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USGS2014

Status and understanding of groundwater quality in the South Coast Interior groundwater basins, 2008: California GAMA Priority Basin Project

Groundwater quality in the approximately 653-square-mile (1,691-square-kilometer) South Coast Interior Basins (SCI) study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The South Coast Interior Basins study unit contains eight priority groundwater basins grouped into three study areas, Livermore, Gilroy, and Cuyama, in the Southern Coast Ranges hydrogeologic province. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA South Coast Interior Basins study was designed to provide a spatially unbiased assessment of untreated (raw) groundwater quality within the primary aquifer system, as well as a statistically consistent basis for comparing water quality between basins. The assessment was based on water-quality and ancillary data collected by the USGS from 50 wells in 2008 and on water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer system was defined by the depth intervals of the wells listed in the CDPH database for the SCI study unit. The quality of groundwater in the primary aquifer system may be different from that in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. The first component of this study, the status of the current quality of the groundwater resource, was assessed by using data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as trace elements and minor ions. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifer system of the SCI study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal or California regulatory or non-regulatory benchmarks for drinking-water quality. A relative-concentration greater than 1.0 indicates a concentration greater than a benchmark, and a relative-concentration less than or equal to 1.0 indicates a concentration equal to or less than a benchmark. Relative-concentrations of organic constituents and special-interest constituents were classified as “high” (relative-concentration greater than 1.0), “moderate” (relative-concentration greater than 0.1 and less than or equal to 1.0), or “low” (relative-concentration less than or equal to 0.1). Relative-concentrations of inorganic constituents were classified as “high” (relative-concentration greater than 1.0), “moderate” (relative-concentration greater than 0.5 and less than or equal to 1.0), or “low” (relative-concentration less than or equal to 0.5). Aquifer-scale proportion was used as the primary metric in the status assessment for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the area of the primary aquifer system with a relative-concentration greater than 1.0 for a particular constituent or class of constituents; percentage is based on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the areal percentage of the primary aquifer system with moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially weighted—were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable in the SCI study unit (within 90-percent confidence intervals). Inorganic constituents (one or more) with health-based benchmarks were detected at high relative-concentrations in 29 percent of the primary aquifer system, at moderate relative-concentrations in 37 percent, and at low relative-concentrations in 34 percent. High aquifer-scale proportions of inorganic constituents primarily reflected high aquifer-scale proportions of nitrate (14 percent), boron (8.6 percent), molybdenum (8.6 percent), and arsenic (5.7 percent). In contrast, the relative-concentrations of organic constituents (one or more) were high in 1.6 percent, moderate in 2.0 percent, and low or not detected in 96 percent of the primary aquifer system. Of the 207 organic and special-interest constituents analyzed for, 15 constituents were detected. Perchlorate was found at moderate relative-concentrations in 34 percent of the aquifer. Two organic constituents were frequently detected (in greater than 10 percent of samples): the trihalomethane chloroform and the herbicide simazine. The second component of this study, the understanding assessment, identified natural and human factors that may have affected groundwater quality by evaluating land use, physical characteristics of the wells, and geochemical conditions of the aquifer. This evaluation was done by using statistical tests of correlations between these potential explanatory factors and water-quality data. Concentrations of arsenic, molybdenum, and manganese were generally greater in anoxic and pre-modern groundwater than other groundwater. In contrast, concentrations of nitrate and perchlorate were significantly higher in oxic and modern groundwater. Concentrations of simazine were greater in modern than pre-modern groundwater. Chloroform detections were positively correlated with greater urban land use. Boron concentrations and chloroform detections were higher in the Livermore study area than in the other study areas of the SCI; total dissolved solids and sulfate concentrations were greater in the Cuyama study area.

California↗

USGS2022

Status and understanding of groundwater quality in the Sacramento Metropolitan Domestic-Supply Aquifer study unit, 2017—California GAMA Priority Basin Project

Groundwater quality in the Sacramento Metropolitan Domestic-Supply Aquifer study unit (SacMetro-DSA) was studied from August to November 2017 as part of the second phase of the Priority Basin Project of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in parts of Amador, Placer, Sacramento, and Sutter Counties, and the extent of the study unit was defined by the location of three California Department of Water Resources groundwater subbasins: the North American, the South American, and the Cosumnes. The SacMetro-DSA focused on groundwater resources used for domestic drinking-water supply, which generally correspond to shallower parts of aquifer systems than those of groundwater resources used for public drinking water supply in the same area. The assessments characterized the quality of untreated groundwater, not the quality of drinking water. This study included two components: (1) a status assessment, which characterized the status of the quality of the groundwater resources used for domestic supply and (2) an understanding assessment, which evaluated the natural and human factors potentially affecting water quality in those resources. The first component of this study—the status assessment—was based on water-quality data collected from 49 sites sampled by the U.S. Geological Survey for the GAMA Priority Basin Project in 2017. The samples were analyzed for volatile organic compounds, pesticides, and naturally present inorganic constituents, such as major ions and trace elements. To provide context, concentrations of constituents measured in groundwater were compared to U.S. Environmental Protection Agency and California State Water Resources Control Board Division of Drinking Water regulatory and non-regulatory benchmarks for drinking-water quality. The status assessment used a grid-based method to estimate the proportion of the groundwater resources that had concentrations of water-quality constituents approaching or above benchmark concentrations. This method provides statistically unbiased results at the study-area scale and permits comparisons to other GAMA Priority Basin Project study areas. The second component of this study—the understanding assessment—identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, groundwater age, and geochemical and hydrologic conditions of the domestic-supply aquifer and related these data to constituents identified in the status assessment for further evaluation. In the SacMetro-DSA study unit, arsenic was the only inorganic constituent detected above health-based benchmarks and was detected in 10 percent of the domestic-supply aquifer system. Inorganic constituents were detected above the non-health-based California State Water Resources Control Board—Division of Drinking Water secondary maximum contaminant levels (SMCL-CA) in 16 percent of the system. The inorganic constituents detected above the SMCL-CA were chloride, iron, manganese, and total dissolved solids (TDS). Organic constituents (volatile organic compounds and pesticides) with health-based benchmarks were not detected above health-based benchmarks; however, chloroform was detected at concentrations higher than 10 percent of the health-based benchmark (80 micrograms per liter) in 2 percent of the domestic-supply aquifer system. Of the 310 organic constituents analyzed, 16 constituents were detected; however, only bentazon and chloroform had detection frequencies greater than 10 percent. Inorganic constituents with health-based benchmarks that were evaluated in the understanding assessment included arsenic and hexavalent chromium. Arsenic and hexavalent chromium are natural constituents of aquifer sediments in the study unit and did not appear to be influenced by anthropogenic processes; rather, the presence of arsenic and hexavalent chromium appeared to be related to geochemical conditions controlled by oxidation–reduction reactions in the aquifer system. Naturally occurring inorganic constituents with SMCL-CAs evaluated in the understanding assessment were the trace elements iron and manganese, the major ion chloride, and TDS. Like arsenic and hexavalent chromium, the presence of iron and manganese was most strongly related to geochemical conditions in the aquifer system, specifically reducing conditions, which were most common near the western edge of the study unit close to the Sacramento River. Concentrations of chloride and TDS are indicators of salinity and were correlated with variables related to well location and included redox, agricultural land use, and elevation. Chloride and TDS were positively correlated to reducing conditions, and agricultural land use was negatively correlated to elevation and well depth. Observed correlations among variables were likely driven by the characteristics of the western part of the study unit, such as its higher proportion of agricultural land use and its relatively low elevation. A large portion of the western edge of the study unit is located in the center of the Sacramento Valley, defined by the location of the Sacramento River. The special-interest constituent perchlorate, also included in the understanding assessment, has natural and anthropogenic sources. Perchlorate was detected frequently and at moderate relative concentrations. In some areas of the study unit, concentrations of perchlorate were higher than what might be expected in nature; therefore, anthropogenic introduction of perchlorate or anthropogenically induced migration of native perchlorate could be occurring.

California↗

USGS2014

Status and understanding of groundwater quality in the Sierra Nevada Regional study unit, 2008: California GAMA Priority Basin Project

Groundwater quality in the Sierra Nevada Regional (SNR) study unit was investigated as part of the California State Water Resources Control Board’s Groundwater Ambient Monitoring and Assessment Program Priority Basin Project. The study was designed to provide statistically unbiased assessments of the quality of untreated groundwater within the primary aquifer system of the Sierra Nevada. The primary aquifer system for the SNR study unit was delineated by the depth intervals over which wells in the State of California’s database of public drinking-water supply wells are open or screened. Two types of assessments were made: (1) a status assessment that described the current quality of the groundwater resource, and (2) an evaluation of relations between groundwater quality and potential explanatory factors that represent characteristics of the primary aquifer system. The assessments characterize untreated groundwater quality, rather than the quality of treated drinking water delivered to consumers by water distributors. The status assessment was based on water-quality data collected by the U.S. Geological Survey from 83 wells in the SNR study unit in 2008 and from 117 wells in 3 small study units within the SNR study unit in 2006–07 and on water-quality data compiled in the State’s database for 1,066 wells sampled in 2006–08. To provide some context for the results, water-quality data were converted to relative-concentrations (RCs), which are the sample concentrations divided by the concentrations of Federal or California regulatory and non-regulatory benchmarks for drinking-water quality. RCs for inorganic constituents (major ions, trace elements, nutrients, and radioactive constituents) were classified as “high” (RC > 1.0, indicating that concentration is above the benchmark), “moderate” (1.0 ≥ RC > 0.5), or “low” (RC ≤ 0.5). For organic constituents (volatile organic compounds and pesticides) and special-interest constituents (perchlorate and N -nitrosodimethylamine [NDMA]), the boundary between moderate and low RCs was set at 0.1. All benchmarks used for organic constituents were health-based, whereas health-based and aesthetic-based benchmarks were used for inorganic constituents. The primary metric used for quantifying regional-scale groundwater quality was “aquifer-scale proportion.” Aquifer-scale proportions were calculated as the areal percentages of the primary aquifer system having high, moderate, and low RCs for a given constituent or class of constituents. The SNR study unit area was classified into four aquifer lithologic types—granitic rocks, metamorphic rocks, sedimentary deposits, and volcanic rocks—and aquifer-scale proportions were calculated on an area-weighted basis for each of the four aquifer lithologies and for the study unit as a whole (aggregated system). The results of the status assessment indicated that inorganic constituents were present at high and moderate RCs in greater proportions in the SNR study unit aggregated primary aquifer system than were organic constituents and that there were significant differences (p < 0.05) between the four aquifer lithologies. One or more inorganic constituents with health-based benchmarks were present at high RCs in 16 percent of the aggregated primary aquifer system and at moderate RCs in 21 percent. Arsenic (9.7 percent), uranium (2.9 percent), boron (2.0 percent), fluoride (1.8 percent), and nitrate (1.4 percent) were the constituents most commonly present at high RCs. For inorganic constituents with aesthetic-based benchmarks, 18 percent of the aggregated primary aquifer system had high RCs of one or more constituent, and 6.8 percent had moderate RCs. Iron (15.8 percent), manganese (15.1 percent), and total dissolved solids (1.3 percent) were the constituents most commonly present at high RCs. Organic constituents were not detected in 72 percent of the primary aquifer system. One or more organic constituents had high RCs in 0.1 percent of the primary aquifer system, moderate RCs in 3.0 percent, and low RCs in 25 percent. Proportions of the four lithologic primary aquifer systems with high or moderate concentrations of organic constituents were not significantly different. Three organic constituents had area-weighted detection frequencies greater than 10 percent in the primary aquifer system as a whole or at least one of the four lithologic primary aquifer systems: the gasoline oxygenate methyl tert -butyl ether, the trihalomethane chloroform, and the herbicide simazine. The special-interest constituent perchlorate was detected at high RCs in 0.01 percent of the primary aquifer system and at moderate RCs in 1.0 percent, and detection frequencies could be accounted for by the distribution of perchlorate under natural conditions. Statistical tests were used to evaluate relations between constituent concentrations and potential explanatory factors descriptive of land use, geography, depth, geochemical conditions, and groundwater age. Higher concentrations of trace elements, radioactive constituents, and constituents with aesthetic-based benchmarks generally were associated with anoxic conditions, higher pH, and location within a particular compositional band in the Sierra Nevada batholith corresponding to the southwestern part of the study unit. High concentrations of organic constituents generally were associated with greater proportions of urban land use. No significant relations were observed between the concentrations of organic constituents and measures of well depth or groundwater age, perhaps because of the high proportions of springs and modern groundwater in the dataset.

California↗

USGS1999

The ecological condition of estuaries in the Gulf of Mexico

The Gulf of Mexico is a vast natural resource encompassing the coastal areas of western Florida, Alabama, Mississippi, Louisiana, and Texas, as well as a portion of Mexico. Many estuaries flow into the Gulf of Mexico and serve as nursery grounds for fish, habitat for a wide variety of wildlife, shipping routes, and a source of recreation. Estuarine-dependent species constitute more than 95 percent of the commercial fishery harvests from the Gulf of Mexico, and many important recreational fishery species depend on estuaries during some part of their life cycle. Gulf estuaries are diverse and productive ecosystems that provide a variety of valuable resources, including fish and shellfish, recreation, transportation, and water supply. Assessing the overall condition of Gulf of Mexico estuaries required incorporating data from other federal, state, and local monitoring programs to augment the information on ecological indicators collected by the U.S. Environmental Protection Agency’s (USEPA) Environmental Monitoring and Assessment Program (EMAP). The resulting document would provide a synthesis of the available knowledge about the condition of Gulf of Mexico estuaries. This document is intended for use by scientists and other citizens concerned with the ecological condition of estuaries, as well as by managers and lawmakers interested in the sustained use of estuaries for commercial and recreational purposes. It also addresses public concerns about the aesthetic quality of coastal areas vital to tourism and recreation. By producing this report on the ecological condition of estuaries in the Gulf of Mexico, we have taken one step in assessing the health of this environmental resource. We have produced an environmental “report card” to be used as a guide in the evaluation of management decisions and research directions. This report is organized in three parts: (1) an introduction that gives background information on the Gulf of Mexico, estuarine ecology, and the factors that impact estuaries in the gulf, (2) the main section on priority ecological indicators used to measure the condition of estuaries in the gulf and (3) an ecological report card that summarizes the data on ecological indicators and provides a rating of the condition of estuaries in each gulf state and for gulf estuaries overall. Many of the ratings were based on the percent area of estuaries in each state exhibiting degraded or adverse levels of an indicator. Eutrophication, a condition of high nutrients often resulting in low oxygen levels and other adverse effects, is an important water quality concern for estuaries along the gulf coast. The National Oceanic and Atmospheric Administration (NOAA) has compared the Gulf of Mexico to other coastal regions like the middle Atlantic and has ranked the Gulf of Mexico as having the highest number of point sources of nutrients and the highest percentage of land use devoted to agriculture. We evaluated monitoring data for nitrogen, chlorophyll, and dissolved oxygen as indicators of eutrophication. Although most of the estuaries exhibited high nitrogen or chlorophyll or low dissolved oxygen concentrations at least once during a survey, many times these conditions were observed in small rivers or bayous rather than in the entire estuary. Often, the percent area affected was low. The gulf estuaries had moderate conditions overall for nutrients and dissolved oxygen. Definite nutrient problems were observed in >25% of the estuarine area in Louisiana and Texas and definite dissolved oxygen problems were observed in Alabama. Contaminants in estuarine sediments provide evidence of the accumulation of chemicals from anthropogenic sources. We compared the concentrations of sediment contaminants to established guideline values to determine the proportion of estuarine area that could have potential adverse effects on living organisms. Although detectable levels of contaminants were measured in almost every estuary in the Gulf of Mexico, <25% of the estuarine area in all states had contaminant concentrations that exceeded these guidelines. Wetlands are integral parts of estuarine systems. Declining acreage means habitat loss that may be the result of commercial and residential development, hydrologic alterations, or dredge and fill operations. The Gulf of Mexico region contains more than 50% of the coastal wetland acreage in the U.S. and yet it also has the highest rate of coastal wetland loss. Nine of the top ten estuarine drainage areas ranked by total wetland area are in the Gulf of Mexico region. The most current estimates of total wetland loss over the past 200 years range from 41% to 54% for the gulf states. Although coastal wetlands continue to be altered or destroyed, some estimates indicate that the rate of loss has slowed. All gulf states were rated as having severe problems with wetland loss. The condition of benthic (bottom-dwelling) invertebrates, fish and shellfish, birds, and threatened and endangered species was used to evaluate the health of estuarine fauna. Degraded benthic communities inhabited <25% of the estuarine area in all gulf states except for Texas. Commercial fish and shellfish landings may be used as an indicator of population stability while fish biomarkers are used to measure the health of individuals in the population. Commercial landings of the top four fisheries (shrimp, menhaden, blue crab, and oyster) are stable in the gulf states while fish biomarkers indicate fair to poor fish health in Alabama and Texas and good fish health elsewhere. Coastal and marine bird populations appear to be in good condition throughout the gulf. Four threatened or endangered species inhabit coastal areas in the Gulf of Mexico: brown pelican, Gulf sturgeon, manatee, and Kemp’s ridley sea turtle. In general, populations of these species are in good to fair condition in the gulf states. Public health indicators include shellfish bed closures and chemicals found in edible fish tissue. Harvest of shellfish (primarily oyster in the Gulf of Mexico) is restricted or prohibited when concentrations of bacteria or other pathogens reach levels that could impair human health. The gulf states contain the most acreage of shellfish-growing waters in the U.S. but also have the most acreage restricted for harvest. All gulf states except Mississippi have >25% of their shellfish-growing waters restricted for harvest, mostly due to pollution from wastewater treatment plants or other upstream sources. Advisories may be issued that limit consumption when the concentrations of chemicals in fish tissue exceed levels known to be harmful to humans. Although seafood consumption advisories have been issued in all gulf states, the percent of the fish population with high concentrations of contaminants is relatively low in the gulf overall.

Alabama, Florida, Louisiana, Mississippi, Texas↗

USGS2023

Application of the Stream Salmonid Simulator (S3) model to assess fall Chinook salmon (Oncorhynchus tshawytscha) production in the American River, California

Executive Summary Anadromous fish returning to the lower American River are restricted to 36 kilometers of free-flowing river between Nimbus Dam and American River’s confluence with the Sacramento River, California. Salmon in the American River provide an important freshwater recreational fishery. However, annual salmon production in the American River in recent years has been low relative to the mid-1990s (Surface Water Resources, Inc., 2001). To investigate the low production of fall-run Chinook salmon ( Oncorhynchus tshawytscha ), the Bureau of Reclamation requested that the U.S. Geological Survey apply the Stream Salmonid Simulator (S3) model to the population of fall-run Chinook salmon on the American River. The American River was chosen among seven candidate Sacramento Basin rivers for S3 application. The American River was selected because of its management and public interest, recently low anadromous fish production, and rich time series of key demographic data needed for S3 application. Data that were not available, however, were empirical estimates on juvenile salmon habitat suitability in the American River. Therefore, a large component of applying S3 to the American River was devoted to the estimation of juvenile salmon habitat suitability and capacity. This entailed snorkeling the lower American River for 3 weeks in March 2021 during the early out-migration period for juvenile Chinook salmon. These efforts were fruitful and showed that the typically small fish (<55 millimeters) in the American River preferred much shallower depths than predicted by habitat suitability criteria derived from the literature for this population. Having empirical estimates on juvenile salmon in the American River provided a solid foundation from which to simulate the population using the S3 model. The S3 model is a spatially explicit population model that runs on a daily time step to simulate redd superimposition, egg maturation, fry emergence and the subsequent growth, survival, and emigration of juvenile Chinook salmon from the river. The key features of this model relevant to this report include (1) a temperature-dependent bioenergetics model driving daily growth rates; (2) density-dependent dynamics that are influenced by the effect of flow on suitable habitat area; and (3) within-year habitat, river flow, and water temperature effects specific to spawning, egg incubation, and fry, parr, and smolt life stages. We used estimates of spawning escapement and geo-referenced redd locations to quantify the spatial and temporal distribution of female spawners for brood years 2014–19. These estimates of female spawners initiate the simulation of each year’s juvenile salmon emergence and emigration over a spatial domain extending from Nimbus Dam to the river’s confluence with the Sacramento River. Using weekly estimates of juvenile salmon abundance and size (fork length) that passed the Watt Avenue fish trap (river kilometer 14.7), we calibrated the S3 model by estimating three key demographic parameters for each year, y : (1) S y , the average daily survival probability, (2) M 0y , the intercept for density-dependence in movement, representing the average daily probability of remaining in a habitat at zero abundance, and (3) C y , the average daily proportion of maximum consumption. These parameters were obtained by minimizing the Mallow’s distance (Lupu and others, 2017) between distributions of weekly abundances and sizes of fish at the traps and weekly simulated abundances and sizes (by S3). Investigation of model fit showed excellent agreement between simulated annual abundances and the abundance of fish passing the fish trap. However, when we compared weekly abundances at the fish trap, S3 under-predicted peaks and over-predicted troughs in the time series of weekly abundances at the fish trap. Thus, some unknown within-year effects have yet to be identified and incorporated in the S3 model. Identifying these important effects and incorporating them in the S3 model would help explain the lack of fit between estimated and simulated weekly abundances. We estimated parameters for 6 years that included a wide range of female spawner abundances (3,057–10,753) and water year types (Critical–Wet). We contrast our estimated parameters to the corresponding number of female spawners and the water year type for the Sacramento Valley. By happenstance, years having higher annual spawner abundances concurred with Critical to Dry water year types. Estimates of survival trended lower with higher spawner abundances and Critical to Dry conditions. In contrast, the extremely wet water year of 2017 had the lowest M 0y , suggesting less density-dependence in fish movement, and the lowest C y , suggesting lower average consumption in this year. When this high-flow year was excluded, a trend towards higher probabilities of fish remaining in a habitat at low abundance and lower proportions of maximum consumption was apparent from Critical to Wet conditions, but only 5 years of data were included. Except for 2017, daily proportions of maximum consumption were relatively high ( C y > 0.83), suggesting that fish were feeding at reasonably high proportions relative to the expected maximum consumption as defined by the “Wisconsin” bioenergetics model (Stewart and Ibarra, 1991). Survival estimates from fry emergence to outmigration at the Sacramento River confluence were generally low when integrated over time. The highest daily survival probability was S y = 0.93 in 2019, or 50 percent total mortality after 10 days. In contrast, our lowest daily survival probability was S y = 0.74 in 2015, or 95 percent total mortality after 10 days. Consequently, even our highest estimated daily survival probability might be considered low. This is especially true given that S y was estimated over a relatively short distance (<14.7 kilometers) from emergence to the Watt Avenue fish trap. Several factors, including our assumed and relatively high daily egg survival rate of 0.9975, could influence juvenile survival estimates. For example, an egg survival rate of 0.9975 results in 3-percent total mortality after 10 days. Egg mortality estimates used in S3 calibration were approximated from egg survivorship studies in the Yakima River, Washington (Johnson and others, 2012), and remains one of the greater uncertainties in S3 when estimating survival across life stages. By including bona fide estimates of egg survival in S3 simulations, the validity of the S3’s current daily egg survival rate could be assessed specifically for the American River. Tagging studies also could provide S3 with direct estimates of juvenile survival and movement; survival during egg incubation then could be estimated indirectly via model fitting.

California↗

USGS1974

Population ecology of the mallard: II. Breeding habitat conditions, size of the breeding populations, and production indices

This report, the second in a series on a comprehensive analysis of mallard population data, provides information on mallard breeding habitat, the size and distribution of breeding populations, and indices to production. The information in this report is primarily the result of large-scale aerial surveys conducted during May and July, 1955-73. The history of the conflict in resource utilization between agriculturalists and wildlife conservation interests in the primary waterfowl breeding grounds is reviewed. The numbers of ponds present during the breeding season and the midsummer period and the effects of precipitation and temperature on the number of ponds present are analyzed in detail. No significant cycles in precipitation were detected and it appears that precipitation is primarily influenced by substantial seasonal and random components. Annual estimates (1955-73) of the number of mallards in surveyed and unsurveyed breeding areas provided estimates of the size and geographic distribution of breeding mallards in North America. The estimated size of the mallard breeding population in North America has ranged from a high of 14.4 million in 1958 to a low of 7.1 million in 1965. Generally, the mallard breeding population began to decline after the 1958 peak until 1962, and remained below 10 million birds until 1970. The decline and subsequent low level of the mallard population between 1959 and 1969 .generally coincided with a period of poor habitat conditions on the major breeding grounds. The density of mallards was highest in the Prairie-Parkland Area with an average of nearly 19.2 birds per square mile. The proportion of the continental mallard breeding population in the Prairie-Parkland Area ranged from 30% in 1962 to a high of 600/0 in 1956. The geographic distribution of breeding mallards throughout North America was significantly related to the number of May ponds in the Prairie-Parkland Area . Estimates of midsummer habitat conditions and indices to production from the July Production Survey were studied in detail. Several indices relating to production showed marked declines from west to east in the Prairie-Parkland Area , these are: (1) density of breeding mallards (per square mile and per May pond), (2) brood density (per square mile and per July pond), (3) average brood size (all species combined), and (4) brood survival from class II to class III. An index to late nesting and renesting efforts was highest during years when midsummer water conditions were good. Production rates of many ducks breeding in North America appear to be regulated by both density-dependent and density-independent factors. Spacing of birds in the Prairie-Parkland Area appeared to be a key factor in the density-dependent regulation of the population. The spacing mechanism, in conjunction with habitat conditions, influenced some birds to overfly the primary breeding grounds into less favorable habitats to the north and northwest where the production rate may be suppressed. The production rate of waterfowl in the Prairie Parkland Area seems to be independent of density (after emigration has taken place) because the production index appears to be a linear function of the number of breeding birds in the area. Similarly, the production rate of waterfowl in northern Saskatchewan and northern Manitoba appeared to be independent of density. Production indices in these northern areas appear to be a linear function of the size of the breeding population. Thus, the density and distribution of breeding ducks is probably regulated through a spacing mechanism that is at least partially dependent on measurable environmental factors. The result is a density-dependent process operating to ultimately effect the production and production rate of breeding ducks on a continent-wide basis. Continental production, and therefore the size of the fall population, is probably partially regulated by the number of birds that are distributed north and northwest into environments less favorable for successful reproduction. Thus, spacing of the birds in the Prairie-Parkland Area and the movement of a fraction of the birds out of the prime breeding areas may be key factors in the density-dependent regulation of the total mallard population.

Resource Publication↗

USGS2015

Status and understanding of groundwater quality in the Northern Coast Ranges study unit, 2009: California GAMA Priority Basin Project

Groundwater quality in the 633-square-mile (1,639-square-kilometer) Northern Coast Ranges (NOCO) study unit was investigated as part of the Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) Program and the U.S. Geological Survey (USGS) National Water-Quality Assessment Program. The study unit is composed of two study areas (Interior Basins and Coastal Basins) and is located in northern California in Napa, Sonoma, Lake, Colusa, Mendocino, Glenn, Humboldt, and Del Norte Counties. The GAMA-PBP is being conducted by the California State Water Resources Control Board in collaboration with the USGS and the Lawrence Livermore National Laboratory. The GAMA NOCO study was designed to provide a spatially unbiased assessment of the quality of untreated (ambient) groundwater in the primary aquifer system within the study unit. The assessment is based on water-quality and ancillary data collected in 2009 by the USGS from 58 sites and on water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer system is defined by the perforation intervals of sites listed in the CDPH water-quality database for the NOCO study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallow or deep water-bearing zones. The first component of this study, the status assessment of the current quality of the groundwater resource, was performed by using data from samples analyzed for inorganic constituents (such as trace elements and major and minor ions), organic constituents (volatile organic compounds and pesticides and pesticide degradates), the special-interest constituent perchlorate, and microbial indicators. This status assessment is intended to characterize the quality of groundwater resources in the primary aquifer system of the NOCO study unit, not the quality of treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal or California regulatory or nonregulatory benchmarks for drinking-water quality. A relative-concentration greater than (>) 1.0 indicates a concentration greater than a benchmark, and a relative-concentration less than or equal to (≤) 1.0 indicates a concentration less than or equal to a benchmark. Relative-concentrations of organic constituents and perchlorate were classified as “high” (relative-concentration >1.0), “moderate” (0.1 < relative-concentration ≤1.0), or “low” (relative-concentration ≤0.1). Relative-concentrations of inorganic constituents were classified as “high” (relative-concentration >1.0), “moderate” (0.5 < relative-concentration ≤1.0), or “low” (relative-concentration ≤0.5). Aquifer-scale proportion was used as the primary metric in the status assessment for evaluating regional-scale groundwater quality. High aquifer-scale proportion was defined as the percentage of the area of the primary aquifer system with a relative-concentration >1.0 for a particular constituent or class of constituents; the percentage is based on an aerial rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifer system with moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially weighted—were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable in the NOCO study unit (within 90 percent confidence intervals). Inorganic constituents (one or more) with health-based benchmarks were detected at high relative-concentrations in 10.3 percent and at moderate relative-concentrations in 13.8 percent of the primary aquifer system. The high aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of boron (in 8.6 percent of the primary aquifer system), arsenic (in 3.4 percent), and barium (in 1.7 percent). Inorganic constituents with aesthetic-based benchmarks were detected at high relative-concentrations in 39.7 percent and at moderate relative-concentrations in 10.3 percent of the primary aquifer system. The constituents present at high relative-concentrations were iron (25.9 percent) and manganese (39.7 percent). Relative-concentrations of organic constituents with health-based benchmarks (one or more) were high in 0.2 percent, moderate in 1.7 percent, and low in 39.7 percent of the primary aquifer system. Organic constituents were not detected in 58.4 percent of the primary aquifer system. Of the 168 organic constituents analyzed, 11 constituents were detected. Two organic constituents had detection frequencies >10 percent: the trihalomethane chloroform and the herbicide simazine. For the 10 detected organic constituents that had health-based benchmarks, nearly all detections had low relative-concentrations. The special-interest constituent perchlorate was detected at moderate relative-concentrations in 1.7 percent and at low relative-concentrations in 22.4 percent of the primary aquifer system. Perchlorate was not detected in 75.9 percent of the primary aquifer system. The second component of this study, the understanding assessment , evaluated relations between constituent concentrations and values of selected potential explanatory factors to identify the factors potentially affecting the concentrations and occurrences of constituents found at high relative-concentrations or, for organic constituents, with detection frequencies >10 percent. The potential explanatory factors evaluated were land use (including density of septic tanks and leaking or formerly leaking underground fuel tanks), well construction (well depth and depth to the top of the perforated interval in the well), hydrologic conditions (aridity index, field water temperature, and distance to nearest hot spring and geothermal well), pH, dissolved oxygen concentration, study area, groundwater age distribution, and geochemical conditions. High and moderate relative-concentrations of boron primarily occurred in the Interior Basins study area and may be attributed to groundwater interacting with hydrothermal systems. High and moderate relative-concentrations of boron were associated with elevated groundwater temperatures, groundwater chemistry characteristics similar to those of geothermal waters, and distance to known geothermal areas. Boron concentrations generally were higher where low dissolved oxygen concentrations or anoxic conditions exist. High and moderate relative-concentrations of arsenic predominantly occur in the Interior Basins study area under reducing conditions. Arsenic concentrations also may be influenced by hydrothermal systems (when present). Chloroform, simazine, and perchlorate were observed in the Interior Basins and Coastal Basins study areas, predominantly at shallow sites with top-of-perforation depths ≤70 feet below land surface, with modern water (post-1950s), and with oxic groundwater conditions.

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USGS2012

Status and understanding of groundwater quality in the two southern San Joaquin Valley study units, 2005-2006 - California GAMA Priority Basin Project

Groundwater quality in the southern San Joaquin Valley was investigated from October 2005 through March 2006 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project is conducted by the U.S. Geological Survey (USGS) in collaboration with the California State Water Resources Control Board and the Lawrence Livermore National Laboratory. There are two study units located in the southern San Joaquin Valley: the Southeast San Joaquin Valley (SESJ) study unit and the Kern County Subbasin (KERN) study unit. The GAMA Priority Basin Project in the SESJ and KERN study units was designed to provide a statistically unbiased, spatially distributed assessment of untreated groundwater quality within the primary aquifers. The status assessment is based on water-quality and ancillary data collected in 2005 and 2006 by the USGS from 130 wells on a spatially distributed grid, and water-quality data from the California Department of Public Health (CDPH) database. Data was collected from an additional 19 wells for the understanding assessment. The aquifer systems (hereinafter referred to as primary aquifers) were defined as that part of the aquifer corresponding to the perforation interval of wells listed in the CDPH database for the SESJ and KERN study units. The status assessment of groundwater quality used data from samples analyzed for anthropogenic constituents such as volatile organic compounds (VOCs) and pesticides, as well as naturally occurring inorganic constituents such as major ions and trace elements. The status assessment is intended to characterize the quality of untreated groundwater resources within the primary aquifers in the SESJ and KERN study units, not the quality of drinking water delivered to consumers. Although the status assessment applies to untreated groundwater, Federal and California regulatory and non-regulatory water-quality benchmarks that apply to drinking water are used to provide context for the results. Relative-concentrations (sample concentration divided by benchmark concentration) were used for evaluating groundwater. A relative-concentration greater than 1.0 indicates a concentration greater than the benchmark and is classified as high. The relative-concentration threshold for classifying inorganic constituents as moderate or low was 0.5; for organic constituents the threshold between moderate and low was 0.1. Aquifer-scale proportion was used as the primary metric for assessing the quality of untreated groundwater for the study units. High aquifer-scale proportion is defined as the areal percentage of the primary aquifers with a high relative-concentration for a particular constituent or class of constituents. Moderate and low aquifer-scale proportions were defined as the areal percentage of the primary aquifers with moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially weighted—were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable for the two study units in the southern San Joaquin Valley (within 90 percent confidence intervals). The status assessment showed that inorganic constituents were more prevalent than organic constituents and that relative-concentrations were higher for inorganic constituents than for organic constituents. For inorganic constituents with human-health benchmarks, the relative-concentration of at least one constituent in the SESJ study unit was high in 30 percent of the primary aquifers. In the KERN study unit, the relative-concentration of at least one constituent was high in 23 percent of the primary aquifers. In the SESJ and KERN study units, the inorganic constituents with human-health benchmarks detected at high relative-concentrations in more than 2 percent of the primary aquifers were arsenic, boron, vanadium, nitrate, uranium, and gross alpha radioactivity. Additional constituents with human-health benchmarks—antimony, radium, and fluoride—were detected at high relative-concentrations in the KERN study unit. For inorganic constituents with aesthetic benchmarks (secondary maximum contaminant levels, SMCLs), the relative-concentration of at least one constituent in the SESJ study unit was high in 6.6 percent of the primary aquifers. In the KERN study unit, the relative-concentration of at least one constituent was high in 22 percent of the primary aquifers. Inorganic constituents with aesthetic benchmarks detected at high relative-concentrations in the primary aquifers in the SESJ and KERN study units were iron and manganese. Additional constituents with aesthetic benchmarks—total dissolved solids (TDS), sulfate, and chloride—were detected at high relative-concentrations in the KERN study unit. In contrast, the status assessment for organic constituents with human-health benchmarks showed that relative-concentrations were high in 4.8 percent and 2.1 percent of the primary aquifers in the SESJ and KERN study units, respectively. The special-interest constituent, perchlorate, was detected at high relative-concentrations in 1.2 percent of the primary aquifers in the SESJ study unit. Twenty-eight of the 78 VOCs (not including fumigants) analyzed were detected. Of these 28 VOCs, benzene had high relative-concentrations in the SESJ study unit, and relative-concentrations for the other 27 VOCs were moderate and low. Five of the 10 fumigants were detected; 1,2-dibromo-3-chloropropane (DBCP) was the only fumigant with high relative-concentrations in the SESJ and KERN study units. Of the 136 pesticides and pesticide degradates analyzed, 33 were detected. Human-health benchmarks were established for eighteen of the detected pesticides. Dieldrin was detected at moderate relative-concentrations in the SESJ and KERN study units. All other pesticides detected with human-health benchmarks were present at low relative-concentrations. The detection frequencies for two of these pesticides—simazine and atrazine—were greater than or equal to 10 percent in the SESJ and KERN study units. The understanding assessment of groundwater quality included an analysis of correlations of selected water-quality constituents or classes of constituents with potential explanatory factors. The understanding assessment indicated that the concentrations of many trace elements and major ions were correlated to well depth, groundwater age, and/or geochemical conditions. Many trace elements were positively correlated with depth. Arsenic, boron, vanadium, fluoride, manganese, and iron concentrations increased with well depth or depth to top-of-perforations. The concentrations for these trace elements also were higher in older (pre-modern) groundwater. In contrast, uranium concentrations decreased with increasing depth and groundwater age. Most trace elements were correlated to geochemical conditions. Arsenic, antimony, boron, fluoride, manganese, and iron concentrations generally were higher wherever the pH of the groundwater was greater than 7.6. Concentrations for these constituents generally were higher at low concentrations of dissolved oxygen (DO). Uranium was the exception; uranium concentrations generally were lower at high pH and at high concentrations of DO. Nitrate concentrations generally were lower in deeper wells. Nitrate concentrations also were higher in groundwater with higher DO. Total dissolved solids, sulfate, and chloride concentrations were higher in the KERN study unit than in the SESJ study unit. Total dissolved solids were negatively correlated with pH in the KERN study unit. Total dissolved solids and sulfate were higher in areas with more agricultural land use. Chloride concentrations increased with depth to top-of-perforations in the KERN study unit. Organic constituents and constituents of special interest, like many inorganic constituents, were correlated with well depth, groundwater age, and DO. Unlike most trace elements, however, solvent and pesticide detections, and total trihalomethanes (THM), DBCP, and perchlorate concentrations decreased with increasing well depth. Volatile organic compound, solvent, and pesticide detections, and THM concentrations also were lower in older (pre-modern) groundwater than in modern-age groundwater. Solvent detections and total THM, DBCP, and perchlorate concentrations increased with increasing DO concentrations.

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