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Groundwater from Lower Cretaceous rocks in Kansas

Sandstones in Lower Cretaceous rocks contain supplies, of water that may be adequate to meet increasing present and future demands for supplemental municipal and domestic use in central and western Kansas. An estimated 70 to 80 million acre-feet (86,000 to 99,000 cubic hectometers) of water containing less than 1,000 milligrams per liter dissolved solids may be acceptable for use at the present (1976). An additional 10 to 15 million acre-feet (12,000 to 18,000 cubic hectometers) containing 1,000 to 3,000 milligrams per liter dissolved solids is estimated to be available for use in the future with appropriate desalinization. Lower Cretaceous rocks crop out from Washington County on the north to Comanche County on-the south. The rocks dip from a structural high in the southwest part of the State to structural lows in the northwest and north-central part. Depth below land surface increases generally northwestward to about 2,600 feet (790 meters); thickness of the rocks increases westward, nearly zero to about 850 feet (260 meters). The rocks consist chiefly of marine to nonmarine shale and silt- stone interbedded with coastal to deltaic sandstone. The interbedded sandstone, which composes about one-third of the rocks, consists of one or more lenses that thicken westward to about 400 feet (120 meters) in the central part of western Kansas. The yield of water to individual wells is related to areal extent, thickness, and interconnection of the sand lenses and to grain size and cementation of the sand. Large amounts of water may be pumped by wells where loosely cemented sand lenses are interconnected. Wells commonly yield adequate supplies for domestic and stock use; reported yields from municipal and irrigation wells range from about 100 to 2,000 gallons per minute (6 to 125 liters per second). Recharge to the Lower Cretaceous-rocks occurs in the area of outcrop and from hydraulically connected saturated Cenozoic rocks, especially in the southern part of the State. Movement of water is principally northeastward from areas of recharge to areas of discharge where streams intersect the sandstone outcrops. Water in the sandstone aquifers commonly is confined between beds of relatively impermeable shale, causing water in wells to rise above the top of the aquifer. Water levels fluctuate in response to changes in atmospheric pressure, recharge, and discharge; greatest fluctuations result from discharge to wells for municipal and irrigation use. Progressive declines in water levels have occurred where irrigation withdrawals exceed recharge. Calcium bicarbonate water is dominant near recharge areas; mixed sodium and calcium bicarbonate water and sodium chloride water become successively dominant as the water moves downgradient from the recharge areas. The quality of water ranges from fresh to very saline (less than 1.000 to 35,000 milligrams per liter dissolved solids). In the areas of generally fresh water, localized areas of calcium sulfate water result from solution of gypsum in the Kiowa Formation, and areas of sodium chloride water result from contamination by oil-field brines.

Open-File Report↗

Deep-sea fan deposition of the lower Tertiary Orca Group, eastern Prince William Sound, Alaska

The Orca Group is a thick, complexly deformed, sparsely fossiliferous sequence of flysch-like sedimentary and tholeiitic volcanic rocks of middle or late Paleocene age that crops out over an area of. roughly 21,000 km2 in the Prince William Sound region and the adjacent Chugach Mountains. The Orca Group also probably underlies a large part of the Gulf of Alaska Tertiary province and the continental shelf south of the outcrop belt; coextensive rocks to the southwest on Kodiak Island are called the Ghost Rocks and Sitkalidak Formations. The Orca Group was pervasively faulted, tightly folded, and metamorphosed regionally to laumontite and prehnite-pumpellyite facies prior to, and perhaps concurrently with, intrusion of early Eocene granodiorite and quartz monzonite plutons. In eastern Prince William Sound, 95% of the Orca sedimentary rocks are interbedded feldspathic and lithofeldspathic sandstone, siltstone, and mudstone turbidites. Lithic components vary widely in abundance and composition, but labile sedimentary and volcanic grains dominate. A widespread yet minor amount of the mudstone is hemipelagic or pelagic, with scattered foraminifers. Pebbly mudstone with rounded clasts of exotic lithologies and locally conglomerate with angular blocks of deformed sandstone identical to the enclosing matrix are interbedded with the turbidites. Thick and thin tabular bodies of altered tholeiitic basalt are locally and regionally conformable with the sedimentary rocks, and constitute 15-20% of Orca outcrops in eastern Prince William Sound. The basalt consists chiefly of pillowed and nonpillowed flows, but also includes minor pillow breccia, tuff, and intrusive rocks. Nonvolcanic turbidites are interbedded with the basalt; lenticular bioclastic limestone, red and green mudstone, chert, and conglomerate locally overlie the basalt, but are supplanted upward by turbidites. From west to east, basalts within the Orca Group become increasingly fragmental and amygdaloidal. Such textural changes probably indicate shallower water to the east. A radial distribution of paleocurrents and distinctive associations of turbidite facies within the sedimentary rocks suggest that the Orca Group in eastern Prince William Sound was deposited on a westward-sloping, complex deep-sea fan. Detritus was derived primarily from 'tectonized' sedimentary, volcanic, and plutonic rocks. Coeval submarine volcanism resulted in intercalation of basalt within prisms of terrigenous sediment.

Open-File Report↗

Glaciomarine deposits of Miocene through Holocene age in the Yakataga Formation along the Gulf of Alaska margin, Alaska

Perhaps the world's longest and most complete onshore sedimentary record of late Cenozoic glaciation is preserved in the Gulf of Alaska Tertiary province that extends 800 km along the coast of southern Alaska. The Yakataga Formation, with an aggregate outcrop thickness of about 5,000 m, is characterized by variable amounts of distinctive neritic marine tillite-like diamictite and laminated siltstone containing dropstones interpreted as ice-rafted glacial debris. The lithology, sedimentary structures and molluscan fauna of the formation suggest that active tidal glaciers or an ice shelf were present along the landward margin of the basin possibly beginning in early or early middle Miocene time. Dropstone distribution in outcrop sections indicates that glaciers reached tidewater intermittently during the Miocene and were almost continuously present throughout the Pliocene and much of the Pleistocene. Paleomagnetic and nannoplankton dating of the upper 1,181 m of the Yakataga Formation at Middleton Island indicate that this part of the sequence probably was entirely deposited during the Matuyama reversed polarity epoch of the Pleistocene during which the sedimentation rate was of the order of 1 m/1,000 years.

Alaska↗

Petrology of Potomac Group sands in Fairfax County, Virginia

The Potomac Group sands sampled in Fairfax County are dominantly microcline-rich lithic arkoses. Quartz averages 59%, microcline 25%, plagioclase less than 1% and lithic grains 16%. Most sands are texturally submature and medium grained. Microcline is somewhat more abundant in the deeper beds in the subsurface than in the shallow subsurface and outcrop sections, with quartz correspondingly more abundant at the surface. Zircon is the only abundant non-opaque heavy mineral in the outcrop section as well as in the shallow subsurface, but tourmaline, rutile and staurolite are also common. In contrast, the lower beds in the subsurface have a heavy mineral assemblage with zircon, garnet and apatite as the dominant species. Several alternative explanations for the vertical variation in mineral assemblages from less to more stable types in the Potomac Group sands are possible: 1) removal of primary Piedmont apatite-bearing igneous and garnet-bearing metamorphic source rock by erosion or burial by overlapping Potomac Group sediments, 2) deep weathering of primary Piedmont source areas and destruction of less stable minerals (apatite and garnet) in Cretaceous time, 3) destruction of less stable minerals (apatite and garnet) near the surface and in the shallow subsurface by post-Cretaceous deep weathering and/or intrastratal solution.

Open-File Report↗

Potentiometric map of the Gordo Aquifer in northeastern Mississippi, September, October, and November 1978

This potentiometric map of the Gordo aquifer in northeastern Mississippi is the second in a series of maps, prepared by the U.S. Geological Survey in cooperation with the Mississippi Department of Natural Resources, Bureau of Land and Water Resources, delineating the potentiometric surfaces of the major aquifers in Mississippi. The potentiometric surface of the Gordo aquifer slopes generally to the west away from the outcrop area and it is depressed generally by large ground-water withdrawals in the Tupelo and Columbus areas. Historically, water levels in or near the outcrop of the Gordo aquifer have shown little or no long-term changes. Heavy withdrawals from the downdip area have caused long-term water-level declines of 1 to 2 feet per year in much of the confined part of the aquifer. Water-level decline in one observation well in Tupelo has averaged about 5 feet per year since 1966. (USGS)

Open-File Report↗

Primary and secondary faulting in the Najd fault system, Kingdom of Saudi Arabia

The Najd fault system is a major transcurrent (strike-slip) fault system of Proterozoic age in the Arabian Shield. The system is a braided complex of parallel and curved en echelon faults. Complex arrays of secondary structures including strike-slip, oblique-slip, thrust, and normal faults, together with folds and dike swarms, are associated with some major faults, particularly near their terminations. The secondary structures indicate that compressional and extensional and dilational conditions existed synchronously in different parts of the fault zone. The outcrop traces of faults and syntectonic dikes have been used to interpret the configuration of principal compressive stresses during formation of parts of the secondary fracture systems. Second-order deformation was a series of separate events in a complex episodic faulting history. Comparison with model studies indicates that master faults extended in length in stages and periodically developed arrays of secondary structures. Propagation of the major faults took place along splay trajectories, which inter-connected to form a subparallel sheeted and braided zone. Interpretation of the aeromagnetic maps indicates that the Najd system is broader at depth than the outcropping fault complex, and that more continuous structures underlie arrays of faults at surface. The fault pattern is mechanically explicable in terms of simple shear between rigid blocks beneath the exposed structures.

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Water resources of the southern Powder River area of southeastern Montana

The southern Powder River area comprises about 2,230 square miles in southeastern Montana. Sedimentary rocks beneath this area range in age from Cambrian to Holocene and attain a maximum thickness of about 12,000 feet. Rocks exposed in the study area range in age from Late Cretaceous to Holocene. Water for domestic, stock, and public use in the southern Powder River area is available from the Fox Hills-lower Hell Creek aquifer and the upper part of the Hell Creek Formation, both of Late Cretaceous age, and the Fort Union Formation of Paleocene age. Water for industrial use might be available from the Madison Group of Mississippian age. Where adequate quantities are available, water from the Madison Group is suitable for irrigation. Water from alluvium of Holocene and Pleistocene age along the Powder River is marginally suitable for irrigation, and surface water from the Powder River is suitable for irrigation, except during periods of low flow. The Madison Group is a sequence of carbonate rocks that underlies the entire study area and ranges in thickness from 800 to 1,500 feet. Depth to the top of the group is about 4,000 feet in the southeastern part of the area and as much as 9,000 feet in the southwestern part. Water-supply wells at the Bell Creek oil field in the southeastern part of the study area flow as much as 1,300 gal/min (gallons per minute). Oil-field water from this area contains calcium, magnesium, and sulfate as major ions, and contains less than 1,000 mg/L (milligrams per liter) dissolved solids. The Fox Hills-lower Hell Creek aquifer is predominantly sandstone interbedded in part with sandy shale and siltstone. The aquifer crops out in the eastern part of the study area and dips generally westward beneath the land surface at about 40 to 200 feet per mile. Wells in the Fox Hills-lower Hell Creek aquifer range in depth from 25 feet in the outcrop area to 1,358 feet between the Powder and Little Powder Rivers. Measured well yields range from 3 to 200 gal/min. Many flowing wells along the principal rivers yield as much as 20 gal/min. The water contains calcium, magnesium, and bicarbonate or sulfate as major ions in the outcrop area. Downgradient, sodium and bicarbonate are predominant. The dissolved-solids concentration ranges from 261 to 2,230 mg/L. The upper part of the Hell Creek Formation consists of interbedded shale, siltstone, claystone, and sandstone. Wells in the upper part of the Hell Creek are as deep as 1,045 feet. Flowing wells along the Powder and Little Powder Rivers yield as much as 40 gal/min, but pumped wells generally yield less. The water quality is similar to that of the Fox Hills-lower Hell Creek aquifer. The dissolved-solids concentration ranges from 236 to 1,580 mg/L. The Fort Union Formation consists of interbedded sandstone, siltstone, shale, and coal. The formation crops out in the western three-fourths of the study area and is about 2,100 feet thick in the southwestern part. Wells tapping this unit range in depth from 120 to 1,100 feet. Wells and springs are reported to yield as much as 20 gal/min; many wells flow. The upper part of the formation is a major aquifer west of the Powder River valley. The water contains calcium, magnesium, sodium, bicarbonate, and sulfate as the major ions in most any relative proportion. The dissolved-solids concentration ranges from 541 to 2,160 mg/L. Alluvium is unconsolidated deposits of interbedded clay, silt, sand, and gravel, mostly along the river valleys. Maximum measured thicknesses of these deposits were 62 and 55 feet along the Powder and Little Powder Rivers, respectively. Several irrigation wells drilled in the alluvium along the Powder River have reported yields of as much as 900 gal/min. Water contains calcium, magnesium, and sulfate as major ions. The dissolved-solids concentration of two water samples from the Powder River valley was 1,780 and 2,240 mg/L. The only perennial streams are the Powder and Little Powder Rivers. Based on available streamflow records, the mean-annual discharge of the Powder River at Moorhead, in the southwestern part of the area, is 448 cubic feet per second; discharge varies from 0 to 23,000 cubic feet per second. Mean-annual discharge of the Little Powder River near Broadus, in the north-central part of the area, is 31 cubic feet per second; discharge varies from 0 to 2,440 cubic feet per second. Water from the Powder River normally contains calcium and sulfate as the major ions. Dissolved-solids concentration ranges from 20 to 3,460 mg/L.

Montana↗

Preliminary report on the geology of the continental slope adjacent to OCS Lease Sale 55, eastern Gulf of Alaska: Petroleum resource implications

Forty samples of Tertiary and Cretaceous outcrop or suspected outcrop were dredged along the 250-km-long northwest-trending continental slope between long 138°00' W. and 142°30' W. These samples, from water depths of 3,150 m to 200 m, combined with seismic reflection data, identify seven rock units in apparently normal stratigraphic position. From oldest to youngest they are: Unit A: Hard graywacke, argillite, and possible intrusive rocks of inferred Late Cretaceous age that crop out in the eastern part of the slope and probably underlie much of the Fairweather Ground. Unit B: At least 900 m of sandstone, conglomerate, shale, and subordinate basaltic volcanic rocks west of Yakutat Seavalley between 142° W. and 143° W. that is not dated but is probably of late Paleocene to early Eocene age. Unit C: 1,300 m of basaltic flow and pyroclastic rocks with associated clastic marine sedimentary rocks that makes up much of the rugged lower slope throughout the area. This sequence is largely, or entirely, of early Eocene age. Unit D: Up to 2,100 m of early and middle Eocene sandstone, conglomerate, siltstone, and tuffaceous organic-rich shale that partly overlies, and partly intertongues with, the volcanic unit. Unit E: 800 m of early to late Eocene and early Oligocene(?) organic-rich shale, tuffaceous shale, siltstone, and sandstone that partly intertongues with, and partly overlies units C and D. Unit F: 300+ m of siltstone, at least in part of late Oligocene age, that crops out locally along the upper slope where it unconformably overlies Unit E. Unit G: Up to 2,000 m of late Cenozoic (middle Miocene? and younger) clastic sedimentary rocks including abundant glaciomarine deposits that unconformably overlie all the older units. The early Tertiary sequence sampled on the continental slope differs strikingly in lithology and structure from coeval rocks exposed onshore or penetrated in unsuccessful exploratory wells on the adjacent mainland. Units B, D, and E include abundant source rocks that have undergone a thermal history resulting in local generation of hydrocarbons. Sandstones from Units D and E locally have secondary porosities up to 31 percent and permeabilities to 36 md. Seismic reflection data indicate that the sequence with the most favorable source and reservoir potential (Units B, D, E) dips northeastward beneath OCS Lease Sale 55 where it could be a favorable exploratory target if involved in suitable traps. Young anticlinal folds are not present, but other important traps are likely to include drape structures, horsts, and faults within the early Tertiary sequence and pinchouts, fault traps, or combination structural/stratigraphic traps along the northeastern margin of the early Tertiary basin.

Alaska↗

Potentiometric map of the Lower Wilcox Aquifer in Mississippi, fall 1979

The potentiometric map of the lower Wilcox aquifer is one of a series of maps, prepared by the U.S. Geological Survey in cooperation with the Mississippi Department of Natural Resources , delineating the potentiometric surfaces of the major aquifers in Mississippi. In the outcrop area of the lower Wilcox aquifer the potentiometric surface is strongly affected by recharge from precipitation, by topography, and by drainage of the aquifer by streams. The potentiometric surface slopes downward generally to the west away from the area of outcrop but is strongly affected by pumpage from public and industrial wells in several areas in northwestern Mississippi. This pumpage has caused a large shallow depression in the potentiometric surface in the Marks-Batesville-Charleston-Tunica area. (USGS)

Open-File Report↗

Uranium potential of the Burro Canyon Formation in western Colorado

The Burro Canyon Formation of Early Cretaceous age overlies the Morrison Formation (Late Jurassic) and underlies the Dakota Sandstone (Late Cretaceous) over most of southeastern Utah and southwestern Colorado. It consists mainly of alternating beds of fluvial sandstone and overbank mudstone with sandstone dominating in the lower part of the formation and mudstone in the upper part. At the outcrop, the sandstones in the formation exhibit almost all the characteristics that are considered favorable for the occurrence of sandstone-type uranium deposits, but only a few small deposits have been discovered in the Colorado-Utah area. The major deficiency of the Burro Canyon in these outcrop areas is the absence of a reductant such as carbonaceous debris, humic or humate materials, or pyrite. Reductants were probably removed during a period of extensive oxidation at the time of deposition and during a subsequent erosional episode prior to deposition of the Dakota Sandstone. The formation reaches a lobate, inexactly located eastern margin that extends from near Meeker, Colorado, southward through the Piceance basin to near Aztec, New Mexico, in the northwestern part of the San Juan Basin. Along much of this distance, the formation is in the subsurface and has been penetrated by only a few drill holes. Along this eastern margin, the lobes project eastward where fluvial distributary streams built minor alluvial fans of relatively high-energy deposits out from the main axis of Burro Canyon stream deposition. The lower and distal reaches of these lobes may have survived the period of post depositional erosion and oxidation in a reduced condition because of low relief and the protection of a high water table. If so, the peripheral and distal parts of these lobes may have retained the precipitants necessary to form a uranium deposit. Two of the lobes extend into the southwest margin of the Piceance Basin and are considered the possible location of uranium deposits. Two additional lobes extend into the northwestern part of the San Juan Basin but have not been evaluated in this study.

Open-File Report↗

Characteristics and description of cores from the USGS core hole CRU-1, Parachute Creek Member, Green River Formation, east-central Uinta Basin, Utah

Oil-yield, lithologic, and mineral distribution data were determined for cores taken from a 497.7-foot drill hole in the upper part of the Parachute Creek Member of the Eocene Green River Formation. The drill hole, 1050 feet FEL, 700 feet FNL, sec. 3, T. 12 S., R. 24 E., Uintah County, Utah, started slightly below the contact between the Uinta Formation, also of Eocene age, and the underlying Green River Formation. It ended 32 feet below the base of the Mahogany bed (the richest oil-shale bed between A groove and B groove--which define the upper and lower boundaries, respectively, of the Mahogany zone). Most of the interval studied is kerogen- or carbonate-rich, commonly tuffaceous, and is very fine grained. Several thin (<3 feet) oil-shale beds which yield as much as 25 gallons of oil per ton occur above the Mahogany zone, but are probably not of economic interest. The cored sequence contains several tuff beds. The thickest of these beds is approximately 2 feet thick; the average thickness is rarely greater than 0.5 feet. Two oil-saturated tuff beds occur approximately 65 feet above the Mahogany oil-shale bed. Although these two tuffs are exposed on nearby surface outcrops, no evidence of oil is seen on outcrop. The Mahogany zone is approximately 69 feet thick at the drill site; the lowermost few feet were not penetrated. At the site cored, the Mahogany zone is overlain by 435 feet of overburden. Fischer assays indicate that 42.3 feet of oil shale within the Mahogany zone could yield at least 25 gallons of oil per ton from beds at least 10 feet thick.

Open-File Report↗

Geophysical investigations of the Umm ar Rummf copper prospect, Al Qunfudhah Quadrangle, Kingdom of Saudi Arabia

The Umm ar Rummf copper prospect, located about 30 km east of Al Qunfudhah, Kingdom of Saudi Arabia, consists of zones of malachite disseminations and fracture fillings in outcrops of north-trending impure quartzite of the Bahah group. Systematic Crone electromagnetic and self-potential surveys indicate that weakly conductive tabular bodies having a weak to moderate self-potential effect extend downdip from two discontinuously exposed, parallel ridges of mineralized quartzite. Crone electromagnetic data were quantitatively interpreted using characteristic parameter lines adapted for use at 1830 and 5010 Hz, the frequencies employed at Umm ar Rummf. Depths to the top of the conductors were computed to be from 20 to 40 m or about the thickness of the oxidized zone, which behaves as a variably conductive overburden. Both tabular conductors can also be traced geophysically to the north and south of the copper-bearing outcrops. The association of the geophysical anomalies with copper-mineralized rocks has been proved by drilling. Reconnaissance MAXMIN electromagnetic profiles across the target using a wide coil separation show broad, low-amplitude anomalies that may indicate mineralized rocks at depth, and reconnaissance ground-magnetic profiles show strong total-field intensity anomalies associated with basaltic dikes of probable Tertiary age. In the central part of the area of investigation, these dikes produce large disturbances of the electrical fields.

Open-File Report↗

Hydrology of the Jasper (Miocene) Aquifer in the Southeast Texas coastal plain

The Jasper (Miocene) aquifer is one of several important hydrologic units in the Gulf Coastal Plain. Because the Jasper aquifer underlies shallower aquifers in many areas, regional water withdrawals from the Jasper are not significant; however, it is capable of yielding 3,000 gallons per minute (200 liters per second) or more of water to wells in certain areas. The Jasper is underlain by the Catahoula confining system (restricted) and overlain by the Burkeville confining system. The Evangeline and Chicot aquifers, in turn, overlie the Burkeville and also are prolific water-yielding aquifers. The ground-water hydrology of the Jasper aquifer in an area of about 20,000 square miles (52,000 square kilometers) was simulated by a two-dimensional digital model using a steady-state approach. The model represents hydrologic conditions prior to development by wells, when natural recharge equaled natural discharge. The model's grid pattern of 15 x 24 nodes varies from a dimension of 5 by 10 miles (8 by 16 kilometers) in the outcrop to 10 by 10 miles (16 by 16 kilometers) in the artesian section downdip from the outcrop.

Texas↗

The mineral resource potential of the Wadi Habawnah and Najran quadrangles, sheets 17/44A and 17/44C, Kingdom of Saudi Arabia

The metallic resource potential of the Wadi Habawnah and Najran quadrangles in the southern Precambrian Arabian Shield has been determined primarily by reconnaissance rock geochemistry, limited wadi-sediment and colluvium geochemistry, and gossanous and ferruginous outcrop geochemistry. These surveys were guided by geological information acquired during previous reconnaissance mapping. Locally anomalous areas in alkalic and calc-alkalic granitic terrane are possible sources of niobium-zirconiumthorium-fluorite, tin-tungsten, and copper-molybdenum, although the potential of these areas does not appear to be outstanding. The reconnaissance geochemistry of the layered volcanic terrane and the geochemistry of gossanous and ferruginous outcrops indicate that the potential for stratiform base metal sulfide deposits is low.

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Ground water-surface water relations in the Flathead River valley near the proposed Cabin Creek coal mine, British Columbia, Canada

The area of the proposed Cabin Creek coal mine was studied to obtain information needed to respond to questions posed by the International Joint Commission advisers concerning water resources near the international border. Specific interest focused on determining the extent and character of surficial material in the Flathead River valley, identifying gaining and losing reaches of the river and major tributaries, and documenting ambient water quality at selected sites. Thickness of the alluvial deposits depends on depth to underlaying Quaternary glacial deposits or Tertiary bedrock. The alluvial deposits in the Flathead River valley thin to a veneer of cobbles near the mouth of Couldrey Creek. Measurements of streamflow at 20 sites in the Flathead River valley indicate that water discharges from the alluvial deposits to most of the tributaries and to the river near the proposed mine. The Flathead River gains 0.87 cu m/sec (31 cu ft/sec) of flow near Howell Creek. The Flathead River and Couldrey Creek gained about 0.81 cu m/sec (28.5 cu ft/sec) of flow near the mouth of Couldrey Creek where bedrock crops out in the streambeds. Bedrock outcrops effectively interrupt the alluvial aquifer system between the proposed mine site and the international border. The Flathead River lost 0.87 cu m/sec (31 cu ft/sec) of flow between the bedrock outcrops and the international border; this streamflow loss enters alluvial deposits and flows across the international border as subsurface flow. Analysis of samples from 18 stream sites and 1 spring site indicates general trends in water quality. In Howell Creek, concentrations of calcium, magnesium, and sulfates increased slightly downstream. Conversely, samples from Sage and Couldrey Creeks indicate downstream increases in concentrations of calcium, magnesium, and alkalinity, but decreases in concentrations of sulfate. Water quality of Cabin Creek was relatively stable through the sampled reach. Decreased concentrations of calcium and alkalinity in the Flathead River reflect the effect of inflow from Couldrey Creek and the groundwater inflow documented by streamflow measurements. (Author 's abstract)

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Ground-water resources of the upper White River basin in Arkansas

The upper White River basin in Arkansas lies almost entirely within the Ozark Plateaus physiographic province, which consists of deeply dissected plateaus underlain by limestone, shale, and dolomite. Significant water-yielding units within the upper White River basin include the Eminence and Potosi Dolomites, the Roubidou Formation, the Gasconade Dolomite and the Van Buren Formation, outcrops of undifferentiated Paleozoic rocks, the Nacatoch Sand, and quaternary deposits. Water in the Quaternary deposits is the most heavily used, but areally, other units are significant sources of groundwater for domestic and rural use. The quality of groundwater withdrawn from the various units generally is suitable for most uses, although groundwater in the study area is typically very hard. Iron concentrations commonly exceed allowable limits. Yields from the different water-yielding units are highly variable. The Eminence and Potosi Dolomites are known to yield as much as 230 gal/min. Nearer the surface, the Gunter Sandstone Member of the Van Buren Formation yields as much as 500 gal/min. Above the Gunter Sandstone, the Roubidoux Formation yields as much as 450 gal/min to wells. In contrast to the high yields from these deeper units , the outcrops of Paleozoic rocks commonly yield less than 10 gal/min. The Quaternary deposits yield as much as 2,500 gal/min of very hard water. Elevated nitrate concentrations that exceed U.S. Environmental Protection Agency primary drinking-water standards occur in Marion County. In addition, saline water is present in the Quaternary deposits near Bald Knob and Cord, Arkansas. (USGS)

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Age and correlation of the Calera Limestone in the Permanente terrane of northern California

Planktonic foraminifers indicate that outcrops of Calera Limestone from the Permanente terrane in the Franciscan Complex of northern California range in age from possibly as old as Barremian to late Turonian. Underlying black limestone, which is devoid of planktonic foraminifers, presumably is Barremian in age or older. The top of the sequence exposed in major quarries is always faulted. Improved biostratigraphic resolution shows two patterns of missing time intervals. The primary pattern, which is found at all localities and involves missing planktonic foraminiferal zones in the late Aptian to early Albian and the late Albian, is linked to paleoceanographic changes in the Cretaceous Pacific Ocean. The secondary pattern, which is found at the scattered outcrops outside the major quarries and involves missing zones in the Albian and Cenomanian, suggests the results of a common tectonic history related to the accretion of a large seamount.

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Ground-water-quality assessment of the Central Oklahoma Aquifer, Oklahoma: Geochemical and geohydrologic investigations

The National Water-Quality Assessment pilot project for the Central Oklahoma aquifer examined the chemical and isotopic composition of ground water, the abundances and textures of minerals in core samples, and water levels and hydraulic properties in the flow system to identify geochemical reactions occurring in the aquifer and rates and directions of ground-water flow. The aquifer underlies 3,000 square miles of central Oklahoma and consists of Permian red beds, including parts of the Permian Garber Sandstone, Wellington Formation, and Chase, Council Grove, and Admire Groups, and Quaternary alluvium and terrace deposits. In the part of the Garber Sandstone and Wellington Formation that is not confined by the Permian Hennessey Group, calcium, magnesium, and bicarbonate are the dominant ions in ground water; in the confined part of the Garber Sandstone and Wellington Formation and in the Chase, Council Grove, and Admire Groups, sodium and bicarbonate are the dominant ions in ground water. Nearly all of the Central Oklahoma aquifer has an oxic or post-oxic environment as indicated by the large dissolved concentrations of oxygen, nitrate, arsenic(V), chromium(VI), selenium(VI), vanadium, and uranium. Sulfidic and methanic environments are virtually absent. Petrographic textures indicate dolomite, calcite, sodic plagioclase, potassium feldspars, chlorite, rock fragments, and micas are dissolving, and iron oxides, manganese oxides, kaolinite, and quartz are precipitating. Variations in the quantity of exchangeable sodium in clays indicate that cation exchange is occurring within the aquifer. Gypsum may dissolve locally within the aquifer, as indicated by ground water with large concentra-tions of sulfate, but gypsum was not observed in core samples. Rainwater is not a major source for most elements in ground water, but evapotranspiration could cause rainwater to be a significant source of potassium, sulfate, phosphate and nitrogen species. Brines derived from seawater are the most likely source of bromide and chloride in the aquifer. The dominant reaction in recharge is the uptake of carbon dioxide gas from the unsaturated zone (about 2.0 to 4.0 millimoles per liter) and the dissolution of dolomite (about 0.3 to 1.0 millimoles per liter). This reaction generates calcium, magnesium, and bicarbonate water composition. If dolomite does not dissolve to equilibrium, pH values range from 6.0 to 7.3; if dolomite dissolves to equilibrium, pH values are about 7.5. By the time recharge enters the deeper flow system, all ground water is saturated or supersaturated with dolomite and calcite. After carbonate-mineral equilibration has occurred, cation exchange of calcium and magnesium for sodium is the dominant geochemical reaction, which occurs to a substantial extent only in parts of the aquifer. Mass transfers of cation exchange greater than 2.0 millimoles per liter occur in the confined part of the Garber Sandstone and Wellington Formation and in parts of the Chase, Council Grove, and Admire Groups. Associated with cation exchange is dissolution of small quantities of dolomite, calcite, biotite, chlorite, plagioclase, or potassium feldspar, which produces pH values that range from 8.6 to 9.1. Large tritium concentrations indicate ground-water ages of less than about 40 years for most samples of recharge. Carbon-14 ages for samples from the unconfined aquifer generally are less than 10,000 years. Carbon-14 ages of ground water in the confined part of the aquifer range from about 10,000 to 30,000 years or older. These ages produce a time trend in deuterium values that qualitatively is consistent with the timing of the transition from the last glacial maximum to the present interglacial period. The most transmissive geologic units in the Central Oklahoma aquifer are the Garber Sandstone and Wellington Formation and the alluvium and terrace deposits; the Chase, Council Grove, and Admire Groups are less transmissive on the basis of available specific-capacity data. The transmissivities of the Permian geologic units depend largely on the percentage of sandstone; the percentage is greatest in the central part of the aquifer and decreases in all directions from this central part. Because of large mudstone and siltstone contents, the Hennessey Group and the Vanoss Formation are assumed to be confining units above and below the aquifer. The Cimarron and Canadian Rivers are defined to be the northern and southern extent of the aquifer because of decreases in transmissivity beyond the rivers and because there is no indication of ground-water underflow at these rivers. The eastern boundary of the aquifer is the limit of the outcrop of the Chase, Council Grove, and Admire Groups. The presence of brines in the western part of the study unit and below the aquifer indicate the extent of the freshwater flow system in these directions. Regional ground-water flow is west to east; the Deep Fork is a major discharge area for the regional flow system. Local flow systems are present within the unconfined part of the study unit. Most streams are gaining streams, and very few losing streams are evident. Median values of aquifer properties were estimated as follows: recharge to the saturated zone, 1.6 inches per year; evapotranspiration of water that never reaches the saturated zone, 25 to 30 inches per year; porosity, 0.22; storage coefficient, 0.0002; transmissivity, 260 to 450 feet squared per day; horizontal hydraulic conductivity, 4.5 feet per day; and the ratio of horizontal to vertical hydraulic conductivity, 10,000. Reported ground-water withdrawals peaked in 1985 at 13,900 million gallons but had decreased to 7,860 million gallons by 1989. Unreported domestic withdrawals were estimated to be 1,685 million gallons in 1980. The flow system in the aquifer can be considered to have three major components: (1) A shallow, local flow system in the unconfined part of the aquifer, (2) a deep, regional flow system in the unconfined part of the aquifer, and (3) a deep, regional flow system in the confined part of the aquifer. In the shallow, local flow system, water flows relatively quickly along short flowlines from the point of recharge to the point of discharge at the nearest stream. Many water samples from shallow wells contain large concentrations of tritium, which indicate ground-water ages of less than 40 years. In the deep, regional flow system in the unconfined part of the aquifer, water takes more time to flow along longer flowlines than in the shallow, local flow system. Much of the water in this flow system is recharged along ridges that correspond to ground-water divides between drainage basins. Transit times for water recharging the aquifer along ridges is greater than 5,000 years, computed using a numerical flow model in conjunction with a particle-tracking model. The deep, regional flow system in the confined part of the Garber Sandstone and Wellington Formation is recharged from a small part of the outcrop area of the Garber Sandstone. From the recharge area, water flows west under the confining unit to discharge to streams as far away as the Cimarron River. Flowpaths are relatively long, as much as 50 miles. The transit times in this flow system range from thousands to tens of thousands of years. The long-term hydrogeochemical process occurring in the Central Oklahoma aquifer is removal of unstable minerals, including dolomite, calcite, biotite, chlorite, and feldspars, and the replacement of exchangeable sodium on clays with calcium and magnesium. Over geologic time, the flux of water through the rapidly moving, local flow system has been sufficient to remove most of the dolomite, calcite, and exchangeable sodium. In places, chlorite and feldspars have been removed. In the deep, regional flow system of the unconfined part of the Garber Sandstone and Wellington Formation, the flux of water has been sufficient to remove most of the exchangeable sodium, but carbonate minerals remain sufficiently abundant to maintain dolomite and calcite equilibrium. In the confined part of the Garber Sandstone and Wellington Formation and in the less transmissive parts of the unconfined aquifer, including the Chase, Council Grove, and Admire Groups, ground-water flow is slowest, and the flux of water and extent of reaction have been insufficient to remove either the carbonate minerals or the exchangeable sodium on clays.

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