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At least 37 records · Page 2Linked to original sources

Hydraulic conductivity of a sandy soil at low water content after compaction by various methods

To investigate the degree to which compaction of a sandy soil influences its unsaturated hydraulic conductivity K , samples of Oakley sand (now in the Delhi series; mixed, thermic, Typic Xeropsamments) were packed to various densities and K was measured by the steady-state centrifuge method. The air-dry, machine packing was followed by centrifugal compression with the soil wet to about one-third saturation. Variations in (i) the impact frequency and (ii) the impact force during packing, and (iii) the amount of centrifugal force applied after packing, produced a range of porosity from 0.333 to 0.380. With volumetric water content θ between 0.06 and 0.12, K values were between 7 × 10 −11 and 2 × 10 −8 m/s. Comparisons of K at a single θ value for samples differing in porosity by about 3% showed as much as fivefold variation for samples prepared by different packing procedures, while there generally was negligible variation (within experimental error of 8%) where the porosity difference resulted from a difference in centrifugal force. Analysis involving capillary-theory models suggests that the differences in K can be related to differences in pore-space geometry inferred from water retention curves measured for the various samples.

Soil Science Society of America Journal

Distribution of selenium in soils of agricultural fields, western San Joaquin Valley, California

Soils from three agricultural fields in the Panoche Creek alluvial fan area in the western San Joaquin Valley, California, were analyzed for soluble, adsorbed, and total concentrations of selenium (Se) to assess the distribution and forms of Se in relation to the leaching of Se from soils. This assessment is needed to evaluate the importance of soil Se in affecting ground water concentrations. Soil samples were collected from three fields with drainage systems of different ages (6, 15, 1.5 yr) and different Se concentrations in drain water (58, 430, 3700 µg L −1 , respectively). Concentrations of soluble Se and salinity were highest in soils from the field drained for 1.5 yr and lowest in the field drained for 6 yr. Of the total concentration of soil Se from all three fields, the proportion of adsorbed and soluble Se ranged from 1 to 11% and <1 to 63%, respectively. Most of the soluble Se was present as selenate and most of the adsorbed Se was found to be selenite. Consistent with a model of evaporative concentration of Se and salinity in soils and shallow ground water in this area, most of the variance in soluble Se is explained by salinity (r 2 > 0.68) in saturation extracts of soils sampled from below the water table. In contrast, most soluble salts and Se apparently have been leached from the unsaturated soils in the fields drained for 6 and 15 yr. For the leached soils, dissolution and precipitation of evaporite minerals containing Se may no longer control concentrations of soluble Se.

California

Development rates of Late Quaternary soils, Silver Lake playa, California

Soils formed on alluvial fan deposits that range in age from about 35 000 to 200 yr BP near Silver Lake playa in the Mojave Desert permit study of the rates of soil development in an arid, hyperthermic climate. Field-described properties of soils were quantified and analyzed using a soil development index that combines properties and horizon thicknesses. We compared the variability in index values from five independent descriptions of the same soil profile with the variability in values from four soils of the same age described by different people. The variability due to description accounts for between 30 and 80% of the total variability (that due to both the soils and description) for the properties described, which emphasizes the need for consistent soil descriptions. Pedogenic CaCO 3 (as indicated by color), pH increase, and dry consistence appear to change with age at linear rates, whereas rubification appears to change at a logarithmic rate. The linear rates are best attributed to the progressive accumulation of CaCO 3 - and salt-rich eolian dust derived from the playa and other more distant sources. The total-texture values of soils on fans older than 10 000 yr BP are similar, which suggests that playas in this area may have been wet enough to restrict the availability of fines from these sources for many thousands of years prior to 10 000 yr BP. Index values for most properties of soils on the lower fans adjacent to the playa increase at faster rates than those of soils of the same age on the upper fans farther from the playa, probably due to the proximity to this local dust source. Equations derived from regressions of soil age and properties can be used to estimate ages of undated, lithologically similar deposits in similar climates and geomorphic settings.

California

Selenium speciation methods and application to soil saturation extracts from San Joaquin Valley, California

Methods to determine soluble concentrations of selenite, selenate, and organic Se were evaluated on saturation extracts of soil samples collected from three sites on the Panoche Creek alluvial fan in the western San Joaquin Valley, California. The methods were used in combination with hydride-generation atomic-absorption spectrometry for detection of Se, and included a selective chemical-digestion method and three chromatographic methods using XAD-8 resin, Sep-Pak C 18 cartridge, and a combination of XAD-8 resin and activated charcoal. The chromatography methods isolate dissolved organic matter that can inhibit Se detection by hydride-generation atomic-absorption spectrometry. Isolation of hydrophobic organic matter with XAD-8 did not affect concentrations of selenite and selenate, and the isolated organic matter represents a minimal estimation of organic Se. Ninety-eight percent of the Se in the extracts was selenate and about 100% of the isolated organic Se was associated with the humic acid fraction of dissolved organic matter. The depth distribution of Se species in the soil saturation extracts support a hypothesis that the distribution of soluble Se and salinity in these soils is the result of evaporation from a shallow water table and leaching by irrigation water low in Se and salinity.

California

Variability of an unsaturated sand unit underlying a radioactive- waste trench

Properties of soils vary considerably within any field. This study was conducted to investigate the variability in properties of an unsaturated sand unit that lies at a depth of 13 m below land surface. Four-hundred-forty soil core samples, obtained from a 1.75 by 18-m horizontal plane within a sand unit underlying a waste trench, were used to describe the variability of moisture content, tritium concentration, and several physical properties. A simple model based on unit-gradient theory was used to calculate fluxes of water and tritium through the study plane. The effects of including spatial variability of properties in model calculations were examined. The sand was uniform in terms of median particle size, bulk density, and proposity, but several variables, including saturated hydraulic conductivity ( K s ) and tritium concentration, showed considerable variability. In general, correlation coefficients calculated between variables were low. Spatial correlation structures were identified for moisture content, tritium concentration, and a few particle-size variables, but were absent for K s and most other variables. Variances of K s and field-measured volumetric moisture content (θ) were lower than published values for soils. Model-calculated fluxes of water and tritium that accounted for spatial variability of properties were considerably higher than those that did not account for the variability. Model results were more sensitive to changes in θ and residual moisture content (each parameters of the relative hydraulic conductivity function) than to changes in K s .

Illinois

Collimated neutron probe for soil water content measurements

The use of uncollimated (undirected) neutron moisture meters is common in the biological and geophysical sciences. A collimated neutron probe was designed to enable measurements in specific directions from the access tube. To determine the size and shape of soil volume affecting the neutron counts, experiments were conducted to evaluate: (i) the vertical distance of soil above and below the probe that influences neutron counts, (ii) the horizontal distance away from the probe into the soil that influences neutron counts, (iii) the angle of soil viewed by the probe from the collimator, and (iv) the three-dimensional thermal-neutron density field. The distance and the angular dimensions of the volume of influence were defined as the horizontal distance of neutron penetration from the edge of the probe, the vertical distance above and below the center of the effective measurement point of the probe, and the angle from the center of the probe, which would allow the determination of relative water content to within 95%. The vertical distance was ≈0.5 m, the horizontal distance was ≈0.2 m, and the angle of soil viewed by the probe from the collimator was ≈120°. Thermal neutrons detected from distances or angles larger than these values influence the determination of relative water content by 5% or less.

Soil Science Society of America Journal

Selenium mobility and distribution in irrigated and nonirrigated alluvial soils

Dissolution and leaching of soil salts by irrigation water is a primary source of Se to shallow groundwater in the western San Joaquin Valley, California. In this study, the mobility and distribution of selenite and selenate in soils with different irrigation and drainage histories was evaluated using sorption experiments and an advection-dispersion model. The sorption studies showed that selenate (15–12400 µg Se L −1 ) is not adsorbed to soil, whereas selenite (10–5000 µg Se L −1 ) is rapidly adsorbed. The time lag between adsorption and desorption of selenite is considerable, indicating a dependence of reaction rate on reaction direction (hysteresis). Selenite adsorption and desorption isotherms were different, and both were described with the Freundlich equation. Model results and chemical analyses of extracts from the soil samples showed that selenite is resistant to leaching and therefore can represent a potential long-term source of Se to groundwater. In contrast, selenate behaves as a conservative constituent under alkaline and oxidized conditions and is easily leached from soil.

Soil Science Society of America Journal

Semiempirical model of soil water hysteresis

In order to represent hysteretic soil water retention curves accurately using as few measurements as possible, a new semiempirical model has been developed. It has two postulates related to physical characteristics of the medium, and two parameters, each with a definite physical interpretation, whose values are determined empirically for a given porous medium. One parameter represents the fraction of the pore space that is not subject to Haines jump hysteresis. Its associated postulate is that a single value of this parameter characterizes a given medium, or, equivalently, that the medium is self-similar with respect to the division between hysteretic and nonhysteretic pore space. The second parameter is the effective body-to-neck size ratio of the medium's largest pore. The second postulate specifies a particular relation between the size distributions of pore bodies and of pore necks. Tests of the model show that it provides high-quality optimized fits to measured water content vs. matric pressure wetting curves for a wide variety of media. The parameter values obtained through optimization correlate plausibly with such media properties as uniformity of particles, complexity of structure, and degree of compaction. A practical use of this model is to provide a complete simulated main wetting curve for a medium where only a main drying curve and two points on the wetting curve have been measured. With additional development, it may be possible to do without the two measured wetting points if parameters can be evaluated from other measurements or known properties of the medium.

Soil Science Society of America Journal

An improved method for quantifying soil macroporosity

Quantitative information on macroporosity is needed to predict water flow and solute transport in field soils. A method was developed for determining the number, shape, and size distribution of soil macropores. Horizontal serial sections sawed from paraffin-impregnated soil cores were photographed under ultraviolet (UV) light. Anthracene, mixed with the paraffin, fluoresces a bright bluish white under UV light and provides a sharp contrast between the soil matrix and the paraffin-filled pore space. Section photographs were converted to 256 level, grey-scale digital images using a flat-bed scanner. Image processing was used to classify each pixel in a digital image as pore space or soil matrix, to group the pore space pixels into pores, and to measure the area and perimeter of each pore. The method was able to measure pores with an equivalent radius ≥85 µm. Macroporosity in soil cores sampled form a tillage path and from an adjacent, undisturbed (notill) region was quantified. Tillage sections contained, on the average, 9.4 macropores/cm 2 with an equivalent macroporosity of 8%, while no-till sections contained 0.8 macropores/cm 2 with an equivalent macroporosity of 0.3%. Computed intrinsic permeabilities for tillage sections that included macropore information were significantly larger than values computed using micropore information alone, suggesting that macropores must be included in permeability calculations when the number of macropores is large. The developed method should be useful for quantifying macroporosity in nonskeletal soils.

Soil Science Society of America Journal

Variations in water balance and recharge potential at three western desert sites

Radioactive and hazardous waste landfills exist at numerous desert locations in the USA. At these locations, annual precipitation is low and soils are generally dry, yet little is known about recharge of water and transport of contaminants to the water table. Recent water balance measurements made at three desert locations, Las Cruces, NM, Beatty, NV, and the U.S. Department of Energy's Hanford Site in the state of Washington, provide information on recharge potential under three distinctly different climate and soil conditions. All three sites show water storage increases with time when soils are coarse textured and plants are removed from the surface, the rate of increase being influenced by climatic variables such as precipitation, radiation, temperature, and wind. Lysimeter data from Hanford and Las Cruces indicate that deep drainage (recharge) from bare, sandy soils can range from 10 to >50% of the annual precipitation. At Hanford, when desert plants are present on sandy or gravelly surface soils, deep drainage is reduced but not eliminated. When surface soils are silt loams, deep drainage is eliminated whether plants are present or not. At Las Cruces and Beatty, the presence of plants eliminated deep drainage at the measurement sites. Differences in water balance between sites are attributed to precipitation quantity and distribution and to soil and vegetation types. The implication for waste management at desert locations is that surface soil properties and plant characteristics must be considered in waste site design in order to minimize recharge potential.

Soil Science Society of America Journal

Evaluation of measurement scale using imbibition experiments in volcanic tuffs

A major issue in the site characterization at Yucca Mountain, Nevada, a potential site for a high-level nuclear waste repository, is the relevance of laboratory-scale measurements on cores to field-scale processes, particularly water flow. Calculation of Philip`s sorptivity parameter using imbibition of water into rock was selected as a simple test to describe hydrologic parameters at both laboratory and field scales and to study effects of sample size and spatial variability. Laboratory-scale imbibition experiments were conducted on two sizes of core from two boreholes drilled in layered nonwelded tuff and fractured welded tuff. Laboratory experiments were compared with field experiments in the boreholes using neutron logs and a field-scale Mariotte system. Measured sorptivity for both sizes of core were virtually identical and both could predict field-scale sorptivity if enough samples were used to account for spatial heterogeneity. Core data was less useful in predicting the neutron log data due to the nature of the neutron probe measurement and difficulties in accounting for effects of the unique system geometry. Mean neutron log values could not predict the field results from the welded borehole due to fractures transmitting but not retaining water, and could not predict laboratory results because of scale and sampling volume differences. The mean neutron log data could, however, approximate the large-scale field results in the nonwelded borehole.

Nevada

Land subsidence in drained histosols and highly organic mineral soils of California

This study was conducted to determine historical trends in subsidence in the Sacramento-San Joaquin Delta and their environmental controls. In the western Delta, average subsidence rates were 2.3 cm yr-1 from 1910 to 1.5 cm yr-1 from 1952 to 1988. Spatially variability in subsidence was correlated with organic matter content of the soil which in turn was related to the depositional and drainage history of the Delta. Subsidence rates appaeared to be independent of crops grown.

California

Carbon sequestration in an aggrading forest ecosystem in the Southeastern USA

An analysis of C pools at the Panola Mountain Research Watershed (PMRW) near Atlanta, GA, indicates that aggrading forests in the U.S. Southeast are an important regional C sink. The forests in this area were cut in the early 1800s and the land was cultivated until the early 1900s, when farming was abandoned and forest regeneration began. Cultivation resulted in extensive erosion, which depleted soil C pools. The rate of soil C sequestration during the 70-yr period of forest regeneration was estimated to be between 0.34 (standard error [SE] = 0.12) and 0.79 (SE = 0.19) Mg C ha −1 yr −1 . There is a large potential for continued C accumulation in the soil at PMRW based on the difference between current measured soil C pools of 82 Mg C ha −1 at PMRW and 122 Mg C ha −1 at the nearby “undisturbed” Fernbank Forest in Atlanta, GA. The rate of C sequestration in biomass at PMRW was 1.47 Mg C ha −1 yr −1 for the regeneration period, bringing the ecosystem total to between 1.81 and 2.26 Mg C ha −1 yr −1 . Carbon sequestration in temperate forest ecosystems partially mitigates the effects of increased atmospheric loading of CO 2 .

Georgia

Improved method for measuring water imbibition rates on low-permeability porous media

Existing methods for measuring water imbibition rates are inadequate when imbibition rates are small (e.g., clay soils and many igneous rocks). We developed an improved laboratory method for performing imbibition measurements on soil or rock cores with a wide range of hydraulic properties. Core specimens are suspended from an electronic strain gauge (load cell) in a closed chamber while maintaining the lower end of the core in contact with a free water surface in a constant water level reservoir. The upper end of the core is open to the atmosphere. During imbibition, mass increase of the core is recorded continuously by a datalogger that converts the load cell voltage signal into mass units using a calibration curve. Computer automation allows imbibition rate measurement on as many as eight cores simultaneously and independently. Performance of each component of the imbibition apparatus was evaluated using a set of rock cores (2.5 cm in diameter and 2–5 cm in length) from a signle lithostratigraphic unit composed of non-to-moderately welded ash-flow tuff (a glass-rich pyroclastic rock partially fused by heat and pressure) with porosities ranging from 0.094 to 0.533 m 3 m -3 . Reproducibility of sample handling and testing procedures was demonstrated using replicate measurements. Precision and accuracy of load cell measurements were assessed using mass balance calculations and indicated agreement within a few tenths of a percent of total mass. Computed values of sorptivity, S , ranged from 8.83 × 10 -6 to 4.55 × 10 -4 m s -0.5 . The developed method should prove useful for measuring imbibition rates on a wide range of porous materials.

Soil Science Society of America Journal

Porosity factors that control the hydraulic conductivity of soil-saprolite transitional zones

Slowly permeable transitional horizons separate soil and saprolite, but these horizons cannot be identified easily in the field. The objectives of this study were to determine why the soil-saprolite transitional zone (BC and CB horizons) is slowly permeable, and to evaluate ways for identifying it in the field. Two saprolite deposits were studied in the North Carolina Piedmont. At each site, saturated and unsaturated hydraulic conductivities ( K sat and K unsat ) were measured for major horizons. Volume fractions of water-conducting pores were also compared with the changes in hydraulic conductivity with depth. Horizon mean K sat values at both sites ranged from virtually 0 to approximately 3 cm h -1 . The lowest K sat values (<0.3 cm h -1 ) occurred in or near the transitional horizons that were directly below the Bt horizons. Changes in the volume of pores within or between mineral grains (termed inter/intraparticle pores ) with depth corresponded to changes in both K sat and K unsat . In the transitional horizons, the inter/intraparticle pores were plugged with clay and this caused the horizons to have low K values. In situ measurements of K sat with depth were the most accurate technique to use for identifying transitional zones in the field. Examination of both the soil and rock structures in pits was also an acceptable technique. Texture and consistence were not considered reliable for pin-pointing transitional horizons.

North Carolina

Exchangeable hydrogen explains the pH of spodosol Oa horizons

The chemistry of extremely acid Oa horizons does not conform to traditional pH, Al, and base saturation relationships. Results from two separate studies of northeastern U.S. forested soils were used to investigate relationships between pH in water or dilute salt solutions and other soil characteristics. In Oa horizons with pH below 4, soil pH in dilute CaCl 2 solution was correlated with exchangeable H + measured either by titration ( r = −0.88, P = 0.0001, n = 142) or by electrode ( r = −0.89, P = 0.0001, n = 45). Exchangeable H + expressed as a percentage of the cation-exchange capacity (CEC) was linear with pH and showed similar slopes for data from both studies. For all samples, pHw = 4.21 − 1.80 × H + /CEC ( R 2 = 0.69, n = 194). The reciprocal of the H + /CEC ratio is base saturation with Al added to the bases. Because of the low pH, exchangeable Al does not appear to behave as an acid. Exchangeable H + remains an operationally defined quantity because of the difficulty in separating exchange and hydrolysis reactions. In a variety of neutral-salt extractants, concentrations of H + were correlated with 0.1 M BaCl 2 -exchangeable H + ( r > 0.91, P = 0.0001, n = 26) regardless of the strength of the extract. Nine successive extractions with 0.33 m M CaCl 2 removed more H + than was removed by single batch extractions with either 1 M KCl or 0.1 M BaCl 2 (average H + of 70, 43, and 49 mmol kg −1 , respectively for 26 samples). The data showed little difference in the chemical behavior of Oa horizons from a variety of geographical sites and vegetation types.

Maine, New Hampshire, New York, Vermont

Woody debris decomposition in the Atchafalaya River Basin of Louisiana following hurricane disturbance

The contribution of woody debris to some biogeochemical functions of forested wetlands was examined in the Atchafalaya River Basin in Louisiana following disturbance by Hurricane Andrew. Woody debris decomposition processes were characterized in terms of mass, C, N, and P dynamics. These were compared between different diameters of debris, areas recieving different intensities of disturbance, and between different positions relative to the soil. Disturbance intensity (as defined by canopy closure) had little effect on decomposition processes when compared with soil orientation (i.e., whether in contact with or suspended above the soil). Rates of mass loss varied between 0.055 and 0.068 for suspended and ground-contact coarse woody debris, respectively. Fine woody debris rate coefficients averaged 0.060 and 0.085 for the same respective orientations. In general, woody debris displayed strong source activity for P but a greater tendency toward sink behavior for N. In terms of biogeochemical transformations, these data suggest that woody debris might act as a phosphate source during sheet flow events but could provide short-term retention of inorganic N associated with floodwaters.

Louisiana

Inexpensive automated paging system for use at remote research sites

The use of a flow-activated automatic sampler at a remote research site required personnel to periodically visit the site to collect samples and reset the automatic sampler. To reduce site visits, a cellular telephone was modified for activation by a datalogger. The purpose of this study was to demonstrate the use and benefit of the modified telephone. Both the power switch and the speed-dial button on the telephone were bypassed and wired to a relay driver. The datalogger was programmed to compare values of a monitored environmental parameter with a target value. When the target value was reached or exceeded, the datalogger pulsed a relay driver, activating power to the telephone. A separate relay activated the speed dial, dialing the number of a tone-only pager. The use of this system has saved time and reduced travel costs by reducing the number of trips to the site, without the loss of any data.The use of a flow-activated automatic sampler at a remote research site required personnel to periodically visit the site to collect samples and reset the automatic sampler. To reduce site visits, a cellular telephone was modified for activation by a datalogger. The purpose of this study was to demonstrate the use and benefit of the modified telephone. Both the power switch and the speed-dial button on the telephone were bypassed and wired to a relay driver. The datalogger was programmed to compare values of a monitored environmental parameter with a target value. When the target value was reached or exceeded, the datalogger pulsed a relay driver, activating power to the telephone. A separate relay activated the speed dial, dialing the number of a tone-only pager. The use of this system has saved time and reduced travel costs by reducing the number of trips to the site, without the loss of any data.

Soil Science Society of America Journal