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Multi-site evaluation of a postfire debris-flow runout forecast method

Postfire debris flows pose a hazard to human life, property, and infrastructure when they travel from steep source areas to urbanized alluvial fans or other developed areas. Existing methods for rapid (<1 week) postfire debris-flow hazard assessment document the increase in the likelihood and size of debris flows as the magnitude of high-intensity rain necessary to initiate debris flows increases but do not indicate the extent of downstream debris-flow runout. Although many models for the simulation of debris-flow motion are available, there is no established approach for using these models to delineate locations susceptible to postfire debris-flow runout that (a) is feasible to use at the spatial scale of an entire fire; (b) is appropriate for runout onto unconfined areas; (c) reproduces observed relations between runout and rainfall intensity; and (d) characterizes inherent uncertainty in runout, even without spatiotemporally variable rainfall. We propose and evaluate a method for generating postfire debris-flow runout hazard maps that has all the above qualities. Selection of case studies prioritized events triggered by a range of rainfall intensities, locations within and outside of southern California, and observed runout onto unconfined topography. Qualitative and quantitative assessment of performance for four events indicate that simulation results broadly match observations albeit with some discrepancies at a scale larger than structure or land parcel level (approximately 20-m by 20-m). The method may be used to identify potentially hazardous areas immediately following a fire and to provide approximate runout forecasts when a storm is imminent.

Arizona, California

Simulation of groundwater flow to evaluate hydrogeologic controls on a PFAS plume, Coakley Landfill Superfund site, Rockingham County, New Hampshire

Per- and polyfluoroalkyl substances (PFAS), including perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), have been detected at combined concentrations above 2,000 nanograms per liter (ng/L) at groundwater seep locations near the Coakley Landfill Superfund site, in North Hampton, New Hampshire. The landfill was active from 1972 to 1985. An impermeable cap was placed on the landfill in 1998. The adjacent area to the Coakley Landfill has many water supply wells, and transport of PFAS compounds to the wells is a concern. Fracture anisotropy in the underlying bedrock aquifer complicates the understanding of PFAS transport because groundwater preferentially travels along fractures that may not align with the prevailing groundwater flow direction. In 2018, the U.S. Environmental Protection Agency and the U.S. Geological Survey began an investigation of the groundwater flow from the Coakley Landfill site. This report describes the modification of a numerical groundwater-flow model for the local area around the Coakley Landfill and summarizes findings of the investigation. In addition, this report includes a brief description of PFOA and PFOS occurrence, a discussion of model construction, evaluation of model performance through calibration, and discussion of simulation results for two periods (before and after capping). Limitations are also discussed. Results show that simulated groundwater flow moves from the Coakley Landfill to the west and north. Advective transport modeling using particle tracking shows that groundwater from the landfill discharges primarily to streams to the west and north, and a small amount is transported to distal wells. Dilution of contaminants through advection and dispersion likely plays a role in whether PFAS compounds from the landfill will be detected above laboratory reporting levels at distal wells.

New Hampshire

Evidence of mineral alteration in a salt marsh subterranean estuary: Implications for carbon and trace element cycling

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments of dissolved organic and inorganic carbon (DOC and DIC), Si, Ba, and Mn, with variable source/sink behavior of Fe and net removal of U. Submarine groundwater discharge dominated Ba fluxes, whereas pore water drainage from marsh peat acted as the main sink for U and source of Si. Fe cycling was variable, with terrestrial Fe largely removed as groundwater passed through the STE, consistent with Fe-sulfide and amorphous phase formation. Radium isotope ratios identified two distinct subsurface flow pathways, influenced by metal-oxide cycling and organic matter breakdown. Si production was decoupled from DIC, suggesting Si originates from mineral alteration, whereas DIC results from both mineral weathering and microbial respiration. Silicate mineral alteration, coupled with marsh pore water drainage, accounts for up to 16% of annual DIC exports (66 g C m −2 y −1 ), highlighting the importance of STEs in coastal carbon and trace element cycling, especially as marshes face environmental change.

Massachusetts

Wind River subbasin restoration: Annual report of U.S. Geological Survey activities January 2024 through December 2024

We sampled juvenile wild Oncorhynchus mykiss (Steelhead Trout) in headwater streams of the Wind River, Washington, to characterize population attributes and investigate life-history metrics, particularly migratory patterns, and early life-stage survival. Additionally, this sampling provides an index of abundance of non-native Brook Trout Salvelinus confluentus . We used passive integrated transponder (PIT) tagging and a series of instream PIT-tag interrogation systems (PTISs) to track juveniles and adults. The Wind River subbasin is considered a wild Steelhead refuge by Washington Department of Fish and Wildlife (WDFW). No hatchery Steelhead Trout have been released in the Wind River subbasin since 1997, and hatchery adults are estimated at less than one percent of spawners in most years. Over 25 years of Steelhead Trout status and trend monitoring and research in the subbasin is contributing to understanding of population response to numerous restoration actions in the subbasin, including removal of Hemlock Dam from Trout Creek in 2009, which had an inadequate adult ladder and contributed to increased water temperatures, to near lethal levels for salmonids. Data from our study, and companion work by WDFW, are contributing to the Columbia Basin Fish and Wildlife Program (2009) Research, Monitoring, and Evaluation (RM&E) Strategy of Fish Population Status Monitoring. Specifically, this work addresses the sub-strategies of 1) Assessing the Status and Trends of Diversity of Natural Origin Fish Populations and Uncertainties Research regarding differing life histories of a wild Steelhead Trout population, 2) Assessing the Status and Trend of Adult Natural Origin Fish Populations, and 3) Monitoring and Evaluating the Effectiveness of Tributary Habitat Actions Relative to Environmental, Physical, or Biological Performance Objectives. During summer and fall 2024, we PIT-tagged 2,075 Steelhead Trout parr (age-0 and age-1), in the Trout Creek and upper Wind River watersheds. Age-0 and age-1 parr were at high abundance due to strong spawner numbers in 2023 and 2024 (Estimate of 932 in 2023; and a moderate number of spawners in 2024 though an estimate is not available at this time; 24-year median = 619; Charlie Cochran, WDFW Fish Biologist, personal commun., 2025). An additional 100 parr (age-0 and age-2 or older) were tagged to provide fish for estimating detection efficiencies at PTISs. Steelhead Trout parr were recaptured and detected through repeat headwater sampling, smolt trapping, instream PTISs and Columbia River mainstem PIT-tag detection. We maintained and upgraded six instream PTISs to detect PIT-tagged Steelhead Trout parr, smolts, and adults, providing data for population assessments, and life-cycle research. Detection data from PIT-tagged adult Steelhead Trout at our four primary PTISs allow assessment of adult escapement to tributary watersheds within the Wind River subbasin. Most adult Steelhead detected were tagged by WDFW at an adult trap in the lower Wind River and some as smolts at screw traps. Adult Steelhead Trout detection efficiency estimates at our primary PTIS in Trout Creek have been greater than 99 percent during eight of the past ten years and have exceeded 97% at our primary PTIS in the Wind River during nine of the past ten years. Adult escapement estimates to tributary watersheds are helping evaluate the efficacy of the 2009 removal of Hemlock Dam from rkm 2.0 of Trout Creek. Detections at the instream PTISs have shown trends of age-0 and age-1 Steelhead Trout parr emigration from natal areas during summer and fall, in addition to the expected movement of parr and smolts in spring. Our data suggest that most fish from a cohort that migrate downstream will do so at age-1 for additional rearing in the subbasin. We have estimated that from 15% to 56% of parr tagged as age-0 fish in headwater areas make downstream migrations at age-1 for additional rearing (median = 29%). We have estimated that from 1% to 27% of Steelhead Trout parr, tagged as age-1 fish, make downstream migrations during fall (median = 3.5%): this is especially pronounced in the upper Wind River portion of the watershed (median 10%). These findings raise questions about parr rearing habitat and whether migrations are density- or habitat-quality driven, and answers to such questions are long-term goals of this study as active and passive habitat restoration occurs. Repeat sampling at sites in the subbasin within and between years has enabled assessment of juvenile Steelhead Trout growth patterns. Growth rates (relative change in weight) of age-0 PIT-tagged parr during summer have been similar across the subbasin, though slightly lower in the Trout Creek watershed (Trout Creek sites, 0.57 - 1.25%/day, Wind River sites = 0.94 – 2.48%/day). Summer growth rates have been lower for age-1 parr in the Trout Creek watershed than the upper Wind River watershed (Trout Creek sites, = 0.03 - 0.14%/day, Wind River sites = 0.05 – 0.19%/day). Yearly relative growth was similar across the subbasin for both age-0 and age-1 tagged parr. During 2024 range of mean daily relative change in weight from the previous year for age-0 tagged fish was: Trout Creek sites = 0.96 – 1.41%/day, Wind River sites = 0.80 – 1.30 %/day; and for age1 tagged fish was: Trout Creek sites = 0.37 - 0.50 %/day, Wind River sites = no age-1 tagged recaptures. Non-native Brook Trout are present in the subbasin, chiefly the Trout Creek watershed. Mean percent-of-catch that is Brook Trout, at four sample sites in Trout Creek, has declined from the period 1998 – 2003 to the period 2011 – 2024 (range of decrease = 19 - 82%). Percent-of-catch (of 64 samples, 52 < 10%; 3 > 20%) and number of Brook Trout at the Trout Creek sites from 2011 through 2024, though variable, have generally declined. Habitat restoration evaluation efforts are critical to ensure efficient use of money and resources but require long-term monitoring of population metrics. Detailed viable salmonid population and life-history data, such as that provided by PIT-tagging and instream PTIS networks inform fisheries policy and management and enable assessment of long-term effects of habitat restoration actions such as the removal of Hemlock Dam on Trout Creek and proposed major instream habitat restoration in the upper Wind River.

Washington

Continuous hydrologic simulation of runoff for the Middle Fork and South Fork of the Beargrass Creek basin in Jefferson County, Kentucky

The Hydrological Simulation Pro-gram-FORTRAN (HSPF) was applied to an urban drainage basin in Jefferson County, Ky to integrate the large amounts of information being collected on water quantity and quality into an analytical framework that could be used as a management and planning tool. Hydrologic response units were developed using geographic data and a K-means analysis to characterize important hydrologic and physical factors in the basin. The Hydrological Simulation Program FORTRAN Expert System (HSPEXP) was used to calibrate the model parameters for the Middle Fork Beargrass Creek Basin for 3 years (June 1, 1991, to May 31, 1994) of 5-minute streamflow and precipitation time series, and 3 years of hourly pan-evaporation time series. The calibrated model parameters were applied to the South Fork Beargrass Creek Basin for confirmation. The model confirmation results indicated that the model simulated the system within acceptable tolerances. The coefficient of determination and coefficient of model-fit efficiency between simulated and observed daily flows were 0.91 and 0.82, respectively, for model calibration and 0.88 and 0.77, respectively, for model confirmation. The model is most sensitive to estimates of the area of effective impervious land in the basin; the spatial distribution of rain-fall; and the lower-zone evapotranspiration, lower-zone nominal storage, and infiltration-capacity parameters during recession and low-flow periods. The error contribution from these sources varies with season and antecedent conditions.

Kentucky

A regional model comparison between MODPATH and MT3D of groundwater travel time distributions

Groundwater quality changes in wells and streams lag behind changes to land use due to groundwater travel times. Two contaminant transport methods were compared to assess differences in their simulated travel time distributions (TTDs) to streams and wells in the Wisconsin Central Sands. MODPATH simulates advective groundwater flow with particle tracking, while MT3D simulates age-mass using a finite difference solution without dispersion to allow for direct comparison of the two methods. MODPATH appropriately simulates groundwater TTDs from the water table to surface discharge but is subject to inaccuracies at weak-sink well cells due to the flow-model grid discretization and imprecise location of well discharge within well cells. MT3D better represents weak-sink well cells since it removes mass in proportion to the prescribed pumping rate, although travel time within well cells is neglected. Conversely, MT3D's treatment of surface water boundary cells is not as accurate as MODPATH because mass should be removed from the water table rather than the full cell volume. MT3D simulations of TTDs can also be confounded by the instantaneous vertical distribution of mass introduced throughout recharge cells instead of at the water table, which initiates mass along deeper flow paths. We evaluated 9 MODPATH and 13 MT3D implementations, generating differences in median travel times of up to 18 years. Both methods have strengths and weaknesses, with MT3D better representing weak-sink well cell behavior and MODPATH better representing surficial recharge and discharge. The effect of these characteristics on simulated TTDs, along with ideas for ameliorating method weaknesses, is discussed.

Wisconsin

Stream nitrate dynamics driven primarily by discharge and watershed physical and soil characteristics at intensively monitored sites: Insights from deep learning

We developed a suite of models using deep learning to make hindcast predictions of the 7‐day average backward‐looking nitrate concentration at 46 predominantly agricultural sites across the midwestern and eastern United States. The models used daily observations of discharge and meteorological variables and watershed attributes describing anthropogenic modification to hydrology, nitrogen application, climate, groundwater, land use, watershed physiographic attributes, and soils. Across all sites, discharge and watershed soil and physiographic attributes showed a strong influence on model performance. Analysis of drivers across sites revealed considerable regional differences related to controlling processes such as groundwater contributions. We tested several ways to pool data across sites to develop accurate models and make the most effective use of available data. Single‐site models, in which models are trained and tested at a single location, showed generally strong predictive performance (median Kling‐Gupta Efficiency = 0.66), and accuracy at poorly performing sites could be improved by grouping sites with similar characteristics. Developing a single model for all sites reduced performance at several locations with distinct characteristics, suggesting that there is a threshold of dissimilarity beyond which more data does not improve the model. While many deep learning studies have shown that national or even global models can outperform local models, it is not clear that this is true for water quality constituents. This study demonstrates how data can be combined effectively, using deep learning to develop accurate and interpretable models of instream nitrate at sites where varying processes are responsible for changes in nitrate concentration.

Water Resources Research

A 10-year continuous daily simulation of chloride flux from a suburban watershed in Fairfax County, Virginia, USA

Increasing levels of chloride in surface water are associated with detrimental effects on water quality, aquatic ecosystems, infrastructure, and human health. Numerous mass-balance studies have inferred watershed transport processes by interpreting chloride inputs and outputs, but few represent internal dynamics explicitly. We constructed a coupled water/chloride mass balance model to gain insights into storage, residence time, and transport processes in a 10-km 2 urban watershed. The model, which operates over a 10-year period at a daily time scale, represents storage in a dynamic soil-moisture reservoir, quick-flow runoff from storm events, and slow-flow runoff that sustains streamflow in dry weather. The calibrated model accurately represented (a)the observed transition from a streamflow enrichment regime in cold months to a dilution regime in warmer months, (b) the observed tendency for late-summer concentrations to be higher after winters with heavy snowfall, and (c) a period-of-record downward trend in chloride concentration likely associated with a downward trend in annual snowfall. Estimated chloride inputs averaged 195 metric tons per year, while the average output was 270 metric tons per year. In contrast, estimated storage was only 107 metric tons. The estimated mean residence time in groundwater was 1.27 years. This short residence time indicates that efforts to reduce inputs will manifest as decreased concentrations in streamflow on a management-relevant time scale of several years. The coupled mass balance model yielded insights into internal watershed dynamics that would not be possible from simple input/output analysis; such models can be useful tools for gaining insight into small watershed hydrology and pollutant transport.

Virginia

Pesticide occurrence in shallow groundwater in three regions of agricultural land use: Baldwin County, the Wiregrass region, and the Tennessee River valley region of Alabama, 2009–20

As part of a cooperative investigation between the U.S. Geological Survey and the Alabama Department of Agriculture and Industries, a network of 22 groundwater wells were sampled from 2014 through 2020 for about 230 pesticide and pesticide degradate compounds. Wells were located in three regions of intensive agricultural land use in Alabama: Baldwin County, the Wiregrass region, and the Tennessee River valley region. Metolachlor sulfonic acid, a degradate of the herbicide metolachlor, was the most frequently detected compound, occurring in about 70 percent of the samples. Three other compounds, metolachlor, atrazine, and 2-chloro-4-isopropylamino-6-amino-s-triazine, were also detected in more than half of the samples. Metolachlor and its degradates accounted for 33 of the 50 greatest compound concentrations study-wide, including the maximum pesticide concentration across all compounds (62,500 nanograms per liter). The frequency and magnitude of detections of many specific pesticide compounds varied among the three regions, but all detected pesticide concentrations were well below the U.S. Environmental Protection Agency maximum contaminant levels and applicable human health benchmarks. Sample results were combined with results of previous (2009–13) sampling to provide a continuous time-series of data for 2009–20. More than half of the 289 pesticide compounds analyzed during 2009–20 were not detected in any samples. Only four compounds were detected at great enough frequency throughout the 10 sampling years to evaluate patterns of change through time. Metolachlor and its degradate, metolachlor sulfonic acid, were frequently detected in all regions. Atrazine and its degradate, 2-chloro-4-isopropylamino-6-amino-s-triazine, were also detected in wells from all regions, but the variability and magnitude of concentrations were greatest in the Tennessee River valley region. No apparent temporal pattern in concentrations was found.

Alabama

Integrity of production wells and confining unit at the Naval Weapons Industrial Reserve Plant, Dallas, Texas, 1995

Ground water in the shallow alluvial aquifer is contaminated at the Naval Weapons Industrial Reserve Plant, Dallas, Texas. Five production wells at the site are cased through the alluvial aquifer and underlying units and are screened in either the Paluxy or Twin Mountains aquifers. Three abandoned wells, originally completed in the Twin Mountains aquifer but filled with drilling mud in 1958, also penetrate the alluvial aquifer. The Paluxy and Twin Mountains aquifers are used for drinking-water supplies in and around the Dallas-Fort Worth metroplex. Trichloroethylene and its degradation products, dichloroethylene and vinyl chloride, and the metal chromium previously have been detected in the shallow alluvial aquifer. Current (1995) analyses of water-quality samples taken from the static water column of the five production wells and one of the abandoned wells indicate no trichloroethylene, dichloroethylene, or vinyl chloride in the water column of these wells. Chromium was detected in all samples, but concentrations were less than the practical quantitation limit, which is the regulatory action level for this site. The results of borehole geophysical log analysis indicate that two of the production wells could have vertically connected intervals where cement bonding in the well annulus is poor. The other production wells have overall good bonding. Temperature logs do not indicate flow behind casing except in the screened interval of one well. Geophysical logs show the Eagle Ford Shale ranges from 147 to 185 feet thick at the site. The Eagle Ford Shale has low permeability and a high plasticity index. These physical characteristics make the Eagle Ford Shale an excellent confining unit.

Texas

Hydrologic investigations and a preliminary conceptual model of the groundwater system at North Penn Area 1 Superfund Site, Souderton, Montgomery County, Pennsylvania

The U.S. Geological Survey (USGS) conducted hydrogeologic investigations, reviewed existing data, and developed a preliminary conceptual model of the groundwater system as part of technical support of the U.S. Environmental Protection Agency (EPA) at the North Penn Area 1 Superfund Site (hereafter, the NP1 Site) located within the Borough of Souderton in Montgomery County, Pennsylvania. Field work and monitoring took place during 2012–18. The area is underlain by sedimentary formations that form a fractured-rock aquifer used for drinking water and industrial supply. The EPA placed the Site on the National Priorities List in 1989, identifying tetrachloroethylene (PCE) and trichloroethylene (TCE) as contaminants of concern. During 2012–18, the USGS conducted field activities that included drilling an 82-foot (ft)-deep monitoring well (MG 2220) in 2016, reconstructing a 208-ft-deep former industrial production well (MG 668 [Granite Knitting Mill]), and collecting borehole geophysical and video logs and water levels from those and five additional wells, which ranged in depth from about 50 to 200 ft below land surface. Continuous water levels were collected during 2014–17, and a synoptic set of water levels were measured in April 2018 in the seven wells. The borehole geophysical logs (caliper, acoustic televiewer, natural gamma, single-point resistance, vertical flow, and fluid temperature and resistivity) and borehole video logs in the seven wells were evaluated to assess potential for lithologic correlation and to identify and describe water-bearing features, which included both low- and high-angle fractures and other openings oriented along dipping bedding planes, joints, or possible faults. Borehole geophysical logs collected by USGS in 1992 in a 300-ft-deep former production well near the Site were also evaluated. Few to no distinctive features were identified on geophysical logs (natural gamma and single-point resistance) that could be used for correlation, thus limiting this approach to determining local geologic structure. Extensive fracturing in the upper 62 ft of monitoring well MG 2220 indicates that the well was likely drilled through a zone of faulting, and other evidence of faulting is present in the area near the Site. Assessment of continuous water levels showed hydraulic connections among some wells as indicated by rising or falling water levels in response to changes in pumping rates at nearby wells. A map of water levels measured in April 2018 indicates potential for groundwater flow generally toward the stream to the south and southwest of the Site, but the limited water-level data are insufficient to describe vertical groundwater gradients or lateral gradients in any detail. Review of 1999–2022 volatile organic compound (VOC) monitoring data collected by the Pennsylvania Department of Environmental Protection for five monitoring wells indicates that the highest groundwater concentrations of PCE and TCE were found in samples from extraction well MG 2201 (S-1) downgradient from, and nearest to, the previously identified Site contaminant source area, and these concentrations fluctuated through time. PCE concentrations were higher than TCE concentrations in samples from all five monitoring wells and were much higher than TCE concentrations in samples from extraction well MG 2201 (S-1). Temporally variable recharge is a possible factor affecting observed fluctuations in PCE concentrations in groundwater samples from well extraction MG 2201 (S-1), as indicated by a general inverse relation between PCE concentrations and water levels in a nearby long-term observation well. The PCE concentration of 1,830 micrograms per liter (μg/L) in a May 2018 water sample from monitoring well MG 2220 was more than four times the PCE concentration of 444 μg/L in a December 2017 sample from the nearby extraction well MG 2201 (S-1), which is open to fewer fractures. Low concentrations of VOCs were measured in surface water at two stream sites downgradient from wells with the highest groundwater VOC concentrations at the Site, indicating that discharge of contaminated groundwater to the stream is likely. Development of a conceptual model of the groundwater system was constrained by limited data. In areas with no pumping, groundwater-flow directions generally are thought to be controlled by topography and geologic structure (bedding orientation) and likely to the south and southwest of the Site, with local flow directions affected by orientations of fractures, joints, and local faults. Additional investigations that could help improve the conceptual model of the groundwater system and help delineate the extent of groundwater contamination and its transport are discussed.

Pennsylvania

A roadmap for identifying and interpreting physical processes and national water model prediction bias associated with baseflow index regimes across the contiguous United States

Understanding how groundwater–surface water interactions shape streamflow variability is critical for diagnosing low flow behavior and prediction bias in continental scale hydrologic models. We present a process informed framework that links observed baseflow (BF) dynamics, watershed attributes, and National Water Model (NWM) performance across the contiguous United States. Using daily observed streamflow from 797 reference quality streamgages, we developed monthly baseflow index (BFI) signatures using a streamgage specific, calibrated digital filter. Hierarchical clustering of these signatures identified seven distinct BFI regimes capturing regional and seasonal variability. We evaluated NWM v3.0 retrospective streamflow performance within each regime using multiple hydrograph and flow duration curve-based metrics. Model skill varied systematically across regimes: mixed flow systems were simulated most accurately, while predominantly BF dominated and quickflow dominated regimes exhibited substantially poorer performance. Across nearly all regimes, the NWM underestimated observed BFI magnitude and frequently failed to reproduce seasonal BF patterns, indicating systematic biases in simulated low flow contributions. To relate these regimes to potential process controls, we trained a Random Forest classifier using static watershed attributes and applied Shapley Additive Explanations to identify features most strongly associated with each regime. Results highlight regionally varying influences, including the dominant role of snow fraction and seasonal runoff timing in snow dominated basins and the importance of evapotranspiration and aridity in quickflow dominated systems. Collectively, these findings demonstrate how hydrologic signatures combined with interpretable machine learning can diagnose regime specific model biases and generate process-based hypotheses about limitations in large scale hydrologic prediction systems.

contiguous United States

Perchlorate, metals, organic compounds, and lead isotopes in groundwater, surface water, shallow groundwater, and soil within and near the Middleton Municipal Airport–Morey Field (C29), Middleton, Wisconsin, 2022

The Middleton Municipal Airport–Morey Field (C29) is in the City of Middleton and adjacent to the towns of Middleton and Springfield, Wisconsin. Nearby homes in the towns rely on private drinking water wells, and residents are concerned about the potential contamination of groundwater and surface water by airport activities, including flights by small aircraft that use leaded aviation fuel and a fireworks display in July 2021. The U.S. Geological Survey, in cooperation with the Town of Middleton, completed a study in 2022 to characterize the occurrence and sources of perchlorate, metals (including lead), and organic compounds in samples of groundwater, surface water, shallow groundwater, and soils within and near the airport. Lead isotopes were also measured to determine sources of lead by comparing samples to environmental references. Magnitudes of concentrations from samples of water and soil collected in 2022, and their spatial patterns across site locations, indicate the fireworks display in July 2021 was a likely source of perchlorate and metals in the airport study area. The highest perchlorate concentration was measured in surface water at the southeastern corner of the airport near the fireworks launch site; the highest concentrations of fireworks-associated metals were measured in shallow groundwater near the same location. Fireworks were not the only possible source of perchlorate and metals in the airport study area because both were also detected upgradient and away from the fireworks launch site. Ratios of lead isotopes indicate that lead measured in water and soil within the airport study area was primarily sourced from background atmospheric lead deposition or Wisconsin galena lead ore. However, two groundwater samples (one upgradient and one downgradient from the airport; both with concentrations less than 1 microgram per liter) had isotopic signatures matching leaded aviation fuel sold at the airport.

Wisconsin

Dissolved arsenic concentrations in surface waters within the upper portions of the Klamath River Basin, Oregon and California

Arsenic toxicity is an environmental health problem. Levels of arsenic in surface waters at some locations in the Klamath River Basin in southern Oregon and northern California can exceed the U.S. Environmental Protection Agency (EPA) standard for drinking water. There are both anthropogenic and natural sources of arsenic. The Klamath River Basin consists primarily of volcanic deposits and contains an underground geothermal system with hot springs and warm water wells, all known natural sources of arsenic. Anthropogenic sources of arsenic are related to the agricultural use of herbicides, fungicides, and insecticides. Surface water arsenic levels can also be affected by fertilizer amendments, evaporative concentration, oxygen-level depletion, and various geochemical transformations that can increase arsenic mobilization. In this study by the U.S. Geological Survey and the Bureau of Reclamation, dissolved concentrations of arsenic, copper, and lead were measured in surface waters at 39 unique sites within the upper portions of the Klamath River Basin between 2018 and 2022. In every year, except 2022, sites were sampled four times between April and November. Surface-water arsenic concentrations varied up to four-orders of magnitude among sites. Median arsenic concentration was lowest at Cherry Creek (0.03 micrograms per liter [μg/L]) and highest at Wood Kimball Spring (36.7 μg/L), two sites located north of Upper Klamath Lake. The highest arsenic concentrations (17.4±4.9 μg/L, n =3) were found in drain sites (defined here as a waterbody returning used irrigation water) while the lowest arsenic concentrations were found in an artesian well (0.8 μg/L, n =1). The elevated arsenic concentrations of the drain sites suggest that arsenic might be concentrated or mobilized by agricultural activities, water re-use practices, and (or) by geochemical processes occurring around water stored in drains (that is, in the water column and across sediment water boundaries). A source of arsenic in drain water in the Klamath Strait Drain area includes water used for irrigation originating from Ady Canal. Other potential sources include groundwater, geothermal water, and local soils and sediments. Seasonal differences in surface-water arsenic concentrations were detected at 13 sites, 10 of which had higher arsenic concentrations in summer than in either spring or fall. The sites sampled around Upper Klamath Lake, the impounded rivers, one of the two canal sites, and 5 of the 14 river sites had higher surface-water arsenic concentrations in the summer than in either spring or fall. Surface-water arsenic concentrations from groundwater sources (that is, springs and in the artesian well) did not vary significantly among seasons (p-values greater than 0.1). Median surface-water concentrations of copper and lead ranged from 0.03 to 3.7 μg/L, and from 0.013 to 0.175 μg/L ( n =2–18), respectively. Dissolved concentrations of both metals were below acute toxicity endpoints reported by the EPA for freshwater animals. Surface-water arsenic concentrations varied independently from corresponding changes in surface-water lead or copper concentrations. However, arsenic concentrations measured in bed-sediment samples collected from a subset of sites located north of Upper Klamath Lake correlated strongly and significantly with the corresponding sedimentary lead concentrations ( p =0.015). Aqueous arsenic speciation measured in a subset of sites in 2019 and 2022 showed that all the arsenic existed as arsenic (V), the most oxidized arsenic species, and presumably, the least toxic. The highest proportions of arsenite (As(III)), the presumably most toxic arsenic species, relative to total arsenic concentrations were found at drain sites. Our assessment of dissolved arsenic concentrations in various surface-water bodies in the Upper Klamath River Basin reveals geographical areas of consistently low (below 2.1 μg/L), moderate (below 10 μg/L) and high (above 10 μg/L) surface-water arsenic concentrations. South of Upper Klamath Lake, surface-water arsenic concentrations were consistently higher than 20 μg/L at two drain sites located in an area of predominant agricultural land use with extensive water re-use practices. North of Upper Klamath Lake, surface-water arsenic concentrations greater than 20 μg/L were consistently measured at sites with limited nearby agricultural activities, suggesting a geogenic source. The consistently high arsenic levels from the Wood River at Jackson F. Kimball State Park, Fort Creek, and Crooked Creek, which are sites located at or near headwater spring sources, suggest a natural background source of arsenic. Water flowing downstream from this area could be a potential source of arsenic to Upper Klamath Lake and the Upper Klamath River.

California, Oregon

Regional models for postfire debris-flow likelihood and rainfall thresholds across the western United States

The U.S. Geological Survey (USGS) uses an empirical model developed with logistic regression (the ‘M1’ model) to rapidly assess debris-flow likelihood and to identify quantitative rainfall thresholds for debris flows after wildfire in the western United States. The M1 model was calibrated to a debris-flow inventory from southern California (United States) and has been applied throughout the western United States. Limited spatial coverage in the calibration dataset has motivated evaluation of M1 model accuracy outside the calibration region (e.g., the Sierra Nevada or the eastern Cascade Range, United States). Previous test cases showed that M1 overpredicts debris-flow likelihood and underpredicts rainfall thresholds for some locations (e.g., Arizona, northern California, Colorado, New Mexico, United States). We sought to improve the regional applicability of a debris-flow likelihood model by expanding the debris-flow inventory used for calibration, testing multiple potential models and generating an updated model framework. The updated inventory includes 3788 observations from 67 burned areas paired with short duration rainfall ratios. The updated model framework consists of a modified model structure and sets of coefficients calibrated separately to the entire updated inventory and to subsets of the inventory that intersect three Environmental Protection Agency (EPA) Level 2 ecoregions (Mediterranean California, Upper Gila Mountains and Western Cordillera). Comparisons of predictions from the updated models with observed rainfall and debris-flow activity show that the updated models outperform the M1 model by ~15%–60% and improve the uniformity of predictive performance across the western United States. The updated models also reduce false positive rates relative to M1 and generate rainfall thresholds that are better aligned with relative differences in regional climatology and debris-flow activity.

Arizona, California, Colorado, Idaho, Montana, Nev

U-Pb scheelite ages of tungsten and antimony mineralization in the Stibnite-Yellow Pine district, central Idaho

The Stibnite-Yellow Pine district contains the largest antimony resource in the United States, as well as significant gold, and is a historic producer of tungsten. Application of in situ laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) direct dating of scheelite from two Au-Sb-W ore deposits, Yellow Pine and Hangar Flats, yielded an older group of U-Pb ages in the range of 60.0 ± 2.8 to 57.0 ± 1.1 Ma and a younger U-Pb age for scheelite intergrown with stibnite of 47.4 ± 1.1 Ma. These in situ analyses were calibrated by isotope dilution-thermal ionization mass spectrometry (ID-TIMS) U-Pb lower intercept ages of two coarsely crystalline scheelite samples that yielded ages of 57.52 ± 0.22 and 56.62 ± 0.16 Ma. Scheelite of the latter age is of sufficient quality to serve as a primary reference material for LA-ICP-MS scheelite U-Pb geochronology. The group of older U-Pb scheelite ages agrees with 40 Ar/ 39 Ar ages of 56.9 ± 1.2 to 56.38 ± 0.54 Ma on adularia from Yellow Pine and Hangar Flats, whereas the younger U-Pb scheelite age is similar to an 40 Ar/ 39 Ar age of 46.00 ± 0.40 Ma on adularia from an epithermal gold-silver deposit in the adjacent Thunder Mountain caldera. Our results indicate that the main stage of tungsten mineralization occurred at ca. 57 Ma, whereas the main stage of antimony mineralization occurred at ca. 47 Ma—thereby providing first-time age constraints for antimony and tungsten mineralization in the Stibnite-Yellow Pine district.

Idaho

Earthquake-triggered ground-failure inventory associated with the M7.1 2018 Southcentral Alaska earthquake

The 30 November 2018, magnitude (Mw) 7.1 earthquake in Southcentral Alaska triggered substantial landslides, liquefaction, and ground cracking throughout the region, resulting in widespread geotechnical damage to buildings and infrastructure. Despite a challenging reconnaissance and remote-sensing environment, we constructed a detailed digital inventory of ground failure associated with the event from several sources. Sources included information derived from remotely sensed data, and data compiled from literature, social media postings, and earthquake damage information compiled by local, state, and federal agencies. Each instance of ground failure within the inventory contains information on the location and type of observed ground failure, and the methods and data used to document the occurrence. Where high-quality data, such as LIDAR or satellite imagery, were available and showed the ground-failure instance clearly, the extent is mapped as a polygon or polyline. All other locations are mapped as points. There are a total of 886 ground-failure instances documented within the inventory (400 landslides, 286 liquefaction features, and 200 features unattributed to specific processes). A semi-quantitative confidence scheme is used to describe mapping certainty associated with each ground-failure feature. This inventory represents a relatively moderate ground-failure-triggering event that occurred in a subarctic environment. This data paper describes the content within the inventory, the inventory data collection procedures, and limitations of the data. Events of this type are not often documented in detail; thus, adding the inventory data to the US Geological Survey Open Repository of Earthquake-Triggered Ground-Failure Inventories further diversifies the datasets available to the scientific community to be used to better understand and model earthquake-triggered ground failure.

Alaska

A review of abrupt permafrost thaw: Definitions, usage, and a proposed conceptual framework

Purpose of Review We review how ‘abrupt thaw’ has been used in published studies, compare these definitions to abrupt processes in other Earth science disciplines, and provide a definitive framework for how abrupt thaw should be used in the context of permafrost science. Recent Findings We address several aspects of permafrost systems necessary for abrupt thaw to occur and propose a framework for classifying permafrost processes as abrupt thaw in the future. Based on a literature review and our collective expertise, we propose that abrupt thaw refers to thaw processes that lead to a substantial persistent environmental change within a few decades. Abrupt thaw typically occurs in ice-rich permafrost but may be initiated in ice-poor permafrost by external factors such as hydrologic change (i.e., increased streamflow, soil moisture fluctuations, altered groundwater recharge) or wildfire. Summary Permafrost thaw alters greenhouse gas emissions, soil and vegetation properties, and hydrologic flow, threatening infrastructure and the cultures and livelihoods of northern communities. The term ‘abrupt thaw’ has emerged in scientific discourse over the past two decades to differentiate processes that rapidly impact large depths of permafrost, such as thermokarst, from more gradual, top-down thaw processes that impact centimeters of near-surface permafrost over years to decades. However, there has been no formal definition for abrupt thaw and its use in the scientific literature has varied considerably. Our standardized definition of abrupt thaw offers a path forward to better understand drivers and patterns of abrupt thaw and its consequences for global greenhouse gas budgets, impacts to infrastructure and land-use, and Arctic policy- and decision-making.

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