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At least 307 records · Page 17Linked to original sources
USGS2025

Chlorophyll trends are negative for lakes but positive for estuarine–coastal waters

Nutrient (nitrogen and phosphorus) pollution is an environmental problem of global concern because overenrichment of water bodies increases phytoplankton biomass and ecosystem metabolism, depletes oxygen in bottom waters, and increases the frequency and intensity of harmful algal blooms. These responses to nutrient pollution have motivated policies to reduce anthropogenic nutrient inputs. However, these policies have not been universally implemented and their success at reducing phytoplankton biomass is confounded by other components of global change that regulate the conversion of nutrients into biomass. These regulating processes themselves are changing in the Anthropocene. Our study is an assessment of changing phytoplankton biomass over the period 2000–2019, using chlorophyll a trends measured in 191 lakes and 159 estuarine-coastal sites. Our results show that phytoplankton biomass has decreased in most lakes, increased in most coastal sites, and the largest trends have been predominantly negative for lakes and positive for coastal sites. These results provide evidence of opposing directions of phytoplankton biomass change between lakes and coastal sites in this recent period of unprecedented global change. Nutrient pollution is a knotty environmental problem, and our study indicates that it might be a particularly challenging problem for ecosystems situated in densely populated landscapes where freshwater and sea water meet. Success at overcoming this challenge will require deeper scientific understanding of changes in processes that regulate the conversion of nutrients into phytoplankton biomass, substantial investments of time and resources to reduce nutrient inputs, and a flexible strategy designed to anticipate and adapt to a changing world.

PNAS↗
USGS2012

Estimating the benefits of land imagery in environmental applications: a case study in nonpoint source pollution of groundwater

Moderate-resolution land imagery (MRLI) is crucial to a more complete assessment of the cumulative, landscape-level effect of agricultural land use and land cover on environmental quality. If this improved assessment yields a net social benefit, then that benefit reflects the value of information (VOI) from MRLI. Environmental quality and the capacity to provide ecosystem services evolve because of human actions, changing natural conditions, and their interaction with natural physical processes. The human actions, in turn, are constrained and redirected by many institutions and regulations such as agricultural, energy, and environmental policies. We present a general framework for bringing together sociologic, biologic, physical, hydrologic, and geologic processes at meaningful scales to interpret environmental implications of MRLI applications. We set out a specific application using MRLI observations to identify crop planting patterns and thus estimate surface management activities that influence groundwater resources over a regional landscape. We tailor the application to the characteristics of nonpoint source groundwater pollution hazards in Iowa to illustrate a general framework in a land use-hydrologic-economic system. In the example, MRLI VOI derives from reducing the risk of both losses to agricultural production and damage to human health and other consequences of contaminated groundwater.

Book chapter↗
USGS1971

Geochemical Survey of Missouri: Plans and progress for fifth six-month period (July-December 1971)

This is the fifth of a series of progress reports to the Environmental Health Surveillance Center of the University of Missouri; each report covers a six-month period in our reconnaissance geochemical survey of the State of Missouri that is designed to provide epidemiologists of the Environmental Health Center with data on the variability in the geochemical environment throughout the State. The survey is being directed at geologic units (including both surficial and bedrock units), both agricultural and uncultivated soils, native vegetation and farm crops, and both ground and surface waters. Emphasis is on the environment in its natural state; artificial pollution of the environment is being investigated in a few small areas-principally where such pollution is thought to complicate our efforts to determine the natural environmental character. Adequate knowledge of the natural environmental character is necessary in order to establish a background for judging the degree and extent of environmental pollution.

Missouri↗
USGS2000

Using structural equation modeling to investigate relationships among ecological variables

Structural equation modeling is an advanced multivariate statistical process with which a researcher can construct theoretical concepts, test their measurement reliability, hypothesize and test a theory about their relationships, take into account measurement errors, and consider both direct and indirect effects of variables on one another. Latent variables are theoretical concepts that unite phenomena under a single term, e.g., ecosystem health, environmental condition, and pollution (Bollen, 1989). Latent variables are not measured directly but can be expressed in terms of one or more directly measurable variables called indicators. For some researchers, defining, constructing, and examining the validity of latent variables may be the end task of itself. For others, testing hypothesized relationships of latent variables may be of interest. We analyzed the correlation matrix of eleven environmental variables from the U.S. Environmental Protection Agency's (USEPA) Environmental Monitoring and Assessment Program for Estuaries (EMAP-E) using methods of structural equation modeling. We hypothesized and tested a conceptual model to characterize the interdependencies between four latent variables-sediment contamination, natural variability, biodiversity, and growth potential. In particular, we were interested in measuring the direct, indirect, and total effects of sediment contamination and natural variability on biodiversity and growth potential. The model fit the data well and accounted for 81% of the variability in biodiversity and 69% of the variability in growth potential. It revealed a positive total effect of natural variability on growth potential that otherwise would have been judged negative had we not considered indirect effects. That is, natural variability had a negative direct effect on growth potential of magnitude -0.3251 and a positive indirect effect mediated through biodiversity of magnitude 0.4509, yielding a net positive total effect of 0.1258. Natural variability had a positive direct effect on biodiversity of magnitude 0.5347 and a negative indirect effect mediated through growth potential of magnitude -0.1105 yielding a positive total effects of magnitude 0.4242. Sediment contamination had a negative direct effect on biodiversity of magnitude -0.1956 and a negative indirect effect on growth potential via biodiversity of magnitude -0.067. Biodiversity had a positive effect on growth potential of magnitude 0.8432, and growth potential had a positive effect on biodiversity of magnitude 0.3398. The correlation between biodiversity and growth potential was estimated at 0.7658 and that between sediment contamination and natural variability at -0.3769.

Environmental and Ecological Statistics↗
USGS2014

Organic substances in produced and formation water from unconventional natural gas extraction in coal and shale

Organic substances in produced and formation water from coalbed methane (CBM) and gas shale plays from across the USA were examined in this study. Disposal of produced waters from gas extraction in coal and shale is an important environmental issue because of the large volumes of water involved and the variable quality of this water. Organic substances in produced water may be environmentally relevant as pollutants, but have been little studied. Results from five CBM plays and two gas shale plays (including the Marcellus Shale) show a myriad of organic chemicals present in the produced and formation water. Organic compound classes present in produced and formation water in CBM plays include: polycyclic aromatic hydrocarbons (PAHs), heterocyclic compounds, alkyl phenols, aromatic amines, alkyl aromatics (alkyl benzenes, alkyl biphenyls), long-chain fatty acids, and aliphatic hydrocarbons. Concentrations of individual compounds range from < 1 to 100 μg/L, but total PAHs (the dominant compound class for most CBM samples) range from 50 to 100 μg/L. Total dissolved organic carbon (TOC) in CBM produced water is generally in the 1–4 mg/L range. Excursions from this general pattern in produced waters from individual wells arise from contaminants introduced by production activities (oils, grease, adhesives, etc.). Organic substances in produced and formation water from gas shale unimpacted by production chemicals have a similar range of compound classes as CBM produced water, and TOC levels of about 8 mg/L. However, produced water from the Marcellus Shale using hydraulic fracturing has TOC levels as high as 5500 mg/L and a range of added organic chemicals including, solvents, biocides, scale inhibitors, and other organic chemicals at levels of 1000 s of μg/L for individual compounds. Levels of these hydraulic fracturing chemicals and TOC decrease rapidly over the first 20 days of water recovery and some level of residual organic contaminants remain up to 250 days after hydraulic fracturing. Although the environmental impacts of the organics in produced water are not well defined, results suggest that care should be exercised in the disposal and release of produced waters containing these organic substances into the environment because of the potential toxicity of many of these substances.

International Journal of Coal Geology↗
USGS1987

Ground-water data for Indian Wells Valley, Kern, Inyo, and San Bernardino Counties, California, 1977-84

Ground water is the sole source of water in Indian Wells Valley. Since 1966, annual ground-water pumpage has exceeded estimates of mean annual recharge, and continued and increased stresses on the aquifer system of the valley are expected. In 1981 the U.S. Geological Survey began a 10-year program to develop a data base that could be used in evaluating future water-management alternatives for the valley. This report tabulates existing water-level and water-quality data in order to provide a basis for the design of a ground-water monitoring network for Indian Wells Valley. Water-levels were measured in 131 wells during 1977-84. About 62 percent of the wells that have water-level measurements spanning at least 3 years during the period 1977-84 show a net water-level decline; the decline in 23 percent of the wells is greater than 5 feet. Water-quality samples from 85 wells were analyzed for major dissolved constituents. At selected wells water samples were also analyzed for nutrients and trace metals. Seventy-nine of the wells sampled contained water with concentrations of one or more dissolved constituents that equaled or exceeded U.S. Environmental Protection Agency primary or secondary maximum contaminant levels for drinking water. Dissolved-solids concentrations, which ranged from 190 to 67,000 milligrams per liter, equaled or exceeded 500 milligrams per liter (the Environmental Protection Agency secondary maximum contaminant level) in 85 percent of the sampled wells and 1,000 milligrams per liter in 59 percent. Water samples collected in 1984 from eight wells near the industrial-waste ponds of the China Lake Naval Weapons Center were analyzed for the presence of organic compounds designated 'priority pollutants' by the U.S. Environmental Protection Agency. Priority pollutants were detected in three wells. Trichloroethylene, methylene chloride, vinyl chloride, and chloroform were identified; concentrations were less than 10 micrograms per liter except for trichloroethylene and chloroform, at 94 and 12 micrograms per liter, respectively. Trichloroethylene in one sample and vinyl chloride in another exceeded Environmental Protection Agency proposed maximum contaminant levels.

California↗
USGS2006

Contaminant exposure and potential effects on terrestrial vertebrates residing in the National Capital Region network and Mid-Atlantic network

Part of the mission of the National Park Service is to preserve the natural resources, processes, systems, and associated values of its units in an unimpaired condition. Environmental contamination and pollution processes are well recognized stressors addressed by its management policies and plans. A recent study indicates that contemporary terrestrial vertebrate ecotoxicological data are lacking for 59 of 126 Park Service units located in coastal watersheds exhibiting serious water quality problems or high vulnerability to pollution. Based upon these findings, a more in-depth evaluation of contaminant threats and ecotoxicological data gaps related to terrestrial vertebrates was undertaken at 23 Inventory and Monitoring National Park units in National Capital Region and Mid-Atlantic Networks. Ecotoxicological data were compiled for each park unit through literature searches and meetings with Park Service personnel. Information on contemporary and on persistent legacy pollutants in air, water, soil, and terrestrial vertebrates (amphibians, reptiles, birds and mammals) were evaluated. To identify contaminant threats in proximity to the 23 Park Service study units, data was gathered on National Priority List Superfund sites, Section 303(d) Impaired Waterbodies, the number and relative toxicity of current use pesticides and herbicides, Toxic Release Inventory sites and discharge of priority pollutants, and Fish Consumption Advisories. A metric was derived that described the quality and quantity of existing data for each park, and in combination with known contaminant threats, park units in need of additional study were identified. Results demonstrated that over half of the Park Service study units are near Toxic Release Inventory sites discharging dioxins, polychlorinated biphenyls, lead or mercury into air or water, and fish consumption advisories are in effect at or near 22 of the 23 study units. Pesticide and herbicide use at the park units is minimal, with the exception of those units with significant agricultural leases. Despite highly regulated use, many of the pesticides and herbicides applied are believed to be highly toxic to amphibians, and some of the compounds are also highly toxic to birds. Only 70 reports were found that describe terrestrial vertebrate ecotoxicology data on or near the study units. Of the greater than 75,000 compounds in commerce in the United States, existing terrestrial vertebrate exposure and effects data in the pr esent study were limited to 58 legacy organochlorine pesticides, polychlorinated biphenyls and individual congeners, insecticides and rodenticides, metals, and some contemporary compounds (e.g., polybrominated diphenyl ether flame retardants, and alkylphenol and ethoxylate surfactants). Based upon these and other findings, ecotoxicological monitoring and research investigations of terrestrial vertebrates are warranted at several National Parks. These include Shenandoah National Park, Richmond National Battlefield, Chesapeake & Ohio Canal National Historic Park, Valley Forge National Historic Park, Hopewell Furnace National Historic Site, Monocacy National Battlefield, and Harpers Ferry National Historic Park. The types of investigations vary according to the species present at these parks and potential contaminant threats, but should focus on contemporary use pesticides and herbicides, polychlorinated biphenyls, mercury, lead, and perhaps, emerging contaminants including antibiotics, flame retardants, pharmaceuticals, and surfactants. Other management recommendations include additional training for natural resource staff members in the area of ecotoxicology, inclusion of terrestrial vertebrate contaminant monitoring and the Contaminant Assessment Process (U.S. Geological Survey Biomonitoring of Environmental Status and Trends Project) into the National Park Service Vital Signs Program, development of protocols for hand ling and toxicological analysis of dead or seemingly affected wildlife, consideration of some alternative methods and compounds for pest management and weed control, and use of non-toxic fishing tackle by visitors.

Maryland, Pennsylvania, Virginia↗
USGS1978

Recent biogenic phosphorite: Concretions in mollusk kidneys

Phosphorite concretions have been detected in the kidneys of two widespread species of mollusks, Mercenaria mercenaria and Argopecten irradians , which have relatively high population densities. These concretions are the first documentation of the direct biogenic formation of phosphorite grains. The concretions are principally amorphous calcium phosphate, which upon being heated yields an x-ray diffraction pattern which is essentially that of chlorapatite. These concretions appear to be a normal formation of the excretory process of mollusks under reproductive, environmental, or pollutant-induced stress. Biogenic production of phosphorite concretions over long periods of time and diagenetic change from amorphous to crystalline structure, coupled with secondary enrichment, may account for the formation of some marine phosphorite deposits which are not easily explained by the chemical precipitation-replacement hypothesis.

Science↗
USGS2008

Differential exposure, duration, and sensitivity of unionoidean bivalve life stages to environmental contaminants

Freshwater mussels (superfamily Unionoidea) are in serious global decline and in urgent need of protection and conservation. The declines have been attributed to a wide array of human activities resulting in pollution and water-quality degradation, and habitat destruction and alteration. Linkages among poor water quality, pollutant sources, and mussel decline in rivers and streams have been associated with results of laboratory-based tests of specific pollutants. However, uncertainties remain about the relationship of laboratory data to actual contaminant exposure routes for various mussel species, life stages, and in the habitats occupied during these exposures. We evaluated the pathways of exposure to environmental pollutants for all 4 life stages (free glochidia, encysted glochidia, juveniles, adults) of unionoidean mussels and found that each life stage has both common and unique characteristics that contribute to observed differences in exposure and sensitivity. Free glochidia typically are exposed only briefly (e.g., seconds to days) through surface water, whereas adults sustain exposure over years to decades through surface water, pore water, sediment, and diet. Juveniles live largely burrowed in the sediment for the first 0 to 4 y of life. Thus, sediment, pore water, and diet are the predominant exposure routes for this life stage, but surface water also might contribute to exposure during certain periods and environmental conditions. The obligate parasitic stage (encysted glochidia stage) on a host fish might be exposed from surface water while partially encysted or from toxicants in host-fish tissue while fully encysted. Laboratory methods for testing for acute and chronic exposures in water have advanced, and toxicant-specific information has increased in recent years. However, additional research is needed to understand interactions of life history, habitat, and long-term exposure to contaminants through water, pore water, sediment, and diet so that the risks of environmental exposures can be properly assessed and managed. ?? 2008 by The North American Benthological Society.

Journal of the North American Benthological Societ↗
USGS2021

Rapid metal pollutant deposition from the volcanic plume of Kīlauea, Hawai’i

Long-lived basaltic volcanic eruptions are a globally important source of environmentally reactive, volatile metal pollutant elements such as selenium, cadmium and lead. The 2018 eruption of Kīlauea, Hawai’i produced exceptionally high discharge of metal pollutants, and was an unprecedented opportunity to track them from vent to deposition. Here we show, through geochemical sampling of the plume that volatile metal pollutants were depleted in the plume up to 100 times faster than refractory species, such as magnesium and iron. We propose that this rapid wet deposition of complexes containing reactive and potentially toxic volatile metal pollutants may disproportionately impact localised areas close to the vent. We infer that the relationship between volatility and solubility is an important control on the atmospheric behaviour of elements. We suggest that assessment of hazards from volcanic emissions should account for heterogeneous plume depletion of metal pollutants.

Hawaii↗
USGS2003

Changing anthropogenic influence on the Santa Monica Bay watershed

Santa Monica Bay is an open coastal embayment located directly seaward of Los Angeles, California. The Bay provides vital economic value through its water-dependent activities, such as swimming, diving, boating, and fishing. An increase from 100,000 residents in 1900 to 10 million in 2000 has imposed numerous environmental stressors on the Bay, including urbanization of the watershed. Pollutant discharges into the Bay increased throughout the early part of the century, but declined following passage of the Clean Water Act in 1972. Since that time, the predominant source of pollutant inputs has changed from point sources to non-point urban runoff. To assess how present-day and historical pollution interact to affect the environmental quality of Santa Monica Bay, three organizations collaborated on a multi-disciplinary study in 1997, towards which this volume is focused. This paper details the temporal patterns of anthropogenic influence on Santa Monica Bay to provide context for the papers that follow.

California↗
USGS2022

Pharmaceutical pollution of the world’s rivers

Environmental exposure to active pharmaceutical ingredients (APIs) can have negative effects on the health of ecosystems and humans. While numerous studies have monitored APIs in rivers, these employ different analytical methods, measure different APIs, and have ignored many of the countries of the world. This makes it difficult to quantify the scale of the problem from a global perspective. Furthermore, comparison of the existing data, generated for different studies/regions/continents, is challenging due to the vast differences between the analytical methodologies employed. Here, we present a global-scale study of API pollution in 258 of the world’s rivers, representing the environmental influence of 471.4 million people across 137 geographic regions. Samples were obtained from 1,052 locations in 104 countries (representing all continents and 36 countries not previously studied for API contamination) and analyzed for 61 APIs. Highest cumulative API concentrations were observed in sub-Saharan Africa, south Asia, and South America. The most contaminated sites were in low- to middle-income countries and were associated with areas with poor wastewater and waste management infrastructure and pharmaceutical manufacturing. The most frequently detected APIs were carbamazepine, metformin, and caffeine (a compound also arising from lifestyle use), which were detected at over half of the sites monitored. Concentrations of at least one API at 25.7% of the sampling sites were greater than concentrations considered safe for aquatic organisms, or which are of concern in terms of selection for antimicrobial resistance. Therefore, pharmaceutical pollution poses a global threat to environmental and human health, as well as to delivery of the United Nations Sustainable Development Goals.

Proceedings of the National Academy of Sciences↗
USGS2002

Time-of-travel of solute data collected by the Mississippi Department of Environmental Quality for Mississippi streams

This report summarizes the time-of-travel of solutes information for Mississippi streams that is available in the files at the Mississippi Department of Environmental Quality, Office of Pollution Control. The time-of-travel information was tabulated for 112 miles of stream reaches in eight of the ten major drainage basins in the State. The data were collected during studies conducted from 1981 through 1998. Estimation of time-of-travel of solutes is important for environmental studies of streams and may be critical in the event of accidental or other spills of contaminants into a waterway.

Data Series↗
USGS2010

Effects of urbanization, construction activity, management practices, and impoundments on suspended-sediment transport in Johnson County, northeast Kansas, February 2006 through November 2008

The U.S. Geological Survey, in cooperation with the Johnson County, Kansas, Stormwater Management Program, investigated the effects of urbanization, construction activity, management practices, and impoundments on suspended-sediment transport in Johnson County from February 2006 through November 2008. Streamgages and continuous turbidity sensors were operated at 15 sites within the urbanizing 57-square-mile Mill Creek Basin, and 4 sites downstream from the other largest basins (49 to 66 square miles) in Johnson County. The largest sediment yields in Johnson County were observed downstream from basins with increased construction activity. Sediment yields attributed to the largest (68 acre) active construction site in the study area were 9,300 tons per square mile in 2007 and 12,200 tons per square mile in 2008; 5 to 55 times larger than yields observed at other sampling sites. However, given erodible soils and steep slopes at this site, sediment yields were relatively small compared to the range in historic values from construction sites without erosion and sediment controls in the United States (2,300 to 140,000 tons per square mile). Downstream from this construction site, a sediment forebay and wetland were constructed in series upstream from Shawnee Mission Lake, a 120-acre reservoir within Shawnee Mission Park. Although the original intent of the sediment forebay and constructed wetland were unrelated to upstream construction, they were nonetheless evaluated in 2008 to characterize sediment removal before stream entry into the lake. The sediment forebay was estimated to reduce 33 percent of sediment transported to the lake, whereas the wetland did not appear to decrease downstream sediment transport. Comparisons of time-series data and relations between turbidity and sediment concentration indicate that larger silt-sized particles were deposited within the sediment forebay, whereas smaller silt and clay-sized sediments were transported through the wetland and into the lake. Data collected at sites up and downstream from the constructed wetland indicated that hydraulic retention alone did not substantially reduce sediment loading to Shawnee Mission Lake. Mean-daily turbidity values at sampling sites downstream from basins with increased construction activity were compared to U.S. Environmental Protection Agency turbidity criteria designed to reduce discharge of pollutants from construction sites. The U.S. Environmental Protection Agency numeric turbidity criteria specifies that effluent from construction sites greater than 20 acres not exceed a mean-daily turbidity value of 280 nephelometric turbidity units beginning in 2011; this criteria will apply to sites greater than 10 acres beginning in 2014. Although numeric criteria would not have been applicable to data from sampling sites in Johnson County because they were not directly downstream from construction sites and because individual states still have to determine additional details as to how this criteria will be enforced, comparisons were made to characterize the potential of construction site effluent in Johnson County to exceed U.S. Environmental Protection Agency Criteria, even under extensive erosion and sediment controls. Numeric criteria were exceeded at sampling sites downstream from basins with increased construction activity for multiple days during the study period, potentially indicating the need for additional erosion and sediment controls and (or) treatment to bring discharges from construction sites into compliance with future numeric turbidity criteria. Among sampling sites in the Mill Creek Basin, sediment yields from the urbanizing Clear Creek Basin were approximately 2 to 3 times those from older, more stable urban or rural basins. Sediments eroded from construction sites adjacent to or surrounding streams appear to be more readily transported downstream, whereas sediments eroded from construction sites in headwater areas are more likely to

Scientific Investigations Report↗
USGS2020

Primary sources of polycyclic aromatic hydrocarbons to streambed sediment in Great Lakes tributaries using multiple lines of evidence

Polycyclic aromatic hydrocarbons (PAHs) are among the most widespread and potentially toxic contaminants in Great Lakes (USA/Canada) tributaries. The sources of PAHs are numerous and diverse, and identifying the primary source(s) can be difficult. The present study used multiple lines of evidence to determine the likely sources of PAHs to surficial streambed sediments at 71 locations across 26 Great Lakes Basin watersheds. Profile correlations, principal component analysis, positive matrix factorization source‐receptor modeling, and mass fractions analysis were used to identify potential PAH sources, and land‐use analysis was used to relate streambed sediment PAH concentrations to different land uses. Based on the common conclusion of these analyses, coal‐tar–sealed pavement was the most likely source of PAHs to the majority of the locations sampled. The potential PAH‐related toxicity of streambed sediments to aquatic organisms was assessed by comparison of concentrations with sediment quality guidelines. The sum concentration of 16 US Environmental Protection Agency priority pollutant PAHs was 7.4–196 000 µg/kg, and the median was 2600 µg/kg. The threshold effect concentration was exceeded at 62% of sampling locations, and the probable effect concentration or the equilibrium partitioning sediment benchmark was exceeded at 41% of sampling locations. These results have important implications for watershed managers tasked with protecting and remediating aquatic habitats in the Great Lakes Basin.

Indiana, Michigan, Minnesota, New York, Ohio, Wisc↗
USGS2001

Occurrence and distribution of organochlorine pesticides, polychlorinated biphenyls, and trace elements in fish tissue in the lower Tennessee River basin, 1980-98

The U.S. Geological Survey, as part of the National Water-Quality Assessment Program, evaluated the occurrence and distribution of organochlorine pesticides, polychlorinated biphenyls, and trace elements in fish tissue in samples collected in the lower Tennessee River Basin study unit. Fish tissue analysis provides a time-averaged measurement of contaminants as well as a direct measurement of the contaminants that bioaccumulate in fish tissue. Bioaccumulation of contaminants in fish tissue may result in concentrations that can affect human, wildlife, or aquatic health. Data for two types of tissue analyses were evaluated to assess the occurrence and distribution of contaminants: whole fish for organochlorine pesticides and polychlorinated biphenyls and fish fillets for organochlorine pesticides, polychlorinated biphenyls, and trace elements. The fish tissue data analyzed for this study cover an 18-year span including data collected in 1998 by the U.S. Geological Survey as part of the National Water-Quality Assessment Program; data collected from 1980 through 1997 by the Tennessee Valley Authority; and data collected from 1992 through 1997 by the Tennessee Department of Environment and Conservation. Concentration data for constituents that are on the U.S. Environmental Protection Agency Priority Pollutant List were summarized and compared against existing action levels or guidelines. From the list of organochlorine pesticide compounds analyzed, p,p' -dichlorodiphenyldichloroethylene ( p,p' -DDE), a breakdown product of dichlorodiphenyltrichloroethane (DDT), was the most commonly detected compound with detections at 83 percent of the sites sampled. Eleven p,p' -DDE samples exceeded action levels or guidelines with concentrations ranging from 0.20 to 12.8 milligrams per kilogram. Five other organochlorine compounds, p,p' -dichlorodiphenyldichloroethane ( p,p' -DDD), dieldrin, endrin, chlordane, and polychlorinated biphenyls, also exceeded action levels and guidelines, but the detection frequencies at sampling sites generally were less than 70 percent. Mercury, the only trace element to exceed a guideline, was detected at 51 of 102 sites sampled for trace elements. Selenium was detected in fish fillet samples from 70 of 102 sites sampled, which was more sites than for any other trace element; however, selenium did not exceed the 50 micrograms per gram U.S. Environmental Protection Agency screening criteria. Arsenic and cadmium also were detected at 44 and 54 percent of the sampling sites, respectively.

Alabama, Georgia, Kentucky, Mississippi, Tennessee↗
USGS1982

Small mammal-heavy metal concentrations from mined and control sites

Total body concentrations of zinc, copper, cadmium, lead, nickel, mercury and arsenic were determined for Peromyscus maniculatus and Microtus pennsylvanicus from an active zinc-copper mine near Timmins, Ontario, Canada, and a proposed zinc-copper mine near Crandon, Wisconsin, USA. Metal concentrations were evaluated with respect to area, species, sex and age groups. Metal concentrations in Peromyscus from the proposed mine site were not different from those collected in a third area where no mine or deposit exists. This is probably due to the 30 m of glacial material over the proposed mine site deposit. A statistical interaction between area, species, sex and age was observed for zinc and copper concentrations in small mammals we examined. Peromyscus from the mine site had consistently higher metal concentrations than Peromyscus from the control site. Greater total body cadmium and lead concentrations in adult?compared with juvenile?Peromyscus collected at the mine site suggests age-dependent accumulation of these toxic metals. Microtus did not exhibit this age-related response, and responded to other environmental metals more erratically and to a lesser degree. Differences in the response of these two species to environmental metal exposure may be due to differences in food habits. Nickel, mercury and arsenic concentrations in small mammals from the mine site were not different from controls. Heavy metal concentrations are also presented for Sorex cinereus, Blarina brevicauda and Zapus hudsonicus without respect to age and sex cohorts. Peromyscus may be a potentially important species for the monitoring of heavy metal pollution.

Environmental Pollution (Series A)↗
USGS1991

Heavy metal contamination of sediments in the upper connecting channels of the Great Lakes

In 1985, sampling at 250 stations throughout the St. Marys, St. Clair, and Detroit rivers and Lake St. Clair &mdash; the connecting channels of the upper Great Lakes &mdash; revealed widespread metal contamination of the sediments. Concentrations of cadmium, chromium, copper, lead, mercury, nickel, and zinc each exceeded U.S. Environmental Protection Agency sediment pollution guidelines at one or more stations throughout the study area. Sediments were polluted more frequently by copper, nickel, zinc, and lead than by cadmium, chromium, or mercury. Sediments with the highest concentrations of metals were found (in descending order) in the Detroit River, the St. Marys River, the St. Clair River, and Lake St. Clair. Although metal contamination of sediments was most common and sediment concentrations of metals were generally highest near industrial areas, substantial contamination of sediments by metals was present in sediment deposition areas up to 60 km from any known source of pollution.

Hydrobiologia↗