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Favorability mapping for hydrothermal power resource assessments of the Great Basin, USA

The U.S. Geological Survey (USGS) is updating the 2008 assessment of conventional hydrothermal resources for the Great Basin in the western United States. As part of this work, the workflow for hydrothermal resource favorability maps is being modified to integrate modern data-driven machine learning (ML) methods. Improvements include: [1] using new and refined evidence layers (features); [2] using an order of magnitude more training sites (labeled examples); [3] utilizing simple but non-linear supervised ML algorithms; [4] representing positive training sites (wells with measured heat flow) with their ordinal value proportional to the magnitude of convective upflow (i.e., low, high, or very high convective signals instead of past strategies using positive-negative labels); [5] supplementing training sites with additional sites with low convective signals to represent diverse under-sampled areas where hydrothermal systems are unlikely to exist; [6] comparing with competing approaches; and [7] utilizing Monte Carlo cross-validation to estimate and evaluate prediction uncertainty. For the new favorability map, over half of the power-producing systems (i.e., 15 of 28) are predicted in the 99th percentile of most favorable locations (i.e., the highest 1 % of favorability, corresponding to 1 % of the map area), exceeding the performance of past models that have explicitly used power plants as training sites. Previous favorability maps predicted approximately half of the power-producing hydrothermal systems above the 80th percentile (i.e., 20 % of the map area). For the new favorability map, 93 % of power-producing systems (i.e., 26 of 28) are above the 80th percentile. The power-producing systems for which the new model does not perform well are either comparatively small, low-temperature systems or systems also not predicted well by prior modeling approaches, suggesting that these few systems are unusual when compared with most power-producing systems. Focusing research on these known, seemingly different systems may yield new insights and subsequent discovery of new prospects.

California, Idaho, Nevada, Oregon, Utah

An empirical Green’s function approach for isolating directivity effects in earthquake ground-motion amplitudes

In this study, we apply an empirical Green’s function (eGf) method within a ground‐motion modeling framework to mitigate trade‐offs between source, path, and site effects. Many physical processes contribute to spatial variations in observed ground motions, including earthquake radiation pattern, directivity, variable path attenuation, and site effects. Current nonergodic ground‐motion models use spatially varying coefficients for path and site effects, but they do not address trade‐offs with complex earthquake source effects. To quantify the influence of directivity on ground‐motion amplitudes, we use records from multiple smaller earthquakes with epicenters near that of a larger event. We use these small magnitude events as eGfs and estimate repeatable path and site effects at individual stations, assuming that the average adjustments are not controlled by directivity. We adjust residuals from the larger earthquake using the eGf terms, isolating effects related to the rupture. This method clearly enhances the observed broadband directivity observed in the 2022 M 5.1 and 2007 M 5.4 Alum Rock earthquake ground motions, reinforcing the conclusion that their ruptures were unilateral. For the 2004 M 6.0 Parkfield earthquake, we find a bilateral rupture model better fits the data because variations in rupture velocity, slip rate, and slip distribution seem to have a stronger effect on the ground motions than rupture direction alone. Applying eGf adjustments reduces the standard deviation of the rupture models over the three earthquakes by 32% on average and by up to 57% for the 2022 Alum Rock earthquake, confirming we have effectively removed repeatable effects related to the wave propagation path and site response. We propose a novel measure of the frequency‐dependent directivity amplification strength as the reduction in ground‐motion residual variability gained by fitting a directivity model; for the three earthquakes considered, this parameter varies between 25% and 75%, indicating that directivity can strongly influence ground motions and should be considered in ground‐motion modeling.

California

Time-varying rates of organic and inorganic mass accumulation in southeast Louisiana marshes: Relationships to sea-level anomalies and tropical storms

Louisiana's coastal wetlands are complex systems that require a continuous input of organic and inorganic material to keep pace with relative sea-level rise. Coastal restoration projects such as sediment diversions are being implemented to mitigate land loss and increase availability of inorganic sediment to coastal wetlands, and marshes specifically rely on organic material to build soil volume and maintain surface elevation. Interannual-to-decadal sea-level anomalies such as hurricanes can affect marsh accretion, mineral deposition, and plant productivity. In this light, complex ecogeomorphic feedback controls whether a marsh surface is sustainable or eroded/drowns. This study performs some of the first differential vertical accretion rates (VARs) and organic and inorganic mass accumulation rates (MARs) over time in SE Louisiana marshes determined from the 210 Pb Constant Rate of Supply model, coupled with standard 137 Cs VARs. These accumulation rates over the past ∼100 years were measured from a total of six brackish and salt marsh locations in Barataria Basin near the proposed Mid-Barataria Sediment Diversion. They were then related to interannual sea-surface elevations at Grand Isle, Louisiana, over the last ∼60 years and recorded hurricane activity in the delta. Results show VARs range from 0.63 cm/y to 1.69 cm/y and total MARs range from 0.11 to 0.43 g/cm 2 /y. Temporally, VARs and MARs (total, inorganic, and organic) are characterized by gradual increases in rates with decreasing age along with episodic peaks in VARs and MARs. The findings of this study indicate that no relationship occurs between sea-level anomalies and VARs or organic and inorganic MARs; however, a strong relationship appears to occur between major hurricanes to VAR and MAR contributions. Furthermore, high water content (81 ± 8%) and organic-rich soils in the sediment cores highlight the significance of belowground biomass and associated pore volume in maintaining marsh elevation in the study area.

Louisiana

Peak streamflow trends in South Dakota and their relation to changes in climate, water years 1921–2020

Peak-flow (flood) frequency analysis is essential to water-resources management applications, including the design of critical infrastructure such as bridges and culverts, and floodplain mapping. Federal guidelines for performing peak-flow flood frequency analyses are presented in a U.S. Geological Survey Techniques and Methods Report known as Bulletin 17C. A basic assumption within Bulletin 17C, which documents the guidelines for determining annual peak streamflow frequency, is that, for basins without major hydrologic alterations (for example, regulation, diversion, and urbanization), statistical properties of the distribution of annual peak streamflows are stationary; that is, the mean, variance, and skew are constant through time. Nonstationarity is a statistical property of a peak-flow series such that the long-term (on the order of decades) distributional properties change one or more times either gradually or abruptly through time. Individual nonstationarities may be attributed to one source such as flow regulation, land-use change, or climate but are often the result of a combination of sources, making detection and attribution of nonstationarities challenging. In response to a growing concern regarding nonstationarity in peak streamflows in the region, the U.S. Geological Survey, in cooperation with the Departments of Transportation of Illinois, Iowa, Michigan, Minnesota, Missouri, South Dakota, and Wisconsin; the Montana Department of Natural Resources and Conservation; and the North Dakota Department of Water Resources, assessed the potential nonstationarity in peak streamflows in the north-central United States. This chapter characterizes the effects of natural hydroclimatic shifts and potential climate change on annual peak streamflows in the State of South Dakota. Annual peak and daily streamflow as well as model-simulated gridded climatic data were examined for temporal monotonic trends, change points, and other statistical properties indicative of changing climatic and environmental conditions. Changes in annual peak and daily flows were evaluated among 13, 35, and 81 qualifying U.S. Geological Survey streamgages for the 75-, 50-, and 30-year trend periods through water year 2020 (the period from October 1, 2019, to September 30, 2020) in South Dakota, respectively. No qualifying streamgages were in the 100-year trend period in the State. Statistical tests for autocorrelation (independent and identically distributed assumption), monotonic trends, and change points in the median and scale are analyzed to evaluate potential stationarity violations (nonstationarity) for performing at-site peak-flow flood-frequency analysis. The trends are reported using a likelihood approach as an alternative to simply reporting significant trends with an arbitrary p -value cutoff point. A distinct east-west spatial pattern of likely upward and downward monotonic trends and change points, respectively, was detected in 75- and 50-year trend periods, but an inconsistent spatial pattern was detected in the 30-year trend period. Additionally, change points in the median annual peak streamflows were detected in the late 1970s and early 1980s in the western part of the State, but in the east, the change point was more commonly detected in 1992–93. A similar east-west spatial pattern of likely upward and downward trends was detected in the annual peak-flow timing, the day of the year of the annal peak streamflow. In the western part of the State, the annual peak streamflows are arriving earlier, but in the east, the annual peak streamflows are arriving later. A peaks-over-threshold (POT) analysis where, on average, there are two events per year (POT2) and four events per year (POT4) was also used to evaluate changes in the frequency (count) of daily streamflows exceeding the threshold. Similar to detected changes in the annual peak streamflow, an east-west likely upward or downward change corresponding to an increase or decrease, respectively, in the frequency of daily streamflow greater than a POT2 and POT4 threshold was detected. A monthly water-balance model was used to evaluate hydroclimatic variation in annual and seasonal precipitation, snowfall, potential evapotranspiration, and soil moisture storage for all qualifying streamgages in the 75-, 50-, and 30-year trend periods. Detected trends in the annual hydroclimatic metrics for the 75- and 50-year trend periods indicate a spatially consistent statewide increase in precipitation, decrease in snowfall, increase in potential evapotranspiration, and increase in soil moisture storage. Furthermore, detected trends in seasonal precipitation in the 75- and 50-year trend periods highlight a pronounced change in precipitation in winter and later into the summer season, especially in the 50-year trend period in the eastern part of the State. Statewide increases in seasonal soil moisture storage were also detected, highlighting year-round increasing flood magnitudes, particularly in the eastern part of the State. Based on the results of these stationarity tests for the qualifying streamgages in South Dakota among the 75-, 50-, and 30-year trend periods, consistent temporal and spatial patterns of nonstationarity were detected among the 75- and 50-year trend periods. Furthermore, when nonstationarity is detected in daily streamflow, increased streamflow and volume (increasing frequency in POT), as well as potentially bridge scour, may have implications on culvert and highway design in the eastern part of South Dakota. Thus, when performing at-site peak-flow flood-frequency analyses in South Dakota, potential nonstationarities and alternative approaches are important considerations.

South Dakota

Exploring landscape and geologic controls on spatial patterning of streambank groundwater discharge in a mixed land use watershed

Preferential groundwater discharge features along stream corridors are ecologically important at local and stream network scales, yet we lack quantification of the multiscale controls on the spatial patterning of groundwater discharge. Here we identify physical attributes that best explain variation in the presence and lateral extent of preferential groundwater discharges along two 5th order streams, the Housatonic and Farmington Rivers, and 32 1st to 4th order reaches across the Farmington River network. We mapped locations of preferential groundwater discharge exposed along streambanks using handheld thermal infrared cameras paired with high-resolution topographic and land use land cover datasets, surficial soil characteristic maps, and depth-to-bedrock geophysical measurements. The unconfined Housatonic River, MA, USA (12 km) had fewer discharge locations and less lateral extent (41 discharge locations with 38 m of active discharge/km of river) compared to the partially confined Farmington River, CT, USA (26 km; 169 discharge locations with 129 m of active discharge/km of river). Using a moving window analysis, we found along both rivers that discharge was more likely to occur where bank slopes were steeper, floodplain extent was narrower, and degree of confinement was higher. Along the Farmington River, groundwater discharge was more likely to occur where saturated hydraulic conductivity was higher and depth-to-bedrock was shallower. Among the 32 stream reaches surveyed (33.2 km of total stream length) within the Farmington River watershed, preferential discharge was observed in all but two stream reaches, varied from 0 to 25% of lateral extent along stream banks (mean = 6%), and was more likely to occur where stream reach slopes were steep, saturated hydraulic conductivity was high, and watershed urbanization was low. Our results show that, though both surface (e.g., topographic, land use land cover) and subsurface (e.g., soil characteristics, bedrock depth) factors control the prevalence of streambank preferential groundwater discharge, the dominant controls vary across valley settings and stream sizes.

Connecticut, Massachusetts

Monitoring and assessment of urban stormwater best management practices at selected Chicago public schools in Chicago, Illinois, from September 1, 2016, to July 1, 2017

The Space to Grow program helps transform aging and neglected schoolyards of Chicago Public Schools into outdoor community spaces with the goal of promoting health and learning while addressing neighborhood flooding issues. Virgil I. Grissom Elementary School and Donald L. Morrill Math and Science School were selected in 2014 for schoolyard upgrades and the installation of various green infrastructure (GI) improvements. The U.S. Geological Survey installed sensors to measure precipitation, groundwater levels, and stormwater runoff volumes from September 1, 2016, to July 1, 2017. At Virgil I. Grissom Elementary School, about 933,000 gallons of water fell on the schoolyard during the monitoring period. No discharge was recorded coming from the GI sewer lines, but backflow indicated water was flowing from the sewer line draining the impervious running track into the combined manhole structure and backwards into the GI retention basins (as designed). This design allowed for a 100-percent capture rate. Native soil at Virgil I. Grissom Elementary School also was conducive to rapid infiltration. Soil borings at Virgil I. Grissom Elementary School indicated about 10.5 feet (ft) of fine sand overlying silty clay to a depth of at least 16 ft. At Donald L. Morrill Math and Science School, about 1,120,000 gallons of water fell on the schoolyard during the monitoring period. About 72.5 precent of this water was discharged into the sewer system, and the other 27.5 percent was captured by the GI. Unlike Virgil I. Grissom Elementary School, the soil profile at Donald L. Morrill Math and Science School consisted of about 5 ft of clay loam overlying stiff blue clay to a depth of at least 12 ft. The sewer line coming from the GI under the football field was at the bottom of the reservoir. This design seemed to allow water to flow out of the line before being absorbed by the retention basin.

Illinois

Development of liquefaction-targeted design basis in U.S. seismic provisions

Seismic design criteria for new buildings in the United States have historically focused on life safety performance objectives through minimizing the potential for structural collapse. Development of design criteria to meet this performance objective has evolved over time, leading to the current, risk-targeted maximum considered earthquake (MCE R ) design basis. Corresponding MCE R seismic design loads incorporate the full range of probabilistic ground motion hazard information available from U.S. Geological Survey National Seismic Hazard Models, as well as a representation of the uncertainty in structural collapse capacity. Despite these considerable advances in structural design criteria, guidelines for geotechnical hazards such as liquefaction-induced damage, which continue to be based on uniform ground-shaking hazard (i.e., MCE ground motions), are not well-connected with risk-based, collapse prevention performance objectives. This study, undertaken as part of Building Seismic Safety Council efforts to update recommended seismic provisions through the National Earthquake Hazards Reduction Program, presents probabilistic, liquefaction-targeted design objectives and corresponding ground motion parameters, with a focus on improving consistency in first-level screening criteria for liquefaction hazard assessment. This study identifies a potential maximum acceptable annualized probability of liquefaction triggering ( P L,max ) of 2.5% in 50 years, above which liquefaction consequences and potential mitigation measures would be considered. The P L,max -based design basis is calibrated to effective probabilistic liquefaction hazard levels obtained in practice using current MCE peak ground accelerations, and could be implemented via a new liquefaction-targeted maximum considered earthquake (MCE L ) peak ground acceleration ( PGA L ). The proposed PGA L is derived from probabilistic liquefaction hazard curves and includes uncertainties inherent to liquefaction hazard modeling. The potential design effects of the proposed PGA L are demonstrated via comparison with current MCE PGA levels, effects on first-level liquefaction screening analyses, and improvements in the consistency of P L,max levels across the United States, and for a wide range of site conditions.

conterminous United States

Groundwater flowpath characteristics drive variability in per- and polyfluoroalkyl substances (PFAS) loading across a stream-wetland system

Groundwater-dependent ecosystems in areas with industrial land use are at risk of exposure to a PFAS chemicals. We investigated one such system with several known PFAS source areas, where high and low permeability sediments (glacial) coupled with groundwater-lake and groundwater/surface-water interactions created complex ‘source to seep’ dynamics. Using heat-tracing and chemical methods, numerous preferential groundwater discharge zones were identified and sampled across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, downgradient of Joint Base Cape Cod (JBCC). Surface-water and groundwater samples were analyzed for 40 PFAS compounds between March and October 2022. Samples were collected from groundwater seeps identified as preferential discharge points (PDPs), wells upgradient of the stream-wetland system, contributing flow-through kettle lakes, and along Quashnet River surface-waters. PFAS from sampled waters contained perfluorinated carboxylates (PFPea, PFHxA, PFNA), perfluorinated sulfonates (PFBS, PFPeS, PFHxS, PFOS), fluorotelomer sulfonates (6:2, 8:2 FtS), and perfluoroalkyl sulfonamides (PFOSA). Samples from PDPs and wells had measured PFAS concentrations ranging from non-detect to 4677 ng/L ng/L (mean = 418 ng/L, std. = 709 ng/L), and a range of deuterium excess values (3.2 to 15.9 per mil) indicative of varying degrees of groundwater-lake interaction prior to groundwater flowpath emergence at PDPs. Correlations ( p < 0.01) between deuterium excess, %PFAS precursors, and terminal PFAS compounds highlighted potential precursor transformations associated with lake-groundwater exchange along flowpaths sourcing PDPs. However, some seepages had higher total PFAS concentrations (>1000 ng/L) than upgradient kettle lakes despite showing lake (evaporative) isotopic signatures, indicating the potential for groundwater flowpath convergence at wetland discharge zones and the influence of lakebed PFAS precursor reactions. Results from these synoptic surveys address gaps in the existing PFAS literature by demonstrating the importance of subsurface fate and transport on PFAS compound concentrations and mass loading in preferential groundwater discharge zones.

Massachusetts

A novel drive-point multilevel system to investigate PFAS and other contaminants of global concern in the hyporheic zone of a wastewater effluent dominated stream

Contaminants found in treated wastewater discharged to streams, including pharmaceuticals and per- and polyfluoroalkyl substances (PFAS), are of global concern due to their deleterious effects on aquatic ecosystems and potential impacts to human health. Hyporheic zones have strong potential for contaminant attenuation. Assessing this potential requires collection of physical and biogeochemical data within the hyporheic zone. This study tested the applicability of a novel drive-point multilevel system (DP-MLS) for quantifying head profiles and characterizing contaminant concentrations in the hyporheic zone of a temperate region effluent dominated stream (EDS). DP-MLS, each with 4 ports, were installed in the stream bed at two sites, DS-1 and DS-2, 0.2 and 4.7 km downstream of the effluent outfall, respectively. Head profiles were measured and groundwater collected for analysis of pharmaceuticals and PFAS temporally over two years. The DP-MLS withstood rapid changes in stage, ice formation, and floating debris. Vertical hydraulic gradients (VHG) were generally upward but varied in magnitude indicating heterogeneity in hydraulic conductivity and variability in flow conditions. Upward VHG were also about 2X larger at DS-1 than at DS-2. Contaminant concentration profiles consistently showed penetration of pharmaceuticals and PFAS to 1 m below the bed at DS-2 while there was less penetration, lower groundwater concentrations, and more temporal variability in concentrations at DS-1. Integration of the physical and chemical data suggests weaker upwelling conditions at DS-2 are more easily reversed during periods of high stream stage, which could facilitate migration of wastewater contaminants into the bed. However, further studies incorporating other transport processes and reach scale dynamics are required to fully characterize these exchanges. Overall, this study demonstrates the efficacy of these novel DP-MLSs for characterization of the hyporheic zone and provides new insights into the occurrence, composition, and persistence of wastewater derived contaminants in the hyporheic zone of a well-studied EDS.

Iowa

Geophysical characterization of mine influenced groundwater and surface water in the Mayflower section of the Animas River, Bonita Peak Mining District, Silverton Colorado

This report details findings from geophysical investigations to identify possible groundwater - surface water interactions near the Mayflower Section of the Animas River in Silverton, Colorado. The Mayflower Section is a mine influenced Superfund Site in Colorado. This investigation utilized electromagnetic induction (EM or EMI), magnetic, and fiber optic distributed temperature system (FODTS) geophysical methods to measure the bulk earth electrical conductivity, magnetic susceptibility, and temperature of specific surveyed volumes of the earth near the Mayflower Section of the Animas River. These physical parameters are used to understand the groundwater – surface water interactions, which can guide decision makers in their assessment of mine-impacted surface water. This report details the results from characterization and monitoring technologies to provide high data density and continuous monitoring of bulk earth electrical conductivity and temperature in the Mayflower section of the Animas River to identify zones of groundwater – surface water interactions and potential metal loading from mine influenced water. The investigation separated right and left bank characterization for each method and indicates more groundwater is entering from the right bank than the left bank and these predominantly right bank discharges potentially contain metal-rich water compared to the left bank. Results also indicate mineral veins facilitate preferential groundwater discharge to the river due to possible jointing, fractures, and permeability differences sometimes occurring along veins relative to host rock. For example, Boulder Gulch is likely groundwater dominated and may be receive water impacted by Mayflower Impoundments #1 and #2. Additionally, the beaver ponds near Blair Gulch may influence groundwater discharge and Mayflower Impoundment #4 is possibly impacting groundwater and surface water and may be connected to the wetlands to the west of the impoundment. These data could be further analyzed for smaller spatial scale analysis within areas of interest. The identification of these locations along sections of the river likely impacted by mine influenced groundwater potentially entering the Animas River and can be used by site investigators, decision makers, and stakeholders in mitigation decisions and strategies.

Colorado

On-orbit calibration and performance of the EMIT imaging spectrometer

The Earth surface Mineral dust source InvesTigation (EMIT) is a remote visible to shortwave infrared (VSWIR) imaging spectrometer that has been operating onboard the International Space Station since July 2022. This article describes EMIT's on-orbit spectroradiometric calibration and validation. Accurate spectroscopy is vital to achieve consistent mapping results with orbital imaging spectrometers. EMIT takes a unique approach to this challenge, with just six optical elements, no shutter, and no onboard calibration systems. Its simple design focuses on uniformity and stability to enable vicarious spectroradiometric calibration. Our experiments demonstrate that this approach is successful, approaching the fidelity of manual field spectroscopy in some cases, and enabling new and more accurate products across diverse Earth science disciplines. EMIT achieves several notable firsts for an instrument of its class. It demonstrates successful on-orbit adjustments of Focal Plane Array (FPA) alignment with sub-micron precision. It offers spectral uniformity better than 98%. Optical artifacts in the measurement channels are at least three orders of magnitude below the primary solar-reflected surface signals. Its noise performance enables percent-level discrimination in the depths of mineral absorption features. In these aspects, EMIT satisfies the stringent performance needs for the next generation of VSWIR imaging spectrometers to observe the Earth's ecosystems, geology , and water resources.

Remote Sensing of Environment

Groundwater quality near the Placerita Oil Field, California, 2018

Groundwater-quality data and potential fluid-migration pathways near the Placerita Oil Field in Los Angeles County, California, were examined by the U.S. Geological Survey to determine if oil-field fluids (water and gas from oil-producing and non-producing zones) have mixed with groundwater resources. Six of the 13 new groundwater samples collected for this study contained petroleum hydrocarbons, thermogenic gas, inorganic chemical signatures, and (or) isotopic values consistent with potential mixing with fluids from hydrocarbon-bearing formations. For historical groundwater samples, benzene was the most detected petroleum hydrocarbon. The historical groundwater samples with a benzene concentration greater than 0.5 micrograms per liter were from environmental monitoring wells at industrial or commercial facilities unrelated to oil and gas development that, in many cases, have identified soil or groundwater contamination and were not typically analyzed for other constituents that could provide additional lines of evidence for potential mixing with oil-field fluids. Methane was not detected in any of the 12 historical samples with a reported measurement. Reviewing historical data revealed factors that could potentially adversely affect groundwater quality in the study area. These factors include modified hydraulic gradients caused by large volumes of water extracted from the main production area and reinjected downgradient into nonproducing zones, well-barrier failures in wells constructed in the northern part of the oil field before the 1970s, well-barrier failures in produced-water disposal wells downgradient from the main production area, and naturally occurring hydrocarbons at shallow intervals. The groundwater samples most geochemically similar to samples from hydrocarbon-bearing formations were in areas where hydrocarbons are naturally occurring at shallow intervals and where oil development is at shallow depths. Additional data for hydraulic heads, water quality, and formation temperatures at multiple depths in areas with large injection volumes and well-integrity issues are needed to evaluate whether those factors have contributed to mixing between fluids from oil-producing or injection formations and groundwater resources.

California

Geomorphic map of the Umatilla River corridor, Oregon

This map portrays the distribution of landforms along the Umatilla River in northeastern Oregon and covers a corridor 127 kilometers long from the confluence of the Umatilla River with the Columbia River upstream to Meacham Creek. The map encompasses the valley bottom and extends about 1 kilometer up the adjoining hillslopes. Map data are intended to support water quality and fisheries enhancement efforts pursuant to the First Foods, a resource-management approach that focuses on traditionally gathered foods including water, fish, big game, roots, and berries and calls attention to the reciprocity between people and the foods upon which humans depend. The Umatilla River drains about 6,300 square kilometers on the northwest slope of the Blue Mountains in northeast Oregon. Most of the drainage basin is underlain by Miocene basalt flows of the Columbia River Basalt Group. Younger, weakly lithified, late Miocene and early Pliocene gravel deposits of local origin (for example, McKay Formation) are mapped in a few places. Upland surfaces are mantled with windborne silt (loess) correlative with deposits elsewhere known as the Palouse Formation. Surfaces below an elevation of about 340 meters were inundated repeatedly by large Pleistocene glacial outburst floods, most emanating from glacial Lake Missoula in western Montana. In backflooded areas such as the lower Umatilla River valley, Missoula floods deposited extensive slack-water silt. Areas mapped as open water, active channel and tie channel, flood basin, valley bottom, and modified land constitute the geomorphic floodplain: the area subject to occasional inundation by the Umatilla River. Deposits and landforms within the floodplain are inset into Missoula flood deposits and hence postdate the 20–15-kilo-annum Missoula floods. Some floodplain deposits are no more than a few centuries old, as indicated by substantial erosion and deposition during the Umatilla River flood of February 2020, the largest since systematic measurements began in October 1903. Deposits and landforms of the floodplain are transient features within the longer-term incision of the Umatilla River into mid-Miocene flood basalts and younger gravel of the McKay Formation.

Oregon

Relating systematic molecular and textural properties of graptolite pyrolyzed via gold tube hydrous pyrolysis: Implications for thermal proxies in lower Paleozoic marine shales

A series of gold tube pyrolysis experiments (72 h, 300–550 °C, 50 MPa) conducted on a graptolite-rich lower Paleozoic marine shale generated pyrolysis residues for a comprehensive evaluation of the molecular and structural variability of three types of graptolite periderm. Organic petrology, Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM) with energy dispersive spectroscopy (EDS) were combined to evaluate the thermal evolution process. The three types of graptolite periderm, namely granular, non-granular, and nodular graptolite, were analyzed by Raman spectroscopy wherein point measurements were obtained after the maceral was identified and the location verified by organic petrology. Distinct thermal evolution pathways among non-granular, granular, and nodular graptolite periderms were recorded. The evolution patterns of the Raman parameters, particularly D1 and G bands, highlight the differences in geochemical composition of the graptolite periderm types and the alteration of molecular structure with increasing thermal maturity. Raman parameters D1 (position of the D1 peak), G-FWHM (full width at half maximum of the G peak), and ratios D1-FWHM/G-FWHM (full width at half maximum of the D1 peak ratioed to G-FWHM) and A D1 /A G (ratio of D1 and G peak intensities) showed effectiveness in assessing thermal maturity. Bireflectance with increasing gold tube pyrolysis temperature followed a hierarchy: non-granular > granular > nodular, reflecting different molecular alignment intensities. Qualitative FE-SEM evaluation showed that fine-grained mineral inclusions (primarily Fe-sulfide as determined via EDS) were associated with the graptolite populations, with granular graptolite containing greater amounts of coarser-grained (e.g., ∼300–1400 nm) mineral inclusions relative to non-granular and nodular graptolite, which contain finer-grained (e.g., ∼100–200 nm) inclusions difficult to resolve with optical microscopy. These findings are investigated to highlight the mechanisms that drive organic matter evolution within graptolite during thermal maturation, as well as to explore some of the limitations of using spectroscopic parameters as thermal maturity proxies.

International Journal of Coal Geology

Methodology for inclusion of produced and stored carbon dioxide in the U.S. Geological Survey Federal lands greenhouse gas inventory

The U.S. Geological Survey (USGS) has developed two new carbon dioxide (CO2) emissions and sequestration accounting methods for use in future reports. The first method is a Federal lease-produced CO2 emissions calculation for an update of the report, “Federal Lands Greenhouse Gas Emissions and Sequestration in the United States.” The methodology to incorporate Federal lease CO2 production emissions into the updated report relies on CO2 sales royalty data from the Office of Natural Resources Revenue (ONRR). The end usage points for the gas include enhanced oil recovery with CO2 (CO2-EOR), food and beverage, and chemical production. CO2-EOR is the main end point for natural CO2 production in the United States; it accounted for 94% of usage in 2022 [1]. Federal lands emissions from this sector are estimated at 460 metric tons of CO2 in 2022, a very small amount relative to most other Federal lands emissions sector estimates. The second new method, planned for a separate report, is a calculation of the geologic storage of CO2 on Federal lands. The second method estimates the CO2 stored under Federal surface lands and documents Federal climate change mitigation efforts. Currently, there is no storage of CO2 at an industrial level on Federal lands, however multiple proposals and projects are planned. This method was developed on non-Federal lands datasets in an effort to prepare for when these activities on Federal lands will require accounting. National estimates for CO2 geologic storage using this method, but without a Federal lands filtering step, totaled 8.0 million metric tons (Mt) in 2022. The two methods described here are new benchmark methods in a collection of accounting procedures to document the current state of greenhouse gas emissions and their storage on Federal lands. These benchmarks can then be used to measure any subsequent changes in emissions from or carbon storage beneath Federal lands. While the magnitude of the values is currently non-existent to small, emissions mitigation goals established by decision makers indicate that these values will grow, and their documentation will take on greater value and use.

continental United States

Beavers in the Tualatin River Basin, northwestern Oregon

Growing interest in beaver-assisted restoration in the Tualatin River Basin of northwestern Oregon motivated a series of studies by the U.S. Geological Survey to assess the capacity of the stream network to support beaver dams and to evaluate the effects of beaver dams and ponds on urban streams. This multichapter volume describes the data collection from 2016–17 and the findings of these studies, which were done in partnership with Clean Water Services. Chapter A documents the locations of beaver dams in the Tualatin River Basin and how many beaver dams the stream network could support with existing and improved riparian vegetation. Beaver dam capacity was estimated by modifying existing tools to account for the low gradient of many streams in the Tualatin River Basin. Chapter B describes the effects of beaver dams and ponds on hydrologic and hydraulic responses of storm flows. Hydrologic and hydraulic responses for two urban stream reaches were compared with and without beaver dams and ponds and for a range of streamflow conditions using two-dimensional hydraulic models. Chapter C characterizes the effects of beaver dams and ponds on the transport and deposition of suspended sediment. Continuous turbidity, discrete suspended-sediment samples, and streamflow measurements collected during storms and base-flow periods were used to assess: (1) suspended-sediment loads upstream and downstream from two beaver-affected reaches, and (2) seasonal and longitudinal turbidity patterns. Chapter D describes the effects of beaver dams and ponds on longitudinal, spatial, and seasonal water-quality patterns. Continuous and synoptic water-quality data were collected along urban stream reaches, and net ecosystem production was calculated for two beaver-affected reaches. The findings of these studies illustrate that the effects of beaver dams and ponds on hydrology, hydraulics, suspended-sediment transport and deposition, and water quality are dependent on the characteristics of a stream reach (for example, channel gradient, groundwater exchange, and riparian vegetation) and the characteristics of beaver dams and ponds along that reach. This information can be used to consider the implications of beaver-assisted restoration in the Tualatin River Basin and the effects of beaver dams and ponds in urban streams.

Oregon

Indications of preferential groundwater seepage feeding northern peatland pools

Groundwater seepage from underlying permeable glacial sedimentary structures, such as eskers, has been hypothesized to directly feed pools in northern peat bogs. These hypotheses directly contradict classical peat bog models for ombrogenous systems, wherein meteoric water is the sole water input to these systems. Variations in the underlying mineral sediment in contact with the peat imply that unrecognized hydrogeologic connectivity may exist with pools in northern peat bogs, particularly where high permeability materials are in contact with the peat. Seepage dynamics originating from these structural variations were investigated using a suite of thermal and hydrogeophysical methods deployed around pools in a peat bog of northeastern Maine, USA. Thermal characterization methods mapped anomalies that were confirmed as matrix seepage or preferential flow pathways (PFPs). Geochemical methods were employed at identified thermal anomalies to confirm upwelling of solute-rich groundwater. Conduits around pools were associated with surficial terminations of suspected peat pipes, based on the inference of pathways extending down into the peat, that focus flow through PFPs in the peat matrix. Discharge also occurred through the peat matrix adjacent to suspected pipe structures and matrix seepage rates were quantified using analysis of diurnal temperature signals recorded at multiple depths. Seepage rates, with a maximum of nearly 0.4 m/d, were measured at localized points around pools. Periods of synchronized temperatures paired with highly muted diurnal temperature signals, recorded in diurnal temperature with depth data, were interpreted qualitatively as activation of strong upward discharge rates through suspected peat pipes. These time periods correlated strongly with local precipitation events around the peatland. Ground-penetrating radar surveys revealed discontinuities in the low permeability glacio-marine clay at the mineral sediment-peat interface, interpreted to be regional glacial esker deposits, which were located beneath and around pools. Heat tracing, specific conductance contrasts, seepage rates, and trace metal concentrations all imply groundwater seepage originating from underlying permeable glacial esker deposits and directly sourcing pools. Preferential groundwater inputs into northern peat bogs may play a key role in developing and maintaining pool systems, with enhanced solute transport impacting peatland ecology, water resources, and carbon cycling.

Maine

Characterization of the hydrogeologic framework, groundwater-flow system, geochemistry, and aquifer hydraulic properties of the shallow groundwater system in the Wilcox and Lorraine process areas of the Wilcox Oil Company Superfund site near Bristow, Oklahoma, 2022

The Wilcox Oil Company Superfund site (hereinafter referred to as “the site”) was formerly an oil refinery northeast of Bristow in Creek County, Oklahoma. Historical refinery operations contaminated the soil, surface water, streambed sediments, alluvium, and groundwater with refined and stored products at the site. The Wilcox and Lorraine process areas are where the highest concentrations of volatile organic compounds, semivolatile organic compounds, polycyclic aromatic hydrocarbons, and trace elements (including metals) (collectively hereinafter referred to as “contaminants”) were measured in a local shallow perched groundwater system within the alluvium (hereinafter referred to as the “alluvial aquifer”) at the site during previous site assessments. In order to understand the potential migration of contaminants through the soil and groundwater in these areas, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, investigated aquifer characteristics of the alluvial aquifer in the Wilcox and Lorraine process areas of the site to (1) document hydraulic conductivity and other aquifer characteristics of the alluvial aquifer that govern contaminant fate and transport, (2) describe the geospatial extent and concentration of the contaminants in the alluvial aquifer in the Wilcox and Lorraine process areas, and (3) describe the geochemical controls pertaining to oxidation and reduction governing the fate and transport and the degradation potential of contaminants in the groundwater. Various data were compiled and collected to evaluate the aquifer characteristics at the site including the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer. A total of 20 new (2022) groundwater monitoring wells were installed at the site to collect data used to supplement groundwater-level altitude and groundwater-quality data collected from older, existing groundwater monitoring wells and piezometers. Data compiled and collected for the study were used to evaluate the characteristics of the alluvial aquifer at the site. These aquifer characteristics are defined by the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer.

Oklahoma