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Documentation for the MODFLOW 6 Groundwater Flow Model

This report documents the Groundwater Flow (GWF) Model for a new version of MODFLOW called MODFLOW 6. The GWF Model for MODFLOW 6 is based on a generalized control-volume finite-difference approach in which a cell can be hydraulically connected to any number of surrounding cells. Users can define the model grid using one of three discretization packages, including (1) a structured discretization package for defining regular MODFLOW grids consisting of layers, rows, and columns, (2) a discretization by ver­tices package for defining layered unstructured grids consisting of layers and cells, and (3) a general unstruc­tured discretization package for defining flexible grids comprised of cells and their connection properties. For layered grids, a new capability is available for removing thin cells and vertically connecting cells overlying and underlying the thin cells. For complex problems involving water-table conditions, an optional Newton-Raphson formulation, based on the formulations in MODFLOW-NWT and MODFLOW-USG, can be acti­vated. Use of the Newton-Raphson formulation will often improve model convergence and allow solutions to be obtained for difficult problems that cannot be solved using the traditional wetting and drying approach. The GWF Model is divided into “packages,” as was done in previous MODFLOW versions. A package is the part of the model that deals with a single aspect of simulation. Packages included with the GWF Model include those related to internal calculations of groundwater flow (discretization, initial conditions, hydraulic conduc­tance, and storage), stress packages (constant heads, wells, recharge, rivers, general head boundaries, drains, and evapotranspiration), and advanced stress packages (streamflow routing, lakes, multi-aquifer wells, and unsaturated zone flow). An additional package is also available for moving water available in one package into the individual features of the advanced stress packages. The GWF Model also has packages for obtaining and controlling output from the model. This report includes detailed explanations of physical and mathematical concepts on which the GWF Model and its packages are based. Like its predecessors, MODFLOW 6 is based on a highly modular structure; however, this structure has been extended into an object-oriented framework. The framework includes a robust and generalized numeri­cal solution object, which can be used to solve many different types of models. The numerical solution object has several different matrix preconditioning options as well as several methods for solving the linear system of equations. In this new framework, the GWF Model itself is an object as are each of the GWF Model packages. A benefit of the object-oriented structure is that multiple objects of the same type can be used in a single sim­ulation. Thus, a single forward run with MODFLOW 6 may contain multiple GWF Models. GWF Models can be hydraulically connected using GWF-GWF Exchange objects. Connecting GWF models in different ways permits the user to utilize a local grid refinement strategy consisting of parent and child models or to couple adjacent GWF Models. An advantage of the approach implemented in MODFLOW 6 is that multiple models and their exchanges can be incorporated into a single numerical solution object. With this design, models can be tightly coupled at the matrix level.

Techniques and Methods↗

Parameter estimation at the conterminous United States scale and streamflow routing enhancements for the National Hydrologic Model infrastructure application of the Precipitation-Runoff Modeling System (NHM-PRMS)

This report documents a three-part continental-scale calibration procedure and a new streamflow routing algorithm using the U.S. Geological Survey National Hydrologic Model (NHM) infrastructure along with an application of the Precipitation-Runoff Modeling System (PRMS). The traditional approach to hydrologic model calibration and evaluation, which relies on comparing observed and simulated streamflow, is not sufficient for accurately representing the non-streamflow parts of the water budget. If intermediate process variables computed by the hydrologic model are not examined, the variables could be characterized by parameter values that do not replicate those hydrological processes present in the physical system. In answer to this potential problem, alternative hydrologic process variables from the model (in addition to streamflow) are included in a calibration procedure applied to the conterminous United States (CONUS) domain. The three-part calibration procedure presented in this report considers volume (calibration by hydrologic response unit [byHRU]), timing (calibration by headwater watershed [byHW]), and measured streamflow [byHWobs]). The first part, byHRU, is considered a water-balance volume calibration that uses five alternative (non-streamflow) hydrologic quantities (runoff, actual evapotranspiration, recharge, soil moisture, and snow-covered area) as calibration targets for each hydrologic response unit (HRU). These alternative data products were derived, with error bounds, from multiple sources for each of the 109,951 HRUs in the NHM on time scales varying from annual to daily. The second part of the calibration, byHW, is considered a streamflow timing calibration that uses statistically based streamflow simulations developed using ordinary kriging for 7,265 headwater watersheds that had drainage areas of less than 3,000 square kilometers (1,158 square miles) across the CONUS. Two streamflow routing algorithms were tested in this byHW calibration: (1) continuity without attenuation of the flood pulse and (2) a new formulation of the Muskingum routing method, which was added to the PRMS as part of this study. The third part of the calibration, byHWobs, refines the model parameters using available measured streamflow using 1,417 streamgage locations. A multiple-objective, stepwise, automated calibration procedure was used to identify the optimal set of parameters for each calibration procedure. Using a variety of alternative datasets for calibration of the water budget provides users of the NHM-PRMS with improved initial parameters and helps alleviate the equifinality problem (getting the right answer for the wrong reason). Through a community effort, these alternative data products, with error bounds, can be used to improve and expand our understanding of hydrologic-process representation in models. The broader modeling community can use these data products, with error bounds, to calibrate and evaluate hydrologic models using more than streamflow.

Conterminous United States↗

An improved method for isolating viruses from asymptomatic carrier fish

This paper describes a method using elevated levels of penicillin, streptomycin, and nystatin instead of filters to control bacteria and mold contaminants in specimens processed for virus isolation. Filters were shown to significantly reduce the virus concentration. Virus and tissue cultures were not affected by this procedure. In field tests nearly three times more specimens were positive for virus with this method than with the widely used filter technique. Moreover, the cost of materials was less. This method is recommended for inspection and certification purposes.

Transactions of the American Fisheries Society↗

Resource Assessment Economic Filter (RAEF)—A graphical user interface supporting implementation of simple engineering mine cost analyses of quantitative mineral resource assessment simulations

Economic evaluations of undiscovered mineral resources provide important context in which to consider the results of quantitative mineral resource assessments. The U.S. Geological Survey economic analysis method uses a simple engineering cost model approach developed by the U.S. Bureau of Mines that applies mine and mill engineering cost equations to simulated undiscovered deposits. The important characteristics of these deposits are derived from Monte Carlo simulations that combine probabilistic estimates of undiscovered deposits that might occur in a study area and a grade-tonnage model defined for a specific deposit type. This report describes the Resource Assessment Economic Filter (RAEF), a graphical user interface (GUI) tool that applies a set of mine cost equations to the deposits under consideration. RAEF, which is written in the open-source statistical programming language R, is an easy-to-use tool to apply user-defined mine, mill, and study area parameters to simulated deposits. For a given deposit type, it estimates the undiscovered resources that might be economic to extract. In addition, RAEF provides a series of graphical, tabular, and statistical summaries that document the results of the economic filter analysis.

Techniques and Methods↗

Oil and gas reclamation—Operations, monitoring methods, and standards

This publication provides broad guidance for surface management of oil and gas development with a focus on promoting successful reclamation. Successful reclamation depends on sound best management practices, clear standards and expectations, defensible monitoring for effectiveness, and management of production facilities to minimize surface disturbance. This publication provides specific guidelines for surface management of oil and gas, including operations, standards, and monitoring. The development of this report was guided by existing Federal reclamation policy, a review of the scientific and other literature, as well as practical field experience. Expertise was pulled from multiple sources including Federal and State agencies, oil and gas contractors, and academia. The target audience for this report is primarily operators and contractors conducting oil and gas activities on U.S. Federal or Tribal lands and the surface management agencies responsible for guiding and enforcing these activities. The guidance on surface management presented here will also be useful for managing oil and gas activities on State and private lands and where private land occurs over Federal mineral estate (split estate).

Techniques and Methods↗

Environmental DNA sampling protocol - filtering water to capture DNA from aquatic organisms

Environmental DNA (eDNA) analysis is an effective method of determining the presence of aquatic organisms such as fish, amphibians, and other taxa. This publication is meant to guide researchers and managers in the collection, concentration, and preservation of eDNA samples from lentic and lotic systems. A sampling workflow diagram and three sampling protocols are included as well as a list of suggested supplies. Protocols include filter and pump assembly using: (1) a hand-driven vacuum pump, ideal for sample collection in remote sampling locations where no electricity is available and when equipment weight is a primary concern; (2) a peristaltic pump powered by a rechargeable battery-operated driver/drill, suitable for remote sampling locations when weight consideration is less of a concern; (3) a 120-volt alternating current (AC) powered peristaltic pump suitable for any location where 120-volt AC power is accessible, or for roadside sampling locations. Images and detailed descriptions are provided for each step in the sampling and preservation process.

Techniques and Methods↗

Lunar grid systems, coordinate systems, and map projections for the Artemis missions and lunar surface navigation

Foreward This document contains design specifications of a navigational standard for the Moon, including a Lunar Transverse Mercator system, a Lunar Polar Stereographic system, a Lunar Grid Reference System, and a unique coordinate structure, Artemis Condensed Coordinates, for Artemis mission navigation and lunar surface science. The National Aeronautics and Space Administration (NASA) Artemis campaign seeks to place humans on the Moon for the first time since the Apollo missions. Early Artemis missions are heavily focused on the lunar south pole, which promises to return valuable data on the Moon’s geologic record, amongst other mission objectives. Coordinate systems in use today for the lunar south pole provides crew members on the surface neither an efficient nor intuitive means to communicate their position and orientation. A novel grid coordinate system, the Lunar Grid Reference System, is proposed to address these concerns for use in real-time extravehicular activity operations on the lunar surface. The many stakeholders involved in the Artemis missions will need a common system to communicate position and orientation while astronauts are operating on the lunar surface. To that end, Artemis crew members will need that system to be efficient and intuitive to promote efficient extravehicular activity timelines and reduce confusion. In the context of this document, these characteristics are addressed on the design of lunar coordinate systems: Efficient.—The number of characters required to communicate a location within a desired precision level in both local and global contexts, and how many steps are required for a recipient or sender to interpret a location. Intuitive.—How well the system aligns with human perceptual abilities, and whether the system yields distances that have the same relationship to actual lunar surface distance in all directions from the point where a person is located. Technological systems are currently being investigated to supplement the crew members’ ability to locate and orient themselves and other assets on the lunar surface; however, it is unlikely that those systems will be fully operational for the first few landed missions. Even with future positional aids, crew members will still need an efficient and intuitive means to communicate position and orientation. In addition, if technological systems fail, the crews will require land navigation skills and have maps available, thus providing further motivation for a crew-centric coordinate system. The contents of this U.S. Geological Survey (USGS) document detail a comprehensive framework for standardizing lunar crewed surface navigation within NASA and outlines the protocols, methods, and designs necessary for achieving consistency and interoperability across relevant space mission teams and lunar surface navigators. Key components of this document include designs of map projections, projected coordinate reference systems (Lunar Transverse Mercator and Lunar Polar Stereographic systems), and a grid system (Lunar Grid Reference System and Artemis Condensed Coordinates) for the Moon. The work proposed in this document seeks to accomplish something similar to the National Geospatial-Intelligence Agency (NGA) document SIG 0012 (NGA, 2014a), but for using grid systems for the Moon. This report incorporates initial feedback and input from NASA’s Artemis Geospatial Data Team, NASA’s Flight Operations Directorate, National Geodetic Survey, USGS Astrogeology Science Center, and NGA and is intended to serve as a resource for all involved with the Artemis missions, as well as for engineers designing and operating lunar infrastructure.

Techniques and Methods↗

A data exchange standard for wadeable stream habitat monitoring data

Data from wadeable streams collected by monitoring programs are used to assess watershed condition status and trends. Federally managed programs collect a suite of similar habitat measurements using compatible methods and produce individual program datasets for their prescribed geographic and temporal range. We identified four programs that produce similar data: the Bureau of Land Management Assessment, Inventory, and Monitoring lotic division, the U.S. Environmental Protection Agency National Aquatic Resource Surveys National Rivers and Streams Assessment survey section, the Federal interagency Aquatic and Riparian Effectiveness Monitoring Program, and the PacFish/InFish Biological Opinion Monitoring Program. Their datasets answer agency-specific management questions and fulfill reporting requirements, but the datasets are not released in full, or at all, and in some cases, there was no method to integrate data from the four programs to provide data at a larger spatial scale. The Pacific Northwest Aquatic Monitoring Partnership (PNAMP) led a working group of experts from the four monitoring programs to determine data compatibility, develop a Stream Habitat Metrics Integration (SHMI) data exchange standard, and integrate compatible wadeable stream data. The resulting SHMI data exchange standard contains a data mapping file used to transform data from the source program data to a conformed format based on a controlled vocabulary. After extensive discussions assessing and comparing program collection and analyses methods, the working group found 26 stream habitat metrics to be sufficiently comparable to be integrated into a meaningful dataset. Furthermore, a subset of PIBO MP data previously available only by request and AREMP data available only as a proprietary ESRI ArcGIS geodatabase were made publicly available in non-proprietary formats via the integrated SHMI dataset. A selection of data from the four programs determined to be compatible among 14 datasets were filtered, transformed, standardized, and combined using R code to create the integrated SHMI dataset containing about 12,000 locations, 19,000 events, and 200,000 measurements from 2000 to 2022. This report describes the SHMI data exchange standard and its development, the metric compatibility assessment, and the data integration process, so that others may reuse the SHMI data exchange standard and its components as well as the data integration processes.

Techniques and Methods↗

Glass laser ablation-inductively coupled plasma-mass spectrometry analysis methods, precision, and accuracy data for tephra studies in Alaska

This publication reports the analytical conditions, standard reference material (SRM) results, and preferred post-processing methodologies for laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) measurements supporting tephra studies in Alaska between 2018 and 2024. We evaluate the long-term accuracy and precision of our methodologies by comparing our calculated SRM concentrations to the Geological and Environmental Reference Materials database (GeoReM) preferred concentration values for the following SRMs: BCR-2G, BHVO-2G, ATHO-G, NIST-612, GSD-1G, and GSE-1G. We show that our LA-ICP-MS methodologies produce accurate and consistent measurements across numerous analytical sessions, even when instrumentation changed. Overall, these results indicate that Alaska tephra matrix glass measurements, like SRM measurements, are accurate, precise, and comparable between analytical sessions. This work allows us to better correlate tephra units from Alaska volcanoes throughout the Alaska-Aleutian arc, ultimately enhancing our understanding of spatiotemporal patterns of volcanism in the region. This enhanced understanding will aid in refining volcanic hazard classification and response strategies. Future versions of this dataset will provide updates to SRM results or analytical routines for sessions that have transpired since the publishing of this version.

Alaska↗

User's manual for the National Water-Quality Assessment Program Invertebrate Data Analysis System (IDAS) software, version 5

The Invertebrate Data Analysis System (IDAS) software was developed to provide an accurate, consistent, and efficient mechanism for analyzing invertebrate data collected as part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program. The IDAS software is a stand-alone program for personal computers that run Microsoft Windows(Registered). It allows users to read data downloaded from the NAWQA Program Biological Transactional Database (Bio-TDB) or to import data from other sources either as Microsoft Excel(Registered) or Microsoft Access(Registered) files. The program consists of five modules: Edit Data, Data Preparation, Calculate Community Metrics, Calculate Diversities and Similarities, and Data Export. The Edit Data module allows the user to subset data on the basis of taxonomy or sample type, extract a random subsample of data, combine or delete data, summarize distributions, resolve ambiguous taxa (see glossary) and conditional/provisional taxa, import non-NAWQA data, and maintain and create files of invertebrate attributes that are used in the calculation of invertebrate metrics. The Data Preparation module allows the user to select the type(s) of sample(s) to process, calculate densities, delete taxa on the basis of laboratory processing notes, delete pupae or terrestrial adults, combine lifestages or keep them separate, select a lowest taxonomic level for analysis, delete rare taxa on the basis of the number of sites where a taxon occurs and (or) the abundance of a taxon in a sample, and resolve taxonomic ambiguities by one of four methods. The Calculate Community Metrics module allows the user to calculate 184 community metrics, including metrics based on organism tolerances, functional feeding groups, and behavior. The Calculate Diversities and Similarities module allows the user to calculate nine diversity and eight similarity indices. The Data Export module allows the user to export data to other software packages (CANOCO, Primer, PC-ORD, MVSP) and produce tables of community data that can be imported into spreadsheet, database, graphics, statistics, and word-processing programs. The IDAS program facilitates the documentation of analyses by keeping a log of the data that are processed, the files that are generated, and the program settings used to process the data. Though the IDAS program was developed to process NAWQA Program invertebrate data downloaded from Bio-TDB, the Edit Data module includes tools that can be used to convert non-NAWQA data into Bio-TDB format. Consequently, the data manipulation, analysis, and export procedures provided by the IDAS program can be used to process data generated outside of the NAWQA Program.

Techniques and Methods↗

USGS Polar Temperature Logging System, Description and Measurement Uncertainties

This paper provides an updated technical description of the USGS Polar Temperature Logging System (PTLS) and a complete assessment of the measurement uncertainties. This measurement system is used to acquire subsurface temperature data for climate-change detection in the polar regions and for reconstructing past climate changes using the 'borehole paleothermometry' inverse method. Specifically designed for polar conditions, the PTLS can measure temperatures as low as -60 degrees Celsius with a sensitivity ranging from 0.02 to 0.19 millikelvin (mK). A modular design allows the PTLS to reach depths as great as 4.5 kilometers with a skid-mounted winch unit or 650 meters with a small helicopter-transportable unit. The standard uncertainty (uT) of the ITS-90 temperature measurements obtained with the current PTLS range from 3.0 mK at -60 degrees Celsius to 3.3 mK at 0 degrees Celsius. Relative temperature measurements used for borehole paleothermometry have a standard uncertainty (urT) whose upper limit ranges from 1.6 mK at -60 degrees Celsius to 2.0 mK at 0 degrees Celsius. The uncertainty of a temperature sensor's depth during a log depends on specific borehole conditions and the temperature near the winch and thus must be treated on a case-by-case basis. However, recent experience indicates that when logging conditions are favorable, the 4.5-kilometer system is capable of producing depths with a standard uncertainty (uZ) on the order of 200-250 parts per million.

Techniques and Methods↗

Protocol for Monitoring Fish Assemblages in Pacific Northwest National Parks

Rivers and streams that drain from Olympic, Mount Rainier, and North Cascades National Parks are among the most protected corridors in the lower 48 States, and represent some of the largest tracts of contiguous, undisturbed habitat throughout the range of several key fish species of the Pacific Northwest. These watersheds are of high regional importance as freshwater habitat sanctuaries for native fish, where habitat conditions are characterized as having little to no disturbance from development, channelization, impervious surfaces, roads, diversions, or hydroelectric projects. Fishery resources are of high ecological and cultural importance in Pacific Northwest National Parks, and significantly contribute to economically important recreational, commercial, and tribal fisheries. This protocol describes procedures to monitor trends in fish assemblages, fish abundance, and water temperature in eight rivers and five wadeable streams in Olympic National Park during summer months, and is based on 4 years of field testing. Fish assemblages link freshwater, marine, and terrestrial ecosystems. They also serve as focal resources of national parks and are excellent indicators of ecological conditions of rivers and streams. Despite the vital importance of native anadromous and resident fish populations, there is no existing monitoring program for fish assemblages in the North Coast and Cascades Network. Specific monitoring objectives of this protocol are to determine seasonal and annual trends in: (1) fish species composition, (2) timing of migration of adult fish, (3) relative abundance, (4) age and size structure, (5) extent of non-native and hatchery fish, and (6) water temperature. To detect seasonal and annual trends in fish assemblages in reference sites, we rely on repeated and consistent annual sampling at each monitoring site. The general rationale for the repeated sampling of reference sites is to ensure that we account for the high interannual variability in fish movements and abundances in rivers. One underlying assumption is that the monitoring program is designed in perpetuity, and consequently our capability to detect trends substantially increases with time. The protocol describes sampling designs, methods, training procedures, safety considerations, data management, data analysis, and reporting. The allocation of sampling effort represents a balance between ecological considerations, a sound monitoring approach, and practical limitations caused by logistical constraints and a limited annual budget of $55,000. The widespread declines of native fish species in western North America highlights the importance and urgency of understanding trends in fish assemblages from undisturbed habitats. Seasonal and annual trends in fish assemblages will provide insights at the individual, population, and assemblage level. This protocol will allow managers to detect increases and decreases in abundance of priority management species, and occurrence of non-native, hatchery, and federally listed fish. The detection of trends in fish assemblages will allow for specific management actions that may include: implementation of more appropriate fishing regulations, evaluation of existing hatchery releases, control of non-native fish species, and prioritization of habitat restoration projects. Dissemination and communication of scientific findings on North Coast and Cascades Network fish assemblages will be a core product of this protocol, which will have much relevance to decision makers, park visitors, researchers, and educators.

Techniques and Methods↗

JUPITER: Joint Universal Parameter IdenTification and Evaluation of Reliability - An Application Programming Interface (API) for Model Analysis

he Joint Universal Parameter IdenTification and Evaluation of Reliability Application Programming Interface (JUPITER API) improves the computer programming resources available to those developing applications (computer programs) for model analysis. The JUPITER API consists of eleven Fortran-90 modules that provide for encapsulation of data and operations on that data. Each module contains one or more entities: data, data types, subroutines, functions, and generic interfaces. The modules do not constitute computer programs themselves; instead, they are used to construct computer programs. Such computer programs are called applications of the API. The API provides common modeling operations for use by a variety of computer applications. The models being analyzed are referred to here as process models, and may, for example, represent the physics, chemistry, and(or) biology of a field or laboratory system. Process models commonly are constructed using published models such as MODFLOW (Harbaugh et al., 2000; Harbaugh, 2005), MT3DMS (Zheng and Wang, 1996), HSPF (Bicknell et al., 1997), PRMS (Leavesley and Stannard, 1995), and many others. The process model may be accessed by a JUPITER API application as an external program, or it may be implemented as a subroutine within a JUPITER API application . In either case, execution of the model takes place in a framework designed by the application programmer. This framework can be designed to take advantage of any parallel processing capabilities possessed by the process model, as well as the parallel-processing capabilities of the JUPITER API. Model analyses for which the JUPITER API could be useful include, for example: Compare model results to observed values to determine how well the model reproduces system processes and characteristics. Use sensitivity analysis to determine the information provided by observations to parameters and predictions of interest. Determine the additional data needed to improve selected model predictions. Use calibration methods to modify parameter values and other aspects of the model. Compare predictions to regulatory limits. Quantify the uncertainty of predictions based on the results of one or many simulations using inferential or Monte Carlo methods. Determine how to manage the system to achieve stated objectives. The capabilities provided by the JUPITER API include, for example, communication with process models, parallel computations, compressed storage of matrices, and flexible input capabilities. The input capabilities use input blocks suitable for lists or arrays of data. The input blocks needed for one application can be included within one data file or distributed among many files. Data exchange between different JUPITER API applications or between applications and other programs is supported by data-exchange files. The JUPITER API has already been used to construct a number of applications. Three simple example applications are presented in this report. More complicated applications include the universal inverse code UCODE_2005 (Poeter et al., 2005), the multi-model analysis MMA (Eileen P. Poeter, Mary C. Hill, E.R. Banta, S.W. Mehl, and Steen Christensen, written commun., 2006), and a code named OPR_PPR (Matthew J. Tonkin, Claire R. Tiedeman, Mary C. Hill, and D. Matthew Ely, written communication, 2006). This report describes a set of underlying organizational concepts and complete specifics about the JUPITER API. While understanding the organizational concept presented is useful to understanding the modules, other organizational concepts can be used in applications constructed using the JUPITER API.

Techniques and Methods↗

Methods for synthesis of some jarosites

Experimental procedures in this report summarize attempts to synthesize potassium-, hydronium-, sodium-, and mixed-composition (hydronium-bearing) jarosites. After experimentation, some acceptable combinations of chemical and physical factors were found to routinely synthesize chemically different jarosites, which were used as part of a characterization study of some natural and synthetic jarosites. Jarosite is a sulfate mineral that is common in geologic settings where iron sulfide minerals such as pyrite or marcasite are subject to oxidative weathering. The presence of jarosite is a hallmark of acidic conditions. Jarosite forms as a secondary mineral in weathered sulfidic ores, coal mine wastes, on oxidizing mine wastes, and in streams affected by acid mine drainage. Jarosite also forms in acid-sulfate soils, as an alteration product of sulfidic shales, and in hydrothermal environments. Because of its important role in earth surface processes, the USGS is conducting mineralogical, geochemical, and remote sensing studies to characterize natural jarosites and to elucidate its stability range and conditions of formation. The presence of jarosite is not limited to the Earth. The recent identification of jarosite in the rocks at the Meridiani Planum on Mars has given planetary geologists reason to think that jarosite may be evidence of relict lacustrine (lake systems) or hydrothermal (water enriched magma emanations) systems on the Martian surface. USGS scientists are currently developing jarosite detection systems that can be placed on orbiting spectrometers. One day these systems may guide Mars landers to sites abundant in jarosite, sites most likely to have sheltered ancient Martian life.

Techniques and Methods↗

Guide to the Revised Ground-Water Flow and Heat Transport Simulator: HYDROTHERM - Version 3

The HYDROTHERM computer program simulates multi-phase ground-water flow and associated thermal energy transport in three dimensions. It can handle high fluid pressures, up to 1 ? 109 pascals (104 atmospheres), and high temperatures, up to 1,200 degrees Celsius. This report documents the release of Version 3, which includes various additions, modifications, and corrections that have been made to the original simulator. Primary changes to the simulator include: (1) the ability to simulate unconfined ground-water flow, (2) a precipitation-recharge boundary condition, (3) a seepage-surface boundary condition at the land surface, (4) the removal of the limitation that a specified-pressure boundary also have a specified temperature, (5) a new iterative solver for the linear equations based on a generalized minimum-residual method, (6) the ability to use time- or depth-dependent functions for permeability, (7) the conversion of the program code to Fortran 90 to employ dynamic allocation of arrays, and (8) the incorporation of a graphical user interface (GUI) for input and output. The graphical user interface has been developed for defining a simulation, running the HYDROTHERM simulator interactively, and displaying the results. The combination of the graphical user interface and the HYDROTHERM simulator forms the HYDROTHERM INTERACTIVE (HTI) program. HTI can be used for two-dimensional simulations only. New features in Version 3 of the HYDROTHERM simulator have been verified using four test problems. Three problems come from the published literature and one problem was simulated by another partially saturated flow and thermal transport simulator. The test problems include: transient partially saturated vertical infiltration, transient one-dimensional horizontal infiltration, two-dimensional steady-state drainage with a seepage surface, and two-dimensional drainage with coupled heat transport. An example application to a hypothetical stratovolcano system with unconfined ground-water flow is presented in detail. It illustrates the use of HTI with the combination precipitation-recharge and seepage-surface boundary condition, and functions as a tutorial example problem for the new user.

Techniques and Methods↗

Determination of the δ 13 C of dissolved inorganic carbon in water; RSIL lab code 1710

The purpose of the Reston Stable Isotope Laboratory (RSIL) lab code 1710 is to present a method to determine the δ 13 C of dissolved inorganic carbon (DIC) of water. The DIC of water is precipitated using ammoniacal strontium chloride (SrCl 2 ) solution to form strontium carbonate (SrCO 3 ). The δ 13 C is analyzed by reacting SrCO 3 with 100-percent phosphoric acid (H 3 PO 4 ) to liberate carbon quantitatively as carbon dioxide (CO 2 ), which is collected, purified by vacuum sublimation, and analyzed by dual inlet isotope-ratio mass spectrometry (DI-IRMS). The DI-IRMS is a DuPont double-focusing mass spectrometer. One ion beam passes through a slit in a forward collector and is collected in the rear collector. The other measurable ion beams are collected in the front collector. By changing the ion-accelerating voltage under computer control, the instrument is capable of measuring mass/charge ( m/z ) 45 or 46 in the rear collector and m/z 44 and 46 or 44 and 45, respectively, in the front collector. The ion beams from these m/z values are as follows: m/z 44 = CO 2 = 12 C 16 O 16 O, m/z 45 = CO 2 = 13 C 16 O 16 O primarily, and m/z 46 = CO 2 = 12 C 16 O 18 O primarily. The data acquisition and control software calculates δ 13 C values.

Techniques and Methods↗

Classification of river regimes: A context for hydroecology

Over the past 30 years, ecologists have demostrated the importance of flow and temperature as primary variables in driving running water, riparian and floodplain ecosystems. As it is important to assess the size and timing of discharge variations in relation to those in temperature, a method is proposed that uses multivariate techniques to separately classify annual discharge and temperature regimes according to their 'shape' and 'magnitude', and which then combines the classifications. This paper: (i) describes a generally applicable method; (ii) tests the method by applying it to riparian systems on four British rivers using a 20-year record (1977-97) of flow and air temperature: (iii) proposes a hydroecological interpretation of the classification; (iv) considers the degree to which the methodology might provide information to support the design of ecologically acceptable flow regimes. 'Regimes' are defined for discharge and air temperature using monthly mean data. The results of applying the classification procedure to four British rivers indicates that the 'typical' regimes for each of the four catchments are composite features produced by a small number of clearly defined annual types that reflect interannual variability in hydroclimatological conditions. Annual discharge patterns are dominated by three 'shape' classes (accounting for 94% of the station years: class A, early (November) peak; class B, intermediate (December-January) peak; and class C, late (March) peak) and one 'magnitude' class (70% of the station years fall into class 3, intermediate), with two subordinate 'magnitude' classes: low-flow years (18%) and high flow years (12%). For air temperature, annual patterns are classified evenly into three 'shape' and four 'magnitude' classes. It is argued that this variety of flow-temperature patterns is important for sustaining ecosystem integrity and for establishing benchmark flow regimes and associated frequencies to aid river management. Copyright ?? 2000 John Wiley & Sons, Ltd.Over the past 30 years, ecologists have demonstrated the importance of flow and temperature as primary variables in driving running water, riparian and floodplain ecosystems. As it is important to assess the size and timing of discharge variations in relation to those in temperature, a method is proposed that uses multivariate techniques to separately classify annual discharge and temperature regimes according to their `shape' and `magnitude', and which then combines the classifications. This paper: (i) describes a generally applicable method; (ii) tests the method by applying it to riparian systems on four British rivers using a 20-year record (1977-97) of flow and air temperature; (iii) proposes a hydroecological interpretation of the classification; (iv) considers the degree to which the methodology might provide information to support the design of ecologically acceptable flow regimes. `Regimes' are defined for discharge and air temperature using monthly mean data. The results of applying the classification procedure to four British rivers indicates that the `typical' regimes for each of the four catchments are composite features produced by a small number of clearly defined annual types that reflect interannual variability in hydroclimatological conditions. Annual discharge patterns are dominated by three `shape' classes (accounting for 94% of the station years: class A, early (November) peak; class B, intermediate (December-January) peak; and class C, late (March) peak) and one `magnitude' class (70% of the station years fall into class 3, intermediate), with two subordinate `magnitude' classes: low-flow years (18%) and high flow years (12%). For air temperature, annual patterns are classified evenly into three `shape' and four `magnitude' classes. It is argued that this variety of flow-temperature patterns is important for sustaining ecosystem integrity and for establishing benchmark flow regimes and associated frequencies to aid

Hydrological Processes↗

Documentation of a restart option for the U.S. Geological Survey coupled Groundwater and Surface-Water Flow (GSFLOW) model

A new option to write and read antecedent conditions (also referred to as initial conditions) has been developed for the U.S. Geological Survey (USGS) Groundwater and Surface-Water Flow (GSFLOW) numerical, hydrologic simulation code. GSFLOW is an integration of the USGS Precipitation-Runoff Modeling System (PRMS) and USGS Modular Groundwater-Flow Model (MODFLOW), and provides three simulation modes: MODFLOW-only, PRMS-only, and GSFLOW (or coupled). The new capability, referred to as the restart option, can be used for all three simulation modes, such that the results from a pair (or set) of spin-up and restart simulations are nearly identical to results produced from a continuous simulation for the same time period. The restart option writes all results to files at the end of a spin-up simulation that are required to initialize a subsequent restart simulation. Previous versions of GSFLOW have had some capability to save model results for use as antecedent condiitions in subsequent simulations; however, the existing capabilities were not comprehensive or easy to use. The new restart option supersedes the previous methods. The restart option was developed in collaboration with the National Oceanic and Atmospheric Administration, National Weather Service as part of the Integrated Water Resources Science and Services Partnership. The primary focus for the development of the restart option was to support medium-range (7- to 14-day) forecasts of low streamflow conditions made by the National Weather Service for critical water-supply basins in which groundwater plays an important role. The spin-up simulation should be run for a sufficient length of time necessary to establish antecedent conditions throughout a model domain. Each GSFLOW application can require different lengths of time to account for the hydrologic stresses to propagate through a coupled groundwater and surface-water system. Typically, groundwater hydrologic processes require many years to come into equilibrium with dynamic climate and other forcing (or stress) data, such as precipitation and well pumping, whereas runoff-dominated surface-water processes respond relatively quickly. Use of a spin-up simulation can substantially reduce execution-time requirements for applications where the time period of interest is small compared to the time for hydrologic memory; thus, use of the restart option can be an efficient strategy for forecast and calibration simulations that require multiple simulations starting from the same day.

Techniques and Methods↗