2-chloro-6-ethylamino-4-amino-s-triazine, 2-chloro-4,6-diamino-s-triazine, 4-hydroxychlorothalonil, and metolachlor sulfonic acid were detected in more than 10 percent of domestic groundwater resources, but concentrations did not exceed regulatory benchmarks. Land use, groundwater age (fraction of modern water and mean age), and geochemical environment (oxic or anoxic conditions, pH, alkalinity) were associated with the distribution of high relative concentrations of inorganic and organic constituents. Young, oxygenated water is recharged along the Kern River and adjacent recharge ponds, or as irrigation water in the agricultural areas. High concentrations of nitrate and volatile organic compounds occurred in the oxic water in urban and agricultural areas. The fumigants 1,2,3-TCP, DBCP, and EDB were reported throughout the agricultural areas, whereas chloroform, tetrachloroethene, and PFAS were associated with urban land use. High uranium concentrations were associated with young, modern groundwater in agricultural areas with low pH and high bicarbonate. Total dissolved solids increased with distance from the Kern River, as the contributions of fresh, oxic water decreased. High concentrations of arsenic were present in older anoxic or alkaline groundwater away from areas of recharge. Overall, groundwater age, redox conditions, and the source of recharge as a result of different land uses contribute to large aquifer-scale portions of domestic groundwater resources that exceed health-based benchmarks for nitrate, uranium, and fumigant concentrations.

California

Central Valley Hydrologic Model version 2 (CVHM2): Decision support tool for groundwater and land subsidence management

The San Joaquin Valley (SJV) of California is one of the world’s most productive agricultural regions. Reliance on groundwater has led to some of the greatest rates of human-induced land subsidence in the world in the 20th century, as well as more recently. The United States Geological Survey (USGS) has recently developed an integrated surface–subsurface hydrologic model, the Central Valley Hydrologic Model 2 (CVHM2), that represents the major components of the hydrologic system of California’s Central Valley. In this study, CVHM2 was applied as a decision support tool while simulating various management strategies to mitigate the land subsidence caused by the extraction of groundwater. CVHM2 was extended through to 2073 and applied to simulate management scenarios in terms of three primary drivers and their impact on subsidence along the Delta–Mendota Canal (DMC), a critical piece of infrastructure in the western SJV. The drivers considered were agricultural water demands, managed aquifer recharge (MAR), and changes in future climate. The results show that future subsidence is most sensitive to water demands, second most sensitive to future changes in climate, and relatively insensitive to MAR when it is applied as a surface application in the western SJV. However, we demonstrate via proof-of-concept scenarios that the MAR is capable of arresting subsidence when implemented via injection below the Corcoran Clay Member of the Tulare Formation instead of as a surface application. We also examine the uncertainty that is the result of climate variability and how to use the tool to identify the most appropriate strategies to constrain future subsidence to acceptable levels.

California

Spatiotemporal variability of algal biomass and nitrate in Owasco and Seneca Lakes in the Finger Lakes Region, New York, in 2019

Cyanobacterial harmful algal blooms (CyanoHABs) have become increasingly common, threatening the security of water resources globally. The U.S. Geological Survey conducted high-resolution nearshore mapping surveys using boat-mounted multiparameter sondes and nitrate sensors during the summer and fall of 2019 on Owasco Lake and Seneca Lake, two lakes with documented CyanoHABs in the Finger Lakes region of New York State. Discrete sensor measurements and water-quality samples were collected at fixed points along survey routes and continuous data were generated at open-water monitoring platforms. This investigation examined whether water-quality information from nearshore surveys was representative of open-water conditions and if nearshore surveys could be used to identify areas with localized nearshore CyanoHABs and potential sources of nutrients not captured by tributary sampling. In addition to comparisons across methods, nearshore concentrations of nitrate and chlorophyll were evaluated relative to tributary outlets, cyanobacterial abundance and biovolume at discrete locations, and the locations of near-surface CyanoHABs that were designated as “confirmed with high toxins” by the New York State Department of Environmental Conservation. Nitrate and chlorophyll concentrations were comparable across methods for each lake, although concentration ranges were typically higher for nearshore mapping datasets than for nearshore discrete datasets. Nearshore surveys indicated areas of nitrate enrichment that varied temporally in both lakes. Orthophosphate was not routinely detected. Across methods, median chlorophyll concentrations were higher for the summer survey than for the fall survey in Owasco Lake. Nearshore chlorophyll concentrations varied more temporally in Owasco Lake than in Seneca Lake. Phytoplankton and cyanobacterial abundance and biovolume were about five times higher in Owasco Lake than in Seneca Lake. Cyanobacteria dominated the phytoplankton community in most samples, and Microcystis comprised the bulk of the cyanobacterial biovolume. The most abundant potential cyanotoxin-producing (specifically microcystins) genera were Microcystis , Synechococcus , Aphanocapsa , and Pseudanabaena . The cyanobacterial community composition was comparable between open-water monitoring platforms and nearshore samples. Microcystins were detected in seven survey samples from Owasco Lake, in one survey sample from Seneca Lake, and in one sample each from the open-water monitoring platforms on Owasco and Seneca Lakes that were collected about 7 days before the fall surveys. Microcystin detections were not consistently associated with high cyanobacterial cell counts or cyanotoxin-producing genera. Results from nearshore surveys were comparable to open-water monitoring platforms and discrete nearshore observations in the absence of nearshore or open-water CyanoHABs in these systems during the study. Patterns of nearshore concentrations of nitrate and chlorophyll from nearshore surveys may aid in the identification of areas with localized nitrate loading and shifts in phytoplankton abundance and community composition.

New York

Hydrogeologic framework of the Mountain Home area, southern Idaho

In the arid western Snake River Plain around the City of Mountain Home, Idaho, declining groundwater levels concern agricultural, municipal, and other water users who rely on groundwater for sustenance because surface-water resources are limited. The U.S. Geological Survey developed this hydrogeologic framework to provide an updated characterization of groundwater resources in the western Snake River Plain around the City of Mountain Home. The hydrogeologic framework comprises: (1) a conceptual description of hydrogeologic units, (2) a three-dimensional hydrogeologic model and borehole database, (3) a map of groundwater levels and change, and (4) a discussion of groundwater occurrence and movement within the study area. Hydrogeologic units were defined based on existing literature and the borehole database compiled for this study; the five hydrogeologic units are granite, rhyolite, basalt, fine-grained sediments, and coarse-grained sediments. Each unit can bear water, but the main regional aquifer in the study area occurs in the basalt and fine-grained sediment units with depth to water ranging from 150 to 765 feet. A perched groundwater zone near the City of Mountain Home is primarily hosted in basalt and used domestically with most depths to water ranging from 30 to 100 feet. Interflow zones, scoria, and vertical fractures create heterogeneity within the basalt hydrogeologic unit that exerts strong control on groundwater movement, creating horizontal perching conditions and zones of enhanced vertical conductivity that facilitate downward groundwater percolation. In the fine- and coarse-grained sediments and rhyolite units, inferred faults both impede and enhance groundwater movement. The borehole database was constructed by digitizing 540 well-driller reports and was used to build a three-dimensional hydrogeologic framework model which reasonably represents the spatial distribution of hydrogeologic units in the study area. Generally, fine-grained sediments underlie much of the study area, with basalt concentrated in the central and western study area and rhyolite and granite in the uplands to the north. Groundwater levels were measured in 180 wells in March and November 2023; these data were used to develop water-table contour maps and describe groundwater-level change over an irrigation season. Groundwater generally flows south-southwest to the Snake River and groundwater levels declined across most of the study area (from 0.03 to 22.01 feet) between spring and autumn 2023, which is consistent with long-term declines in the Cinder Cone Butte Critical Groundwater Area and Mountain Home Groundwater Management Area. Groundwater levels rose (0.6 to 15.44 feet) over the irrigation season in most wells in the perched groundwater zone near the City of Mountain Home and near the Snake River, indicating the importance of surface-water recharge to groundwater in areas where surface water irrigation occurs. In aggregate, this hydrogeologic framework provides an updated characterization of and new insights into groundwater resources in the study area to help inform water resources management.

Idaho

Disparate groundwater responses to wildfire

Post-wildfire investigations of groundwater response reveal a range of outcomes, varying from substantial increases to notable decreases in recharge and baseflow, with some studies indicating negligible or short-lived effects. This review assesses these varied responses within five critical categories: climate, vegetation, hydrogeology, fire characteristics, and the cryosphere, examining both short-term (within 2 years) and intermediate (2–10 years post-fire) effects. Despite considerable variability, some consistent patterns emerge. For instance, in hydroclimatic settings where water input and evaporative demand cycles are out of sync, post-wildfire groundwater responses tend to be positive (i.e., increased flux or storage), whereas under low fire severity conditions or in vegetation types that quickly recover, groundwater responses tend to be negative (i.e., decreased flux or storage). We synthesize relevant findings into a compendium of testable hypotheses aimed at explaining the spatiotemporal variability in observed post-wildfire groundwater responses. A recurring theme is the critical influence of the pre-wildfire groundwater regime on expected response and recovery. We identify opportunities for specific improvements in post-wildfire monitoring and modeling that would further advance capabilities to predict groundwater response. A key area for further research is understanding how wildfire effects on snow dynamics and other cryospheric processes translate to changes in groundwater.

WIREs Water

Reconnaissance of potential alternate water supply sources for the City of Gary, West Virginia

Seven potential sources of water, consisting of free-flowing discharge from abandoned coal mines at six locations and one abandoned flooded underground coal mine air shaft, were sampled for chemical analysis to assess the quality of the groundwater emanating from the seven mine sources. The six free-flowing mine discharge sources were also assessed for discharge by current-meter measurements on two separate occasions. The U.S. Geological Survey assessed these seven sources to provide information to the City of Gary, West Virginia (W. Va.), and the City of Gary’s consulting engineer with groundwater-quality and flow data to allow them to assess the seven sites as potential alternate sources of water for the City of Gary to augment its existing supply. For the six sites where discharge could be measured, discharge ranged from a minimum of 0.082 cubic feet per second (ft 3 /s) to a maximum of 3.685 ft 3 /s. Of the six sites measured, only two, Harmon Branch at Thorpe, W. Va. (USGS site 372201081303501) and the abandoned public-supply water wells near Havaco, W. Va. (USGS site 372358081344601), had discharge in excess of 1.00 ft 3 /s. Discharge from the abandoned public supply wells was 3.685 ft 3 /s on September 20, 2023, and 2.888 ft 3 /s on October 16, 2023, and discharge from Harmon Branch at Thorpe, W. Va., was 1.049 ft 3 /s on September 22, 2023, and 1.038 ft 3 /s on October 17, 2023. Discharge in the abandoned underground mine air shaft (USGS site 372224081340901) could not be assessed, but the air shaft drains an abandoned mine that likely contains water stored in approximately 1.7 square miles (mi 2 ) of abandoned underground coal mines in the Pocahontas No. 3 coal seam, and possibly an additional 0.9 mi 2 of leakage from the overlying Pocahontas No. 4 coal seam. Discharge for the six sites measured for the study was measured during a period between September 20 and October 18, 2023, and corresponded to the 12th to the 15th percentile of flow-duration statistics for the Tug Fork downstream of Elkhorn Creek at Welch, W. Va. streamgage (USGS site 03212750). Water-quality data for the seven sites sampled overall were acceptable with respect to drinking water standards. Of the 203 constituents analyzed, only a few failed to meet applicable U.S. Environmental Protection Agency (EPA) drinking water standards. Iron exceeded the 300 micrograms per liter (μg/L) secondary maximum contaminant level (SMCL) at only 1 of the 7 sites (14.3 percent) sampled. Iron concentrations ranged from a minimum of less than (<) 5.00 μg/L to a maximum of 724 μg/L with a median concentration of 7.62 μg/L. Manganese exceeded the 50.0 μg/L SMCL at 2 of the 7 sites (28.6 percent) sampled. Manganese concentrations ranged from a minimum of 1.93 μg/L to a maximum of 271 μg/L with a median concentration of 4.03 μg/L. No sites sampled exceeded the arsenic maximum contaminant level (MCL) of 10 μg/L. Arsenic concentrations ranged from a minimum of <0.100 μg/L to a maximum of 2.35 μg/L with a median arsenic concentration of 0.200 μg/L. None of the seven sites sampled for selenium for this study exceeded the EPA MCL of 50.0 μg/L. Selenium concentrations ranged from a minimum of <0.050 μg/L to a maximum of 5.26 μg/L with a median concentration of 3.21 μg/L. All seven sites were sampled for volatile organic compounds (VOCs), semivolatile organic compounds (SVOCs), and polychlorinated biphenyls (PCBs), but most had concentrations below the detection limit. Of the 10 PCB compounds analyzed for the seven sites sampled, none contained detectable concentrations of PCBs or Aroclor compounds. Of the 44 SVOCs analyzed at each of the seven sites sampled, only 1 SVOC, acenaphthene, was detected, at a concentration of 0.02 μg/L. Of the 96 VOCs analyzed, from each of the seven sites sampled, only two were found at detectable concentrations. Trichloromethane was detected only at 1 of the 7 (14.3 percent) sites sampled at a concentration of 0.027 μg/L, and benzene was detected at the same site and 3 additional sites (4 of the 7 sites or 57.1 percent of the sites sampled) at concentrations of 0.028, 0.029, 0.021, and 0.035 μg/L, but none exceeded the EPA MCL for benzene of 5.00 μg/L. Total coliform bacteria are ubiquitous in the environment, and their presence only suggests the potential for contamination by near-surface processes. Escherichia coli ( E. coli ) bacteria are derived from either human or animal fecal material and can be an indicator of potential contamination by pathogenic bacteria or viruses. Total coliform bacteria were detected at all 7 sites sampled at concentrations ranging from 17.5 to greater than (>) 2,420 most probable number per 100 mL (MPN/100 mL) of sample, with a median total coliform concentration of 1,553 MPN/100 mL. Escherichia coli bacteria were detected at 4 of the 7 sites sampled at concentrations ranging from <1 to 11.9 MPN/100 mL, with a median E. coli concentration of 5.1 MPN/100 mL.

West Virginia

Beyond the wedge: Impact of tidal streams on salinization of groundwater in a coastal aquifer stressed by pumping and sea-level rise

Saltwater intrusion (SWI) is a well-studied phenomenon that threatens the freshwater supplies of coastal communities around the world. The development and advancement of numerical models has led to improved assessment of the risk of salinization. However, these studies often fail to include the impact of surface waters as potential sources of aquifer salinity and how they may impact SWI. Based on field-collected data, we developed a regional, variable-density groundwater model using SEAWAT for east Dover, Delaware. In this location, major users of groundwater from the surficial aquifer are the City of Dover and irrigation for agriculture. Our model includes salinized marshland and tidal streams, along with irrigation and municipal pumping wells. Model scenarios were run for 100 years and included changes in pumping rates and sea-level rise (SLR). We examined how these drivers of SWI affect the extent and location of salinization in the surficial aquifer by evaluating differences in chloride concentration near surface waters and the subsurface freshwater-saltwater interface. We found the presence of the marsh inverts the typical freshwater-saltwater wedge interface and that the edge of the interface did not migrate farther inland. Additionally, we found that tidal streams are the dominant pathways of SWI at our site with salinization from streams being exacerbated by SLR. Our results also show that spatial distribution of pumping affects both the magnitude and extent of salinization, with an increase in concentrated pumping leading to more intensive salinization than a more widely distributed increase of the same total pumping volume.

Delaware

Roadway runoff induced acute mortality in juvenile coho salmon during spring storm events

Extensive mortalities of adult coho salmon ( Oncorhynchus kisutch ), often called “Urban Runoff Mortality Syndrome” (URMS), have been documented during the fall in creeks where water quality has been degraded by roadway runoff. The primary cause of mortality is 6PPD-quinone (6PPDQ; N -(1,3-dimethylbutyl)- N ′-phenyl- p -phenylenediamine quinone)–an ozone transformation product that forms on all vehicle tires. Laboratory studies have shown that juvenile coho salmon are highly sensitive to 6PPDQ exposure. Unlike adults, juveniles reside in impacted watersheds year-round, including during the spring when 6PPDQ concentrations can frequently exceed lethal thresholds during storms. To assess the potential incidence of URMS in springtime rearing habitats for juvenile coho salmon, we conducted a paired water quality and toxicology study at Miller Creek, a runoff-impacted watershed in Normandy Park, WA, USA. Using a small field facility, three naïve groups of juvenile coho salmon ( N = 720) were exposed to either creek water or groundwater ( N = 120 per treatment per storm), across three spring storms while comparing water quality and mortality end points. In creek water during exposures, peak 6PPDQ concentrations reached 73–110 ng/L, exceeding reported median lethal concentrations (LC 50 ) for coho salmon. Over each 24–73 h storm exposure period, ∼80% of Miller Creek-exposed juvenile salmon died. No mortality occurred among control fish exposed to groundwater. These results indicate previously unidentified mortality risks for juvenile life stages of coho salmon during spring storms, suggesting substantial and year-round water quality impediments to coho salmon health and recovery across roadway runoff-impacted spawning, rearing, and migratory habitats.

Washington

Using a time-of-travel sampling approach to quantify per- and polyfluoroalkyl substances (PFAS) stream loading and source inputs in a mixed-source, urban catchment

Understanding per- and polyfluoroalkyl substances (PFAS) mass distribution in surface and groundwater systems can support source prioritization, load reduction, and water management. Thirteen sites within an urban catchment were sampled utilizing a time-of-travel sampling approach to minimize the influence of subdaily fluctuations in mass from PFAS point sources and to quantify PFAS and ancillary chemical loads from various PFAS sources. A larger increase in perfluoroalkyl sulfonate (PFSA) loads (8 to 11 μg/s, up to 618%) than in perfluoroalkyl carboxylate (PFCA) loads (no change to 3.4 μg/s, up to 122%) was observed at sites below tributaries influenced by military bases with known groundwater discharge. Point discharges from two sewage treatment plants (STPs) resulted in increases in PFCA and PFSA loads that were similar (6 and 10 μg/s respectively) below the first STP and greater for PFCA compared to PFSA loads (23 and 13 μg/s respectively) below the second STP. Overall, percent increases in total PFAS load ranged from 20 to 277% for military base inputs and 44 to 77% for STP inputs. A focus catchment that represents only 14% (76.9 km 2 ) of the drainage area at the most downstream site (544 km 2 ) accounted for about 70% of PFSA and 40% of PFCA loads observed at the most downstream site. Results show that by using a time-of-travel sampling approach in mixed, urban settings with several PFAS sources, it is possible to quantify stream loads from individual PFAS sources, thereby improving source attribution and providing actionable data for water-resource managers.

ACS ES&T Water

Wetland sedimentation and vegetation patterns near selected highway crossings in West Tennessee

Wetland sedimentation and vegetation patterns at 11 highway crossings in West Tennessee were studied from 1987 to 1989. The purpose of the study was to investigate potential adverse effects of highway crossings on wetlands. Sedimentation rates, determined from root-burial depths, were highly variable. Average rates offine-grained deposition ranged from 0.005 to 0.033 foot per year for stations in locally ponded areas and from -0.002 to 0.039 foot per year for stations in drained areas. Sedimentation rates upstream from highway crossings were not significantly different from downstream rates at 8 of the 11 study sites. Three study sites had significantly greater sedimentation rates downstream. Sand splays were observed downstream from bridges at most study sites. Vegetation patterns and tree growth appear most strongly related to hydropetiod, defined as the average length of time an area is covered by water each year. The influence of sedimentation on tree growth is difficult to separate from the influence of hydroperiod because areas with high sedimentation rates typically have long hydroperiods. Estimated hydroperiod increased no more than 1 percent because of backwater from the highway crossings at the 11 study sites, while the estimated average depth of flood-plain inundation increased by an average of 6 percent.

Tennessee

Water-quality characteristics of the Red River of the North and tributaries in the Fargo-Moorhead metropolitan area, North Dakota, 2019–22

The Flood Risk Management Project was initiated in 2008 in the Fargo-Moorhead metropolitan area to reduce flood risk, flood damages, and flood protection costs in the Fargo-Moorhead metropolitan area. In cooperation with the U.S. Army Corps of Engineers, the U.S. Geological Survey initiated a water-quality monitoring study to describe the water-quality characteristics of the Red River of the North and its tributaries in the Fargo-Moorhead metropolitan area during the preconstruction period of the Flood Risk Management Project from October 1, 2019, to October 1, 2022. The monitoring study included the collection of discrete and continuous water-quality data and streamflow monitoring at selected sites that integrated and enhanced existing monitoring programs within the study area. Discrete samples collected at 10 sites in the Fargo-Moorhead metropolitan area were analyzed for major ions, trace elements, nutrients, suspended sediment, pesticides, and fecal indicator bacteria. In general, major ion concentrations were higher at sites on the tributaries (Wild Rice, Sheyenne, and Maple Rivers) compared to sites on the Red River of the North. In general, bicarbonate, calcium, magnesium, and sulfate represented most of the dissolved ions measured in samples collected at the 10 sites. Calcium, chloride, fluoride, potassium, silica, and sodium were also measured in samples, but they represented a smaller portion of the total dissolved ions. Sulfate was the most dominant dissolved ion that had the highest concentrations among the major ions measured in samples. A total of 18 trace elements were analyzed in discrete samples. Several of the trace elements had concentrations below the laboratory reporting level in all of the samples, including antimony, beryllium, cadmium, chromium, silver, and thallium. Sites on the Wild Rice River generally had the highest concentrations of arsenic, barium, boron, manganese, and nickel compared to the other sites. Nutrients analyzed in discrete samples included filtered and unfiltered concentrations of ammonia, nitrate plus nitrite, phosphorus, and organic carbon. The median filtered ammonia concentration at most sites was less than the laboratory reporting level of 0.03 milligram per liter as nitrogen except for the Sheyenne River at Harwood, North Dakota (U.S. Geological Survey [USGS] station 05060400), and Red River of the North near Georgetown, Minnesota (USGS station 05062130). The lowest median unfiltered nitrate plus nitrite concentration was measured at sites on the Red River of the North upstream from the Fargo-Moorhead metropolitan area and the highest median was at sites on the Red River of the North downstream from the Fargo-Moorhead metropolitan area compared to all other sites. The increase in nitrate plus nitrite concentrations could reflect the effect of the wastewater-treatment plant discharge that enters the Red River of the North upstream from the site located downstream from the Fargo-Moorhead metropolitan area and from urban runoff. Phosphorus (unfiltered) concentrations were generally higher at sites on the Maple and Sheyenne Rivers compared to the other sites and were higher at sites on the Red River of the North downstream from the Fargo-Moorhead metropolitan area compared to sites upstream on the Red River of the North. Suspended-sediment concentrations were generally highest at sites in the Sheyenne River and lowest in the upstream Red River of the North sites. Suspended-sediment concentration was highly variable in samples collected at the 10 sites, mostly influenced by the occurrence of snowmelt and rainfall-runoff events. The Sheyenne River near Kindred, N. Dak. (USGS station 05059000) had the largest range in sediment concentrations in samples collected at the 10 sites. For all sites other than the Sheyenne River near Kindred, N. Dak., 95 percent or more of the suspended sediment had particle diameter sizes less than 0.0625 millimeter in 50 percent of the samples (median). Of the 102 pesticides and pesticide degradates analyzed, 45 constituents had no detectable concentrations in any of the 17 samples collected at five sites. The remaining 57 pesticides had at least one detection in the samples collected at the five sites. The sites on the Wild Rice River (near Abercrombie, N. Dak., USGS station 05053000, and near St. Benedict, N. Dak., USGS station 05053500) and Sheyenne River near Kindred, N. Dak., had fewer pesticide detections compared to the Maple River below Mapleton, N.Dak. (USGS station 05060100) and the Red River of the North at Fargo, N. Dak (USGS station 05054000) and near Georgetown, Minn. Patterns in annual loads generally followed the same pattern as streamflow at the 10 sites for water years 2020–22. A water year is the 12-month period from October 1 to September 30 and is designated by the calendar year in which it ends. The greatest loads for all constituents were delivered at the two downstream sites on the Red River of the North; sites that also had the highest annual streamflows among the sites and the greatest loads were delivered in water year 2020 when the highest streamflows occurred at the sites. Likewise, the least loads for most constituents were at the Maple River and were least in 2021 compared to the other years because of low-streamflow conditions. Water-quality measurements continuously recorded at the Red River of the North at Hickson, N. Dak. (USGS station 05051522); Red River of the North at Fargo, N. Dak.; and Red River of the North near Georgetown, Minn. included water temperature, specific conductance, dissolved oxygen, pH, and turbidity. Specific conductance values were similar for the Red River of the North near Hickson, N. Dak., and Red River of the North at Fargo, N. Dak., when compared to the Red River of the North near Georgetown, Minn. that had higher values than the other two sites. Dissolved oxygen concentrations and pH were similar among the three sites on the Red River. The patterns in turbidity were mostly related to streamflow conditions and were similar among the three sites on the Red River of the North.

Minnesota, North Dakota

Potentiometric surface maps and groundwater-level hydrographs for confined aquifers of the New Jersey Coastal Plain, 2018

The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection (NJDEP), prepared potentiometric surface maps for 10 confined aquifers of the New Jersey Coastal Plain physiographic province based on water-level measurements collected during late 2018 and early 2019 from 951 wells in New Jersey and parts of Pennsylvania and Delaware. Maps were prepared for the confined Cohansey aquifer, Rio Grande water-bearing zone, Atlantic City 800-foot sand, Piney Point aquifer, Vincentown aquifer, Wenonah-Mount Laurel aquifer, Englishtown aquifer system, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system. Potentiometric surface maps indicate regional cones of depression in the following aquifers and the counties in which they are centered: Atlantic City 800-foot sand in Atlantic County, the Piney Point aquifer in Cumberland County, the Wenonah-Mount Laurel aquifer and Englishtown aquifer system in Monmouth and Ocean Counties, the Wenonah-Mount Laurel aquifer in Camden and Gloucester County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Ocean County, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system in Camden County. Cones of depression with smaller areal extents were in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand centered in Cape May County, the Piney Point aquifer centered in Ocean County, the Wenonah-Mount Laurel aquifer in Salem and Burlington Counties, the Englishtown aquifer system in Camden County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth County, and the middle aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth, Ocean, and Salem Counties. No cone of depression was interpreted in the Vincentown aquifer. Long-term hydrographs are presented for 75 wells spanning each of the 10 confined aquifers, and contain a mix of discrete water-level measurements and daily mean water levels based on continuously recorded 15-minute data. Changes of water levels during 2014–19, as indicated by the hydrographs, were compared with those of previous periods to assess any departures from historical data. During 2014–19, water levels were stable and fluctuated within similar ranges as previous periods in the following aquifers and locations: all wells in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Vincentown aquifer, the Englishtown aquifer system, the Piney Point aquifer wells in Burlington and Ocean Counties, six of eight wells in the Wenonah-Mount Laurel aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system except those within NJDEP Critical Area II. Increasing water levels in 2014–19, ongoing since historical periods, were indicated in the following aquifers and locations: Atlantic County wells in the Piney Point aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system within NJDEP Critical Area II. Water levels in the Atlantic City 800-foot sand also increased during 2014–19 in wells in Atlantic County and northern Cape May County closer to the center of the cone of depression in that aquifer, which is a response unique to this period and absent from previous periods. During 2013–19, continued decreasing water levels, ongoing since previous periods, were indicated by hydrographs of Atlantic City 800-foot sand wells in southern Cape May County, Piney Point aquifer wells in Cumberland County where the regional cone of depression is located, and two wells in the Wenonah-Mount Laurel aquifer—070478, which in 2014–19 departed from previous periods, and 330020, which continued a gradual decrease throughout its period of record.

New Jersey

Estimating the importance of floating surface material to the total phosphorus transport in Silver Creek, Wisconsin using Particle Image Velocimetry

Various techniques are used to estimate nutrient delivery in streams that combine flow and water-quality data. However, the transport of surface floating material is difficult to measure, and is therefore typically neglected when stream sampling and in the estimated nutrient delivery. Here, we describe an approach to estimate the amount of material (duckweed ( Lemna genus), filamentous algae, and other macrophyte fragments) and associated nutrients (in this case, phosphorus, P) transported on the surface of Silver Creek, Wisconsin, to determine if this material is an important transport mechanism and if historical P loads were underestimated. This approach includes estimating the transport of surface material using 10 s videos collected every 15 min from a downward-looking camera installed beneath a bridge. The average velocity of the surface material was first determined using Large-Scale Particle Image Velocimetry (LSPIV), which uses short videos to analyze surface particle movement. The amount of surface material in each video was then computed using computer-vision techniques. The P load associated with the transported surface material was then estimated by combining surface velocities, coverage of floating material, and laboratory-measured P content. Surface material transported ~9–11% of the total summer P load and ~4–7% of the annual load in Silver Creek.

Wisconsin

A process-based model for forecasting wave runup along the coast of Georgia

Wave runup is an important nearshore process that impacts total water level, sediment transport, and coastal design. Current methods for forecasting wave runup implement an empirical model that considers offshore wave height, wave period, and generalized beach slope. In this study, the authors generated wave runup forecasts from offshore wave conditions and a system of polynomial equations derived from numerical simulations at three different still water datums for each beach profile. They developed a process-based methodology that incorporated site-specific cross-shore topobathy into the phase-resolving numerical model. A comparison between the system of equations, deterministic hydrodynamic simulations, and observed high-water marks was made using Hurricanes Matthew (2016) and Irma (2017) for 12 cases, and it showed that the polynomials were capable of being consistent with the results from full simulation runs, while not requiring hours of runtime when a forecast was needed—the differences between the polynomial and the observed high water marks ranged from 3 to 32 cm for the Irma hindcast and 9–70 cm for Matthew. Then, using forcings from Hurricanes Ian and Nicole (2022), the model predicted the occurrence of dune collision, overwash, and inundation for the coast of Georgia and suggested that wave runup was impacted by the still water level and local topobathy.

Georgia

Fiber-optic distributed temperature sensing of hydrologic processes—Diverse deployments and new applications by the U.S. Geological Survey

Fiber-optic distributed temperature sensing instruments harness the temperature-dependent properties of glass to measure temperature continuously along optical fibers by using precise pulses of laser light. In the mid-2000s, this technology was refined for environmental monitoring purposes such as snowpack-air exchange, groundwater/surface-water exchange, and lake-water stratification. Fiber-optic distributed temperature sensing has revealed unprecedented details about preferential flow processes; however, the method is labor intensive and requires specific training, resulting in limited use by the broader water community. With the ongoing national implementation of the U.S. Geological Survey Next Generation Water Observing System, there has been renewed interest in harnessing the unique spatiotemporal monitoring capabilities of fiber-optic distributed temperature sensing. This fact sheet briefly describes this technology, highlights uses by the U.S. Geological Survey, and discusses current applications and future opportunities.

Fact Sheet