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Geology and ground-water resources of North Dakota, with a discussion of the chemical character of the water

Water is the most valuable of the mineral resources. The study of ground waters is therefore clearly within the field of economic geology and constitutes an important part of the work of the geological surveys, both State and national, as defined by law. In the spring of 1911 the investigation of the ground waters of North Dakota was begun by the North Dakota Geological Survey, and the work was assigned to the author of this paper. During each of the three summers 1911, 1912, and 1913 several weeks were devoted by the author to the field work of a general survey. A report on the ground waters of the State was then prepared by him and was transmitted by the director of the North Dakota Geological Survey to the State printing commission for publication. However, owing to lack of available funds the report was not published. A portion of the summer of 1914 was given to a study of artesian conditions in the Souris River Basin. Since that time considerable work has been done in connection with detailed surveys made for a number of cities and villages in an effort to obtain the best available supply of water for public use. During the summer of 1920 arrangements were made by the United States Geological Survey with the North Dakota Geological Survey whereby the author completed the work as fully as possible by correspondence and brought the report up to date. In the spring of 1921 samples of water from 196 sources were collected by the author and J. H. Buchanan and were sent to the United States Geological Survey for analysis. Most of these samples were analyzed by H. B. Riffenburg, who has used the analyses for a description of the chemical character of ground waters in the State. In addition to the analyses of samples collected in connection with the preparation of this report, over 700 partial analyses from different sources were examined. These analyses are not given in this paper, because the location of many of the wells was not stated definitely, and most of the analyses were incomplete. They were useful, however, in confirming the conclusions based on the analyses that are printed, particularly for counties where only a few samples were collected for this report.

North Dakota↗

Geomedia: Mapping Colorado at a fine scale

Currently, only 24 percent of Colorado's spectacular geology has been mapped at the fine scale of 1:24,000. At the same time, the state hosts many geologic hazards. Most maps of Colorado are at much broader scales, failing to show detail of basic geology crucial to safe engineering and building practices in a state that had the third-fastest-growing population during the 1990s. And the 2000 Census showed that the state, despite some economic woes, remains one of the fastest growing. Detailed geologic maps also aid the mineral industries that help fuel such growth. Since 1992, the Colorado Geological Survey (CGS) has mapped 1:24,000-scale quadrangles in high-impact areas under the STATEMAP component of the National Cooperative Geologic Mapping Program. In 2002, CGS completed its 43rd geologic quadrangle map. The long-range plan for the state is to complete 116 high-priority quadrangles in the next 15 years. The survey's approach is to select rapidly growing areas with relatively high potential for hazards and map contiguous quadrangles. In addition to mapping bedrock, CGS geologists have mapped the Quaternary deposits at the surface. Understanding these deposits is extremely important for implementing sound engineering practices because of potential for subsidence and landslides. The CGS mapping has not only yielded information about potential hazards, but also advanced scientific understanding of the state.

Geotimes↗

Secular variation in economic geology

The temporal pattern of ore deposits on a constantly evolving Earth reflects the complex interplay between the evolving global tectonic regime, episodic mantle plume events, overall changes in global heat flow, atmospheric and oceanic redox states, and even singular impact and glaciation events. Within this framework, a particular ore deposit type will tend to have a time-bound nature. In other words, there are times in Earth history when particular deposit types are absent, times when these deposits are present but scarce, times when they are abundant, and still other times for which we lack sufficient data. Understanding of such secular variation provides a critical first-order tool for exploration targeting, because rocks that have formed or were deformed during a certain time slice may be very permissive for a given deposit type, whereas identification of rocks of less favorable ages would help eliminate large areas during exploration programs. Secular analysis, therefore, is potentially a powerful tool for mineral resource assessment in poorly known terranes, providing a quick filter for favorability of a given deposit type using age of host rocks. Factors bearing on the known age distribution of a particular type of deposit include the following: (1) uneven preservation, (2) data gaps, (3) contingencies of plate motions, and (4) long-term secular changes in the Earth System. The present special issue of Economic Geology is focused on the latter factor, although all of these are interrelated. The selective preservation of certain mineral deposit types and the greater susceptibility for shallowly formed ores in tectonically active environments to be lost to erosion define a pattern that is superimposed on the secular formational trends (e.g., Groves et al., 2005a , b ; Kerrich et al., 2005 ). With improved geochronological methods and the availability of information on important mineral deposits from most parts of the world, data gaps for defining broad temporal distributions of ore types are becoming smaller. It has been increasingly recognized that ore deposit formation is also correlated with plate tectonic setting. Nevertheless, a complex Earth history of supercontinent assembly and breakup has led to the fragmentation of many Paleozoic and Precambrian mineral provinces. The use of plate reconstructions in economic geology, although extremely controversial and conjectural before the late Paleozoic, is critical for defining these provinces prior to the added complications resulting from post-ore plate motions. It is now well established that the temporal patterns of many types of mineral deposits (Fig. 1 1 ) reflect the formation or break-up of supercontinents and the preservation potential of deposits formed during these periods ( Barley and Groves, 1992 ; Titley, 1993 ; Kerrich et al., 2005 ; Goldfarb et al., 2009 ). Approximate time periods for such formation and break-up, respectively, include 2800–2500 and 2450–2100 Ma for Kenorland, 2100–1800 and 1600–1300 Ma for Nuna/Columbia, 1300–1100 and 850–600 Ma for Rodinia, and 600–300 Ma and 200–60 Ma for Gondwanaland-Pangea. A new supercontinent, Amasia, has begun to form during the past 250 m.y., thus overlapping Pangea break-up. Many of the formation-preservation patterns are themselves controlled by progressive cooling of Earth, the change from a mantle-plume buoyancy style to subduction-dominated tectonics, a decreasing buoyancy of the subcontinental lithospheric mantle, and depth of ore formation. In general, orogenic Au, volcanogenic massive sulfide (VMS), epithermal Au-Ag, and porphyry Cu±Au and Mo porphyry deposits form in active margins during periods of supercontinent assembly. Numerous other ore deposit types show an association with supercontinent formation, but develop inland of the active margin. These include many of the MVT Pb-Zn deposits and unconformity-type U deposits. The Tertiary Carlin-type deposits within the deformed shelf sequences along the North American craton margin also appear to have formed during the ongoing growth of Amasia. Those ores associated with periods of supercontinent breakup or attempted breakup are more difficult to define. They probably include diamond, Bushveld-type Ni-Cu-PGE, IOCG, and clastic-dominated Pb-Zn (or SEDEX) deposits in intracontinental areas of failed rifting, and other clastic-dominated Pb-Zn deposits in areas of actual breakup. In all cases, however, these temporal/spatial distributions are ultimately controlled by the secular character of Earth history.

Economic Geology↗

Investigations needed to stimulate the development of Jordan's mineral resources

The level of living that any society can attain is a direct function of the use it makes of all kinds of raw materials (soil, water, metals, nonmetals, etc.), all kinds of energy (both animate and inanimate), and all kinds of human ingenuity; and is an inverse function of the size of the population that must share the collective product. The relation between raw materials, energy and ingenuity is such that use of a large amount of one may offset the need for large amounts of others. The most vital raw materials are water, soil, and construction materials, for these are needed in large quantities and are hard to import. Metals, chemicals, and inanimate energy are necessary for industrialization. The more of these minerals a nation possess, the better, but not nation can hope to be self-sufficient in all of the m and therefore must trade for some essential materials. Jordan’s natural resources have been little explored. The grantitc-metamorphic terrane in the southeastern part of the Kingdom could contain deposits of tungsten, rare earths, feldspar, mica, fluorite etc. and the sedimentary terrane over much of the rest of the county is favorable for the occurrence of oil. Even if none of these minerals is found, however, Jordan’s other mineral resource, if fully explored and developed in the light of modern technology, will support a far higher level of living than her people now enjoy. Very likely she can increase her rainfall by about 10 percent by cloud seeding, and she undeveloped supplies in both surface and ground water that are sufficient to nearly double her usable water supply. Even if she does not have oil or have it in large quantities, she can buy it cheaply from neighboring counties, and in addition has undeveloped sources of hydroelectric power, large reserves of bituminous limestone, large reserves of nuclear power as uranium in phosphate rock, and can use solar and wind power for special purposes. Her large supplies of construction, fertilizer, and other chemical raw materials will not only satisfy her own needs, but will yield both raw materials and some manufactured products for export. And she has valuable resource of touristic interest in the form of incomparable scenery, antiquities, and holy places, which, if properly advertised, could well become her largest single source of foreign currency. Revenues obtained from this source and from the export of agricultural products, nonmetallic minerals, and mineral products should support foreign oil purchase of oil, machinery, and other products not mined or produced internally. Full development of Jordan’s economic potential will take years to achieve and involves many complex activities. One of the most essential is one that can be pressed in the early years, namely the gathering of facts and basic data concerning the character, extent, and distribution of her resources, and the uses that can be made of them. Without each fundamental data or the understanding of their meaning or the ways to use and apply them, costly developmental projects and similar efforts to raise the level of living are likely to have limited success at best. Basic data and mineral resources are best gathered and published by permanent government agencies, for private organizations and individual cannot afford to take the risks involved in gathering data that may not have an immediate economic return; and even if private parties do collect such data they are not likely to make them general available. Of the activities needed in the field of mineral resources, some are already underway as the established function of government agencies. No bureau however, seems to have responsibility for making geologic maps and for gathering data on such things as steam flow, composition and properties of minerals and rocks, or for investigating the uses to which Jordan’s minerals might be put. To satisfy these needs, a Geological Survey and a Bureau of Mineral Industries should be formed and placed in operation as quickly as possible. The task of collecting and interpreting basic data or mineral resources must be done largely by Jordanians, for only in this way will Jordan acquire the technical competence needed to use the information. Few Jordanians have enough training or experience to work independently in these fields now, however, so help from outside technicians would be necessary over an initial training period of several years. But the number of outside technicians should never exceed the number of Jordanian technicians, and for this reason, neither organization could have a staff of more than a few people during the early years of operation.

Open-File Report↗

The United Nations framework classification for fossil energy and mineral reserves and resources 2009

Effective resource management in a globalizing economy requires accurate assessments of fossil energy and minerals resources. The recoverable quantities must be described and categorized in a manner that is consistent with scientific and social/economic information describing the economy as well as with the information describing the projects to recover them. A number of different standards have evolved over time in response to various professional needs Under a mandate given by the United Nations Economic and Social Council, the United Nations Economic Commission for Europe (UNECE) has cooperated with Governments, regulatory agencies, industry, international organizations, and professional organizations (including Committee for Mineral Reserves International Reporting Standards (CRIRSCO), the Society of Petroleum Engineers (SPE), the American Association of Petroleum Geologists (AAPG), and the Society of Petroleum Evaluation Engineers (SPEE)), as well as with outstanding experts, to define a global classification for extractive activities (including oil, gas, heavy oil and bitumen extraction) that reflects the principal concerns of existing petroleum and mineral classifications. The United Nations Framework Classification for Fossil Energy and Mineral Reserves and Resources-2009 (UNFC-2009) aims to serve the following four principal needs: 1. The needs in international energy and mineral studies to formulate robust and long-sighted policies. 2. The needs of governments in managing their resources accordingly, allowing market prices to be transferred to the wellhead with as little loss as possible. 3. The industries' needs for information while deploying technology, management and finance to secure energy supplies and capture value efficiently within the established frameworks to serve its host countries, shareholders and stakeholders. 4. The financial community's need for information to allocate capital appropriately, providing reduced costs and improved long-sightedness through the application of lower risk-compensated discount factors. The projects are categorised with respect to economic and social viability, project feasibility and maturity and uncertainty with respect to the quantities addressed. The categorisation of projects rather than of accumulations provides coherence with other critical management information such as production, cash flows, value and demand for various input factors. This key aspect of UNFC-2009 reflects the critical relationship between the quantities that can be recovered economically and the recovery processes (projects) that must be implemented to achieve those recoveries. It facilitates the recognition of potential wastage of resources through flaring or inefficient recovery processes and therefore also the potential for improvement. Copyright 2011, Society of Petroleum Engineers.

Conference Paper↗

Topographic and Hydrographic GIS Datasets for the Afghanistan Geological Survey and U.S. Geological Survey 2014 Mineral Areas of Interest

Mineral extraction and associated industries play an important role in the Afghan economy, particularly in the “transitional era” of declining foreign aid and withdrawal of foreign troops post 2014. In addition to providing a substantial source of government revenue, other potential benefits of natural resource development include boosted exports, employment opportunities, and strengthened industrialization (Joya, 2012). Continued exploration and investment in these industries has resulted in large economic improvements since 2007, when this series of studies was initiated. At that time, the “Preliminary Non-Fuel Mineral Resource Assessment of Afghanistan” was completed by members of the U.S. Geological Survey and Afghanistan Geological Survey (Peters and others, 2007). The assessment published a series of country-wide datasets, including a digital elevation model (DEM), elevation contours, hydrography, transportation routes, geophysics, and cultural datasets (Peters and others, 2007). It also delineated 20 mineralized areas for further study using a geologic-based methodology. A second data product, “Summaries of Important Areas for Mineral Investment and Production Opportunities of Nonfuel Minerals in Afghanistan,” was released by Peters and others in 2011. This work highlighted geologic, geohydrologic, and hyperspectral studies that were carried out in specific Areas of Interest (AOIs) to assess the location and characteristics of mineral resources. Also included in the 2011 publication is a collection of appendixes and inventories of Geographic Information System (GIS) datasets for each of the 24 identified AOIs. A third data product was released in 2013 (Casey and Chirico, 2013), publishing datasets for five different AOIs, two subareas, and one AOI extension. Each dataset contains vector shapefiles of the AOI boundary, streams, roads, and contours at 25-, 50-, and 100-meter (m) intervals, as well as raster files of the AOI’s DEM and hillshade. This work represents the fourth installment of the series, and publishes a dataset of eight new AOIs and one subarea within Afghanistan. These areas include Dasht-e-Nawar, Farah, North Ghazni, South Ghazni, Chakhansur, Godzareh East, Godzareh West, and Namaksar-e-Herat AOIs and the Central Bamyan subarea of the South Bamyan AOI (datasets for South Bamyan were published previously in Casey and Chirico, 2013). For each AOI and subarea, this dataset collection consists of the areal extent boundaries, elevation contours at 25-, 50-, and 100-m intervals, and an enhanced DEM. Hydrographic datasets covering the extent of four AOIs and one subarea are also included in the collection. The resulting raster and vector layers are intended for use by government agencies, developmental organizations, and private companies in Afghanistan to support mineral assessments, monitoring, management, and investment.

Open-File Report↗

Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada-Results of a 5-year project

This report presents summary papers of work conducted between 2002 and 2007 under a 5-year project effort funded by the U.S. Geological Survey Mineral Resources Program, formerly entitled 'Tintina Metallogenic Province: Integrated Studies on Geologic Framework, Mineral Resources, and Environmental Signatures.' As the project progressed, the informal title changed from 'Tintina Metallogenic Province' project to 'Tintina Gold Province' project, the latter being more closely aligned with the terminology used by the mineral industry. As Goldfarb and others explain in the first chapter of this report, the Tintina Gold Province is a convenient term used by the mineral exploration community for a 'region of very varied geology, gold deposit types, and resource potential'. The Tintina Gold Province encompasses roughly 150,000 square kilometers, bounded by the Kaltag-Tintina fault system on the north and the Farewell-Denali fault system on the south. It extends westward in a broad arc, some 200 km wide, from northernmost British Columbia, through the Yukon, through southeastern and central Alaska, to southwestern Alaska. The climate is subarctic and, in Alaska, includes major physiographic delineations and ecoregions such as the Yukon-Tanana Upland, Tanana-Kuskokwim Lowlands, Yukon River Lowlands, and the Kuskokwim Mountains. Although the Tintina Gold Province is historically important for some of the very first placer and lode gold discoveries in northern North America, it has recently seen resurgence in mineral exploration, development, and mining activity. This resurgence is due to both new discoveries (for example, Pogo and Donlin Creek) and to the application of modern extraction methods to previously known, but economically restrictive, low-grade, bulk-tonnage gold resources (for example, Fort Knox, Clear Creek, and Scheelite Dome). In addition, the Tintina Gold Province hosts numerous other mineral deposit types, possessing both high and low sulfide content, which are not currently in development.

Alaska, Yukon↗

Contributions to economic geology (short papers and preliminary reports), 1927: Part I - Metals and nonmetals except fuels

The Geological Survey's "Contributions to economic geology" are published in two parts, one including papers on metals and nonmetals except fuels and the other including papers on mineral fuels. As the subtitle indicates, most of the papers in these volumes are of three classes (1) short papers describing as thoroughly as conditions will permit areas or deposits on which no other report is likely to be prepared; (2) brief notes on mining districts or economic deposits whose examination has been merely incidental to other work; and (3) preliminary reports on economic investigations the results of which are to be published later in more detailed form. Although these papers set forth mainly the practical results of economic investigations, they include brief theoretical discussions and summary statements of conclusions if these appear to require prompt publication.

Bulletin↗

Structure and petrology of the alpine-type peridotite at Burro Mountain, California, U.S.A.

The alpine-type peridotite at Burro Mountain is a partially serpentinized harzburgite-dunite body approximately 2 km in diameter. It lies in a chaotic mélange derived from the Franciscan Formation (Upper Jurassic to Upper Cretaceous) of the southern Coast Ranges of California. The peridotite is bounded on the east by a vertical fault in the Nacimiento fault zone that brings sedimentary rocks of Taliaferro's (1943 b ) Asuncion Group (Upper Cretaceous) into contact with the peridotite. The peridotite appears to be one of a number of tectonic lenses, having a wide range in size, that make up the mélange . These lenses include metagraywacke, metachert, greenstone, amphibolite, and blueschist, as well as ultramafic rocks, and represent a wide range of pressure-temperature environments. The outer shell of the peridotite is a sheared serpentinite zone 10–15 m thick. The peridotite was tectonically emplaced at its present level as a cold solid mass and had little effect on the mineral assemblages of the Franciscan Formation. Local development of lawsonite and aragonite in shear zones may be related to the peridotite emplacement. Foliated harzburgite forms approximately 60 per cent of the peridotite. It is a lithologically uniform rock that has an olivine: orthopyroxene ratio of approximately 75:25. Accessory clinopyroxene and chromian spinel generally make up less than 5 per cent of the harzburgite. Dunite, composed of olivine, accessory chromian spinel (< 5 per cent), and trace amounts of pyroxene, makes up approximately 40 per cent of the peridotite and occurs as dikes, sills, and irregular bodies in the harzburgite. Olivine and pyroxene show small but significant compositional variations and chromian spinel shows a large range in the cation ratio Cr/(Cr+Al+ Fe 3+ ). The compositional variations in these minerals are related to original differences in bulk chemical composition. The following compositional ranges were determined for minerals in the harzburgite: olivine, Fo 91.1 −Fo 91.4 ; orthopyroxene, En 89.8 −En 91.1 ; clinopyroxene, Ca 47.0 Mg 50.0 Fe 3.0 −Ca 48.7 Mg 48.2 Fe 3.1 ; chromian spinel, Cr/(Cr+Al+Fe 3+ ) 0.37−0.55. The pyroxenes have a range in A1 2 O 3 content of 1.3−3.0 wt per cent. Olivine from dunite ranges from Fo 91 to Fo 92 7 and the chromian spinel has a range in the Cr/(Cr+Al+Fe 3+ ) ratio of 0.30−0.75. Although all the dunites are lithologically similar, three distinct types are recognized on the basis of composition of coexisting olivine and chromian spinel. Structural relations between the three types of dunite suggest three periods of emplacement (possibly overlapping) of dunite into harzburgite. The evidence indicates that the dunite, and probably also the harzburgite crystallized from an ultramafic magma, probably in the upper mantle. After the magmatic episode and crystallization, the peridotite was subjected to a deep-seated plastic deformation and recrystallization. The first phase of the deformation produced a pervasive, planar structural element (S 1 ) that crosscuts many harzburgite-dunite contacts. It is probable that some of the dunite sills were emplaced during this deformation. The foliation, S 1 , is defined by layers of different orthopyroxene content in harzburgite, and by discontinuous layers of chromian spinel in dunite. Flow or slip along S 1 produced slip folds in harzburgite—dunite contacts with axial planes parallel to S 1 . At a later stage, isoclinal folds developed in S 1 , and the present olivine microfabric was probably formed by recrystallization in the stress field that produced the isoclinal folding. In the olivine microfabric, X tends to be perpendicular to the axial planes (S 2 ) of the isoclinal folds and Y and Z tend to form double maxima in S 2 approximately 90° apart. Mg−Fe 2+ distribution between coexisting mineral pairs yields a calculated temperature of formation of approximately 1200 °C. Although this temperature is only a nominal value, it indicates that the mineral pairs equilibrated at a significantly high temperature. In view of the deformation and recrystallization, the calculated temperature possibly represents subsolidus re-equilibration of the minerals during this event. The deformation and recrystallization probably occurred shortly after crystallization while the peridotite was still at a high temperature. A later deep-seated deformation produced small scattered kink folds in S 1 that tend to disrupt the major olivine microfabric. The kink folding was accompanied or followed by the development of kink bands in olivine that reflect intragranular gliding on the system T = [ Okl ], t = [100]. The kink bands probably formed at a minimum temperature of 1000 °C. Following the deep-seated deformation, which probably took place in the mantle, the peridotite mass was tectonically detached and moved upward to its present level in the crust. Cleavages, joints, and faults provided channels for water to pervade the peridotite and allow alteration of the primary minerals.

California↗

Geochemical constraints on the genesis of the Scheelite dome intrusion-related gold deposit, Tombstone gold belt, Yukon, Canada

The Scheelite dome intrusion-related gold deposit, western Selwyn basin, Yukon, is hosted in hornfelsed metasedimentary strata that lie adjacent to the exposed apices of a monzogranite to quartz monzonite plutonic complex of the mid-Cretaceous Tombstone-Tungsten magmatic belt, Tintina gold province, Alaska and Yukon. A variety of mineralization styles occur throughout a 10- ?? 3-km east-trending corridor and include reduced Au- and W-rich skarns, Au, W- and Ag-Pb-Zn-Sb-rich quartz tension-vein arrays, and multiphase fault veins and isolated zones of Au-rich sericite-carbonate altered rock. Integrated U-Pb SHRIMP data for magmatic zircon and Ar-Ar data for magmatic and hydrotbermal biotite indicate that gold mineralization occurred within 1 to 2 m.y. of magma emplacement. Fluid inclusion, oxygen isotope, and arsenopyrite geothermometry data indicate that hydrothermal minerals formed at depths of 6 to 9 km over a temperature range from <300?? to >550??C. High-temperature Au-rich skarns formed at >400??C, whereas vein-hosted mineralization formed at 280?? to 380??C. In skarns, Au is strongly associated with enrichments of Bi, Te, W, and As, whereas a variety of Au-rich veins occur, with Asrich (type 1), and Te- and W-rich (type 2) end members. Silver-Pb-Zn-Sb veins are typically Au poor and represent the latest and lowest temperature phase in the hydrothermal paragenesis. The fluid inclusion data indicate that all mineralization styles were formed from low-salinity (???4 wt % NaCl equiv) aqueous-carbonic fluids, consistent with the composition of fluid inclusions within infilled miarolitic cavities in the intrusive rocks. However, the nonaqueous fluid was predominantly CH4 in skarn, CO2 in Au-Te and Au-W veins, and a fluid with roughly equal amounts Of CO2, CH4, and N2 in Au-As and Ag-Pb-Zn-Sb veins. Oxygen isotope data are consistent with a mineralizing fluid of predominantly magmatic origin that was variably modified to more positive ??18O values during interaction with 18O-enriched metasedimentary strata. Sulfur isotope data suggest two possible sources of sulfur, a magmatic source characterized by ??34S values of approximately -5 to 0 per mil and sulfur from the metasedimentary country rocks characterized by more negative ??34S values of approximately -15 to -10 per mil. Collectively the data indicate that gold at Scheelite Dome was deposited from a magmatic-hydrothermal system. Interaction of magmatic fluids with graphitic hornfels rocks resulted in reduction of the ore fluids, higher CH4/CO2 ratios, and modification of the oxygen and sulfur isotope values of the ore fluids toward those of the metasedimentary hornfels. Progressive reduction and cooling of hydrotbermal fluids, in addition to phase separation in vein-hosted mineralization, were the mechanisms for gold deposition. Compared to other intrusion-related gold deposits associated with the Tombstone-Tungsten magmatic belt magmatism, exposed mineralization at Scheelite Dome is predominantly hosted by hornfelsed metasedimentary rocks. This results in more diverse mineralization styles and a greater spread of isotope and fluid inclusion data. ?? 2006 Society of Economic Geologists, Inc.

Economic Geology↗

Spectroscopic mapping of the white horse alunite deposit, Marysvale volcanic field, Utah: Evidence of a magmatic component

Previous studies have demonstrated that the replacement alunite deposits just north of the town of Marysvale, Utah, USA, were formed primarily by low-temperature (100??-170?? C), steam-heated processes near the early Miocene paleoground surface, immediately above convecting hydrothermal plumes. Pyrite-bearing propylitically altered rocks occur mainly beneath the steam-heated alunite and represent the sulfidized feeder zone of the H2S-dominated hydrothermal fluids, the oxidation of which at higher levels led to the formation of the alunite. Maps of surface mineralogy at the White Horse deposit generated from Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data were used in conjunction with X-ray diffraction studies of field samples to test the accuracy and precision of AVIRIS-based mineral mapping of altered rocks and demonstrate the utility of spectroscopic mapping for ore deposit characterization. The mineral maps identified multiple core zones of alunite that grade laterally outward to kaolinite. Surrounding the core zones are dominantly propylitically altered rocks containing illite, montmorillonite, and chlorite, with minor pyrite, kaolinite, gypsum, and remnant potassium feldspar from the parent rhyodacitic ash-flow tuff. The AVIRIS mapping also identified fracture zones expressed by ridge-forming selvages of quartz + dickite + kaolinite that form a crude ring around the advanced argillic core zones. Laboratory analyses identified the aluminum phosphate-sulfate (APS) minerals woodhouseite and svanbergite in one sample from these dickite-bearing argillic selvages. Reflectance spectroscopy determined that the outer edges of the selvages contain more dickite than do the medial regions. The quartz + dickite ?? kaolinite ?? APS-mineral selvages demonstrate that fracture control of replacement processes is more prevalent away from the advanced argillic core zones. Although not exposed at the White Horse deposit, pyrophyllite ?? ordered illite was identified using AVIRIS in localized, superimposed conduits within propylitically altered rocks in nearby alteration systems of similar age and genesis that have been eroded to deeper levels. The fracture zones bearing pyrophyllite, illite, dickite, natroalunite, and/or APS minerals indicate a magmatic component in the dominantly steam-heated system. ?? 2006 Society of Economic Geologists, Inc.

Economic Geology↗

Primary borates in playa deposits: Minerals of high hydration

The primary borate minerals in nonmarine bedded borate deposits - those of the playa type, and their deformed derivatives - are the high hydrates. Both field and laboratory data indicate that the high hydrates are the borate minerals that form stable phases at the lowest temperatures: under the surface conditions of playas. From a study of hand specimens of borate minerals from the new Turkish borate deposits, Meixner suggested that the borate minerals having the lowest specific gravity, and hence, highest water content, are the primary minerals. The role of temperature in the formation of the hydrous borates is shown by solid phases in the system Na 2 B 4 O 7 -H 2 O. As temperature increases, hydration of the solid phase decreases successively from borax (10H 2 O) through tincalconite (5H 2 O), kernite (4H 2 O), to metakernite (2H 2 O). This suggests that in the temp- erature ranges considered in the present paper - those of playas - the high hydrate (borax) is the one most likely to form as the primary mineral in nature. Studies of the Ca, Mg, and Ca-Na hydrous borate systems suggest that the same statement holds in these systems. Until recently, only borax and ulexite (Na 2 O . 2CaO . 5B 2 O 3 . 16H 2 O) have been known as primary minerals of playa deposits. However, inderite (2MgO . 3B 2 O 3 . 15H 2 O) has recently been found as a primary mineral I 5i in Argentina and primary inyoite (2CaO . 3B 2 O 3 . 13H 2 O) has been found in Peru. These 4 minerals are the high hydrates of their respective mineral series. None of the lower hydrates are known as primary minerals in nonmarine bedded deposits. On burial and deformation of the primary minerals, the changes in temperatures and pressures are almost certainly in such a direction as to encourage minerals of higher density and lower hydration to become stable phases. Field evidence bears this out; in all deformed deposits secondary minerals of low hydration are quantitatively important.

Economic Geology↗

Gold abundance in igneous rocks; bearing on gold mineralization

Review of quantitative data, restricted range in gold content (rarely more than 10 ppb, generally below 5 ppb), mafic rocks have more, so do early crystallizing minerals, no use in exploration, factors other than concentration determine mineralization; examples

Economic Geology↗

Geology and geochemistry of Summitville, Colorado: An epithermal acid sulfate deposit in a volcanic dome

Geologic studies during recent open-pit mining at Summitville, Colorado, have provided new information on an epithermal acid sulfate Au-Ag-Cu deposit formed in a volcanic dome. Geologic mapping, geochemical studies of whole-rock samples from blast holes, and geologic and geochemical traverse studies refine the details of the evolution of the Summitville deposit. Six distinct events followed emplacement of the quartz latite volcanic dome and define the development of the Summitville deposit: (1) an early stage of acid sulfate alteration, (2) subsequent Cu sulfide and gold mineralization, (3) widespread hydrothermal brecciation, (4) volumetrically minor, base metal sulfide-bearing barite veining, (5) volumetrically minor, kaolinite matrix brecciation, and finally, (6) supergene oxidation. Events 1 and 2 were the most important for the formation of the Summitville deposit. Acid sulfate altered rock is primarily found in the quartz latite volcanic dome rock and consists of vuggy silica (central), quartz-alunite, quartz-kaolinite, argillic, and propylitic (distal) zones. Ore deposition (event 2) of enargite, luzonite, covellite, pyrite, native sulfur, marcasite, and minor sphalerite, native gold, + or - barite and galena overprinted the acid sulfate altered rocks. Events 3, 4, and 5 are geologically important but rarely formed units large enough to be considered mineable ore by open-pit mining. The final supergene oxidation event affected much of the near-surface portion of the deposit and leached copper and sulfide minerals forming oxide zones. Near-surface oxide zones contain the highest Au grades and decrease progressively with depth.Fractures were important fbr localizing both the acid sulfate altered rock and ore deposition at Summitville. Such fracture control is apparent despite a lack of distinct throughgoing open-space quartz veins; instead, laterally and vertically extensive ore zones are identified by their highly silicified character that can be traced laterally for up to 500 m and vertically up to 200 m. Ore zones strike parallel to regional faults related to rifting and basin and range development, suggesting that hydrothermal fluids followed preexisting fractures. Ore zones follow two northwest trends, a N 30 degrees W + or - 20 degrees trend, and a N 60 degrees W trend. Most fractures and faults in the open pit dip steeply from 65 degrees to vertical. Ore zones intersect near the center of the deposit to form a large zone approximately 150 by 400 m. Ore zones form a rough radial pattern located near the center of the deposit and a discontinuous arcuate feature on the northern side. This radial pattern, arcuate feature, and the intersection of ore zones near the center of the deposit are probably related to the intrusion of a porphyry below the deposit. The overall low Au-grade, high-tonnage character of the Summitville deposit is related to low permeability in the quartz latite volcanic dome rock and absence of well-developed open-space hydrothermal veins.Gold analyses of development drill holes and blast hole samples, in conjunction with geologic mapping in the open pit, indicate that vuggy silica, quartz-alunite, and quartz-kaolinite altered rock constitute most of the Au ore. Vuggy silica averaged 2.4 ppm Au, quartz-alunite averaged 1.2 ppm Au, and quartz-kaolinite averaged 0.86 ppm Au during open-pit mining. Grades for argillically altered rock were usually below the ore cutoff of 0.34 ppm Au. Propylitically altered rock rarely contained detectable Au concentrations (0.03 ppm Au) and constituted only waste rock. Although volumetrically minor, event 4 base metal sulfide-bearing barite veins and event 5 kaolinite matrix breccias contained high Au grades (up to about 800 ppm Au), producing approximately 5 to 15 percent of the total Au mined in the deposit.Geochemical studies of samples collected across traverses of altered and mineralized ore zones indicate that Te, Bi, and Pb are characteristic trace elements, in addition to Au, Ag, Cu, and As that are typical of acid sulfate mineral deposits. Anomalous Te is associated with Cu sulfides and gold in vuggy silica zones. Anomalous Bi and Pb concentrations correlate most consistently with quartz-alunite zones. Thallium is also anomalous at Summitville. Highest concentrations of Tl are found in argillic rock, whereas silicified zones are depleted in it. The anomalous Tl in distal zones is similar to observations in some porphyry Cu systems. Pronounced lateral zonation of Ag/Au ratios is present in the deposit. The Ag/Au ratios vary from about 2:1 near the center of the orebody to greater than 20:1 on the periphery.The Summitville deposit is located in the midlevel portion of a mineralized volcanic dome, with a porphyry system at depth, and a hot springs environment at the surface. Drill holes through the volcanic dome intersected a quartz monzonite porphyry approximately 600 m below the surface that is altered to sericite and pyrite similar to some porphyry deposits. Laterally extensive cristobalite and opal replacing quartz latite are found southwest of the deposit and represent a hot-spring environment. Bedded siliceous sinter, some of which contains plant debris, overlies the cristobalite and opal at some localities. These deposits may represent surface vents for the fluids responsible for acid sulfate alteration or mineralization of the volcanic dome.

Economic Geology↗

Sedimentary exhalative nickel-molybdenum ores in south China

Unique bedded Ni-Mo ores hosted by black shales were discovered in localized paleobasins along the Yangzte platform of southern China in 1971. Textural evidence and radiometric dates imply ore formation during sedimentation of black shales that grade into readily combustible beds, termed stone coals, which contain 10 to 15 percent organic carbon. Studies of 427 fluid inclusions indicate extreme variation in hydrothermal brine salinities that were contained by Proterozoic dolostones underlying the ore zone in Hunan and Guizhou. Variations of fluid inclusion salinities, which range from 0.1 to 21.6 wt percent NaCl equiv, are attributed to differences in the compositions of brines in strata underlying the ore bed, complicated by the presence of sea-water and dilute fluids that represent condensates of vapors generated by boiling of mineralizing fluids or Cambrian meteoric water. The complex processes of ore deposition led to scattered homogenization temperatures ranging from 100 degrees to 187 degrees C within the Hunan ore zone and from 65 degrees to 183 degrees C within the Guizhou ore zone. While living organisms probably did not directly accumulate metals in situ in sufficient amounts to explain the unusually high grades of the deposits, sulfur isotope ratios indicate that bacteria, now preserved as abundant microfossils, provided sufficient sulfide for the ores by reduction of seawater sulfate. Such microbiota may have depended on vent fluids and transported organic matter for key nutrients and are consistent with a sedex origin for the ores. Vent fluids interacted with organic remains, including rounded fragments of microbial mats that were likely transported to the site of ore deposition by the action of waves and bottom currents prior to replacement by ore minerals.

Economic Geology↗

Lithium anomaly near Pringle, southern Black Hills, South Dakota, possibly caused by unexposed rare-mineral pegmatite

Six samples of biotite schist from a site near Pringle, South Dakota, contained from 140 to 750 parts per million lithium. These values are far greater than are found in mica schists in most of the rest of the southern Black Hills. The lithium may have emanated from concealed lithium pegmatite, and such pegmatite can be of interest as a possible source of rare minerals, especially tantalite and beryl. Whether making a full test of the anomaly will become economically judicious is much less clear.

Circular↗

Rare earth elements on the Moon

Rare earth elements (REEs) are a scarce but vital resource for our modern economies and lifestyles. Since the late 1990s, China has supplied the vast majority of the world’s refined REEs. Increasing global demand has broadened the search for REE deposits to unconventional places, including the Moon. Although most lunar rocks have very low REE concentrations, Apollo samples showed that one type of lunar rock containing potassium (K), REEs, and phosphorus (P)—known by the acronym KREEP—has high concentrations of REEs. Data from orbiting satellites have identified locations where substantial deposits of KREEP are likely. The viability of mining these deposits depends on the evolution of REE economics, the development of the Earth-Moon infrastructure, and the findings from future lunar mineral exploration missions.

Fact Sheet↗